BI TP ANKAN Cu 1 : Khi t chy hon ton V lt hn hp kh CH4,C2H6,C3H8 thu c 44 gam CO2 v 28,8 gam H2O . Gi tr ca V l A. 8,96 B. 11,2 C.

13,44 D. 15,68 Cu 2 : Cho butan qua xc tc ( nhit cao) thu c hn hp X gm C4H10,C4H8,C4H6,H2. T khi ca X so vi butan l 0,4 . Nu cho 0,6 mol X tc dng vi dung dch Brom d th s mol Brom ti a phn
ng l : A. 0,48 B. 0,36 C. 0,6 D. 0,24 Cu 3 : t chy hon ton 6,72 lt hn hp A gm CH4,C2H6,C3H8,C2H4 v C3H6 thu c 11,2 lt kh CO2 v 12,6 gam H2O . Tng th tch ca C2H4 v C3H6 trong hn hp A l A. 5,6 B. 3,36 C. 4,48 D. 2,24 Cu 4 : t chy hon ton m gam hn hp X gm 2 hidrocacbon thuc cng dy ng ng cn dng 6,16 lt O2 v thu c 3,36 lt CO2 . Gi tr ca m l A. 2,3 gam B. 23 gam C. 3,2 gam D. 32 gam Cu 5 : Cracking 40 lt n-Butan thu c 56 lt hn hp A gm H2,CH4,C2H4,C2H6,C3H6,C4H8 v mt phn C4H10 cha b cracking ( cc kh o cng iu kin ). Gi s ch c cc p to ra cc sn phm trn . Hiu sut phn ng to hn hp l A. 40% B. 20% C. 80% D. 60% Cu 6 : t chy hon ton m gam hp cht hu c A. Sn phm thu c hp th vo nc vi trong d thu c 4 gam kt ta. Lc kt ta cn li bnh thy khi lng bnh nc vi trong gim 1,376 gam. A c CTPT l A. CH4 B. C5H12 C. C3H8 D. C4H10 Cu 7 : Trn 2 th tch bng nhau ca C3H8 v O2 ri bt tia la in t chy hn hp . Sau phn ng lm lnh hn hp ( hi nc ngng t) ri a v iu kin ban u. Th tch hn hp sn phm khi y ( V2) so vi th tch hn hp kh ban u ( V1) l A. V2=V1 B. V2>V1 C. V2=0,5V1 D. V2/V1=7/10 Cu 8 : t chy hn hp X gm 2 hidrocacbon l ng ng k tip , sau phn ng thu c VCO2:VH2O=1:1,6 ( o cng k) . X gm A. CH4 v C2H6 B. C2H4 v C3H6 C. C2H2 v C3H6 D. C3H8 v C4H10 Cu 9 : t chy hon ton hn hp X gm 2 hidrocacbon thuc cng dy ng ng ri hp th ht sn phm chy vo bnh ng nc vi trong d thu c 25 gam kt ta v khi lng nc vi trong gim 7,7 gam . CTPT ca 2 hidrocacbon trong X l A. CH4 v C2H6 B. C2H6 v C3H8 C. C3H8 v C4H10 D. C4H10 v C5H12 Cu 10 : Khi cracking hon ton 1 ankan X thu c hn hp Y ( cc kh o cng iu kin ), t khi ca Y so vi H2 bng 14,5 .Cng thc ca X l A. C6H14 B. C3H8 C. C4H10 D. C5H12 p n : 1C

2B 3D 4A 5A 6B 7C 8A 9B 10B

BI TP ANKEN
Cu 1 : t chy hon ton 20 ml hn hp X gm C3H6,CH4,CO ( th tch CO gp 2 ln th tch CH4) thu c 24ml CO2 ( cc kh o cng iu kin) . T khi ca X so vi H2 l A. 12,9 B. 25,8 C. 22,2 D. 11,1 Cu 2 : kh hon ton 200 ml dung dch KMnO40,2M to thnh cht rn mu nu en cn V lt kh C2H4 (ktc) . Gi tr ti thiu ca V l

