TNG HP CU HI L THUYT HAY V KH Cu 1.

Cho cc phn ng sau: (a) CuO + HCl (c) (b) K2Cr2O7 + HCl (c) (c) Cu + NaNO3 + HCl (d) Zn + H2SO4 (long) (e) Mg + HNO3(long) (g) CaCO3 + HNO3 (c) (h) FeCO3 + H2SO4 (long) (i) FeSO4 + KMnO4 + H2SO4 (long) S phn ng m ion H+ ca axit ng vai tr cht oxi ha l A. 1. B. 3. C. 2. D. 4. Cu 2. Cho cc pht biu sau: (a) Dung dch natri isopropylat trong nc c th lm qu tm ha xanh. (b) Dung dch axit axetic c th ha tan c CuO to thnh dung dch c mu xanh. (c) Oxi ha ancol bc mt bng CuO (to) thu c xeton. (d) Naphtalen tham gia phn ng th brom kh hn so vi benzen. (e) Phn ng tch H2O t ancol etylic dng iu ch etilen trong cng nghip. (g) Benzen c th tham gia phn ng th v phn ng cng clo. S pht biu ng l A. 3. B. 4. C. 2. D. 5. Lin kt cng ho tr l lin kt c to nn gia hai nguyn t bng mt hay nhiu cp electron dng chung Cu 3:Thc hin cc th nghim sau: (a) Cho dung dch FeCl2 tc dng vi dung dch AgNO3 d. (b) Cho Cl2 tc dng vi toluen trong iu kin chiu sng (khng c xc tc). (c) Sc kh HI vo dung dch FeCl3. (d) Cho Fe3O4 tc dng vi dung dch HCl. (e) Sc kh axetilen vo dung dch brom trong dung mi CCl4. S th nghim xy ra phn ng oxi ha - kh l A. 3. B. 4. C. 2. D .5. Cu 4:Hp cht T c to bi 4 nguyn t ca 2 nguyn t phi kim R v X (s hiu nguyn t ca R nh hn s hiu nguyn t ca X). Tng s ht mang in trong mt phn t T l 20. Pht biu sai l: Gii: T l NH3 (Ni N c ha tr V thc ra khng ng, v N c cu hnh e l 1s2 2s2 2p3, c 3e c thn nn ch c ha tr III thi. Nu tnh thm LK cho nhn nh N2O5 th l IV. Cn P th khc. P cng c ha tr III nh N (VD PH3) nhng do P c phn lp 3d trng nn khi b kch thch, electron 3s ca P s "nhy" sang to thnh 5e c thn, nn P c ha tr V (VD PCl5)) A. Hp cht T c th to c lin kt hiro vi nc. B. Trong cc hp cht vi cc nguyn t khc, R c th c s oxi ha bng -1. C. trng thi kch thch, nguyn t nguyn t X c 5 electron c thn. D. Trong phn t T, nguyn t X trng thi lai ha sp3.(3 ni n) Cu 5:. Cho dy cc cht: benzyl axetat, vinyl axetat,metyl fomat, anlyl clorua, phenyl fomat, isopropyl clorua, triolein. S cht trong dy khi thy phn trong dung dch NaOH (d), un nng sinh ra ancol l A. 4. B.6. C. 5. D. 3.

