CU HI TRC NGHIM PHN ANKEN Thc hin : INH THANH T K5- Cao hc ho hc HGD Cu 1 : Cho isopentan tc dng vi Cl2

theo t l mol 1;1 c nh sng khuch tn .Sn phm monoclo no d hnh thnh nht ? A. CH3CHClCH(CH3)2 B. CH3CH2CCl(CH3)2 C. (CH3)2CHCH2CH2Cl D. CH3CH2CH(CH3)CH2Cl Cu 2: Cho 4,48 lt hn hp X (ktc) gm hai hirocacbon mch h li t t qua bnh cha 1,4 lt dung dch brom 0,5M . Sau khi phn ng hon ton , s mol brom gim i mmt na v khi lng bnh tng thm 6,7 gam .Cng thc phn t ca 2 hirocacbon l: A. C2H2 v C4H6 B. C2H2 v C4H8 C. C3H4 v C4H8 D. C2H2 v C3H8 Cu 3: Cho 0,455 gam hn hp 2 anken ng ng k tip va lm mt mu dung dch cha 1,6 gam brom . Bit rng khi hirat hn hp 2anken ny thu c hn hp 3 ancol. Hai anken v t l mol trong hn hp l : A. Eten v propen theo t l mol 3:1 B. Propen v but- 1-en theo t l mol 3:1 C. Propen v but-2-en theo t l mol 3:1 D. Propen v but-2-en theo t l mol 1:3 Cu4: Hidrocacbon X mch h c cng thc phn t C6H12 tc dng vi HBr ch cho mt loi sn phm cng duy nht , s lng ng phn cu to ca X l: A. 1 B.2 C. 3 D. 4 Cu 5: X mch h c cng thc C3Hy . Mt bnh c dung tch khng i cha hn hp kh gm X v O2 d 150oC c p sut l 2atm .Bt tia la in t chy X sau a bnh v 150o C , p sut trong bnh vn l 2atm. Ngi ta trn 9,6 g X vi H2 ri cho bnh ng Ni nung nng (H = 100%) th thu c hn hp Y . Kh i l ng mol trung b nh c a Y c gi tr l : A. 42,5 B.46,5 C. 48,5 D. 52,5 Cu 6 : M t b nh k n cha hn h p kh X gm hirocacbon A mch h l kh iu kin thng ,mt t bt Ni , t khi hi ca X so vi H2 l 3,0 .Nung bnh phn ng xy ra hon ton thu c hn hp kh Y , t khi hi ca Y so vi H2 l 4,5 .Cng th ca A l : A. C2H2 B. C3H4 C. C4H2 D.C2H2 hoc C4H2 Cu 7: Anken X l cht kh iu kin thng ct khi so vi khng kh ln hn 1 . Cho X tc dng vi nc c H2SO4 lm xc tc thu dc sn phm chnh l cht h c Y . Oxi ho Y bng CuO t nng thu c sn phm hu c Z . Kt lun no sau y ng : A. Z c kh nng tham gia phn ng s trng gng . B. Z khng c kh nng tham gia phn ng trng gng. C. Z c kh nng tham gia phn ng trng gng nu X l C3H6 D. Z c th hoc khng tham ga phn ngs trng gng . Cu 8: Hn hp kh X ( ktc ) gm nhng th tch bng nhau c CH4 v mt. Hirocacbon A . X c t khi so vi H2 bng 15 . t chy hn ton V lit hn hp kh ny ri choi ton b sn phm chy vo dung dch Ba(OH)2 d th thu c 15,76 gam kt ta . V c gi tr l: A. 1,120 lit B. 0,448 lit C. 0,896 lit D. 0,672 lit Cu 9 : t chy hon ton mt hp cht hu c A ch thu c 7,92 gam CO2 v 3,24 gam H2O .A tc dng vi HBr ch to ra mt sn phm duy nht l B trong phn t c cha 48,48% brom v khi lng . S ng phn cu to ca A l A. 1 B. 2 C. 3 D. 4 Cu10: Hirocacbon A tacs dng vi Cl2 iu kin thch hp thu c sn phm hu c B . t chy hon toang 11,3 gam B thu c 6,72 lit CO2 ( ktc ) v 5,4 gam H2O . Sps ng phn cu to ca A l :

A. 1 B. 2 C. 3 D.4 C 11: Khi trng hp buta-1,3- ien, ngoi cao su buna cn thu c mt sn phm ph A , bit rng khi A hir ho thu c etylxclohexan. Cng tc cu to ca A l cht no di y?

