S GIO DC & O TO TRNG THPT TRN NG NINH

THI TH H LN I NM HC 2012 - 2013

Mn thi: Ha hc Thi gian lm bi: 90 pht;

H v tn: . . . . . .. . . . . . . . . .. . . . . . . . .. . .. . Lp: .. . . . . . . . . . ..

M thi 925 Cho Li = 7, Na = 23, Al = 27, Mg = 24, K = 39, Ca = 40, Fe = 56, Cu = 64, Zn = 65, Cr = 52 Ag = 108, Ba = 137, C = 12, N = 14, O = 16, H = 1, S = 32, Cl = 35,5, Br = 80 Cu 1: Nung nng hn hp gm 0,4 mol N 2 v 1,6 mol H2 trong bnh kn (c xc tc) ri a v nhit t0C thy p sut trong bnh lc ny l P 1. Sau cho mt lng d H2SO4 c vo bnh (nhit lc ny trong bnh l t 0C) n khi p sut n nh th thy p sut trong bnh lc ny l P 2 (P1 = 1,75P2). Hiu sut tng hp NH3 l: A. 65,25%. B. 50%. C. 75%. D. 60%. Cu 2: Dy gm cc kim loi u c iu ch bng phng php nhit luyn l A. Na, Ni, Cu B. Ca, Zn, Fe C. Al, Cu, Ba D. Fe, Cu, Pb Cu 3: Dy gm cc cht d b nhit phn l: A. NH4HCO3, KNO3, NH4NO2, AgNO3. B. Cu(OH)2, Mg(NO3)2, KHCO3, BaSO4 C. Cu(NO3)2, NH4Cl, Mg(HCO3)2, Na2CO3 D. CaCO3, Pb(NO3)2, (NH4)2CO3, K2CO3 Cu 4: Chia 0,30 mol hn X gm C 2H6, C2H4, C2H2 thnh hai phn bng nhau. t chy hon ton phn 1 thu c 5,40 gam H 2O. Cho phn 2 li qua dd brom (d) thy khi lng bnh nc brom tng 2,70 gam. Phn trm khi lng ca C 2H6 c trong hn hp X l A. 34,05% B. 35,71% C. 33,33% D. 71,42% Cu 5: Cho 8,4 gam Fe tc dng va vi dd cha 0,4 mol H 2SO4 c, nng (gi thit SO 2 l sn phm kh duy nht). Sau khi phn ng xy ra hon ton c cn dd c m gam mui khan. Gi tr ca m l: A. 35,2 gam B. 30 gam C. 27,6 gam D. 22,8 gam Cu 6: t chy hon ton 29,6 gam hh X gm CH3COOH ,CxHyCOOH v (COOH)2 thu c 0,8 mol H2O v m gam CO2. Cng cho 29,6 gam X tc dng vi lng d NaHCO 3 thu c 0,5 mol CO2. Gi tr ca m l A. 11. B. 33. C. 22. D. 44. Cu 7: Cho lung kh CO d i qua hn hp BaO, Al 2O3 v FeO t nng thu c cht rn X 1. Ho tan cht rn X1 vo nc thu c dd Y 1 v cht rn E1. Sc kh CO2 d vo dd Y1 thu c kt ta F1. Ho tan E1 vo dd NaOH d thy b tan mt phn v cn cht rn G 1. Cho G1 vo dd AgNO3 d (Coi CO2 khng phn ng vi nc). Tng s phn ng xy ra l: A. 7 B. 6 C. 8 D. 9 + 3+ 2Cu 8: Dd X gm 0,1 mol H , z mol Al , t mol NO3 v 0,02 mol SO4 . Cho 120 ml dd Y gm KOH 1,2M v Ba(OH)2 0,1M vo X, sau khi cc phn ng kt thc, thu c 3,732 gam kt ta. Gi tr ca z, t ln lt l : A. 0,020 v 0,012 B. 0,020 v 0,120 C. 0,120 v 0,020 D. 0,012 v 0,096 Cu 9: Cho cc pht biu sau: a) Photpho v photpho trng l hai ng phn ca nhau. b) P v P trng u khng tan trong nc, u tan trong mt s dung mi hu c nh benzen, clorofom... c) Photpho trng pht quang mu lc nht trong bng ti, photpho khng pht quang. d) Photpho trng c cu trc tinh th nguyn t, photpho c cu trc polime. e) Photpho trng hot ng mnh hn P . Trong cc phn ng P th hin tnh oxi ha hoc tnh kh. f) Khi un nng khng c khng kh, P chuyn thnh hn, khi lm lnh th hi ngng t thnh Ptrng. g) Photpho v photpho trng c ng dng sn xut dim, photpho nm u que dim. S pht biu ng l: A. 2. B. 5. C. 4. D. 3.

