De Cuong On Tap Mon Hoa Hoc HKI 1

TRNG THPT CHU THNH
T HA HC
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HC K I
Nm hc 2012-2013
MC LC
Chng trang
-Cng thc tnh ..................................................................................................2 -Chng 1: ESTER ............................................................................................4 - Chng 2: CACBOHIDRAT..........................................................................8 -Chng 3: AMIN-AMINO ACID..................................................................12 -Chng 4: POLIME........................................................................................19 -Chng 5: I CNG V KIM LOI.....................................................23 - Gii thiu kim tra, thi hc k v ma trn .........................................33
cng n tp mn Ha hc lp 12 - Nm hc 2012-2013
Cng thc tnh nhanh
Mt s cng thc thng p dng
+ Tnh s mol (n) =
+ S tnh mol ( n) cht kh ktc :=
+ Tnh nng mol/l ( CM) =
+Tnh nng (%) (C%) = + Tnh khi lng dung dch (mdung dch) = D.Vdung dch (l) + Tnh s mol (n) = Lu : Ch cn thuc nhng cng thc c bn ta suy ra cc i lng cn thit * Mt s khi lng mol phn t thng gp: ( khng yu cu cc em thuc nhng y l nhng cht thng gp ph bin em no nh th c li th tnh rt nhanh nht l bi ton trc nghim ) H2SO4=98, HNO3= 63, HCl =36.5, NaOH=40, KOH= 56, CaCO3 = 100, Al(OH)3 =78, BaSO4= 233, AgCl=143.5, Fe2O3= 160, Fe3O4= 232 Glucosse C6H12O6=180, saccacrosse C12H22O11=342, TB (C6H10O5)n = 162n, anilin C6H5NH2= 93, glixerol C3H5(OH)3=92, ancol etylicC2H5OH=46, axit axetic CH3COOH=60, Xenlulosetrinitrat= 297 , benzenC6H6= 78, C6H2NH2Br3= 330 Mt s gc hirocacbon thng gp H=1, CH3- ( M=15), -CH2- (M= 14), C2H5-(M=29), -C2H4- (M= 28), CH2=CH- ( M= 27), C6H5- (M= 77)
Chng 1- ESTER- CHT BO
CHNG 1: ESTE - CHT BO
Bi 1. ESTE . I. Khi nim : Khi thay nhm OH nhm cacboxyl ca axit cacboxylic bng nhm OR th c este Este n chc RCOOR, Trong R l gc hidrocacbon hay H; R l gc hidrocacbon , khc H Este no n chc CnH2nO2 ( vi n 2) Tn ca este : Tn gc R(yl)+ tn gc axit RCOO (ui at) Vd : CH3COOC2H5 : Etylaxetat CH2=CH- COOCH3 metyl acrylat Cng thc HCOOCH3 HCOOC2H5 CH3COOCH3 CH3COOC2H5 C2H5COOCH3 Tn gi Metyl fomat Etyl fomat Metyl axetat Etyl axetat Metyl propionat Cng thc CH3COOCH=CH2 CH2=CHCOOCH3 CH2=C(CH3)-COOCH3 Tn gi Vinyl axetat Metyl acrylat Metyl metacrylat
Ch : C2H4O2 c 2 ng phn n chc (1 este, 1 axit), C3H6O2 c 3 ng phn n chc (2 este, 1 axit) C4H8O2 c 6 ng phn n chc (4 este, 2 axit) ESTE no,n chc:CTC CnH2nO2 S ng phn =2n-2 ( n<5 ) II.L tnh - Tnh cht vt l: trng thi, t khi, tnh tan, nhit si, mi c trng. -Mt s mi c trng : Isoamyl axetat : mi chui chn ; Etyl butiat ,etyl propionat c mi da Nhit si ca este(RCOOR< nhit si ca ancol (ROH) < nhit si ca axit cacboxylic (RCOOH) III. Ha tnh : a.Thy phn trong mi trng axit :to ra 2 lp cht lng, l phn ng thun nghch (2 chiu ) H 2 SO4 d RCOOH + R,OH RCOOR, + H2O
to
b.Thy phn trong mi trng baz ( P/ x phng ha ) : l ph/ng 1 chiu RCOOR, + NaOH t RCOONa + R,OH H 2 SO ,0 4 t este + H2O IV.IU CH : axit + ancol
0
H 2 SO , 4 t RCOOR + H2O . RCOOH + ROH Bi 2. Lipit. I. Khi nim:Lipit l nhng hp cht hu c c trong t bo sng,khng ha tan trong nc nhng tan nhiu trong dung mi hu c khng phn cc. II. Cht bo: 1/ Khi nim: Cht bo l trieste ca glixerol vi axit bo gi chung l triglixerit hay triaxylglixerol. Cng thc:R1COO-CH2 R1,R2,R3: l gc hidrocacbon R2COO-CH 3 R COO-CH2 Vd:[CH3(CH2)16COO]3C3H5 hay (C17H35COO)3C3H5 : tristearoylglixerol (tristearin) (C17H33COO)3C3H5 : trioleoylglixerol (triolein); (C15H31COO)3C3H5 : tripanmitglixerol (tripanmitin) Ch : T 2 axit bo khc nhau v glixerol c th to ra 6 trieste S ng phn trieste to bi glixerol v hn hp n axt bo =n2(n +1)/2
---------------------------------------------------------------------------------------------------------------------------T Ha hc Trng THPT Chu Thnh - Gio vin son Hunh Tn Ng Trang 4
2/ Tnh cht vt l: - nhit thng,cht bo trng thi lng( du) khi trong phn t c gc hidrocacbon khng no. trng thi rn(m) khi trong phn t c gc hidrocacbon no. 3/ Tnh cht ha hc: a.Phn ng thy phn: H 3CH (CH ) COOH+C H (OH) [CH3(CH2)16COO]3C3H5+3H2O 3 2 16 3 5 3 t b. Phn ng x phng ha: t0 [CH3(CH2)16COO]3C3H5 + 3NaOH 3[CH3(CH2)16COONa] +C3H5(OH)3 tristearin Natristearat x phng c. Phn ng cng hidro ca cht bo lng thnh cht bo rn (b nhn to) Ni (C17H33COO)3C3H5+3H2 1751950 C (C17H35COO)3C3H5 lng rn
+ o
B. BI TP N TP * Dng bi tp v ng phn Cu 1: S ng phn este ng vi cng thc phn t C3H6O2 l A. 5. B. 4. C. 2. D. 3. Cu 2: S ng phn este ng vi cng thc phn t C4H8O2 l A. 2. B. 3. C. 4. D. 5. Cu 3: S ng phn n chc ng vi cng thc phn t C3H6O2 l A. 2. B. 3. C. 4. D. 5. Cu 4: S ng phn n chc ng vi cng thc phn t C4H8O2 l A. 6. B. 3. C. 4. D. 5. Cu 5: Cho tt c cc ng phn n chc, mch h, c cng cng thc phn t C2H4O2 ln lt tc dng vi: Na, NaOH, NaHCO3. S phn ng xy ra l A. 2. B. 5. C. 4. D. 3. Cu 6: Cht X c cng thc phn t C3H6O2, l este ca axit axetic. Cng thc cu to thu gn ca X l A. C2H5COOH. B. HO-C2H4-CHO. C. CH3COOCH3. D. HCOOC2H5. Cu 7: Hp cht X c cng thc cu to: CH3CH2COOCH3. Tn gi ca X l: A. etyl axetat. B. metyl propionat. C. metyl axetat. D. propyl axetat. Cu 8: Thy phn este E c cng thc phn t C4H8O2 (c mt H2SO4 long) thu c 2 sn phm hu c X v Y. T X c th iu ch trc tip ra Y bng mt phn ng duy nht. Tn gi ca E l: A. metyl propionat. B. propyl fomat. C. ancol etylic. D. etyl axetat. Cu 9 Cht X c cng thc phn t C2H4O2, cho cht X tc dng vi dung dch NaOH to ra mui v nc. Cht X thuc loi A. ancol no a chc. B. axit khng no n chc. C. este no n chc. D. axit no n chc. Cu 10: C th gi tn este (C17H33COO)3C3H5 l A. triolein B. tristearin C. tripanmitin D. stearic *Dng bi tp v xc nh cng thc cu to Cu 1: Este etyl axetat c cng thc l A. CH3CH2OH. B. CH3COOH. C. CH3COOC2H5. D. CH3CHO. Cu 2: un nng este HCOOCH3 vi mt lng va dung dch NaOH, sn phm thu c l A. CH3COONa v C2H5OH. B. HCOONa v CH3OH. C. HCOONa v C2H5OH. D. CH3COONa v CH3OH. Cu 3: Este etyl fomiat c cng thc l A. CH3COOCH3. B. HCOOC2H5. C. HCOOCH=CH2. D. HCOOCH3. Cu 4: un nng este CH3COOC2H5 vi mt lng va dung dch NaOH, sn phm thu c l A. CH3COONa v CH3OH. B. CH3COONa v C2H5OH. C. HCOONa v C2H5OH. D. C2H5COONa v CH3OH. ---------------------------------------------------------------------------------------------------------------------------T Ha hc Trng THPT Chu Thnh - Gio vin son Hunh Tn Ng Trang 5
Cu 5: Thy phn este X trong mi trng kim, thu c natri axetat v ancol etylic. Cng thc ca X l A. C2H3COOC2H5. B. CH3COOCH3. C. C2H5COOCH3. D. CH3COOC2H5. Cu 6: Este metyl acrilat c cng thc l A. CH3COOCH3. B. CH3COOCH=CH2. C. CH2=CHCOOCH3. D. HCOOCH3. Cu 7: Este vinyl axetat c cng thc l A. CH3COOCH3. B. CH3COOCH=CH2. C. CH2=CHCOOCH3. D. HCOOCH3. Cu 8: un nng este CH3COOCH=CH2 vi mt lng va dung dch NaOH, sn phm thu c l A. CH2=CHCOONa v CH3OH. B. CH3COONa v CH3CHO. C. CH3COONa v CH2=CHOH. D. C2H5COONa v CH3OH. Cu 9: un nng este CH2=CHCOOCH3 vi mt lng va dung dch NaOH, sn phm thu c l A. CH2=CHCOONa v CH3OH. B. CH3COONa v CH3CHO. C. CH3COONa v CH2=CHOH. D. C2H5COONa v CH3OH. Cu 10: Cho dy cc cht: HCHO, CH3COOH, CH3COOC2H5, HCOOH, C2H5OH, HCOOCH3. S cht trong dy tham gia phn ng trng gng l A. 3. B. 6. C. 4. D. 5. Cu 11: Hai cht hu c X1 v X2 u c khi lng phn t bng 60 vC. X1 c kh nng phn ng vi: Na, NaOH, Na2CO3. X2 phn ng vi NaOH (un nng) nhng khng phn ng Na. Cng thc cu to ca X1, X2 ln lt l: A. CH3-COOH, CH3-COO-CH3. B. (CH3)2CH-OH, H-COO-CH3. C. H-COO-CH3, CH3-COOH. D. CH3-COOH, H-COO-CH3. Cu 12: Cho s chuyn ha sau (mi mi tn l mt phng trnh phn ng): Tinh bt X Y Z metyl axetat. Cc cht Y, Z trong s trn ln lt l: A. C2H5OH, CH3COOH. B. CH3COOH, CH3OH. C. CH3COOH, C2H5OH. D. C2H4, CH3COOH. Cu 13: Mt este c cng thc phn t l C4H6O2, khi thu phn trong mi trng axit thu c axetanehit. Cng thc cu to thu gn ca este l A. HCOO-C(CH3)=CH2. B. HCOO-CH=CH-CH3. C. CH3COO-CH=CH2. D. CH2=CH-COO-CH3. Cu 14: Cho glixerol phn ng vi hn hp axit bo gm C17H35COOH v C15H31COOH, s loi trieste c to ra ti a l A. 6. B. 3. C. 5. D. 4. Cu 15: Cho cc cht: etyl axetat, anilin, ancol etylic, axit acrylic, phenol, phenylamoni clorua, ancol benzylic, p-crezol. Trong cc cht ny, s cht tc dng c vi dung dch NaOH l A. 4. B. 6. C. 5. D. 3. Cu 16: Propyl fomat c iu ch t A. axit fomic v ancol metylic. B. axit fomic v ancol propylic. C. axit axetic v ancol propylic. D. axit propionic v ancol metylic. Cu 17: Khi x phng ha tristearin ta thu c sn phm l A. C15H31COONa v etanol. B. C17H35COOH v glixerol. C. C15H31COOH v glixerol. D. C17H35COONa v glixerol. Cu 18: Khi x phng ha tripanmitin ta thu c sn phm l A. C15H31COONa v etanol. B. C17H35COOH v glixerol. C. C15H31COONa v glixerol. D. C17H35COONa v glixerol. Cu 19: Khi x phng ha triolein ta thu c sn phm l A. C15H31COONa v etanol. B. C17H35COOH v glixerol. C. C15H31COONa v glixerol. D. C17H33COONa v glixerol. Cu 20: Khi thu phn trong mi trng axit tristearin ta thu c sn phm l A. C15H31COONa v etanol. B. C17H35COOH v glixerol. C. C15H31COOH v glixerol. D. C17H35COONa v glixerol. * Dng bi ton vn dng Cu 1: un 12 gam axit axetic vi 13,8 gam etanol (c H 2SO4 c lm xc tc) n khi phn ng t ti trng thi cn bng, thu c 11 gam este. Hiu sut ca phn ng este ha l (Cho H = 1; C = 12; O = 16). A. 50% B. 62,5% C. 55% D. 75% ---------------------------------------------------------------------------------------------------------------------------T Ha hc Trng THPT Chu Thnh - Gio vin son Hunh Tn Ng Trang 6
Cu 2: Cho 6 gam mt este ca axit cacboxylic no n chc v ancol no n chc phn ng va ht vi 100 ml dung dch NaOH 1M. Tn gi ca este l A. etyl axetat. B. propyl fomiat. C. metyl axetat. D. metyl fomiat. Cu 3: trung ha lng axit t do c trong 14 gam mt mu cht bo cn 15ml dung dch KOH 0,1M. Ch s axit ca mu cht bo trn l (Cho H = 1; O = 16; K = 39) ( gim ti) A. 4,8 B. 6,0 C. 5,5 D. 7,2 Cu 4: X phng ho hon ton 22,2 gam hn hp gm hai este HCOOC2H5 v CH3COOCH3 bng dung dch NaOH 1M (un nng). Th tch dung dch NaOH ti thiu cn dng l A. 400 ml. B. 300 ml. C. 150 ml. D. 200 ml. Cu 5: X phng ho hon ton 17,24 gam cht bo cn va 0,06 mol NaOH. C cn dung dch sau phn ng thu c khi lng x phng l A. 16,68 gam. B. 18,38 gam. C. 18,24 gam. D. 17,80 gam. Cu 6: X phng ha 8,8 gam etyl axetat bng 200 ml dung dch NaOH 0,2M. Sau khi phn ng xy ra hon ton, c cn dung dch thu c cht rn khan c khi lng l (cho H = 1, C = 12, O = 16, Na = 23) A. 3,28 gam. B. 8,56 gam. C. 8,2 gam. D. 10,4 gam. Cu 7: Khi t chy hon ton mt este no, n chc th s mol CO2 sinh ra bng s mol O2 phn ng. Tn gi ca este l A. n-propyl axetat. B. metyl axetat. C. etyl axetat. D. metyl fomiat. Cu 8: t chy hon ton 7,8 gam este X thu c 11,44 gam CO2 v 4,68 gam H2O. Cng thc phn t ca este l A. C4H8O4 B. C4H8O2 C. C2H4O2 D. C3H6O2 Cu 9: Thu phn hon ton 11,44 gam este no, n chc, mch h X vi 100ml dung dch NaOH 1,3M (va ) thu c 5,98 gam mt ancol Y. Tn gi ca X l A. Etyl fomat B. Etyl axetat C. Etyl propionat D. Propyl axetat Cu 10: Thu phn este X c CTPT C4H8O2 trong dung dch NaOH thu c hn hp hai cht hu c Y v Z trong Y c t khi hi so vi H2 l 16. X c cng thc l A. HCOOC3H7 B. CH3COOC2H5 C. HCOOC3H5 D. C2H5COOCH3 Cu 11: un nng cht bo cn va 40 kg dung dch NaOH 15%, gi s phn ng xy ra hon ton. Khi lng (kg) glixerol thu c l A. 13,8 B. 4,6 C. 6,975 D. 9,2 Cu 12: X phng ho hon ton 37,0 gam hn hp 2 este l HCOOC 2H5 v CH3COOCH3 bng dung dch NaOH, un nng. Khi lng NaOH cn dng l A. 8,0g B. 20,0g C. 16,0g D. 12,0g Cu 13: Hp cht Y c cng thc phn t C 4H8O2. Khi cho Y tc dng vi dung dch NaOH sinh ra cht Z c cng thc C3H5O2Na. Cng thc cu to ca Y l A. C2H5COOC2H5. B. CH3COOC2H5. C. C2H5COOCH3. D. HCOOC3H7. Cu 14: X phng ho hon ton 17,6 gam hn hp 2 este l etyl axetat v metyl propionat bng lng va v (ml) dung dch NaOH 0,5M. Gi tr v dng l A. 200 ml. B. 500 ml. C. 400 ml. D. 600 ml. Cu 15: Trong phn t este (X) no, n chc, mch h c thnh phn oxi chim 36,36 % khi lng. S ng phn cu to ca X l A. 4. B. 2. C. 3.
Chng 2- CACBOHIDRAT
CHNG 2: CACBOHIDRAT
A. T THUYT CN NH CACBOHYDRAT ( GLUXIT) *nh ngha : Cacbohidrat l nhng hp cht hu c tp chc v thng c CTC : C n(H2O)m * Phn loi: Cacbohidrat chia lm 3 nhm ch yu : + Monosaccarit l nhm khng b thy phn . vd: glucoz , fuctoz ( C6H12O6) + isaccarit l nhm m khi thy phn mi phn t sinh ra 2 phn t monosaccarit .vd : saccaroz , mantoz ( C12H22O11) +Polisaccarit l nhm m khi thy phn n cng mi phn t sinh ra nhiu phn t monosaccarit . vd : tinh bt , xenluloz . ( C6H10O5)n BI 5. GLUCOZ I.L tnh v trng thi t nhin - Cht rn, khng mu, tam trong nc, v ngt ( khong 0.8 ln ng ma) - C nhiu trong qu chn ( nhiu nht qu nho). Trong mu ngi c nng glucoz khng i khong 0,1% . II.Cu to .Glucoz c CTPT : C6H12O6 Glucoz c CTCT : CH2OH-CHOH-CHOH-CHOH-CHOH-CHO hoc CH2OH[CHOH]4CHO . Glucoz l hp cht tp chc Trong thc t Glucoz tn ti ch yu dng mch vng: dng -glucoz v - glucoz III. Ha tnh . Glucoz c tnh cht andehit v ancol a chc ( poliancol ) . 1/ Tnh cht ca ancol a chc: a/ Tc dng vi Cu(OH)2: nhit thng to phc ng glucoz (dd mu xanh lam- nhn bit glucoz) b/ Phn ng to este: to este cha 5 gc axit 2/ Tnh cht ca andehit: a/ Oxi ha glucoz: ( tnh kh ca glucose) + bng dd AgNO3 trong NH3: amoni gluconat v Ag (nhn bit glucoz) + bng Cu(OH)2 mi trng kim: natri gluconat v Cu2O gch (nhn bit glucoz) b/ Kh glucoz bng H2 sobitol ( tnh oxi ha ca glucose) 3/ Phn ng ln men: ancol etylic + CO2 ( y l phn ng ring ca glucose) IV. 1/ iu ch: trong cng nghip + Thy phn tinh bt + Thy phn xenluloz, xt HCl 2/ ng dng: lm thuc tng lc, trng gng, rut phch, V/ Fructoz: ng phn ca glucoz + CTCT mch h: CH2OH-CHOH-CHOH-CHOH-CO-CH2OH + Tnh cht ancol a chc (p/ Cu(OH)2 nhit thng to dd xanh lam) Fructoz
OH
glucoz
+ Trong mi trng baz fructoz chuyn thnh glucoz fructoz b oxi ha bi AgNO3/NH3 v Cu(OH)2 trong mi trng kim. BI 6.SACCAROZ ,TINH BT ,XENLULOZ I. SACCAROZ (ng knh, ng ma) CTPT: C12H22O11 -Saccaroz l mt isaccarit c cu to t mt gc glucoz v mt gc fructoz lin kt vi nhau qua nguyn t oxi. -Khng c nhm chc CHO nn khng c phn ng trng bc v khng lm mt mu nc brom. 3. Tnh cht ha hc. C tnh cht ca ancol a chc v c phn ng thy phn. a) Phn ng vi Cu(OH)2 2C12H22O11+Cu(OH)2(C12H21O11)2Cu+2H2O mu xanh lam H + , t0 b) Phn ng thy phn.C12H22O11+H2O C6H12O6 + C6H12O6 b) ng dng: dng trng gng, trng phch. II.TINH BT 1. Tnh cht vt l:L cht rn, dng bt v nh hnh, mu trng, khng tan trong nc lnh 2. Cu trc phn t: Tinh bt thuc loi polisaccarit, Phn t tinh bt gm nhiu mt xch -glucoz lin kt vi nhau CTPT : (C6H10O5)n . Cc mt xch -glucoz lin kt vi nhau to hai dng: -Dnh l xo khng phn nhnh (amiloz). -Dng l xo phn nhnh (amilopectin). Tinh bt ( trong cc ht ng cc , cc loi c )
Chng 2- CACBOHIDRAT
3. Tnh cht ha hc. a) Phn ng thy phn: tinh bt b thy phn thnh glucoz. H + ,t o (C6H10O5)n + nH2O n C6H12O6 dng nhn bit iot hoc tinh bt. b) Phn ng mu vi iot:To thnh hp cht c mu xanh tm III. XENLULOZ 1. Tnh cht vt l, trng thi t nhin. -Xenluloz l cht rn dng si, mu trng, khng tan trong nc v dung mi hu c, nhng tan trong nc Svayde (dd thu dc khi ha tan Cu(OH)2 trong amoniac) . -Bng c gn 98% xenluloz 2. Cu trc phn t: - Xenluloz l mt polisaccarit, phn t gm nhiu gc -glucoz lin kt vi nhau -CT : (C6H10O5)n hay [C6H7O2(OH)3]n C cu to mch thng. 3. Tnh cht ha hc: H + ,t o a) Phn ng thy phn: (C6H10O5)n + nH2O nC6H12O6 b) Phn ng vi axit nitric H 2SO 4 d,t 0 [C6H7O2(OH)3]n + 3nHNO3(c) [C6H7O2(ONO2)3]n + 3nH2O Xenluloz trinitrat rt d chy v n mnh khng sinh ra khi nn c dng lm thuc sng khng khi.
B. BI TP N TP *Dng cu hi l thuyt: Cu 1: Trong phn t ca cacbohyrat lun c A. nhm chc axit. B. nhm chc xeton. C. nhm chc ancol. D. nhm chc anehit. Cu 2: Cht thuc loi isaccarit l A. glucoz. B. saccaroz. C. xenluloz. D. fructoz. Cu 3: Hai cht ng phn ca nhau l A. glucoz v mantoz. B. fructoz v glucoz. C. fructoz v mantoz. D. saccaroz v glucoz. Cu 4: Trong iu kin thch hp glucoz ln men to thnh kh CO2 v A. C2H5OH. B. CH3COOH. C. HCOOH. D. CH3CHO. Cu 5: Saccaroz v glucoz u c A. phn ng vi AgNO3 trong dung dch NH3, un nng. B. phn ng vi dung dch NaCl. C. phn ng vi Cu(OH)2 nhit thng to thnh dung dch xanh lam. D. phn ng thu phn trong mi trng axit. Cu 6: Cho s chuyn ho: Glucoz X Y CH3COOH. Hai cht X, Y ln lt l A. CH3CHO v CH3CH2OH. B. CH3CH2OH v CH3CHO. C. CH3CH(OH)COOH v CH3CHO. D. CH3CH2OH v CH2=CH2. Cu 7: Cht tham gia phn ng trng gng l A. xenluloz. B. tinh bt. C. fructoz. D. saccaroz. Cu 8: Cht khng phn ng vi AgNO3 trong dung dch NH3, un nng to thnh Ag l A. C6H12O6 (glucoz). B. CH3COOH. C. HCHO. D. HCOOH. Cu 9: Dy gm cc dung dch u tc dng vi Cu(OH)2 l A. glucoz, glixerol, ancol etylic. B. glucoz, andehit fomic, natri axetat. C. glucoz, glixerol, axit axetic. D. glucoz, glixerol, natri axetat. Cu 10: chng minh trong phn t ca glucoz c nhiu nhm hiroxyl, ngi ta cho dung dch glucoz phn ng vi A. Cu(OH)2 trong NaOH, un nng. B. AgNO3 trong dung dch NH3, un nng. C. Cu(OH)2 nhit thng. D. kim loi Na. Cu 11: un nng xenluloz trong dung dch axit v c, thu c sn phm l A. saccaroz. B. glucoz. C. fructoz. D. mantoz. Cu 12: Cho s chuyn ha sau: Tinh bt X Y axit axetic. X v Y ln lt l A. ancol etylic, anehit axetic. B. glucoz, ancol etylic. C. glucoz, etyl axetat. D. glucoz, anehit axetic. Cu 13: Tinh bt, xenluloz, saccaroz, mantoz u c kh nng tham gia phn ng A. ho tan Cu(OH)2. B. trng ngng. C. trng gng. D. thy phn. Cu 14: Mt cht khi thy phn trong mi trng axit, un nng khng to ra glucoz. Cht l ---------------------------------------------------------------------------------------------------------------------------T Ha hc Trng THPT Chu Thnh - Gio vin son Hunh Tn Ng Trang 9
Chng 2- CACBOHIDRAT
A. protit. B. saccaroz. C. tinh bt. D. xenluloz. Cu 15: Cho dy cc cht: glucoz, xenluloz, saccaroz, tinh bt, fructoz. S cht trong dy tham gia phn ng trng gng l A. 3. B. 4. C. 2. D. 5. Cu 16: Trong cc cht sau: axit axetic, glixerol, glucoz, ancol etylic, xenluloz. S cht ha tan c Cu(OH)2 nhit thng l A. 3 B. 5 C. 1 D. 4 Cu 17: Cho cc dung dch sau: saccaroz, glucoz, anehit axetic, glixerol, ancol etylic, axetilen, fructoz. S lng dung dch c th tham gia phn ng trng gng l A. 3. B. 4. C. 5. D. 2. Cu 18: Khi thy phn saccaroz th thu c A. ancol etylic. B. glucoz v fructoz. C. glucoz. D. fructoz. Cu 19: Cng thc no sau y l ca xenluloz? A. [C6H7O2(OH)3]n. B. [C6H8O2(OH)3]n. C. [C6H7O3(OH)3]n. D. [C6H5O2(OH)3]n. Cu 20: Dy cc cht no sau y u c phn ng thu phn trong mi trng axit? A. Tinh bt, xenluloz, glucoz. B. Tinh bt, xenluloz, fructoz. C. Tinh bt, xenluloz, saccaroz. D. Tinh bt, saccaroz, fructoz * Dng bi ton vn dng: Cu 1: un nng dung dch cha 27 gam glucoz vi AgNO3 trong dung dch NH3 (d) th khi lng Ag ti a thu c l A. 16,2 gam. B. 10,8 gam. C. 21,6 gam. D. 32,4 gam. Cu 2: Khi ln men 360 gam glucoz vi hiu sut 100%, khi lng ancol etylic thu c l A. 184 gam. B. 276 gam. C. 92 gam. D. 138 gam. Cu 3: Cho m gam glucoz ln men thnh ru etylic vi hiu sut 80%. Hp th hon ton kh CO2 sinh ra vo nc vi trong d thu c 20 gam kt ta. Gi tr ca m l A. 14,4 B. 45. C. 11,25 D. 22,5 Cu 4: Cho 50ml dung dch glucoz cha r nng tc dng vi mt lng d AgNO 3 trong dung dch NH3 thu c 2,16 gam bc kt ta. Nng mol (hoc mol/l) ca dung dch glucoz dng l (Cho Ag = 108) A. 0,20M B. 0,01M C. 0,02M D. 0,10M Cu 5: Lng glucoz cn dng to ra 1,82 gam sobitol vi hiu sut 80% l A. 2,25 gam. B. 1,80 gam. C. 1,82 gam. D. 1,44 gam. Cu 6: Thy phn 324 gam tinh bt vi hiu sut ca phn ng l 75%, khi lng glucoz thu c l A. 250 gam. B. 300 gam. C. 360 gam. D. 270 gam. Cu 7: T 16,20 tn xenluloz ngi ta sn xut c m tn xenluloz trinitrat (bit hiu sut phn ng tnh theo xenluloz l 90%). Gi tr ca m l A. 26,73. B. 33,00. C. 25,46. D. 29,70. Cu 8: Cho cc cht: ancol etylic, glixerol, glucoz, imetyl ete v axit fomic. S cht tc dng c vi Cu(OH)2 l A. 3. B. 1. C. 4. D. 2. Cu 9: Mun c 2610 gam glucoz th khi lng saccaroz cn em thu phn hon ton l A. 4595 gam. B. 4468 gam. C. 4959 gam. D. 4995 gam. Cu 10: un nng 37,5 gam dung dch glucoz vi lng AgNO3/dung dch NH3 d, thu c 6,48 gam bc. Nng % ca dung dch glucoz l A. 11,4 % B. 14,4 % C. 13,4 % D. 12,4 % Cu 11: Phn t khi trung bnh ca xenluloz l 1620 000. Gi tr n trong cng thc (C6H10O5)n l A. 10000 B. 8000 C. 9000 D. 7000 Cu 12: Trng bc hon ton m gam glucoz thu c 86,4 gam Ag. Nu ln men hon ton m gam glucoz ri cho kh CO2 thu c hp th vo nc vi trong d th lng kt ta thu c l A. 60g. B. 20g. C. 40g. D. 80g. Cu 13: Ln men 41,4 gam glucoz vi hiu sut 80%, lng kh thu c cho hp th hon ton vo dung dch nc vi trong d th lng kt ta thu c l A. 18,4 B. 28,75g C. 36,8g D. 23g. Cu 14: Cho m gam glucoz ln men thnh ancol etylic. Kh sinh ra cho vo nuc vi trong d thu c 120 gam kt ta, bit hiu sut qu trnh ln men t 60%. Gi tr m l ---------------------------------------------------------------------------------------------------------------------------T Ha hc Trng THPT Chu Thnh - Gio vin son Hunh Tn Ng Trang 10
Chng 2- CACBOHIDRAT
A. 225 gam. B. 112,5 gam. C. 120 gam. D. 180 gam. *Dng ton vn dng cao: Cu 16: Ln men m gam glucoz vi hiu sut 90%, lng kh CO2 sinh ra hp th ht vo dung dch nc vi trong, thu c 10 gam kt ta. Khi lng dung dch sau phn ng gim 3,4 gam so vi khi lng dung dch nc vi trong ban u. Gi tr ca m l A. 20,0. B. 30,0. C. 13,5. D. 15,0. Cu 17: Khi lng ca tinh bt cn dng trong qu trnh ln men to thnh 5 lt ru (ancol) etylic 46 l (bit hiu sut ca c qu trnh l 72% v khi lng ring ca ru etylic nguyn cht l 0,8 g/ml) A. 5,4 kg. B. 5,0 kg. C. 6,0 kg. D. 4,5 kg. Cu 18. Xenluloz trinitrat c iu ch t xenluloz v axit nitric c c xc tc axit sunfuric c, nng. c
29,7 kg xenluloz trinitrat, cn dng dung dch cha m kg axit nitric (hiu sut phn ng t 90%). Gi tr ca m l (cho H = 1, C =12, N = 14, O = 16) A. 42 kg. B. 10 kg. C. 30 kg. D. 21 kg.
Cu 19. Khi lng ca tinh bt cn dng trong qu trnh ln men to thnh 5 lt ru (ancol) etylic 46 l (bit hiu sut ca c qu trnh l 72% v khi lng ring ca ru etylic nguyn cht l 0,8 g/ml) A. 5,4 kg. B. 5,0 kg. C. 6,0 kg. D. 4,5 kg. Cu 20. Nh my ru bia H Ni sn xut ancol etylic t mn ca g cha 50% xenluloz. Mun iu ch 920 kg ancol etylic ( hiu sut c qu trnh l 75 %) th khi lng ( kg) mn ca g cn dng l: A. 3640. B. 1620. C. 4320. D. 2160.
cng n tp mn Ha hc lp 12 - Nm hc 2012-2013 PEPTIT_PROTEIN
Chng 3-AMIN-AMINOAXIT-
CHNG 3: AMIN - AMINOAXIT - PEPTIT PROTEIN AMIN - ANILIN