A
CH2CH3

B
CH=CH2

C
CH=CH 2

D
CH 3

Cu 12 : Trong s cc cht c cng thc phn t C6H6 th s lng cht to kt ta vi dung dch AgNO3 / NH3 l : A. 2 cht B. 3cht C. 5cht D. nhiu hn 5 cht Cu 13: t chy hon ton hodrocacbon A , ri hp th hon ton sn phm chy vo dung dch Ca(OH)2 d , sau phn ng thy co 60 gam kt ta v khi lng trong bnh gim i 21 gam . CTPT ca A l; A. C5H12 B. C6H12 C. C6H14 D. C4H10 Cu 14 : Cho hn hp X gm 2 anken . t chy hon ton 1lit X cn va 3,9 lt O2. Trong hn hp X c 25% - 35% anken nng hn . Cc th tch kh o cng u kin. CTPT ca cc anken l: A. C3H6 v C4H8 B.C2H4 v C3H6 C. C2H4 v C4H8 D. C3H4 v C5H10 Cu 15 : Hn hp A gm mt ankan v mt anken . t chy hn hp A thu c mol H2O v b mol CO2 . T s T= a/b c gi tr trong khong no? A. 1,2 < T< 1,5 B. 1< T <2 C.1 T 2 D. 0 T 1 Cu 16: Cho 0,75 mol hn hp kh X gm H2 v 2 anken l ng ng k tip qua bt Ni nung nng th thu c hn hp kh Y . Phn ng xong dn Y qua nc Br2 d th mu nu nht i . Mt khc t chy hon ton hn hp kh Y th thu c 79,2 gam CO2 ( ktc) v 36,9 gam H2O . Cng thc phn t ca 2 anken v d X/ H2 c gi tr l: A. C4H8 v C5H10 dX/H2= 29,3 B. C3H6 v C4H8 , dX/H2 =17,15 C. C2H4, C3H6 v dX/H2 = 15,2 D. C3H6, C4H8 v dX/ H2 = 16,4 Cu 17 : t chy hon ton 1,82 gam hn hp gm C4H10, C3H4, C2H2, dn to b sn phm vo bnh (1) ng P2O5 d , bnh (2) ng 2 lit dung dch Ca(oh)2 0,05 M . Sau khi phn ng xong thy khp lng bnh (1) tng 2,43 gam , bnh (2) c m gam kt ta . Ga tr m l: A. 5,72 B. 7,0 C. 10,0 D.13,0 Cu 18: t chy ht 0,672 lt ( ktc) hn hp kh gm CXH2X ( dng kh nhit thng ) v CH4 chim b hn 50% v th tch , cho sn phm chy hp th vo 350 ml dung dch Ba(OH)2 0,2M thu c 9,85 gam kt ta .CXH2X l g? A. C2H4 v C4H8 B. C4H8 C. C2H4 D. C2H4 v C3H6 Cu 19 : em crackinh mt lng C4H10 thu c 5 hirocacbon . Cho hn hp kh ny vo dung dchj nc Br2 d th c 25,6 gam Br2 phn ng . Sau th nghim khi lng bnh Br2 tng thm 5,32 gam . H n hp kh cn li thot ra khi dung dch Br2 c t khi so vi CH4 l 1,9625 . Hiu sut phn ng crackinh C4H10 l: A. 60% B. 75% C.80% D. 84% Cu 20 : Trong bnh kn cha hidrocacbon X v H2 .Nung nng bnh n khi phn ng xy ra hon ton thu c ankan Y duy nht . a cng nhit , p sut trc khi nung gp 3 ln p sut trong bnh sau khi nung . t chy mt lng Y thu c 8,8 gam CO2 v 5,4 gam nc . ng thc phn t ca X l : A. C2H2 B.C2H4 C. C4H6 D.C3H4

