n cng ngh 2

Thit k dy chuyn sn xut nha Epoxy ED- 5

Phn I C S L THUYT NHA EPOXY

Chng 1. L THUYT TNG HP NHA EPOXY ED-5 1.1 Gii thiu chung v nha Epoxy: Nha Epoxy l mt loi nha nhit rn. Ging nh cc loi nha nhit rn khc nh nha Phenol Formaldehyt, nha Ure Formaldehyt, UPE, n c kh nng chuyn sang trng thi khng nng chy, khng ho tan trong nhng iu kin nht nh c cht ng rn. Trong nha ny c cha nhm Epoxy nn c gi l nha epoxy. Oxyt Etylen l hp cht Epoxy n gin nht, c kh nng phn ng ln. Ngay t nhng nm 1860 Buoc-Xo cho rng n d trng hp thnh cht cao phn t. Nhng mi n nm 1936 mi ng dng n trong cng nghip. T nm 1948, trong cng nghip dng nhiu loi nha Epoxy iu ch t Epyclohydrin ngng t vi Diphenylpropan c mt dung dch NaOH lm cht xc tc. Cc sn phm to ra sau khi ng rn c nhiu tnh cht l, ha tt nh: bm dnh rt tt vi nhiu loi vt liu, tnh in mi tt, khi ng rn co ngt khng ln, chu c tc dng ca axt, kim. Nha Epoxy c a vo thng mi ho nhng nm 1940 v ngy cng ng vai tr quan trng trong cng nghip polymer. Theo s liu thng k ti M, lng nha epoxy bn trong nhng nm 1970 v 1980 lun c tc tng hng nm >10%.
Bng 1. Sn xut nha Epoxy hng nm ca M tnh n 1994
Nm 1955 1960 1965 1970 1975 1980 1985 Lng nha SX (tnh 103.MT) 10 30 55 79 100 201 347

SVTH: inh Ngc Duy

-1-

GVHD: Dng Th Hy

 n cng ngh 2

Thit k dy chuyn sn xut nha Epoxy ED- 5 475 433

1990 1994

Cho n nay, nha epoxy pht trin rt mnh c v s lng sn xut ra, chng loi nha n cc lnh vc ng dng ca n rt l a dng v phong ph. Nht l trong lnh vc ng dng vt liu composite. S nc sn xut c loi nha ny tng ln rt ng k.
Bng2. Kh nng sn xut nha Epoxy cc nc Chu Tha Bnh Dng (2001). (Ngun cung cp bi Dow Chemical). Nc Nht i Loan Trung Quc Hn Quc Thi Lan Malaysia Philippines Tng cng Kh Nng Sn Xut. 1000 MT/nm 240 239 100 180 30 10 10 809

Cc loi nha iu ch t cc hp cht ca Polyhydroxyl v Epyclohydrin c nht khng ln v c kh nng ng rn. Do nhm hydroxyl khng tc dng ht trong mch thng nn ngay c khi trng thi ng rn nha cng khng chu c nhit v nc tt, ngi ta thng dng n pha vo nha Epoxy thng. Nha Epoxy c nhiu u im hn khi n c ng rn bng cc loi amin. Amoniac v polyamin l hai hp cht c bit d dng tc dng vi Epyclohydrin, Glyxerin, Diclohydrin to ra hp cht khng tan, c tnh kim dng lm nha trao i ion. Nu iu kin phn ng tha nhiu amin hoc Epyclohydrin th to ra sn phm tan dng trong cng nghip giy v dt lm tng chu nc ca bt xenlulo v lm tng bn c xt ca vi. Epoxy c sn xut vi nhiu loi khc nhau, trong thng dng nht l hai loi DE-5 v ED6. Hai loi ny c qui trnh sn xut ging nhau, ch khc nhau yu cu sn phm nh: hm lng cht bc, hm lng nhm Epoxy, nht, t trng v trng lng phn t khc nhau. Ni
SVTH: inh Ngc Duy -2GVHD: Dng Th Hy

