Material Safety Data Sheet

0 BYK&
Revision Date 03/29/2011

Add~tives Instruments

Version 5

Print Date 04/04/2011

SECTION 1 PRODUCT AND COMPANY IDENTIFICATION . Product name Product Use Description Company Prepared by Telephone Visit our web site E-mail address Emergency telephone number

: : :
:

BYKJET-9133 Wetting & Dispersing Additive BYKUSAInc. 524 South Cherry Street Wallingford CT 06492 J.Nole, Safety; M.McCutcheon, Regulatory (203) 265-2086 www.byk.com ehs.byk.usa@altana.com CHEMTREC 800-424-9300

: : : :

SECTION 2. HAZARDS IDENTIFICATION Emergency Overview Form Colour Odour OSHA Regulatory Status This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR1910.1200) Potentlal Health Effects Eyes Skin Ingestion Inhalation Chronic Exposure Aggravated Medical Condition Primary Routes of Entry
: liquid : amber : sweet

: Contact will probably cause irritation. : Contact will probably cause irritation. : Ingestion may irritate the digestive tract. : None expected.
: No known chronic health effects. : May be aggravating to some skin condit~ons : Skin contact Skin absorption Inhalation Eyes Ingestion

Carcinogenicity: 119

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No component of this product present at levels greater than or equal to 0.loAis identified as probable, possible or confirmed human carcinogen by IARC. No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. No component of this product present at levels greater than or equal to 0 1 is identified as a known .% or anticipated carcinogen by NTP. No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH.
Environmental Effects

Environmental Effects

: No information available.

SECTION 3. COMPOSlTlONllNFORMATION ON INGREDRNTS Chemical nature

Alkylammonium salt of a high molecular weight copolymer

Hazardous components

The specific chemical identitylweight percent of proprietary ingredient(s) is a trade secret Component Phosphoric ester salt
SECTION 4. FIRST AID MEASURES First aid procedures

CAS-No.

Weight percent

30.00- 60.00

Inhalation Skin contact

: Remove to fresh air. Administer artificial respiration if necessary. Get medical aid as soon as possible. : Remove contaminated clothing. Immediately flush contaminated skin wlwater at least 20 min. Get medical aid as soon as possible. : Immediately flush with plenty of water for at least 20 minutes. Get medical aid. : Do not induce vomiting. Get immediate medical attention. Never give anything by mouth to an unconscious person.

Eye contact Ingestion

Notes to physician

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Material Safety Data Sheet

0 BYK Instruments
Add~tives & Revision Date 03/29/2011 Print Date 04/04/2011

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Version 5 Risks

: No information available.

SECTION 5. FIRE-FIGHTING MEASURES Flammable properties Flash point Ignition temperature Suitable extinguishing media Unsuitable extinguishing media Special protective equipment for fire-fighters Specific hazards during fire f~ghting Hazardous decomposition products due to incomplete combustion. Further information

: 135 "C (275.00 4)

Method: 49 (Pensky-Martens)

: > 200 OC (> 392 OF) : Foam

Carbon dioxide (C02) Dry chemical

: No information available. : In the event of fire, wear self-contained breathing apparatus.

: Cool closed containers exposed to fire with water spray. Will not explode on mechanical impact.

: Carbon oxides
nitrogen oxides (NOx) Oxides of phosphorus : Keep away from heat and sources of ignition. agents. Keep away from ox~dizing

SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions : Wear protective equipment: goggles, chemically resistant clothing and gloves, and appropriate respirator if in a confined area. : Prevent spilled material from entering the ground, water and/or air by using appropriate containment methods. : Stop leak. Dike and contain spill. : Pump into salvage tanks andlor absorb with suitable material. Use sparkless shovels to remove material. : No further information is available.

Environmental precautions Methods for containment Methods for cleaning up Additional advice

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SECTION 7. HANDLING AND STORAGE Handling Handling

: Avoid contact with skin and eyes. Handle as an industrial chemical. Keep container tightly closed. Keep away from oxidizing agents.

Storage Advice on common storage

: Keep in a dry, cool and well-ventilated place.

SECTION 8. EXPOSURE CONTROLSIPERSONAL PROTECTION Exposure Guidelines Contams no substances with occupational exposure limit values. Engineering measures Engineering measures
: Use with local exhaust ventilation.

Personal protective equipment Eye protection Hand protection Skin and body protection Respiratory protection Hygiene measures
: Safety Glasses Goggles : Neoprene gloves

: Choose body protection according to the amount and concentration of the dangerous substance at the work place.
: Not necessary.