Cu 6:. Cho cc pht biu sau: (a) C th dng nc brom phn bit saccaroz v mantoz. (b) C th phn bit saccaroz v mantoz bng phn ng vi dung dch AgNO3 trong NH3. (c) Trong dung dch, saccaroz v mantoz u ha tan Cu(OH)2 nhit thng cho dung dch mu xanh lam. (d) Trong dung dch, saccaroz tn ti ch yu dng mch h. (e) Trong mi trng baz, saccaroz v mantoz c th chuyn ha ln nhau. (g) Trong phn t saccaroz c nhm -OH hemiaxetal. S pht biu ng l A. 5. B. 4. C. 3. D. 2. Cu 7. Tin hnh cc th nghim sau: (a) Cho dung dch Ba(OH)2 vo dung dch NaHCO3. (b) Cho dung dch Al2(SO4)3 ti d vo dung dch NaAlO2 (hoc dung dch Na[Al(OH)4]. (c) Sc kh CH3NH2 ti d vo dung dch FeCl3. (d) Sc kh propilen vo dung dch KMnO4. (e) Sc kh CO2 vo dung dch Na2SiO3. (g) Sc kh H2S vo dung dch SO2. (h) Sc kh NH3 ti d vo dung dch AgNO3. Sau khi cc phn ng kt thc, c bao nhiu th nghim thu c kt ta? A. 6 B. 3 C. 5 D. 4 Cu 8 Cho dy cc cht: Cr(OH)3, CrO3, ZnO, Ca(HCO3)2, Al(OH)3, CrO, CO2, NO2, P2O5, N2O5, PCl5, Al4C3. S cht tc dng c vi dung dch NaOH long, ngui l A. 10. B. 11. C. 9. D. 12. Cu 9. Trong cc th nghim sau: (a) Cho kh O3 tc dng vi dung dch KI. (b) Nhit phn amoni nitrit. (c) Cho NaClO tc dng vi dung dch HCl c. (d) Cho kh H2S tc dng vi dung dch FeCl3. (e) Cho kh NH3 tc dng vi kh Cl2. (g) Cho dung dch H2O2 tc dng vi dung dch cha KMnO4 v H2SO4 (long). (h) Sc kh O2 vo dung dch HBr.(axit HI, HBr c tnh kh lu ngy trong kk b ha nu do b O2 oxi ha, to n cht Br2) (i) Cho NaI tc dng vi dung dch axit H2SO4 c, nng. (k) Cho SiO2 tc dng vi Na2CO3 nng chy. S th nghim to ra n cht l A. 5 B. 8 C. 7 D. 6 Cu 10:Pht biu khng ng l: A. Vt liu compozit, vt liu nano, vt liu quang in t l nhng vt liu mi c nhiu tnh nng c bit. B. Cc kh SO2, NO2 gy ma axit, kh CO2 gy hiu ng nh knh cn hp cht CFC gy thng tng ozon. C. Cc cht: Penixilin, amphetamin, erythromixin thuc loi thuc khng sinh, cn: Seduxen, moocphin, ampixilin thuc loi cht gy nghin. D. Vic s dng cc cht: Fomon, ure, hn the, phn m trong bo qun v ch bin thc phm l vi phm v sinh an ton thc phm. Cu 11: . Pht biu no sau y l sai? A. Tnh axit ca HF yu hn tnh axit ca HI.

B. Nhit si ca hiro florua cao hn nhit si ca hiro clorua. C. Tnh kh ca HCl mnh hn tnh kh ca HBr. D. Bn knh ca ion F- nh hn bn knh ca ion ClCu 12: t chy hon ton 18 gam mt este X n chc thu c 20,16 lt CO2 (ktc) v 12,96 gam nc. mt khc nu cho 21 gam X tc dng vi 200 ml dd KOH 1,2M sau c cn dd thu c 34,44 gam cht rn khan. Cng thc phn t ca axit to ra X l: A.C5H6O3 B. C5H8O3 C. C5H10O3 D. C5H10O2 y l este vng Cu 13: Cho cc cht: isobutan, isobutilen, isopren, vinyl axetilen, ivinyl, metylxiclopropan, toluen, naphtalen, xiclohexan, xiclohexen. Trong s cc cht trn, s cht phn ng c vi nc brom l A. 7. B. 6. C. 4. D. 5. Cu 14: Cho cc cht sau: C2H2; PROPIN; CH2=CHCH3; C2H3CH2CH2CH3; C2H4Cl2; C4H10; CH3CHO; C2H5OH; CH3COONa; C6H5CH2CH3. C bao nhieu cht trong s cc cht trn bng 1 phn ng duy nht iu ch c axit axetic: A. 6 B. 7 C. 8 D. 9 Cu 15:Nu in phn cc dung dch mui Na ca cc ion Cl- ,Br- ,I- cng nng mol th hi cng mt thi gian no dd no