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Product Use: Shipping Name Petroleum crude oil Process Stream, Fuel & Lubricants production Chemical Family Complex mixture of Aliphatic & Aromatic Hydrocarbons and small amount of sulphur. Manufacturer/Supplier Nigerian Agip Oil Company limited Street Address Mile 4,Ikwerre Road, City Port Harcourt Postal Code Emergency Telephone 234 + 234 (0)70 501 77220 Date MSDS Prepared MSDS Prepared By Phone Number 06/03/2013 Terminal Operations Asst. Mgr. + 234 (0)70 501 77221
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Data
Liquid Brown to Black Viscous liquid Petroleum N/A 181gmol-1 N/A 0.70-0.95 2.5-5.0 N/A Neutral < 1.0 N/A < -400C 38 - 496 < -40 Slightly Soluble 0.5-200 @ 20 deg. C.
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Eye Contact:
Skin Contact:
Inhalation:
Ingestion:
General Advice:
Use positive pressure self-contained breathing apparatus, supplied air breathing apparatus, or cartridge respirator approved for organic vapors where concentrations may exceed exposure limits (note: cartridge respirator not suitable for oxygen deficiency or IDLH situations) Viton (nitrile adequate for short exposure to liquid) SCBA, SABA or cartridge respirator approved for organic vapours.
Gloves: Respiratory:
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Chemical splash goggles As per safety policy. As per fire protection policy Use only in well ventilated areas. Mechanical ventilation required in confined areas equipment must be explosion proof. Stop leak if safe to do so. Use personal protective equipment. Use water spray to cool containers. Remove all ignition sources. Provide explosion proof clearing ventilation, if possible prevent from entering confined spaces. Dyke and pump into containers for recycling or disposal. Notify appropriate regulatory authorities. Contact appropriate regulatory authorities for disposal requirements.
Avoid contact with liquid. Avoid inhalation. Bond and ground all transfers. Avoid sparking conditions. .
Storage Requirements:
Store in a cool, dry, well ventilated area away from heat, strong sunlight, and ignition sources.
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This material is flammable and can be ignited by heat, sparks, flames, or other sources of ignition. Vapors may travel considerable distance to a source of ignition where they can ignite, flashback, or explode. May create vapor/air explosion hazard indoors, in confined spaces or outdoors. Vapors are heavier than air and can accumulate in low areas. If container is not properly cooled, it can rupture in the heat of a fire.
SECTION 7 - TOXICOLOGICAL PROPERTIES OF PRODUCT Routes of Entry: Skin Absorption: Skin Contact: Eye Contact: Inhalation: Acute: Chronic: Ingestion:
Yes Yes (liquid) Yes Yes Yes Yes
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Effects of Acute Exposure: Vapour may cause irritation of eyes, nose and Contact with skin: Contact with eyes: Effects of Chronic Exposure:
throat. May cause irritation and possibly dermatitis. Absorbed through intact skin. Contact of liquid with eyes may cause severe irritation.
Due to presence of benzene and n-hexane, long term exposure may increase the risk of anemia, leukemia and nervous system damage. No Yes None reported Possibly Possibly Possibly
Evacuate all dangerous contact objects and eliminate all spark ignition sources. Evacuate personnel and contact the emergency spill response team . Contain spill. Absorb with an inert absorbent and disposed the used absorbent appropriately. The appropriate responsible body should address all leaks.
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Large pools may be covered with appropriate absorbent to contain the spill. The contained spill should be removed with an explosion proof vacuum-cleaning machine. The appropriate responsible body should address all leaks.
Storage:
Store in accordance with local regulations. Store in a segregated and approved area. Store away from direct sunlight in a dry, cool and well- ventilated area away from incompatible materials (see section 9 ). Eliminate all ignition sources Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination
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Strong acids. Strong oxidizers. Chlorine. Oxides of carbon. Oxides of nitrogen. Aldehydes. Hazardous sulphur dioxide and related oxides of sulphur may be generated upon combustion.
Under normal conditions of storage and use, hazardous polymerization will not occur
Hygiene measures:
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Hands:
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Regulatory information
UN number
Class
Packing group
Label
TDG classification
UN 1267
I or II
IMDG classification
UN 1267
3 II
DOT Classification
UN 1267
3 II
IATA/ICAO Classification
UN 1267
3 II
SECTION 15 - REGULATIONS
Primarily, the regulatory controls in the handling, storage and transportation of petroleum Crude oil hinges on its intrinsic properties of being flammable and having toxic contents which have been identified and classified by WHMIS(Canada) as listed in section 3 of hazards Identification. Also, this product has been classified in accordance with the hazards criteria of the CPR and the MSDS documentation suffices in the detailing all the required information by the CPR that are needed to safely guide a user
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Label requirements
HMIS Rating
2 2 0 0 x x
ACGIH: ASTM: API: BS &W: BOD COD: CAS: CPR: DOT: HMIS: IATA: IMDG: LD: LC: N/A: NIOSH: OSHA: OEL : PPE : PEL: STEL: TLV: TWA: UN NUMBER: WHMIS:
American Conference of Governmental Industrial Hygienists American society for Testing Materials American Petroleum institute Bottom Sediment and Water Biological Oxygen Demand Chemical Oxygen Demand Chemical Abstract Service registry number Controlled Products Regulations US Department of Transportation Hazardous Material Information System International Air Transport Association International Maritime Dangerous Goods Lethal Dose Lethal Concentration Not Available National Institute for Occupational Safety and Health, US Department of Health and Human Services Occupational Safety and Health Administration, US Department of Labor Occupational Exposure limit Personal Protective Equipment Permissible Exposure Limit Short Term Exposure Limit Threshold Limit Value Time-weighted Average United Nations registry number Work Place Hazardous Materials Information
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