S GD - T H Tnh Trng THPT Trn Ph M 123 ( c 4 trang)

thi th i hc ln 2 nm hc 2010-2011 Mn: Ho hc Thi gian: 90 pht (khng k thi gian giao )

I. Phn chung cho tt c cc th sinh (40 cu, t cu 1 n cu 40) Cu 1. Nguyn t X c 7 eletron p. Nguyn t Y c tng s ht mang in nhiu hn s ht mang in ca X l 8 ht. Trong hp cht gia X v Y c bao nhiu electron? A. 54 B. 36 C. 64 D. 30 Cu 2. Cho cc cht sau: ancoletylic(1), metanol (2), phenol (3), nc (4), Para-nitrophenol(5). Th t tng dn ca tnh axit l: A. (4)<(2)<(1)<(3)< (5) B. (1)<(2)<(4)<(3)<(5) C. (2)<(1)<(4)<(3)<(5) D. (2)<(1)<(4)<(5)<(3) Cu 3. Cho cc phn ng sau: 1. St t oxit + dung dch H2SO4 long 2. St (III) oxit + dung dch HNO3 3. Fe(NO3)2 + ddHCl 4. St (II)hirxit + dung dch HNO3 long 5. AlCl3 +dd Na2CO3 6. dd FeCl3 + H2S Phn ng oxi ho kh l: A. 1,3,4,6 B. 3,4,5,6 C. 1,2,3,4 D. 3,4,6 Cu 4. Hp cht 2-metybut-2-en l sn phm chnh ca phn ng tch t cht no trong cc cht sau? A. 2-Brom-2-metyl butan B. 2-metyl butan 2- ol C. 3-metyl butan -2- ol D. tt c u ng Cu 5. Cho dy cc cht: Cr(OH)3 ,NaHSO4 , Ca(HCO3)2 ,NH4Cl , (NH4)2CO3 ,ZnSO4, Al(OH)3, Zn(OH)2 , CrO3. S cht trong dy c tnh cht lng tnh l: A. 6 B. 4 C. 3 D. 5 Cu 6: Trn dung dch A cha Ba2+; OH- 0,06 mol v Na+ 0,02 mol vi dung dch B cha HCO30,04 mol ; CO32- 0,03 mol v Na+. Khi lng kt ta thu c sau khi trn l: A. 3,94g B. 5,91g C. 7,88 g D. 1,71g Cu 7. Dy gm tt c cc cht u phn ng vi HCOOH l : A . AgNO3/NH3 , CH3NH2, C2H5OH, KCl B . NH3, K, Cu, NaOH, O2, H2, Na2CO3 C . AgNO3/NH3 , CH3NH2, C2H5OH, Na2CO3, KOH D . Na2O, NaCl, Fe, CH3OH, C2H5Cl Cu 8. Cho 2,13 gam hn hp X gm 3 kim loi Mg, Cu v Al dng bt, tc dng hon ton vi oxi thu c hn hp Y gm cc oxit c khi lng 3,33 g. Tnh th tch HCl 2M va phn ng ht vi Y l: A. 57 ml B. 50 ml C. 75 ml D. 90 ml Cu 9. Ngm mt cy inh st c qun dy ng vo dung dch HCl, hin tng quan st c l: A. Kh thot ra rt nhanh trn b mt cy inh st B. Kh thot ra rt nhanh trn b mt dy ng C. Kh thot ra trn b mt cy inh st v dy ng u nhau D. Khng thy kh thot ra trn b mt cy inh st cng nh dy ng Cu 10. in phn ht 0,1 mol Cu(NO3)2 trong dung dch in cc tr, th sau khi in phn khi lng dung dch gim bao nhiu gam? A. 1,6 B. 6,4 C. 8 D. 18,8 Cu 11. Hn hp X gm Na v mt kim loi kim th A c tng khi lng l 3,15 g. Ho tan ho ton X trong nc d, kt thc phn ng thy c 1,68 lt kh thot ra (ktc). Tn kim loi A l: A. Ba B. Mg C. Ca D. Sr Cu 12. S este khng no mch h c chung cng thc C 4H6O2 khi tham gia phn ng x phng ho to ra ancol no l: A. 1 B. 2 C. 3 D. 4 Cu 13. Khi thm t t dung dch cha 0,3 mol HCl vo 200 ml dung dch Na 2CO3 1M n kt thc phn ng thu c dung dch X v kh Y.Thm nc vi d vo dung dch X th thu c bao nhiu gam kt ta? A. 15 g B. 10 g C. 8 g D. 9 g Ha - M 123 Trang 1/5