 n cng ngh 2

Thit k dy chuyn sn xut nha Epoxy ED- 5

chung yu cu thng s ny i vi ED 6 cao hn. Quy trnh to nha di cc iu kin phn ng khc nhau nh: tc phn ng, dung mi, nng cht xc tc, thi gian phn ng, c bit l t l 2 monomer ban u s cho cc sn phm khc nhau l ED-5, ED-6 hay cc loi Epoxy khc. Gn y ngi ta iu ch c nha Epoxy phn t thp c ni i t poly butadien. Do vy m n c kh nng ng rn khi c Amin, Anhydric ca axit 2 chc hoc Peroxyt. 1.2 Nguyn liu sn xut nha Epoxy ED -5. Nguyn liu chnh sn xut nha DiEpoxy l Epiclohydrin v Diphenyl propan. C th dng cc dn xut diphenyl khc nh Rezorcin, Dihydroxylcrezol thay cho Diphenyl propan, nhng thc t t c dng. 1.2.1 Epiclohydrin. * Cng thc cu to: CH2 Cl *Tnh cht ca Epiclohydrin: Epiclohydrin l cht lng trong sut, khng mu, khng tan trong nc nhng tan trong benzen, axeton, ru v cc dung mi khc, c mi mnh, c bit l rt c, si nhit 116-117 0C, t trng 20 0C = 1,175 1,35 g/cm3, nhit nng chy = 57,2 0C. t tan trong nc nhit 20 0C ch ha tan 6,58 % trng lng, to hn hp ng ph vi nc nhit si 84,1 0C v chim 81% trng lng hn hp. * iu Ch Epiclohydrin: ** i t Glyxerin. u tin cho kh HCl khan tc dng vi Glyxerin nhit t 110 n 1150C th chuyn thnh Diclohydrin Glyxerin.
CH2 OH CH OH CH2 OH

CH O

CH2

2 HCl

110_115 C

CH2 Cl

CH OH

CH2 + 2 H2 O Cl

hiu sut phn ng cao th Glyxerin phi tht khan hoc cha rt t nc. Ngoi ra, cn phi c cc cht ht nc nh Anhydric axetic hoc Axit axetic. Giai on ha vng, dng kim kh HCl to ra Epiclohydrin.
SVTH: inh Ngc Duy -3GVHD: Dng Th Hy

 n cng ngh 2

Thit k dy chuyn sn xut nha Epoxy ED- 5

CH2 Cl

CH OH

CH2 Cl

NaOH

CH2 Cl

CH O

CH

2 H2 O

NaCl

Phn ng ha vng tin hnh nhit thng, nng v tc tc dng ca NaOH vi Diclohydrin c nh hng rt nhiu n hiu sut phn ng v ngoi phn ng to thnh Epiclohydrin cn c phn ng x phng ha Epiclohydrin thnh Glyxerin
CH2 Cl CH O CH
2

NaOH

H O 2

CH OH

CH OH

CH2 OH

NaCl

C th dng cc loi kim yu hn nh Ca(OH)2 , Na2CO3 kh HCl. Phng php ny c ng dng nhiu Lin X, Trung Quc. nc ta sn lng du tho mc (Glyxerin tch ra khi x phng ha du tho mc) kh ln nn n cng thun li ng k. **i t Propylen. Clo ha Propylen di p sut 18 Kg/cm2 v nhit 5000C to thnh Clorua-alkyl, tip n cho HClO tc dng ln ni i v cui cng dng kim kh HCl ca Diclohydrin to thnh Epiclohydrin.
CH2 CH CH
3

Cl 2 o 500 C ,18at

CH2 CH Cl

CH

CH Cl
2

HCl

CH2 CH Cl

CH

CH Cl
2

+ +

HClO

CH OH CH

CH2 Cl CH Cl

CH OH

CH2 Cl

NaOH

CH2 O

NaCl

+ H2O

Sn phm ph l Triclopropan, Diclohydrin cha phn ng. Trong hai phng php trn th phng php ph hp i vi nc ta l phng php i t Glyxrin cn phng php i t Propylen ch ph hp vi nhng nc c ngnh cng nghip ch bin du m pht trin mnh.

