GSTT Group su tm v gii thiu

S GIO DC-O TO THI BNH

THI CHN HC SINH GII LP 12 NM HC 2009 -2010 Mn: HO HC Thi gian lm bi: 90 pht (khng k thi gian giao ) gm 04 trang; Th sinh lm bi vo Phiu tr li trc nghim
M : 258

Cu 1. Nhng thanh Mg vo dung dch cha 0,1 mol mui sunphat ca mt kim loi M, sau phn ng hon

ton ly thanh Mg ra thy khi lng thanh Mg tng 4,0 gam. Hy cho bit c bao nhiu mui tho mn? A. 0 B. 3 C. 2 D. 1
Cu 2. Cho cc cp dung dch sau: (1) Na2CO3 v AlCl3 ; (2) NaNO3 v FeCl2 ; (3) HCl v Fe(NO3)2

(4) NaHCO3 v BaCl2 ; (5) NaHCO3 v NaHSO4 . Hy cho bit cp no xy ra phn ng khi trn cc cht trong cc cp vi nhau? A. (3) (2) (5) B. (1) (3) (5) C. (1) (3) (4) D. (1) (4) (5)
Cu 3. Cho s sau:
HCl du KOH CH3OH , HCl khan NaOH ,t X (C4H9O2N) X2 H2N-CH2COOK X3 X1 Vy X2 l: A. ClH3N-CH2COOH B. H2N-CH2-COOH C. H2N-CH2-COONa D. H2N-CH2-COOC2H5
0

Cu 4. Cho 18,3 gam hn hp X gm Na v Ba vo nc thu c dung dch Y v 4,48 lt H2 (ktc). Xc

nh th tch CO2 (ktc) cho vo dung dch Y thu c kt ta cc i? A. 4,48 lt V 6,72 lt B. 2,24 lt V 6,72 lt C. 2,24 lt V 4,48 lt

D. 1,12 lt V 6,72 lt

Cu 5. Hp cht X l dn xut ca benzen c CTPT C8H10O2. X tc dng vi NaOH theo t l mol 1:1. Mt

khc cho X tc dng vi Na th s mol H2 thu c ng bng s mol ca X phn ng. Nu tch mt phn t H2O t X th to ra sn phm c kh nng trng hp to polime. S CTCT ph hp ca X l A. 6 B. 2 C. 7 D. 9 NaOH c d, t0 cao, p cao thu c cht Y c CTPT l C7H7O2Na. Cho bit X c bao nhiu CTCT tha mn? A. 2 B. 5 C. 3 D. 4
Cu 7. Cho cc cht sau C2H5OH(1), CH3COOH(2), CH2=CH-COOH(3), C6H5OH(4), p-CH3-C6H4OH(5),

Cu 6. Hp cht X c cha vng benzen v c cng thc phn t l C 7H6Cl2. Thy phn hon ton X trong

C6H5-CH2OH(6). Sp xp theo chiu tng dn linh ng ca nguyn t H trong nhm -OH ca cc cht trn l A. (1), (6), (5), (4), (2), (3) B. (3), (6), (5), (4), (2), (1) C. (1), (6), (5), (4), (3), (2) D. (1), (5), (6), (4), (2), (3) d ZnO22- + e NH3 + g H2O Tng cc h s (cc s nguyn ti gin) ca cc cht tham gia phn ng (a+b+c) l A.10 B.11 C.12 D.9
Cu 8. Cho phng trnh ion rt gn: a Zn + bNO3 + c OH Cu 9. Cho t t 100 ml dung dch HCl 1,5 M vo 0,4 lt dung dch X gm Na 2CO3 v KHCO3 thu c
-

