CODE

TEST - 13
COURSE NAME : VIKAAS (JA) & VIPUL (JB)

COURSE CODE : CLINIC CLASSES

Max. Marks : 80

TARGET : JEE (IITs) 2014

Date : 14-03-2013 Duration : 1 Hour
Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.

CHEMISTRY (THERMO CHEMISTRY) INSTRUCTIONS

A. General : 1. This Question Paper contains 22 questions. 2. 3. 4. 5. 6. 7. No additional sheets will be provided for rough work. Blank paper, clipboard, log tables, slide rules, calculators, cellular phones, pagers and electronic gadgets in any form are not allowed. The answer sheet, a machine-gradable Objective Response Sheet (ORS), is provided separately. Do not Tamper / mutilate the ORS or this booklet.

Write your Name, Roll No. and Sign in the space provide on the back page of this booklet.

B. Filling the bottom-half of the ORS : Use only Black ball point pen only for filling the ORS. Do not use Gel / Ink / Felt pen as it might smudge the ORS. 8. Write your Roll no. in the boxes given at the top left corner of your ORS with black ball point pen. Also, darken the corresponding bubbles with Black ball point pen only. Also fill your roll no on the back side of your ORS in the space provided (if the ORS is both side printed). Fill your Paper Code as mentioned on the Test Paper and darken the corresponding bubble with Black ball point pen.

9.

10. If student does not fill his/her roll no. and paper code correctly and properly, then his/her marks will not be displayed and 5 marks will be deducted (paper wise) from the total. 11. Since it is not possible to erase and correct pen filled bubble, you are advised to be extremely careful while darken the bubble corresponding to your answer. 12. Neither try to erase / rub / scratch the option nor make the Cross (X) mark on the option once filled. Do not scribble, smudge, cut, tear, or wrinkle the ORS. Do not put any stray marks or whitener anywhere on the ORS. 13. If there is any discrepancy between the written data and the bubbled data in your ORS, the bubbled data will be taken as final. C. Question paper format and Marking scheme : 14. The question paper consists of 1 parts. The part consists of Two Sections. 15. For each question in SectionI, you will be awarded 3 marks if you darken the bubble(s) corresponding to the correct choice for the answer and zero mark if no bubbled is darkened. In case of bubbling of incorrect answer, minus one (1) mark will be awarded. 16. For each question in SectionII, you will be awarded 5 marks if you darken the bubble corresponding to the correct answer and zero marks if no bubble is darkened. In case of bubbling of incorrect answer, minus one (1) mark will be awarded.

DO NOT BREAK THE SEALS WITHOUT BEING INSTRUCTED TO DO SO BY THE INVIGILATOR

Do not break the seals of the question-paper booklet before instructed to do so by the invigilators.

CHEMISTRY

Atomic masses : [H = 1, D = 2, Li = 7, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24, Al = 27, Si = 28, P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr = 52, Mn = 55, Fe = 56, Cu = 63.5, Zn = 65, As = 75, Br = 80, Ag = 108, I = 127, Ba = 137, Hg = 200, Pb = 207]

SECTION - I

Straight Objective Type

This section contains 15 questions. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of which ONLY ONE is correct. 1. The enthalpy of neutralisation of a weak monoacidic base(1M) with strong acid is 56.9 KJ/mol. If the enthalpy of ionisation of weak monoacidic base is 1.8 KJ/mol the ionisation of weak base in its molar solution is [Given that Hneutralisation of strong acid and strong base = 57.3 KJ/mol] (A) 100/3 (B) 200/3 (C) 25% (D) None of these Under the same condition how many mL of 0.1 M NaOH and 0.05 M H2A (strong diprotic acid) solution should be mixed for a total volume of 100 mL produce the highest rise in temperature : (A) 25 : 75 (B) 50 : 50 (C) 75 : 25 (D) 66.66 : 33.33 Only N2, CO and CO2 gases remain after 0.72 gm of carbon is treated with one litre of air at 27C and 4.92 atm pressure. Assume air composition O2 = 20%, N2 = 79% and CO2 = 1% (by volume). The heat evolved (in Kcal) under constant pressure is : Given : C + O2 C+ (A) 1 kcal
Space for Rough Work

2.

3.

CO2, CO,

H = 100 Kcal/mol H = 25 Kcal/mol (C) 3 kcal (D) 4 kcal

1 O 2 2

(B) 2 kcal

RESONANCE

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4.

Hf of HgO (s) is 20 kcal/mol. The mass (in gm) of mercury, which can be liberated if 800 cal of heat is given to excess of HgO (s) is : (A) 8 g (B) 12 g (C) 16 g (D) 20 g The standard heat of combustion of ethene gas is 330 Kcal mol1 calculate bond energy( in kcal/ 1 mol) assuming that bond energy of CH bond is 93.6 KCal mol Given : Hf for CO2(g) and H2O () are 94.2 and 61 Kcal mol1 respectively. Heat of atomisation of carbon and hydrogen are 150 and 51.5 Kcal mol1 respectively. (A) 82 Kcal/mol (B) 92 Kcal/mol (C) 102 Kcal/mol (D) 112 Kcal/mol A substance XY3 decomposes as :

5.

