Professional Documents
Culture Documents
Aggarw al Corporat e Height s, 3rd Floor, Plot No. A - 7, Net aj i Subhash Place,
Pit am Pura, Delhi - 110034 Phone: 011-45221190-93. Fax : 25222953
AI EEE Home Pract ice Test - 3/ 2012
TI M E : 3. 00 Hrs M . M . : 360
Read t he follow ing Inst ruct ions very carefully before you proceed.
The paper cont ai ns a t ot al of 90 quest i ons
Sect i on - I : Chemi st r y, Sect i on - II : Physi cs & Sect i on - III : M at hemat i cs.
Each quest ion carries 4 M arks. - 1 w ill aw arded f or every w rong answ er ( Negat ive M arking) .
For answ er i ng a quest i on an ANSWER SHEET i s pr ovi ded separ at el y.
Pl ease f ol l ow t he di r ect i ons i n t he quest i on paper . Pl ease dar ken t he ent i r e ci r cl e t hat cor r esponds
t o your answ er f or each quest i on. Use onl y HB penci l t o mar k answ er , and er ase penci l mar ks
compl et el y t o make a change.
Do not scr i bbl e anyt hi ng on t he answ er sheet .
Please Fill your Roll Number & Personal I nf ormat ion Properly in t he space provided in t he ANSW ER SHEET.
W rong w ay of f illing Right w ay of f illing
A B C D A B C D A B C D
Please f ill t he f ollow ing inf ormat ion
REGISTRATION NO.
NAM E
Invigilat ors Signat ure
2 Vidyamandir Classes
SECTION - I (Chemist ry) 30 4 = 120
1. The Cl C Cl angle in 1, 1, 2, 2-tetrachloroethene and tetrachloromethane, respectively, will be about :
(A) 120 and 109.5 C (B) 109.5 C and 90
(C) 90 and 109.5 C (D) 109.5 C and 120
2. Which of the following orders regarding the electronegativity of hybrid orbital of carbon is correct ?
(A)
2 3
sp sp sp > > (B)
2 3
sp sp sp < < (C)
2 3
sp sp sp > < (D)
2 3
sp sp sp < >
3. The IUPAC name of the compound
is :
(A) 1-amino-1-phenyl-2-methylpropane (B) 1-amino-2-methyl-1-phenylpropane
(C) 2-methyl-1-amino-1-phenylpropane (D) 1-isopropyl-1-phenylmethyl amine
4. Keto-enol tautomerism is observed in :
(A)
||
5 6
O
H C C H (B)
||
5 6 3
O
H C C CH
(C)
||
5 6 6 5
O
H C C C H (D)
|| ||
5 6 2 3
O O
H C C CH C CH
5. In which of the following molecules, the resonance effect is not present ?
(A) (B) (C) (D)
6. Which of the following orders is not correct regarding the I effect of the substituents ?
(A) I Cl Br F < < < (B)
3 2
NR OR
+ +
<
(C)
2
NR OR F
+
< < (D)
