www.daykemquynhon.ucoz.

com

Bi dng kin thc vn ha cho hc sinh cp 2 + 3

3 THI TH I HC MN HA
1
KHO ST CHT LNG LP 12 LN 3 MN HA HC

Thi gian: 90 pht (khng k thi gian giao ) M thi 137 Lu :

- Cho : H = 1; O = 16; S = 32; N = 14; Na = 23; K = 39; Ag = 108; Mn = 55; Cl = 35,5; Ba = 137; F = 19; Br = 80; I = 127; Al = 27; Mg = 24; Fe = 56; C = 12.

- Hc sinh khng c dng Bng tun hon cc nguyn t ho hc. - Cn b coi thi khng gii thch g thm. Cu 1: un si dn xut halogen X vi nc mt thi gian, sau thm dung dch AgNO 3 vo thy xut hin kt ta. X l : A. CH2=CHCl B. CH2=CHCH2Cl C. C6H5Cl D. CH3-CH2-CH2Cl Cu 2: Trn 200 ml dung dch hn hp H2SO4 0,04 M v HNO3 0,02 M vi 300 ml dung dch hn hp NaOH 0,04 M v KOH 0,02 M. pH ca dung dch to thnh l (trong cc s cho di y) A. 1,9 B. 1,6 C. 2,4 D. 2,7 Cu 3: Dung dch nc ca A lm qu tm ng sang mu xanh, cn dung dch nc ca cht B khng lm i mu qu tm. Trn ln hai dung dch hai cht li th xut hin kt ta. A v B c th l: A. K2CO3 v Ba(NO3)2 B. NaOH v K2SO4 C. KOH v FeCl3 D. Na2CO3 v KNO3 Cu 4: Cho 0,15 mol hn hp X gm CH 3OH, HCOOH, HCOOCH3 tc dng va vi 0,1 mol NaOH un nng. Oxi ha ancol sinh ra thnh anehit, cho lng anehit ny tc dng ht vi Ag2O/NH3 (d) c 0,4 mol Ag. S mol ca HCOOCH3 l A. 0,05 mol B. 0,04 mol C. 0,02 mol D. 0,06 mol Cu 5: Cho cc cht v ion sau: Mg2+, Cu2+, KNO2, Ca, SO2, Fe2+ v NO2. Cc cht v ion va c tnh oxi ha va c tnh kh l: A. Fe2+, NO2, SO2, KNO2 B. Br2, Ca, SO2, KNO2 2+ 2+ C. Mg , Fe , NO2, SO2 D. Fe2+, NO2, Cu2+, SO2 Cu 6: t chy hon ton m gam hn hp gm anehit fomic, axit axetic, glucoz v glixerol thu c 29,12 lt CO 2 (ktc) v 27 gam H2O. Thnh phn phn trm v khi lng ca glixerol trong hn hp c gi tr l A. 35,1 % B. 43,8 % C. 46,7% D. 23,4% Cu 7: Trong s cc tinh th cho sau y, tinh th no thuc tinh th phn t ? A. Kim cng B. Photpho trng C. Mui n D. Bc kim loi Cu 8: t chy hon ton 0,1 mol cht A (C xHyO2) thu c 0,7 mol CO2. trung ho 0,2 mol A cn 0,2 mol NaOH. Mt khc, 0,5 mol A tc dng ht vi natri d thu c 0,5 mol H2. S nguyn t hiro trong phn t cht A l
1

www.daykemquynhon.ucoz.com

Bi dng kin thc vn ha cho hc sinh cp 2 + 3

A. 4 B. 10 C. 6 D. 8 Cu 9: Brakiinin c tc dng lm gim huyt p. l mt nonapeptit c cng thc l: Arg-Pro-Pro-Gly-Phe-Ser-Pro-Phe-Arg. Khi thu phn khng hon ton brakiinin c th thu c ti a s tripeptit c cha phenyl alanin (Phe) l A. 5 B. 2 C. 4 D. 3 Cu 10: Khi nung nng 22,12 gam kalipemanganat thu c 21,16 gam hn hp cht rn X. Cho X tc dng hon ton vi dung dch HCl c, nng (d). Tnh th tch kh Cl 2 thu c ( ktc). Bit cc phn ng xy ra hon ton. A. V = 7,84 lt B. V = 6,496 lt C. 5,152 lt D. V = 4,48 lt Cu 11: t chy hon ton 0,1 mol hn hp X gm stiren v p-xilen thu c CO2 v nc. Hp th hon ton sn phm chy bng 500 ml dung dch NaOH 2M c dung dch Y. Khi lng kt ta thu c khi cho dung dch BaCl2 d vo dung dch Y l A. 19,7 gam. B. 59,1 gam. C. 39,4 gam. D. 157,6 gam Cu 12: Hn hp A gm axit hu c no, n chc, mch h v este no, n chc, mch h. phn ng ht vi m gam A cn 400 ml dung dch NaOH 0,5M. Nu t chy hon ton m gam hn hp ny thu c 0,6 mol CO2. Gi tr ca m l A. 8,4 g B. 14,8 g C. 26,4 g D. 11,6 g Cu 13: trung ha dung dch thu c khi thy phn 4,5375 gam mt photpho trihalogenua cn dng 550 ml dung dch NaOH 0,3M. Cng thc phn t ca photpho trihalogenua l A. PF3 B. PI3 C. PCl3 D. PBr3 Cu 14: Phn ng no di y lm thay i cu to ca nhn thm ? A. stiren + Br2 (trong CCl4) B. benzen + Cl2 (as) C. cumen + Cl2 (as) D. toluen + KMnO4 + H2SO4 (t0) Cu 15: Cho 0,5 mol H2 v 0,5 mol N2 vo mt bnh kn dung tch khng i l 0,5 lt ( t0C). Khi cn bng ho hc c thit lp, ngi ta thy to thnh 0,2 mol NH 3. Hng s cn bng Kc ( t0C) l A. 3,125 B. 0,625 C. 15,625 D. 62,5 Cu 16: X l hn hp kim loi Ba v Al. Ha tan m gam X vo lng d nc thy thot ra 8,96 lt kh H2 (ktc). Cng ha tan m gam X vo dung dch NaOH d th thu c 12,32 lt kh H2 (ktc). Khi lng m bng A. 58,85 gam B. 21,80 gam. C. 57,50 gam D. 13,70 gam Cu 17: Trong cc nguyn t cho di y . Nguyn t ca nguyn t no c s electron c thn nhiu nht? A. Fe (Z= 26) B. Ga (Z= 31) C. Cu (Z= 29) D. Co (Z = 27) Cu 18: Ho tan hon ton 8,862 gam hn hp gm Al v Mg vo dung dch HNO 3 long, thu c dung dch X v 3,136 lt ( ktc) hn hp Y gm hai kh khng mu, trong c mt kh ho nu trong khng kh. Khi lng ca Y l 5,18 gam. Cho dung dch NaOH (d) vo X v un nng, khng c kh mi khai thot ra. Phn trm khi lng ca Al trong hn hp ban u l (chn trong cc s cho di y)
2