Cu 10: Cho hn hp X (gm CH3OH, C2H4(OH)2, C3H5(OH)3) c khi lng m gam. t chy hon ton X thu c 5,6 lt kh CO2 ( kc). Cng m gam hn hp X trn cho tc dng vi kali thu c V lt kh (ktc). Ga tr ca V bng A. 2,8 B. 11,2 C. 5,6 D. 3,36 Cu 11: Tng s ng phn va tc dng vi axit, va tc dng vi bazo ng vi cng thc phn t C2H7O2N l A. 4 B. 3 C. 1 D. 2 Cu 12: Cho hn hp gm 6,96 gam Fe 3O4 v 6,40 gam Cu vo 300 ml dd HNO 3 CM (mol/l). Sau khi cc phn ng kt thc thu c kh NO, dd X v cn li 1,60 gam Cu. Gi tr C M l A. 0,15. B. 1,20. C. 1,50. D. 0,12. Cu 13: Trong cc th nghim sau, (1) Cho kh O3 tc dng vi dd KI. (2) Nhit phn amoni nitrit. (3) Cho NaClO3 tc dng vi dd HCl c. (4) Cho kh H2S tc dng vi dd FeCl3. (5) Cho kh NH3 d tc dng vi kh Cl2. (6) Cho axit fomic tc dng vi H2SO4 c. (7) Cho H2SO4 c vo dd NaBr. (8) Cho Al tc dng vi dd NaOH. (9) Cho CO2 tc dng vi Mg nhit cao. (10) Cho dd Na2S2O3 tc dng vi dd H 2SO4 (long). s th nghim to ra n cht l: A. 7 B. 9 C. 8 D. 6 Cu 14: Cho cc pht biu sau: (a) Anehit va c tnh oxi ha va c tnh kh (b) Phenol tham gia phn ng th brom kh hn benzen (c) Anehit tc dng vi H2 (d) c xc tc Ni un nng, thu c ancol bc mt (d) Dd axit axetic tc dng c vi Cu(OH)2 (e) Dd phenol trong nc lm qu tm ha (f) Trong cng nghip, axeton c sn xut t cumen S pht biu ng l: A. 5. B. 2. C. 4. D. 3. Cu 15: Dd X gm (KI v mt t h tinh bt ). Cho ln lt tng cht sau: O 2, O3, Cl2, H2O2, FeCl3 tc dng vi dd X. S cht lm dd X chuyn mu xanh tm l : A. 5. B. 4 C. 3. D. 2. Cu 16: Th tch dd Ba(OH) 2 0,025M cn cho vo 100ml dd hn hp gm HNO 3 v HCl c pH = 1, thu c dd c pH =2 l A. 0,336 lt. B. 0,224 lt. C. 0,448 lt. D. 0,15 lt. Cu 17: Cho cc phn ng sau: a) FeO + HNO3 (c, nng) b) FeS + H2SO4 (c, nng) c) Al2O3 + HNO3 (c, nng) d) AgNO3 + dd Fe(NO3)2 0 t , Ni e) HCHO + H2 f) Cl2 + Ca(OH)2 g) C2H4 + Br2 h) glixerol + Cu(OH)2 Dy gm cc phn ng u thuc loi phn ng oxi ha - kh l A. a, b, c, d, e, g. B. a, b, c, d, e, h. C. a, b, d, e, g, h. D. a, b, d, e, f, g. Cu 18: Cho 15,6 gam hn hp X gm Mg v Al ha tan ht trong V lt dd HNO 3 1M va thu c 3,136 lt hn hp N2O v N2 (c t l th tch l 5:2 v ktc) v dd Z cha 118,8 gam mui. Th tch HNO3 cn dng l: A. 2,28 lt B. 1,88 lt C. 1,74 lt D. 1,98 lt Cu 19: Cho a mol Fe vo dd cha b mol AgNO 3, phn ng xong, dd cn li cha Fe(NO 3)2 v Fe(NO3)3 th t s b/a l A. 1 < b/a < 2 B. b/a 2 C. 2 < b/a < 3 D. b/a = 3 Cu 20: Hn hp X cha: NaHCO3, NH4NO3 v CaO (cc cht c cng s mol). Ha tan hn hp X vo H2O (d), un nng. Sau phn ng kt thc, lc b kt ta, thu c dd Y. Dd Y c mi trng A. Baz. B. trung tnh. C. Axit. D. lng tnh. 2