*An ton khi s dng Epiclohydrin.

SVTH: inh Ngc Duy

-4-

GVHD: Dng Th Hy

 n cng ngh 2

Thit k dy chuyn sn xut nha Epoxy ED- 5

Do tnh cht c hi ca Epiclohydrin nn yu cu thng cha, ng dn phi kn m bo an ton cho cng nhn. Khi vn chuyn nn ng Epiclohydrin vo chai thy tinh ln hay s dng thng bng thp c y kn cn thn cho cng nhn thao tc khi b ng c. 1.2.2 Diphenylol propan (4,4-Dioxy Difenylol propan), hay gi tt l
Bis phenol A.

Diphenylol propan c iu ch bng cch cho Phenol tc dng vi Axeton trong mi trng axit mnh nhit 10-15 0C.
CH 3 CH3 C O CH3 + 2HO HO C CH3 OH + H2O

to mi trng H+ c th s dng dung dch H2SO4, hoc l hi HCl. Thc nghim chng t rng lng H2SO4 ch nh hng n phn ng gii hn nht nh, nhng nng axit l yu t quan trng quyt nh hiu sut phn ng. Hin nay, ngi ta dng xc tc l dn xut Mercaptan ca axit no mch thng nh Tiodiaxetic (HOOCCH2SCH2COOH) iu ch t Monocloaxetic v Sunfohydro. *Tnh cht ca Difenylol propan. Diphenylol propan l loi bt tinh th ng nht c nhit nng chy t 155157 0C, khng ha tan trong nc, tan d trong axetol v ru. Bo qun bng bao giy khng thm nc hay thng thp c np y kn. Ngoi ra, trong cng nghip ngi ta cn sn xut nha Epoxy t nha Phenolformaldehit.
1.3 L thuyt to nha Epoxy.

1.3.1 Phn ng a t nha Epoxy. Nguyn liu sn xut ete diglyxit v polymer ca chng l phenol a chc v hp cht cha nhm Epoxy. Nhng hp cht cha nhm hyroxyl c th dng l: Rezosin, Hydroquinol, Dioxit diphenolpropan, nha Phenolfocmandehit dng novolacNhng thng c s dng rng ri nht l diphenylpropan v Epyclohydrin. Phn ng xy ra trong mi trng kim c hai nhm nh chc l Epoxy l Clo. Diphenylpropan c hai

SVTH: inh Ngc Duy

-5-

GVHD: Dng Th Hy

 n cng ngh 2

Thit k dy chuyn sn xut nha Epoxy ED- 5

nhm hydroxyl c hai nguyn t hyr linh ng nn kh nng tham gia phn ng ln. Ph thuc vo t l hai cht cht m c th thu c cc sn phm khc nhau t lng nht n rn. Nu tha Epyclohyrin th c th thu c ete diglixit diphenylpropan, phn ng xy ra trong mi trng NaOH. Trong dung mi tr c 0,2 n 0,5% NaOH th thu c ete diglyxerit c sch cao, c nht si 210230 0C p sut 0,05mHg v ch s khc x D20= 1,57507. 90175 0C ete diglixit diphenylpropan trong mi trng kim s chuyn thnh polymer dng thu tinh do c nhm Epoxy trng hp. Khi lng phn t ca nha tu thuc vo t l gia Epiclohydrin v dian. Khi t l Epiclohydrin cng ln th khi lng phn t ca nha Epoxy cng b. Sn phm thu c trong sut, khng mu, bn vi kim, d x l v c tnh cht c hc cao. Do vy nha thu c l mt hn hp ng ng polymer c di mch khc nhau. T l mol gia Epyclohydrin v Diphenylpropan cng gim th nhit nng chy v trng lng phn t cng tng. Tt nht l iu ch nha trong dung dch nc NaOH, Ca(OH) 2 hoc Ba(OH)2. Nu tin hnh phn ng khng c kim m thm cc axit v c hoc xc tc Frien- Craft th cui phn t vn cn nhm Clohydrin. Do phi kh HCI, tc nhn thng dng kh HCI l kim nhng tt nht l Alumiat Natri hoc l Canxi trong mi trng ioxan. Khi tng hp nha Epoxy trng lng phn t thp thng ho tan vo mt lng tha Epyclohydrin ri thm dn dung dch kim nc, nhit phn ng 6070 0 C. Phn ng to nha xy ra nh sau: +Nhm Epoxy trong Epyclohydrin tc dng vi Hydroxyl diphenylpropan.
CH 3 CH Cl
2