Cu 14. Cho hi nc i qua than nung thu c 78,4 lt hn hp kh X(ktc) gm kh CO, CO 2, H2. Kh ht 1/2 hn hp X bng CuO (d) nng thu c cht rn Y. Ho tan hon ton Y trong dung dch HNO3 long thu c 22,4 lt (ktc) kh NO (sn phm kh duy nht). Phn trm th tch kh CO trong X l: A. 28,57 % B. 14,28 % C. 57,15 % D. 18,42 % Cu 15. Khi thu phn hon ton 500g Protein A thu c 170 g Alanin. Nu phn t khi ca A l 50.000 vc th s mt xch Alanin trong phn t A l: A. 191 B. 119 C. 291 D. 219 Cu 16. C 4 cht hu c X, Y , Z, T sau: anilin (1), Para- Crezol(2) , toluen(3) , Para- amino phenol(4). Trong : - Cht X ch tc dng vi NaOH, khng tc dng vi HCl - Cht Y ch tc dng vi HCl, khng tc dng vi NaOH - Cht Z va tc dng vi NaOH va tc dng vi HCl 4 cht X,Y,Z,T theo th t ln lt l: A. (1) ,(2),(3),(4) B. (2),(4),(3),(1) C. (2),(1),(4),(3) D. (2),(3),(4),(1) Cu 17. Cho hn hp gm BaO, FeO, Al2O3 vo nc d thu c dung dch A v phn khng tan B. Sc kh CO2 vo dung dch A thu c kt ta C. B tan mt phn trong dung dch NaOH. Kt ta C l: A. BaCO3 B. Al(OH)3 C. BaCO3, Al(OH)3 D. BaCO3, FeCO3 Cu 18. Dung dch KHCO3 c ln tp cht l K2CO3. Dng cch no sau y loi b tp cht, thu c K HCO3 tinh khit? A. Sc kh CO2 d vo ri c cn dung dch thu c B. Cho tc dng vi KOH d ri c cn dung dch thu c C. Cho tc dng vi dung dch HCl ri c cn dung dch thu c D. Cho tc dng vi BaCl2 d ri c cn dung dch thu c Cu 19. Cho 75,2 gam hn hp Fe v Cu vo 4 lit dung dch HNO 3 x mol/lit, sau phn ng thu c dung dch X v 22,4 lt kh NO(ktc). Thm dung dch H 2SO4 long d vo dung dch X li thu c 4,48 lt NO (ktc). Bit NO l sn phm kh duy nht trong 2 qu trnh. Gi tr x l? A. 1M B. 1,1M C. 1,2M D. 1,5M Cu 20. Trong s cc cht Toluen, Benzen, Propilen, Propin, ivinyl, xiclobutan, stiren, metylxiclopropan. C bao nhiu cht lm mt mu dung dch Brm? A. 3 B. 4 C. 5 D. 6 Cu 21. Bn knh nguyn t ca cc nguyn t : Li, O, F, Na c xp theo th t tng dn t tri sang phi l A. F, Li, O, Na B. F, O, Li, Na C. Li, Na , O, F D. F, Na , O, Li Cu 22. T toluen mun iu ch o-nitrobenzoic ngi ta thc hin theo s sau + X(xt, t0) +Y(xt, t0) C6H5CH3 (A) O-O2NC6H4COOH X, Y ln lt l: A. KMnO4 v HNO3 B. KMnO4 v NaNO2 C. HNO3 v H2SO4 D. HNO3 v KMnO4 Cu 23. Hn hp kh A cha hir v mt anken. T khi hi ca A i vi H 2 l 6. un nng nh A c mt xc tc Ni th A bin thnh hn hp kh B khng lm mt mu nc Brm v c t khi i vi H2 l 8. Tm cng thc phn t ca anken? A. C2H4 B. C3H6 C. C5H10 D. C4H8 Cu 24. Cho phn ng oxi ho kh sau: K2Cr2O7 + HCl KCl + CrCl 3 + Cl2 + H2O. S phn t HCl b oxi ho l A. 3 B.6 C. 8 D. 14 Cu 25. Cho 47 gam phenol tc dng vi hn hp gm 200 g HNO 3 68% v 250g H2SO4 96% .Gi