A. Kin thc cn nh
AMIN. 1. Khi nim: Amin l nhng hp cht hu c c c khi thay th mt hoc nhiu nguyn t hidro trong phn t NH3 bng mt hoc nhiu gc hidrocacbon. Th d: CH3NH2 (1) ; C2H5NH2 (2) CH3 NH CH3 (3) CH3 N CH3 (4) ; CH2=CH-CH2-NH2 (5) CH3 C6H5NH2 (6) 2. Phn loi Amin c phn loi theo 2 cch thng dng: a ) Theo c im cu to ca gc hidrocacbon. - Amin thm: Nhm NH2 gn vo nhn benzen. VD: C6H5NH2;... - amin bo: Nhm NH2 gn vo C mang lin kt n. VD: CH3NH2; C2H5NH2; C3H7NH2;.... b ) Theo bc ca amin - amin bc 1: CH3NH2 ; C2H5NH2 ( R-NH2) - amin bc 2: CH3 NH CH3 ( R-NH-R) - amin bc 3: CH3 N CH3 CH3 3. Danh php - Cch gi tn theo danh php gc-chc: Tn gc hidrocacbon + amin. VD: CH3NH2 metylamin; C2H5NH2 etylamin - Tn thng thng: Ch p dng cho mt s amin nh: C6H5NH2 Anilin 4. ng phn: Amin c cc loi ng phn: - ng phn v mch cacbon.- ng phn v v tr nhm chc. - ng phn v bc ca amin. VD: - Amin C2H7N c 2 ng phn, trong c 1 ng phn bc 1 v 1 ng phn bc 2 - Amin C3H9N c 4 ng phn, trong c 2 ng phn bc 1, 1 ng phn bc 2 v 1 p bc 3 - Amin C4H11N c 8 ng phn, trong c 4 ng phn bc 1, 3 ng phn bc 2 v 1 p bc 3
5. L tnh: Cc amin no u dy (metyl,etyl) l nhng cht kh c mi khai kh chu , d tan trong nc. Cc amin ng ng cao hn l nhng cht lng hoc rn, tan trong nc gim dn theo chiu tng ca khi lng phn t. 6. Ha tnh: a) Tnh baz: * Cc amin u c tnh bazo : t/d vi axit Mui * Tc dng vi qu hoc phenolphtalein Metylamin Anilin Qu tm Xanh Khng i mu Phenolphtalein Hng Khng i mu * So snh tnh baz: CH3-NH2 >NH3 > C6H5NH2 b) Phn ng th nhn thm ca anilin: Phn ng vi nc brom ( i vi anilin) Hoc gn: C6H5NH2+ 3Br2 C6H2NH2(Br3) (trng) + 3HBr 93g 330g 7. iu ch: Anilin v cc amin thm thng c iu ch bng cch kh nitro benzen (hoc dn xut nitro tng ng) bi hidro mi sinh (Fe + HCl)
C 6H 6
+HNO3 C H NO + [H] 6 5 2 C6H5NH2( anilin) ( Fe+HCl) (H2SO4 c, xt)
B. BI T TP LUYN TP ---------------------------------------------------------------------------------------------------------------------------T Ha hc Trng THPT Chu Thnh - Gio vin son Hunh Tn Ng Trang 12
*Dng cu hi l thuyt Cu 1: S ng phn amin c cng thc phn t C2H7N l A. 4. B. 3. C. 2. D. 5. Cu 2: S ng phn amin c cng thc phn t C3H9N l A. 4. B. 3. C. 2. D. 5. Cu 3: S ng phn amin c cng thc phn t C4H11N l A. 5. B. 7. C. 6. D. 8. Cu 4: S ng phn amin bc mt ng vi cng thc phn t C3H9N l A. 4. B. 3. C. 2. D. 5. Cu 5: S ng phn amin bc mt ng vi cng thc phn t C4H11N l A. 4. B. 3. C. 2. D. 5. Cu 6: C bao nhiu amin cha vng benzen c cng cng thc phn t C7H9N ? A. 3 amin. B. 5 amin. C. 6 amin. D. 7 amin. Cu 7: Anilin c cng thc l A. CH3COOH. B. C6H5OH. C. C6H5NH2. D. CH3OH. Cu 8: Trong cc cht sau, cht no l amin bc 2? A. H2N-[CH2]6NH2 B. CH3CH(CH3)NH2 C. CH3NHCH3 D. C6H5NH2 Cu 9: C bao nhiu amin bc hai c cng cng thc phn t C5H13N ? A. 4 amin. B. 5 amin. C. 6 amin. D. 7 amin. Cu 10: Trong cc tn gi di y, tn no ph hp vi cht CH3CH(CH3)NH2? A. Metyletylamin. B. Etylmetylamin. C. Isopropanamin. D. Isopropylamin. Cu 11: Trong cc tn gi di y, cht no c lc baz mnh nht ? A. NH3 B. C6H5CH2NH2 C. C6H5NH2 D. (CH3)2NH Cu 12: Trong cc tn gi di y, cht no c lc baz yu nht ? A. C6H5NH2 B. C6H5CH2NH2 C. (C6H5)2NH D. NH3 Cu 13: Trong cc tn gi di y, tn no ph hp vi cht C6H5-CH2-NH2? A. Phenylamin. B. Benzylamin. C. Anilin. D. Phenylmetylamin. Cu 14: Trong cc cht di y, cht no c tnh baz mnh nht ? A. C6H5NH2. B. (C6H5)2NH C. p-CH3-C6H4-NH2. D. C6H5-CH2-NH2 Cu 15: Cht khng c kh nng lm xanh nc qu tm l A. Anilin B. Natri hiroxit. C. Natri axetat. D. Amoniac. Cu 16: Cht khng phn ng vi dung dch NaOH l A. C6H5NH3Cl. B. C6H5CH2OH. C. p-CH3C6H4OH. D. C6H5OH. Cu 17: tch ring tng cht t hn hp benzen, anilin, phenol ta ch cn dng cc ho cht (dng c,iu kin th nghim y ) l A. dung dch NaOH, dung dch HCl, kh CO2. B. dung dch Br2, dung dch HCl, kh CO2. C. dung dch Br2, dung dch NaOH, kh CO2. D. dung dch NaOH, dung dch NaCl, kh CO2. Cu 18: Dy gm cc cht u lm giy qu tm m chuyn sang mu xanh l: A. anilin, metyl amin, amoniac. B. amoni clorua, metyl amin, natri hiroxit. C. anilin, amoniac, natri hiroxit. D. metyl amin, amoniac, natri axetat. Cu 19: Kt ta xut hin khi nh dung dch brom vo A. ancol etylic. B. benzen. C. anilin. D. axit axetic. Cu 20: Cht lm giy qu tm m chuyn thnh mu xanh l A. C2H5OH. B. CH3NH2. C. C6H5NH2. D. NaCl. Cu 21: Anilin (C6H5NH2) phn ng vi dung dch A. NaOH. B. HCl. C. Na2CO3. D. NaCl. Cu 22: C 3 cht lng benzen, anilin, stiren, ng ring bit trong 3 l mt nhn. Thuc th phn bit 3 cht lng trn l A. dung dch phenolphtalein. B. nc brom. C. dung dch NaOH. D. giy qu tm. Cu 23: Anilin (C6H5NH2) v phenol (C6H5OH) u c phn ng vi A. dung dch NaCl. B. dung dch HCl. C. nc Br2. D. dung dch NaOH. Cu 24: Dung dch metylamin trong nc lm A. qu tm khng i mu. B. qu tm ha xanh. C. phenolphtalein ho xanh. D. phenolphtalein khng i mu. Cu 25: Cht c tnh baz l ---------------------------------------------------------------------------------------------------------------------------T Ha hc Trng THPT Chu Thnh - Gio vin son Hunh Tn Ng Trang 13
A. CH3NH2. B. CH3COOH. C. CH3CHO. D. C6H5OH. Cu 26: Ba cht lng: C2H5OH, CH3COOH, CH3NH2 ng trong ba l ring bit. Thuc th dng phn bit ba cht trn l A. qu tm. B. kim loi Na. C. dung dch Br2. D. dung dch NaOH. Cu 27. Dy gm cc cht c xp theo chiu tnh baz gim dn t tri sang phi l A. CH3NH2, NH3, C6H5NH2. B. CH3NH2, C6H5NH2, NH3. C. C6H5NH2, NH3, CH3NH2. D. NH3, CH3NH2, C6H5NH2. Cu 28: Cho dy cc cht: phenol, anilin, phenylamoni clorua, natri phenolat, etanol. S cht trong dy phn ng c vi NaOH (trong dung dch) l A. 3. B. 2. C. 1. D. 4. Cu 29. Tnh baz ca cc cht tng dn theo th t:
A. NH3< C6H5NH2 < CH3NHCH3 < CH3CH2NH2. B. NH3< CH3CH2NH2< CH3NHCH3 <. C6H5NH2. C. C6H5NH2. < NH3< CH3CH2NH2 < CH3NHCH3. D. C6H5NH2. < NH3 < CH3NHCH3. < CH3CH2NH2. Cu 30. Cho cc cht: C6H5NH2, C6H5OH, CH3NH2, CH3COOH. Cht no lm i mu qu tm sang mu xanh? A. CH3NH2 B. C6H5NH2, CH3NH2 C. C6H5OH, CH3NH2 D. C6H5OH, CH3COOH
* Dng bi ton vn dng: Cu 1: Cho 9,3 gam anilin (C6H5NH2) tc dng va vi axit HCl. Khi lng mui thu c l A. 11,95 gam. B. 12,95 gam. C. 12,59 gam. D. 11,85 gam. Cu 2: Cho 5,9 gam etylamin (C3H7NH2) tc dng va vi axit HCl. Khi lng mui (C3H7NH3Cl) thu c l (Cho H = 1, C = 12, N = 14) A. 8,15 gam. B. 9,65 gam. C. 8,10 gam. D. 9,55 gam. Cu 3: Cho 4,5 gam etylamin (C2H5NH2) tc dng va vi axit HCl. Khi lng mui thu c l A. 7,65 gam. B. 8,15 gam. C. 8,10 gam. D. 0,85 gam. Cu 4: Cho anilin tc dng va vi dung dch HCl thu c 38,85 gam mui. Khi lng anilin phn ng l A. 18,6g B. 9,3g C. 37,2g D. 27,9g. Cu 5: Trung ha 11,8 gam mt amin n chc cn 200 ml dung dch HCl 1M. Cng thc phn t ca X l A. C2H5N B. CH5N C. C3H9N D. C3H7N Cu 6: Cho lng d anilin phn ng hon ton vi dung dch cha 0,05 mol H 2SO4 long. Khi lng mui thu c bng bao nhiu gam? A. 7,1g. B. 14,2g. C. 19,1g. D. 28,4g. Cu 7: trung ha 20 gam dung dch ca mt amin n chc X nng 22,5% cn dng 100ml dung dch HCl 1M. Cng thc phn t ca X l (Cho H = 1; C = 12; N = 14) A. C2H7N B. CH5N C. C3H5N D. C3H7N Cu 8: Cho 10 gam amin n chc X phn ng hon ton vi HCl (d), thu c 15 gam mui. S ng phn cu to ca X l A. 8. B. 7. C. 5. D. 4. Cu 9: t chy hon ton 0,2 mol metylamin (CH3NH2), sinh ra V lt kh N2 ( ktc). Gi tr ca V l A. 4,48. B. 1,12. C. 2,24. D. 3,36. Cu 10: t chy hon ton m gam metylamin (CH3NH2), sinh ra 2,24 lt kh N2 ( ktc). Gi tr ca m l A. 3,1 gam. B. 6,2 gam. C. 5,4 gam. D. 2,6 gam. Cu 11: Th tch nc brom 3% (d = 1,3g/ml) cn dng iu ch 4,4 gam kt ta 2,4,6 tribrom anilin l A. 164,1ml. B. 49,23ml. C 146,1ml. D. 16,41ml. Cu 12: t chy hon ton amin no n chc X, thu c 16,8 lt CO2 ; 2,8 lt N2 (ktc) v 20,25 g H2O. Cng thc phn t ca X l A. C4H9N. B. C3H7N. C. C2H7N. D. C3H9N. Cu 13: Mt amin n chc c cha 31,111%N v khi lng. Cng thc phn t v s ng phn ca amin tng ng l ---------------------------------------------------------------------------------------------------------------------------T Ha hc Trng THPT Chu Thnh - Gio vin son Hunh Tn Ng Trang 14
A. CH5N; 1 ng phn. B. C2H7N; 2 ng phn. C. C3H9N; 4 ng phn. D. C4H11N; 8 ng phn. Cu 14: Cho 11,25 gam C2H5NH2 tc dng vi 200 ml dung dch HCl x(M). Sau khi phn ng xong thu c dung dch c cha 22,2 gam cht tan. Gi tr ca x l A. 1,3M B. 1,25M C. 1,36M D. 1,5M Cu 15: t chy hon ton mt amin no, n chc, mch h thu c t l khi lng ca CO 2 so vi nc l 44 : 27. Cng thc phn t ca amin l A. C3H7N B. C3H9N C. C4H9N D. C4H11N Cu 16: Cho m gam Anilin tc dng ht vi dung dch Br 2 thu c 9,9 gam kt ta. Gi tr m dng l A. 0,93 gam B. 2,79 gam C. 1,86 gam D. 3,72 gam Cu 17: Cho 500 gam benzen phn ng vi HNO3 (c) c mt H2SO4 c, sn phm thu c em kh thnh anilin. Nu hiu sut chung ca qu trnh l 78% th khi lng anilin thu c l A. 456 gam. B. 564 gam. C. 465 gam. D. 546 gam. Cu 18. Cho hn hp gm cc amin n chc tc dng va vi dung dch HCl 1M ri c cn dung dch th thu
c 31,86 gam hn hp mui. Th tch dung dch HCl dng l A. 100 ml B. 50 ml C. 200ml D. 320 ml
AMINOAXIT PEPTIT PROTEIN