A. 2,24 B. 2,688 C. 4,48 D. 1,344 Cu 3 : 0,05 mol hodrocacbon X lm mt mu va dung dch cha 8 gam brom cho ra sn phm c hm lng brom t 69,56%. Cng thc phn t ca X l A. C3H6 B. C4H8 C. C5H10 D. C5H8 Cu 4 : Hn hp X gm 2 olefin ng ng k tip. t chy 5 lt X cn va 18 lt O2 cng iu kin . Dn X vo H2O c xc tc thch hp thu c hn hp Y trong t l v s mol cac ru bc I so vi bc II l 7:3 . Tnh % khi lng ru bc II trong Y A. 34,88 B. 53,57% C. 66,67% D. 23,07% Cu 5 : Cho hn hp X gm Etilen v H2 c t khi vi H2 l 4,25 . Dn X qua bt Niken nung nng ( hiu sut p l 75%). T khi ca Y so vi H2 l A. 5,23 B. 3,25 C. 5,35 D. 10,46 Cu 6 : X,Y,Z l 3 hidrocacbon k tip trong dy ng ng , trong MZ=2MX . t chy hon ton 0,1 mol Y ri cho hp th ton b sn phm chy v 2 lt dung dch Ba(OH)2 0,1M c 1 lng kt ta l A. 19,7 B. 39,4 C. 59,1 D. 9,85 Cu 7 : Hn hp kh A ktc gm 2 olefin . t chy 7 th tch A cn 31 th tch O2 (ktc). Bit Olefin cha nhiu C chim khong 4050% th tch hn hp. CTPT ca 2 olefin l A. C2H4 v C3H6 B. C3H6 v C4H8 C. C2H4 v C4H8 D. A hoc C ng Cu 8 : Mt hn hp X gm 2 hidrocacbon A,B c cng s nguyn t C . A,B ch c th l ankan hoc anken. t chy 4,48 lt(ktc) hn hp X thu c 26,4 gam CO2 v 12,6 gam H2O. CTPT v s mol ca A,B l A. 0,1 mol C3H8 v 0,1 mol C3H6 B. 0,2 mol C2H6 v 0,2 mol C2H4 C. 0,08 mol C3H8 v 0,12 mol C3H6 D. 0,1 mol C2H6 v 0,2 mol C2H4 Cu 9 : t chy hon ton 1 mol Anken X thu c CO2 v hi nc. Hp th hon ton sn phm bnng 100 gam dung dch NaOH21,62% thu c dung dch mi trong nng ca NaOH ch cn 5%. CTPT ca X l A. C2H4 B. C3H6 C. C4H8 D. C5H10 Cu 10 : Cho 10 lt hn hp kh (54,6oC, 0,8064 atm) gm 2 olefin li qua bnh ng dung dch Brom thy khi lng bnh tng 16,8 gam. CTPT 2 olefin l ( Bit s C trong cc anken khng vt qu 5 ) A. C2H4 v C5H10 B. C3H6 v C5H10 C. C4H8 v C5H10 D. A hoc B p n : 1A 2D 3C 4A 5A 6A 7C 8A 9A 10D

BI TP ANKIN
Cu 1 : Hn A gm H2,C3H8,C3H4 . Cho t t 12 lt A qua bt Niken xc tc .Sau p thu c 6lt kh duy nht . T khi ca A so vi H2 l A. 11 B. 22 C. 26 D. 13 Cu 2 : Hn hp X gm 3 kh C3H4,C2H2 v H2 . Cho X vo bnh kn dung tch 9,7744 lt 25oC p sut 1 atm , cha 1 t bt Ni . Nung nng bnh mt thi gian thu c hn hp kh Y c dX/Y=0,75 . S mol H2 tham gia p l A. 0,75 B. 0,3 C. 0,15 D. 0,1 Cu 3 : Hn hp ban u gm 1 ankin, 1 anken v 1 ankan v H2 vi p sut 4 atm. un nng bnh vi Ni xt thc hin p cng sau a bnh v nhit ban u thu c hn hp kh Y , p sut l 3 atm. T khi ca X v Y so vi H2 ln lt l 24 v x . Gi tr ca x l A. 18 B. 34 C. 24 D. 32 Cu 4 : t chy hon ton 1 th tch gm C2H6 v C2H2 thu c CO2 v H2O c t l mol l 1:1. Phn trm th tch mi kh trong hn hp u ln lt l