Cu 21: Hirocacbon X v Y tc dng vi Cl2 u cho sn phm c cng thc phn t l C2H4Cl2 . X to mt sn phm duy nht , Y to hn hp 2sn phm . Cng thc phn t ca X v Y ln lt l: A. C2H4 v C2H6 B. C2H 4 v C2H2 C. C2H2 v C2H6 D. C2H4 v C2H6 Cu 21: P v Q c cng CTPT l C5H8 v c mach cacbon phn nhnh . P c kh nng trng hp to polyme c tnh n hi cao , Qc kh nng kt ta khi cho qua dung dch AgNO3? NH3 . P v Q l: A. penta-1,3-ien , 3mtyl but-1-in B. 2-metyl butaien v 3-metyl but-1-in C. penta-1,3- ien v pen-1-in D. 2-metylbutaien v pen -1-in Cu 22: Hn hp A c axetilen, etan, propilen . t chy hon ton 24,8 gam A thu c 28,8 gam nc . Mt khc c 0,5 mol A tc dng va 500 gam dung dch Br2 20% .Thnh phn % khi phn ng hon ton ch cn li 0,448 lt kh thot ra v c 8 gam Br2 tham gia phn ng. t chy hon ton hn hp X trn dn ton b sn phm vo dung dch Ca(OH)2 d th thu c 29 gam kt ta trng . CTPT ca 2 hirocacbon l; A. CH4 v C2H2 B. C3H6 v C2H6 C.C2H4 v C3H4 D. C3H8 v C2H4 Cu 23: Cho 135 ml hn hp kh A gm H2 , mt anken v mt ankin qua bt Ni nung nng th sau phn ng ch cn 60 ml mt hiroccbon duy nht . Mt khc t chy hon ton 60 ml hn hp kh A th thu c 80 ml kh CO2 , cc th tch kh o cng iu kin v nhit v p sut . CTPT ca 2 hirocacbon l: A. C5H10 v C5H8 B. C2H4 v C2H2 C. C3H6 v C3H4 D.C4H8 v C4H6 Cu 24: Cho 0,2 mol hn hpM gm mt ankanX v mt anken Y c khi lng l 10,6 gam . Khi cho Mtc dng vi H2 d (Ni, to C ) c hn hp 2 ankan l ng ng k tip . t chy hon ton 0,2 mol M c 16,8 lt kh CO2 ( ktc) v 14,4 gam H2O.Cng thc X v Y ln lt l: A. C3H8 v C4H8 B. C2H6 , C3H6 C. CH4 , C2H4 D. C4H10 , C5H10 Cu 25:Trong bnh kn cha hn hp kh A gm hirocacbon X v H2 vi Ni .N ung nng bnh mt thi gian ta thu c mt kh B duy nht .t chy B thu c 8,8 gam CO2 v 5,4 gam H2O . Bit VA= 2VB .CTPT ca X l: A. C3H4 B. C3H6 C4H8 D. C2H4 Cu 26: nhn bit 3 kh ng trong l mt nhn : C2H6, C2H4, C2H2 ngi ta dng cc ho cht no di y: A. Dung dch brom B. Dung dch AgNO3/NH3 v dung dch Br2 C. Dung dch AgNO3/NH3 D. Dung dch HCl v dung dch Br2 Cu 27: Chn phng n no trong cc phng n sau phn bt prpilen v xiclopropan A. Cho tc dng vi dung dch nc Br2 B. Cho tc dng vi Br2 c chiu sng C. Cho tc dng vi dung dch KMnO4 D.Th tnh tan trong Benzen Cu 28: Etilen c ln tp cht SO2 v CO2, hi nc . C th loi b tp cht bng cch no di y: A. Dn hn hp i qua bnh ng dung dch Br2 d. B. Dn hhn hp i qua bnh ng dung dch BaCl2 d. C. Dn hn hp ln lt i qua NaOH d v bnh ng CaO D. Dn hn hp i qua dung dch brom d v bnh ng dung dch H2SO4 c Cu 29: Trong phng th nghim ngi ta c th iu ch mt lng nh kh etilen theo cch no di y ? A. Crackinh propan B. un etylclorua vi KOH / C2H5OH o C. un ancol etilic vi H2SO4 c 170 C D. Loi H2 ca etan c xc tc bt Ni, nung nng Cu 30 : C bao nhiu anken ng phn cu to ca nhau khi cng H2 u to thnh 2- metyl butan? 3