www.daykemquynhon.ucoz.com

Bi dng kin thc vn ha cho hc sinh cp 2 + 3

A. 19,53% B. 15,25% C. 12,80% D. 10,52% Cu 19: Ho tan hon ton hn hp gm 0,02 mol FeS 2 v 0,03 mol FeS vo mt lng d dung dch H2SO4 c nng, thu c Fe2(SO4)3 , SO2 v H2O. Hp th ht SO2 vo mt lng va dung dch KMnO4 long, thu c V lt dung dch Y khng mu c pH = 2. Tnh V (lt) A. V = 20,8 lt B. V = 19,2 lt C. V = 11,4 lt D. V = 22,8 lt Cu 20: Dy no di y ch gm cc cht c th lm nht mu dung dch nc Br2 ? A. Tt c cc dy kia u ng B. buta-1,3-ien, axetilen, stiren C. xiclopropan, glucoz, axit fomic. D. Kh sunfur, propilen, axetilen Cu 21: un 0,875g lng trng trng vi dung dch NaOH m c, d. Cht kh thot ra c mi khai v c hp th ht bi 200ml dung dch H 2SO4 0,2M. trung ho lng axit d, phi dng 70ml dung dch NaOH 1M. Hm lng nguyn t N c trong lng trng trng l A. 18% B. 8% C. 14% D. 16% Cu 22: Cho 6,72 gam Fe vo 400ml dung dch HNO 3 1M, n khi phn ng xy ra hon ton, thu c kh NO (sn phm kh duy nht) v dung dch X. Dung dch X c th ho tan ti a m gam Cu. Gi tr ca m l A. 3,84 B. 0,64 C. 1,92 D. 3,20 Cu 23: Ho tan 17 gam hn hp X gm K v Na vo nc c dung dch Y v 6,72 lt kh H2 (ktc). trung ho mt na dung dch Y cn dung dch hn hp H 2SO4 v HCl (t l mol 1:3). Khi lng mui khan thu c l A. 42,1 gam B. 41,3 gam C. 21,05 gam D. 20,65 gam Cu 24: Cho cc cht sau: axit metanoic, axetanehit, axetilen; vinyl axetilen, mantoz, acrolein. S cht tham gia c phn ng trng gng l A. 2 B. 4 C. 5 D. 3 Cu 25: Cho cc cht : FeCl3; O3; H2SO4 c; Br2 ; H2S; IO3- (trong dung dch axit). Hi ion I- trong dung dch KI c th oxi ho c bao nhiu trong s cc cht A. 3 B. 6 C. 4 D. 5 Cu 26: t chy hon ton hn hp gm 2 este no, mch h, n chc cn 5,68 g kh oxi v thu c 3,248 lt kh CO2 (ktc). Cho hn hp este trn tc dng va vi KOH thu c 2 ancol l ng ng k tip v 3,92 g mui ca mt axit hu c. Cng thc cu to ca 2 este l A. C2H5COOCH3 v CH3COOCH3 B. C3H7COOCH3 v CH3COOC2H5 C. HCOOCH3 v HCOOC2H5 D. CH3COOCH3 v CH3COOC2H5 Cu 27: Ha tan hon ton m g hn hp bt gm Fe 3O4 v FeCO3 trong dung dch HNO3 nng d, thu c 3,36 lt hn hp A gm 2 kh CO 2 v NO2 (o ktc), v dung dch B. T khi hi ca A i vi hiro bng 22,6. Gi tr m l A. 15,24 g B. 6,96 g C. 13,92 g D. 69,6 g Cu 28: C cc dung dch long cng nng sau: Na2CO3 (1); H2SO4 (2); HCl (3); KNO3 (4); AlCl3 (5). Gi tr pH ca cc dung dch c sp xp theo th t tng dn t tri sang phi l
3

www.daykemquynhon.ucoz.com

Bi dng kin thc vn ha cho hc sinh cp 2 + 3

A. (2), (1), (5), (3), (4) B. (1), (4), (5), (3), (2) C. (1), (4), (3), (2), (5) D. (2), (3), (5), (4), (1) Cu 29: Cho 2,16 gam Mg tc dng vi dung dch HNO 3 (d). Sau khi phn ng xy ra hon ton thu c 0,896 lt kh NO ( ktc) v dung dch X. Khi lng mui khan thu c khi lm bay hi dung dch X l : A. 13,92 gam B. 13,32 gam C. 8,88 gam D. 6,52 gam Cu 30: Hai cht no di y l ng phn ca nhau: A. Fructoz v mantoz B. Saccaroz v mantoz C. Saccaroz v glucoz D. Tinh bt v xen luloz Cu 31: Phng php luyn thp no sau y c th luyn c loi thp c cht lng cao? A. Phng php l bng B. Phng php l in C. Phng php l thi oxi D. Phng php l thi oxi v l in Cu 32: 10 gam hn hp X gm CH 4, C3H6 v C2H2 lm mt mu 48 gam Br2 trong dung dch. Mt khc 13,44 lt kh X (ktc) tc dng va vi AgNO 3/NH3 c 36 gam kt ta. Thnh phn % v khi lng ca CH4 c trong X l A. 25% B. 32% C. 20% D. 50% Cu 33: T ngun nguyn liu chnh l kh thin nhin v cc cht v c cn thit, c th iu ch c anilin. S phn ng ti thiu cn phi thc hin l A. 3 B. 4 C. 5 D. 2 Cu 34: Dy no di y ch gm cc cht tan tt trong nc nhit thng? A. C3H5(OH)3, CH2OH(CHOH)4CHO, H2NCH2COOH v CH3COOC2H5 B. CH3NH2, C6H5NH2, CH3CH2OH v CH3COOH C. CH3OH, CH3CH2CH2CH2OH, CH3CH2COOH v C6H5OH D. C2H4(OH)2, (COOH)2, HCHO, CH3CHO v CH3COCH3 Cu 35: Hn hp X gm etylen v propylen vi t l th tch tng ng l 3:2. Hirat ho hon ton mt th tch X thu c hn hp ancol Y, trong t l v khi lng cc ancol bc 1 so vi ancol bc 2 l 28:15. Thnh phn % v khi lng ca propan-1-ol trong hn hp Y l A. 21,12%. B. 18,34%. C. 11,63%. D. 19,58%. Cu 36: Trong s cc polime cho di y, polime no c cu trc khng gian ? A. Rezol B. amilopectin C. Rezit D. xenluloz Cu 37: Sp xp theo th t tng dn tnh baz ca cc cht sau: (1) NH 3, (2) CH3NH2, (3) C6H5NH2, (4) (CH3)2NH, (5) C2H5NH2, (6) p-O2N-C6H4NH2. A. (6), (3), (1), (2), (5), (4). B. (3), (6), (1), (2), (4), (5). C. (6), (5), (2), (3), (1), (4). D. (1), (2), (3), (4), (5), (6). Cu 38: Cho 5,4 gam Al vo dung dch X cha 0,15 mol HCl v 0,3 mol CuSO 4, sau mt thi gian c 1,68 lt kh H 2(ktc), dung dch Y v cht rn Z. Cho Y tc dng vi dung dch NH3 th c 7,8 gam kt ta. Khi lng Z l : A. 7,5 gam B. 15 gam C. 9,6 gam D. 19,2 gam Cu 39: Cho 7,22 g hn hp gm Fe v kim loi M c ha tr khng i. Chia hn hp thnh 2 phn bng nhau. Phn 1 ha tan ht trong dung dch HCl d thu c 2,128 lt H 2
4