Cu 21: Hai hp cht hu c X, Y c cng cng thc phn t C 3H6O2. C X v Y u tc dng vi Na; X tc dng c vi NaHCO3 cn Y c kh nng tham gia phn ng trng bc. Cng thc cu to ca X v Y ln lt l A. C2H5COOH v CH3CH(OH)CHO. B. HCOOC2H5 v HOCH2COCH3. C. C2H5COOH v HCOOC2H5. D. HCOOC2H5v HOCH2CH2CHO. Cu 22: Trn 100 ml dd A (KHCO3 1M v K2CO3 1M) vo 100 ml dd B (NaHCO3 1M v Na2CO3 1M) thu c dd C; Nh t t 100 ml dd D (H 2SO4 1M v HCl 1M) vo dd C thu c V lt CO 2 (ktc) v dd E; Cho Ba(OH)2 ti d vo dd E thu c m gam kt ta. Gi tr ca m v V ln lt l A. 82,4 gam v 2,24 lt B. 82,4 gam v 5,6 lt C. 23,3 gam v 2,24 lt D. 59,1 gam v 2,24 lt Cu 23: 1 mol X c th phn ng ti a 2 mol NaOH. X c th l: (1) CH3COOC6H5 (2) ClH3NCH2COONH4 (3) ClCH2CH2Br (4) HOC6H4CH2OH (5) H2NCH2COOCH3 (6) ClCH2COOCH2Cl C bao nhiu cht X tho mn: A. 5 B. 4 C. 3 D. 2 Cu 24: Cho cc cp oxi ha kh c sp xp theo chiu tng dn tnh oxi ha ca dng oxi ha nh sau: Fe2+/Fe, Cu2+/Cu, Fe3+/Fe2+. Pht biu no sau y l ng? A. Fe3+ oxi ha c Cu thnh Cu2+. B. Cu kh c Fe3+ thnh Fe. C. Cu2+ oxi ha c Fe2+ thnh Fe3+. D. Fe2+ oxi ha c Cu thnh Cu2+. Cu 25: Cho dy cc cht: axit fomic, metyl fomiat, etanol, etanal, axit etanoic. Cht c nhit si cao nht trong dy l A. etanal B. axit etanoic. C. etan D. etanol. Cu 26: Cho cc cp dd sau: (1) Na 2CO3 v AlCl3; (2) NaNO3 v FeCl2; (3) HCl v Fe(NO3)2; (4) NaHCO3 v BaCl2; (5) NaHCO3 v NaHSO4. Hy cho bit c bao nhiu cp xy ra phn ng khi trn cc cht trong cc cp vi nhau? A. 3 cp B. 2 cp C. 4 cp D. 5 cp Cu 27: Hn hp X gm KClO3, Ca(ClO3)2, CaCl2 v KCl c tng khi lng l 83,68 gam. Nhit phn hon ton X thu c 17,472 lt O 2 (ktc) v cht rn Y gm CaCl2 v KCl. Y tc dng va 0,36 lt dd K2CO3 0,5M thu c dd Z. Lng KCl trong Z nhiu gp 22/3 ln lng KCl trong X. Phn trm khi lng KClO3 trong X l A. 23,51%. B. 47,62%. C. 58,55%. D. 81,37%. Cu 28: t a mol X l trieste ca glixerol v axit n chc, mch h thu c b mol CO 2 v c mol H2O, bit b-c=4a. Hiro ha m gam X cn 6,72 lt H 2 (ktc) thu c 39 gam X. Nu un m gam X vi dd cha 0,7mol NaOH n phn ng sau y c cn dd sau phn ng th thu c bao nhiu gam cht rn? A. 61,48 gam B. 57,2 gam C. 53,2 gam D. 52,6 gam Cu 29: Tin hnh cc th nghim sau: (1) Sc kh H2S vo dd FeSO4 (2) Sc kh H2S vo dd CuSO4 (3) Sc kh CO2 (d) vo dd Na2SiO3 (4) Sc kh CO2 (d) vo dd Ca(OH)2 (5) Nh t t dd NH 3 n d vo dd Al 2(SO4)3 (6) Nh t t dd Ba(OH) 2 n d vo dd Al2(SO4)3 Sau khi cc phn ng xy ra hon ton, s th nghim thu c kt ta l A. 6 B. 4 C. 3 D. 5 Cu 30: Dy cht no sau y u th hin tnh oxi ha khi phn ng vi SO 2? A. O3, nc clo, dd KMnO4. B. O3, H2S, nc brom. C. Dd Ba(OH)2, H2O2, dd KMnO4. D. H2SO4 c, O2, nc brom. Cu 31: Ln men m gam glucoz vi hiu sut 90%, lng kh CO 2 sinh ra hp th ht vo dd nc vi trong, thu c 10 gam kt ta. Khi lng dd sau phn ng gim 3,4 gam so vi khi lng dd nc vi trong ban u. Gi tr ca m l: A. 13,5 B. 15,0 C. 20,0 D. 30,0 Cu 32: Cho cc pht biu sau 1, Phn ng thun nghch l phn ng xy ra theo 2 chiu ngc nhau. 2, Cht xc tc lm tng tc phn ng thun v nghch. 3

3, Ti thi im cn bng trong h vn lun c mt cc cht phn ng v cc sn phm. 4, Khi phn ng t trng thi cn bng ho hc, nng cc cht vn c s thay i. 5, Khi phn ng t trng thi cn thun nghch bng ho hc, phn ng dng li. Cc pht biu sai l A. 2,3. B. 4,5. C. 3,4. D. 3,5. Cu 33: Thy phn ht hn hp gm m gam tetrapeptit Ala-Gly-Ala-Gly (mch h) thu c hn hp gm 21,7 gam Ala-Gly-Ala, 7,5 gam Gly v 14,6 gam Ala Gly. Gi tr ca m l: A. 42,16 gam. B. 43,8 gam. C. 34,8 gam. D. 41,1 gam. Cu 34: C ba dd: amoni hirocacbonat, natri aluminat, natri phenolat v ba cht lng: ancol etylic, benzen, anilin ng trong su ng nghim ring bit. Nu ch dng mt thuc th duy nht l dd HCl th nhn bit c ti a bao nhiu ng nghim? A. 4. B. 5. C. 6. D. 3. Cu 35: Cho dy cc cht: N2, H2, NH3, NaCl, HCl, H2O. S cht trong dy m phn t ch cha lin kt cng ha tr phn cc l A. 3. B. 6. C. 5. D. 4. Cu 36: Khi tin hanh ng trung hp acrilonitrin va buta-1,3-ien thu c mt loai cao su Buna-N cha 8,69% Nit v khi lng. Ti l s mol acrilonitrin va buta-1,3- ien trong cao su thu c la A. 1:1 B. 2:1 C. 3:1 D. 1:2 Cu 37: Tripeptit M v tetrapeptit Q u c to ra t mt amino axit X mch h, phn t c mt nhm -NH2. Phn trm khi lng ca N trong X l 18,667%. Thu phn khng hon ton m gam hh M, Q (t l mol 1 : 1) trong mi trng axit thu c 0,945 gam M ; 4,62 gam ipeptit v 4,125 gam X. Gi tr ca m l A. 9,69. B. 8,7. C. 8,389 D. 18,725. Cu 38: Cho 13,6 gam mt cht hu c X (C, H, O) tc dng va vi 300 ml dung dch AgNO3/NH3 2M thu c 43,2 gam kt ta. Bit t khi ca X so vi oxi l 2,125. X l A. anehit n chc, mt ni ba u mch. B. anehit no, 2 chc. C. anehit n chc, mt ni ba gia mch. D. anehit n chc, 1 ni i. Cu 39: Mt cht hu c A n chc cha cc nguyn t ( C,H,O ) v khng c kh nng trng bc. A tc dng va vi 96g dd KOH 11,66%. Sau khi phn ng c cn dd thu c 23g cht rn Y v 86,6g nc. t chy hon ton Y thu c sn phm gm 15,68 lt CO 2 ( ktc ) v 7,2g nc v mt lng K2CO3. CTCT ca A l: A. HCOO-C6H4-CH3; B. CH3COO-C6H4-CH3; C. CH3-COO-C6H5; D. CH3-C6H4-COOH; Cu 40: Dy gm cc cht u c kh nng tham gia phn ng trng hp l: A. buta-1,3-ien; cumen; etilen; trans-but-2-en. B. 1,2-iclopropan; vinylaxetilen; vinylbenzen; toluen. C. stiren; clobenzen; isopren; but-1-en. D. 1,2-icloeten; propilen; stiren; vinyl clorua. Cu 41: Cho cc cht tham gia phn ng: a, S+ F2 b, SO2 + H2S c, SO2 + O2 d, S+H2SO4(c nng) e, H2S + Cl2 (d ) + H2O f, FeS2 + HNO3 Khi cc iu kin (xt v nhit ) c s phn ng to ra sn phm m lu hunh mc s oxi ho + 6 l A. 4. B. 2. C. 3. D. 5. Cu 42: Cho dy cc cht: phenylamoni clorua, benzyl clorua, isopropyl clorua, m-crezol, ancol benzylic, natri phenolat, anlyl clorua. S cht trong dy tc dng c vi dd NaOH long, un nng l A. 4. B. 6. C. 5. D. 3. Cu 43: Loi t no sau y c iu ch bng phn ng trng hp? A. T nitron. B. T xenluloz axetat. C. T nilon-6,6. D. T visco. 4