AMINO AXIT 1. nh ngha: Aminoaxit l loi HCHC tp chc m phn t cha ng thi nhm amino (NH2) v nhm cacboxyl (COOH). CTQ : (NH2)xR (COOH)y VD: H2N CH2 COOH Axit aminoaxetic (cn gi l glixin) CH3 CH[NH2] COOH Axit -aminopropionic (cn gi l Alanin) 2. Cu to phn t: Nhm COOH v nhm NH2 trong amino axit tng tc vi nhau to ra ion lng cc, ion ny nm cn bng vi dng phn t. 3. L tnh: Cc aminoaxit l cc cht rn khng mu, v hi ngt, nhit nng chy cao, d tan trong nc. 4. Ha tnh: Tnh cht axit baz ca dd amino axit - Amino axit tc dng vi axit v c mnh to mui VD: HOOC CH2 NH2 + HCl HOOC CH2 NH3Cl - Amino axit tc dng vi baz mnh to mui v nc VD: NH2 CH2 COOH + NaOH NH2 CH2 COONa + H2O * amino axit c tnh lng tnh: va tc dng vi axit, va tc dng vi baz. Phn ng este ha nhm COOH
Kh HCl
VD: NH2 CH2 COOH + C2H5OH NH 2 CH2 COOC2H5 + H2O Phn ng trng ngng VD: nH NH [CH2]5CO OH (- NH[CH2]5CO-)n + nH2O PEPTIT 1. Khi nim: - Lin kt ca nhm CO vi nhm NH gia 2 n v -aminoaxit c gi l lin kt peptit V d: H2N-CH2-CO-NH-CH-COOH CH3
Lin kt peptit - Peptit l nhng hp cht cha t 2 n 50 gc -aminoaxit lin kt vi nhau bng lin kt peptit 2. Phn loi: (gm 2 loi) - Oligopeptit: c t 2 n 10 gc -aminoaxit - Polipeptit: c t 11 n 50 gc -aminoaxit 3. Cu to: Phn t peptit hp thnh t cc phn t -aminoaxit lin kt vi nhau bng lin kt peptit theo 1 trt t nht nh. V d: H2N-CH-CO-NH-CH-CO-NH-CH-CONH-CH-COOH R1 R2 R3 Rn u N lin kt peptit u C 4. Danh php: c tn aminoaxit t u N n u C
V d: H2NCH2CO-NHCH2COOH GlyxylGlyxin(Gly-Gly) H2NCH2CO-NHCHCOOH CH3 Glyxylalanin(Gly-Ala) ng phn: Vi n aminaxit khc nhau c n ! peptit ng phn cha cc gc aminoaxit khc nhau. VD: - Ala v Gly to 2 ipeptit cha c Ala v Gly - Ala, Gly v Val to 6 tripeptit cha c Ala, Gly v Val. 6. Tnh cht ho hc a. Phn ng mu biure: Peptit + Cu(OH)2 phc mu tm Ch : i peptit khng c phn ng ny b. phn ng thu phn: to ra cc -aminoaxit PROTEIN 1- Khi nim v phn loi: - Protein l nhng polipeptit cao phn t c pt khi t vi chc nghn n vi triu. - Protein gm 2 loi: + Protein n gin: c to thnh t cc gc -aminoaxit + protein phc tp: c to thnh t protein n gin cng vi thnh phn phi protein nh axit nucleic, lipit, cacbohidrat, 2. Tnh cht ha hc ca protein: a/ P thy phn: Protein polipeptit cc - aminoaxit b/ phn ng mu: + P vi Cu(OH)2 (p biure): Protein + Cu(OH)2 phc mu tm + P vi HNO3 c: Protein + HNO3c kt ta mu vng
A*Cu hi l thuyt: Cu 1: Amino axit l hp cht hu c trong phn t A. cha nhm cacboxyl v nhm amino. B. ch cha nhm amino. C. ch cha nhm cacboxyl. D. ch cha nit hoc cacbon. Cu 2: C4H9O2N c my ng phn amino axit c nhm amino v tr ? A. 4. B. 3. C. 2. D. 5. Cu 3: C bao nhiu amino axit c cng cng thc phn t C4H9O2N? A. 3 cht. B. 4 cht. C. 5 cht. D. 6 cht. Cu 4: C bao nhiu amino axit c cng cng thc phn t C3H7O2N? A. 3 cht. B. 4 cht. C. 2 cht. D. 1 cht. Cu 5: Trong cc tn gi di y, tn no khng ph hp vi cht CH3CH(NH2)COOH ? A. Axit 2-aminopropanoic. B. Axit -aminopropionic. C. Anilin. D. Alanin. Cu 6: Trong cc tn gi di y, tn no khng ph hp vi cht CH3-CH(CH3)-CH(NH2)-COOH? A. Axit 3-metyl-2-aminobutanoic. B. Valin. C. Axit 2-amino-3-metylbutanoic. D. Axit -aminoisovaleric. Cu 7: Trong cc cht di y, cht no l glixin? A. H2N-CH2-COOH B. CH3CH(NH2)COOH C. HOOC-CH2CH(NH2)COOH D. H2NCH2-CH2COOH Cu 8: Dung dch ca cht no sau y khng lm i mu qu tm : A. Glixin (CH2NH2-COOH) B. Lizin (H2NCH2-[CH2]3CH(NH2)-COOH) C. Axit glutamic (HOOCCH2CHNH2COOH) D. Natriphenolat (C6H5ONa) Cu 9: Cht X va tc dng c vi axit, va tc dng c vi baz. Cht X l A. CH3COOH. B. H2NCH2COOH. C. CH3CHO. D. CH3NH2. Cu 10: Cht no sau y va tc dng c vi H2NCH2COOH, va tc dng c vi CH3NH2? A. NaCl. B. HCl. C. CH3OH. D. NaOH. Cu 11: Cht rn khng mu, d tan trong nc, kt tinh iu kin thng l A. C6H5NH2. B. C2H5OH. C. H2NCH2COOH. D. CH3NH2. Cu 12: Cht tham gia phn ng trng ngng l A. C2H5OH. B. CH2 = CHCOOH. C. H2NCH2COOH. D. CH3COOH. Cu 13: Cho dy cc cht: C6H5NH2 (anilin), H2NCH2COOH, CH3CH2COOH, CH3CH2CH2NH2, C6H5OH (phenol). S cht trong dy tc dng c vi dung dch HCl l A. 4. B. 2. C. 3. D. 5. ---------------------------------------------------------------------------------------------------------------------------T Ha hc Trng THPT Chu Thnh - Gio vin son Hunh Tn Ng Trang 16
Cu 14: chng minh aminoaxit l hp cht lng tnh ta c th dng phn ng ca cht ny ln lt vi A. dung dch KOH v dung dch HCl. B. dung dch NaOH v dung dch NH3. C. dung dch HCl v dung dch Na2SO4 . D. dung dch KOH v CuO. Cu 15: Cht phn ng c vi cc dung dch: NaOH, HCl l A. C2H6. B. H2N-CH2-COOH. C. CH3COOH. D. C2H5OH. Cu 16: Axit aminoaxetic (H2NCH2COOH) tc dng c vi dung dch A. NaNO3. B. NaCl. C. NaOH. D. Na2SO4. Cu 17: Dung dch ca cht no trong cc cht di y khng lm i mu qu tm ? A. CH3NH2. B. NH2CH2COOH C. HOOCCH2CH2CH(NH2)COOH. D. CH3COONa. Cu 18: phn bit 3 dung dch H2NCH2COOH, CH3COOH v C2H5NH2 ch cn dng mt thuc th l A. dung dch NaOH. B. dung dch HCl. C. natri kim loi. D. qu tm. Cu 19: C cc dung dch ring bit sau: C6H5-NH3Cl (phenylamoni clorua), H2N-CH2-CH2-CH(NH2)COOH, ClH3N-CH2-COOH, HOOC-CH2-CH2-CH(NH2)-COOH, H2N-CH2-COONa. S lng cc dung dch c pH < 7 l A. 2. B. 5. C. 4. D. 3. Cu 20: Glixin khng tc dng vi A. H2SO4 long. B. HCl. C. C2H5OH. D. NaCl. Cu 21: Tripeptit l hp cht A. m mi phn t c 3 lin kt peptit. B. c lin kt peptit m phn t c 3 gc amino axit ging nhau. C. c lin kt peptit m phn t c 3 gc amino axit khc nhau. D. c 2 lin kt peptit m phn t c 3 gc -amino axit. Cu 22: C bao nhiu tripeptit m phn t cha 3 gc amino axit khc nhau? A. 3 cht. B. 5 cht. C. 6 cht. D. 8 cht. Cu 23: Trong cc cht di y, cht no l ipeptit ? A. H2N-CH2-CO-NH-CH2-CH2-COOH. B. H2N-CH2-CO-NH-CH(CH3)-COOH. C. H2N-CH2-CO-NH-CH(CH3)-CO-NH-CH2-COOH. D. H2N-CH(CH3)-CO-NH-CH2-CO-NH-CH(CH3)-COOH Cu 24: T glyxin (Gly) v alanin (Ala) c th to ra my cht ipeptit ? A. 1 cht. B. 2 cht. C. 3 cht. D. 4 cht. Cu 25: Sn phm cui cng ca qu trnh thy phn cc protein n gin nh cht xc tc thch hp l A. -aminoaxit. B. -aminoaxit. C. axit cacboxylic. D. este. Cu 26: S ng phn ipeptit to thnh t 1 phn t glyxin v 1 phn t alanin l A. 3. B. 1. C. 2. D. 4. Cu 27. Thy phn tng phn mt pentapeptit thu c cc ipeptit v tripeptit sau : Gly - Ala ; Val - Glu ; Ala Val ; Glu - Phe ; Ala - Val - Glu. Trnh t ca cc aminoaxit trong pentapeptit trn l : A. Ala - Val - Glu - Gly - Phe. B. Val - Glu - Phe - Gly - Val. C. Gly - Ala - Val - Glu - Phe. D. Gly - Ala - Glu - Phe - Val.
Cu 28. phn bit c cc dung dch : glucoz, glixerol, h tinh bt v lng trng trng, ta dng
A. Cu(OH)2 c thm dung dch NaOH. B. dung dch HNO3 c v dung dch AgNO3 trong NH3. C. dung dch I2 v dung dch HNO3 c. D. dung dch I2 v dung dch AgNO3 trong NH3.
Cu 29. Thuc th c dng phn bit Gly-Ala-Gly vi Gly-Ala l A. dung dch NaOH. B. dung dch NaCl. C. Cu(OH)2 trong mi trng kim. D. dung dch HCl. Cu 30. Amino axit l nhng hp cht hu c ........................., trong phn t cha ng thi nhm chc ................. v nhm chc ................... in vo ch trng cn thiu l : A. n chc, amino, cacboxyl B. Tp chc, cacbonyl, amino C. Tp chc, amino, cacboxyl D. Tp chc, cacbonyl, hidroxyl *Bi ton vn dng: ---------------------------------------------------------------------------------------------------------------------------T Ha hc Trng THPT Chu Thnh - Gio vin son Hunh Tn Ng Trang 17
Cu 1: Cho 7,5 gam axit aminoaxetic (H2N-CH2-COOH) phn ng ht vi dung dch HCl. Sau phn ng, khi lng mui thu c l (Cho H = 1, C = 12, O = 16, Cl = 35, 5) A. 43,00 gam. B. 44,00 gam. C. 11,05 gam. D. 11,15 gam. Cu 2: Cho 7,5 gam axit aminoaxetic (H2N-CH2-COOH) phn ng ht vi dung dch NaOH. Sau phn ng, khi lng mui thu c l (Cho H = 1, C = 12, O = 16, Na = 23) A. 9,9 gam. B. 9,8 gam. C. 7,9 gam. D. 9,7 gam. Cu 3: Cho m gam alanin phn ng ht vi dung dch NaOH. Sau phn ng, khi lng mui thu c 11,1 gam. Gi tr m dng l (Cho H = 1, C = 12, O = 16, Na = 23) A. 9,9 gam. B. 9,8 gam. C. 8,9 gam. D. 7,5 gam. Cu 4: Trong phn t aminoaxit X c mt nhm amino v mt nhm cacboxyl. Cho 15,0 gam X tc dng va vi dung dch NaOH, c cn dung dch sau phn ng thu c 19,4 gam mui khan. Cng thc ca X l A. H2NC3H6COOH. B. H2NCH2COOH. C. H2NC2H4COOH. D. H2NC4H8COOH. Cu 5: 1 mol - amino axit X tc dng va ht vi 1 mol HCl to ra mui Y c hm lng clo l 28,287% Cng thc cu to ca X l A. CH3-CH(NH2)COOH B. H2N-CH2-CH2-COOH C. H2N-CH2-COOH D. H2N-CH2-CH(NH2 )-COOH Cu 6: Khi trng ngng 13,1 g axit - aminocaproic vi hiu sut 80%, ngoi aminoaxit cn d ngi ta thu c m gam polime v 1,44 g nc. Gi tr m l A. 10,41 B. 9,04 C. 11,02 D. 8,43 Cu 7: Este A c iu ch t ancol metylic v amino axit no B(cha mt nhm amino v mt nhm cacboxyl). T khi hi ca A so vi oxi l 2,78125. Amino axit B l A. axit amino fomic. B. axit aminoaxetic. C. axit glutamic. D. axit -amino propionic. Cu 8: C 0,01 mol aminoaxit (A) phn ng va vi 40 ml dung dch NaOH 0,25M. Mt khc 1,5 gam aminoaxit (A) phn ng va vi 80 ml dung dch NaOH 0,25M. Khi lng phn t ca A l A. 150. B. 75. C. 105. D. 89. Cu 9: 0,01 mol aminoaxit (A) tc dng va vi 50 ml dung dch HCl 0,2M. C cn dung dch sau phn ng c 1,835 gam mui khan. Khi lng phn t ca A l A. 89. B. 103. C. 117. D. 147. Cu 10: Mt - amino axit X ch cha 1 nhm amino v 1 nhm cacboxyl. Cho 10,68 gam X tc dng vi HCl d thu c 15,06 gam mui. Tn gi ca X l A. axit glutamic. B. valin. C. alanin. D. glixin Cu 11: Este A c iu ch t -amino axit v ancol metylic. T khi hi ca A so vi hidro bng 44,5. Cng thc cu to ca A l: A. CH3CH(NH2)COOCH3. B. H2N-CH2CH2-COOH C. H2NCH2COOCH3. D. H2NCH2CH(NH2)COOCH3. Cu 12: A l mt aminoaxit. Cho bit 1 mol A phn ng va vi 1 mol HCl, hm lng clo trong mui thu c l 19,346%. Cng thc ca A l : A. HOOCCH2CH2CH(NH2)COOH B. HOOCCH2CH2CH2CH(NH2)COOH C. CH3CH2CH(NH2)COOH D. CH3CH(NH2)COOH Cu 13. Cho 23,9g hn hp gm axit aminoaxetic v axit -aminopropionic vo 0,6 lt dung dch NaOH 0,5M. Phn trm v s mol ca 2 axit ln lt l A. 40,5% v 59,5% B. 20,3% v 79,7% C. 24,5% v 75,5% C. 33,3% v 66,7% Dng bi ton vn dng cao:
Cu 14*. Cho 1 mol amino axit X phn ng vi dung dch HCl (d), thu c m1 gam mui Y. Cng 1 mol amino axit X phn ng vi dung dch NaOH (d), thu c m2 gam mui Z. Bit m2 - m1 = 7,5. Cng thc phn t ca X l A. C5H9O4N. B. C4H10O2N2. C. C5H11O2N. D. C4H8O4N2. Cu 15*. Cho 0,02 mol amino axit X tc dng va vi 200 ml dung dch HCl 0,1M thu c 3,67 gam mui khan. Mt khc 0,02 mol X tc dng va vi 40 gam dung dch NaOH 4%. Cng thc ca X l A. H2NC2H3(COOH)2. B. H2NC3H5(COOH)2. C. (H2N)2C3H5COOH. D. H2NC3H6COOH
Chng 4-POLIME-VAT LIEU POLIME
CHNG 4: POLIME - VT LIU POLIME