2
SR OR OR
+
< <
7. A concentrated solution of sodium iso-butyrate is electrolysed, the product obtained at anode is :
(A) propane (B) isobutane (C) 2, 5-Dimethyl hexane (D) 2, 3-Dimethyl butane
8. Which of the following order regarding relative stability of the given alkenes is correct ?
(A) 1-Pentene < trans-2-pentene < 2-methyl-2-butene
(B) 1-Pentene < trans-2-pentene > 2-methyl-2-butene
(C) 1-Pentene > trans-2-pentene < 2-methyl-2-butene
(D) 1-Pentene > trans-2-pentene > 2-methyl-2-butene
9. Which of the following has the highest boiling point ?
(A) 1-Butyne (B) 2-Butyne (C) 1-Pentyne (D) 2-Hexyne
10. An ortho-para directing group
(A) activates ortho and para positions and deactivates the meta position
(B) activates meta position and deactivates ortho and para positions
(C) activates ortho and para positions more than the meta position
(D) deactivates ortho and para positions less than the meta position
C CH
CH
3
CH
3
NH
2
H
NH
2
NH
2
OH CCl
3
Vidyamandir Classes 3
11. Which of the following is not true ?
(A) Petrol containing a larger amount of straight-chain hydrocarbons produces less knocking
(B) Petrol containing a larger amount of branched-chain hydrocarbons produces less knocking
(C) Octane rating is zero for n-heptane
(D) Octane rating is 100 for isooctane
12. Which of the following has the highest nucleophilicity ?
(A) F
(B) OH
(C)
3
CH
(D)
2
NH
13. Which of the following alcohols is expected to have minimum boiling point ?
(A) 1-Butanol (B) 2-Butanol (C) 2-Methyl-2-propanol (D) 1-Pentanol
14. Bottles containing C
6
H
5
I and C
6
H
5
CH
2
I lost their original labels. They were labelled A and B for testing.
A and B were separately taken in test tubes and boiled with NaOH solution. The end solution in each tube was
made acidic with dilute HNO
3
and then some AgNO
3
solution was added. Substance B gave a yellow
precipitate. Which one of the following statements is true for this experiment ?
(A) Addition of HNO
3
was unnecessary (B) A was C
6
H
5
I
(C) A was C
6
H
5
CH
2
I (D) B was C
6
H
5
I
15. For which of the following parameters the structural isomers C
2
H
5
OH and CH
3
OCH
3
would be expected to
have the same values ? (Assume ideal behaviour)
(A) heat of vaporization
(B) vapour pressure at the same temperature
(C) boiling points
(D) gaseous densities at the same temperature and pressure
16. The best reagent to convert pent-3-en-2-ol into pent-3-en-2-one is :
(A) chromic anhydride in glacial acetic acid (B) pyridinium chlorochromate
(C) acidic permanganate (D) acidic dichromate
17. p-cresol reacts with chloroform in alkaline medium to give the compound A which adds hydrogen cyanide to
form the compound B. The latter on acidic hydrolysis gives chiral carboxylic acid. The structure of the
carboxylic acid is :
(A) (B) (C) (D)
18. Which of the following expressions correctly represents the van der Waals equation of state ?
(A) ( )
2
na
p V nb nRT
V
| |
+ =
|
\ .
(B) ( )
na
p V nb nRT
V
| |
+ =
|
\ .
(C) ( )
2
n a
p V nb nRT
V
| |
+ =
|
|
\ .
(D) ( )
2
2
n a
p V nb nRT
V
| |
+ =
|
|
\ .
19. Which of the following atoms would be expected to be most paramagnetic ?
(A)
3
Li (B)
4
Be (C)
5
B (D)
6
C
CH
3
OH
CH
2
COOH
CH
3
OH
CH
2
COOH
CH
3
OH
CH(OH)COOH
CH
3
OH
CH(OH)COOH
4 Vidyamandir Classes
20. Which of the following statements is not correct ?
(A) Special stability associated with half-filled and fully-filled configurations amongst s and p blocks
elements is reflected in ionization potential trends along a period.
(B) Special stability associated with half-filled and fully-filled configurations amongst s and p blocks
elements is reflected in electron affinity trends along a period
(C) Aufbau order is not obeyed in cases where energy difference between ns and ( ) n 1 d subshells is
larger
(D) Special stability of half-filled subshell is attributed to higher exchange energy of stabilization
21. In the phenomenon of osmosis through the semipermeable membrane
(A) solvent molecules pass from solution to solvent
(B) solvent molecules pass from solvent to solution
(C) solute molecules pass from solution to solvent
(D) solute molecules pass from solvent to solution
22. For a reversible reaction at temperature T, which of the following is true ?
(A) T H/ S > A A (B) T H/ S < A A (C) T H/ S = A A (D) T S/ H = A A
23. A gas expands from 1.5 to 6.5 L against a constant pressure of 0.5 atm and during this process the gas also
absorbs 100 J of heat. The change in the internal energy of the gas is :
(A) 153.3 J (B) 353.3 J (C) 153.3J (D) 353.3J
24. For given equilibrium reaction, an increase in temperature will :
(A) increase the rate of the exothermic direction more than the endothermic direction
(B) increase the rate of endothermic direction more than the exothermic direction
