Mater

PIEZO CERAMIC PRODUCTS
Material grade specifications Piezoelectric Ceramics

2001 May 16
Morgan Electro Ceramics
Product specification
Piezoelectric Ceramics
CONTENTS 1 2 3 4 5 6 7 8 9 MATERIAL GRADES SURVEY OF GRADES PXE 5 SPECIFICATIONS PXE 52 SPECIFICATIONS PXE 59 SPECIFICATIONS PXE 21 SPECIFICATIONS PXE 41 SPECIFICATIONS PXE 42 SPECIFICATIONS PXE 43 SPECIFICATIONS
2001 May 16
1 MATERIAL GRADES PXE 41
Material grade specifications
PXE 5 This material combines a high coupling coefficient and high piezoelectric charge constant. It is ideally suited for low-power applications. Among these are numerous non-resonant applications such as pick-up elements, fine movement control, feedback plates, microphones, pressure and acceleration sensors, and hydrophones. PXE 5 can also be used for low-power resonant applications (e.g. air transducers for remote control purposes). This grade has an excellent time stability characteristic, and a high electrical resistivity at high temperatures. PXE 52 A material with a higher permittivity and a higher charge constant than PXE 5. Due to its lower Curie point it also has a lower temperature stability. The material is suitable for sensitive detection, tone generation and for fine movement control applications. PXE 59 A material with a slightly lower permittivity and charge constant than PXE 5. Due to its high Curie temperature it has a high temperature stability and a higher stress stability than PXE 5. PXE 21 A grade which has been developed for ignition purposes. It has a high voltage constant which ensures a high voltage output. This material is suitable for impact mechanisms used for the ignition of gases and explosives.
A low-loss material for medium power applications. In particular, the high mechanical quality factor and low loss factor (even at intensive drive) make PXE 41 suitable for high power ultrasound applications at medium range temperatures and pre-stresses. Furthermore, PXE 41 can be exposed to high repetitive quasi-static loads and dynamic loads for ignition purposes PXE 42 A low -oss material for high power applications. Its low dielectric loss and high mechanical quality factor, combined with a tolerance of high temperature and mechanical stress, make it particularly suitable for the generation of ultrasonic power. It is the recommended material for ultrasonic cleaning. PXE 43 A low-loss material for high power applications. Its low dielectric loss and high mechanical quality factor, combined with very good behaviour at high electric fields and increased temperatures, make it suitable for ultrasonic welding.
2001 May 16
2 SURVEY OF GRADES
Survey of grades
The following grades, consisting of modified lead zirconate titanates, are distinguished according to their electrical and mechanical properties and field of application. Table 1 gives typical values measured on discs 16 1 mm at 21 1 C, 24 hours after poling. Table 1 Typical values PXE 5 PXE 52 PXE 59
The properties of components manufactured with these grades depend upon the dimensions of the product, the method of manufacture and on the applied voltage level. Therefore, a meaningful interpretation of the properties of the material is best made in consultation with the supplier.
PROPERTY AND SYMBOL Thermal data Curie temperature Specific heat Thermal conductivity Mechanical data Density m Compliance: E S ----33 E S ----11 E S ----55 Poisson's ratio Mechanical quality factor E for radial mode Q ---m Frequency constants: E N --P D D - = 1 2 --N --3 3 E E - = 1 2 --N --1 1 E E - = 1 2 --N --5 5 Compressive strength Tensile strength
PXE 21
PXE 41
PXE 42
PXE 43 C J/kg K W/m K
UNIT
285 420 1.2
165 420 1.2
360 420 1.2
270 420 1.2
315 420 1.2
325 420 1.2
300 420 1.2
7.8
7.8
7.9
7.8
7.9
7.8
7.8
103 kg/m3
18 15 39 0.3 75
20 16 0.3 65
18 16 45 0.35 80
19 15 0.3 75
15 12 37 0.3 1200
15 13 0.3 750
13 11 0.3 1000
1012/Pa 1012/Pa 1012/Pa
1975 1850 1450 930 >600 80
1 925 1800 1400 >600 80
1970 2060 1400 900 >600 100
2000 1900 >600 80
2175 2000 1620 950 >600 80
2200 2015 >600 80
2350 2050 >600 80
Hz m or m/s Hz m or m/s Hz m or m/s Hz m or m/s 106 Pa 106 Pa
2001 May 16
Material grade specifications
PROPERTY AND SYMBOL Electrical data Relative permittivity (0 = 8.85 1012 F/m): T - ----33 0 T - ----11 0 Resistivity T - (25 C) Time constant ----33 Dielectric loss factor tan Electro-mechanical data Coupling factor: kp k33 k31 k15 Piezoelectric charge constants: d33 d31 d15 Piezoelectric voltage constants: g33 g31 g15 Time stability (%) Coupling factor kp T Permittivity ----33 E Frequency constant N --P E Quality factor Q ---m Dielectric loss factor tan
PXE 5
PXE 52
PXE 59
PXE 21
PXE 41
PXE 42
PXE 43
UNIT
2100 1800 5 >300 20
3900 3300 1 >500 16
1850 1650 5 >100 17
2000 5 >25 15
1225 1400 1 >7 2.5
1325 1 3.5
1000 1 2 1010 m minute 103
0.68 0.75 0.38 0.66 500 215 515 24 10 33 0.5 1.0 0.5
0.70 0.80 0.39 700 280 20 10 0.6 1.0 0.3 3.0
0.66 0.71 0.37 0.68 460 195 550 28 13 37 0.1 2.0 +0.1 +0.1 0.1
0.64 0.74 0.37 450 200 25 12 1.5 2.0 0.5
0.64 0.74 0.38 0.70 325 150 480 30 12 39 1.5 1.0 0.5 10.0 10
0.61 0.70 0.34 315 130 27 11 2.5 6.0 1.5
0.53 0.66 0.30 230 100 27 11 2.0 4.5 1.0 relative change per time decade (days) 1012 C/N or m/V 1012 C/N or m/V 1012 C/N or m/V 103 Vm/N or m2/C 103 Vm/N or m2/C 103 Vm/N or m2/C
2001 May 16
3 PXE 5 SPECIFICATIONS SYMBOL d33 d31 g33 g31 kp 33 ------0 NP S 33 TC
E E T
PXE 5
TYPICAL VALUE 500 215 24 10 0.68 2100 1975 18 285 Hzm
UNIT 1012 m/V 1012 m/V 103 Vm/N 103 Vm/N