A. KIN THC CN NH BI 13. I CNG V POLIME I. KHI NIM Polime l nhng hp cht c phn t khi rt ln do nhiu n v c s (gi l mt xch) lin kt vi nhau to nn. - Th d: polietilen: (CH2 - CH2 )n , xenluloz : (C6H10O5)n *Phn loi : **Theo ngun gc : -polime tng hp :Vd: polietilen -Polime thin nhin : vd : tinh bt -Polime bn tng hp : vd : t visco **Theo cch tng hp : -Polime trng hp :vd : polipropilen -Polime trng ngng : vd : nilon-6,6
III.TNH CHT VT L -Cht nhit do : polime nng chy , ngui thnh rn . -Cht nhit rn : polime khng nng chy , m b phn hy . IV.TNH CHT HA HC 1/ Phn ng phn ct mch polime - Polime c nhm chc trong mch d b thy phn Th d : tinh bt , xenluloz b thy phn thnh glucoz 2/ Phn ng gi nguyn mch polime Nhng polime c lin kt i trong mch hoc nhm chc ngoi mch c th tham gia cc phn ng c trng 3/ Phn ng tng mch polime ( phn ng khu mch polime ) Khi c iu kin thch hp cc mch polime c th ni vi nhau BI 14. VT LIU POLIME . I. Cht do: 1. Khi nim v cht do v vt liu compozit * Cht do l nhng cht liu polime c tnh do. - Thnh phn: polime Cht n, cht ho do, cht ph gia. *Vt liu Com pozit l vt liu hn hp gm t nht 2 thnh phn phn tn vo nhau m khng ho tan vo nhau. Thnh phn: Cht nn (polime) Cht n, si bt (silicat), bt nh (CaCO3 ) 2. Mt s polime dng lm cht do: a/ Polietilen: (P.E) b/ poli (Vinylclorua) (PVC) c/ poli(metyl metacrylat) thu tinh hu c (plexiglas) d/ poli (phenol-fomandehit) (P.P.F) II. T: 1. Khi nim T l nhng vt liu polime hnh si di v mnh, bn nht nh. 2. Phn loi: c 2 loi - T t nhin: Len, t tm, bng - T ho hc + T tng hp: Ch to t polime tng hp: tpoliamit, vinylic + T bn tng hp: (t nhn to): ch to t polime thin nhin nh t visco, xenluloz axetat. 3. Mt s loi t tng hp thng gp: a/ T nilon-6.6 b/ T nitron (olon) % V khi lng clo trong t clorin :% Cl = 35,5( n+1)x100/( 62,5n + 34,5) n l s mc xch m clo tham gia phn ng th III. Cao su: 1. Khi nim: Cao su l vt liu polime c tnh n hi. 2. Phn loi: C 2 loi: cao su thin nhin v cao su tng hp a/ Cao su thin nhin: ly t m cy cao su - Cu to: l polime ca isopren b/ Cao su tng hp: cao su buna v Cao su buna-S v cao su buna-N IV. Keo dn tng hp. 1/ Khi nim: Keo dn l loi vt liu c kh nng kt dnh 2 mnh vt liu rn ging hoc khc nhau m khng lm bin i bn cht ca vt liu c kt dnh. 2. Mt s loi keo dn tng hp thng dng: C/ Keo dn ure-fomandehit a/ Nha v sm: l dung dch c ca cao su trong dung mi hu c
b/ keo dn epoxi: lm t polime c cha nhm epoxi
B. BI TP N TP
* Dng cu hi l thuyt Cu 1: Polivinyl clorua c cng thc l A. (-CH2-CHCl-)2. B. (-CH2-CH2-)n. C. (-CH2-CHBr-)n. D. (-CH2-CHF-)n. Cu 2: Cht khng c kh nng tham gia phn ng trng hp l A. stiren. B. isopren. C. propen. D. toluen. Cu 3: Cht c kh nng tham gia phn ng trng hp l A. propan. B. propen. C. etan. D. toluen. Cu 4: Qu trnh nhiu phn t nh (monome) kt hp vi nhau thnh phn t ln (polime) ng thi gii phng nhng phn t nc gi l phn ng A. nhit phn. B. trao i. C. trng hp. D. trng ngng. Cu 5: Tn gi ca polime c cng thc (-CH2-CH2-)n l A. polivinyl clorua. B. polietilen. C. polimetyl metacrylat. D. polistiren. Cu 6: T monome nao sau y co th iu ch c poli(vinyl ancol)? A. CH2=CH-COOCH3. B. CH2=CH-OCOCH3. C. CH2=CH-COOC2H5. D. CH2=CH-CH2OH. Cu 7: Cht tham gia phn ng trng hp to ra polime l A. CH3-CH2-Cl. B. CH3-CH3. C. CH2=CH-CH3. D. CH3-CH2-CH3. Cu 8: Monome c dng iu ch polietilen l A. CH2=CH-CH3. B. CH2=CH2. C. CHCH. D. CH2=CH-CH=CH2. Cu 9: Dy gm cc cht c dng tng hp cao su Buna-S l: A. CH2=C(CH3)-CH=CH2, C6H5CH=CH2. B. CH2=CH-CH=CH2, C6H5CH=CH2. C. CH2=CH-CH=CH2, lu hunh. D. CH2=CH-CH=CH2, CH3-CH=CH2. Cu 10: Cho cc polime sau: (-CH2 CH2-)n ; (- CH2- CH=CH- CH2-)n ; (- NH-CH2 -CO-)n Cng thc ca cc monome khi trng hp hoc trng ngng to ra cc polime trn ln lt l A. CH2=CHCl, CH3-CH=CH-CH3, CH3- CH(NH2)- COOH. B. CH2=CH2, CH2=CH-CH= CH2, NH2- CH2- COOH. C. CH2=CH2, CH3- CH=C= CH2, NH2- CH2- COOH. D. CH2=CH2, CH3- CH=CH-CH3, NH2- CH2- CH2- COOH. Cu 11: Trong s cc loi t sau: (1) [-NH-(CH2)6-NH-OC-(CH2)4-CO-]n (2) [-NH-(CH2)5-CO-]n (3) [C6H7O2(OOC-CH3)3]n . T nilon-6,6 l A. (1). B. (1), (2), (3). C. (3). D. (2). Cu 12: Nha phenolfomandehit c iu ch bng cch un nng phenol (d) vi dung dch A. HCOOH trong mi trng axit. B. CH3CHO trong mi trng axit. C. CH3COOH trong mi trng axit. D. HCHO trong mi trng axit. Cu 13: Polivinyl axetat (hoc poli(vinyl axetat)) l polime c iu ch bng phn ng trng hp A. C2H5COO-CH=CH2. B. CH2=CH-COO-C2H5. C. CH3COO-CH=CH2. D. CH2=CH-COO-CH3. Cu 14: Nilon6,6 l mt loi A. t axetat. B. t poliamit. C. polieste. D. t visco. Cu 15: Polime dng ch to thu tinh hu c (plexiglas) c iu ch bng phn ng trng hp A. CH2=C(CH3)COOCH3. B. CH2 =CHCOOCH3. C. C6H5CH=CH2. D. CH3COOCH=CH2. Cu 16: Polivinyl clorua (PVC) iu ch t vinyl clorua bng phn ng A. trao i. B. oxi ho - kh. C. trng hp. D. trng ngng. Cu 17: Cng thc cu to ca polibutaien l A. (-CF2-CF2-)n. B. (-CH2-CHCl-)n. C. (-CH2-CH2-)n. D. (-CH2-CH=CH-CH2-)n. Cu 18: T c sn xut t xenluloz l A. t tm. B. t capron. C. t nilon-6,6. D. t visco. Cu 19: Monome c dng iu ch polipropilen l A. CH2=CH-CH3. B. CH2=CH2. C. CHCH. D. CH2=CH-CH=CH2. Cu 20: T c sn xut t xenluloz l A. t visco. B. t nilon-6,6. C. t tm. D. t capron. Cu 21: T lapsan thuc loai A. t poliamit. B. t visco. C. t polieste. D. t axetat. Cu 22: T capron thuc loai A. t poliamit. B. t visco. C. t polieste. D. t axetat. Cu 23: T nilon - 6,6 c iu ch bng phn ng trng ngng
A. HOOC-(CH2)2-CH(NH2)-COOH. B. HOOC-(CH2)4-COOH v HO-(CH2)2-OH. C. HOOC-(CH2)4-COOH v H2N-(CH2)6-NH2. D. H2N-(CH2)5-COOH. Cu 24: Cho s chuyn ho: Glucoz X Y Cao su Buna. Hai cht X, Y ln lt l A. CH3CH2OH v CH3CHO. B. CH3CH2OH v CH2=CH2. C. CH2CH2OH v CH3-CH=CH-CH3. D. CH3CH2OH v CH2=CH-CH=CH2. Cu 25: Cao su buna c to thnh t buta-1,3-ien bng phn ng A. trng hp B. trng ngng C. cng hp D. phn ng th Cu 26: Cng thc phn t ca cao su thin nhin A. ( C5H8)n B. ( C4H8)n C. ( C4H6)n D. ( C2H4)n Cu 27: Cht khng c kh nng tham gia phn ng trng ngng l : A. glyxin. B. axit terephtaric. C. axit axetic. D. etylen glycol. Cu 28: T nilon -6,6 thuc loi A. t nhn to. B. t bn tng hp. C. t thin nhin. D. t tng hp. Cu 29: T visco khng thuc loi A. t ha hc. B. t tng hp. C. t bn tng hp. D. t nhn to. Cu 30. Trong cc loi t di y, t nhn to l A. t visco. B. t capron. C. t nilon -6,6. D. t tm. Cu 31. Teflon l tn ca mt polime c dng lm A. cht do. B. t tng hp. C. cao su tng hp. D. keo dn. Cu 32: Polime c cu trc mng khng gian (mng li) l A. PVC. B. nha bakelit. C. PE. D. amilopectin. Cu 33: T nilon-6,6 c tng hp t phn ng A. trng hp gia axit aipic v hexametylen i amin C. trng hp t caprolactan B. trng ngng gia axit aipic v hexametylen i amin D. trng ngng t caprolactan Cu 34. T nilon-6,6 l sn phm ca phn ng trng ngng gia A. HOOC-[CH2]4-COOH v H2N-[CH2]4- NH2 B. HOOC-[CH2]4-COOH v H2N-[CH2]6- NH2 C. HOOC-[CH2]6-COOH v H2N-[CH2]6- NH2 D. HOOC-[CH2]6-NH2 v H2N-[CH2]6- COOH Cu 35. Trong cc polime: PE, PVC, polibutadien, poliisopren, amilose, amilopectin, xenlulose, cao su lu ha. Cc polime c cu trc mch khng nhnh l: A. PE, polibutadien, poliisopren, amilose, amilopectin, xenlulose, cao su lu ha B. PE, PVC, polibutadien, poliisopren, xenlulose, cao su lu ha C. PE, PVC, polibutadien, poliisopren, amilose, xenlulose. D. PE, PVC, polibutadien, poliisopren, amilose, amilopectin, xenlulose. Cu 36. C cc polime thin nhin: tinh bt (C 6H10O5)n; cao su isopren (C5H8)n; t tm (NH-R-CO)-n. Polime thin nhin no trong s cc polime c th l sn phm ca phn ng trng hp ? A. Tinh bt (C6H10O5)n B. T tm C. Tinh bt; cao su isopren D. Cao su isopren Cu 37.Trong s cc polime sau y; t tm, si bng, len, t enang, t visco, nilon 6-6, t axetat. Loi t c ngun gc xenluloz l: A. t tm, si bng, nilon 6-6. B. si bng, len, t axetat. C. si bng, len, nilon 6-6. D. t visco, nilon 6-6, t axetat. Cu 38. Pht biu no sau y l ng? A. T visco l t tng hp. B. Trng ngng buta-1,3-ien vi acrilonitrin c xc tc Na c cao su buna-N. C. Trng hp stiren thu c poli(phenol-fomanehit). D. Poli(etylen terephtalat) c iu ch bng phn ng trng ngng cc monome tng ng. Cu 39 Poli(metyl metacrylat) v nilon-6 c to thnh t cc monome tng ng l A. CH2=CH-COOCH3 v H2N-[CH2]6-COOH. B. CH2=C(CH3)-COOCH3 v H2N-[CH2]6-COOH. C. CH3-COO-CH=CH2 v H2N-[CH2]5-COOH. D. CH2=C(CH3)-COOCH3 v H2N-[CH2]5-COOH.
*Bi tp vn dng:
Cu 1. Phn t khi trung bnh ca polietilen X l 50000. H s polime ho ca PE xp x A. 920 B. 1230 C. 1529 D. 1786 Cu 2. Khi clo ha PVC ta thu c mt loi t clorin cha 63,96%. Trung bnh 1 phn t clo tc dng vi boa nhiu mt xch PVC?
A. 1 B. 2 C. 3 D. 4 Cu 3. tng hp 120 kg poli(metyl metacrylat) vi hiu sut ca qu trnh ho este l 60% v qu trnh trng hp l 80% th cn cc lng axit v ru l A. 215 kg axit v 80 kg ancol C. 85 kg axit v 40 kg ancol B. 49,356 kg axit v 18,432 kg ancol D. 80 kg axit v 215 kg ancol Cu 4:Polime X c phn t khi M = 280000 vC v h s trng hp n = 10000. Vy X l A.Polietilen (PE) B.Polivinylclorua (PVC) C.Polistiren (PS) D.Polivinylaxetat (PVAc)
Cu 5: Phn t khi trung bnh ca PVC l 750000. H s polime ho ca PVC l A. 12.000 B. 15.000 C. 24.000 D. 25.000 Cu 6: Phn t khi trung bnh ca polietilen X l 420000. H s polime ho ca PE l A. 12.000 B. 13.000 C. 15.000 D. 17.000 Cu 7: Khi lng ca mt on mch t nilon-6,6 l 27346 vC v ca mt on mch t capron l 17176 vC. S lng mt xch trong on mch nilon-6,6 v capron nu trn ln lt l A. 113 v 152. B. 121 v 114. C. 121 v 152. D. 113 v 114. Cu 8: T 4 tn C2H4 c cha 30% tp cht c th iu ch bao nhiu tn PE ? (Bit hiu sut phn ng l 90%) A. 2,55 B. 2,8 C. 2,52 D.3,6 Bi ton vn dng cao Cu 1. PVC c iu ch t kh thin nhin ( cha 80% CH4) theo s sau: CH4 C2H2 CH2=CHCl PVC Nu hiu sut ton b qu trnh iu ch l 20% th th tch kh thin nhin ( ktc) cn dng iu ch ra 1 kg PVC l A. 3584 lt B. 4480 lt C. 2867.2 lt D. 197.5 lt Cu 2. T 115 lt dung dch ru etilic 40o ( d= 0.8 gam/ml) c th iu ch c bao nhiu kg cao su buna? Bit hiu sut phn ng 75% A. 12.6kg B. 28.8 kg C. 16.2 kg D. 21.6 kg Cu 3. C 5,668 gam cao su buna-S phn ng va ht vi 3.462 gam brom trong CCl 4. T l mt xch butadien v stiren trong cao su buna S l A. 2:3 B. 1:2 C. 1:3 D. 3:5 Cu 4. Khi lng ca mt on mch t nilon-6,6 l 27346 vC v ca mt on mch t capron l 17176 vC. S lng mt xch trong on mch nilon-6,6 v capron nu trn ln lt l A. 121 v 152. B. 113 v 152. C. 113 v 114. D. 121 v 114. Cu 5. Cho s chuyn ha: CH4 C2H2 C2H3Cl PVC. tng hp 250 kg PVC theo s 3 trn th cn V m kh thin nhin ( ktc). Gi tr ca V l (bit CH4 chim 80% th tch kh thin nhin v hiu sut ca c qu trnh l 50%) A. 448,0. B. 224,0. C. 358,4. D. 286,7.
Chng 5-I CNG V KIM LOI
CHNG 5: I CNG KIM LOI
BI 17. V TR CA KIM LOI TRONG BTH . I. V tr ca kim loi trong bng h thng tun hon: _ Nhm IA ( tr hidro), nhm IIA, nhm IIIA( tr bo) v mt phn ca nhm IVA,VA,VIA. _ Cc nguyn t nhm B ( t IB n VIIIB). _ H latan v actini. II. Cu to ca kim loi: 1. cu to nguyn t: Nguyn t ca hu ht cc nguyn t kim loi iu c t electron lp ngoi cng ( 1,2 hoc 3). 2. Cu to tinh th: nhit thng cc kim loi th gn v c cu to tinh th( tr thy ngn th lng). Tinh th kim loi c 3 kiu mng tinh th ph bin sau: a) Mng tinh th lc phng: V d: Be,Mg,Zn, b) Mng tinh th lp phng tm din: V d: Li,Na,K, c) Mng tinh th lp phng tm khi: V d: Cu,Ag,Al, 3. Lin kt kim loi: L lin kt c hnh thnh gia cc nguyn t v ion kim loi trong mng tinh th do s tham gia ca cc electron t do BI 18. TNH CHT CA KIM LOI . DY IN HA CA KIM LOI . I TNH CHT VT L . 1 .Tnh cht vt l chung . iu kin thng cc kim loi u trng thi rn (tr Hg) c tnh do dn in ,dn nhit v nh kim . Tm li ;tnh cht vt l chung ca kim loi gy nn bi s c mt ca cc e t do trong mng tinh th kim loi II TNH CHT HO HC Tnh cht ho hc chung ca kim loi l tnh kh M Mn+ + ne 1 Tc dng vi phi kim to a/ Vi clo 2Fe + 3 Cl2 2 FeCl3 .
t b/ Vi Oxi 3Fe + 2O2 Fe3O4 c/ Vi lu hunh phn ng cn un nng (tr Hg to thng ) 2 Tc dng vi dung dch axit . a/Vi dd HCl,H2SO4 long .Tr cc kim loi ng sau hidro trong dy in ha . b/ vi dd HNO3 ,H2SO4 c Hu ht kim loi (tr Au,Pt) kh c N+5(HNO3 loang) N+2 v S+6 (H2SO4 c nng) S+4 Ch ; HNO3 ,H2SO4 c ngui lm th ng ho Al,Fe, Cr, . . . 3 Tc dng vi nc -Ch c cc kim loi nhm IAv IIA BTH (tr Be,Mg) kh H2O nhit thng . 2Na + 2H2O 2NaOH + H2 -Cc kl cn li c tnh kh yu hn nn kh nc t0cao: Fe, Zn, 4 Tc Dng Vi Dung Dch Mui. VD: Fe + CuSO4 FeSO4 + Cu Fe cht kh : Cu2+ cht oxh III. DY IN HO KIM LOI 1 Cp oxi ha kh ca kim loi . Vd Ag+ /Ag ,Cu2+/Cu,. . . . 2 So snh tnh cht cp oxi ha kh Tnh oxh cc ion ; Ag+> Cu2+> Zn2+ Tnh kh . Zn>Cu>Ag 3 Dy in ha ca kim loi Tnh oxi ha ca ion kim loi tng
o
K+ Na+ Mg2+ Al3+ Zn2+ Fe2+ Ni2+ Sn2+ Pb2+ H+ Cu2+ Fe3+ Ag+ Hg2+ Au3+ K Na Mg Al Zn Fe Ni Sn Pb H2 Cu Fe2+ Ag Hg Au
Tnh kh ca kim loi gim 4 ngha dy in ha Cho php d on chiu ca p gia 2 cp oxh-kh theo qui tc vd phn ng gia 2 cp Cu2+/Cu v Fe2+/Fe. Fe + Cu2+ Fe2+ + Cu c.k m c. oxh m c. oxh y c.k y BI 19. HP KIM . I KHI NIM H p kim l vt liu kim loi c bn v mt s kim loi hoc phi kim khc . II TNH CHT . Hp kim c nhiu tnh cht ha hc tng t tnh cht ca cc n cht tham gia thnh hp kim ,nhng tnh cht vt l v tnh cht c hc ca hp kim li khc nhiu tnh cht cc n cht . III NG DNG Trn thc t ,hp kim c s dng nhiu hn kim loi nguyn cht . Hp kim Au vi Ag , Cu ( vng ty) p v cng , dng ch to trang sc v trc y mt s nc dng c tin .
B. BI TP N TP *V v tr ca kim loi trong BTH Cu 1: S electron lp ngoi cng ca cc nguyn t kim loi thuc nhm IIA l A. 3. B. 2. C. 4. D. 1. Cu 2: S electron lp ngoi cng ca cc nguyn t kim loi thuc nhm IA l A. 3. B. 2. C. 4. D. 1. Cu 3: Cng thc chung ca oxit kim loi thuc nhm IA l A. R2O3. B. RO2. C. R2O. D. RO. Cu 4: Cng thc chung ca oxit kim loi thuc nhm IIA l A. R2O3. B. RO2. C. R2O. D. RO. Cu 5: Cu hnh electron ca nguyn t Na (Z =11) l A. 1s22s2 2p6 3s2. B. 1s22s2 2p6. C. 1s22s22p63s1. D. 1s22s22p6 3s23p1. Cu 6: Hai kim loi u thuc nhm IIA trong bng tun hon l A. Sr, K. B. Na, Ba. C. Be, Al. D. Ca, Ba. Cu 7: Hai kim loi u thuc nhm IA trong bng tun hon l A. Sr, K. B. Na, K. C. Be, Al. D. Ca, Ba. Cu 8: Nguyn t Fe c Z = 26, cu hnh e ca Fe l A. [Ar ] 3d6 4s2. B. [Ar ] 4s13d7. C. [Ar ] 3d7 4s1. D. [Ar ] 4s23d6. Cu 9: Nguyn t Cu c Z = 29, cu hnh e ca Cu l A. [Ar ] 3d9 4s2. B. [Ar ] 4s23d9. C. [Ar ] 3d10 4s1. D. [Ar ] 4s13d10. Cu 10: Nguyn t Cr c Z = 24, cu hnh e ca Cr l A. [Ar ] 3d4 4s2. B. [Ar ] 4s23d4. C. [Ar ] 3d5 4s1. D. [Ar ] 4s13d5. Cu 11: Nguyn t Al c Z = 13, cu hnh e ca Al l A. 1s22s22p63s23p1. B. 1s22s22p63s3. C. 1s22s22p63s23p3. D. 1s22s22p63s23p2. Cu 12: Cation M+ c cu hnh electron lp ngoi cng 2s22p6 l A. Rb+. B. Na+. C. Li+. D. K+. * Tnh cht ca kim loi Cu 1: Kim loi no sau y c tnh dn in tt nht trong tt c cc kim loi? A. Vng. B. Bc. C. ng. D. Nhm. Cu 2: Kim loi no sau y do nht trong tt c cc kim loi? A. Vng. B. Bc. C. ng. D. Nhm. Cu 3: Kim loi no sau y c cng ln nht trong tt c cc kim loi? A. Vonfam. B. Crom C. St D. ng Cu 4: Kim loi no sau y l kim loi mm nht trong tt c cc kim loi ? A. Liti. B. Xesi. C. Natri. D. Kali. Cu 5: Kim loi no sau y c nhit nng chy cao nht trong tt c cc kim loi? A. Vonfam. B. St. C. ng. D. Km. Cu 6: Kim loi no sau y nh nht ( c khi lng ring nh nht ) trong tt c cc kim loi ? A. Natri B. Liti C. Kali D. Rubidi Cu 7: Tnh cht ha hc c trng ca kim loi l A. tnh baz. B. tnh oxi ha. C. tnh axit. D. tnh kh. Cu 8: Hai kim loi u phn ng vi dung dch Cu(NO3)2 gii phng kim loi Cu l A. Al v Fe. B. Fe v Au. C. Al v Ag. D. Fe v Ag. Cu 9: Cp cht khng xy ra phn ng l A. Fe + Cu(NO3)2. B. Cu + AgNO3. C. Zn + Fe(NO3)2. D. Ag + Cu(NO3)2. Cu 10: Hai kim loi Al v Cu u phn ng c vi dung dch A. NaCl long. B. H2SO4 long. C. HNO3 long. D. NaOH long Cu 11: Kim loi Cu phn ng c vi dung dch A. FeSO4. B. AgNO3. C. KNO3. D. HCl. Cu 12: Dung dch FeSO4 v dung dch CuSO4 u tc dng c vi A. Ag. B. Fe. C. Cu. D. Zn. Cu 13: ho tan hon ton hn hp gm hai kim loi Cu v Zn, ta c th dng mt lng d dung dch
A. HCl. B. AlCl3. C. AgNO3. D. CuSO4. Cu 14: Hai dung dch u tc dng c vi Fe l A. CuSO4 v HCl. B. CuSO4 v ZnCl2. C. HCl v CaCl2. D. MgCl2 v FeCl3. Cu 15: Cho cc kim loi: Ni, Fe, Cu, Zn; s kim loi tc dng vi dung dch Pb(NO3)2 l A. 1. B. 2. C. 3. D. 4. Cu 16: Dung dch mui no sau y tc dng c vi c Ni v Pb? A. Pb(NO3)2. B. Cu(NO3)2. C. Fe(NO3)2. D. Ni(NO3)2. Cu 17: Tt c cc kim loi Fe, Zn, Cu, Ag u tc dng c vi dung dch A. HCl. B. H2SO4 long. C. HNO3 long. D. KOH. Cu 18: Cho cc kim loi: Na, Mg, Fe, Al; kim loi c tnh kh mnh nht l A. Al. B. Na. C. Mg. D. Fe. Cu 19: Cho phn ng: aAl + bHNO3 cAl(NO3)3 + dNO + eH2O. H s a, b, c, d, e l cc s nguyn, ti gin. Tng (a + b) bng A. 5. B. 4. C. 7. D. 6. Cu 20: Dy no sau y ch gm cc cht va tc dng c vi dung dch HCl, va tc dng c vi dung dch AgNO3 ? A. Zn, Cu, Mg B. Al, Fe, CuO C. Fe, Ni, Sn D. Hg, Na, Ca Cu 21: Cho phn ng ha hc: Fe + CuSO4 FeSO4 + Cu. Trong phn ng trn xy ra A. s kh Fe2+ v s oxi ha Cu. B. s kh Fe2+ v s kh Cu2+. C. s oxi ha Fe v s oxi ha Cu. D. s oxi ha Fe v s kh Cu2+. Cu 22: Cp cht khng xy ra phn ng ho hc l A. Cu + dung dch FeCl3. B. Fe + dung dch HCl. C. Fe + dung dch FeCl3. D. Cu + dung dch FeCl2. Cu 23: Cho kim loi M tc dng vi Cl2 c mui X; cho kim loi M tc dng vi dung dch HCl c mui Y. Nu cho kim loi M tc dng vi dung dch mui X ta cng c mui Y. Kim loi M c th l A. Mg B. Al C. Zn D. Fe Cu 24: kh ion Cu2+ trong dung dch CuSO4 c th dng kim loi A. K B. Na C. Ba D. Fe 3+ 2+ Cu 25: kh ion Fe trong dung dch thnh ion Fe c th dng mt lng d A. Kim loi Mg B. Kim loi Ba C. Kim loi Cu D. Kim loi Ag Cu 26: Th t mt s cp oxi ha - kh trong dy in ha nh sau : Fe 2+/Fe; Cu2+/Cu; Fe3+/Fe2+. Cp cht khng phn ng vi nhau l A. Cu v dung dch FeCl3 B. Fe v dung dch CuCl2 C. Fe v dung dch FeCl3 D. dung dch FeCl2 v dung dch CuCl2 Cu 27: X l kim loi phn ng c vi dung dch H2SO4 long, Y l kim loi tc dng c vi dung dch Fe(NO3)3. Hai kim loi X, Y ln lt l (bit th t trong dy th in ho: Fe3+/Fe2+ ng trc Ag+/Ag) A. Fe, Cu. B. Cu, Fe. C. Ag, Mg. D. Mg, Ag. Cu 28: Dy gm cc kim loi c xp theo th t tnh kh tng dn t tri sang phi l A. Mg, Fe, Al. B. Fe, Mg, Al. C. Fe, Al, Mg. D. Al, Mg, Fe. Cu 29: Dy gm cc kim loi u phn ng vi nc nhit thng to ra dung dch c mi trng kim l A. Na, Ba, K. B. Be, Na, Ca. C. Na, Fe, K. D. Na, Cr, K. 2+ Cu 30: Trong dung dch CuSO4, ion Cu khng b kh bi kim loi A. Fe. B. Ag. C. Mg. D. Zn. Cu 31: Cho dy cc kim loi: Fe, Na, K, Ca. S kim loi trong dy tc dng c vi nc nhit thng l A. 4. B. 1. C. 3. D. 2. Cu 32: Kim loi phn ng c vi dung dch H2SO4 long l A. Ag. B. Au. C. Cu. D. Al. Cu 33: Cho dy cc kim loi: Na, Cu, Fe, Ag, Zn. S kim loi trong dy phn ng c vi dung dch HCl l A. 5. B. 2. C. 3. D. 4.
Cu 34: ng (Cu) tc dng c vi dung dch A. H2SO4 c, nng. B. H2SO4 long. C. FeSO4. D. HCl. Cu 35: Cho dy cc kim loi: Na, Cu, Fe, Zn. S kim loi trong dy phn ng c vi dung dch HCl l A. 3. B. 1. C. 4. D. 2. Cu 36: Cho dy cc kim loi: K, Mg, Na, Al. Kim loi c tnh kh mnh nht trong dy l A. Na. B. Mg. C. Al. D. K. *Bi tp v s n mn kim loi Cu 1: Mt s ho cht c trn ngn t c khung bng kim loi. Sau 1 thi gian, ngi ta thy khung kim loi b g. Ho cht no di y c kh nng gy ra hin tng trn? A. Ancol etylic. B. Dy nhm. C. Du ho. D. Axit clohydric. Cu 2: Bit rng ion Pb2+ trong dung dch oxi ha c Sn. Khi nhng hai thanh kim loi Pb v Sn c ni vi nhau bng dy dn in vo mt dung dch cht in li th A. c Pb v Sn u b n mn in ho. B. c Pb v Sn u khng b n mn in ho. C. ch c Pb b n mn in ho. D. ch c Sn b n mn in ho. Cu 3: Cho cc cp kim loi nguyn cht tip xc trc tip vi nhau : Fe v Pb; Fe v Zn; Fe v Sn; Fe v Ni. Khi nhng cc cp kim loi trn vo dung dch axit, s cp kim loi trong Fe b ph hy trc l A. 4 B. 1 C. 2 D. 3 Cu 4: Khi lu trong khng kh m mt vt bng st ty (st trng thic) b sy st su ti lp st bn trong, s xy ra qu trnh: A. Sn b n mn in ha. B. Fe b n mn in ha. C. Fe b n mn ha hc. D. Sn b n mn ha hc. Cu 5: bo v v tu bin lm bng thp ngi ta thng gn vo v tu (phn ngm di nc) nhng tm kim loi A. Cu. B. Zn. C. Sn. D. Pb. Cu 6: C 4 dung dch ring bit: a) HCl, b) CuCl2, c) FeCl3, d) HCl c ln CuCl2. Nhng vo mi dung dch mt thanh Fe nguyn cht. S trng hp xut hin n mn in ho l A. 0. B. 1. C. 2. D. 3. Cu 7: Cho cc hp kim sau: Cu-Fe (I); Zn-Fe (II); Fe-C (III); Sn-Fe (IV). Khi tip xc vi dung dch cht in li th cc hp kim m trong Fe u b n mn trc l: A. I, II v III. B. I, II v IV. C. I, III v IV. D. II, III v IV. * Bi tp v iu ch kim loi( HKII) Cu 1: Khi iu ch kim loi, cc ion kim loi ng vai tr l cht A. b kh. B. nhn proton. C. b oxi ho. D. cho proton. Cu 2: loi b kim loi Cu ra khi hn hp bt gm Ag v Cu, ngi ta ngm hn hp kim loi trn vo lng d dung dch A. AgNO3. B. HNO3. C. Cu(NO3)2. D. Fe(NO3)2. Cu 3: Cht khng kh c st oxit ( nhit cao) l A. Cu. B. Al. C. CO. D. H2. Cu 4: Hai kim loi c th iu ch bng phng php nhit luyn l A. Ca v Fe. B. Mg v Zn. C. Na v Cu. D. Fe v Cu. Cu 5: Phng php thch hp iu ch kim loi Ca t CaCl2 l A. nhit phn CaCl2. B. in phn CaCl2 nng chy. C. dng Na kh Ca2+ trong dung dch CaCl2. D. in phn dung dch CaCl2. Cu 6: Oxit d b H2 kh nhit cao to thnh kim loi l A. Na2O. B. CaO. C. CuO. D. K2O. Cu 7: Phng trnh ho hc no sau y th hin cch iu ch Cu theo phng php thu luyn ? A. Zn + CuSO4 Cu + ZnSO4 B. H2 + CuO Cu + H2O C. CuCl2 Cu + Cl2 D. 2CuSO4 + 2H2O 2Cu + 2H2SO4 + O2 Cu 8: Phng trnh ha hc no sau y biu din cch iu ch Ag t AgNO 3 theo phng php thu luyn ?
A. 2AgNO3 + Zn 2Ag + Zn(NO3)2 B. 2AgNO3 2Ag + 2NO2 + O2 C. 4AgNO3 + 2H2O 4Ag + 4HNO3 + O2 D. Ag2O + CO 2Ag + CO2. Cu 9: Trong phng php thu luyn, iu ch Cu t dung dch CuSO 4 c th dng kim loi no lm cht kh? A. K. B. Ca. C. Zn. D. Ag. Cu 10: Cho kh CO d i qua hn hp gm CuO, Al 2O3, MgO (nung nng). Khi phn ng xy ra hon ton thu c cht rn gm A. Cu, Al, Mg. B. Cu, Al, MgO. C. Cu, Al2O3, Mg. D. Cu, Al2O3, MgO. Cu 11: Cho lung kh H2 (d) qua hn hp cc oxit CuO, Fe2O3, ZnO, MgO nung nhit cao. Sau phn ng hn hp rn cn li l: A. Cu, FeO, ZnO, MgO. B. Cu, Fe, Zn, Mg. C. Cu, Fe, Zn, MgO. D. Cu, Fe, ZnO, MgO. Cu 12: Hai kim loi c th c iu ch bng phng php in phn dung dch l A. Al v Mg. B. Na v Fe. C. Cu v Ag. D. Mg v Zn. Cu 13: Cp cht khng xy ra phn ng ho hc l A. Cu + dung dch FeCl3. B. Fe + dung dch HCl. C. Fe + dung dch FeCl3. D. Cu + dung dch FeCl2. Cu 14: Dy cc kim loi u c th c iu ch bng phng php in phn dung dch mui ca chng l: A. Ba, Ag, Au. B. Fe, Cu, Ag. C. Al, Fe, Cr. D. Mg, Zn, Cu. Cu 15: Hai kim loi c th c iu ch bng phng php in phn dung dch l A. Al v Mg. B. Na v Fe. C. Cu v Ag. D. Mg v Zn. Cu 16: Khi in phn NaCl nng chy (in cc tr), ti catt xy ra A. s kh ion Cl-. B. s oxi ho ion Cl-. C. s oxi ho ion Na+. D. s kh ion Na+. Cu 17: Oxit d b H2 kh nhit cao to thnh kim loi l A. Na2O. B. CaO. C. CuO. D. K2O. Cu 18: Trong cng nghip, kim loi c iu ch bng phng php in phn hp cht nng chy ca kim loi l A. Na. B. Ag. C. Fe. D. Cu. Cu 19: Phng php thch hp iu ch kim loi Mg t MgCl2 l A. in phn dung dch MgCl2. B. in phn MgCl2 nng chy. C. nhit phn MgCl2. D. dng K kh Mg2+ trong dung dch MgCl2. Cu 20.Cho lung kh H2 (d) qua hn hp cc oxit CuO, Fe2O3, ZnO, MgO nung nhit cao. Sau phn ng hn hp rn cn li l: A. Cu, Fe, Zn, MgO. B. Cu, Fe, ZnO, MgO. C. Cu, Fe, Zn, Mg. D. Cu, FeO, ZnO, MgO * Bi ton vn dng: Dng 1: kim loi tc dng vi phi kim: Cu 1. Bao nhiu gam clo tc dng va kim loi nhm to ra 26,7 gam AlCl3? A. 21,3 gam B. 12,3 gam. C. 13,2 gam. D. 23,1 gam. Cu 2: t chy bt Al trong bnh kh Clo d, sau khi phn ng xy ra hon ton khi lng cht rn trong bnh tng 4,26 gam. Khi lng Al phn ng l A. 1,08 gam. B. 2,16 gam. C. 1,62 gam. D. 3,24 gam. Cu 3. Bao nhiu gam Cu tc dng va vi clo to ra 27 gam CuCl2? A. 12,4 gam B. 12,8 gam. C. 6,4 gam. D. 25,6 gam. Cu 4. Cho m gam 3 kim loi Fe, Al, Cu vo mt bnh kn cha 0,9 mol oxi. Nung nng bnh 1 thi gian cho n khi s mol O2 trong bnh ch cn 0,865 mol v cht rn trong bnh c khi lng 2,12 gam. Gi tr m dng l: A. 1,2 gam. B. 0,2 gam. C. 0,1 gam. D. 1,0 gam. Cu 5: t 1 lng nhm(Al) trong 6,72 lt O2. Cht rn thu c sau phn ng cho ho tan hon ton vo dung dch HCl thy bay ra 6,72 lt H2 (cc th tch kh o kc). Khi lng nhm dng l A. 8,1gam. B. 16,2gam. C. 18,4gam. D. 24,3gam. Dng 2: kim loi tc dng vi dung dch axit: Cu 1. Cho 10 gam hn hp cc kim loi Mg v Cu tc dng ht vi dung dch HCl long d thu c 3,733 lit H2(kc). Thnh phn % ca Mg trong hn hp l: A. 50%. B. 35%. C. 20%. D. 40%. Cu 2. Mt hn hp gm 13 gam km v 5,6 gam st tc dng vi dung dch axit sunfuric long d. Th tch kh hidro (ktc) c gii phng sau phn ng l.
A. 2,24 lit. B. 4,48 lit. C. 6,72 lit. D. 67,2 lit. Cu 3. Cho 4,05 gam Al tan ht trong dung dch HNO3 thu V lt N2O (kc) duy nht. Gi tr V l A. 2,52 lt. B. 3,36 lt. C. 4,48 lt. D. 1,26 lt. Cu 4: Hn hp X gm Fe v Cu, trong Cu chim 43,24% khi lng. Cho 14,8 gam X tc dng ht vi dung dch HCl thy c V lt kh (ktc) bay ra. Gi tr ca V l A. 1,12 lt. B. 3,36 lt. C. 2,24 lt. D. 4,48 lt. Cu 5: Ho tan hon ton 1,5 gam hn hp bt Al v Mg vo dung dch HCl thu c 1,68 lt H 2 (kc). Phn % khi lng ca Al trong hn hp l A. 60%. B. 40%. C. 30%. D. 80%. Cu 6: Ho tan m gam Fe trong dung dch HCl d, sau khi phn ng kt thc thu c 4,48 lt kh H2 ( ktc). Gi tr ca m l (Cho Fe = 56, H = 1, Cl = 35,5) A. 2,8. B. 1,4. C. 5,6. D. 11,2. Cu 7: Ha tan 6,5 gam Zn trong dung dch axit HCl d, sau phn ng c cn dung dch th s gam mui khan thu c l (Cho H = 1, Zn = 65, Cl = 35,5) A. 20,7 gam. B. 13,6 gam. C. 14,96 gam. D. 27,2 gam. Cu 8: Ho tan 6,4 gam Cu bng axit H 2SO4 c, nng (d), sinh ra V lt kh SO 2 (sn phm kh duy nht, ktc). Gi tr ca V l A. 4,48. B. 6,72. C. 3,36. D. 2,24. Cu 9: Ho tan m gam Al bng dung dch HCl (d), thu c 3,36 lt H2 ( ktc). Gi tr ca m l A. 4,05. B. 2,70. C. 5,40. D. 1,35. Cu 10: Ho tan 5,6 gam Fe bng dung dch HNO 3 long (d), sinh ra V lt kh NO (sn phm kh duy nht, ktc). Gi tr ca V l A. 6,72. B. 4,48. C. 2,24. D. 3,36. Cu 11: Cho 10 gam hn hp gm Fe v Cu tc dng vi dung dch H2SO4 long (d). Sau phn ng thu c 2,24 lt kh hiro ( ktc), dung dch X v m gam cht rn khng tan. Gi tr ca m l (Cho H = 1, Fe = 56, Cu = 64) A. 6,4 gam. B. 3,4 gam. C. 5,6 gam. D. 4,4 gam. Cu 12: Cho 20 gam hn hp bt Mg v Fe tc dng ht vi dung dch HCl thy c 1 gam kh H 2 bay ra. Lng mui clorua to ra trong dung dch l bao nhiu gam ? A. 40,5g. B. 45,5g. C. 55,5g. D. 60,5g. Cu 13: Cho m gam hn hp X gm Al, Cu vo dung dch HCl (d), sau khi kt thc phn ng sinh ra 3,36 lt kh ( ktc). Nu cho m gam hn hp X trn vo mt lng d axit nitric (c, ngui), sau khi kt thc phn ng sinh ra 6,72 lt kh NO2 (sn phm kh duy nht, ktc). Gi tr ca m l A. 15,6. B. 10,5. C. 11,5. D. 12,3. Cu 14: Trong hp kim Al Mg, c c 9 mol Al th c 1 mol Mg. Thnh phn phn % khi lng ca hp kim l A. 80% Al v 20% Mg. B. 81% Al v 19% Mg. C. 91% Al v 9% Mg. D. 83% Al v 17% Mg. Cu 15: Ho tan 6 gam hp kim Cu, Fe v Al trong axit HCl d thy thot ra 3,024 lt kh (kc) v 1,86 gam cht rn khng tan. Thnh phn phn % ca hp kim l A. 40% Fe, 28% Al 32% Cu. B. 41% Fe, 29% Al, 30% Cu. C. 42% Fe, 27% Al, 31% Cu. D. 43% Fe, 26% Al, 31% Cu. Cu 16. Ho tan hon ton 7,8 gam hn hp gm Mg, Al trong dung dch HCl d thy to ra 8,96 lt kh H2 (kc). C cn dung dch sau phn ng thu c m gam mui khan. Gi tr ca m l A. 18,1 gam. B. 36,2 gam. C. 54,3 gam. D. 63,2 gam. Cu 17. Cho 11,9 gam hn hp gm Zn, Al tan hon ton trong dung dch H2SO4 long d thy c 8,96 lit kh (kc) thot ra. Khi lng hn hp mui sunfat khan thu c l: A. 44,9 gam. B. 74,1 gam. C. 50,3 gam. D. 24,7 gam. Cu 18. Cho m gam Fe vo dung dch HNO3 ly d ta thu c 8,96 lit(kc) hn hp kh X gm 2 kh NO v NO2 c t khi hi hn hp X so vi oxi bng 1,3125. Gi tr ca m l A. 0,56 gam. B. 1,12 gam. C. 11,2 gam. D. 5,6 gam. Cu 19. Cho 60 gam hn hp Cu v CuO tan ht trong dung dch HNO3 long d thu c 13,44 lit kh NO (kc, sn phm kh duy nht). Phn % v khi lng ca Cu trong hn hp l: A. 69%. B. 96%. C. 44% D. 56%.
Cu 20. Cho 2,8 gam hn hp bt kim loi bc v ng tc dng vi dung dch HNO 3 c, d th thu c 0,896 lt kh NO2 duy nht ( ktc). Thnh phn phn trm ca bc v ng trong hn hp ln lt l: A. 73% ; 27%. B. 77,14% ; 22,86% C. 50%; 50%. D. 44% ; 56% Cu 21. Cho 8,3 gam hn hp Al v Fe tc dng vi dung dch HNO3 long d th thu c 45,5 gam mui nitrat khan. Th tch kh NO (ktc, sn phm kh duy nht) thot ra l: A. 4,48 lt. B. 6,72 lt. C. 2,24 lt. D. 3,36 lt. Cu 22. Cho 1,86 gam hn hp Al v Mg tc dng vi dung dch HNO3 long d th thu c 560 ml lt kh N2O (ktc, sn phm kh duy nht) bay ra. Khi lng mui nitrat to ra trong dung dch l: A. 40,5 gam. B. 14,62 gam. C. 24,16 gam. D. 14,26 gam. Cu 23. Cho 5 gam hn hp bt Cu v Al vo dung dch HCl d thu 3,36 lt H2 ktc. Phn trm Al theo khi lng hn hp u l A. 27%. B. 51%. C. 64%. D. 54%. Cu 24: Ho tan hon ton 1,23 gam hn hp X gm Cu v Al vo dung dch HNO3 c, nng thu c 1,344 lt kh NO2 (sn phm kh duy nht, ktc). Phn trm v khi lng ca Cu trong hn hp X l A. 21,95%. B. 78,05%. C. 68,05%. D. 29,15%. Cu 25. Cho a gam bt Al tc dng va vi dung dch HNO3 long thu c dung dch A ch cha mt mui duy nht v 0,1792 lt (ktc) hn hp kh NO, N2 c t khi hi so H2 l 14,25. Tnh a ? A. 0,459 gam. B. 0,594 gam. C. 5,94 gam. D. 0,954 gam. Cu 26. Ho tan hon ton 7,8 gam hn hp gm Mg, Al trong dung dch HCl d. Sau phn ng thy khi lng dung dch tng thm 7 gam. Khi lng ca Al c trong hn hp ban u l A. 2,7 gam. B. 5,4 gam. C. 4,5 gam. D. 2,4 gam. Cu 27: Cho hn hp A gm Cu v Mg vo dung dch HCl d thu c 5,6 lt kh (kc) khng mu v mt cht rn khng tan B. Dng dung dch H2SO4 c, nng ho tan cht rn B thu c 2,24 lt kh SO2 (kc). Khi lng hn hp A ban u l: A. 6,4 gam. B. 12,4 gam. C. 6,0 gam. D. 8,0 gam. Cu 28: Ho tan hon ton 1,5 gam hn hp bt Al v Mg vo dung dch HCl thu c 1,68 lt H 2 (kc). Phn % khi lng ca Al trong hn hp l A. 60%. B. 40%. C. 30%. D. 80%. Dng 3: Tm tn kim loi Cu 1. Ho tan 2,52 gam mt kim loi bng dung dch H2SO4 long d, c cn dung dch thu c 6,84 gam mui khan. Kim loi l: A. Mg. B. Al. C. Zn. D. Fe. Cu 2. Ho tan ht m gam kim loi M bng dung dch H2SO4 long, ri c cn dung dch sau phn ng thu c 5m gam mui khan. Kim loi M l: A. Al. B. Mg. C. Zn. D. Fe. Cu 3: Ngm mt l kim loi c khi lng 50 gam trong dung dch HCl. Sau khi thu c 336 ml kh H2 (ktc) th khi lng l kim loi gim 1,68%. Kim loi l A. Zn. B. Fe. C. Ni. D. Al. Cu 4. Nhit phn hon ton 3,5 gam mt mui cacbonat kim loi ho tr 2 thu c 1,96 gam cht rn. Mui cacbonat ca kim loi dng l: A. FeCO3. B. BaCO3. C. MgCO3. D. CaCO3. Cu 5. Ho tan hon ton 0,575 gam mt kim loi km vo nc. trung ho dung dch thu c cn 25 gam dung dch HCl 3,65%. Kim loi ho tan l: A. Li. B. K. C. Na. D. Rb. Cu 6. Cho 9,1 gam hn hp hai mui cacbonat trung ho ca 2 kim loi kim 2 chu k lin tip tan hon ton trong dung dch HCl d thu c 2,24 lt CO2(ktc). Hai kim loi l: A. K v Cs. B. Na v K. C. Li v Na. D. Rb v Cs. Cu 7. Ho tan 1,3 gam mt kim loi M trong 100 ml dung dch H2SO4 0,3M. trung ho lng axit d cn 200 ml dung dch NaOH 0,1M. Xc nh kim loi M? A. Al. B. Fe. C. Zn. D. Mg. Cu 8. Lng kh clo sinh ra khi cho dung dch HCl c d tc dng vi 6,96 gam MnO2 oxi ho kim loi M (thuc nhm IIA), to ra 7,6 gam mui khan. Kim loi M l: A. Ba. B. Mg. C. Ca. D. Be.
Cu 9. Ho tan hon ton 2 gam kim loi thuc nhm IIA vo dung dch HCl v sau c cn dung dch ngi ta thu c 5,55 gam mui khan. Kim loi nhm IIA l: A. Be. B. Ba. C. Ca. D. Mg. Cu 10: Cho 1,67 gam hn hp gm hai kim loi 2 chu k lin tip thuc nhm IIA tc dng ht vi dung dch HCl (d), thot ra 0,672 lt kh H2 ( ktc). Hai kim loi l (Mg= 24, Ca= 40, Sr= 87, Ba = 137) A. Be v Mg. B. Mg v Ca. C. Sr v Ba. D. Ca v Sr. Cu 11. Khi in phn mui clorua kim loi nng chy, ngi ta thu c 0,896 lt kh (ktc) anot v 3,12 gam kim loi catot. Cng thc mui clorua in phn l A. NaCl. B. CaCl2. C. KCl. D. MgCl2. Cu 12. Cho 19,2 gam kim loi (M) tan hon ton trong dung dch HNO3 long th thu c 4,48 lt kh NO (ktc, sn phm kh duy nht). Kim loi (M) l: A. Cu. B. Zn. C. Fe. D. Mg. Dng 4: kim loi tc dng vi dung dch mui Cu 1. Ho tan 58 gam CuSO4. 5H2O vo nc c 500ml dung dch CuSO4. Cho dn dn mt st vo 50 ml dung dch trn, khuy nh cho ti khi dung dch ht mu xanh th lng mt st dng l: A. 0,65g. B. 1,2992g. C. 1,36g. D. 12,99g. Cu 2. Ngm mt inh st sch trong 200 ml dung dch CuSO4 sau khi phn ng kt thc, ly inh st ra khi dung dch ra nh lm kh nhn thy khi lng inh st tng thm 0,8 gam. Nng mol/lt ca dung dch CuSO4 dng l: A. 0,25M. B. 0,4M. C. 0,3M. D. 0,5M. Cu 3. Ngm mt l km vo dung dch c ho tan 8,32 gam CdSO4. Phn ng xong ly l km ra khi dung dch, ra nh, lm kh th thy khi lng l km tng thm 2,35% so vi khi lng l km trc phn ng. Khi lng l km trc phn ng l: A. 80gam B. 60gam C. 20gam D. 40gam Cu 4. Nhng mt inh st c khi lng 8 gam vo 500ml dung dch CuSO4 2M. Sau mt thi gian ly inh st ra cn li thy nng 8,8 gam. Nng mol/l ca CuSO4 trong dung dch sau phn ng l: A. 0,27M B. 1,36M C. 1,8M D. 2,3M Cu 5: Ngm l km trong dung dch cha 0,1 mol CuSO4. Phn ng xong thy khi lng l km: A. tng 0,1 gam. B. tng 0,01 gam. C. gim 0,1 gam. D. khng thay i. Cu 6: Ho tan hon ton 28 gam bt Fe vo dung dch AgNO3 d th khi lng cht rn thu c l A. 108 gam. B. 162 gam. C. 216 gam. D. 154 gam. Cu 7: Nhng 1 thanh nhm nng 50 gam vo 400ml dung dch CuSO 4 0,5M. Sau mt thi gian ly thanh nhm ra cn nng 51,38 gam. Hi khi lng Cu thot ra l bao nhiu? A. 0,64gam. B. 1,28gam. C. 1,92gam. D. 2,56gam. Cu 8: Ngm mt l Fe trong dung dch CuSO 4. Sau mt thi gian phn ng ly l Fe ra ra nh lm kh, em cn thy khi lng tng thm 1,6 gam. Khi lng Cu bm trn l Fe l bao nhiu gam? A. 12,8 gam. B. 8,2 gam. C. 6,4 gam. D. 9,6 gam. Cu 9: Ngm mt l km trong 100 ml dung dch AgNO 3 0,1M. Khi phn ng kt thc, khi lng l km tng thm A. 0,65 gam. B. 1,51 gam. C. 0,755 gam. D. 1,3 gam. Dng 5: Bi ton v nhit luyn Cu 1: Cho V lt hn hp kh ( ktc) gm CO v H2 phn ng vi mt lng d hn hp rn gm CuO v Fe3O4 nung nng. Sau khi cc phn ng xy ra hon ton, khi lng hn hp rn gim 0,32 gam. Gi tr ca V l A. 0,448. B. 0,112. C. 0,224. D. 0,560. Cu 2: Dn t t V lt kh CO ( ktc) i qua mt ng s ng lng d hn hp rn gm CuO, Fe2O3 ( nhit cao). Sau khi cc phn ng xy ra hon ton, thu c kh X. Dn ton b kh X trn vo lng d dung dch Ca(OH)2 th to thnh 4 gam kt ta. Gi tr ca V l A. 1,120. B. 0,896. C. 0,448. D. 0,224. Cu 3: Cho kh CO kh hon ton n Fe mt hn hp gm: FeO, Fe 2O3, Fe3O4 thy c 4,48 lt CO2 (ktc) thot ra. Th tch CO (ktc) tham gia phn ng l A. 1,12 lt. B. 2,24 lt. C. 3,36 lt. D. 4,48 lt. Cu 4: Thi mt lung kh CO i qua ng s ng m gam hn hp Fe 3O4 v CuO nung nng thu c 2,32 gam hn hp rn. Ton b kh thot ra cho hp th ht vo bnh ng dung dch Ca(OH) 2 d thu c 5 gam kt ta. Gi tr ca m l: A. 3,22 gam. B. 3,12 gam. C. 4,0 gam. D. 4,2 gam.
Cu 5: kh hon ton 30 gam hn hp CuO, FeO, Fe2O3, Fe3O4, MgO cn dng 5,6 lt kh CO ( ktc). Khi lng cht rn sau phn ng l A. 28 gam. B. 26 gam. C. 22 gam. D. 24 gam. Cu 6: Kh hon ton 17,6 gam hn hp X gm Fe, FeO, Fe 2O3 cn 2,24 lt CO ( ktc). Khi lng st thu c l A. 5,6 gam. B. 6,72 gam. C. 16,0 gam. D. 8,0 gam. Cu 7: Cho lung kh CO (d) i qua 9,1 gam hn hp gm CuO v Al 2O3 nung nng n khi phn ng hon ton, thu c 8,3 gam cht rn. Khi lng CuO c trong hn hp ban u l A. 0,8 gam. B. 8,3 gam. C. 2,0 gam. D. 4,0 gam. Cu 8. Cho dng kh CO d i qua hn hp (X) cha 31,9 gam gm Al 2O3, ZnO, FeO v CaO th thu c 28,7 gam hn hp cht rn (Y). Cho ton b hn hp cht rn (Y) tc dng vi dung dch HCl d thu c V lt H2 (kc). Gi tr V l A. 5,60 lt. B. 4,48 lt. C. 6,72 lt. D. 2,24 lt. Cu 9. kh hon ton 45 gam hn hp gm CuO, FeO, Fe 3O4, Fe v MgO cn dng va 8,4 lt CO (ktc). Khi lng cht rn thu c sau phn ng l: A. 39g B. 38g C. 24g D. 42g Dng 6: Bi ton v in phn dung dch Cu 1. Khi cho dng in mt chiu I=2A qua dung dch CuCl 2 trong 10 pht. Khi lng ng thot ra catod l A. 40 gam. B. 0,4 gam. C. 0,2 gam. D. 4 gam. Cu 2. in phn n ht 0,1 mol Cu(NO3)2 trong dung dch vi in cc tr, th sau in phn khi lng dung dch gim bao nhiu gam? A. 1,6 gam. B. 6,4 gam. C. 8,0 gam. D. 18,8 gam. Cu 3. in phn dng in cc tr dung dch mui sunfat kim loi ho tr 2 vi cng dng in 3A. Sau 1930 giy thy khi lng catot tng 1,92 gam. Mui sunfat in phn l A. CuSO4. B. NiSO4. C. MgSO4. D. ZnSO4. Cu 4. in phn hon ton 1 lt dung dch AgNO3 vi 2 in cc tr thu c mt dung dch c pH= 2. Xem th tch dung dch thay i khng ng k th lng Ag bm catod l: A. 0,54 gam. B. 0,108 gam. C. 1,08 gam. D. 0,216 gam. Cu 5: in phn 200 ml dung dch mui CuSO4 trong thi gian, thy khi lng dung dch gim 8 gam. Dung dch sau in phn cho tc dng vi dd H2S d thu c 9,6g kt ta en. Nng mol ca dung dch CuSO4 ban u l A. 1M. B.0,5M. C. 2M. D. 1,125M. Cu 6: in phn dung dch AgNO3 (in cc tr) trong thi gian 15 pht, thu c 0,432 gam Ag catot. Sau lm kt ta ht ion Ag+ cn li trong dung dch sau in phn cn dng 25 ml dung dch NaCl 0,4M. Cng dng in v khi lng AgNO3 ban u l (Ag=108) A. 0,429 A v 2,38 gam. B. 0,492 A v 3,28 gam. C. 0,429 A v 3,82 gam. D. 0,249 A v 2,38 gam. Cu 7: in phn 200 ml dung dch AgNO3 0,4M (in cc tr) trong thi gian 4 gi, cng dng in l 0,402A. Nng mol/l cc cht c trong dung dch sau in phn l A. AgNO3 0,15M v HNO3 0,3M. B. AgNO3 0,1M v HNO3 0,3M. C. AgNO3 0,1M D. HNO3 0,3M Cu 8: Sau mt thi gian in phn 200 ml dung dch CuCl 2 thu c 1,12 lt kh X ( ktc). Ngm inh st vo dung dch sau in phn, khi phn ng xy ra hon ton thy khi lng inh st tng thm 1,2 gam. Nng mol ca CuCl2 ban u l A. 1M. B. 1,5M. C. 1,2M. D. 2M. Cu 9: in phn bng in cc tr dung dch mui sunfat ca kim loi ho tr II vi dng in c cng 6A. Sau 29 pht in phn thy khi lng catot tng ln 3,45 gam. Kim loi l: A. Zn. B. Cu. C. Ni. D. Sn. Cu 10: in phn 400 ml dung dch CuSO 4 0,2M vi cng dng in 10A trong 1 thi gian thu c 0,224 lt kh (kc) anot. Bit in cc dng l in cc tr v hiu sut in phn l 100%. Khi lng catot tng l A. 1,28 gam. B. 0,32 gam. C. 0,64 gam. D. 3,2 gam.
Gii thiu kim tra
Gii thiu kim tra