(C) increase both rates equally
(D) decrease both rates equally
25. Which of the following expressions is not true ?
(A) For a neutral solution
w
H OH K
+
( (
= =
(B) For an acidic solution
w w
H K and OH K
+
( (
< <
(C) For an alkaline solution
w w
H K and OH K
+
( (
< >
(D) For a neutral solution
7
H OH 10 M
+
( (
= =
at all temperatures
26. If s
0
, s
1
, s
2
and s
3
are the solubilities of AgCl in water, 0.01 M CaCl
2
, 0.01 M NaCl and 0.05 M AgNO
3
solutions, respectively, then :
(A) s
0
> s
1
> s
2
> s
3
(B) s
0
> s
2
> s
1
> s
3
(C) s
0
> s
2
> s
3
> s
1
(D) s
0
> s
1
= s
2
> s
3
27. The ion precipitating first when a solution containing 0.01 M each of Pb
2+
, Zn
2+
, Mn
2+
and Co
2+
is saturated
with H
2
S (which provides
14
1.0 10 M
of
2
S
in the solution) is :
(A) Pb
2+
(B) Zn
2+
(C) Mn
2+
(D) Co
2+
28. Which of the following statement is not correct ?
(A) Electrons enter through cathode in an electrolytic cell
(B) Electrons leave through anode in an electrolytic cell
(C) Cations in the electrolytic cell move toward cathode and anions toward anode
(D) Cations are reduced at anode and anions are oxidized at cathode in an electrolytic cell
Vidyamandir Classes 5
29. If
eq eq eq 2 4
(NaCl), (KCl) and (K SO )
A A A are 123.7, 147.0 and 152.1
1 2 1
cm eq
O , then the
eq 2 4
(Na SO )
A would be :
(A)
1 2 1
128.8 cm eq
O (B)
1 2 1
257.6 cm eq
O
(C)
1 2 1
105.5 cm eq
O (D)
1 2 1
118.6 cm eq
O
30. Given that E values of
Ag
+
| Ag, K
+
| K, Mg
2+
| Mg and Cr
3+
| Cr are 0.80 V, 2.93 V, 2.37 V and 0.74 V , respectively.
Which of the following orders regarding the reducing power of metals is correct ?
(A) Ag > Cr > Mg > K (B) Ag < Cr < Mg < K
(C) Ag > Cr > K > Mg (D) Cr > Ag > Mg > K
SECTION - II (Physics) 30 4 = 120
31. The radius of the orbital of electron in the hydrogen atom is 0.5 . The speed of the electron is
6
2 10 m/ s .
Then the current in the loop due to the motion of the electron is :
(A) 1 mA (B) 1.5 mA (C) 2.5 mA (D)
2
1 5 10 . A
32. A heater boils a certain quantity of water in time t
1
. Another heater boils the same quantity of water in time t
2
.
If both heaters are connected in parallel, the combination will boil the same quantity of water in time.
(A) ( )
1 2
1
2
t t + (B) ( )
1 2
t t + (C)
( )
1 2
1 2
t t
t t +
(D)
1 2
t t
33. When one mole of monoatomic gas expands at constant pressure, the ratio of the heat supplied that increases
the internal energy of the gas and that used in expansion is :
(A) (B) zero (C) 3/2 (D) 2/3
34. A conducting square loop of side a is moving with uniform velocity
v as shown. Emf induced in the loop is equal to :
(A) Bva
(B)
2
Bva
(C) 2Bva
(D) zero
35. The magnetic moment at the centre O of the configuration shown in figure :
(A)
2
3
2
IR t (B)
2
IR t
(C)
2
3
2
IR t
(D)
2
IR t
36. The time in which number of radioactive nuclei reduces to half of its original value is known as :
(A) Mean-life (B) Average-life (C) Half-life (D) None of these
37. Two convex lenses of focal length f
1
and f
2
are separated by a distance d. The combination will work as a glass
slab is :
(A) d = f
1
+ f
2
(B) d < f
1
+ f
2
(C) d > f
1
+ f
2
(D) None of these
a
v
Constant B
2R
R
O
I
6 Vidyamandir Classes
38. Thermions are :
(A) protons (B) electrons (C) photons (D) positrons
39. On heating a liquid of coefficient of cubical expansion in a container having coefficient of linear expansion
3
t
(B) ( )
0
1 2
4
I I
d
t
(C)
( )
1 2
2 2 0
1 2
2
/
I I
d
t
+ (D)
0 1 2
1 2
2
I I
d I I
t
| |
|
+
\ .
