Volumetric Analysis - Acid/Base Titration Using Indicators

Excel Template

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A B C Chem1310 Name: Partner's Name: Section: Date of Experiment Performed: Date of Report Prepared:

B3 9-Sep 25-Sep

Volumetric Analysis- Acid/Base Titration Using Indicators

Your SRS serves as your "Laboratory Notebook", where original and permanent record of your work is kept, and required to submit your SRS with your completed assignment every week. However, since you will be completing your calculation/analysis on Excel Spreadsheet, you are not required to complete your SRS (Your TA will only check your "collected data" to prove your work) unless otherwise noted in the "Assignment Instruction".

Part I: Standardization of NaOH Solution

-Dealing with Significant Figures
Enter your data (Numerical Values ONLY. Do not inclue unit.) into the following table "Taburated Data". Then, Format each cell to show correct significant figures. See Excel Instruction - "Adjusting Significant Figures in Excel" on WebCT for the detailed instructions. You may omit any trial you didn't perform.

Tabulated Data Mass KHP (g) Initial buret reading NaOH (mL) Final buret reading NaOH (mL)

Trial 1 0.3499 0.00 35.59

Trial 2 0.3881 0.00 40.10

Trial 3

Remember the following rules about Significant Figures in our Lab

Graduated Cylinder - Decimal Place is 1 Thermometer - Decimal Place is 1 (eg. 24.3 Volumetric Pipet - Decimal Place is 2 (eg. 10.00 mL) Buret - Decimal Place is 2 (eg. 34.64 mL) Analytical Balance - Decimal Place is 4 ~ 5 (eg. 15.1538 or 15.15383g) *You can read to 2nd decimal on some graduated cylinder

"Unit" is already supplied in each category, so input only numerical values here.

-Mathematical Calculation Directly on Excel

Using the data you just entered above, complete the following table "Tabulated Results". You should complete this section by calculating directly on this spreadsheet using Excel. No calculator is allowed. See Excel Instruction - "Calculations in Excel 1" on WebCT for the detailed instructions.

Useful Units MW* of KHP (g/mol)

*MW=Molecular Weight

204.22

It's a great idea to list any "Literature Value" that you need to use in your calculation. Note that KHP is "potassium hydrogen phthalate" (KHC8H4O4)

Tabulated Results Volume used NaOH (mL) Moles KHP Moles NaOH in dispensed volume Molarity NaOH solution (M) Average Molarity of NaOH (M)

Trial 1 35.59 0.001713 0.001713 0.04814 0.047765

Trial 2 40.1 0.001900 0.001900 0.04739

Trial 3

"Hint" The formula for the Moles KHP =E28/$D$45 "$" is placed so that cell D45 (MW of KHP) is fixed and won't move when you "Click" "Hold" & "Drag to the right" to complete the calculation for the rest of trials. See Excel Instruction - "Calculations in Excel 1" for more detailed instructions.

Input only numerical values here. Be sure to show appropriate Sig. Fig. Acid:Base ratio between KHP and NaOH is 1:1. You needed certain amount of NaOH to react with known moles of KHP, thus moles of NaOH in the dispensed volume should be? Remember, Molarity (M) is moles per Liter

Chem1310 Laboratory

Copyright (c) 2003 Tatsuya Maehigashi

Volumetric Analysis - Acid/Base Titration Using Indicators

Excel Template

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-Supporting Calculation
Show Supporting Calculation for the indicated item. At this point, no strict format is specified for this part of the assignment (Hand writing is absolutely fine). If you'd like to try "Equation Editor", see the Excel Instruction available on WebCT.

Supporting Calculation Molarity NaOH solution (M) Trial 1 Only

Part II: Titration of Diluted Vinegar

Now, utilize the techniques that you have learned so far, complete the following tables according to your obtained laboratory data. Be sure to calculate directly on this spreadsheet (No calculator) and adjust the decimal place that correct significant figures are shown for each value. Refer to the section "Reporting Data Accuracy Figures" on your manual regarding Sig. Fig. rules upon basic calculations (+ , - , and ).

Useful Units Average Molarity of NaOH standardized (M) Tabulated Data Mass Flask (g) Mass Flask + water, calibration (g) Temperature water (C) Density water, at observed temp (g/ml) Initial buret Reading NaOH (ml) Final buret Reading NaOH (ml) Tabulated Results Mass water, delivered by pipet, calibration (g) Volume water, delivered by pipet, calibration (ml) Volume vinegar, delivered (ml) Volume NaOH delivered (ml) Molarity Acetic Acid in diluted vinegar (M) Molarity Acetic Acid in stock vinegar (M) Average Molarity Acetic Acid in stock vinegar (M)

From Part I (E53). Type = and click the cell E53, then hit "Enter Key". Now it's linked!