A. 50%, 50% B. 30%, 70% C. 25% ,75% D. 70% ,30% Cu 5 : Cho hn hp X gm CH4,C2H4, v C2H2 . Ly 8,6 gam X tc dng ht vi dung dch brom d th khi lng brom p l 48 gam. Mt khc nu cho 13,44 lt (ktc) hn hp kh X tc dng vi lng d AgNO3/NH3, thu c 36 gam kt ta . Phn trm th tch CH4 trong hn hp l A. 40% B. 20% C. 25% D. 50% Cu 6 : A l hn hp gm C2H6,C2H4 v C3H4 . Cho 6,12 gam A tc dng vi lng d dung dch AgNO3/NH3 thu c 7,35 gam kt ta. Mt khc, 2,128 lt A (ktc) p va vi 70ml dung dch Brom 1M. %C2H6 (theo khi lng) trong 6,12 gam A l A. 49,01% B. 52,63% C. 18,3% D. 65,35% Cu 7 : t chy hon ton 1 ankin X th kh thu c CO2 v H2O c tng khi lng l 23gam. Nu cho sn phm chy qua dung dch Ca(OH)2 d thu c 40 gam kt ta . CTPT ca X l A. C3H4 B. C2H2 C. C4H6 D. C5H8 Cu 8 : Trong bnh kn cha hidrocacbon A th kh v O2 (d). Bt tia la in t chy ht A , a hn hp v iu kin ban u trong % th tch ca CO2 v hi nc ln lt l 30% v 20% . Cng thc ca A v %A trong hn hp l A. C3H4 ;10% B. C3H4 ;10% C. C3H8 ;20% D. C4H6 ;30% Cu 9 : Cho 4,48 lt hn hp X gm 2 hidrocacbon mch h li t t qua bnh cha 1,4 lt dung dch Brom 0,5M. Sau khi p hon ton , s mol Brom gim i mt na v khi lng bnh tng thm 6,7gam. CTPT ca 2 hidrocacbon l A. C3H4 v C4H8 B. C2H2 v C3H8 C. C2H2 v C4H8 D. C2H2 v C4H6 Cu 10 : t chy hon ton m gam hidrocacbon th kh, nng hn khng kh thu c 7,04 gam CO2 . Sc m gam hidrocacbon ny vo nc brom d n khi p hon ton thy c 25,6 gam Brom p. Gi tr ca m l A. 2,08 B. 2 C. 10 D. C A v B p n : 1A

2D 3D 4A 5D 6A 7C 8A 9C 10B

BI TP HIDRO CACBON THM (AREN ) Cu 1 : Cho 100 ml Benzen ( d=0,879 gam/ml) tc dng vi 1 lng va brom lng ( xc tc bt Fe )thu c 80 ml brombenzen ( d=1,495 gam/ml)/ Hiu sut phn ng l A. 67,6% B. 73,49% C. 85,3% D. 65,35% Cu 2 : Nitro ha benzen thu c hn hp 2 cht hu c X,Y trong Y nhiu hn X mt nhm NO2 . t chy hon ton 12,75 gam hn hp X,Y thu c CO2 v H2O v 1,232 lt N2(ktc). Cng thc phn t v s mol ca X trong hn hp l A. C6H5NO2;0,9 B. C6H5NO2;0,09 C. C6H4(NO2)2;0,1 D. C6H5NO2;0,19 Cu 3 : t chy ht 9,18 gam 2 ng ng k tip thuc dy ng ng ca benzen A,B thu c H2O v 30,36 gam CO2 . CTPT ca A,B l A. C6H6;C7H8 B. C8H10;C9H12 C. C7H8;C9H12 D. C9H12;C10H14 Cu 4 : 1,3 gam cht A chy hon ton thu c 4,4 gam CO2 v 0,9 gam H2O . T khi ca Aso vi Oxi l d tha mn iu kin 3<d<3,5 . CTPT ca A l A. C2H2 B. C8H8 C. C4H4 D. C6H6 Cu 5 : hidro ha etylbenzen ta thu c stiren ; trng hp stiren ta c polistiren vi hiu sut 80% . Khi lng etylbenzen cn thit sn xut 10,4 tn polistiren l

A. 13,52 tn B. 10,6 tn C. 13,25 tn D. 8,48 tn Cu 6 : t 0,13 gam mi cht A,B u thu c 0,01 mol CO2 v 0,09 mol H2O . T khi hi ca A so vi B l 3. t khi hi ca B so vi H2 l 13. CTPT ca A,B l A. C2H2;C6H6 B. C6H6;C2H2 C. C2H2;C4H4 D. C6H6;C8H8 Cu 7 : t chy hon ton 1,3 gam A (CxHy) to ra 0,9 gam H2O. Cng thc ca A l A. (CH)n B. (C2H3)n C. (C3H4)n D. (C4H7)n Cu 8 : Cho a gam cht A (CxHy) chy thu c 13,2 gam CO2 v 3,6 gam H2O. Tam hp Athu c B ,mt ng ng ca ankylbenzen. Cng thc ca A,B l A. C3H6;C9H8 B. C2H2;C6H6 C. C3H4;C9H12 D. C9H12;C3H4 Cu 9 : Khi t 1,12 lt kh thin nhin cha CH4,N2,CO2 cn 2,128 lt O2 . Cc th tch o cng iu kin. Phn trm CH4 trong kh thin nhin l A. 93% B. 94% C. 95% D. 96% Cu 10 : Bit 1 mol kh axetilen chy hon ton ta ra 1 lng nhit l 1320 kJ . Nhit lng ta ra khi t chy 1 kg Axetilen l A. 50769,24kJ B.50976,2kJ C.50697,2kJ D.50679,2kJpn:1A 2B 3B 4B 5C 6B 7A 8C 9C 10A$