41. If the error in the measurement of the volume of a sphere is 6%. Then the error in the measurement of its
surface area will be :
(A) 2% (B) 3% (C) 4% (D) 7.5%
42. Work done by the force of friction :
(A) Always positive (B) Always negative
(C) May be positive, negative or zero (D) Always zero
43. To obtain a p-type semiconductor germanjum crystal, it must be doped with foreign atom whose valency is :
(A) 3 (B) 5 (C) 6 (D) 4
44. The energy level diagram of hydrogen atom is shown in figure, along with some transitions marked A, B, C, D
and E. The transitions A, B and C respectively represent :
(A) the ionization potential of hydrogen, third member of Balmer
series and third member of Paschen series
(B) the ionization potential of hydrogen, second member of
Balmer series and third member of Paschen series
(C) the series limit of Lyman series, third member of Balmer
series and second member of Paschen series
(D) the series limit Lyman series, second member of Balmer series
and second member of Pachen series
45. After 4o and 3| emissions :
(A) Atomic number decreases by 5 (B) Mass number decreases by 4
(C) Atomic number increases by 5 (D) Mass number increases by 4
46. Two radiations of photon energies, twice and five times the work function of metal are incident successively on
the metal surface. The ratio of the maximum velocity of photoelectrons emitted in the two cases will be :
(A) 1 : 1 (B) 1 : 2 (C) 1 : 3 (D) 1 : 4
O
A
B
C
D
I
1
I
2
d
p
n = 7
n =
n = 6
n = 5
n = 4
n = 3
n = 2
n = 1 13.58
3.39
1.51
0.85
0.54
0.36
0.00
eV
CONTINUOUS LEVELS
B
A
C
D
E
Vidyamandir Classes 7
47. Two moving particles P and Q are 10m apart at a certain instant. The
velocity of P is 8 m/s making an angle of 30
with PQ as shown
in figure. Then angular velocity of P with respect to Q is :
(A) zero (B) 0.1 rad/sec
(C) 0.4 rad/sec (D) 0.7 rad/sec
48. The motion of a body is given by the equation
2
4
dv
v
dt
= + where v is speed in m/s and t is time in seconds. If
the body was at rest at t = 0, then its velocity at 6 t / sec t = ,
(A)
2
3
(B)
3
2
(C) 2 3 (D) None of these
49. During S.H.M.., a particle has displacement x from mean position. If acceleration, kinetic energy and excess
potential energy are represented by a, K and U respectively. Then choose the appropriate graph :
(A) (B) (C) (D)
50. A milliammeter of range 25mA has a coil of resistance 5O. To use it as a voltmeter of range 2.5 V, the
resistance that should be connected in series with it is :
(A) 0 95 . O (B) 9 5 . O (C) 95O (D) 950O
51. A secondary battery consists of 20 cells in series each having an e.m.f. of 1.8 volt when discharged and
2.6 volt when charged. The internal resistance of each cell can be assumed to be constant and equal to
0.1 ohm. If the charging supply of 80 volt is available then the value of variable resistance required to maintain
the charging current at a constant value of 10 amp throughout the charging period is :
(A) 80 ohm to 16 ohm (B) 2.4 ohm to 0.8 ohm
(C) 4.8 ohm to 16 ohm (D) 2.1 ohm to 1.2 ohm
52. If particle A of mass m carrying a charge q is moving with velocity v in x-y plane in circular path because of
magnetic field
B B.k =
. The particle B of mass 2m, carrying a charge 4q is moving with velocity 2v in x-y
plane in circular path because of same magnetic field. Ratio of radii R
A
: R
B
is :
(A) 1 : 1 (B) 2 : 1 (C) 1 : 2 (D) None of these
53. A magnet of magnetic moment M moves with velocity v towards a magnet. Consider a small circular loop
whose plane is normal to v . Its radius r is so small that magnetic inductance is almost constant over it. Then :
(A) The magnetic flux through the area of the loop is constant
(B) The electric field intensity along the tangent to the loop and in the plane of the loop is of magnitude
0
4
3
4
Mvr
x
t
and direction E v
(C) The electric field intensity is in the direction along v
(D) The electric field intensity is not induced anywhere
P
Q 30
30
8 m/s
K
O x
U
O
a
K
O
a
U
O
K
r
S N
x
8 Vidyamandir Classes
54. Find the number N of nuclei of a radioactive element X at time t, if at time t = 0, the element has N
0
number of
nuclei. Assume nuclei of the element X is being produced at a constant rate ' ' o and the element has a decay
constant :
(A)
( ) 0
1
t t
N e N e
o
= + (B)
( ) 0
1
t t
N e N e
o
= +
(C)
( ) 0
1
t t
N e N e
o
o
= + (D)
( ) 0
1
t t
N e N e
= +
o
o
55. A light source is placed at a distance b from a screen. The power of the lens required to obtain k-fold magnified
image is :
(A)
1 k
kb
+
(B)
( )
2
1 k
kb
+
(C)
( ) 1
k
k b +
(D)
( )
2
1
k
k b
56. n moles of an ideal gas undergo a process A B as shown in the figure.