CH

CH2 + HO OH CH2 Cl CH OH

C CH 3 CH
2

OH t

CH

CH CH2 OH Cl

SVTH: inh Ngc Duy

-6-

GVHD: Dng Th Hy

 n cng ngh 2

Thit k dy chuyn sn xut nha Epoxy ED- 5

Giai on ny to nhit mnh ( 20 0C, H = -17,09 Kcal/mol). Sn phm to ra c nhm OH bc 2 nm v tr so vi nguyn t Clo. v tr nh vy, trong mi trng kim s xy ra t HCl v to nhm Epoxy mi. + To ra nhm Epoxy mi do t HCl (kh):
CH Cl
2

CH OH

CH2

CH

CH OH

CH Cl

2NaOH

o t

CH 2 O

CH

CH2 O

CH

CH O

CH 2

2NaCl

2HO
2

+ Cc sn phm ban u tip tc ngng t vi Diphenylpropan, kt qu to ra nha mch thng:

2 CH 2 O CH 2 O CH CH2 O R O CH 2 CH CH2 O R O CH
2

CH O CH OH

CH 2

HO

OH

to

CH2 O
2

CH2 CH O

CH2

+ H2O

+ Suy ra cng thc tng qut:

CH 2 O CH CH O 2 R O CH2 CH OH CH 2 O
n

CH

CH O

CH

*C ch phn ng nh sau:
Trc ht NaOH phn ng vi Bisphenol A to thnh mui Natri Bisphenol A theo phng trnh phn ng:

SVTH: inh Ngc Duy

-7-

GVHD: Dng Th Hy

 n cng ngh 2

Thit k dy chuyn sn xut nha Epoxy ED- 5

phn t mui to thnh, c mt nguyn t oxy vi 3 cp electron cha ng gp vi bt k nguyn t no v n c iu kin thun li ng gp vi nguyn t cacbon trong phn t Epyclohydrin bn cnh. Nguyn t ny l nguyn t cacbonc lin kt clo. Nguyn t clo v nguyn t cacbon c mt cp electron chung nhng v m in ca nguyn t clo ln nn n c khuynh hng chim phn cp electron ny. Do nguyn t cacbon s d dng tch cp electron, kt hp vi nguyn t oxy, nguyn t clo s ra khi Epyclohydrin. Sn phm to thnh l mt phn t tng t Bisphenol A v ch vi mt nhm Epoxy trn n, bn cnh chng ta cng thu c mui n. Qu trnh phn ng xy ra nh sau:

Tu thuc vo t l gia hai cu t tham gia phn ng m trng ngng ca phn ng c th cao (n=25). Nu t l mol l 1:1 th phn ng kt

SVTH: inh Ngc Duy

-8-

GVHD: Dng Th Hy

 n cng ngh 2

Thit k dy chuyn sn xut nha Epoxy ED- 5

thc vi mt nhm Epoxy to thnh u bn kia, nhm mui Bisphenol A bn tri khng cn phn ng. Nhng nu c t hn hai phn t Epyclohydrin cho mi phn t Bisphenol A th khi khng phi tt c nhm mui Bisphenol A u c th phn ng vi Epyclohydrin. Gi s chng ta a ra t l l ba phn t Epyclohydrin vi hai phn t Bisphenol A. Khi tt c cc phn t Epyclohydrin phn ng ht th to thnh hn hp 50:50 ca hai phn t sau:

Hai phn t ny c th phn ng vi nhau to thnh phn t sau:

Qu trnh ngng vi mt dimer, l mui Natri. Nguyn t oxy mang in tch m, khi mt phn t nc tin n (chng ta to ra phn t nc khi to mui