1,008 lt CO2 (ktc) v dung dch Y. Thm dung dch Ba(OH) 2 d vo dung dch Y thu c 29,55 gam kt ta. Nng mol/lit ca Na2CO3 v KHCO3 trong dung dch X ln lt l A. 0,2625M v 0,1225M B. 0,0375 M v 0,05M C. 0,2625M v 0,225M D. 0,1125M v 0,225M
Cu 10. Hn hp X gm mt hirocacbon th kh v H2 (t khi hi ca X so vi H2 bng 4,8). Cho X i

qua Ni un nng n phn ng hon ton thu c hn hp Y (t khi hi ca Y so vi CH4 bng 1). CTPT ca hirocacbon l A. C3H4 B. C2H4 C. C2H2 D. C3H6 so vi H2 bng 21,75. Hiu sut ca phn ng Crckinh butan l bao nhiu? A. 50.33% B. 66,67% C. 33,33%

Cu 11. Khi Crckinh V lt butan c hn hp A ch gm cc anken v ankan. T khi hi ca hn hp A D. 46,67%

Cu 12. Hai cht no di y khi tham gia phn ng trng ngng to t nilon-6,6? A. Axit picric v hexametyleniamin B. Axit aipic v etilen glicol C. Axit aipic v hexametyleniamin D. Axit glutamic v hexametyleniamin GSTT Group Sharing the value!

GSTT Group su tm v gii thiu

Cu 13. Thu phn hon ton 34,2 gam saccaroz. Ly ton b sn phm X ca phn ng thu phn cho

tc dng vi lng d AgNO3/NH3 thu c a gam kt ta. Cn nu cho ton b sn phm X tc dng vi dung dch nc brom d th c b gam brom phn ng.Gi tr ca a,b ln lt l A. 21,6 v 16 B. 43,2 v 16 C. 21,6 v 32 D. 43,2 v 32 o Cu 14. C hai bnh kn khng gin n ng y cc hn hp kh t C nh sau: - Bnh (1) cha H2 v Cl2 - Bnh (2) cha CO v O2 Sau khi un nng cc hn hp phn ng xy ra, a nhit v trng thi ban u th p sut trong cc bnh thay i nh th no? A. Bnh (1) gim, bnh (2) tng. B. Bnh (1) tng, bnh (2) gim. C. Bnh (1) khng i, bnh (2) gim. D. Bnh (1) khng i, bnh (2) tng. Cu 15. Cho 0,15 mol este X mch h vo 150 gam dung dch NaOH 8%, un nng phn ng thu phn este xy ra hon ton thu c 165 gam dung dch Y. C cn dung dch Y thu c 22,2 gam cht rn khan. Hy cho bit X c bao nhiu CTCT tho mn? A. 2 B. 1 C. 3 D. 4 Cu 16. Mt hp cht hu c X mch h cha (C,H,O) c khi lng phn t l 60(u). X tc dng vi Na gii phng H2. S cc cht tho mn gi thit trn l A. 5 B. 3 C. 2 D. 4 Cu 17. Cho cc cht lng C2H5OH, C6H5OH, C6H5NH2, cc dung dch C6H5ONa, NaOH, CH3COOH, HCl. Cho cc cht trn tc dng vi nhau tng i mt iu kin thch hp. S cp cht xy ra phn ng ho hc l A. 8 B. 11 C. 9 D. 10 Cu 18. Dy gm cc cht u c kh nng lm i mu dung dch qu tm l A. CH3NH2, C6H5OH, HCOOH B. CH3NH2, C2H5NH2, H2N-CH2-COOH C. C6H5NH2, C2H5NH2, HCOOH D. CH3NH2, C2H5NH2, HCOOH Cu 19. t chy hon ton a mol anehit X (mch h) to ra b mol CO2, c mol H2O (bit b=a+c). Trong phn ng trng gng 1phn t X ch cho 2 electron. X l anehit c c im g? A. Khng no, n chc, c mt ni i B. No, hai chc C. No, n chc D. Khng no, n chc, c hai ni i Cu 20. iu ch O2 trong phng th nghim t thuc tm, kaliclorat, hiropeoxit, natrinitrat (c s mol bng nhau). Lng O2 thu c nhiu nht t A. kaliclorat B. natrinitrat C. hiropeoxit (H2O2) D. thuc tm Cu 21. un nng m gam hn hp X gm C2H2, C2H4 v H2 vi xc tc Ni n phn ng xy ra hon ton, thu c 8,96 lt (ktc) hn hp Y (c t khi so vi hir bng 8). t chy hon ton cng lng hn hp X trn, ri cho sn phm chy hp th hon ton trong dung dch nc vi trong d th khi lng kt ta thu c l A. 40 gam B. 30 gam C. 50 gam D. 20 gam Cu 22. phn bit hai ng phn glucoz v fructoz ngi ta c th dng A. Cu(OH)2/NaOH B. nc brom C. dung dch AgNO3/NH3 D. nc vi trong
Cu 23. Nguyn t khi trung bnh ca Clo bng 35,5. Clo c hai ng v
35 35 17