A. 1 B.2 C.3 D.4 o Cu 31: Cho 10 lt hn hp kh ( 54,6 C : 0,8064 ) gm 2olephin li qu bnh dung dch nc Br2 d thy khi lng bnh tng 16,8 gam . CTPT ca 2 anken l ( Bit s C trong cc anken khng vt qu 5) A C2H4 v C5H10 B. C3H6 v C5H10 C. C4H8 v C5H10 D. A hoc B Cu 32 : Cho cc cht : xiclobutan, 2- metylpropen , but-1-en , c-but-2-en, 2-metylbut-2-en . Dy gm cc cht sau khi phn ng vi H2 ( d, xt Ni, to) cho cng mt sn phm l: A. xiclobutan, cs-but-2-en, but-1-en B. But-1-en, 2-metylpropen , cis-but-2-en C. Xiclobutan, 2-metylbut -2-, but-1-en D. 2-metylpropen, cis-but-2-en, xiclobutan Cu 32: Mt hn hp kh gm mt ankan v 1anken c cng s nhuyn t C trong phn t v c cng s mol . Ly m gam hn hp ny lm mt mu va 80 gam dung dch Br2 20% . t chy hon ton m gam hn hp thu c 0,6 mol CO2 . Ankan v anken c cong thc phn t l : A. C2H4 v C2H6 B. C4H8 v C4H10 C. C3H8 v C3H6 D. C5H12 v C5H10 Cu 33: t chy hon ton 20 ml hn hp X gm C3H6, CH4, CO ( VCO = 2V CH4 ) ,thu c 24ml CO2 (cc th tch kh o cng iu kin nhit v p sut ) . T khi ca X so vi H2 l: A. 12,9 B. 25,8 C. 22,2 D. 11,1 Cu 35: Cho hai hirocacbon A c B , Ac cng thc CxH2y , B c cng thc CxH2x ( tr s x trong cng thc c gi tr bng nhau) . Bit DA/KK = 2 v DB/A =0,482. CTPT ca A v B l: A. C2H4, C4H10 B. C4H10, C3H6 C. C4H10 , C2H4 D. C4H8 v C2H4 Cu 36: t chy cng s mol 3 hirocacbon K,L,M thu c lng CO2 nh nhau v t l s mol H2O : CO2 i vi K,L,M tng ng bng 0,5:1:1,5 .CTPT ca K,L, M ln lt l : A. C3H8, C3H4, C2H4 B. C2H2, C2H4, C2H6 C. C4H4, C3H6, C2H6, D.C2H2,C2H4, Cu 36 : t chy hon ton 5,6 gam mt anken A c t khi hi so vi H2 l 28 thu c 8,96 lt kh CO2( ktc) .Cho A tc dng vi HBr ch cho mt ssn phm duy nht . CTCT ca A l cht no sau y ? A, CH2= CH- CH2CH3 B. CH2 = C(CH3)2 C. CH2CH=CHCH3 D. (CH3)2C=C(CH3)2 Cu 37: Mt hn hp X gm ankan A v anken B, A c nhiu hn B mt nguyn t cacbon , A,B u th kh ktc .Khi cho 6,72 lt kh X (ktc) i qua nc Br2 d thy khi lng bnh tng ln 2,8 gam ,th tch kh cn li ch bng 2/3 th tch hn hp X ban u .CTPT ca A v B v khi lng ca hn hp X l: A. C4H10, C3H6 ; 5,8 gam B. C3H8, C2H4 ; 5,8 gam C. C4H10, C3H6 ; 12,8 gam D. C3H8 , C2H4 ; 11,6 gam Cu 38: Cng thc tng qt ca hirocacbon X bt k c dng CnH2n + 2- 2k ( n nguyn , k 0 ). Kt lun no d; y lun ng ? A. k= 0 CnH2n +2 ( n 1) , X l ankan B. k=1 CnH2n (n 2) X l anken hoc xicloankan C. k=2 CnH2n-2 (n 2) X l ankin hoc ankaien D. k=4 CnH2n-6 (n 6) X l aren Cu 39: iu kin anken c ng phn hnh hc : A. Mi nguyn t cacbon lin kt i lin kt vi 2 nguyn t hoc nhm nguyn t bt k B. Mi nguyn t cacbon lin kt i lin kt vi 2 nguyn t hoc 2 nhm nguyn t khc nhau C. Mi nguyn t cacbon lin kt i lin kt vi 2 nguyn t hoc nhm nguyn t ging nhau . D. 4 ngyun t hoc nhm nguyn t 2 nguyn t cacbon mang ni i phi khc nhau Cu 40:Anken thch hp iu ch ancol di y