600 d33
handbook, halfpage
1000
MBW362
-d31, d33 (10-12C/N) 800
PXE5
400 -d31 200
1012/Pa C
0 20 20 60 T ( o C) 100
Fig.1
Charge constants as a function of temperature.
g31, g33 (103Vm/N)
handbook, halfpage
25
MBG949
g33
PXE5
handbook, halfpage
0.80
MBG958
k33, kp 0.75
PXE5
20
15 g31 10
0.70
k33
0.65
kp
0.60
0 20
20
60
T (oC)
100
0.55 20
20
60
T (oC)
100
Fig.2
Voltage constants as a function of temperature.
Fig.3
Coupling factors as a function of temperature.
2001 May 16
PXE 5
handbook, halfpage
3500
MBG952
/ 33 0
3000
PXE5
handbook, halfpage
20 E E s11 , s 33 (1012/Pa) 18
MBG950
E 33
PXE5
2500
16
E 11
2000
14
1500
12
1000 20
20
60
T (oC)
100
10 20
20
60
T (oC)
100
Fig.4
Dielectric constant as a function of temperature.
Fig.5
Compliances as a function of temperature.
handbook, halfpage
2200 E D N p, N 3 (Hzm) 2100
MBG951
PXE5
handbook, halfpage
350
MBG953
tan (104)
PXE5
300 N E p
2000
250
1900
D 3
200
1800
150
1700 20
20
60
T (oC)
100
100 20
20
60
T (oC)
100
Fig.6
Frequency constants as a function of temperature.
Fig.7
Dielectric loss factor as a function of temperature.
2001 May 16
E E T
PXE 52
UNIT 1012 m/V 1012 m/V 103 Vm/N 103 Vm/N