Cu 44: Hn hp X gm 2 cht hu c mch h c cng cng thc phn t l C 4H9NO2. Cho 10,3 gam X phn ng vi 200 ml dd NaOH 1M thu c dd Z v hn hp hai kh Y (u lm xanh qu tm m) kh hn km nhau 1 nguyn t C. T khi ca Y so vi H 2 bng 13,75 C cn dd Z thu c m gam cht rn. Gi tr ca m l A. 9,75 B. 11,55 C. 15,55 D. 13,75 Cu 45: t chy hon ton 0,11 gam mt este X (to nn t mt axit cacboxylic n chc v mt ancol n chc) thu c 0,22 gam CO2 v 0,09 gam H2O. S ng phn este ca X l A. 5 B. 6 C. 4 D. 2 Cu 46: Cho 0,1 mol -aminoaxit X tc dng vi 50 ml dd HCl 1 M thu c dd A, dd A tc dng vi 250 ml dd NaOH 1 M thu c dd B, c cn dd B cn li 20,625 gam cht rn khan. Cng thc ca X l: A. HOOCCH2CH2CH(NH2)COOH. B. NH2CH2COOH. C. CH3CH(NH2)COOH. D. HOOCCH2CH(NH2)COOH. Cu 47: Hn hp X gm axetilen ( 0,15 mol), vinylaxetilen (0,1 mol), etilen ( 0,1 mol) v hiro ( 0,4 mol). Nung X vi xc tc niken mt thi gian thu c hn hp Y c t khi i vi hiro bng 12,7. Hn hp Y phn ng va vi dd cha a mol Br 2. Ga tr ca a l: A. 0,35 B. 0,65 C. 0,45 D. 0,25 Cu 48: Ha tan ht 3,84 gam Cu trong 100 ml dd hn hp gm HNO 3 0,60M v H2SO4 0,50M. Sau phn ng thu c kh NO duy nht v dd X. Khi lng mui khan thu c khi c cn dd X l? A. 9,88 gam. B. 1,88 gam. C. 8,00 gam. D. 10,00 gam. Cu 49: X l dd AlCl3, Y l dd NaOH 2 M. Thm 150 ml dd Y vo cc cha 100ml dd X, khuy u n phn ng hon ton thy trong cc c 7,8 gam kt ta. Thm tip vo cc 100 ml dd Y, khuy u n phn ng hon ton thy trong cc c 10,92 gam kt ta. Nng mol/l ca dd X bng A. 1,6 M. B. 2,0 M. C. 1,0 M. D. 3,2 M. Cu 50: Cho cht hu c A ch cha mt loi nhm chc tc dng vi 1 lt dd NaOH 0,5M thu c 24,6 gam mui v 0,1 mol ancol. Lng NaOH d c th trung ha ht bng 0,5 lt dd HCl 0,4M. Cng thc cu to thu gn ca A l A. CH3COOC2H5 B. C3H5(OCOCH3)3 C. (CH3COO)2C2H4 D. (HCOO)3C3H5 -------------------------------------------------------- HT ----------

S GIO DC & O TO TRNG THPT TRN NG NINH

1 2 3 4 5 6 7 8 9 10 C D A B C D A B D A 11 12 13 14 15 16 17 18 19 20 D B B C B D D D C B

THI TH H LN I NM HC 2012 - 2013

Mn thi: Ha hc P N
21 22 23 24 25 26 27 28 29 30 A A C A B A C C B A 31 32 33 34 35 36 37 38 39 40 B B D C A D B A C D 41 42 43 44 45 46 47 48 49 50 A C A D C D C A A B