www.daykemquynhon.ucoz.com

Bi dng kin thc vn ha cho hc sinh cp 2 + 3

(ktc). Phn 2 ha tan ht trong dung dch HNO3 d thu c 1,792 lt kh NO (ktc) (sn phm kh duy nht). Kim loi M l A. Zn B. Mg C. Cu D. Al Cu 40: Thy phn 0,2 mol mantoz vi hiu sut 50% c hn hp cht Y. Cho Y phn ng hon ton vi AgNO3/NH3 (d) c m gam kt ta Ag. Gi tr ca m l A. 43,2 gam B. 32,4 gam C. 64,8 gam D. 86,4 gam Cu 41: Cho 0,784 lt kh CO2 (ktc) hp th hon ton vo dung dch hn hp X cha 0,03 mol NaOH v 0,01 mol Ca(OH)2. Khi lng kt ta thu c l A. 1,0 gam B. 3,0 gam C. 3,5 gam D. 1,5 gam Cu 42: Cho m gam hn hp X gm Al, Cu vo dung dch HCl (d), sau khi kt thc phn ng sinh ra 3,36 lt kh ( ktc). Nu cho m gam hn hp X trn vo mt lng d axit nitric (c, ngui), sau khi kt thc phn ng sinh ra 6,72 lt kh NO 2 (sn phm kh duy nht, ktc). Gi tr ca m l A. 10,5 B. 12,3 C. 11,5 D. 15,6 Cu 43: Trong cc dung dch: HNO3, NaCl, Na2SO4, Ca(OH)2, KHSO4 v Mg(NO3)2, dy gm cc cht u tc dng c vi dung dch Ba(HCO3)2 l : A. NaCl, Na2SO4, Ca(OH)2. B. HNO3, NaCl, Na2SO4. C. HNO3, Ca(OH)2, KHSO4, Mg(NO3)2. D. HNO3, Ca(OH)2, KHSO4, Na2SO4. Cu 44: Cho m gam mt ancol no n chc X i qua bnh ng CuO (d), nung nng. Sau khi phn ng xy ra hon ton, khi lng cht rn trong bnh gim 0,32 gam. Hn hp hi thu c c t khi i vi hiro l 15,5. Gi tr ca m l A. 0,46 B. 0,64 C. 0,92 D. 0,32 Cu 45: Ho tan hon ton 24,95 gam hn hp A gm 3 kim loi (X, Y, Z) bng dung dch HNO3 long, d. Thy c 6,72 lt kh NO duy nht thot ra (ktc) v dung dch B ch cha mui kim loi. Khi lng mui nitrat thu c khi c cn cn thn dung dch B l: A. 62,15 gam B. 43,50 gam C. 99,35 gam B. 80,75 gam Cu 46: Trong cc kim loi Mg, Al, Fe, Zn, K, Ba, Ag. Kim loi nh gm A. Mg, Al, Fe, Zn. B. Mg, Ag, Al, Fe. C. Mg, Al, K, Ba. D. Mg, Ba, Zn, Al. Cu 47: Nhit phn hon ton hn hp NH 4NO3, Cu(NO3)2, AgNO3, Fe(NO3)2 th cht rn thu c sau phn ng gm A. CuO, Fe2O3, Ag2O. B. CuO, Fe2O3, Ag. C. CuO, FeO, Ag. D. NH4NO2, Cu, Ag, FeO. Cu 48: Hiro ho hon ton anehit acrylic bng lng d H 2 (xc tc Ni, to) th to thnh ancol X. Ho tan ht lng cht X ny vo 13,5 gam nc thu c dung dch Y. Cho Kali kim loi (d) vo dung dch Y thu c 11,2 lt kh H 2 (ktc). Nng phn trm ca cht X trong dung dch Y l (trong cc s cho sau y) A. 81,63%. B. 81,12%. C. 51,79%. D. 52,63% Cu 49: Cho dy cc cht: FeO, Fe(OH) 2, FeSO4, Fe3O4, Fe2(SO4)3, Fe2O3. S cht trong dy b oxi ha khi tc dng vi dung dch HNO3 c, nng l A. 6 B. 4 C. 5 D. 3
5

www.daykemquynhon.ucoz.com

Bi dng kin thc vn ha cho hc sinh cp 2 + 3

Cu 50: Cho 1mol CH3COOH v 1mol C2H5OH vo mt bnh phn ng c H2SO4 c, nng lm xc tc. Hng s cn bng nng ca phn ng este ho K = 4. Khi lng ca axit c trong hn hp lc cn bng l m gam. Gi tr ca m l A. 15,33 B. 20 C. 29,33 D. 20 < m < 60 P N 1B 6C 11C 16B 21D 26D 31A 36C 41A 46C 2D 7B 12B 17A 22C 27C 32B 37A 42B 47B 3A 8D 13C 18C 23D 28D 33B 37A 43D 48D 4A 9A 14B 19D 24B 29A 34D 39D 44C 49B 5A 10B 15A 20A 25D 30B 35C 40C 45B 50B
S GD T THI BNH TRNG THPT TY THY ANH

2 THI TH I HC, CAO NG LN III MN: HA HC Thi gian lm bi: 90 pht; M thi 132

(Th sinh khng c s dng ti liu) H, tn th sinh:..................................................................... S bo danh: .............................

Cho: H=1; N=14; O=16; C=12; P=31; Cl=35,5; S=32; Br=80; Na=23; Cu=64; Fe=56; Zn=65; Li=7; Na=23; K=39; Ca=40; Mn=55; Al=27; Mg=24; Ag=108; Ba=137; Cu 1: Ho tan 11,6 gam hn hp X gm Fe, FeO, Fe 2O3 trong dung dch HNO3 d, thu c sn phm kh gm V lt hn hp kh gm NO v NO 2 ( ktc) c t khi so vi hiro bng 19. Mt khc nu un nng X vi CO d th sau phn ng hon ton thu c 9,52 gam Fe. Gi tr ca V l: A. 2,24. B. 2,80. C. 4,48. D. 1,12. Cu 2: Cho 0,2 mol mt anehit n chc, mch h X phn ng va vi 300 ml dung dch cha AgNO3 2M trong NH3 d, sau khi phn ng xy ra hon ton thu c 87,2 g kt ta. Cng thc phn t ca anehit l: A. C3H3CHO. B. C4H3CHO. C. C4H5CHO. D. C3H5CHO. Cu 3: Chuyn ha hon ton 4,6 gam hn hp cha 2 ancol bc I (c t l mol 1:1) thnh ankanal cn dng 0,1 mol CuO. Cho ton b ankanal thu c phn ng vi AgNO 3/NH3 d thu c 0,3 mol kim loi kt ta. Hai ancol l: A. CH3OH v C4H9OH. B. CH3OH v C2H5OH. C. CH3OH v C3H7OH. D. C2H4(OH)2 v C3H7OH. Cu 4: Cho 0,1 mol -aminoaxit X tc dng vi 50 ml dd HCl 1 M thu c dung dch A; dung dch A tc dng vi 250 ml dung dch NaOH 1 M thu c dung dch B. C cn dung dch B cn li 20,625 gam cht rn khan. Cng thc ca X l: A. HOOCCH2CH2CH(NH2)COOH. B. NH2CH2COOH. C. CH3CH(NH2)COOH. D. HOOCCH2CH(NH2)COOH. Cu 5: Cho cc cht sau: (NH4)2CO3; Na2HPO3; KHSO4; CH3COONH3CH3; Glyxin; Al2O3; Zn.
6