Chng 1 & 2 ( ln I-HK I) S - 1 kim tra 15 pht- cacbohirat ( dnh cho i tng cc lp TB- yu)
Hy chn cu ng. 1. Mt trong nhng d kin thc nghim dng chng minh c cu to mch h ca glucoz l A. glucoz cho phn ng trng bc. B. glucoz c phn ng este ho. C. 1 mol glucoz chy sinh ra 6 mol CO2 v 6 mol H2O. D. khi c xc tc enzim, dung dch glucoz ln men to etanol. Mt cacbohirat (X) c cc phn ng din ra theo s sau :
Cu(OH)2 / OH t X dung dch xanh lam kt ta gch. Vy X khng th l A. glucoz. B. saccaroz. C. fructoz. D. mantoz.
o
2.
3.
4.
5.
Glucoz ha tan c Cu(OH)2 v glucoz A. c tnh axit. B. c nhiu nhm OH k nhau. C. c nhm CHO. D. c lin kt cng ho tr phn cc. Cht no sau y thuc loi isaccarit ? A. Glucoz. B. Tinh bt. C. Saccaroz. D. Xenluloz. Cacbohirat l A. hp cht a chc, c cng thc chung l (C6H10O5)n. B. hp cht tp chc, a s c cng thc chung l Cn(H2O)m. C. hp cht cha nhiu nhm hiroxil v nhm cacboxil.
6.
7.
D. hp cht a chc, a s c cng thc chung l Cn(H2O)m. Pht biu no di y khng chnh xc ? A. isaccarit l nhng cacbohirat khi thy phn u sinh ra hai loi monosaccarit. B. isaccarit l nhng cacbohirat khi thy phn sinh ra hai phn t monosaccarit. C. Polisaccarit l nhng cacbohirat khi thy phn sinh ra nhiu phn t monosaccarit. D. Tinh bt, mantoz v fructoz ln lt l polisaccarit, isaccarit v monosaccarit. Glucoz khng c tnh cht no di y ? A. Tnh cht ca nhm anehit. B. Tnh cht ancol a chc. C. Tham gia phn ng thy phn. D. Tc dng vi CH3OH trong HCl. Pht biu no di y v xenluloz l khng ng ? A. Xenluloz c trong cc loi rau, c, qu. B. Xenluloz c dng iu ch mt s loi t.
8.
Gii thiu kim tra
9.
10.
C. Xenluloz c dng lm nguyn liu sn xut ancol etylic. D. Xenluloz lm thc phm cho con ngi. Cho 3 kg glucoz c cha 10% tp cht ln men thnh ancol etylic. Trong qu trnh ch bin lng ancol b hao ht mt 10%. Khi lng ancol thu c l A. 1,242 kg. B. 1,533 kg. C. 1,423 kg. D. 1,380 kg. Pht biu no sau y khng ng ? A. Tinh bt phn ng vi dung dch iot cho mu xanh tm. B. T xenluloz c th iu ch t. C. Tinh bt c th tham gia phn ng trng gng. D. Xenluloz b thy phn thnh glucoz. 1 A 2 C 3 B 4 C 5 B 6 A 7 C 8 D 9 A 10 C
p n Cu p n
---------------------------------------------------------------------------------- S 02 KIM TRA 15 PHT - cacbohirat (Chng trnh chun) ( Dnh cho cc lp c bn)
Hy chn cu ng. 1. iu no sau y khng ng khi ni v xenluloz ? A. Tan trong dung dch nc Svay-de B. C th dng iu ch ancol etylic C. Dng sn xut t enang D. Phn ng vi hn hp HNO3 c v H2SO4 c 2. Glucoz v fructoz khng phn ng vi A. H2O (xc tc H+, to). C. Cu(OH)2. 3. B. H2 (xc tc Ni, to). D. dd AgNO3 / NH3.
Cho dy chuyn ho : X tinh bt glucoz Y. Cc cht X, Y ln lt l A. CO2 v C2H5OH. C. C2H5OH v CH3COOH. B. CH3OH v CO2. D. CH3CHO v C2H5OH.
4.
5.
Tnh cht no di y m saccaroz v glucoz khng ng thi c c ? A. Tnh cht ca ancol a chc. B. Tnh cht ca anehit. C. Phn ng chy. D. Tan tt trong nc. Lng kt ta Ag hnh thnh khi tin hnh trng gng hon ton dung dch cha 9 gam glucoz l A. 1,08 gam. B. 2,70 gam. C. 5,04 gam. D. 10,80 gam.
Gii thiu kim tra
6.
Cho dy chuyn ho :
2 4 ln men r u Y Glucoz X 170o C
H SO 98%
7.
8.
9.
10.
Ch xt sn phm chnh th Y trong dy chuyn ho trn l A. kh etilen. B. imetyl ete. C. ancol etylic. D. axit axetic. ng dng no sau y khng ng ? A. Trong cng nghip, ngi ta dng saccaroz trng gng. B. Dung dch saccaroz c truyn vo tnh mch cho ngi bnh. C. Xenluloz dng sn xut vi may mc. D. T g ngi ta sn xut ancol etylic. Cp cht no sau y u thuc loi isaccarit ? A. glucoz, mantoz. B. fructoz, saccaroz. C. saccaroz, mantoz. D. mantoz, xenluloz. Nhn nh no sau y khng ng ? A. Tinh bt c phn ng vi dung dch iot cho mu xanh tm. B. Xenluloz khng tham gia phn ng este ho. C. Tinh bt tham gia phn ng trng gng. D. Tinh bt d b thy phn thnh glucoz. Khi lng glucoz cn iu ch 0,1 lt ancol etylic (D = 0,8 g/ml) vi hiu sut 80% l A. 185,6 g. B. 196,5 g. C. 190 g. D. 200 g. 1 C 2 A 3 A 4 B 5 D 6 A 7 B 8 C 9 C 10 B
p n Cu p n
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Gii thiu kim tra
KIM TRA TIT LN I Khng kim tra tp trung- gio vin c th thit k theo cu trc sau * Ni dung kim tra : Chng 1 v chng 2 * kim tra gm 30 cu trc nghim * Ma trn theo yu cu ca BGH ( Bit 50%- Hiu 30%- Vn dng 20%) Bi c th - Este -Cht bo -Glucose -Tinh bt -Saccarose -Xenlulose Tng s cu Bit (50%) 4 2 3 2 2 2 15 Hiu(30%) 2 1 3 1 1 1 9 Vn dng(20%) 1 1 1 1 1 1 6 Tng s cu 7 4 7 4 4 4 30
* Ni dung : ( gio vin t thit k cu hi) tham kho
KIM TRA 1 TIT- KHI 12- LN 1- HK I- NH: 2012-2013 Cu 1: Lm bay hi hon ton 17,6 gam mt este n chc X thu c th tch hi ng bng 5,6 gam kh nit
trong cng iu kin nhit , p sut. Cng thc phn t ca X ( cho N=14, C=12, H=1, O=16) A. C3H4O3 B. C4H6O2 C. C2H4O2 D. C4H8O2
Cu 2: Cho 75 gam tinh bt ln men thnh ancol etylic vi hiu sut 60 %. Ton b lng kh sinh ra c hp
th hon ton vo dung dch Ca(OH) 2 ly d, thu c m gam kt ta. Gi tr ca m l ( cho Ca=40, C=12, H=1, O=16) A. 75,00 B. 154,32 C. 92,59 D. 55,55
Cu 3: Thy phn hon ton 42,75 g dung dch saccarose 20% trong mi trng axit (va ) c dd X. Cho
dd AgNO3/NH3 vo X un nh c m gam Ag. Gi tr ca m l ( cho Ag= 108, C=12, H=1, O=16) A. 54,00. B. 10,08. C. 5,40. D. 10,8.
Cu 4: Hp cht X c cng thc cu to CH3COOCH2CH3. Tn gi ca X l A. etyl axetat B. metyl axetat C. meyl propionat D. propyl axetat Cu 5: im ging nhau gia tinh bt v xenlulose: A. u l polime thin nhin v c chung cng thc phn t . B. u cho phn ng thu phn to thnh glucose C. u l thnh phn chnh ca go, bp, khoai, sn. D. A, B u ng Cu 6: Xenluloz trinitrat l cht d chy, n mnh, c iu ch t xenlulose v axit nitric c c xc tc
axit sunfuric c, nng. c 29,7 kg xenluloz trinitrat, cn dng m kg xenlulose ( hiu sut phn ng t 90%). Gi tr ca m l (cho H = 1, C =12, N = 14, O = 16) A. 21 B. 18 C. 14,58 D. 16,2
Cu 7: Thy phn X c sn phm gm glucose v fructose. X l A. Tinh bt B. Xenlulose C. Glucose Cu 8: Phn ng no sau y dng chng minh trong cng
D. Saccarose
thc cu to ca glucose c nhiu nhm OH k nhau ? A. Cho glucose tc dng vi H2, ( Ni xc tc, t0) B. Cho glucose tc dng vi Cu(OH)2 nhit thng to dung dch xanh lam. C. Cho glucose tc dng vi dung dch AgNO3/NH3, t0. D. Cho glucose tc dng vi dung dch nc Br2.
Gii thiu kim tra
Cu 9: Phn ng no ca glucose sau y khng chng minh c cha nhm andehyd? A. Phn ng ln men glucose to ra ancol etylic. B. Glucose phn ng vi dd AgNO3/NH3, to. C. Glucose phn ng vi H2 (Ni, t0). D. Glucose phn ng vi Cu(OH)2, khi un nng. Cu 10: iu khng nh no sau y khng ng? A. X phng l hn hp mui natri hoc kali ca cc axit bo c thm cht ph gia. B. X phng c tnh nng git ra l do n c tc dng l gim sc cng b mt ca cc vt bn. C. u im ca x phng l c th git ra ngay c trong nc cng. D. Tt c A, B v C. Cu 11: phn bit tinh bt v xenlulose, ngi ta dng phn ng: A. Phn ng mu vi iod B. Trng gng C. Thu phn D. A, B, C u sai Cu 12: Chn pht biu sai khi ni v tnh cht ca glucose. A. Glucose l cht rn, kt tinh. B. Glucose d tan trong nc , v ngt nhng km hn ng ma. C. Glucose c trong hu ht cc b phn ca cy, c nhiu trong qu nho. D. Glucose cn gi l ng ha hc. Cu 13: trung ha lng axit t do c trong 14 gam cht bo cn 15 ml dung dch KOH 0,1M. Ch s axit
ca cht bo l ( C=12, H=1, O=16, K=39) A. 7 B. 8
C. 6
D. 5
Cu 14: Cho m gam
glucose ln men thnh ancol etylic vi hiu sut 90%. Hp th hon ton kh CO 2 sinh ra vo dung dch nc vi trong d th thu c 10 gam kt ta. Gi tr ca m l ( cho Ca=40, C=12, H=1, O=16, Ca=40) A. 8,10. B. 10,0. C. 9,00. D. 7,29.
Cu 15: Cht bo l: A. Trieste ca glixerol vi cc axit bo B. Este ca glixerol vi cc axit cacboxylic C. Trieste ca glixerol vi cc axit tricacboxylic D. ieste ca glixerol vi cc axit bo. Cu 16: iu khng nh no sau y khng ng? A. Glucose v fructose l 2 cht ng phn ca nhau. B. Glucose v fructose u tham gia phn ng trng gng. C. Glucose v fructose u lm mt mu nc brom. D. Glucoz v fructose u tham gia phn ng cng H2 (Ni/t0). Cu 17: Cht bo tham gia phn ng thy phn v phn ng x phng ha. Vy phn ng no nhanh hn v
khng thun nghch? A. Hai phn ng u thun nghch. C. Phn ng x phng ha
B. Hai phn ng xy ra vi tc ngang nhau. D. Phn ng thy phn
Cu 18: Glucose v fructose tc dng vi cht no sau y to ra cng mt sn phm ? A. ng (II) hidroxit B. Hidro ( xt Ni, to) C. Kali D. Bc nitrat trong nc
amoniac
Cu 19:
Khi thy phn 85,5 gam saccarose trong mi trng axit, thu c m gam hn hp glucose v fructose. Bit rng hiu sut phn ng l 90%. Gi tr ca m l ( cho Ca=40, C=12, H=1, O=16) A. 90 B. 81 C. 100 D. 270
Cu 20: Thy phn este E c cng thc phn t C 4H8O2 (c mt ca axit H2SO4 long) thu c 2 sn phm
hu c A v B. T A c th iu ch trc tip ra B bng mt phn ng duy nht. Tn gi ca A l A. metyl propionat B. propyl fomat C. ancol etylic D. etyl axetat
Cu 21: Thy phn hon ton 2,2 gam este no, n chc, mch h X vi 250 ml dung dch NaOH 0,1M va
thu c 2,4 gam mui. Tn gi ca X l ( cho Na=23, C=12, H=1, O=16) A. metyl propionat B. iso proyl fomat. C. etyl propionat
D. n-propyl fomat
Cu 22: Cho s chuyn ha sau: Tinh bt A. glucoz, etyl axetat. C. ancol etylic, andehit axetic.
AB axit axetic. A v B ln lt l B. glucose, ancol etylic. D. glucoz, andehyd axetic
Gii thiu kim tra
Cu 23: Xa phong hoa 66,6 gam hn hp 2 este la HCOOC 2H5 va CH3COOCH3 a dung ht V ml NaOH 2M.
Tnh V ? ( cho Na=23, C=12, H=1, O=16) A. 300ml B. 450ml
C. 150ml
D. 100ml
Cu 24: Trong mn ca, v bo c cha hp cht no sau y? A. Xenlulose B. Tinh bt C. Saccarose D. Glucose Cu 25: Cht git ra tng hp (bt git) c u im g so vi x phng? A. Cht git ra tng hp s dng c ngay c trong nc cng. B. Cht git ra tng hp b cc vi sinh vt phn hy. C. Cht git ra tng hp khng gy hi cho mi trng. D. Tt c A, B v C u ng. Cu 26: un nng dung dch cha 6,75 gam glucose vi AgNO 3/NH3, gi s hiu sut phn ng l 75% thy
Ag kim loi tch ra. Khi lng Ag kim loi thu c l ( cho Ca=40, C=12, H=1, O=16, Ag= 108) A. 10,8 gam. B. 6,075 gam. C. 24,3 gam. D. 8,1 gam.
Cu 27: Khi thy phn cht bo trong dung dch NaOH, thu c glixerol v hn hp hai mui C 17H35COONa,
C15H31COONa c khi lng hn km nhau 2,201 ln. Trong phn t X c ( cho Na=23, C=12, H=1, O=16) A. 3 gc C15H31COO B. 3 gc C17H35COO C. 2 gc C15H31COO D. 2 gc C17H35COO
Cu 28: Dy gm cc dung dch u tc dng vi Cu(OH)2 l A. glucoz, glixerol, ancol metylic, xenlulose. B. tinh bt, glucoz, glixerol, natri axetat. C. fructose, glucose, glixerol, axit fomic, saccarose. D. glucose, glixerol, anehit fomic, etyl axetat. Cu 29: S ng phn este ng vi cng thc phn t C3H6O2 l A. 4. B. 3. C. 5. Cu 30: Cho cc hp cht hu c sau : glucose, saccarose, fructose,
propionic. C bao nhiu cht khng tham gia phn ng trng gng ? A. 1 cht B. 2 cht C. 3 cht
D. 2.
tinh bt, glyxerol, etyl fomat, axit
D. 4 cht
10 C 25 A 11 A 26 B 12 D 27 D 13 C 28 C 14 B 29 D 15 A 30 D
P N Cu 1 p D n Cu 16 p C n
2 D 17 C
3 D 18 B
4 A 19 B
5 D 20 C
6 B 21 A
7 D 22 B
8 B 23 B
9 A 24 A
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Gii thiu kim tra
Chng 3 & 4: AMIN-AMINO AXIT- PEPTIT-PROTEIN-POLIME KIM TRA 15 PHT