TRNG THPT MINH KHAI c Th - H Tnh

THI TH I HC LN I MN : HO HC Thi gian lm bi : 90 pht

Ma thi: 132
H tn th sinh: .S bo danh: .. Cho bit nguyn t khi ca cc nguyn t: H = 1; C = 12; N = 14; O = 16; S = 32; Cl = 35,5; Na = 23; Mg = 24; Al = 27; Ca = 40; Cr = 52; Fe = 56; Cu = 64; Ag = 108; Ba = 137 PHN CHUNG CHO TT C TH SINH (40 cu) Cu 1: Cho dy cht CH3CH(OH)CH3; C2H2; HCOOCH3; CH2=CH-Cl; CH4; CH3CHCl2. S cht trong dy c th to ra andehit ch bng mt phn ng l A. 5 B. 3 C. 6 D. 4 Cu 2: Nung 24 gam mt hn hp Fe2O3 v CuO trong mt lung kh H2 d, phn ng hon ton. Cho hn hp kh to ra sau phn ng i qua mt bnh ng H 2SO4 c, khi lng bnh ny tng thm 7,2 gam. Tnh khi lng Fe v Cu thu c sau phn ng. A. 5,6 g Fe v 3,2 g Cu B. 11,2 g Fe v 6,4 g Cu C. 5,6 g Fe v 6,4 g Cu D. 11,2 g Fe v 3,2 g Cu Cu 3: Tnh baz ca NH3 v cc Amin c quyt nh bi A. Lin kt gia cc nguyn t trong phn t cc cht l lin kt cng ho tr phn cc B. Nit l nguyn t phi kim c m in ln C. Trn nguyn t N ca NH3 v cc amin cn c cp electron cha chia nn c kh nng nhn proton D. Nguyn t N cn c 3 electron c thn nn c kh nng nhn electron Cu 4: Dy gm cc cht c th iu ch trc tip c axit axetic l A. C2H2, CH3CHO, HCOOCH3 B. C2H5OH, CH3CHO, CH3COOCH3 C. C2H5OH, CH3CHO, HCOOCH3 D. C2H5OH, HCHO, CH3COOCH3 Cu 5: Cho 0,01 mol MgO v 0,14 mol Mg vo dd HNO 3 long, d sau khi cc phn ng hon ton thu c dd X v 0,448 lt kh Y nguyn cht (ktc). C cn dd X thu c 23 gam mui khan. Kh Y l A. N2 B. NO2 C. N2O D. NO Cu 6: Chia 18,6 gam hn hp cht hu c cng chc A, B thnh 2 phn bng nhau. t chy hon ton phn 1 cn dng 11,76 lt O 2 v thu c 10,08 lt CO 2 (cc th tch kh o ktc). un nng phn 2 vi 1 lng NaOH va thu c mt mui ca axit hu c n chc v 3,9 gam hn hp 2 ancol no n chc k tip nhau trong dy ng ng. Cng thc cu to ca A, B l A. C2H3COOH, C2H3COOC2H5 B. C2H3COOCH3, C2H3COOC2H5 C. CH3COOCH3, CH3COOC2H5 D. HCOOCH3, CH3COOC2H5 Cu 7: Ho tan hon ton m gam Fe trong dd HNO 3 thy c 0,3 mol kh NO 2 sn phm kh duy nht thot ra, nh tip dd HCl va vo li thy c 0,02 mol kh NO duy nht bay ra. C cn dd sau phn ng thu c cht rn c khi lng l A. 19,5 g B. 24,27 g C. 29,64 g D. 26,92 g