www.daykemquynhon.ucoz.com

Bi dng kin thc vn ha cho hc sinh cp 2 + 3

S cht lng tnh trong cc hp cht trn l: A. 7. B. 5. C. 6. D. 4. Cu 6: Pht biu no sau y l ng? A. Phn t cc amino axit ch c 1 nhm amino. B. Trong peptit mch h to ra t n phn t H2NRCOOH, s lin kt peptit l (n1). C. Dung dch cc amino axit u khng lm i mu qu tm. D. Phn t ipeptit mch h c 2 lin kt peptit. Cu 7: Hn hp X gm Al, Fe2O3, Cu c s mol bng nhau. Hn hp X c th tan hon ton trong dung dch no sau y? A. dung dch NH3 d. B. dung dch HCl d. C. dung dch AgNO3 d. D. dung dch NaOH d. Cu 8: Cho lng kh CO qua ng s ng m gam Fe2O3 nung nng, sau mt thi gian thu c 19,32g hn hp gm Fe, FeO, Fe3O4, Fe2O3 (hn hp X). Ha tan ht X bng HNO3 c, nng, d thu c 5,824 lt kh NO2 (sn phm kh duy nht, o ktc). Gi tr ca m l: A. 23,48g. B. 21,4g. C. 13,24g. D. 26,60g. Cu 9: Cho m gam Na vo 100 ml dung dch AlCl 3 2M, sau phn ng thu c 7,8 gam kt ta. Gi tr ca m l: A. 16,1 gam. B. 10,8 gam hoc 6,9 gam. C. 6,9 gam. D. 6,9 gam hoc 16,1 gam. Cu 10: Cho 14,2 gam P2O5 vo 100 ml dung dch cha hn hp NaOH 1M v KOH 2M thu c dung dch X. Cc anion c mt trong dung dch X l: A. H 2 PO4 v PO43 . B. PO43 v OH . C. HPO42 v PO43 . D. H 2 PO4 v HPO42 . Cu 11: Cho phn ng oxi ha - kh sau: Al + HNO 3 Al(NO3)3 + N2 + N2O + H2O. Vi t l mol gia N2 v N2O = 2:3 v h s l cc s nguyn ti gin, th h s ca HNO 3 trong phn ng l: A. 142. B. 162. C. 22. D. 24. Cu 12: Th t cc cht xp theo chiu tng dn lc axit l: A. CH3COOH<HCOOH<CH2ClCH2COOH<CH3CHClCOOH. B. CH2ClCH2COOH<CH3CHClCOOH<CH3COOH<HCOOH. C. HCOOH<CH3COOH<CH2ClCH2COOH<CH3CHClCOOH. D. HCOOH<CH3COOH<CH3CHClCOOH<CH2ClCH2COOH. Cu 13: Ho tan hon ton hn hp gm z mol Fe 2O3 v t mol Fe3O4 vo dung dch HCl thu c dung dch X, dung dch X ha tan c x mol Fe v y mol Cu (khng thy c kh bay ra) v thu c dung dch ch cha 2 mui. Mi quan h gia s mol cc cht l: A. x + y = 2z + 2t. B. x + 2y = 2z + 2t. C. x + y = 2z +3t. D. x + y = z + t. Cu 14: S nguyn t m nguyn t ca n ( trng thi c bn) c tng s electron trn cc phn lp s bng 7 l: A. 9. B. 3. C. 5. D. 1. Cu 15: Hp th hon ton 2,688 lt CO 2 (ktc) cn va 2,5 lt dung dch hn hp gm Ba(OH)2 a mol/lt v NaOH 0,04M thu c 15,76g kt ta. Gi tr ca a l: A. 0,025M. B. 0,02M. C. 0,048M. D. 0,032M.
7

www.daykemquynhon.ucoz.com

Bi dng kin thc vn ha cho hc sinh cp 2 + 3

Cu 16: t t m gam H2SO4.2SO3 vo 500ml dung dch c pH = 14 gm NaOH v KOH, sau phn ng hon ton thy dung dch thu c c pH = 0 (coi th tch dung dch khng i sau khi phn ng). Gi tr ca m l: A. 43 gam. B. 86 gam. C. 129 gam. D. 64,5 gam. Cu 17: Ha tan hon ton hn hp gm 0,12mol FeS 2 v a mol Cu2S vo axit HNO3 (va ) thu c dung dch X (ch cha 2 mui sunfat) v kh NO (sn phm kh duy nht). Cho dung dch X tc dng vi dung dch BaCl2 d thu c m gam kt ta. Gi tr ca m l: A. 69,9. B. 46,6. C. 65,24. D. 23,3. Cu 18: t t FeCl2 vo dung dch AgNO3, sau phn ng thu c kt ta X gm 2 cht rn v dung dch Y. Dung dch Y ha tan c Cu v dung dch Y lm mt mu dung dch cha KMnO4 (trong mi trng axit). Cc cht trong dung dch Y l: A. Ag+, Fe3+. B. Ag+, Fe2+. C. Fe2+, Fe3+. D. Fe2+, Fe3+ v Ag+. Cu 19: Dung dch A cha Ca(OH)2. Cho 0,06 mol CO2 vo dung dch A thu c 4m gam kt ta cn khi cho 0,08mol CO2 vo dung dch A th thu c 2m gam kt ta. Gi tr ca m l: A. 1,5 B. 1,0. C. 3,0. D. 2,2. Cu 20: Hn hp gm 2 axit no X v Y. t chy hon ton 0,3 mol hn hp thu c 11,2 lt kh CO2 (ktc). trung ha 0,3 mol hn hp cn 500ml dung dch NaOH 1M. Cng thc cu to ca 2 axit l: A. HCOOH v HOOC-COOH. B. HCOOH v C2H5COOH. C. CH3COOH v HOOC-CH2-COOH. D. CH3COOH v C2H5COOH. Cu 21: C cc dung dch ring bit khng dn nhn: NH4Cl, AlCl3, FeCl3, Na2SO4, (NH4)2SO4, NaCl. Thuc th cn thit nhn bit tt c cc dung dch trn l: A. dung dch NaHSO4. B. dung dch NaOH. C. dung dch Ba(OH)2. D. dung dch BaCl2. Cu 22: Mt cht hu c X (cha mt loi chc, v ch cha C, H, O). Khi cho 2,9g X phn ng vi dung dch AgNO3/NH3 d thu c 21,6g Ag. Vy X c th l: A. CH2(CHO)2. B. OHC CHO. C. HCHO. D. CH3 CHO. Cu 23: Cho cc pht biu sau: (a) Anehit va c tnh oxi ha, va c tnh kh. (b) Phenol tham gia phn ng th brom kh hn benzen. (c) Anehit tc dng vi H2 (d) c xc tc Ni, un nng, thu c ancol bc I. (d) Dung dch axit axetic tc dng c vi Cu(OH)2. (e) Dung dch phenol trong nc lm qu tm ha . (f) Trong cng nghip, axeton c sn xut t cumen. S pht biu ng trong s cc pht biu trn l: A. 5. B. 2. C. 3. D. 4 . Cu 24: Hn hp X gm axit n chc A, ancol n chc B v este E c iu ch t A v B. t chy 9,6 gam hn hp X thu c 8,64 gam H 2O v 8,96 lt kh CO2 (ktc). Bit trong X, ancol B chim 50% v s mol. S mol ancol B trong 9,6 gam hn hp X l: A. 0,075. B. 0,08. C. 0,06. D. 0,09.
8