600
handbook, halfpage
(1012C/N)
1000 d31, d33 800
MBG962
PXE52
d33
400
d31
200
1012/Pa C
0 20 20 60 T (oC) 100
Fig.8
Charge constants as a function of temperature.
g31, g33 (103Vm/N)
handbook, halfpage
30
MBG963
PXE52
handbook, halfpage
0.80
MBG964
PXE52 k33
k33, kp 0.75
25
20 g33 15
0.70
0.65
kp
10
g31
0.60
5 20
20
60
T (oC)
100
0.55 20
20
60
T (oC)
100
Fig.9
Voltage constants as a function of temperature.
Fig.10 Coupling factors as a function of temperature.
2001 May 16
PXE 52
handbook, halfpage
10000
MBG965
T /
PXE52
handbook, halfpage
33 0 8000
22 E E s11 , s 33 (1012/Pa) 20
MBG966
PXE52 s E 33
6000
18 s E 11
4000
16
2000
14
0 20
20
60
T (oC)
100
12 20
20
60
T (oC)
100
Fig.11 Dielectric constant as a function of temperature.
Fig.12 Compliances as a function of temperature.
handbook, halfpage
2200 E D Np , N3 (Hzm) 2100
MBG967
PXE52
handbook, halfpage
350
MBG968
tan (104)
PXE52
300
2000
E N p D N 3
250
1900
200
1800
150
1700 20
20
60
T (oC)
100
100 20
20
60
T (oC)
100
Fig.13 Frequency constants as a function of temperature.
Fig.14 Dielectric loss factor as a function of temperature.
2001 May 16
E E T
PXE 59
UNIT 1012 m/V 1012 m/V 103 Vm/N 103 Vm/N

600 d33 400 -d31 200
handbook, halfpage
1000
MBW438
-d31, d33 (10-12C/N) 800
PXE59
1012/Pa C
0 20 20 60 T ( o C) 100
Fig.15 Charge constants as a function of temperature.
handbook, halfpage
35
MBW439
g33 (103Vm/N) 30
PXE59
handbook, halfpage
0.80
MBW440
k31, kp 0.70 kp
PXE59
25
0.60
20
0.50
15
0.40
k31
10 20
20
60
T ( oC)
100
0.30 20
20
60
T ( oC)
100
Fig.16 Voltage constants as a function of temperature.
2001 May 16
10
PXE 59
handbook, halfpage T 33/0
3500
MBW441
PXE59
handbook, halfpage E s11 12 (10 /Pa)
20
MBW442
PXE59
3000
18
2500
16
2000
14
1500
12
1000 20
20
60
T ( o C)
100
10 20
20
60
T ( oC)
100
handbook, halfpage E Np
2200
MBW443
PXE59
handbook, halfpage
350
MBW444
(Hzm) 2100
tan (104) 300
PXE59
2000
250
1900
200
1800
150
1700 20
20
60
T ( oC)
100
100 20
20
60
T (oC)
100
2001 May 16
11
E E T
PXE 21
UNIT 1012 m/V 1012 m/V 103 Vm/N 103 Vm/N

400
handbook, halfpage
(1012C/N)
600 d31, d33 500
MBG955
PXE21
d33
300 d31
200
1012/Pa C
100 20 20 60 T (oC) 100
g31, g33 (103Vm/N)
handbook, halfpage
30
MBG956
PXE21 g33
handbook, halfpage
0.80
MBG957
PXE21
k33, kp 0.75 k33
25
20
0.70
15 g31 10
0.65
kp
0.60
5 20
20
60
T (oC)
100
0.55 20
20
60
T (oC)
100
Fig.23 Voltage constants as a function of temperature.
2001 May 16
12
PXE 21
handbook, halfpage
3500
MBG959
T /
PXE21
handbook, halfpage
33 0 3000
22 E E s ,s 11 33 (1012/Pa) 20
MBG960
PXE21
E 33
2500
18
2000
16
E 11
1500
14
1000 20
20
60
T (oC)
100
12 20
20
60
T (oC)
100
handbook, halfpage
2200 E D Np , N3 (Hzm) 2100
MBG961
PXE21
handbook, halfpage
350
MBG954
tan (104)
PXE21
300 N E p 250 N D 3
2000
1900
200
1800
150
1700 20
20
60
T (oC)
100
100 20
20
60
T (oC)
100
2001 May 16
13
E E T
PXE 41
UNIT 1012 m/V 1012 m/V 103 Vm/N 103 Vm/N

160 d31 (1012C/N)
handbook, halfpage
200
MBG969
PXE41
180
140
120
1012/Pa C
100 20 20 60 T (oC) 100
handbook, halfpage
0.64
MBG970
kp 0.63
PXE41
handbook, halfpage
2500
MBG971
T 33 0 2000
PXE41
0.62
1500
0.61
1000
0.60
500
0.59 20
20
60
T (oC)
100
0 20
20
60
T (oC)
100
2001 May 16
14
PXE 41
handbook, halfpage E
15
MBG972
s 11 (1012/Pa) 14
PXE41
13
12
11
10 20
20
60
T (oC)
100
2001 May 16
15
E E T
PXE 42
UNIT 1012 m/V 1012 m/V 103 Vm/N 103 Vm/N