4.7765E-02 Trial 1 50.1849 60.1758 25 0.99705 0.00 17.75 Trial 2 50.1849 60.1758 25 0.99705 0.00 18.30 Trial 3

See Table B.1 on your manual (Appendix B)

Use mass & density to compute

Trial 1 Trial 2 9.9909 9.9909 10.02 10.02 10.02 10.02 17.75 18.30 1.1507E-04 1.1507E-04 1.1507E-03 1.1507E-03 1.1507E-03

Trial 3

Use the pipet-calibration result. It is NOT 10.00mL

"diluted vinegar" = Acetic acid solution that you made by diluting stock vinegar with water in a volumetric flask. This is the one you titrated. "stock vinegar" = Original vinegar (undiluted) in stock container.

Chem1310 Laboratory

Copyright (c) 2003 Tatsuya Maehigashi

Volumetric Analysis - Acid/Base Titration Using Indicators

Excel Template

A 125 126 127 128 129 130 131 132 133 134 135 136 137 138 139 140 141 142 143 144 145 146 147 148 149 150 151 152 153 154 155 156 157 158 159 160

B C D E Supporting Calculations Molarity Acetic Acid in diluted vinegar (M) Trial 1 Only

I
Hand-Writing is fine

Molarity Acetic Acid in stock vinegar (M) Trial 1 Only

Hand-Writing is fine

Once finished, print this report (B & W is fine), staple with your actual SRS and other necessary documents (See "Assignment Instruction" for required items), and submit to your TA. Make sure to check/adjust the printing-range you print this assignment (See Excel Instruction - Page Setup and Printing in Excel 1) .

Chem1310 Laboratory

Copyright (c) 2003 Tatsuya Maehigashi

Volumetric Analysis - Acid/Base Titration Using Indicators

Excel Template

K 1 2 3 4 5 6 7

8 9 10 of your work is kept, and you are 11 ce you will be completing your Your TA will only12 check your 13 14 15 16

cators

17 18 19 20 table "Taburated Data". 21 "Adjusting Significant 22 you didn't perform. 23 24 25 er the following 26 rules about Significant Figures in 27 Lab our 28 Decimal Place is 1* (eg. 5.6 mL) 29 Decimal Place is 1 (eg. 24.3 C) 30 Decimal Place is 2 (eg. 10.00 mL) Decimal Place 31 (eg. 34.64 mL) is 2 Decimal Place is 4 ~ 5 32 (eg. 15.1538 or 15.15383g) 33 read to 2nd decimal on some graduated cylinder 34 35 36 37 Results". You should complete 38 See Excel 39 40 41 42 43 44 45 46 47 48 Trial 1 should be KHP =E28/$D$45 49 laced so that cell50 (MW of KHP) is D45 d won't move when you "Click" "Hold" & 51 the right" to complete the calculation for 52 the rest of trials. 53 "Calculations in Excel 1" 54 for more detailed instructions. 55 56 57 58 member, Molarity (M) is moles per Liter 59 60 61 62

Chem1310 Laboratory

Copyright (c) 2003 Tatsuya Maehigashi

Volumetric Analysis - Acid/Base Titration Using Indicators

Excel Template

K L 63 64 65 at is specified for this part of the 66 ", see the Excel 67 Instruction 68 69 70 71 72 73 74 75 76 77 78 79 If you decide to 80 complete this step 81 by hand-writing, 82 don't forget to do so after printing! 83 84 85 86 87

88 89 90 91 tables according to your obtained and adjust the 92 decimal place so eporting Data Accuracy - Significant 93 94 95 96 97 98 99 = and click the cell E53, then hit 100 101 102 103 104 105 See Table B.1 on your manual 106 107 108 Use mass & density to compute 109 110 Use the 111 pipet-calibration result. 10.00mL 112 113 114 = Acetic acid solution that 115 you made by diluting stock vinegar with water in a volumetric flask. This is the one 116 117 = Original vinegar (undiluted) in stock container. 118 119 120 121 122 123 124

Chem1310 Laboratory

Copyright (c) 2003 Tatsuya Maehigashi

Volumetric Analysis - Acid/Base Titration Using Indicators

Excel Template

K 125 126 127 128 129 130 131 132 133 134 135 136 137 138 139 140 141 142 143 144 145 146 147 148 149 150 151 essary documents (See 152 adjust the printing-range before 153 154 155 156 157 158 159 160

Chem1310 Laboratory

Copyright (c) 2003 Tatsuya Maehigashi