www.daykemquynhon.ucoz.com

Bi dng kin thc vn ha cho hc sinh cp 2 + 3

Cu 25: t chy hn hp A gm cc hirocacbon bng oxi thu c 6,72 lt CO 2 (ktc) v 3,6g H2O. Th tch kh O2 (ktc) cn dng l: A. 8,96lt. B. 4,48lt. C. 2,24 lt. D. 6,72lt. Cu 26: Cho cc cht Cu, FeSO4, Na2SO3, FeCl3. S cht tc dng c vi dung dch hn hp gm NaNO3 v HCl l: A. 1. B. 4. C. 3. D. 2. Cu 27: Ha hi m gam cht hu c A (ch cha C,H,O) thu c th tch hi bng 8/15 th tch ca m gam O2, o cng iu kin. C bao nhiu cht A (mch h) tha mn iu kin trn? A. 7. B. 3. C. 6. D. 5. Cu 28: X l ancol bc II c cng thc phn t C 6H14O. un nng X vi H2SO4 c 1700C ch to mt anken duy nht. Tn ca (X) l: A. 3,3-imetylbutan-2- ol. B. 2,3-imetylbutan-3-ol. C. 2,2-imetylbutan-3-ol. D. 2,3-imetylbutan-2-ol. Cu 29: Cho l km nng 100g vo 100ml dung dch hn hp gm Cu(NO3)2 0,8M v AgNO3 0,2M; sau mt thi gian ly l kim loi ra nh, sy kh cn c 101,45g (gi thit cc kim loi sinh ra u bm vo l km). Khi lng km tham gia phn ng l : A. 4,55 gam. B. 8,5 gam. C. 6,55 gam. D. 7,2 gam. Cu 30: Ha tan 16,8g hn hp gm 2 mui M2CO3 v M2SO3 (M l kim loi kim) vo dung dch HCl d, thu c 3,36 lt hn hp kh (ktc). Kim loi kim l: A. Li. B. Rb. C. K. D. Na. Cu 31: Cho 3,84 gam Mg tc dng vi dung dch HNO 3 long, d thu c 1,344 lt NO (ktc) v dung dch X. Khi lng mui khan thu c khi lm bay hi cn thn dung dch X l: A. 25,38 gam. B. 23,68 gam. C. 24,68 gam. D. 25,08 gam. Cu 32: Khi cho dung dch Na2CO3 d vo dung dch cha ion Ba2+, Fe3+, Al3+, NO3 th kt ta thu c gm: A. BaCO3, Al(OH)3. B. Al(OH)3, Fe(OH)3. C. BaCO3, Al(OH)3, Fe(OH)3. D. BaCO3, Fe(OH)3. Cu 33: Cho hn hp gm 0,4 mol Fe v 0,2 mol Zn vo 200 ml dung dch hn hp gm Cu(NO3)2 1M v AgNO3 3M. Sau khi phn ng xong, khi lng dung dch gim: A. 47,8 gam. B. 21,1 gam. C. 53,4 gam. D. 42,2 gam. Cu 34: Cho s chuyn ho : HCl HCl 2 NaOH X + Y + Z. C6H5-CCH + Trong X, Y, Z u l sn phm chnh. Cng thc ca Z l: A. C6H5CH2CH2OH. B. C6H5CH(OH)CH2OH. C. C6H5COCH3. D. C6H5CH(OH)CH3. Cu 35: C 5 dung dch sau: Ba(OH) 2, FeCl2, Pb(NO3)2, CuSO4, FeCl3. Khi sc kh H2S qua 5 dung dch trn, c bao nhiu trng hp c phn ng sinh kt ta? A. 4. B. 2. C. 1. D. 3.
9

www.daykemquynhon.ucoz.com

Bi dng kin thc vn ha cho hc sinh cp 2 + 3

Cu 36: Ba hp cht hu c X, Y, Z c cng cng thc phn t C 3H4O2. X v Y u tham gia phn ng trng bc; X, Z c phn ng cng hp Br 2; Z tc dng vi NaHCO 3. Cng thc cu to ca X, Y, Z ln lt l: A. HCO-CH2-CHO; HCOOCH=CH2; CH2=CH-COOH. B. HCOOCH=CH2; CH2=CH-COOH; HCO-CH2-CHO. C. HCOOCH=CH2; HCO-CH2-CHO; CH2=CH-COOH. D. CH3-CO-CHO; HCOOCH=CH2; CH2=CH-COOH. Cu 37: Hp cht hu c X c cng thc phn t l C4H6O4. Cho X phn ng vi NaOH un nng to ra mt mui Y v mt ancol Z. t chy Y th sn phm to ra khng c nc. Cng thc ca X l: A. HCOOCH2CH2OOCH. B. HOOCCH2COOCH3. C. HOOC-COOC2H5. D. CH3OOC-COOCH3. Cu 38: Thc hin cc th nghim sau: (1) Sc kh SO2 vo dung dch K2Cr2O7 trong H2SO4 long. (2) Sc kh SO2 vo dung dch HNO3 c. (3) Sc kh SO2 vo dung dch Ca(OH)2. (4) Cho KMnO4 vo dung dch HCl c. (5) Cho SiO2 vo dung dch HF. (6) Cho CrO3 vo dung dch NaOH. S th nghim c phn ng oxi ha - kh xy ra l: A. 6. B. 4. C. 3. D. 5. Cu 39: Trung ho hon ton 3 gam mt amin bc I bng axit HCl thu c 6,65 gam mui. Cng thc ca amin l: A. H2NCH2CH2NH2. B. CH3NH2. C. CH3CH2NH2. D. H2NCH2CH2CH2NH2. Cu 40: t chy hon ton 2 lt hn hp kh gm ankin X v hirocacbon Y cn dng 4,5 lt kh O2 sinh ra 3 lt kh CO2 (cc th tch kh o cng iu kin nhit , p sut). Cng thc phn t ca X v Y ln lt l: A. C2H2 v CH4. B. C3H4 v CH4. C. C2H2 v C2H4. D. C3H4 v C2H6. Cu 41: Cho m gam mt ancol, n chc X i qua bnh ng CuO d, nung nng, sau khi phn ng hon ton, cht rn trong bnh gim 0,48 gam. Hn hp hi thu c c t khi i vi hiro l 15,5. Gi tr ca m l: A. 0,32. B. 1,38. C. 0,64. D. 0,92. Cu 42: Khi nhit phn hon ton 100 gam mi cht sau: KClO 3 (xc tc MnO2), KMnO4, KNO3 v AgNO3. Cht m khi nhit phn to ra lng O2 t nht l: A. KMnO4. B. KNO3. C. AgNO3. D. KClO3. Cu 43: Ho tan 45,9 gam kim loi M bng dung dch HNO 3 long, d thu c hn hp sn phm kh gm 0,3 mol N2O v 0,9 mol NO. Kim loi M l: A. Fe. B. Zn. C. Al. D. Mg. Cu 44: Protein A c khi lng phn t l 50000 vC. Thy phn 100 gam A thu c 33,998 gam alanin. S mt xch alanin trong phn t A l:
10