Cu 8: Cho Cu v dung dch H2SO4 long tc dng vi hp cht X(mt loi phn bn ho hc) thy to ra kh khng mu ho nu trong khng kh. Nu cho X tc dng vi dd NaOH to ra kh mi khai. Cht X l A. URE B. Natri nitrat C. Amoni nitrat D. Amophot Cu 9: bo v v tu i bin, trong cc kim loi sau: Cu, Mg, Zn, Pb nn dng kim loi no ? A. Ch c Mg, Zn B. Ch c Cu, Pb C. Ch dng Zn D. Ch dng Mg Cu 10: Mt hn hp 2 anehit A,B c tng s mol l 0,25 mol. Khi cho hn hp ny tc dng vi dung dch AgNO3 /NH3 d thu c 86,4 gam Ag kt ta v khi lng dung dch AgNO 3 gim 77,5 gam. Cng thc cu to ca A, B l: (gi thit khng c kh thot ra) A. CH3CHO, (CHO)2 B. CH3CHO, CH2 = CH CHO C. HCHO, (CHO)2 D. HCHO, CH3CHO Cu 11: X l hn hp ca N2 v H2 c t khi so vi H 2 l 4,25. Nung nng X mt thi gian trong bnh kn c xt ph hp thu c hn hp kh c t khi so vi H 2 bng 6,8. Hiu sut ca phn ng tng hp NH3 l A. 40% B. 20% C. 50% D. 75% Cu 12: Hp th 4,48 lt (ktc) kh CO2 vo 0,5 lt dd NaOH 0,4M v KOH 0,2M thu c dd X. Cho X tc dng vi 0,5 lt dd Y gm BaCl2 0,3M v Ba(OH)2 0,025M. Kt ta thu c l: A. 19,700 (g) B. 39,400 (g) C. 32,013 (g) D. 24,625 (g) Cu 13: t chy hon ton 0,1 mol mt amin no X, mch h bng oxi va thu c 0,5 mol hn hp Y gm kh v hi. Cho 4,6 gam X tc dng vi dd HCl d, s mol HCl phn ng l A. 0,4 B. 0,3 C. 0,2 D. 0,1 Cu 14: Cho x lt dd HCl 0,5M tc dng vi y lt dd NaOH 0,5M thu c dd A c pH=13. T l th tch x/y l A. 1/3. B. 3/2 C.2/3 D. 1 Cu 15: Nguyn t ca nguyn t X c electron mc nng lng cao nht l 3p. Nguyn t ca nguyn t Y c electron mc nng lng 3p v c mt electron phn lp ngoi cng. Nguyn t X v Y c s electron hn km nhau l 2. Nguyn t X,Y ln lt l A. Kim loi v kh him B. Phi kim v kim loi C. Kim loi v phi kim D. Kh him v kim loi Cu 16: Tch ring Ag ra khi hn hp Ag, Cu, Ni, Fe dng bt. Dung dch cn dng l (vn gi nguyn khi lng ca Ag ban u) A. dd H2SO4 long B. dd HCl C. dd HNO3 c ngui D. dd FeCl3 Cu 17: Ancol v amin no sau y cng bc A. (C6H5)2NH v C6H5CH2OH B. (CH3)3COH v (CH3)3CNH2 C. C6H5NHCH3 v C6H5CH(OH)CH3 D. (CH3)2CHOH v (CH3)2CHNH2 Cu 18: in phn dd cha 0,02 mol FeSO 4 v 0,06 mol HCl vi cng dng in I = 1,34 A trong 2 gi (in cc tr c mng ngn). B qua s ho tan ca kh clo trong H 2O, coi hiu sut in phn l 100%. Khi lng kim loi thot ra catot v th tch kh (ktc) thot ra anot l A. 1,12 gam v 0,896 lt B. 0,56 gam v 0,448 lt C. 5,6 gam v 4,48 lt D. 11,2 gam v 8,96 lt Cu 19: X, Y l 2 amin no, n chc mch h ln lt c phn trm khi lng ca nit l 31,11 % v 23,73 %. Cho m gam hn hp X, Y c t l mol tng ng l 1:3 tc dng vi dd HCl va thy to ra 44,16 gam mui. Gi tr ca m l A. 25,5 B. 26,64 C. 30,15 D. 10.18 Cu 20: C 4 l mt nhn X, Y, Z, T cha cc dung dch ngu nhin sau : HCl, AgNO 3, NaI, K2CO3. Bit X to kt ta vi Z, X khng i mu qu tm. Y to 1 kt ta v 1 kh vi Z, T. Vy X, Y, Z, T ln lt l A. NaI, K2CO3, HCl, AgNO3 B. AgNO3, HCl, NaI, K2CO3 C. AgNO3, NaI, HCl, K2CO3 D. NaI, HCl, AgNO3, K2CO3 Cu 21: Cho 10 ml dd ancol etilic 46 phn ng ht vi Na d thu c V lt H 2 (ktc). Bit khi lng ring ca ancol etilic nguyn cht l 0,8 g/ml. Gi tr ca V l A. 0,896 B. 4,256 C. 3,360 D. 2,128 Cu 22: C hn hp X gm 2 axit no l Y v Z. t chy hon ton 0,3 mol X thu c 11,2 lt kh CO2 (ktc). trung ho 0,15 mol X cn 500 ml dd NaOH 0,5M. Cng thc cu to ca Y v X l A. CH3COOH v C2H5COOH B. HCOOH v CH2(COOH)2