S 01- ( dnh cho lp TB-Yu) Hy chn cu ng. 1. Phenol v anilin cng phn ng vi A. dung dch H2SO4. C. Na. 2. 3. B. dung dch NaOH. D. dung dch HNO3 c. D. N-metyletanamin.
Tn thay th ca CH3CH2NHCH3 l A. propylamin. B. etylmetylamin. C. metyletylamin. Amin bc II l amin B. c 2 nhm NH2 trong phn t.
A. c to thnh khi thay th 2 nguyn t H trong NH3 bng 2 gc hirocacbon. C. c 2 nhm NH2 gn vo cng nguyn t C. D. c nhm NH2 gn vo cng nguyn t C bc II. 4. Tn gi no sau y khng ng cho hp cht thm c cng thc C6H5NH2 ? A. Phenylamin B. N-Metylanilin C. Benzenamin D. Anilin Anilin khng tc dng vi A. NH3. C. dung dch HCl. 6. B. dung dch Br2. D. HNO2/HCl ( 0 oC 5oC).
5.
Dy no sau y c sp xp theo chiu tng dn tnh baz ? A. (CH3)2NH < CH3NH2 < C6H5NH2 < NH3 B. CH3NH2 < (CH3)2NH < C6H5NH2 < NH3 C. C6H5NH2 < NH3 < CH3NH2 < (CH3)2NH D. CH3NH2 < (CH3)2NH < NH3 < C6H5NH2
7. 8.
Cng thc C3H9N ng vi s ng phn : A. 3. B. 4. C. 5. D. 2. Tnh cht no sau y khng ng cho protein ? A. ng t khi un nng hay gp axit v kim. B. Thu phn khi un nng vi dung dch axit, baz. C. To kt ta vng vi HNO3 c. D. Tc dng vi dung dch CuSO4 to thnh dung dch c mu tm.
9.
Trong 4 cht : NH2CH2COOH, ClNH3CH2COOCH3, C6H5NH2, Br3C6H2NH2. Cht tan nhiu nht trong nc l A. NH2CH2COOH. B. C6H5NH2. C. ClNH3CH2COOCH3. D. Br3C6H2NH2. Cho hp cht : NH2CH2CONHCH(CH3)CONHCH2COOH. Tn gi c vit gn ca cht ny l A. Gly-Ala-Gly B. Ala-Gly-Gly C. Gly-Gly-Ala D. Gly-Gly-Gly 1 D 2 D 3 A 4 B 5 A 6 C 7 B 8 D 9 A 10 A
10.
p n Cu p n
Gii thiu kim tra
( cho cc lp c bn )
KIM TRA 15 PhT Chng trnh chun