BI TP DN XUT HIDRO CAC BON Cu 1 : un nng 3,57 gam hn hp A gm propylclorua v phenylclorua vi dung dch KOH long, va , sau thm tip dung dch AgNO3 n d vo hn hp sau p thu c 2,87 gam kt ta . Khi lng phenylclorua c trong hn hp A l A. 2 gam B. 1,57 gam C. 1 gam D. 2,57 gam Cu 2 : Da nhn to (PVC) c iu ch theo s CH4 C2H2 CH2=CHCl (CH2CHCl)n Nu hiu sut ton b qu trnh l 20% , mun iu ch c 1 tn PVC th th tch kh thin nhin ( cha 80% metan) ktc cn dng l A. 4375m3 B. 4450m3 C. 4480m3 D. 6875m3 Cu 3 : Cht X c t khi hi so vi Metan bng 6,19 . t chy 1,98 gam X thu c 1,76 gam khCO2 v 0,72 gam H2O . Cho X tc dng vi HNO3 m c v AgNO3 thu c 2,87 gam AgCl . un nng X vi KOH/C2H5OH thu c 0,52 gam cht hu c Y. Cht X c
CTCT l A. CH3Cl B. C2H5Cl C. CH3CHCl2 D. CH2ClCH2Cl Cu 4 : Cho cc hp cht X,Y c cha vng benzen v c CTPT l C7H6Cl2 . Thy phn X v Ytrong NaOH c nhit v p sut cao . T X thu c cht X1 c CTPT l C7H6O . T Ythu c cht Y1 c CTPT l C7H7O2Na. S lng ng phn ca X,Y tha mn tnh cht trn ln lt l : A. 2,3 B. 1,3 C. 1,4 D. 2,4 Cu 5 : A,B,C l 3 hp cht thm c CTPT l C7H6Br2 . Khi un nng vi dung dch NaOHlong th A phn ng theo t l mol 1:2. B phn ng theo t l mol 1:1 cn C khng phn ng . S ng phn cu to ca A,B,C l : A. 1,3,6 B. 1,2,3 C. 1,3,5 D. 1,3,4 Cu 6 : Cho phn ng CH3CCl3+NaOH(d) (X)+NaCl+H2O CTCT ph hp ca X l A. CH3C(OH)3 B. CH3COONa C. CH3COOH D. CH3CHCl(OH)2

Cu 7 : Cho s phn ng X(C4H8Cl2) NaOH (Y) Cu(OH)2 dung dch xanh lam C bao nhiu ng phn ca X tha mn tnh cht trn ? A. 1 B. 2 C. 3 D. 4 Cu 8 : Sn phm chnh khi cho 2-bromnbutan tc dng vi dung dch KOH/C2H5OH , un nng l A. Metylxiclopropan B. But-2-on C. But-1-en D. But-2-en Cu 9 : S ng phn cha vng benzen ca cc cht c CTPT l C7H7Br v C7H6Br2 l A. 5;10 B. 4;9 C. 4;10 D. 5;8 Cu 10 : Dn xut hidrocacbon khng c ng phn cis - trans l : A. CHCl=CHCl B. CH2=CHCH2F C. CH3CH=CBrCH3 D. CH3CH2CH=CHCHClCH3

p n :

1A 2C 3D 4B 5A 6B 7C 8D 9C 10B

BI TP XC NH CTCT HP CHT HC Cu 1 : Hp cht X c cng thc n gin l C4H9ClO. CTPT no sau y ng vi X A. C4H9ClO B. C8H18Cl2O2 C. C12H27Cl3O3 D. p n khc Cu 2 : Axitcacboxylic c cng thc n gin nht l C3H4O3 . A c CTPT l A. C3H4O3 B. C6H8O6 C. C18H24O18 D. C12H16O12 Cu 3 : Mt cht hu c c t khi so vi khng kh bng 2 . t chy hon ton A thu c CO2 v H2O. C bao nhiu cng thc phn t ph hp vi A A. 2 B. 1 C. 3 D. 4 Cu 4 : Khi t chy 1 lt kh X cn 6 lt O2 thu c 4 lt CO2 v 5 lt H2O ( cc kh o cng iu kin ). CTPT ca X l : A. C4H10O B. C4H8O2 C. C4H10O2 D. C3H8O Cu 5 : t chy ht 2,3 gam hp cht hu c X cn V lt O2( ktc) . Sn phm chy cho hp th ht vo bnh ng nc vi trong d thy c 10 gam kt ta v khi lng bnh ng dung dch nc vi tng ln 7,1 gam . Gi tr ca V l A. 3,92 lt B. 3,36 lt C. 4,48 lt D. p n khc Cu 6 : t chy 1 lt hi hidrocacbon vi mt th tch khng kh( d). Hn hp kh thu c sau khi hi nc ngng t c th tch l 18,5 lt , cho qua dung dch KOH d cn 16,5 lt , cho hn hp kh i qua ng nghim cha photpho d th cn li 16 lt . Xc nh CTPT ca hp cht trn bit cc th tch o cng iu kin nhit , p sut v O2 chim 20% th tch khng kh, cn li l Nito A. C2H6 B. C2H4 C. C3H8 D. C2H2 Cu 7 : t chy hon ton 1,18 gam cht Y (CxHyN) bng mt lng khng kh va . Dn ton b hn hp kh sau p vo bnh ng dung dch Ca(OH)2 d , thu c 6 gam kt ta . Cng thc phn t Y l A. C2H7N B. C3H9N C. C4H11N D. C4H9N Cu 8 : Mt hp cht hu c Y khi t chy thu c s mol CO2 bng s mol H2O v lng oxi cn dng bng 4 ln s mol ca Y . CTPT ca Y l A. C2H6O B. C4H8O C. C3H6O D. C3H6O2 Cu 9 : t chy hon ton 0,1 mol cht X cn 6,16 lt O2 ( ktc) , thu c 13,44 lt ( ktc) hn hp CO2,N2 v hi nc . Sau khi ngng t ht hi nc thu c 5,6 lt kh c t khi so vi hidro l 20,4. CTPT ca X l : A. C2H7O2N B. C3H7O2N C. C3H9O2N D. C4H9N