c pH cao nht? A. Cl- B. Br- C. Br- v I- D. ICu 16: C cc pht biu sau: 1. CO km bn v nhit, rt c. 2. Trong cng nghip sn xut Iot t rong bin. 3. iu ch Flo trong cng nghip bng cch in phn hn hp gm KF v NaF iu kin thch hp 4. than xng dng lm cht n cao su, sn xut mc in giy v xi nh giy. 5. C c 2 dng th hnh l kim cng v than ch. 6. Si c 2 th hnh l tinh th v v nh hnh 7. SiO2 c phn ng vi MgCO3 nhit cao. 8. iu ch than g bng cch t chy g trong oxi d. 9. thnh phn chnh ca t st l bng thch(criolit)-Na3AlF6 10. iu ch than than ch t than m, iu ch than mui bng cch nhit phn metan c xc tc S cc pht biu khng ng l: A. 5 B. 6 C. 8 D.7 Cu 17: C cc pht biu sau: 11. glucozo c 2 loi tinh th kt tinh c nhit nng chy khc nhau. Nhm OH hemiaxetal v tr C1 khi chuyn thnh nhm OCH3 th dng vng khng chuyn sang dng mch h c na. 12. trong mu ngi c nng n nh ca glucozo l 0,1%, nc dch glucozo dng cho bnh nhn c nng 5%. Trong y hc glucozo dng lm cht chuyn ha. 13. trong y hc ZnO dng lm thuc gim au dy thn kinh cha bnh nga, chm, eczema 14. trong y hc trn cc kh N2O vi O2 t l th tch 1:4 dng lm thuc gy m cho cc ca m nh 15. photgen c dng lm thuc gim au. 16. hidroquinon v catechol l hai ng phn c cng cng thc phN t C6H4(OH)2 17. Trong dung dch glucozo tn ti ch yu dng mch vng 6 cnh(anpha hoc beta) 18. Trong dung dch fructozo tn ti ch yu dng vng 5, 6 cnh(beta) 19. hn hp tecmit bao gm Al v oxit st, dng lm phng tin hn ni trong c kh. 20. t chy du iezen s c kh c bay ra nh SO2, H2S, CO2 S pht biu ng l:

A. 7 B. 4 C. 5 D.8 Cu 11: c cc pht biu sau: 1. phng php iu ch Oxi trong phng th nghim l in phn nc v chng ct phn on khng kh lng. 2. amophot l phn bn hn hp, nitrophotka l phn bn phc hp. 3. anilin iu kin thng l cht lng mu trng, khi b oxi ha ha en. 4. cacbon chy c trong oxi v ozon, PbS mu en chuyn mu trng khi tc dng vi ozon iu kin thng. 5. ozon l cht ty trng trong cng nghip, oxi l nguyn t ph bin nht trong v tri t. 6. Flo d dng thay th oxi trong nc ngay iu kin thng. 7. iu kin thng, fomandehit l cht kh, tan trong nc to dung dch km bn. 8. trng thi kch thch cc phn t ozon c th va chm mnh v gy n ln. 9. Flo c m in ln nht trong tt c cc nguyn t nn flo d dng phn ng vi Si, Cr nhit thng. 10. trong mui n lun c mt hm lng nh KIO3 11. axeton phn ng vi axit HCN to sn phm khng bn l xianohrin S pht biu khng ng l: A. 4 B. 5 C. 6 D. 7 Cu 12: c cc pht biu sau: 1. photpho trng, tinh th iot, nc c cu trc mng tinh th nguyn t. 2. photgen c cng thc l POCl3, photphoryl clorua c cng thc COCl2 3. phn bn m amoni nn bn vo t t chua, hoc c kh trc bng CaO 4. phn m nitrat Ca(NO3)2 c tc dng kch thch cy trng ra nhiu l, nhiu hoa, thch hp vi t chua. 5. phn ln cn thit cho cy trng thi k sinh trng do thc y qu trnh sinh ha, trao i cht v nng lng thc vt. 6. dinh dng ca phn Kali c nh gi bng hm lng K2O, phn kali gip cy hp th m tt hn cn thit cho vic to cht ng, cht bt, cht x, cht du, tng cng sc chng bnh, chng rt, chu hn ca cy. 7. Trong cng ngh m phm, hidroquinon c dng 1 lng nh lm kem dng da. 8. phenol l axit yu nht, HClO4 l mt trong nhng axit mnh nht trong tt c cc axit 9. trong cng nghip, anken c iu ch bng phn ng ehiro ha ankan 10. trong cng nghip CO2 c diu ch t vic t chy than. S pht biu ng l: A. 7 B. 8 C. 9 D.10 Cu 13: c cc pht biu sau: 1. phenol iu kin thng l cht rn khng tan, cn gi l axit phenic. 