1. Phenol v anilin u phn ng vi A. dung dch HCl. B. dung dch NaOH. C. Na. 2. 3. D. dung dch Br2. D. butan-1-amin Tn thay th ca CH3CH2CH2CH2NH2 l A. butylamin B. butyl-1-amin C. butan-1-amino Dy c sp xp theo chiu tng dn tnh baz l : A. (CH3)2NH < CH3NH2 < C6H5NH2 < NH3 B. CH3NH2 < (CH3)2NH < C6H5NH2 < NH3 C. C6H5NH2 < NH3 < CH3NH2 < (CH3)2NH D. CH3NH2 < (CH3)2NH < NH3 < C6H5NH2 4. 5. S ng phn amin bc 2 ca hp cht C4H11N l A. 4. B. 2. C. 5. D. 3. Pht biu no sau y ng ? A. Khi thay th nguyn t H trong amoniac bng gc hirocacbon ta c amin. B. Amin la hp cht hu c c cha mt hay nhiu nguyn t nit. C. Cng thc tng qut ca amin no, n chc, mch h l CnH2n+2N. D. Bc ca amin l bc ca nguyn t cacbon lin kt trc tip vi nhm amin. 6. 7. Bc ca amin (C2H5)2NC6H5 l A. I. B. II. C. III. D. II v I. t chy hon ton hn hp 2 amin no, n chc, mch h, ng ng lin tip thu c 0,1 mol kh CO2 va 0,2 mol H2O. Cng thc ca 2 amin l A. CH3NH2 v C2H5NH2. B. C2H5NH2 v C3H7NH2. 8. A. H2NCH2COOH. C. H3N CH2COO . 9.
+
C. C3H7NH2 v C4H9NH2. D. C4H9NH2 v C5H11NH2. B. H3NCH2COO. D. H2N+CH2COO.
Trong dung dch, glyxin ch yu tn ti dng
10.
Cho hn hp gm 0,05 mol metylamin v 0,1 mol anilin phn ng vi dung dch HCl d. Khi lng cht rn thu c sau khi c cn dung dch l A. 19,25 gam. B. 3,375 gam. C. 16,325 gam. D. 19,825 gam. S lng tripeptit c to thnh t glyxin v alanin l A. 3. B. 4. C. 5. D. 6. 1 D 2 D 3 C 4 D 5 A 6 C 7 A 8 C 9 C 10 D
p n Cu p n
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Gii thiu kim tra
KIM TRA TIT LN II Kim tra tp trung ton khi lp 12 * Ni dung kim tra : Chng 2- AMIN-AMINO AXIT-PEPTIT PROTEIN Chng 3-POLIME * kim tra gm 30 cu trc nghim * Ma trn theo yu cu ca BGH ( Bit 50%- Hiu 30%- Vn dng 20%)
Bi c th - Amin -Amino axit -Peptit, protein -i cng v polime -Vt liu polime Tng s cu Bit (50%) 3 3 3 3 3 15 Hiu (30%) 2 1 3 2 1 9 Vn dng (20%) 1 2 0 1 2 6 Tng s cu 6 6 6 6 6 30
* Ni dung mu
GC
Amin ( 6 cu) Bit (3) Cu 1. Anilin c cng thc l A. CH3COOH. B. C6H5OH. C. C6H5NH2. D. CH3OH. [ ] Cu 2. Trong cc tn gi di y, tn no ph hp vi cht CH3CH(CH3)NH2? A. Metyletylamin. B. Etylmetylamin. C. Isopropanamin. D. Isopropylamin. [ ] Cu 3. Trong cc cht sau, cht no l amin bc 2? A. H2N-[CH2]6NH2 B. CH3CH(CH3)NH2 C. CH3NHCH3 D. C6H5NH2 [ ] Hiu (2) Cu 4. C 3 cht lng benzen, anilin, stiren, ng ring bit trong 3 l mt nhn. Thuc th phn bit 3 cht lng trn l A. dung dch phenolphtalein. B. nc brom. C. dung dch NaOH. D. giy qu tm. [ ] Cu 5. Dy gm cc cht c xp theo chiu tnh baz gim dn t tri sang phi l A. CH3NH2, NH3, C6H5NH2. B. CH3NH2, C6H5NH2, NH3. C. C6H5NH2, NH3, CH3NH2. D. NH3, CH3NH2, C6H5NH2. [ ] Vn dng (1) Cu 6. Cho 4,5 gam etylamin (C2H5NH2) tc dng va vi axit HCl. Khi lng mui thu c l A. 7,65 gam. B. 8,15 gam. C. 8,10 gam. D. 0,85 gam. [ ] Amino axit ( 6 cu) Bit (3) Cu 1. Amino axit l hp cht hu c trong phn t A. cha nhm cacboxyl v nhm amino. B. ch cha nhm amino. C. ch cha nhm cacboxyl. D. ch cha nit hoc cacbon. [ ] Cu 2. Trong cc cht di y, cht no l glixin? A. H2N-CH2-COOH B. CH3CH(NH2)COOH C. HOOC-CH2CH(NH2)COOH D. H2NCH2-CH2COOH [ ] Cu 3. Cht X va tc dng c vi axit, va tc dng c vi baz. Cht X l A. CH3COOH. B. H2NCH2COOH. C. CH3CHO. D. CH3NH2. [ ] Hiu (1) Cu 4. Cho dy cc cht: C6H5NH2 (anilin), H2NCH2COOH, CH3CH2COOH, CH3CH2CH2NH2, C6H5OH (phenol). S cht trong dy tc dng c vi dung dch HCl l A. 4. B. 2. C. 3. D. 5. Vn dng (2)
Gii thiu kim tra
Cu 5. Mt - amino axit X ch cha 1 nhm amino v 1 nhm cacboxyl. Cho 10,68 gam X tc dng vi HCl d thu c 15,06 gam mui. Tn gi ca X l A. axit glutamic. B. valin. C. alanin. D. glixin [ ] Cu 6. Este A c iu ch t -amino axit v ancol metylic. T khi hi ca A so vi hidro bng 44,5. Cng thc cu to ca A l: A. CH3CH(NH2)COOCH3. B. H2N-CH2CH2-COOH C. H2NCH2COOCH3. D. H2NCH2CH(NH2)COOCH3. [ ] Peptit protein (6) Bit (3) Cu 1. Tripeptit l hp cht A. m mi phn t c 3 lin kt peptit. B. c lin kt peptit m phn t c 3 gc amino axit ging nhau. C. c lin kt peptit m phn t c 3 gc amino axit khc nhau. D. c 2 lin kt peptit m phn t c 3 gc -amino axit. [ ] Cu 2. Sn phm cui cng ca qu trnh thy phn cc protein n gin nh cht xc tc thch hp l A. -aminoaxit. B. -aminoaxit. C. axit cacboxylic. D. este. [ ] Cu 3. S ng phn ipeptit to thnh t 1 phn t glyxin v 1 phn t alanin l A. 3. B. 1. C. 2. D. 4. Hiu (3) Cu 4. Thy phn tng phn mt pentapeptit thu c cc ipeptit v tripeptit sau : Gly-Ala ; Val-Glu ; Ala-Val ; Glu-Phe ; Ala-Val-Glu. Trnh t ca cc aminoaxit trong pentapeptit trn l : A. Ala - Val - Glu - Gly - Phe. B. Val - Glu - Phe - Gly - Val. C. Gly - Ala - Val - Glu - Phe. D. Gly - Ala - Glu - Phe - Val. [ ] Cu 5. phn bit c cc dung dch : glucoz, glixerol, h tinh bt v lng trng trng, ta dng A. Cu(OH)2 c thm dung dch NaOH. B. dung dch HNO3 c v dung dch AgNO3 trong NH3. C. dung dch I2 v dung dch HNO3 c. D. dung dch I2 v dung dch AgNO3 trong NH3. [ ] Cu 6. Trong cc cht di y, cht no l ipeptit ? A. H2N-CH2-CO-NH-CH2-CH2-COOH. B. H2N-CH2-CO-NH-CH(CH3)-COOH. C. H2N-CH2-CO-NH-CH(CH3)-CO-NH-CH2-COOH. D. H2N-CH(CH3)-CO-NH-CH2-CO-NH-CH(CH3)-COOH [ ] i cng v polime(6) Bit (3) Cu 1. Qu trnh nhiu phn t nh (monome) kt hp vi nhau thnh phn t ln (polime) ng thi gii phng nhng phn t nc gi l phn ng A. nhit phn. B. trao i. C. trng hp. D. trng ngng. [ ] Cu 2.Polivinyl clorua c cng thc l A. (-CH2-CHCl-)2. B. (-CH2-CH2-)n. C. (-CH2-CHBr-)n. D. (-CH2-CHF-)n. [ ] Cu 3. Cht tham gia phn ng trng hp to ra polime l A. CH3-CH2-Cl. B. CH3-CH3. C. CH2=CH-CH3. D. CH3-CH2-CH3. [ ] Hiu (2) Cu 4. Cho cc polime sau: (-CH2 CH2-)n ; (- CH2- CH=CH- CH2-)n ; (- NH-CH2 -CO-)n Cng thc ca cc monome khi trng hp hoc trng ngng to ra cc polime trn ln lt l A. CH2=CHCl, CH3-CH=CH-CH3, CH3- CH(NH2)- COOH. B. CH2=CH2, CH2=CH-CH= CH2, NH2- CH2- COOH. C. CH2=CH2, CH3- CH=C= CH2, NH2- CH2- COOH. D. CH2=CH2, CH3- CH=CH-CH3, NH2- CH2- CH2- COOH. [ ] Cu 5. C cc polime thin nhin: tinh bt (C6H10O5)n; cao su isopren (C5H8)n; t tm (NH-R-CO)-n. Polime thin nhin no trong s cc polime c th l sn phm ca phn ng trng hp ? A. Tinh bt (C6H10O5)n B. T tm C. Tinh bt; cao su isopren D. Cao su isopren [ ] Vn dng (1) Cu 6. Phn t khi trung bnh ca polietilen X l 420000. H s polime ho ca PE l A. 12.000 B. 13.000 C. 15.000 D. 17.000 [ ]
Gii thiu kim tra
Vt liu polime(6) Bit (3) Cu 1. Polime dng ch to thu tinh hu c (plexiglas) c iu ch bng phn ng trng hp A. CH2=C(CH3)COOCH3. B. CH2 =CHCOOCH3. C. C6H5CH=CH2. D. CH3COOCH=CH2 [ ] Cu 2. Cng thc phn t ca cao su thin nhin A. ( C5H8)n B. ( C4H8)n C. ( C4H6)n D. ( C2H4)n [ ] Cu 3. Trong cc loi t di y, t nhn to l A. t visco. B. t capron. C. t nilon -6,6. D. t tm. [ ] Hiu (1) Cu 4. Trong s cc polime sau y; t tm, si bng, len, t enang, t visco, nilon 6-6, t axetat. Loi t c ngun gc xenluloz l: A. t tm, si bng, nilon 6-6. B. si bng, len, t axetat. C. si bng, len, nilon 6-6. D. t visco, nilon 6-6, t axetat. [ ] Vn dng (2) Cu 5. Khi clo ha PVC ta thu c mt loi t clorin cha 63,96%. Trung bnh 1 phn t clo tc dng vi bao nhiu mt xch PVC? A. 1 B. 2 C. 3 D. 4 [ ] Cu 6. tng hp 120 kg poli(metyl metacrylat) vi hiu sut ca qu trnh ho este l 60% v qu trnh trng hp l 80% th cn cc lng axit v ancol tng ng l A. 215 kg axit v 80 kg ancol C. 85 kg axit v 40 kg ancol B. 49,356 kg axit v 18,432 kg ancol D. 80 kg axit v 215 kg ancol [ ]
HON V T GC (132-209-303-405)
Trng THPT Chu Thnh KIM TRA MT TIT LN 2 MN HA HC Thi gian lm bi: 45 pht; (30 cu trc nghim) M thi 132 H, tn th sinh:.......................................................................... S bo danh:............................................................................... Cu 1: C 3 cht lng benzen, anilin, stiren, ng ring bit trong 3 l mt nhn. Thuc th phn bit 3 cht lng trn l A. dung dch NaOH. B. giy qu tm. C. nc brom. D. dung dch phenolphtalein. Cu 2: Trong s cc polime sau y; t tm, si bng, len, t enang, t visco, nilon 6-6, t axetat. Loi t c ngun gc xenluloz l: A. t tm, si bng, nilon 6-6. B. t visco, nilon 6-6, t axetat. C. si bng, len, nilon 6-6. D. si bng, len, t axetat. Cu 3: tng hp 120 kg poli(metyl metacrylat) vi hiu sut ca qu trnh ho este l 60% v qu trnh trng hp l 80% th cn cc lng axit v ancol tng ng l A. 85 kg axit v 40 kg ancol. B. 49,356 kg axit v 18,432 kg ancol. C. 80 kg axit v 215 kg ancol. D. 215 kg axit v 80 kg ancol. Cu 4: Trong cc tn gi di y, tn no ph hp vi cht CH 3CH(CH3)NH2? A. Isopropanamin. B. Metyletylamin. C. Etylmetylamin. D. Isopropylamin. Cu 5: Phn t khi trung bnh ca polietilen X l 420000. H s polime ho ca PE l A. 12.000 B. 13.000 C. 15.000 D. 17.000 Cu 6: Trong cc loi t di y, t nhn to l A. t visco. B. t capron. C. t nilon -6,6. D. t tm. Cu 7: Polivinyl clorua c cng thc l A. (-CH2-CHBr-)n. B. (-CH2-CHF-)n. C. (-CH2-CH2-)n. D. (-CH2-CHCl-)2. Cu 8: Thy phn tng phn mt pentapeptit thu c cc ipeptit v tripeptit sau : Gly-Ala ; Val-Glu ; Ala-Val ; Glu-Phe ; Ala-Val-Glu. Trnh t ca cc aminoaxit trong pentapeptit trn l : A. Ala - Val - Glu - Gly - Phe. B. Val - Glu - Phe - Gly - Val. C. Gly - Ala - Val - Glu - Phe. D. Gly - Ala - Glu - Phe - Val.
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Cu 9: Sn phm cui cng ca qu trnh thy phn cc protein n gin nh cht xc tc thch hp l A. -aminoaxit. B. -aminoaxit. C. axit cacboxylic. D. este. Cu 10: Mt - amino axit X ch cha 1 nhm amino v 1 nhm cacboxyl. Cho 10,68 gam X tc dng vi HCl d thu c 15,06 gam mui. Tn gi ca X l A. axit glutamic. B. valin. C. alanin. D. glixin Cu 11: Cho cc polime sau: (-CH2 CH2-)n ; (- CH2- CH=CH- CH2-)n ; (- NH-CH2 -CO-)n Cng thc ca cc monome khi trng hp hoc trng ngng to ra cc polime trn ln lt l A. CH2=CH2, CH3- CH=C= CH2, NH2- CH2- COOH. B. CH2=CH2, CH3- CH=CH-CH3, NH2- CH2- CH2- COOH. C. CH2=CH2, CH2=CH-CH= CH2, NH2- CH2- COOH. D. CH2=CHCl, CH3-CH=CH-CH3, CH3- CH(NH2)- COOH. Cu 12: S ng phn ipeptit to thnh t 1 phn t glyxin v 1 phn t alanin l A. 3. B. 1. C. 2. D. 4. Cu 13: Cho dy cc cht: C6H5NH2 (anilin), H2NCH2COOH, CH3CH2COOH, CH3CH2CH2NH2, C6H5OH (phenol). S cht trong dy tc dng c vi dung dch HCl l A. 3. B. 5. C. 4. D. 2. Cu 14: Trong cc cht di y, cht no l ipeptit ? A. H2N-CH2-CO-NH-CH(CH3)-CO-NH-CH2-COOH. B. H2N-CH(CH3)-CO-NH-CH2-CO-NH-CH(CH3)-COOH C. H2N-CH2-CO-NH-CH2-CH2-COOH. D. H2N-CH2-CO-NH-CH(CH3)-COOH. Cu 15: Trong cc cht di y, cht no l glixin? A. HOOC-CH2CH(NH2)COOH B. H2N-CH2-COOH C. CH3CH(NH2)COOH D. H2NCH2-CH2COOH Cu 16: phn bit c cc dung dch : glucoz, glixerol, h tinh bt v lng trng trng, ta dng A. Cu(OH)2 c thm dung dch NaOH. B. dung dch HNO3 c v dung dch AgNO3 trong NH3. C. dung dch I2 v dung dch HNO3 c. D. dung dch I2 v dung dch AgNO3 trong NH3. Cu 17: Cht X va tc dng c vi axit, va tc dng c vi baz. Cht X l A. CH3NH2. B. CH3CHO. C. CH3COOH. D. H2NCH2COOH. Cu 18: Tripeptit l hp cht A. m mi phn t c 3 lin kt peptit. B. c 2 lin kt peptit m phn t c 3 gc -amino axit. C. c lin kt peptit m phn t c 3 gc amino axit ging nhau. D. c lin kt peptit m phn t c 3 gc amino axit khc nhau. Cu 19: Cht tham gia phn ng trng hp to ra polime l A. CH3-CH3. B. CH3-CH2-Cl. C. CH2=CH-CH3. D. CH3-CH2-CH3. Cu 20: Trong cc cht sau, cht no l amin bc 2? A. CH3CH(CH3)NH2 B. CH3NHCH3 C. H2N-[CH2]6NH2 D. C6H5NH2 Cu 21: Dy gm cc cht c xp theo chiu tnh baz gim dn t tri sang phi l A. CH3NH2, NH3, C6H5NH2. B. NH3, CH3NH2, C6H5NH2. C. CH3NH2, C6H5NH2, NH3. D. C6H5NH2, NH3, CH3NH2. Cu 22: C cc polime thin nhin: tinh bt (C 6H10O5)n; cao su isopren (C5H8)n; t tm (NH-R-CO)-n. Polime thin nhin no trong s cc polime c th l sn phm ca phn ng trng hp ? A. Tinh bt (C6H10O5)n B. T tm C. Tinh bt; cao su isopren D. Cao su isopren Cu 23: Amino axit l hp cht hu c trong phn t A. ch cha nit hoc cacbon. B. cha nhm cacboxyl v nhm amino. C. ch cha nhm amino. D. ch cha nhm cacboxyl. Cu 24: Polime dng ch to thu tinh hu c (plexiglas) c iu ch bng phn ng trng hp A. CH2=C(CH3)COOCH3. B. CH2 =CHCOOCH3. C. C6H5CH=CH2. D. CH3COOCH=CH2 Cu 25: Este A c iu ch t -amino axit v ancol metylic. T khi hi ca A so vi hidro bng 44,5. Cng thc cu to ca A l: A. CH3CH(NH2)COOCH3. B. H2NCH2COOCH3. C. H2NCH2CH(NH2)COOCH3. D. H2N-CH2CH2-COOH
Gii thiu kim tra
Cu 26: Qu trnh nhiu phn t nh (monome) kt hp vi nhau thnh phn t ln (polime) ng thi gii phng nhng phn t nc gi l phn ng A. trao i. B. nhit phn. C. trng ngng. D. trng hp. Cu 27: Cho 4,5 gam etylamin (C2H5NH2) tc dng va vi axit HCl. Khi lng mui thu c l A. 0,85 gam. B. 8,15 gam. C. 8,10 gam. D. 7,65 gam. Cu 28: Khi clo ha PVC ta thu c mt loi t clorin cha 63,96%. Trung bnh 1 phn t clo tc dng vi bao nhiu mt xch PVC? A. 1 B. 2 C. 3 D. 4 Cu 29: Anilin c cng thc l A. C6H5OH. B. C6H5NH2. C. CH3COOH. D. CH3OH. Cu 30: Cng thc phn t ca cao su thin nhin A. ( C5H8)n B. ( C4H8)n C. ( C4H6)n D. ( C2H4)n
---------------------------------------------------------- HT ---------p n kim tra mu Cu 1 2 3 4 5 6 7 8 9 p C D D D C A D C A n Cu 16 17 18 19 20 21 22 23 24 p A D B C B A D B A n
10 C 25 B
11 C 26 C
12 C 27 B
13 A 28 C
14 D 29 B
15 B 30 A
--------------------------------------------------------------------------------------------------
THI HC K I
thi hc k I- tp trung ton khi lp 12 * Ni dung kim tra : Chng 1- Ester Chng 2- Cacbodrat Chng 4- Amin-amino axit Chng 5-Polime Chng 6-i cng v kim loi ( cha kim tra ln no) * kim tra gm 30 cu trc nghim * Ma trn theo yu cu ca BGH ( Bit 50%- Hiu 30%- Vn dng 20%) Bi c th - Ester -Cacbodidrat -Amin, amino axit -Polime -i cng v KL Tng s cu * thi mu (ang lm sau) Bit (50%) 3 2 3 2 5 15 Hiu (30%) 1 2 1 2 3 9 Vn dng (20%) 1 1 1 1 2 6 Tng s cu 5 5 5 5 10 30 Ghi ch
Kim tra ln 1 Kim tra ln 1 Kim tra ln 2 Kim tra ln 2 Cha kim tra