Cu 10 : Trong mt bnh kn cha hi este no , n chc, mch h A ( CnH2nO2) v mt lng gp i Oxi cn thit t chy ht A nhit 140oC v p sut 0,8 atm. t chy hon ton A ri a v nhit ban u , p sut trong bnh lc ny l 0,95 atm . CTPT ca A l A. C2H4O2 B. C3H6O2 C. C4H8O2 D. C5H10O2 p n : 1A

2B 3C 4A 5B 6A 7B 8C 9A 10B D.

BI TP ESTE V CC CH S Bi 1: X phng ho 3,52 gam este X c to ra t axit n chc v ancol n chc bng dung dchNaOH va c mui Y v ancol Z. Nung nng Y vi oxi thu c 2,12 gam Natri cacbonat, khCO2 v hi nc. Ancol Z c chia lm hai phn bng nhau. Phn 1 cho tc dng vi Na va thu c kh H2 c s mol bng 1/2 s mol ancol phn ng v 1,36 gam mui. Phn 2 cho tc dng vi CuO d, nung nng c cht hu c T c phn ng trng bc. Cng thc cu to ca X l: A.HCOOC2H5 B.CH3COOCH=CH2 C.CH3COOC2H5 D.C2H5COOCH3 Bi 2: X phng ho este X n chc, no ch thu c mt cht hu c Y cha Na. C cn, sau thm NaOH/CaO ri nung nng thu c mt ancol Z v mt mui v c. t chy hon ton ancol ny thu c CO2 v hi nc theo t l v th tch l 2:3. Cng thc phn t ca este X l: A. C4H6O2 B. C3H6O2 C. C2H4O2 D. C3H4O2 Bi 3: X phng ho hon ton 9,7 gam hn hp hai este n chc X,Y cn 100 ml dung dch NaOH 1,5M. Sau phn ng, c cn dung dch thu c hn hp hai ancol ng ng k tip v mt mui duy nht. Cng thc cu to thu gn ca 2 este l: A. HCOOCH3 v HCOOCH2CH2CH3. B.CH3COOCH3 v CH3COOCH2CH3. C. C2H5COOCH3 v C2H5COOCH2CH3. D.HCOOCH3 v HCOOCH2CH3. Bi 4: Hn hp X gm 2 cht hu c mch h, cha cng mt loi nhm chc ho hc. Khi un nng 47,2 gam hn hp X vi lng d dung dch NaOH th thu c mt ancol n chc v 38,2 gam hn hp mui ca 2 axit hu c n chc, k tip nhau trong dy ng ng. Mt khc, nu t chy ht 9,44 gam hn hp X cn va 12,096 lt kh O2, thu c 10,304 lt kh CO2. Cc kh o ktc. Cng thc cu to ca cc cht trong X l: A.HCOOCH2CH=CH2 v CH3COOCH2CH=CH2 B.CH3COOCH2CH=CH2 v C2H5COOCH2CH=CH2 C.CH2=CHCOOCH2CH3 v CH3CH=CHCOOCH2CH3 D.CH2=CHCOOCH3 v CH3CH=CHCOOCH3 Bi 5: Hn hp X gm hai este n chc, l ng phn ca nhau. cng iu kin v nhit , p sut, t khi hi ca X so vi khng kh l 3,03. Nu x phng ho hon ton 22 gam X bng 250 ml dung dch KOH 1,25M (H=100%) thu c dung dch Y. C cn dung dch Y thu c 29,75gam cht rn khan. Cho lng cht rn tc dng vi axit HCl d thu c hn hp hai axit k tip nhau trong dy ng ng. Thnh phn % v khi lng cc este trong hn hp X ln lt l: A. 50%; 50% B. 60%; 40% C. 45; 65% D. 75%; 25% Bi 6: Cho hp cht X (cha C,H,O), c mch C khng phn nhnh, ch cha mt loi nhm chc tc dng va ht 91,5 ml dung dch NaOH 25% (D=1,28 g/ml). Sau khi phn ng xy ra hon ton thu c dung dch Y cha mt mui ca axit hu c, hai ancol n chc, no ng ng lin tip trung ho hon ton dung dch Y cn dng 153 ml dung dch HCl 4M. C cn dung dch sau khi trung ho th thu c hn hp hai ancol c t khi hi so vi H2 l 26,5 v 47,202 gam hn hp mui khan. Hp cht X c cng thc cu
to l:

A. C3H7OOCC4H8COOC2H5 B. CH3OOCC3H6COOC3H7 C. C3H7OOCC2H4COOC2H5 D. C2H5OOCC3H6COOC3H7 Bi 7: t chy a gam mt este X cn 11,76 lt O2 (ktc), sau phn ng thu c hn hp CO2 v hi nc. Dn hn hp ny vo bnh ng dung dch Ca(OH)2 d thy khi lng bnh tng 26,04gam v thy xut hin 42 gam kt ta trng. Bit este ny do mt axit n chc v ancol n chc to nn. Cng thc phn t ca X l: A. C4H8O2 B. C2H4O2 C. C3H6O2 D. C5H10O2 Bi 8: Khi t chy hon ton 2,75 gam hp cht hu c X n chc thu c sn phm chy ch gm 2,8 lt CO2 (ktc) v 2,25 gam H2O. Nu cho 2,75 gam X tc dng vi NaOH va n khi phn ng hon ton thu c 3 gam mui ca axit hu c Y v cht hu c Z. Tn ca X l: A. Metyl propionat B. Etyl propionat C. Etyl axetat D. Isopropyl axetat Bi 9: t chy hon ton 3,7 gam cht hu c X cn va 3,92 lt O2 (ktc) thu c CO2 v H2O c t l mol l 1:1. Bit X tc dng vi KOH to ra hai cht hu c. Cng thc phn t ca X l: A. C3H6O2 B. C3H4O2 C. C2H4O2 D. C4H8O2 Bi 10: t chy hon ton 6,24 gam mt este X (MA < 180) cn 6,272 lt kh oxi (ktc). Sn phm chy c hp th hon ton vo dung dch nc vi trong d thy c m gam kt ta, khi lng dung dch nc vi trong gim 12,8 gam. Cng thc phn t ca X l: A. C4H6O2 B. C7H10O2 C. C7H8O4 D. C7H10O4 Bi 11: Hn hp X gm axit fomic v axit axetic (t l mol 1:1). Ly 6,36 gam X tc dng vi 6,9gam ancol etylic (xc tc H2SO4) thu c 7,776 gam hn hp este, hiu sut ca cc phn ng este ho bng nhau. Gi tr ca H l: A. 60% B. 80% C. 85% D. 50% Bi 12: Cho 0,1 mol glixerol phn ng vi 0,15 axit axetic c xc tc H2SO4 c, thu c m gam este B (khng cha chc khc) vi hiu sut phn ng l 80%. Gi tr m l: A. 8,72 g B. 14,02 g C. 13,10 g D. p n khc. Bi 13: Khi cho 58,5 gam mt cht bo c thnh phn chnh l tristearin phn ng vi dung dch iot th thy cn mt dung dch cha 9,91 gam iot. Ch s iot ca mu cht bo trn l: A. 16,93 B. 16,39 C. 19,63 D. 13,69 Bi 14: Khi x phng ho 0,9 gam cht bo cn 24 ml dung dch KOH 0,25M. Ch s x phng ho ca mu cht bo l: A. 37,333 B. 3,733 C. 0,3733 D. 373,33 p n : 1C

2D 3D

4A 5A 6A 7A 8A 9A 10C 11B 12A 13A 14D

BI TP THY PHN ESTE

Cu 1: X l mt cht hu c n chc c M=88. Nu em un 2,2 gam X vi dung dch NaOH d, thu c 2,75 gam mui. Cng thc cu to thu gn ca cht no sau y ph hp vi X: A.HCOOCH2CH2CH3 B.CH3CH2CH2COOH. C.C2H5COOCH3. D.HCOOCH(CH3)2 Cu 2: X l mt este no n chc, c t khi hi i vi CH4 l 5,5. Nu em un 2,2 gam este X vi dung dch NaOH (d), thu c 2,05 gam mui. Cng thc cu to thu gn ca X l: A.C2H5COOCH3. B.HCOOCH2CH2CH3. C.CH3COOC2H5 D.HCOOCH(CH3)2 Cu 3: Cho 20 gam cht hu c X (ch cha C,H,O v mt loi nhm chc) c t khi hi so vi O2 bng 3,125, tc dng vi 0,3 mol NaOH. C cn dung dch sau phn ng thu c 23,2 gam b rn. CTCT ca X c th l: A.CH3COOCH=CHCH3. B.C2H5COOCH=CH2. C.CH2CH=CHCOOCH3 D.CH2=CHCOOC2H5.