s phn ng xy ra hon ton, khi lng ca axit picric sinh ra l: A. 114,5 g B. 124,5g C. 134,5 g D. 144,5g Cu 26. Oxi ho 4g ancol n chc th c 5,6 g mt hn hp X gm anehit , nc v ancol d. Cho hn hp X tc dng ht vi dung dch AgNO 3/NH3 d th s gam Ag thu c l: A. 43,2g B. 10,8g C. 2,16g D. 20,52g Cu 27. Khi lng axit axetic cha trong gim n thu c khi cho ln men 1 lt ru etylic 80 hiu sut phn ng 100%(khi lng ring ca ri etylic nguyn cht l 0,8g/ml) l: A. 83,48g B. 84,38 g C. 88,34 g D. 88,43g Ha - M 123 Trang 2/5

Cu 28. Ho tan hon ton 24,4 gam hn hp gm FeCl 2 v NaCl (c t l mol tng ng l 1:2) vo mt lng nc d thu c dung dch X. Cho dung dch AgNO 3 d vo dung dch X,sau khi phn ng xy ra hon ton sinh ra c m gam cht rn. Gi tr m l: A. 57,4g B. 28,7g C. 10,8 g D. 68,2g Cu 29. Lng Triolein cn iu ch 5,88 kg glyxerol( hiu sut 85%) l: A. 66,47 Kg B. 56,5 Kg C. 48,025 Kg D. 22,26 Kg Cu 30. Ly 14,6 g mt ipeptit to ra t glyxin v alanin cho tc dng va vi dung dch HCl 1M. Th tch dung dch HCl tham gia phn ng l: A. 0,1 lt B. 0,2 lt C. 0,3 lt D. 0,4 lt Cu 31. Thm m gam kali vo 300 ml dung dch cha Ba(OH) 2 0,1M v NaOH 0,1M thu c dung dch X. Cho t t dung dch X vo 200 ml dung dch Al 2(SO4)3 0,1M thu c kt ta Y. thu c lng kt ta Y ln nht th gi tr ca m l: A. 1,59 B. 1,17 C. 1,71 D. 1,95 Cu 32. Cho 10 gam amin n chc X bc I phn ng hon ton vi HCl d, thu c 15 gam mui. S ng phn cu to ca X l: A. 8 B. 7 C. 5 D. 4 Cu 33. Tin hnh cc th nghim sau: TH1: Cho dung dch Ba(OH)2 n d vo dung dch Al2(SO4)3 TH2: Cho dung dch NH3 n d vo dung dch AlCl3 TH3: Cho dung dch HCl n d vo dung dch NaAlO2 hoc Na[Al(OH)4] TH4: Thi CO2 n d vo dung dch Ca(OH)2 TH5: Thi CO2 n d vo dung dch NaAlO2 hoc [Na(Al(OH) 4] S th nghim thu c kt ta l: A. 2 B. 3 C. 4 D. 5 Cu 34. Cho cc dung dch: Glucz, glyxerol, axit axetic, etanol. Thuc th no sau y c th dng phn bit cc dung dch A. Cu(OH)2 trong mi trng kim B. Ag[(NH3)2]OH C. Na kim loi D. Dung dch Brm Cu 35. Hn hp X gm 2 cht hu c A,B ch cha mt loi nhm chc . Cho m gam X tc dng ht vi NaOH thu c mt mui ca axit hu c n chc v hn hp 2 ancol, tch nc hon ton hai ancol ny iu kin thch hp ch thu c mt anken lm mt mu va 24gam Br2 .Bit A,B cha khng qu 4 nguyn t cacbon trong phn t.Gi tr ca m l A . 11,1 g B. 22,2 g C. 13,2 g D. 26,4 g Cu 36. Cho 3,48 gam FeO, Fe2O3, Fe3O4 (S mol FeO = s mol Fe2O3) tc dng va vi V ml dung dch HCl 1M. Gi tr ca V l: A. 90 ml B. 60 ml C. 120 ml D. 140 ml Cu 37. Hp cht hu c A n chc cha C, H, O. t chy hon ton A ta c s mol O 2= s mol CO2 =1,5 s mol H2O. Bit A phn ng c vi dung dch NaOH v tham gia phn ng trng bc. Cng thc cu to ca A l? A. CH2=CH-COOH B. HCOOCH3 C. HCOOCH=CH2 