De Cuong On Tap Mon Hoa Hoc HKI 1

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De Cuong On Tap Mon Hoa Hoc HKI 1

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TRNG THPT CHU THNH

Cng thc tnh nhanh

Mt s cng thc thng p dng

+ Tnh s mol (n) =

+ S tnh mol ( n) cht kh ktc :=

+ Tnh nng mol/l ( CM) =

Chng 1- ESTER- CHT BO

CHNG 1: ESTE - CHT BO

Chng 1- ESTER- CHT BO

Chng 1- ESTER- CHT BO

Chng 1- ESTER- CHT BO

cng n tp mn Ha hc lp 12 - Nm hc 2012-2013 PEPTIT_PROTEIN

CHNG 3: AMIN - AMINOAXIT - PEPTIT PROTEIN AMIN - ANILIN

+HNO3 C H NO + [H] 6 5 2 C6H5NH2( anilin) ( Fe+HCl) (H2SO4 c, xt)

cng n tp mn Ha hc lp 12 - Nm hc 2012-2013 PEPTIT_PROTEIN

cng n tp mn Ha hc lp 12 - Nm hc 2012-2013 PEPTIT_PROTEIN

cng n tp mn Ha hc lp 12 - Nm hc 2012-2013 PEPTIT_PROTEIN

AMINOAXIT PEPTIT PROTEIN

cng n tp mn Ha hc lp 12 - Nm hc 2012-2013 PEPTIT_PROTEIN

cng n tp mn Ha hc lp 12 - Nm hc 2012-2013 PEPTIT_PROTEIN

cng n tp mn Ha hc lp 12 - Nm hc 2012-2013 PEPTIT_PROTEIN

Chng 4-POLIME-VAT LIEU POLIME

CHNG 4: POLIME - VT LIU POLIME

Chng 4-POLIME-VAT LIEU POLIME

b/ keo dn epoxi: lm t polime c cha nhm epoxi

Chng 4-POLIME-VAT LIEU POLIME

Chng 4-POLIME-VAT LIEU POLIME

Chng 5-I CNG V KIM LOI

CHNG 5: I CNG KIM LOI

Chng 5-I CNG V KIM LOI

Chng 5-I CNG V KIM LOI

Chng 5-I CNG V KIM LOI

Chng 5-I CNG V KIM LOI

Chng 5-I CNG V KIM LOI

Chng 5-I CNG V KIM LOI

Chng 5-I CNG V KIM LOI

Chng 5-I CNG V KIM LOI

Chng 5-I CNG V KIM LOI

Chng 5-I CNG V KIM LOI

Gii thiu kim tra

Gii thiu kim tra

Gii thiu kim tra

Gii thiu kim tra

Gii thiu kim tra

* Ni dung : ( gio vin t thit k cu hi) tham kho

Gii thiu kim tra

Cu 14: Cho m gam

B. Hai phn ng xy ra vi tc ngang nhau. D. Phn ng thy phn

AB axit axetic. A v B ln lt l B. glucose, ancol etylic. D. glucoz, andehyd axetic

Gii thiu kim tra

Gii thiu kim tra

Chng 3 & 4: AMIN-AMINO AXIT- PEPTIT-PROTEIN-POLIME KIM TRA 15 PHT

Gii thiu kim tra

KIM TRA 15 PhT Chng trnh chun

C. C3H7NH2 v C4H9NH2. D. C4H9NH2 v C5H11NH2. B. H3NCH2COO. D. H2N+CH2COO.

Trong dung dch, glyxin ch yu tn ti dng

Gii thiu kim tra

Gii thiu kim tra

Gii thiu kim tra

Gii thiu kim tra

Gii thiu kim tra

---------------------------------------------------------- HT ---------p n kim tra mu Cu 1 2 3 4 5 6 7 8 9 p C D D D C A D C A n Cu 16 17 18 19 20 21 22 23 24 p A D B C B A D B A n

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