SVTH: inh Ngc Duy

-9-

GVHD: Dng Th Hy

 n cng ngh 2

Thit k dy chuyn sn xut nha Epoxy ED- 5

Natri ca Bisphenol A ), mt cp electron t oxy s tn cng mt nguyn t hydro ca phn t nc, v ly n t phn t nc:

Nguyn t xi by gi to mt nhm ancol v chng ta thu li c NaOH. Nh trn ta thy nha Epoxy trng thi khng ng rn l nhng mch polymer di, trong nhm Hydroxyl t do nm cch nhau mt khong tng i xa. hai u mch l nhm Epoxy. Nhm Epoxy v Hydroxyl c kh nng phn ng vi nhiu cht v ph thuc vo nh chc ca cc cht m c th thu c nha nhit do bin tnh hoc ng rn khng nng chy v khng tan. Cng thc n gin trn khng phn nh c nhng phn ng ph xy ra trong qu trnh trng ngng lm cho nha c cu to nhnh v cui phn t c cha nhm Hydroxyl v Clohydrin. Trong qu trnh a t cn ch ngn chn nhng phn ng . *Cc phn ng ph c th xy ra: + Thy phn Epiclohydrin thnh Glyxerin:
CH2 CH CH

NaOH

H2 O

CH OH

CH OH

CH2 OH

NaCl

Cl

+ Thy phn nhm Epoxy cui mch to thnh OH:

CH2 CH R

H2O

CH OH

CH2 OH

+ Trng hp nhm Epoxy vi nhm Hydroxyl gy gel ha:

SVTH: inh Ngc Duy Hy - 10 GVHD: Dng Th

 n cng ngh 2

Thit k dy chuyn sn xut nha Epoxy ED- 5

CH2 CH OH

CH2

+ CH CH 2 O

CH2 CH CH2 O CH2 CH

CH2 O CH2 CH OH

CH2

+ Trng hp cc nhm Epoxy to cu trc khng gian lm nha keo kt:

n CH2 CH O R CH O CH2 CH2 CH O CH2 CH O CH2 CH O R R CH O R CH O CH2 CH O CH2 CH2

Khi tng hp nha Epoxy trng lng phn t thp thng ha tan Diphenylolpropan vo mt lng tha Epiclohydrin ri thm dn dung dch kim nc, nhit phn ng 60-70 0C. C th tng hp nha trong mi trng kh tr, un ngt qung, khuy trong 16 gi, iu chnh lng kim th thm vo mi trng lun lun trung tnh, lm nh vy trnh trng hp nhm Epoxy. Qu trnh a t nha Epoxy ht sc phc tp do c nhiu phn ng ph. V vy phi chn iu kin k thut ch to Ete diglyxerit v ng thi phi ch n cc iu kin nh hng n qu trnh phn ng. 1.3.2 Phn ng to nha Polyepoxy. Nha Epoxy i t Epiclohydrin khng ph thuc vo trng lng phn t, trong mi phn t u c khng qu hai nhm Epoxy, nn vic ng rn nha ny bng Polyamin v Anhydric ca axit 2 chc th khng th lm tng nhiu bn nhit. Nha cha trn hai nhm Epoxy trong mi phn t gi l nha Polyepoxy.

*Mt s loi nha Polyepoxy.

SVTH: inh Ngc Duy Hy - 11 GVHD: Dng Th

 n cng ngh 2

Thit k dy chuyn sn xut nha Epoxy ED- 5

+ Nha Poly triglyxidil xianuarat i t axit Xianuaric vi Epiclohydrin

OH

N HO C N

N C OH

3 CH Cl

CH O

CH 2

to

O C N CH 2 Cl CH OH CH
2

CH 2 N

CH OH

CH 2Cl

C N

CH 2

CH OH

CH Cl
2

O C N NaOH CH2 CH O CH
2

CH 2 N

CH O

CH 2

C N

CH 2

CH O

CH 2

So snh tnh cht ca nha Epoxy ng rn i t Diphenylolpropan v t axit Xianuaric th thy rng nha Epoxy i t axit Xianuaric c chu nhit cao hn v tn hao in mi nhit cao b hn nha Epoxy i t Diphenylolpropan. Tuy nhin nha ny t c sn xut do kh khn v nguyn liu. + Nha polyglyxidil phenolfocmaldehyt:
SVTH: inh Ngc Duy Hy - 12 GVHD: Dng Th