: Clean long legged, long sleeved work clothes. Handle in accordance with good industrial hygiene and safety practice.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Form Colour Odour Odor Threshold Flash point
: liquid : amber : sweet : no data available : 135 "C (275.00 "F) Method: 49 (Pensky-Martens)

419

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Material Safety Data Sheet

0 Additives & BYK

Revision Date 03/29/2011

Instruments

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Version 5 Print Date 04/04/2011 Ignition temperature Lower explosion limit Upper explosion limit pH

: > 200 "C (> 392 OF) : no data available : no data available : 5.8 at 20 "C (68 "F)
Method: 26 ( I %ig in Wasser)

Freezing point Boiling point Vapour pressure

: no data available
: no data available

: c 1.0000000 hPa at 20 OC (68.00 T)

Method: calculated

Evaporation rate Density Bulk density Water solubility Partition coefficient: noctanol/water Viscosity, kinematic

: no data available : 1.0500 g/cm3 at 20 OC (68.00 4)Method: DIN EN IS0 2811-3 : not applicable : completely miscible
: no data available : at 20 OC (68.00 F) no data available at 40 "C (104.00 4 ) no data available

Relative vapour density

: no data available

SECTION 10. STABILITY AND REACTIVITY

Conditions to avoid Materials to avoid : None known. : Strong oxidizing agents Metals Gives off hydrogen by reaction with metals. Hazardous decomposition products Chemical stability : None expected : Stable; polymerization will not occur

SECTION 11. TOXICOLOGICAL INFORMATION

Acute oral toxicity (Product)
: LD50 rat

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Dose: > 5,000.000000 mglkg Method: OECD Test Guideline 401 active ingredient Skin irritation (Product)

: rabbit
Result: Skin irritation Method: OECD Test Guideline 404 active ingredient

Sensitisation (Product)

: no data available

SECTION 12. ECOLOGICAL INFORMATION

Toxicity to fish (Product)

: static test LC50 Species: Oncorhynchus mykiss (rainbow trout) Dose: 8.00 mgll Exposure time: 96 h Method: OECD Test Guideline 203 active ingredient

Toxicity to algae (Product)

: EC50
Species: Pseudokirchneriella subcapitata (green algae) Dose: .47 mg/l Exposure time: 72 h Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Additional ecological information (Product)

: There is no data available for this product.

SECTION 13. DISPOSAL CONSIDERATIONS

Further information

: Dispose of in accordance with applicable local/municipal, statelprovincial and federal regulations.

SECTION 14. TRANSPORT INFORMATION

Container sizes: 55 gallon drums, 5 or 6-gallon pails, 20211602 samples)

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UN Number Proper shipping name Class Packing group Emergency Response Guidebook Number

: :
:

3082 Environmentally hazardous substance, liquid, n.0.s. (Alkylammonium salt)

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Ill : 171

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Material Safety Data Sheet

0 BYK&
Additives Revision Date 03/29/2011

Instruments

Version 5

Print Date 0410412011

IATA

UN Number Description of the goods Class Packing group ICAO-Labels Packing instruction (cargo aircraft) Packing instruction (passenger aircraft) Package Instruction (Limited quantity)

: 3082
: Environmentally hazardous substance, liquid, n.0.s. (Alkylammonium salt) : 9 : Ill : 9 : 964

: 964
: Y964 : UN 3082 : Environmentally hazardous substance, liquid, n.0.s. (Alkylammonium salt) : 9 : Ill : 9 : F-A : S-F : yes

IMDG

UN Number Description of the goods Class Packing group IMDG-Labels EmSNumberl EmSNumber2 Marine pollutant

SECTION 15. REGULATORY INFORMATION HMlS Classification

: Health hazard: 2 Flammability: 1 Reactivity: 0 PPI:B

National Fire Protection Association (NFPA) Class

: Ill6

Emergency Planning Community Right-To-Know (EPCRA) SARA 302 Components

: Not applicable

If listed below, this product contains toxic chemical(s) subject to the reporting requirements of Section 313 of Title Ill of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR part 372.

SARA 3111312 Hazards

: Acute Health Hazard

Toxic Substances Control Act (TSCA) : We certify that all of the components of this product are either TSCA Status

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listed on the TSCA Inventory or are not subject to the notification requirements per 40 CFR 720 30(h). Section 4 I 12(b) : Not applicable

Clean Air Act & Related Information Non-volatile (Wt)

: 92-100%
Method: 22 (1Omin1150%) DIN EN IS0 3251

Ozone Depleting Substances

: Not applicable.

Non-volatile information is not a specification.

Hazardous Air Pollutants If not listed above, this product does not contain HAPS at 1% or 0.1% or greater. Refer to Section 3 for HAP weight percentage. Resource Conservation and Recovery Act
EPA Hazardous Waste Code@)

Not applicable.

State Laws Massachusetts Right To Know Components Pennsylvania Right To Know Components New Jersey Right To Know Components New Jersey Trade Secret Registry Number for the product (NJ TSRN) California Prop. 65 Components
: No components are subject to the Massachusetts Right to Know Act.

: Phosphoric ester salt

: Phosphoric ester salt : 800963-5256

: This product does not contain any chemicals known to State of

California to cause cancer, birth defects, or any other reproductive harm.

CONEG Heavy Metal: We certify that this product does not contain Lead, Mercury, Cadmium or hexavalent chromium in the sum concentration of 100 ppm by weight or greater.

Canadian Environmental Protection Act

Material Safety Data Sheet

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Print Date 0410412011

Domestic Substances List DSL Status

: We certify that all of the components of this product are listed

on the DSL.

WHMlS Classification

: 028

SECTION 16. OTHER INFORMATION Further information

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

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