Maximum temperature of the gas during the process is :
(A)
0 0
3
2
P V
n R
(B)
0 0
9
4
P V
n R
(C)
0 0
9
2
P V
n R
(D)
0 0
9 P V
n R
57. A cathode ray tube contains a pair of parallel metal plates 1.0 cm apart and 3.0 cm long. A narrow horizontal
beam of charged particles with a velocity of
7 1
3 10 ms
)
(A)
7
2 10 J
(B)
7
19 10 J
(C)
7
46 10 J
(D)
7
74 10 J
A
B
V
P
P
0
2P
0
V
0
2V
0
Vidyamandir Classes 9
SECTION - III (M at hemat ics) 30 4 = 120
61. If x = 2 + 5i, then the value of x
3
5x
2
+ 33x 19 is equal to:
(A) 5 (B) 7 (C) 7 (D) 10
62. If the imaginary part of
2z 1
iz 1
+
+
is 4, then the locus of the point representing z in the complex plane is:
(A) a straight line (B) a parabola (C) a circle (D) an ellipse
63. If | z | = 3, the area of triangle whose sides are z, ez and z + ez (where e is complex cube root of unity) is :
(A)
9 3
4
(B)
5
2
(C)
3 3
2
(D)
8 3
3
64. If cos i sin
n n
t t
e = + , then value of
2 n 1
1 ... e e e
+ + + + is:
(A) 1 + i (B) 1 + i tan (p/n) (C) 1 + i cot (t/2n) (D) None of these
65. If the roots of (z 1)
25
= 2e
2
(z + 1)
25
(where e is a complex cube roots of unity) are plotted in the argand
plane, they lie on:
(A) a straight line (B) a circle (C) an ellipse (D) None of these
66. Two events A and B have probabilities 0.25 and 0.50 respectively. The probability that both A and B occur
simultaneously is 0.14. The probability that neither A nor B occurs is:
(A) 0.39 (B) 0.25 (C) 0.11 (D) None of these
67. If letters of the word ''ASSASSIN'' are written down at random in a row, the probability that no two S' s occur
together is:
(A) 1/7 (B) 1/14 (C) 1/28 (D) 1/35
68. A bag contains a white and b black balls. Two players, A and B alternately draw a ball from the bag, replacing
the ball each time after the draw till one of them draws a white ball and wins the game. A begins the game.
If the probability of A winning the game is three times that of B, the ratio a : b is:
(A) 1 : 1 (B) 1 : 2 (C) 2 : 1 (D) None of these
69. Let A and B be two events such that P (A) = 0.3 and P (A B) = 0.8. If A and B are independent events, then P
(B) is:
(A) 3/7 (B) 4/7 (C) 5/7 (D) 6/7
70. A box contain N coins, m of which are fair and rest are biased. The probability of getting a head when a fair
coin is tossed is 1/2, while it is 2/3 when a biased coin is tossed. A coin is drawn from the box at random and is
tossed twice. The first time it shows head and the second time it shows tail. The probability that the coin drawn
is fair is:
(A)
8m
8 N m +
(B)
m
8 N m +
(C)
9m
8 N m +
(D)
9 N
8 N m +
71. If ( )
| | ( )
| |
| |
| |
for
0 for x
sin 1 x
x 0
f x x
0
+
=
=