C. CH3COOH v HCOOH D. HCOOH v (COOH)2 Cu 23: Cho cc phn ng sau t a; H2S + O2 d kh X + H2O t b; NH4NO2 kh Y + H2O t c; NH4HCO3 + HCl long kh Z + NH4Cl + H2O Cc kh X, Y, Z ln lt l A. SO3, N2, CO2 B. SO2, N2, CO2 C. SO2, N2, NH3 D. SO2, N2O, CO2 Cu 24: Mt hn hp X gm CxHy mch h A c 2 lin kt trong phn t v H 2 c t khi so vi H 2 l 4,8. Nung nng X vi Ni (xt) phn ng xy ra hon ton thu c hn hp Y c t khi so vi H 2 bng 8. Cng thc v thnh phn % theo th tch ca A trong hn hp X l A. C3H4 20% B. C2H2 20% C. C3H4 80% D. C2H2 80% Cu 25: Cho phn ng : FeS2 + H2SO4 Fe2(SO4)3 + SO2 + H2O Tng h s ti gin ca phng trnh phn ng trn l A. 52 B. 46 C. 13 D. 48 Cu 26: Mt anion X c tng s ht proton, electron v ntron l 116 ht, trong s ht mang in nhiu hn s ht khng mang in l 26. V tr ca X trong bng tun hon l A. Chu k 4, nhm VII A B. Chu k 4, nhm V A C. Chu k 2, nhm VI A D. Chu k 3, nhm VII A. Cu 27: Cho m gam hn hp X gm Na2O v Al ho tan ht vo H2O d thu c 200 ml dd A ch cha mt cht tan duy nht c nng 0,2M. Gi tr ca m l A. 3,52 B. 5,36 C. 3,56 D. 2,32 Cu 28: Cho m gam ancol no, n chc X tc dng vi Na d thu c 3,36 lt H 2. Oxi ho m gam ancol ny mt thi gian thu c ( gm andehit, axit, ancol d v H 2O) . Cho ton b sn phm tc dng vi Na d thy thot ra 4,48 lt H 2.Cc th tch kh u o (ktc). Hiu sut chuyn ho ancol thnh axit l A. 33,33% B. 75,00% C. 66,67% D. 25,00 % Cu 29: Thuc th c dng phn bit tripeptit v ipeptit l A. dd NaOH B. dd HCl C. dd NaCl D. Cu(OH)2 trong mi trng kim Cu 30: Cho st phn ng va ht vi H2SO4 thu c kh A v 8,28 gam mui. Tnh s gam Fe phn ng, bit rng s mol Fe bng 37,5 % s mol H 2SO4 phn ng: A. 5,52 g B. 2,52 g C. 1,92 g D. 19,2 g Cu 31: Hp cht X c cng thc phn t C 7H8O2, khi tham gia phn ng vi Na thu c s mol H 2 bng s mol X phn ng , cn khi tc dng vi NaOH ch phn ng vi t l mol 1:1. S ng phn tho mn ca X l A. 3 B. 2 C. 4 D. 5 Cu 32: Cho dd NH3 n d vo dd cha 3 mui FeCl 3, AlCl3, ZnCl2 thu c kt ta X. Nung X n khi lng khng i c cht rn Y. Cho lung kh H 2 d i qua Y nung nng c cht rn Z. Z cha A. Al2O3 v Fe B. Al, Zn, Fe C. Al v Zn D. Al2O3, Zn v Fe Cu 33: Nhn nh khng ng v kim loi kim l A. Kim loi kim c tnh kh gim dn t Li n Cs B. Kim loi kim u c cng 1 kiu mng tinh th C. bo qun kim loi kim, ngi ta ngn n trong du ho. D. Kim loi kim u c 1 electron lp ngoi cng Cu 34: Cho 0,1 mol cht hu c X, mch h (ch cha mt loi nhm chc) phn ng va vi 100 g dd NaOH 8% thu c 13,4 gam mui ca mt axit hu c v 9,2 gam mt ancol. Bit mt trong 2 cht axit hoc ancol l n chc. Tn gi ca X l A. Etylen Diaxetat B. Dietyl Oxalat C. Dimetyl Oxalat D. Etylen Difomiat Cu 35: Cho tt c cc ng phn mch h ca hp cht c cng thc phn t C 2H4O2 ln lt tc dng vi Na, NaOH, NaHCO3. S phn ng ho hc xy ra l A. 4 B. 3 C. 5 D. 6 Cu 36: Chia 2,29 gam hn hp X gm 3 kim loi Zn, Mg, Al thnh 2 phn bng nhau. Phn 1 ho tan hon ton trong dung dch HCl gii phng 1,456 lt H 2(ktc), phn 2 oxi ho hon ton thu c ti a m gam hn hp 3 oxit. Gi tr ca m l

A. 2,75 B. 2,85 C. 2,185 D. 2,15 Cu 37: Thuc th no sau y phn bit cc dd: glucoz, glixerol, etanol v lng trng trng A. NaOH B. AgNO3/NH3 C. Cu(OH)2 D. HNO3 Cu 38: Cht X c cng thc phn t l C 5H10O2. Bit X tc dng vi Na v NaHCO 3. C bao nhiu cng thc cu to tho mn? A. 4 B. 3 C. 6 D. 5 Cu 39: Cho 1 mol amino axit X phn ng vi HCl d, thu c m 1 gam mui Y. Cng 1 mol amino axit X phn ng vi dung dch NaOH d thu c m2 gam mui Z. Bit m2 m1 = 7,5. Cng thc ca X l A. C5H11O2N B. C4H8O4N2 C. C5H9O4N D. C4H10O2N2 Cu 40: T NH3 ngi ta iu ch HNO3 theo s : NH3 NO NO2 HNO3 T 11,2 lt kh NH3 (ktc) c th iu ch c 200 ml dd HNO 3 x (M). Gi tr ca x l ( bit hiu sut c qu trnh chuyn ha l 56% ). A. 2,5 B. 1,2 C. 1,4 D. 0,8 PHN RING 10 CU Th sinh ch c lm mt trong hai phn Phn 1: Theo chng trnh chun (T cu 41 n cu 50) Cu 41: Cho 11,64 gam hn hp X gm axit axetic, phenol, o- crezol tc dng va vi 120 gam dd NaOH 4% tao thnh m (g) mui. Gi tr ca m l A. 14,28 B. 15,84 C. 13,26 D. 15,03 Cu 42: Cu no sau y l ng A. Khi phn ng thun nghch trang thi cn bng th phn ng dng li B. Ch c nhng phn ng thun nghch mi c trng thi cn bng ho hc C. Bt c phn ng no cng phi t n trng thi cn bng ho hc D. trng thi cn bng, khi lng cc cht hai v ca phng trnh ho hc phi cn bng Cu 43: t chy hon ton 0,025 mol hn hp axit acrylic v axit propionic, hp th sn phm vo 2,8 lt dd Ca(OH)2 0,02 M thu c bao nhiu gam kt ta? A. 7,5 g B. 5,6g C. 3,5 g D. 3,7 g Cu 44: Hp cht no sau y thuc loi dipeptit A. H2N-CH2-NH-CH2COOH B. H2N-CH2CO-NH-CH(CH3)-COOH C. H2N-CH2-CH2-CO-NH-CH2-CH2-COOH D. H2N-CH2-CH2-CO-NH-CH2-COOH Cu 45: Oxi ho m gam hn hp X gm andehit axetic v andehit acrylic bng O 2 c xc tc c (m+3,2) gam hn hp 2 axit. Cho m gam X tham gia phn ng trng bc c P (gam) Ag kt ta. Gi tr ca P l A. 32,4 B. 21,6 C. 43,2 D. 10,8 Cu 46: Cho dd X cha 0,1 mol Al3+, 0,2 mol Mg2+, 0,2 mol NO3-, x mol Cl-, y mol Cu2+. Nu cho dd X tc dng vi dd AgNO3 d th thu c 86,1 gam kt ta. Nu cho 850 ml dd NaOH 1M vo dd X th khi lng kt ta thu c l A. 25,3 g B. 21,05 g C. 26,4 g D. 20,4 g Cu 47: Hn hp X gm 2 cht hu c . Cho X phn ng va vi 100 ml dd NaOH 5M , sau phn ng thu c hn hp 2 mui ca 2 axit no n chc v mt ancol no n chc Y. Cho ton b Y tc dng ht vi Na c 3,36 lt kh H 2. Mt khc, nu t chy ton b mt lng khc cng ca X cn dng ht 6,496 lt O2 v thu c 5,824 lt CO2 (cc th tch kh o ktc). Cng thc cu to cc cht trong X A. CH3COOH, C2H5COOH B. HCOOCH3 C. H-COOC2H5, CH3COOH D. CH3COOH, C2H5COOCH3 Cu 48: Nung m gam hn hp X gm Cu(NO 3)2 v AgNO3 trong bnh kn khng cha khng kh, sau phn ng hon ton thu c cht rn Y v 10,64 lt hn hp kh Z(ktc). Cho Y tc dng vi dd HCl d, kt thc phn ng cn li 16,2 gam cht rn khng tan. Gi tr ca m l A. 44,30 B. 52,80 C. 47,12 D. 52,50 Cu 49: Cho hn hp X gm K2O, NH4Cl, KHCO3 v CaCl2 ( s mol mi cht u bng nhau ) vo nc d, un nng thu c dd cha A. KHCO3, KOH, CaCl2, NH4Cl B. KCl C. KCl, KOH D. KCl, K2CO3, CaCl2

