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ECE handbook for GEAS (EXCEL) second edition 1. What volume of concentrated sulfuric acid would weigh 0.

82 kg if the density is 1.85 g/mol? 2. Under a pressure of 770 torr, 150 ml of gas is enclosed inside a cylinder. What will be the volume in liters of the same amount of gas if the pressure is increased by 1500 torr? 3. In a nuclear explosion, one cubic foot of air is heated from 0 degrees C to 500,000 degrees C. To what volume does the air expand? 4. What is the pressure required to compress 3 liters of gas at 720 mm of pressure and 20 deg. C temperature into a vessel with 0.5 liter capacity at a temperature of -100 deg. C. 5. A chemist has a gas under pressure of 30 atm and it occupies a volume of 25 liters at 300 deg. C. For his research, the gas must be at standard conditions. Once he will perform his experiments, what will the volume of the gas be? 6. Phosgene (COCL2) was a gas used by the German troops in World War 2 to poison American and British soldiers. How many molecules of this gas are ther in mass of 1x 10^8 kg? 7. An old car traveling at a speed of 15 miles per hour produces 0.50 lb of carbon monoxide gas per mile. How many molecules of carbon monoxide are produced per mile? 8. A gas vessel containing hydrogen gas was scaled and its pressure was measured to be 1 atm. At this pressure, the mass of the gas is 0.0042 kg. Calculate the number of molecules present in the hydrogen gas. 9. How many moles of hydrogen gas are there in a 100-liter container if the pressure is 15 atm and the temperature is 25 degrees Celcius? 10. What is the molecular weight of gas if 5 grams of it occupies a volume of 10 liters at 800 torr and temperature of 150 deg. C? 11. A gas vessel contains oxygen gas at pressure of 15 atm and a temperature of 25 deg. C. If the volume of the gas vessel is 15 liters, what is the mass of oxygen gas? 12. An unknown gaseous compound hass mass of 1 g and is made up of Boron (Atomic weight= 10.8 g/mol) and Hydrogen (Atomic weight=1 g/mol) atoms. What is the molecular formula of this compound if it occupies 0.82 liters at 1 atm pressure and 276 K absolute temperature? 13. What is the mole fraction of ethyl alcohol (C2H5OH) if 15 grams of this compound is dissoled in 36 grams water? 14. A mixture of nitrogen gas and oxygen gas is collected by displacement of water at 30 deg. C and pressure of 750 torr. If the partial pressure of nitrogen is 580 torr, what is the partial pressure of oxygen? Assume that the vapor pressure of H2O at a temperature of 30 deg. C is 38 torr.

15. If 50 liters of nitrogen gas are collected at 25 deg. C over water at a pressure of 0.95 atm, what is the volume of dry nitrogen at STP? 16. Under STP, what is the rate of diffusion of inert gas Argon? 17. Two gas compounds, HBr and CH4, have molecular weights of 81 and 16, respectively. The HBr compound diffuses through a samll opening at a rate of 4 ml/s. At what rate in ml/s will the other compound diffuse through the same opening? 18. Freshwater salmon is said to contain 0.15 ppm of mercury. how many mercury atoms would there be in a 500 gram fillet of freshwater salmon? 19. How many molecules are there in a drop of water that weighs 0.15 g? 20. How many carbon atoms are there in 5 grams of C-13 isotope? 21. How many moles are there in 210 grams H3SO4? 22. How many moles are there in 100 g of calcium carbonate? 23. A sample of pure compound contains 9.81 grams zinc, 1.81 X 10^23 atoms of chromium and 0.60 moles of oxygen atoms. what is the simplest chemical formula? 24. What is the equivalent weight in water of oxygen if its atomic weight was 100? 25. There is a compound that is made of vanadium and oxygen atoms. This compound is found to be 56% vanadium. What is the equivalent weight of vanadium in this compound? 26. Determine the simplest formula of a compound that has 72.4% iron and 27.6% oxygen by weight? 27. What is the empirical formula of an unknown compound that is made up of 82.98% potassium and 17.02% oxygen? 28. What is the percentage weight of magnesium in the compound magnesium chloride (MgCl2)? 29. A certain solution contains 5% FeSO4. Hwo many pounds of Fe can be obtained from 1 ton of this solution? 30. What is the mass of 1 Liter of carbon monoxide at STP? 31. A person dropped a 250-gram object inside a tank filled with water. It displaced 50 ml of water when it sunk to the bottom of the tank. In a similar experiment, it displaced only 30 g of oi into which it was dropped. What is the density of oil? 32. What is the mole fraction of the solute in a solution made by dissolving 100 grams of H2SO4(molecular wt=98 g/mol) in 250 grams of water?

33. What is the molalityof a solution in which 32 grams of H2SO4 (molecular wt=98 g/mol) is dissolved in quarter of a kilo of water? 34. Determine the mass of sulfuric acid in 5 L of 0.1 molar solution (MW=98.1g/mol) 35. What is the molarity of a hydrogen peroxide solution prepared by mixing 13 g of hydrogen peroxide (H2O2) per 300 ml of solution? 36. Determine the number of moles present in 151.99 g of Magnesium. 37. How many moles of Cobalt are there in 6 billion atoms of the same element? 38. Determine the molecular mass of CH4O in amu 39. A certain gas occupies a volume of 1 L in a temperature 25 deg. C and a pressure of 500 torr. what is the volume of the gas if the temperature is changed to 55 deg. C and the pressure is increased to 700 torr? 40. A certain gas occupies a volume of 1 L in a temperature 25 deg. C and a pressure of 500 torr. what is the volume of the gas if the temperature is changed to 55 deg. C and the pressure is increased to 700 torr? 41. A sample of gas occupies a 14.3-liter container at a temperature of 100 deg. C and a pressure of 780 mmHg. Determine the number of moles of the gas resent. 42. A block of solid wood has dimension 30 cm X 0.50 cm X 500 cm and weighs 300 kg. Calculate its density in grams per cubic centimeters. 43. If a certain amount of carbon has a mass of 1 X 10^-6 grams, how many atoms are there? 44. The density of one bottle of alcohol is 0.85 g/mol. What is the weight of the alcohol if the volume of the bottle is 50 ml? 45. The density of one bottle of alcohol is 0.85 g/mol. What is the weight of the alcohol if the volume of the bottle is 50 ml? 46. A 40 g methanol sample is mixed with 60 g ethanol sample. One mole of methanol and ethanol has a mass of 32 g and 46 g, respectively. What is the mole fraction of the solvent? 47. A 40 g methanol sample is mixed with 60 g ethanol sample. One mole of methanol and ethanol has a mass of 32 g and 46 g, respectively. What is the mole fraction of the solvent? 48. What is the molality of a solution containing 75.5 g sucrose (molar mass=34,2 g/mol) in 400 g of water? 49. What volume will 1.27 mol of helium gas occupy at STP? Gas constant 0.0821 L-atm/mol-K.

50. The diameter of carbon atom is 1.5 angstrom. How many carbon atoms each with said diameter could be aligned side by side in a straight line across with a pencil line that is 0.20 mm wide?

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