160 d31 (1012C/N)
handbook, halfpage
200
MBG973
PXE42
180
140
120
1012/Pa C
100 20 20 60 T (oC) 100
handbook, halfpage
0.60
MBG974
kp 0.59
PXE42
handbook, halfpage
2500
MBG975
T 33 0 2000
PXE42
0.58
1500
0.57
1000
0.56
500
0.55 20
20
60
T (oC)
100
0 20
20
60
T (oC)
100
2001 May 16
16
PXE 42
15
MBG976
s 11 (1012/Pa) 14
PXE42
13
12
11
10 20
20
60
T (oC)
100
2001 May 16
17
E E T
PXE 43
UNIT 1012 m/V 1012 m/V 103 Vm/N 103 Vm/N

110 d31 (1012C/N)
handbook, halfpage
130
MBG977
PXE43
120
100
90
1012/Pa C
80 20 20 60 T (oC) 100
handbook, halfpage
0.54
MBG978
handbook, halfpage
2500
MBG979
kp 0.52
PXE43
/ 33 0
2000
PXE43
0.50
1500
0.48
1000
0.46
500
0.44 20
20
60
T (oC)
100
0 20
20
60
T (oC)
100
2001 May 16
18
PXE 43
13
MBG980
s 11 (1012/Pa) 12
PXE43
11
10
8 20
20
60
T (oC)
100
2001 May 16
19

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PIEZO CERAMIC PRODUCTS

Material grade specifications Piezoelectric Ceramics

Morgan Electro Ceramics

Morgan Electro Ceramics

Material grade specifications

Morgan Electro Ceramics

PXE 43 C J/kg K W/m K

285 420 1.2

165 420 1.2

360 420 1.2

270 420 1.2

315 420 1.2

325 420 1.2

300 420 1.2

1012/Pa 1012/Pa 1012/Pa

1975 1850 1450 930 >600 80

1 925 1800 1400 >600 80

1970 2060 1400 900 >600 100

2000 1900 >600 80

2175 2000 1620 950 >600 80

2200 2015 >600 80

2350 2050 >600 80

Hz m or m/s Hz m or m/s Hz m or m/s Hz m or m/s 106 Pa 106 Pa

Morgan Electro Ceramics

Material grade specifications

2100 1800 5 >300 20

3900 3300 1 >500 16

1850 1650 5 >100 17

1225 1400 1 >7 2.5

1000 1 2 1010 m minute 103

0.70 0.80 0.39 700 280 20 10 0.6 1.0 0.3 3.0

0.64 0.74 0.37 450 200 25 12 1.5 2.0 0.5

0.61 0.70 0.34 315 130 27 11 2.5 6.0 1.5

Morgan Electro Ceramics

TYPICAL VALUE 500 215 24 10 0.68 2100 1975 18 285 Hzm

UNIT 1012 m/V 1012 m/V 103 Vm/N 103 Vm/N

-d31, d33 (10-12C/N) 800

400 -d31 200

Charge constants as a function of temperature.

g31, g33 (103Vm/N)

Voltage constants as a function of temperature.

Coupling factors as a function of temperature.

Morgan Electro Ceramics

Dielectric constant as a function of temperature.

Compliances as a function of temperature.

2200 E D N p, N 3 (Hzm) 2100

Frequency constants as a function of temperature.

Dielectric loss factor as a function of temperature.

Morgan Electro Ceramics

TYPICAL VALUE 700 280 20 10 0.70 3900 1925 20 165 Hzm

UNIT 1012 m/V 1012 m/V 103 Vm/N 103 Vm/N

1000 d31, d33 800

Charge constants as a function of temperature.

g31, g33 (103Vm/N)

Voltage constants as a function of temperature.

Fig.10 Coupling factors as a function of temperature.

Morgan Electro Ceramics

Fig.11 Dielectric constant as a function of temperature.

Fig.12 Compliances as a function of temperature.

2200 E D Np , N3 (Hzm) 2100

Fig.13 Frequency constants as a function of temperature.

Fig.14 Dielectric loss factor as a function of temperature.

Morgan Electro Ceramics

TYPICAL VALUE 460 195 28 13 0.66 1850 1970 18 360 Hzm