Cl v

37 17

Cl . Phn trm khi

lng ca 17 Cl c trong axit pecloric l gi tr no sau y? (cho H=1; O=16) A. 26,92% B. 26,12% C. 30,12%

D. 27,2%

Cu 24. Cho hn hp dng bt gm Al v Fe vo 100 ml dung dch CuSO 4 0,75 M, khuy k hn hp

phn ng xy ra hon ton thu c 9 gam cht rn A gm hai kim loi. ho tan hon ton cht rn A th cn t nht bao nhiu lt dung dch HNO3 1M (bit phn ng to ra sn phm kh NO duy nht)? A. 0,4 lt B. 0,5 lit C. 0,3 lit D. 0,6 lit dung dch tng theo th t l A. (3), (2), (4), (1). B. (2), (3), (4), (1).

Cu 25. Cho cc dung dch c cng nng mol/l: NaHCO3(1); Na2CO3(2); NaCl(3); NaOH(4). pH ca C. (3), (1), (2), (4). D. (1), (2), (3), (4).

Cu 26. Trn 100 ml dung dch NaOH 2,5M vi 100ml dung dch H3PO4 1,6M thu c dung dch X. Xc

nh cc cht tan c trong X? A. Na3PO4 v NaOH B. Na3PO4 v Na2HPO4

GSTT Group

C. NaH2PO4 v H3PO4

D. Na2HPO4 v NaH2PO4 Sharing the value!

GSTT Group su tm v gii thiu

Cu 27. Cho dung dch NaOH d vo 100 ml dung dch cha ng thi Ba(HCO 3)2 0,5 M v BaCl2 0,4 M

th thu c bao nhiu gam kt ta? A. 19,7 gam B. 29,55 gam

C. 17,73 gam

D. 23,64 gam

Cu 28. Ho tan ht hn hp rn gm CaC2, Al4 C3 v Ca vo H2O thu c 3,36 lt hn hp kh X c t

khi so vi hiro bng 10. Dn X qua Ni un nng thu c hn hp kh Y. Tip tc cho Y qua bnh ng nc brom d th c 0,784 lt hn hp kh Z (t khi hi so vi He bng 6,5). Cc kh o iu kin tiu chun. Khi lng bnh brom tng l A. 2,09 gam B. 3,45gam C. 3,91 gam D. 1,35 gam H2SO4 0,5 M thu c kh NO duy nht v dung dch Z cha m gam cht tan. Gi tr ca m l A. 23,06 B. 20,36 C. 22,96 D. 18,75

Cu 29. Cho 10,32 gam hn hp X gm Cu, Ag tc dng va vi 160 ml dung dch Y gm H NO31M v

Cu 30. Cho dung dch NH3 d vo dung dch X gm AlCl3, ZnCl2 v FeCl3 thu c kt ta Y. Nung kt

ta Y thu c cht rn Z. Cho lung kh H2 d qua Z (un nng) thu c cht rn T. Cc phn ng xy ra hon ton.Trong T c cha A. Al2O3, Fe B. Fe C. Al2O3, ZnO, Fe D. Al2O3, Zn
Cu 31. Cho a gam mt axit n chc phn ng va vn vi A. CH3COOH B. HCOOH

a gam Na. Axit l 2 C. C2H3COOH D. C2H5COOH

Cu 32. Trong 2 lt dung dch HF c cha 4 gam HF nguyn cht c in li ( = 8%). pH ca dung dch HF l A. 2,097 B. 2,50 C. 1,34 D. 1 Cu 33. Cho cc s phn ng sau