Cu 50: Pht biu no sau y l ng ? A. Sc kh Cl2 vo dd NaOH long, nng thu c nc giaven B. Nc c cu trc mng tinh th phn t C. Cho tinh th NaI vo dd H2SO4 c, un nng thu c HI. D. Cng thc oxit cao nht ca Flo l F2O7 Phn 2: Theo chng trnh nng cao (T cu 51 n cu 60). Cu 51:Tnh pH ca dd A gm HF 0,1M v NaF 0,1M.Bit hng s axit ca HF l Ka = 6,8.10 -4. A. 1,37 B. 2,18 C. 3,17 D. 1,18 Cu 52: Ly 21,6 gam Al cho tc dng vi HNO3 long d thu c dd A v 4,48 lt kh (ktc) gm hn hp kh B l N2O v kh X. Lm bay hi A thu c 176,4 gam mui khan. Kh X l A. N2 B. NO2 C. NO D. N2O Cu 53: T Lapsan thuc loi A. T axetat B. T visko C. T Poli ESTE D. T Poli Amit Cu 54: C 5,668 gam cao su BuNa S phn ng va ht vi 3,462 gam Brom trong CCl 4. T l mt xch Buta ien v Stiren trong cao su BuNa S l A. 2/ B. 1/2 C.1/3 D. 2/5 Cu 55: Cht git ra tng hp c u im A. D kim. B. R tin hn x phng C. C th git c trong nc cng. D. C kh nng ho tan tt trong nc Cu 56: Cng thc tng qut ca andehit no n chc c th l cng thc no trong s cc cng thc sau A. CxHyCHO ( ,y B. CxH2xO ( , nguyn) C. CxH2x+1CHO ( , nguyn) D. C B v C u ng Cu 57:S ng phn cu to ca C5H10 phn ng c vi dd Brom l: A. 8 B. 9 C. 10 D. 7 Cu 58: Cho 0,1 mol FeCl3 tc dng vi dung dch Na2CO3 d, thu c cht kh v kt ta. Ly kt ta em nung nhit cao n khi lng khng i th s gam cht rn thu c l A. 5,6 (g) B. 8 (g) C. 11,2 (g) D. 16 (g) Cu 59: Cho 16 gam hn hp gm Fe, Cr tc dng vi lng va dd H 2SO4 (long nng), thu c 6,72 lt kh H2(ktc) v dd A. Cho 350 ml dd Ba(OH) 2 1M vo dd A, trong khng kh cho n khi phn ng xy ra hon ton, thu c m gam kt ta. Gi tr ca m l A. 69,90 B. 80,60 C.90,9 D.96,45 Cu 60: Kh no sau y c trong khng kh lm cho cc dng bng bc lu ngy b xm en ? A. CO2 B. SO2 C. O2 D. H2S ---------------------------------------------------------- HT ----------

AP AN THI TH T 1 MN HOA HOC 1D 11D 21B 31A 41A 51C 2B 12D 22D 32A 42B 52B 3C 13C 23B 33A 43D 53C 4B 14C 24A 34B 44B 54B 5A 15B 25B 35C 45C 55C 6B 16D 26A 36C 46D 56D 7D 17C 27D 37C 47C 57A 8C 18A 28A 38A 48A 58B 9A 19B 29D 39C 49C 59C 10D 20D 30B 40C 50B 60D

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