D. HCOOCH2CH3 Cu 38. Cho cc cht sau: Xiclobutan , 2-metylpropen , but-1-en , cis-but-2-en, 2-metylbut-2-en Dy gm cc cht khi tc dng vi H2 d(c Ni, t0) cho cng mt sn phm l: A. Xiclobutan , but-1-en v cis-but-2-en B. but-1-en , 2-metylpropen v cis-but-2-en C. Xiclobutan , 2-metylbut-2-en v but-1-en D. 2-metylpropen, , cis-but-2-en v Xiclobutan Cu 39.Cho bn hn hp, mi hn hp gm 2 cht rn c s mol bng nhau: Na 2O v Al2O3; Cu v FeCl3 ; BaCl2 v CuSO4 ; Ba v NaHCO3 S hn hp c th tan hon ton trong nc d to ra dung dch l : A. 1 B. 2 C. 3 D. 4 Cu 40. Bit 20 gam hn hp X gm CH4, C2H4, C2H2 lm mt mu 132 gam Brm trong dung dch. Mt khc cng lng kh X(ktc) ny tc dng va vi dung dch AgNO 3/NH3 thu c 48 gam kt ta. Thnh phn phn trm khi lng ca kh Metan trong hn hp X l: A. 20% B. 14,5% C . 29% D. 25% II. Phn ring (10 cu) Th sinh ch c lm mt trong hai phn (Phn A hoc B) A.Theo chng trnh chun (T cu 41 n cu 50) Cu 41. Cho cn bng ho hc sau : Cr2O72- + H2O 2 CrO 42- + 2 H+ (vng da cam) ( mu vng) Ha - M 123 Trang 3/5

Mu vng da cam ca dung dch K2Cr2O7 chuyn thnh dung dch mu vng hoc c kt ta mu vng ti nu A . Thm dd NaOH hoc thm dd BaCl2 B . Thm dd H2SO4 long hoc dd NaCl C . Thm H2SO4 hoc thm dd BaCl2 D . Thm dung dch NaOH hoc dd HCl Cu 42.Trng bc hon ton 4,4 gam mt anehit X no n chc, mch h. Ton b lng bc thu c em ho tan ht vo dung dch HNO3 c nng gii phng V lt kh NO2 (sn phm kh duy nht). Sau phn ng khi lng dung dch thay i 12,4 gam(gi s hi nc bay hi khng ng k). Cng thc cu to thu gn ca X l: A. HCHO B. CH3CHO C. C2H5CHO D. C3H7CHO Cu 43. trung ho hon ton 4,8 gam hn hp X gm hai axit hu c A, B cn a mol NaOH thu c 6,78 gam mui khan. Gi tr ca a l: A. 0,05 B. 0,07 C. 0,09 D. 1,1 Cu 44. Ba cht hu c X,Y,Z mch thng c cng cng thc phn t C 2H4O2 v c tnh cht sau - X tc dng c vi Na2CO3 gii phng CO2 - Y tc dng c vi Na, c phn ng trng gng - Z tc dng c vi dung dch NaOH, khng tc dng vi Na. Cc cht X,Y,Z tha mn tnh cht trn ln lt l: A. HCOOCH3 , CH3COOH , CH2(OH)CHO B. CH3COOH , CH3O-CHO , HCOOCH3 C. CH2(OH)CHO, CH3COOH, HCOOCH3 , D. CH3COOH , CH2(OH)CHO, HCOOCH3 Cu 45. Mt dung dch c tnh cht sau: Tc dng c vi dung dch AgNO3/NH3 v Cu(OH)2 khi un nng; Ho tan c dung dch Cu(OH)2 to ra dung dch mu xanh lam; b thu phn nh axit hoc enzim. Dung dch l: A. Glucz B. Saccarz C. Mantoz D. Tt c u ng Cu 46.Cho 17,7 gam ankyl amin X tc dng vi dung dch FeCl 3 d thu c 10,7 gam kt ta. Cng thc ca X l: A. CH5N B. C2H7N C. C3H9N D. C4H9N Cu 47. C cc cp cht sau: Fe v dung dch ZnSO 4, Zn v dung dch CuSO4 , K v dung dch CuSO4, K v dung dch FeCl3 , CuCl2 v FeCl3 , Fe(NO3)2 v AgNO3 , NaHSO4 v NaHCO3. ( S cp cht xy ra phn ng iu