- X1 + X2 X4 + H2 - X3 + X4 CaCO3 + NaOH - X3 + X5 + X2 Fe(OH)3 + NaCl + CO2 Cc cht thch hp vi X3, X4, X5 ln lt l A. Ca(OH)2, NaHCO3, FeCl2 C. Ca(OH)2, NaHCO3, FeCl3

B. Na2CO3, Ca(OH)2, FeCl2 D. Na2CO3, Ca(OH)2, FeCl3

Cu 34. Hn hp X gm Zn, Fe, Cu. Cho 18,5 gam hn hp X tc dng vi dung dch HCl d thu c

4,48 lit H2(ktc). Mt khc cho 0,15 mol hn hp X phn ng va vi 3,92 lt kh Cl2(ktc). S mol Fe c trong 18,5 gam hn hp X l A. 0,12 mol B. 0,15 mol C. 0,08 mol D. 0,1 mol
Cu 35. Tin hnh trng hp 1mol etilen iu kin thch hp, em sn phm sau trng hp tc dng vi

dung dch brom th lng brom phn ng l 36 gam. Hiu sut phn ng trng hp v khi lng poli etilen (PE) thu c l A. 70% v 23,8 gam B. 77,5% v 21,7 gam C. 77,5 % v 22,4 gam D. 85% v 23,8 gam
Cu 36. Cho nhng nhn xt sau :

1- iu ch kh H2S ngi ta cho mui sunfua tc dng vi cc dung dch axit mnh nh HCl, HNO3,H2SO4(c) 2- Dung dch HCl c, S, SO2, FeO va c kh nng th hin tnh kh va c kh nng th hin tnh oxi ho. 3- V hp bo qun thc phm lm bng st ty (st trng thic) b xy st ti lp st bn trong, khi ngoi khng kh m th thic b n mn trc. 4- Hn hp BaO v Al2O3 c th tan hon ton trong nc. 5- Cho dung dch NaOH d vo dung dch Ca(HCO3)2 th thy xut hin kt ta. 6- Hn hp bt gm Cu v Fe3O4 c th tan hon ton trong dung dch H2SO4 long. S nhn xt ng l A. 6 B. 3 C. 4 D. 5
Cu 37. X v Y ln lt l cc tripeptit v tetrapeptit c to thnh t cng mt amino axit no mch h,

c mt nhm -COOH v mt nhm -NH2. t chy hon ton 0,1 mol Y thu c sn phm gm CO 2, H2O, N2, trong tng khi lng ca CO2 v H2O l 47,8 gam. Nu t chy hon ton 0,3 mol X cn bao nhiu mol O2? A. 2,025 mol B. 2,8 mol C. 1,875 mol D. 3,375 mol
GSTT Group Sharing the value!