 n cng ngh 2

Thit k dy chuyn sn xut nha Epoxy ED- 5

Nha Phenol formaldehit (Novolac, Rezolic) c th x l bng Epiclohydrin trong mi trng kim 70 100 0C to nha Poly glyxidil. Ph thuc vo iu kin phn ng v t l cc cu t m cc nhm Hydroxyl ca Phenol v nhm metylol c th thay th mt phn hay hon ton. Cu to nha Polyglyxidil Phenol Fomaldehit: - T nha Novolac
H2C HC H2 C O H
CH 2

CH 2 CH CH O H
2

- T nha Rezolic:
H C
2

HC
H2 C O H

CH2 CH CH 2

CH2

O CH 2
m

CH2

CH O

CH2

CH2OH

Nha Polyepoxy i t Novolac c dng ph bin hn c. Nhm Epoxy trong nha ny c gi cht hn do sn phm ng rn rt cng v km n hi. Thng nha Polyepoxy c bm dnh vo cc vt liu thp hn so vi nha Epoxy thng. Nhng do khi ng rn tn s ni ngang ln nn lm vt phm c chu nhit cao. Nha ny c bn dng ph kim loi, lm keo dn v cht do thy tinh. Nha Polyepoxy bin tnh bng cch un nng vi mono v Diglyxerit ca du kh v du bn kh, lc nhm Epoxy ca nha tc dng vi nhm Hydroxyl ca Glyxerit v to ete. 1.3.4 Epoxy ha cc hp cht khng no.
SVTH: inh Ngc Duy Hy - 13 GVHD: Dng Th

 n cng ngh 2

Thit k dy chuyn sn xut nha Epoxy ED- 5

Thng thng phng php iu ch nha epoxy, epoxy ho cc hp cht khng no c gi tr hn c v mt l thuyt v thc t. Epoxy ha theo hai cch sau y:
Epoxy ha cc hp cht khng no bng cc peroxit hu c nh

peraxetic, perbenzoic, perpropionic. Cho HClO tc dng ln ni i sau dng kim kh HCl to ra vng Epoxy :
CH CH + H OCl CH OH CH CH OH Cl + NaOH CH O CH Cl CH + NaCl + H2O

Epoxy ha thng tin hnh nhit 25 26 0C trong cc dung mi hu c: benzen, toluen, cloruafoc. 1.4 Bin tnh nha Epoxy. Nh c nhiu nhm hot ng ha hc, nha Epoxy c th tham gia nhiu phn ng bin i ha hc v phi hp vi cc polyme khc. Bin tnh nha Epoxy c gi tr rt quan trng v cho php thay i tnh cht sn phm theo mun. Cc loi nha Epoxy bin tnh ph bin l Epoxy bin tnh bng axit bo ca du tho mc, bin tnh bng ru bo cao cp khng no, ng trng hp vi Styren, vi cc hp cht Vinyl, vi cao su Butadien nitril, phi hp vi Polyamit, dng a t vi hp cht Silic hu c. 1.4.1 Bin tnh bng axit bo u tho mc. Bin tnh bng axit bo du tho mc l phn ng este ha nha Epoxy. Ty iu kin c th este ha ring nhm epoxy, hydroxyl hay l este ha ng thi c hai nhm. Phn ng este ha tin hnh theo hai giai on:

SVTH: inh Ngc Duy Hy

- 14 -

GVHD: Dng Th

 n cng ngh 2

Thit k dy chuyn sn xut nha Epoxy ED- 5

RO

CH2 CH O

CH + R 1COOH 2

RO CH O C R2

CH2 CH 2 O

CH CH 2

OOCR1

CH CH 2 OOCR 1 + R 2COOH OH

OH OOCR1 + H O 2

ng thi este ho c nhm hydroxyl ca nha Epoxy ban u: CH OH + RCOOH CH O C R Phn ng gia nhm Epoxy v axit bo tin hnh nhit khong 160 C, este ha nhm hydroxyl nhit 170 180 0C v cao hn. Tuy nhin, 180 200 0C phn ng ny xy ra chm v khng trng hp nhit. Trong cng nghip thng este ha nhit 220 260 0C.
0