OH CH3 CH2
C

CH2 CH3

C2H5

A. 3-etylpent-2-en B. 3-etylpent-3-en C. 3-etylpent- 1-en D. 3,3- dimetylpent-1-en Cu 41: C 4 cht CH2=CHCH3, CH CCH3, CH2=CHCH=CH2 v benzen. Khi xt kh nng lm mt mu dung dch 4 cht trn , iu khng nh no di y l ng/ A. C 4 cht u c kh nng lm mt mu dung dch brom B. C 3 cht c kh nng lm mt mu dung dch nc brom C. C 2 cht c kh nng lm mt mu nc brom D. C mt cht c kh nng lm mt mu dung dch brom. Cu 42 : t chy hon ton mt hirocacbon X bng mt lng va O2 . n hn hp sn phm chy qua H2SO4 c th th tch kh gim i mt na , X thuc dy ng ng no A . Ankan B. Anken C. Ankin D. ankaien Cu 43: t chy 1 lt hirocacbon X Cn 6 lt O2 to ra 4 lt kh CO2 , Xc th lm mt mu dung dch nc brom . Khi cho Xtc dng vi H2O (xt, to) ta ch thu c mt sn phm duy nht . Cng thc cu to ca X l: A. CH3C C-CH3 B. CH3-CH=CH-CH3 C. CH2 =CH-CH2- CH3 D. CH3-CH2-CH=CH CH2 CH3 Cu 44: Cho 0,2 mol hn hp X gm etan, propan v propen qua dung dch thy khi lng bnh brom 4,2 g . Lng kh cn li em t chy hon ton thu c 6,48gam nc .Vy % th tch eta, propan, propen ln lt l: A. 30%, 20% ,50% B. 20%, 50% , 30% C. 20%, 30%, 50% D. 20%,20%, 40% Cu 45: Da trn bnca lin kt HX (X l halogen) trong cc HX gm: HF, HCl, HBr, HI, HX no cng vo lin kt ni i d nht ? A. HF B. HCl C. HBr D. HI Cu 46: Cho cc anken c cng thc cu to di y
CHCH2CH3 CH3 CH2 CH3 (X) CH3 CH2CH CCH3 CH3 (Z) CH3 CH2C CH3 (T) (Y) CHCH3 CH CHCH3

CH3 CH CH3

CH

An ken no khng c ng phn hnh hc A. X B. Y C. Z D. T Cu 47: Theo chiu tng s nguyn t cacbon trong phn t , phn trm khi lng C trong cc phn t ca cc ng ng anken : A. Tng dn B. Gim dn C. Khng i D. Bin i khng theo quy lut

Cu 48: Hidrocacbon X c CTPT C6H12 , bit X khng lm mt mu dung dch nc brm, khi tc dng vi brom khan ch thu c mt dn xut mnbrom duy nht . X,l cht no di y? A. Hexen-3 B. 1,2-imetylxiclobutan C. 1,2,3-trimetylxiclppan D. xiclohexan Cu 49: C 2 hirocacbon A,B l kh iu kin thng , khng phi l ng phn ca nhau . Khi t chy hon ton mi cht u to ra s mol nc gp 3 ln s mol mi cht chy . Chng tho mn s chuyn ho sau y :

xt, to

Cao su buna

Trong X,Y c cng s lng nguyn t C trong phn t. Vy Y l: A. vinyletilen B. etanol C. butan D. vinylclorua Cu 50: Hai hidrocacbon ng phn A v B c CTPT l C4H8 . A, B u phn ng vi H2 ( Ni, to) .Bit A c ng phn cis, trans v tc dng c vi Br2 trong CCl4 . B khng tham gia phn ng ny . CTCT cu A, B ln lt l :
A. CH3 -CH
H 2C CH H 2C CH 3 , H 2C CH2

CH-CH3 ,
H 2C

CH2
CH2

CH-CH-CH3

B.

C.

CH3

CH CH

CH3

H 2C CH H 2C H 2C CH2 CH2 CH3 ,

D.

CH3 -CH

CH-CH3 ,
H 2C