2. tetralin v ecalin, clorofom, axeton dng lm dung mi. Naphtalen sn xut dc phm trong cng nghip, iu ch naphtol, anhidrit naphtalic, naphtylamin. 3. axeton dng sn xut bisphenol, clorofom v ioofom. 4. nhit thp, but-2-in tc dng vi brom d to sn phm tetrabrom. 5. nhit cao, ankadien u tin to sn phm cng 1,4; c mt cht xc tc Cl2,Br2 th c th cng vo 2 lin kt C=C. 6. anken, ankadien, benzen, trong phn t ca chng cc nguyn t C v H u cng nm trn cng 1 mt phng. 7. trong phn t ankin, cc nguyn t C nm trn cng mt ng thng. Trong phn t xicloankan tr xiclo propan th cc xicloankan khc u c C khng cng nm trn mt mt phng. 8. anilin phn ng vi dung dch hn hp NaNO2 v KHSO4 to n cht kh tr. 9. benzen, stiren, naphtalen l cc cht lng khng mu, nh hn nc v khng tan trong nc. 10. SiO2 l oxit axit, d tan trong kim nng chy v khng tan trong axit. S pht biu ng l: A. 9 B. 6 C.10 D.8 Cu 14: c cc pht biu sau: 1. Qung malachit c cng thc Cu(OH)2.Cu(CO)3. qung hematit nu c cng thc Fe2O3.nH2O, thnh phn chnh

ca t st l cao lanh: Al2O3.2SiO2.2H2O. 2. c 4 cht hu c mch h c cng thc C2H2On tc dng vi AgNO3/NH3 to kt ta. 3. trong mng tinh th kim loi ch c cc nguyn t kim loi cc nt mng tinh th. 4. Cr khng tc dng vi dung dch kim v HNO3 long, Cr2O3 d tan trong dung dch kim long 5. c 3 cng thc cu to ca hp cht l ng phn ca Toluen tham gia phn ng vi AgNO3/NH3 to kt ta vng nht. 6. iu ch butan t etannol cn ti thiu 2 phn ng. 7. clorua vi c dng ph bin hn nc Javen, HNO3 c dng ph bin hn H2SO4 trong lnh vc sn xut v i sng. 8. trong t nhin khng tn ti Si trng thi t do, tn ti dng hp cht: SiO2,cc khong vt silicat, aluminosilicat nh cao lanh, mica fenspat, x vn v thch anh. 9. dung dch ha tan kh hidro sunfua va c tnh kh, va c tnh oxi ha. HNO3 l cht oxi ha kh. 10. thuc u que dim c cha KClO3 ng vai tr cht oxi ha. 11. cc ankan t C2-C4 l cht kh khng mi, t C5-C8 l cht lng c mi xng, C10-C14 c mi du ha. S pht biu ng l: A. 7 B. 8 C. 9 D. 11 Cu 15: Cho hp cht c cng thc phn t C2H2On, s cht khi phn ng vi AgNO3/NH3 to kt ta l: gm 4 cht l C2H2; (CHO)2,; (HCO)2O; HOOC-CHO Cu 16: Cho 4 hp cht hu c c cng thc phn t ln lt l CH2O, CH2O2, C2H2O3, C2H4O2, C3H6O3. S cht mach ho va tc dng vi dung dch NaOH, va c phn ng trng gng l A6B4C5D3 Li gii: HCOOH, HOOC-CHO, HCOOCH3, HCOOCH2CH2OH(c 2), HCOOCH2OCH3. Vy l 6 ha. NI DUNG BM ST THI I HC-TRNG TM Cu 17: tng h s nguyn ti gin sau khi cn bng hai phng trnh ha hc sau ln lt l: (a): FeSO4 + KMnO4 + KHSO4 - Fe2(SO4)3 + K2SO4 + MnSO4 + H2O (b): K2SO3 + KMnO4 + KHSO4 K2SO4 + MnSO4 + H2O A. 52-27 B. 56-28 C. 52-28 D. 56-26 Cu 18: cho cc cht: bc axetilua, metan; 1,2-icloetan; canxi cacbua; propan; etyl clorua; metanol; etanol; nhm cacbua. S cht iu ch etanal bng hai phn ng ha hc l: A-5 B-6 C-7 D-8 Cu 19: s cng thc cu to ca hp cht l ng phn ca Toluen m