1.

Xc nh phn mol ca dung dch cha 20% A (M = Trn 200g hn hp gm 3 cht A,B,C cha 20% A, - Lp th nht c khi lng 60g, v bao gm 50%A v 20%B - Lp th hai cha 80%B, 10g A, 18g C Hy xc nh im biu din ca ba cu t A, B, C trn gin
80

46), 30% B (M =18) v 50% C ( M = 60 ) v khi lng.

2.

khi cn bng hn hp chia lm hai lp

A
10 0 20

tam gic u trong hai lp trn

60 I

J 40

%C

3.

Cho gin pha ca h 3 cu t ( P hnh bn). Xc nh thnh phn ca A, B, C B 100 80 Q 60 H 40 %B khi im h chung l im P v hy kt lun v thnh phn ca A, B khi im h dch chuyn theo ng thng ni t nh C vi im I
40 20 0

%A

Nc nguyn cht c th tn ti 9 dng pha khc nhau ( kh, lng v 7 dng rn). Tnh s pha ti a ca nc c th ng thi nm cn bng nhau. 5. Khi lng ring ca Phenol dng rn v dng lng ln lt l 1,072 v 1,056 g/ml,nhit nng chy ca Phenol l 24,93 cal/g,nhit kt tinh ca n 1 atm l 410C.Tnh nhit nng chy?
4.

60 80 0 10

20

Tnh p sut hi bo ho ca dung dch 5g ng glucose ( C6H12O6) trong 180g nc 200C. Bit rng nhit ny p sut hi bo ho ca nc 17,5 mmHg. 7. 200C p sut hi bo ho ca dung dch cha 52,8g A v 180g H2O l 16.5 mmHg. Xc nh khi lng phn t ca A. bit rng nhit ny p sut hi bo ho ca nc 17.5 mmHg. 8. Xc nh nhit si ca dung dch cha 20% ng glucose ( C6H12O6 ) trong nc p sut thng. Bit hng s nghim si ca nc l 0,513 /mol. 9. p sut hi bo ho ca axit xyanhydric HCN ph thuc vo nhit theo phng trnh: lg (mmHg) =7,04 - 1237
6.
T

Xc nh nhit si v nhit ha hi ca n iu kin thng?

p st thng,nhit si ca nc v cloroform ln lct l 1000C v 600C;nhit ho hi tng ng l 12,0 v 7,0 kcal/mol.Tnh nhit m 2 cht lng trn c cng p sut ? 11. Tnh p sut cn thit nhit si ca nc t c 1200C. Cho bit nhit ho hi ca nc 539 cal/g. 12. Xc nh nng mol v nng molan ca dung dch cha 20g CH3COOH trong 100g nc 250C. Bit nhit ny khi lng ring ca dung dch 1.01 g/cm3.
10.

 500C p sut hi ca n hecxane v n penthane ln lt l 400 v 1200 mmHg. a. Tnh p sut hi ca dung dch cha 50% (khi lng) ca n-penthane b. Xc nh phn mol ca n-hecxane trong pha hi c. Xc nh thnh phn ca hai cu t trn trong pha lng p sut hi ca chng bng nhau
13.

 25 0C p sut hi bo ho ca nc nguyn cht l 23,7 mmHg. Tnh p sut ca hi nc trn dung dch cha 10% glycerin trong nc nhit . 0 15. 50 C dung dch l tng gm 1mol A v 2 mol B c p sut hi tng cng 250mmHg, thm mt mol A vo dung dch ny th p sut tng cng l 300mmHg. Xc nh p sut hi bo ho ca A v B nguyn cht 500C.
14.

ethanol v methanol to thnh dung dch l tng, 20 C p sut hi bo ho ca ethanol v methanol ln lt l 44,5 v 88,7 mmHg. a. Xc nh p sut phn v p sut tng ca dung dch cha 100g ethanol v 100g methanol. b. Xc nh thnh phn ca ethanol v methanol trong pha lng phn mol ca methanol trong pha hi ch cn li 10%
16.
0

Mt dung dch nc kt tinh nhit - 1,50C a. Xc nh nhit si ca dung dch b. Xc nh p sut hi ca dung dch 250C Bit p sut hi ca nc nguyn cht 250C l 23,76 mmHg, hng s nghim ng v hng s nghim si tng ng l 1,86 v 0,513 /mol. 0 18. p sut thm thu ca mu 30 C atm. mun c cng p sut thm thu nh vy th dung dch mui NaCl phi c nng l bao nhiu. Nu xem NaCl phn ly 90%. 19. Dung dch cha 4.2g KOH trong 500g nc c nhit ng t 0.5190C. Tm h s ng trng I ca dung dch. 20. Khi ho tan 0.5 mol KNO3 trong 500 ml nc, nhit ng c ca dung dch 30C. Xc nh in ly biu kin ca dung dch. 21. Tnh p sut thm thu ca dung dch cha NaOH 0.1N trong nc 300C. Nu in ly ca ca dung dch ny 95%.
17.

Tnh nhit si ca dung dch CH3COOH 0,2 M trong nc. Cho bit hng s phn ly K ca CH3COOH l 1,8 . 105 v hng s nghim si ca nc l 0.513 /mol. 23. Tnh nhit kt tinh, nhit ng t, p sut thm thu ca dung dch cha 9g ng glucose ( C6H12O6) trong 100g nc 250C. Cho bit nhit ny p sut hi ca nc 23,76mmHg, khi lng ring ca dung dch 1 g/cm3, hng s nghim lnh v hng s nghim si ca nc tng ng 1,86 v 0,513 /mol. 24. Gin kt tinh ca Sb v Pb c dng nh hnh 24 . Lm lnh 200g h Q. a. M t gin pha ca h hai cu t trn. b. Xc nh bc t do ca vng (I), (II), (III) v ti im e. c. Khi im h Q trng vi im H. hy xc nh thnh phn ca pha lng v pha rn. d. Khi Q kt tinh hon ton, hy xc nh lng eutectic thu c.
22.

Hnh 24

25.

Gin kt tinh ca h A B c dng nh hnh 16. lm lnh 100g h Q. Khi im h nm H. C rn A v rn B kt tinh mt phn. im rn chung nm ti R. a. Xc nh lng rn A v rn B kt tinh v lng lng eutectic cn li. b. Tnh lng eutectic ti a thu c. c. Phi trn bao nhiu % A v %B khi kt tinh thu c hn A v B kt tinh xen k nhau.

Hnh 16