+ HO 2 O

Tr s axit ca epoxy este phi vo khong 110, cao hn 10 s kh chm, chu nc v ha cht kim. Trong qu trnh este ha c th dng cc xc tc oxit kim loi, Paratoluen sulfo axit, Hydroxit bari, Dng CaO v ZnO th thi gian este ha gim nhng nht ca sn phm li b. Dng xc tc c nhc im l dung dch nha b m c khi bo qun. C th tch axit bo t cc loi du lanh, thu du kh nc, hn hp du thu, du tru. Khi la chn axit bo cn ch l s ni i cng nhiu este ha cng nhanh nhng nhiu qu d b keo t. Nha Epoxy este thng dng lm mng sn (pha vo hm hp bng dung mi Xilen + Xenlulo theo nng 30%). Mng sn c kh nng kh nhit thng nu thm cht lm kh Coban (ly 1,04% tnh theo Coban kim loi) v kh 150 0C (khng cn thm cht lm kh). 1.4.2 Bin tnh bng ru bo cao phn t khng no. Khi cho nha Epoxy tc dng vi cc ru bo cao phn t khng no s nhn c hp cht ete. Phn ng ete ha tin hnh c xc tc FridenCraft (BF3), nhit 70-90 0C, trong dung dch Dioxan hay Anisol.
SVTH: inh Ngc Duy Hy - 15 GVHD: Dng Th

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Thit k dy chuyn sn xut nha Epoxy ED- 5

y ch c nhm Epoxy tham gia vo phn ng, nh vy c th trng hp nh ni i ca gc Alyl. 1.4.3 ng trng hp vi cc hp cht vinyl. Cc hp cht vinyl c th dng nh Vinyl clorua, Vinyl axetat, Vinyl idencloric, este ca axit Acrilic v meta Acrilic. Nhng sn phm ng trng hp ny dng tm giy, vi v ch to keo dn. Ngoi ra, sn phm ng trng hp nha Epoxy vi Acrilo nitryl c th gia cng thnh si v mng. 1.4.4 ng trng hp vi Styren. Nha Epoxy ng trng hp vi Styren trong dung dch Xylen v trong mi trng kh tr nhit 145-150 0C c xc tc loi Peroxit. Hoc cng c th tin hnh nh sau: Trc tin cho axit bo ca du lanh v Styren ng trng hp nhit 205 0C c mt xc tc (h thng oxy ha kh gm SO2 v Benzidin). Sau , em hp cht thu c trn vi nha Epoxy. Sn phm to thnh c th gia cng thnh mng ng rn bng Naphtanat Coban. Ngoi ra cn ng trng hp nha Epoxy vi cc dn xut ca Styren nh Octo, Meta, Para metyl Styren, 2.5-Dietyl Styren 1.4.5 ng trng hp vi cao su Butadien nitryl. Sn phm ny c tnh cht gn ging nh cao su nhng c kh nng bo tn cc tnh cht mm cao trong mt gii hn nhit rng. 1.4.6 Phi hp vi Polyamid. Nha Epoxy phi hp vi Polyamid c s dng rng ri trong ngnh cng nghip sn. Thng l dng nha Epoxy vi nha Vacxamit phn t thp. 1.4.7 ng a t vi hp cht Silic hu c. Nha Epoxy Silosan c chu nhit v kh hu cao, bm dnh v co dn tt nn c dng lm mng ph vt liu hn kn, thm vo cc nha khc lm tng tnh chu nhit, lm cht n nh.

SVTH: inh Ngc Duy Hy

- 16 -

GVHD: Dng Th

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Thit k dy chuyn sn xut nha Epoxy ED- 5

SVTH: inh Ngc Duy Hy

- 17 -

GVHD: Dng Th