tham gia phn ng vi AgNO3/NH3 l: A. 1 B. 5 C. 4 D. 2 Cu 19: Cho cc phn ng: Trong cc phn ng trn c bao nhiu phn ng l oxh-kh, bao nhiu phn ng oxi ha kh ni phn t: A. 7 4 B. 6 4 C. 5 4 D. 6 2 Cu 20: cho cc dung dch sau: (1): K2Cr2O7 + H2SO4; (2): H2SO4 c; (3): Na2S; (4): HCl; (5): KBr; (6): Fe(NO3)2. Trn ln lt cc dung dch vi nhau tng cp mt th c bao nhiu cp c phn ng xy ra, trong bao nhiu cp xy ra phn ng oxi ha kh: A. 11-8 B. 10-8 C. 11-7 D. 8-7 Cu 21: tin hnh phn ng nhit phn hn hp X gm butan v heptan( t l mol 1:2) th thu c hn hp Y c t khi so vi H2 l a ( gi s ch xy ra phn ng cracking to thnh anken v ankan vi hiu sut 100%). Kt lun ng l: TH1 d, TH2: heptan cho 2 mol butan v 2 mol propan, thnh ra c 2 mol propan(4 mol sn phm cracking), 3 mol butan( 6 mol sn phm cracking) vy tt c c 10 mol sn phm. A. 12,9=<a<=21,5; B. a=21,5 C. 16=<a<=21,5 D. 12,9=<a<=16 Cu 22: Cho cc pht biu sau:

(1) Tng hp t olon bng cch trng ngng acrilonitrin. (2) Tng hp t nilon 6,6 bng phn ng trng ngng gia axit aipic v hexametylen iamin. (3) Tng hp poli (vinyl ancol) bng phn ng trng hp ancol vinylic. (4) Tng hp nha rezol bng cch un nng nha rezil 1500C (5) Cao su buna-S c tng hp bng phn ng ng trng hp gia buta-1,3-dien vi vinyl xianua. (6) Trong mt nguyn t, s khi bng tng s ht proton v ntron-sai phi l tng khi lng (7) Trong in phn dung dch NaCl trn catot xy ra s oxi ho nc. (8) Khi cho mt t CaCl2 vo nc cng tm thi s thu c nc cng ton phn. (9) T xenluloz axetat thuc loi t ha hc (10) Khi cho fomanehit d tc dng vi phenol, c baz xc tc thu c nha novolac. (11) Trong thc t loi b NH3 thot ra trong phng th nghim ta phun kh Cl2 vo phng (12)Dy cc cht PVC, poliisopren, amiloz, xenluloz.l cc cht khng phn nhnh (13) Nitrophotka l hn hp gm KNO3 v NH4H2PO4. (14) Tnh cht ca cht hu c ch ph thuc vo cu to ha hc m khng ph thuc vo thnh phn phn t ca cht. (15) Trong phn t cht hu c, cc nguyn t lin kt vi nhau theo ng ha tr. (16) Cc cht C2H4 v C3H6 l hai cht ng ng vi nhau. (17) Ancol etylic v axit fomic c khi lng phn t bng nhau nn l cc cht ng phn vi nhau. S pht biu khng chnh xc l? A.8 B.10 C.7 D.9 Cu 24: Co bao nhiu cht co th phan ng vi fomanhit iu kin thich hp trong cac cht sau H2, 02, Br2, C2H2, C2H5OH, H2O, HCN, phenol, ur, KMn04, Ag2O, Cu(0H)2. A, 8 B. 12 C. 9 D. 10 Cu 25: Lay 5,2 gam hh gom FeS2 va Cu2S tac dung hoan toan voi dd HNO3 thi thu duoc dung dich chi chua 2 muoi va 12,208 lit hh khi NO2 va SO2(dktc). Xac dinh % ve khoi luong cua FeS2 trong hon hop ban dau? A. 71,53 hoac 81,39 B. 93,23 hoac 71,53 C. 69,23 hoac 81,39 D. 69,23 hoac 93,23 Cu 26: Cho 33,35 gam hh A gom Fe3O4, Fe(NO3)3, Cu tac dung hoan toan voi dd chua 0,414 mol H2SO4 loang thi thu duoc khi NO duy nhat va dd B chi chua 2 muoi. Co can B thu duoc bao nhieu gam muoi khan? A. 64,4 hoac 61,52 B. 65,976 hoac 61,52 C. 73,122 hoac 64,4 D. 65,976 hoac 75,922 Cu 23: Chn cu pht biu ng Flo l cht oxi ha mnh hn clo v 1. Flo c m in cao hn clo 2. Lin kt F-F km bn hn lin kt Cl-Cl 3. Flo c bn knh nguyn t nh hn clo A. 1, 3 B. 2, 3 C. 1, 2 D. 1, 2, 3