www.daykemquynhon.ucoz.com

Bi dng kin thc vn ha cho hc sinh cp 2 + 3

A. 191. B. 382. C. 562. D. 208. Cu 45: X v Y ln lt l cc tripeptit v hexapeptit c to thnh t cng mt amino axit no, mch h, c mt nhm COOH v mt nhm NH 2. t chy hon ton 0,1 mol X bng O2 va thu c sn phm gm CO2, H2O v N2 c tng khi lng l 40,5 gam. Nu cho 0,15 mol Y tc dng hon ton vi NaOH (ly d 20% so vi lng cn thit), sau phn ng c cn dung dch th thu c bao nhiu gam cht rn? A. 87,3 gam. B. 9,99 gam. C. 107,1 gam. D. 95,4 gam. Cu 46: Hirocacbon X c cng thc phn t C6H10. X tc dng vi dung dch AgNO3/NH3 to ra kt ta vng. Khi hiro ha hon ton X thu c neo-hexan. Tn gi ca X l: A. 2,2-imetylbut-3-in. B. 2,2-imetylbut-2-in. C. 3,3-imetylbut-1-in. D. 3,3-imetylpent-1-in. Cu 47: Thy phn 95,76g saccaroz trong mi trng axit vi hiu sut phn ng t 75% thu c hn hp X. Trung ha axit trong X bng NaOH thu c hn hp Y. Cho Y tc dng vi dung dch AgNO3/NH3 d un nng thu c m gam Ag kt ta. Gi tr ca m l: A. 120,96 gam. B. 60,48 gam. C. 105,84 gam. D. 90,72 gam. Cu 48: Cho x mol Fe tc dng vi dung dch cha y mol HNO 3 to ra kh NO (sn phm kh duy nht) v dung dch X cha cc ion Fe3+, Fe2+, NO3 . Biu thc lin h gia x v y l: A. y 4 < x < 3y8 . B. x = y 4 . C. x > 3y8 . D. y 8 < x < y 4 . Cu 49: Khi cho 0,15 mol este n chc X tc dng vi NaOH d phi dng ht 12 gam NaOH v tng khi lng sn phm hu c thu c l 29,7 gam. S ng phn cu to ca X tha mn l: A. 5. B. 2. C. 4. D. 6. Cu 50: Trong bng tun hon cc nguyn t ho hc, nguyn t X nhm IIA, nguyn t Y nhm VA. Cng thc ca hp cht to thnh t 2 nguyn t trn c dng: A. X5Y2. B. X2Y5. C. X3Y2. D. X2Y3. ----------- HT ----------

p n
1 2 3 4 5 B B C D D 6 7 8 9 10 B B B D D 11 12 13 14 15 B A D B D 16 17 18 19 20 A A C B A 21 22 23 24 25 C B D B A 26 27 28 29 30 C C A A D 31 32 33 34 35 D C A C D 36 37 38 39 40 C D C A A 41 42 43 44 45 B C C A D 46 47 48 49 50 C D A C C

11

www.daykemquynhon.ucoz.com

Bi dng kin thc vn ha cho hc sinh cp 2 + 3

3 S GD-T H NI
TRNG THPT A PHC

-----*****----( thi c 04 trang)

THI TH I HC MN HA HC T 2 NM 2013 Thi gian: 90 pht (khng k thi gian pht )

Ngy thi 14/04/2013

H, tn th sinh:...................................................................... S bo danh:.....................................

M : 154 Hp cht hu c X c cng thc phn t C8H11N, X tan c trong axit. Cho X tc dng vi HNO2 to ra hp cht Y c cng thc phn t C 8H10O. un nng Y vi dung dch H2SO4 c to ra hp cht Z. Trung hp Z thu c polistiren. S ng phn cua X thoa mn l A. 3 B. 2 C. 1 D. 4 Cu 2. Cho hn hp A gm Al, Fe vo dung dch B c cha Cu(NO 3)2 v AgNO3. Sau khi phn ng xy ra hon ton thu c dung dch C; Cho dung dch NaOH d vo C c kt ta D gm hai hiroxit kim loi. Trong dung dch C c cha A. Al(NO3)3, Fe(NO3)2 v Cu(NO3)2 B. Al(NO3)3 v Fe(NO3)2 C. Al(NO3)3 v Fe(NO3)3 v Fe(NO3)2 D. Al(NO3)3 v Fe(NO3)3
Cu 1.

12

www.daykemquynhon.ucoz.com
Cu 3.

Bi dng kin thc vn ha cho hc sinh cp 2 + 3

in phn 100 ml dung dch CuSO4 1M vi in cc tr trong thi gian 25 pht 44 giy, cng dng in l 5A th dng li. Khi lng dung dch gim l A. 3,2 gam B. 2,56 gam C. 3,84 gam D. 2,88 gam Cu 4. Ln men 45 gam glucoz thy c 4,48 lt CO 2 (ktc) bay ra v cn hn hp cht hu c X gm C2H5OH v glucoz d. t chy hon ton X th s mol CO2 thu c l A. 1,3 mol B. 1,2 mol C. 1,5 mol D. 1,15 mol Cu 5. Hn hp X gm Al, Fe2O3 c khi lng 21,67 gam. Tin hnh phn ng nhit nhm hn hp X trong iu kin khng c khng kh. Ha tan hon ton hn hp cht rn sau phn ng bng dung dch NaOH d thu c 2,016 lt H 2 (ktc) v 12,4 gam cht rn khng tan. Hiu sut ca phn ng nhit nhm l A. 80% B. 75% C. 60% D. 71,43% Cu 6. Cho 17,9 gam hn hp gm Fe, Cu v Al vo bnh ng 200 gam dung dch H 2SO4 24,01%. Sau khi cc phn ng xy ra hon ton, thu c 9,6 gam cht rn v c 5,6 lt kh (ktc) thot ra. Thm tip vo bnh 10,2 gam NaNO3, khi cc phn ng kt thc th th tch kh NO (ktc, sn phm kh duy nht) to thnh v khi lng mui trong dung dch l A. 2,688 lt v 59,18 gam B. 2,24 lt v 59,18 gam C. 2,688 lt v D. 2,24 lt v 56,3 gam 67,7 gam Cu 7. Cho cc cht sau: CH3COOCH2CH2Cl, ClH3N-CH2COOH, C6H5Cl (thm), HCOOC6H5 (thm), C6H5COOCH3 (thm), HO-C6H4-CH2OH (thm), CH3CCl3, CH3COOC(Cl2)-CH3. C bao nhiu cht khi tc dng vi NaOH c d, nhit v p sut cao cho sn phm c 2 mui? A. 7 B. 4 C. 5 D. 6 Cu 8. Phng php iu ch polime no sau y l ng? A. ng trng hp axit terephtalic v etylen glicol iu ch c poli(etylenterephtalat) B. Trng hp caprolactam to t nilon-6 C. Trng hp ancol vinylic iu ch poli(vinyl ancol) D. ng trng ngng buta-1,3-ien v vinylxianua iu ch cao su buna-N Cu 9. Cho phn ng CO(k) + H2O(k) CO2 (k) + H2 (k) (H <0) Trong cc yu t: (1) tng nhit , (2) thm lng CO, (3) thm mt lng H 2, (4) gim p sut chung ca h, (5) dng cht xc tc. S yu t lm chuyn dch cn bng l A. 2. B. 4. C. 3. D. 5. Cu 10. Thy phn hon ton mt cht bo bng dung dch NaOH, sau phn ng thu c 2,78 gam C15H31COONa; m2 gam C17H31COONa v m3 gam C17H35COONa. Gi tr ca m2 v m3 ln lt l A. 3,02 gam v 3,05 gam B. 6,04 gam v 6,12 gam C. 3,02 gam v 3,06 gam D. 3,05 gam v 3,09 gam Cu 11. C bao nhiu cht hoc dung dch sau y cho phn ng vi nc brm: glucoz, fructoz, saccaroz, mantoz, ancol etylic, anehit axetic, axit fomic, axit benzoic, phenol v anilin? A. 6 B. 5 C. 7 D. 8 Cu 12. - Cho a gam Fe ( d) vo V1 lit Cu(NO3)2 1M thu c m gam rn. - Cho a gam Fe (d) vo V2 lit AgNO3 1M, sau phn ng thu c m gam rn.
13