6.

XY3 The ratio of partial pressure of XY and XY2 in the mixture of gases obtained by decomposition of XY3 g) is 2 : 1. Find the total enthalpy change for the decomposition of 1 mole of XY3. (A) 53.33 kJ/mol (B) 160 kJ/mol (C) 110 kJ/mol (D) 1110.33 kJ/mol 7. If bond energy of H2, F2 and HF are in the ratio 2 : 1 : 3 and Ha (H2) = 400 kJ/mol. Then H (HF) is : (A) 0 kJ/mol (B) 600 kJ/mol (C) 1200 kJ/mol (D) None of these

Space for Rough Work

RESONANCE

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8.

2Fe +

3 Fe2O3 O 2 2

x kJ / mole y kJ / mole

2FeO 2Fe + O2

The H to form one mole of Fe3O4 from Fe and O2 is : (A)

x +y 2

(B)

2x y 2

(C)

2x y 2

(D)

y 2x 2

9.

One gram of an organic liquid X (molecular mass 78) liberates 160 J of heat on solidification. Hfusion (A) is : (A) 19.2 kJ/mol (B) 12.48 kJ/mol (C) 124.8 kJ/mol (D) None of these Bond energies are equal to dissociation energies in case of : (A) monoatomic molecules (B) polyatomic molecules (C) diatomic molecules (D) all type of molecules

10.

Space for Rough Work

RESONANCE

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11.

SO2, S(rhombic) + O2 SO2, S(monoclinic) + O2

H = 297.5 kJ H = 300 kJ

This data indicates : (A) Rhombic sulphure is yellow in colour (B) monoclinic sulphur is more stable (C) monoclinic sulphur has metallic lustre (D) The process S(rhombic) S(monoclinic) is endothermic 12. The difference between H and E (on a molar basis) for the combustion of n-octane () at 25C would be : (A) 13.6 kJ (B) 1.14 kJ (C) 11.15 kJ (D) + 11.15 kJ Statement-1 : The enthalpy of formation of H2O() is greater than of H2O (g) in magnitude. Statement-2: Enthalpy change is negative for the condensation reaction
H2O() H2O (g)

13.

(A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1. (B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1 (C) Statement-1 is True, Statement-2 is False (D) Statement-1 is False, Statement-2 is True
Space for Rough Work

RESONANCE

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14.

In Haber's process of manufacturing of ammonia :

2NH3(g) ; H0 N2(g) + 3H2(g) 25C = 92.2 kJ

Molecule N2(g) H2(g) NH3(g) CP JK-1 mol1 29.1 28.8 35.1 If CP is independent of temperature, then reaction at 100C as compared to that of 25C will be : (A) More endothermic (B) Less endothermic (C) More exothermic (D) Less exothermic 15. STATEMENT-1 : Heat of neutralization of HCl and NaOH is same as that of H2SO4 with NaOH. STATEMENT-2 : HCl, H2SO4 and NaOH are all strong electrolyte. (A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1. (B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1 (C) Statement-1 is True, Statement-2 is False (D) Statement-1 is False, Statement-2 is True

SECTION - II

Multiple Correct Answer Type

This section contains 7 questions. Each question has 4 choices (A), (B), (C) and (D) for its answer, out of which ONE OR MORE is/are correct. 16. In which of the following changes, H is always negative : (A) enthalpy of solution (C) enthalpy of reaction
Space for Rough Work

(B) enthalpy of hydrogenation (D) enthalpy of neutralisation

RESONANCE

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17.

The standard heat of combustion of solid boron is not equal to : (A) Hf (B2O3) (B) 1/2 Hf (B2O3) (C) 2Hf (B2O3) The following is (are) endothermic reaction(s) : (A) Combustion of methane. (C) Dehydrogenation of ethane to ethylene.

(D) 1/2 Hf (B2O3)

18.

(B) Decomposition of water (D) Conversion of graphite to diamond.

19.

Enthalpy of polymerisation of ethylene, as represented by the reaction, nCH2=CH2 CH2CH2)n is 100 kJ per mole of ethylene. Given bond enthalpy of C=C bond is 600 kJ mol1, enthalpy of CC bond (in kJ mol) will be : (A) 2940 kcal mol1 (B) 350 kJ mol1 (C) 700 kJ mol1 (D) 1470 kcal mol1 Heat of hydrogenation of ethene is x1 and that of benzene is x2. Therefore Resonance energy value cannot be : (A) x1 x2 (B) x1 + x2 (C) 3x1 x2 (D) x1 3x2
C(g) , following process is : C(s, graphite) (A) Hcombustion (B) Hformation (C) Hatomization CO2(g) , following process is : C (s, graphite) + O2(g) (A) Hcombustion (B) Hformation (C) Hatomization

20.

21.

(D) Hsublimation

22.

(D) Hsublimation

Space for Rough Work

RESONANCE

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