Cu 4: un nng 0,1 mol este no, n chc mch h X vi 30 ml dung dch 20% (D=1,2 g/ml) ca mt hiroxit kim loi kim A. Sau khi kt thc phn ng x phng ho, c cn dung dch th thu c cht rn Y v 4,6 gam ancol Z, bit rng Z b oxi ho bi CuO thnh sn phm c kh nng phn ng trng bc. t chy cht rn Y th thu c 9,54 gam mui cacbonat, 8,26 gam hn hp CO2 v hi nc. Cng thc cu to ca X l: A.CH3COOCH3 B.CH3COOC2H5 C.HCOOCH3 D.C2H5COOCH3 Cu 5: Thu phn 11,18 gam este X n chc, mch h (c xc tc axit) n khi phn ng hon ton thu c hn hp hai cht hu c Y v Z. Cho Y,Z phn ng vi dung dch AgNO3/NH3 d thu c 56,16 gam Ag. Cng thc cu to ca X l: A.HCOOC(CH3)=CH2 B.CH3COOCH=CH2 C.HCOOCH=CHCH3 D.HCOOCH2CH=CH2 Cu 6: Este X no n chc lu ngy b thu phn mt phn to ra 2 cht hu c Y v Z. Mun trung ho lng axit to ra t 13,92 gam X phi dng 15 ml dung dch NaOH 0,5M. x phng ho lng este cn li phi dng thm 225 ml dung dch NaOH 0,5M. Nu oxi ho Y s c mt anehit c mch phn nhnh. Khi ho hi 0,4 gam Z c th tch bng th tch ca 0,214 gam O2. Cng thc este X l: A.CH3COOCH2CH2CH2CH3 B.CH3COOCH2CH(CH3)2 C.CH3COOCH(CH3)CH2CH3 D.C2H5COOCH2CH(CH3)2 p n : 1B 2A 3B 4A 5C 6B

BI TP AMIN
Cu 1 : Cho 15 gam hn hp cc amin gm anilin, metylamin, imetylamin, ietylmetylamin tc dng va vi 50 ml dung dch HCl1M. Khi lng sn phm thu c c gi tr l: A. 16,825 gam. B. 20,18 gam. C. 21,123 gam. D. 15,925 gam. Cu 2 : Trung ha hon ton 8,88 gam mt amin (bc 1, mch cacbon khng phn nhnh) bng axit HCl, to ra 17,64 gam mui. Amin c cng thc l : A. H2NCH2CH2CH2NH2 B. CH3CH2CH2NH2 C. H2NCH2CH2NH2 D. H2NCH2CH2CH2NH2 Cu 3 : Cho 27,45 gam hn hp X gm amin n chc, no, mch h Y v anilin tc dng va vi 350 ml dung dch HCl1M. Cng lng hn hp X nh trn khi cho phn ng vi nc brom d, thu c 66 gam kt ta. Cng thc phn t ca Y l: A. C3H9N B.C2H7N C. C4H11N D. CH5N Cu 4 : Cho hn hp X gm 2 cht hu c c cng CTPT C2H7NO2 tc dng va vi dung dchNaOH, un nng thu c dung dch Y v 4,48 lt (ktc) hn hp Z gm 2 kh (u lm xanh qu tm m). T khi ca Z i vi hidro bng 13,75. C cn dung dch Y thu c khi lng mui khan l: A. 16,5 gam B. 14,3 gam C. 8,9 gam D. 15,7 gam Cu 5 : Hn hp A cha 2 cht hu c c cng cng thc phn t C3H9O2N thy phn hon ton hn hp A bng lng va dung dch NaOH thu c hn hp X gm 2 mui v hn hp Ygm 2 amin. Bit phn t khi trung bnh X bng 73,6 vc, phn t khi trung bnh Y c gi tr l : A. 38,4 B. 36,4 C. 42,4 D. 39,4 Cu 6 : Amin RNH2 c iu ch theo phn ng : NH3+RI=>RNH2+HI. Trong RI, iot chim 81,41%. t 0,15 mol RNH2 cn bao nhiu lt O2 (ktc)? A. 7,56 lt B. 12,6 lt C. 17,64 lt D. 15,96 lt Cu 7 : t chy hon ton 5,9 gam mt hp cht hu c n chc X thu c 6,72 lt CO2; 1,12lt N2 (cc th tch o ktc) v 8,1 gam nc. Cng thc ca X l : A. C3H6N B. C3H5NO3 C. C3H9N D. C3H7NO2 Cu 8 : 13,35 gam hn hp X gm 2 amin no, n chc, mch h l ng ng k tip, tc dng va vi dung dch HCl thy to ra 22,475 gam mui. Nu t chy 13,35 gam hn hp X th sn phm chy c VCO2:VH2O=a:b (t l ti gin). Tng a+b c gi tr l:

A. 63 B. 65 C. 67 D. 69 Cu 9 : Hn hp X gm O2 v O3 c t khi so vi H2 l 22. Hn hp kh Y gm metylamin v etylamin c t khi so vi H2 l 17,833. t chy hon ton V1 lt Y cn va V2 lt X (bit sn phm chy gm CO2,H2O v N2, cc cht kh o cng iu kin nhit , p sut). T l V1:V2 l : A. 3:5 B. 5:3 C. 2:1 D. 1:2 Cu 10 : Hn hp kh X gm imetylamin v hai hidrocacbon ng ng lin tip. t chy hon ton 100 ml hn hp X bng mt lng oxi va , thu c 550 ml hn hp Y gm kh v hi nc. Nu cho Y i qua dung dch axit sunfuric c (d) th cn li 250 ml kh (cc th tch kh v hi o cng iu kin). CTPT ca hai hidrocacbon l: A. CH4 v C2H6 B. C2H4 v C3H6 C. C2H6 v C3H8 D. C3H6 v C4H8

p n :

1A 2D 3A 4B 5D 6B 7C 8C 9D 10B

BI TP CACBON HIDDRAT
Cu 1 : Lng Glucozo cn dng to thnh 1,82 gam sobitol vi hiu sut 80% l : A. 2,25 gam B. 1,8 gam C. 1,82 gam D. 1,44 gam Cu 2 : un nng dung dch cha 27 gam glucozo vi dung dch AgNO3/NH3 th khi lng Agthu c ti a l : A. 21,6 gam B. 10,8 gam C. 32,4 gam D. 16,2 gam Cu 3 : Cho 34,2 gam ng Sacarozo c ln mt t Mantozo p hon ton vi dung dch AgNO3/NH3 , thu c 0,216 gam Ag, tinh khit ca ng l : A. 98,45% B. 99,47% C. 85% D. 99% Cu 4 : Thy phn hon ton 3,42 gam hn hp X gm Sacarozo v Mantozo thu c hn hp Y . Bit Y p va vi 0,015 mol Br2. Nu em dung dch cha 3,42 gam hn hp X cho p vi AgNO3/NH3 th khi lng Ag to thnh l : A. 2,16 gam B. 3,24 gam C. 1,08 gam D. 0,54 gam Cu 5 : Khi t chy Gluxit ngi ta thu c khi lng H2O v CO2 theo t l 33:88 . Cng thc phn t ca Gluxit l : A. C6H12O6 B. C12H22O11 C. (C6H10O5)n D. Cn(H2O)m Cu 6 : Cho m gam tinh bt ln men thnh ancol etylic vi hiu sut 81% . Ton b lng kh sinh ra c hp th hon ton vo dung dch Ca(OH)2 ly d , thu c 75 gam kt ta . Gi tr ca m l : A. 75 B. 65 C. 80 D. 55 Cu 7 : Cho 10 tn khoai cha 20% tinh bt ln men ru thu c 1135,8 lt ru etylic tinh khit c khi lng ring 0,8 g/ml . Hiu sut p iu ch l A. 60% B. 70% C. 80% D. 90% Cu 8 : T 16,2 tn xenlulozo ngi ta sn xut c m tn xenlulozo trinitrat( bit hiu sut tnh theo xenlulozo l 90%). Gi tr ca m l A. 26,73 tn B. 33 tn C. 25,46 tn D. 29,7 tn Cu 9 : Th tch HNO367,5%( d=1,5 g/ml) cn dng tc dng vi xenlulozo to thnh 89,1 kg xenlulozo trinitrat l ( bit lng HNO3 b hao ht 20%) A. 55 lt B. 81 lt C. 49 lt D. 70 lt Cu 10 : sn xut ancol etylic ngi ta dng nguyn liu l mn ca v v bo t g cha 50% xenlulozo. Nu mun iu ch 1 tn ancol etylic hiu sut 70% th khi lng nguyn liu cn dng l : A. 5031 kg B. 5000 kg C. 5100 kg D. 6200 kg

p n :

1A 2C 3D 4C 5B 6A 7C 8A 9D 10A