www.daykemquynhon.ucoz.com

Bi dng kin thc vn ha cho hc sinh cp 2 + 3

Mi lin h V1 v V2 l A. 10V1 = V2 B. V1 = 10V2 C. V1 = 2V2 D. V1 = V2 Cu 13. Hn hp X gm axetilen, etilen v hidrocacbon A chy hon ton thu c CO 2 v H2O theo t l mol 1:1. Dn X i qua bnh ng dung dch brom d thy khi lng bnh tng ln 0,82 gam, kh thot ra khi bnh em t chy hon ton thu c 1,32 gam CO 2 v 0,72 gam H2O. % V ca A trong X l A. 75 B. 50 C. 33,33 D. 25 Cu 14. Nhit si ca cc cht CH3Cl, CH3OH, HCOOH, CH4 tng theo th t l A. CH4 < CH3OH < HCOOH < CH3Cl. B. CH4 < CH3Cl < CH3OH < HCOOH. C. CH3Cl < CH4< CH3OH < HCOOH. D. CH3Cl < CH3OH < CH4 < HCOOH. Cu 15. Cho dy cht: phenyl clorua, sec-butyl clorua, natri phenolat, phenylamoni clorua, tinh bt, amoni axetat, crezol. S cht trong dy khng tc dng vi dung dch NaOH long nhit thng l A. 3 B. 6 C. 5 D. 4 Cu 16. Ngi ta iu ch etyl axetat t xenluloz v cc cht v c theo s sau: xenluloz glucoz ancol etylic axit axetic etyl axetat. Tnh khi lng xenluloz cn dng c th iu ch c 1 mol etyl axetat. Bit hiu sut chung ca qu trnh t 40%. A. 162 gam B. 405 gam C. 202,5 gam D. 506,25 gam Cu 17. t chy hon ton 2,24 lt (ktc) hn hp kh gm: CH 4, C2H4, C2H6, C3H8 thu c 6,16 gam CO2 v 4,14 gam H2O. S mol C2H4 trong hn hp trn l A. 0,03 mol. B. 0,09 mol. C. 0,01 mol. D. 0,08 mol. Cu 18. Ho tan ht m gam Al 2(SO4)3 vo nc c dung dch X. Cho 360 ml dung dch NaOH 1M vo dung dch X, thu c 2a gam kt ta. Mt khc, nu cho 400 ml dung dch NaOH 1M vo dung dch th thu c a gam kt ta. Cc phn ng xy ra hon ton, gi tr ca m l A. 19,55. B. 15,39. C. 20,52. D. 18,81. Cu 19. Hirocacbon X chay cho th tich hi nc gp 1,2 ln th tich CO 2 (o cung k). Khi tac dung vi clo tao mt dn xut monoclo duy nht. X co tn la A. etan. B. propan. C. isobutan. D. 2,2- imetylpropan Cu 20. xc nh ru ca dung dch ancol etylic (X) ngi ta ly 10ml dung dch X cho tc dng vi Na d thu c 2,564 lt H 2 (ktc). Tnh ru ca X (bit ancol etylic nguyn cht c d=0,8g/ml, nc c d=1g/ml). A. 85,580 B. 91,00 C. 92,50 D. 87,50 Cu 21. Cho V lt (ktc) hn hp kh gm 2 olefin lin tip nhau trong cng dy ng ng hp nc (xc tc H+) thu c 12,9 gam hn hp X gm 3 ancol. un nng X trong H 2SO4 c 1400C thu c 10,65 gam hn hp Y gm 6 ete khan. Gi s hiu sut cc phn ng l 100%. Cng thc phn t ca 2 olefin v gi tr ca V l A. C2H4, C3H6, 5,6 lt B. C4H8, C5H10, 5,6 lt C. C3H6, C4H8, 4,48 lt D. C2H4, C3H6, 4,48 lt Cu 22. Cho Cacbon (C) ln lt tc dng vi Al, H 2O, CuO, HNO3 c, H2SO4 c, KClO3, CO2 iu kin thch hp. S phn ng m trong C ng vai tr l cht kh? A. 6. B. 4. C. 5. D. 7.
14

www.daykemquynhon.ucoz.com
Cu 23.

Bi dng kin thc vn ha cho hc sinh cp 2 + 3

C 5 dung dch ring bit l: CuCl 2, FeCl3, AgNO3, HCl v HCl c ln CuCl 2. Nhng vo mi dung dch mt thanh Fe nguyn cht. S trng hp xut hin n mn in ha l A. 3 B. 4 C. 2 D. 1 Cu 24. Ha tan 19,5 gam hn hp gm Na 2O v Al2O3 trong nc thu c 500 ml dung dch A trong sut. Thm dn dung dch HCl 1M vo dung dch A n khi xut hin kt ta th dng li thy th tch dung dch HCl cn dng l 100 ml. Phn trm s mol mi cht trong A ln lt l A. 45% v 55% B. 25% v 75% C. 30% v 70% D. 60 % v 40% Cu 25. Hn hp X gm phenol v anilin. Ly m gam X tc dng va vi 200 ml dung dch HCl 1M thu c hn hp Y. Cho hn hp Y tc dng ht vi 500 ml dung dch NaOH 1M, ri c cn thy cn li 31,3 gam cht rn khan. Gi tr ca m l A. 18,7 B. 28 C. 65,6 D. 14 Cu 26. Cho cc phn ng ha hc sau: (1) (NH4)2SO4 + BaCl2 (2) CuSO4 + Ba(NO3)2 (3) Na2SO4 + BaCl2 (4) H2SO4 + BaSO3 (5) (NH4)2SO4 + Ba(OH)2 (6) Fe2(SO4)3 + Ba(NO3)2 Cc phn ng u c cng 1 phng trnh ion rt gn l A. (1), (2), (3), (6) B. (2), (3), (4), (6) C. (1), (3), (5), (6) D. (3), (4), (5), (6) Cu 27. X l este c to bi axit 2 chc, mch h v ancol no, 2 chc, mch h c cng thc n gin nht l C3H2O2. hidro ha hon ton 1 mol X (xt Ni, t 0) cn bao nhiu mol H2? A. 2 mol B. 4 mol C. 3 mol D. 1 mol Cu 28. Nung 13,4 gam hn hp 2 mui cacbonat ca hai kim loi ho tr 2, thu c 6,8 gam cht rn v kh X. lng kh X sinh ra cho hp th vo 75 ml dd NaOH 1M, khi lng mui khan thu c sau phn ng l A. 6,5 g B. 4,2 g C. 5,8 g D. 6,3 g Cu 29. A, B, D l 3 hp cht thm c cng thc phn t l C 7H6Cl2. Khi un nng vi dung dch NaOH long, th A phn ng theo t l mol 1: 2, B phn ng theo t l mol 1:1, cn D khng phn ng. S ng phn cu to ca A, B, D l A. 1, 3, 4 B. 1, 2, 3 C. 1, 3, 5 D. 1, 3, 6 Cu 30. Cho 28,2 gam hn hp hai ancol n chc tc dng ht vi 11,5 gam Na, sau phn ng thu 39,3 gam cht rn. Nu un 28,2 gam hn hp trn vi H 2SO4 c 1400C, th thu c bao nhiu gam ete A. 23,7 gam B. 19,2 gam C. 24,6 gam D. 21,0 gam Cu 31. Cho cc dung dch sau: NaOH, BaCl2, KHSO4, Al2(SO4)3, (NH4)2SO4. phn bit cc dung dch trn, dng thuc th no trong s cc thuc th sau th s cn tin hnh t th nghim nht? A. H2SO4 B. KOH C. Qu tm D. Ba(OH)2 Cu 32. Nu cho 1 mol mi cht: CaOCl 2, KMnO4, K2Cr2O7, MnO2 ln lt phn ng vi lng d dung dch HCl c, cht to ra lng kh Cl2 nhiu nht l A. KMnO4. B. K2Cr2O7. C. CaOCl2. D. MnO2. 2+ Cu 33. Phn ng no sau y chng t Fe c tnh kh yu hn so vi Cu?
15