kin thng l: A. 4 B. 6 C. 5 D. 3 Cu 48. Cho m gam hn hp cng s mol ca FeS 2 v Fe3O4 tc dng hon ton vi lng d dung dch HNO3 un nng thu c dung dch A. 14,336 lt kh B (ktc) gm NO 2 v NO c t khi so vi He l 9,5 (bit NO, NO2 l sn phm kh duy nht). S mol HNO 3 phn ng l: A. 1,92 B. 1,4 C. 1,6 D. 0,96 Cu 49. Cho cc dung dch mui: Al(NO3)3, (NH4)2SO4, NaNO3, NH4NO3, MgCl2, FeCl2 ng trong cc l ring bit b mt nhn. c dng thm mt thuc th no sau y c th phn bit c cc dung dch mui trn: A. NaOH B. BaCl2 C. AgNO3 D. Ba(OH)2 Cu 50. Trong cc dung dch: Na2CO3, KCl, CH3COONa, NH4Cl, NaHSO4, C6H5ONa. S dung dch c PH<7 l: A. 2 B. 3 C. 4 D.5 B. Theo chng trnh nng cao (T cu 51 n cu 60) Cu 51. C 5 dung dch ng ring bit trong 5 ng nghim (NH 4)2SO4, FeCl2, Cr(NO3)3, K2CO3, Al(NO3)3. Cho Ba(OH)2 n d vo 5 dung dch trn. Sau khi phn ng kt thc, s ng nghim c kt ta l: A. 3 B. 5 C. 2 D. 4 Cu 52. C dung dch hn hp AlCl3, CuCl2, ZnCl2. Dng ho cht no dng tch ly c mui AlCl3 m khng thay i khi lng? A. NH3 v HCl B. Al v HCl C. NaOH v HCl D. Na2CO3 v HCl Cu 53. Cho cn bng ho hc sau : Cr2O72- + H2O 2 CrO 42- + 2 H+ (vng da cam) ( mu vng) Cho cc yu t sau : (1 ) thm H2SO4 ; (2) thm Na2CO3 ; (3) thm NaNO3 ; (4) NaOH ; (5) BaCl2 .cc yu t lm cn bng chuyn dch theo chiu thun l : A. (1) B. (2),(3) ,(5) C. (2),(4),(5) D. (2),(4) Cu 54. t chy hon ton 0,2 mol hn hp X gm 2 axit no A v B cn 2,24 lt kh O 2(ktc). Cng thc cu to ca hai axit A v B l: A. HCOOH v CH3COOH B. HCOOH v HOOC-COOH C. CH3COOH v HOOC-COOH D. CH3COOH v HOOC-CH2-COOH Ha - M 123 Trang 4/5

Cu 55. C bao nhiu ng phn cu to mach h ca C 5H8 khi tc dng vi H2 d(Ni, t0) thu c sn phm l isopentan? A. 2 B. 3 C. 4 D. 1 Cu 56.Cho s chuyn ho sau: Tinh bt X Y axit axetic X, Y ln lt l: A. glucz, etyl axetat B. Glucz, anhit axetic C. Glucz, ancol etylic D. ancol etylic, anhit axetic Cu 57. Dng mui it hng ngy phng nga dch bnh bu c. Mui it l: A. NaCl + NaI B. I2 + NaCl C.NaCl + KI + KIO3 D. NaI + MgCl2 Cu 58. Nung m gam hn hp A gm Fe v Cu (trong Fe chim 36,84% v khi lng) trong oxi thu c 36,8 gam hn hp cht rn Y. Ho tan hon ton Y trong V ml dung dch HNO 3 2M ly d 25% so vi lng phn ng thu c 0,2 mol hn hp NO, NO2 c t khi so vi H2 bng 19 (bit NO v NO2 l sn phm kh duy nht, ktc). Gi tr ca m v V ln lt l: A. 30,4 v 875 B. 30,4 v 375 C. 29,5 v 875 D. 29,5 v 375 Cu 59. Cho 11,8 gam hn hp X gm 3 amin: Propyl amin, etyl metyl amin, trimetyl amin.Tc dng va vi V ml dung dch HCl 1M. Gi tr ca V l: A. 100 B. 150 C. 200 D. 250 Cu 60. Cho s phn ng: +Cl2, 5000C +Cl2+H2O + NaOH + Cu(OH) 2 Propilen X1 X2 X3 X 4 . S phn ng oxi ho -kh l: A. 1 B. 3 C. 4 D. 2

Ha - M 123

Trang 5/5