www.daykemquynhon.ucoz.com
A.
2+ 2+

Bi dng kin thc vn ha cho hc sinh cp 2 + 3

B. Fe2+ + CuCu2+ + Fe Fe + Cu Fe + Cu C. Cu2+ + 2Fe2+2Fe3+ + Cu D. 2Fe3+ + Cu 2Fe2+ + Cu2+ Cu 34. Hn hp A gm 2 axit cacboxylic n chc X, Y. Cho 13,4 gam A ha tan ht vo nc ri cho tc dng vi AgNO3/NH3 d c 21,6 gam Ag. Mt khc cng lng hn hp trn trung ha va vi 100 ml dung dch NaOH 2M. CTCT ca X, Y l A. HCOOH, CH3COOH B. CH3COOH, C2H5COOH C. HCOOH, C2H5COOH D. HCOOH, C3H7COOH Cu 35. Cho glixerol (glixerin) phn ng vi hn hp axit bo gm C 17H35COOH v C15H31COOH, s loi trieste c to ra ti a l A. 8. B. 4. C. 6. D. 3. Cu 36. Nguyn t ca nguyn t X c electron mc nng lng cao nht l 3p. Nguyn t ca nguyn t Y cng c electron mc nng lng 3p v c mt electron lp ngoi cng. Nguyn t X v Y c s electron hn km nhau l 2. Nguyn t X, Y ln lt l A. kim loi v kh him. B. kim loi v kim loi. C. phi kim v kim loi. D. kh him v kim loi. Cu 37. Cho 8,04 gam hn hp hi gm CH3CHO v C2H2 tc dng hon ton vi dung dch AgNO3/NH3 thu c 55,2 gam kt ta. Cho kt ta ny vo dung dch HCl d, sau khi kt thc phn ng cn li m gam cht khng tan. Gi tr ca m l A. 61,78 B. 55,2 C. 21,6 D. 41,69 Cu 38. Cc nguyn t thuc nhm IA, theo chiu tng dn ca in tch ht nhn th A. Bn knh nguyn t tng dn. B. Tnh kh gim dn. C. Nng lng ion ho tng dn. D. m in tng dn. Cu 39. Khi lng tripeptit c to thnh t 178 gam alanin v 75 gam glyxin l A. 199g B. 235g C. 217g D. 253 g Cu 40. Cho Na tc dng vi 100ml dd AlCl 3 thu c 5,6 lt H 2(ktc) v kt ta. Lc kt ta ri em nung n khi lng khng i thu c 5,1 gam cht rn. Nng mol/l ca dd AlCl3 l A. 1,5M. B. 1,0M. C. 2,5M. D. 2,0M. 3+ 2+ + 2Cu 41. Dung dch Y gm Al ; Fe ; 0,05 mol Na ; 0,1 mol SO4 ; 0,015 mol Cl-. Cho V lt dung dch NaOH 1M vo dung dch Y thu c kt ta ln nht th gi tr ca V l A. 0,30. B. 0,40. C. 0,25. D. 0,35. Cu 42. Cho x gam P2O5 tc dng ht vi 388 ml dung dch NaOH. C cn dung dch sau phn ng thu c 3x gam cht rn. Gi tr ca x l A. 17,04. B. 14,2. C. 11,36. D. 12,78. Cu 43. Tng s proton trong ht nhn nguyn t X v Y l 25. Y thuc nhm VIIA. dng n gin n cht X tc dng vi Y. Khng nh no sau y ng? A. Cng thc oxit cao nht ca X l Y2O. B. X l kim loi, Y l phi kim. C. Cng thc oxit cao nht ca X l XO3. D. trng thi c bn X c 2 electron c thn. Cu 44. Nung 8,42 gam hn hp X gm Al, Mg, Fe trong oxi sau mt thi gian thu c 11,62 gam hn hp Y. Ha tan hon ton Y trong dung dch HNO 3 d thu c 1,344 lt NO (ktc) l sn phm kh duy nht. S mol HNO3 phn ng l A. 0,72 mol B. 0,56 mol C. 0,48 mol D. 0,64 mol

16

www.daykemquynhon.ucoz.com
Cu 45.

Bi dng kin thc vn ha cho hc sinh cp 2 + 3

Trn 100ml dung dch c pH=1 gm HCl v HNO 3 vi 100ml dung dch NaOH nng a (mol/l) thu c 200ml dung dch c pH=12. Gi tr ca a l (bit trong mi dung dch [H+][OH-]=10-14) A. 0,03 B. 0,30 C. 0,12 D. 0,15 Cu 46. Cho s sau:
+ NaOH

Cht A trong s trn l A. CH2=CHCOOC2H5 B. CH2=CHCOOC4H9 C. CH2=C(CH3)COOCH3 D. CH2=C(CH3)COOC2H5 Cu 47. Cho kh H2S tc dng vi cc cht: dung dch NaOH, kh clo, nc clo, dung dch KMnO4/H+, kh oxi d un nng, dung dch FeCl 3, dung dch ZnCl2, Pb(NO3)2, KClO3. S trng hp xy ra phn ng v s trng hp trong lu hunh b oxi ha ln S+6 l A. 6 v 1 B. 9 v 3 C. 8 v 1 D. 6 v 2 Cu 48. Hin tng no xy ra trong th nghim sau: Cho 0,1 mol Na vo 100 ml dung dch cha CuSO4 1M v H2SO4 1M (long)? A. Ch c kh bay ln. B. Ch c kt ta. C. C kh bay ln v c kt ta mu xanh. D. C kh bay ln v c kt ta mu xanh sau kt ta li tan. Cu 49. Fomalin hay fomon (dng bo qun xc ng vt chng thi ra) l A. Dung dch HCHO 25%- 30% v th tch trong nc B. Ancol C2H5OH 46o C. Dung dch CH3CHO 40% v th tch trong nc D. Dung dch HCHO 37%-40% v khi lng trong nc Cu 50. t chy hon ton hn hp gm 2 este no, h, n chc cn 5,68 g kh oxi v thu c 3,248 lt kh CO2 (ktc). Cho hn hp este trn tc dng va vi KOH thu c 2 ancol l ng ng k tip v 3,92 g mui ca mt axit hu c. Cng thc cu to ca 2 este l A. C3H7COOCH3 v CH3COOC2H5. B. HCOOCH3 v HCOOC2H5. C. CH3COOCH3 v CH3COOC2H5. D. C2H5COOCH3 v C2H5COOC2H5. ---------------------------------HT-------------------------------Th sinh khng c s dng ti liu Cho: H=1, C=12, N=14, O=16, Na=23, Mg=24, Al=27, P=31, S=32, Cl=35,5 K=39, Cr=52, Fe=56, Cu=64, Br=80, Ag=108.
17

www.daykemquynhon.ucoz.com

Bi dng kin thc vn ha cho hc sinh cp 2 + 3

P N 1 2 3 4 5 B A A A B 6 7 8 9 10 C D B C C 11 12 13 14 15 A B D B D 16 17 18 19 20 B C D D A 21 22 23 24 25 A A A D B 26 27 28 29 30 A A D D C 31 32 33 34 35 D B D D C 36 37 38 39 40 C A A C A 41 42 43 44 45 A C C D B 46 47 48 49 50 A C A D C

18