GSTT Group su tm v gii thiu

Cu 38. X l mt hp cht c CTPT C6H10O5 :
C X + 2NaOH t 2Y + H2O Y + HCl(long) Z + NaCl. Hy cho bit khi cho 0.1mol Z tc dng vi Na d thu c bao nhiu mol H 2 ? A. 0,1 mol B. 0,2 mol C. 0,15 mol D. 0,05 mol Cu 39. Thu phn cc cht sau trong mi trng kim: CH 3CHCl2(1), CH3COOCH=CH-CH3(2), CH3COOC(CH3)=CH2(3), CH3CH2CCl3(4), CH3COO-CH2-OOCCH3(5), HCOOC2H5 (6). Nhm cc cht sau khi thu phn c sn phm tham gia phn ng trng gng l A. (1),(4),(5),(6) B. (1),(2),(5),(3) C. (1),(2),(5),(6) D. (1),(2),(3),(6) Cu 40. Cho 11,6 gam FeCO3 tc dng va vi dung dch HNO3 thu c hn hp kh (CO2, NO) v dung dch X. Khi thm dung dch HCl d vo dung dch X th ho tan ti a c bao nhiu gam bt Cu (bit c kh NO bay ra) A. 16 gam B. 28,8 gam C. 48 gam D. 32 gam Cu 41. Ho tan hon ton 74 gam hn hp X gm FeO, Fe3O4, Fe2O3 bng dung dch H2SO4 long d sinh ra 178 gam mui sunfat. Nu cng cho 74 gam hn hp X trn phn ng vi lng d kh CO nhit cao v dn sn phm kh qua dung dch nc vi trong d th khi lng (gam) kt ta to thnh l bao nhiu? (cc phn ng xy ra hon ton) A. 240 B. 130 C. 180 D. 150 Cu 42. Nguyn t nguyn t X c phn lp e lp ngoi cng l 3p. Nguyn t ca nguyn t Y c phn lp e lp ngoi cng l 3s. Tng s e hai phn lp ngoi cng ca X v Y l 7. Bit rn g X v Y d phn ng vi nhau. S hiu nguyn t ca X v Y ln lt l A. 13 v 15 B. 12 v 16 C. 17 v 12 D. 18 v 11 Cu 43. Mt hp cht hu c X c CTPT C3H10O3N. Cho X phn ng vi NaOH d, c cn dung dch sau phn ng thu c cht rn Y (ch c cc hp cht v c) v phn hi Z (ch c mt hp cht hu c no, n chc mch khng phn nhnh). Cng thc cu to ca X l A. H2N-CH(OH)CH(NH2)COOH B. HCOONH3CH2CH2NO2 C. HO-CH2-CH2-COONH4 D. CH3-CH2-CH2-NH3NO3 Cu 44. un nng glixerol vi hn hp hai axit bo n chc c mt H2SO4 c xc tc thu c ti a bao nhiu cht bo? A. 10 B. 6 C. 4 D. 8 Cu 45. Cho cc cht C4H10O,C4H9Cl,C4H10,C4H11N. S ng phn cu to ca cc cht gim theo th t l A. C4H10O, C4H11N, C4H10, C4H9Cl B. C4H10O, C4H9Cl, C4H11N, C4H10 C. C4H11N, C4H10O, C4H9Cl, C4H10 D. C4H10O, C4H9Cl, C4H10, C4H11N. Cu 46. Hp cht hu c X c CTPT C4H6O2Cl2 khi thu phn hon ton trong mi trng kim un nng thu c cc sn phm ch gm hai mui v nc. Cng thc cu to ng ca X l A. CH3COOCH(Cl)CH2Cl B. C2H5COOC(Cl2)H C. HCOO-C(Cl2)C2H5 D. CH3-COOC(Cl2)CH3 Cu 47. Amino axit mch khng phn nhnh X cha a nhm -COOH v b nhm -NH2. Khi cho 1mol X tc dng ht vi axit HCl thu c 169,5 gam mui. Cho 1 mol X tc dng ht vi dung dch NaOH thu c 177 gam mui.CTPT ca X l A. C4H6N2O2 B. C4H7NO4 C. C3H7NO2 D. C5H7NO2 Cu 48. Ho tan hon ton 0,1 mol FeS2 trong dung dch HNO3 c nng. Tnh th tch kh NO2 bay ra (ktc) v s mol HNO3 (ti thiu) phn ng (bit rng lu hunh trong FeS2 b oxi ho ln s oxi ho cao nht) A.33,6 lt v 1,5 mol B.22,4 lt v 1,5 mol C.33,6 lt v 1,4 mol D.33,6 lt v 1,8 mol Cu 49. Cho s sau: Cu + dd mui X khng phn ng; Cu + dd mui Y khng phn ng. Cu + dd mui X + dd mui Y phn ng Vi X, Y l mui ca natri. Vy X,Y c th l A. NaNO3, NaHCO3 B. NaNO2, NaHSO3 C. NaAlO2, NaNO3 D. NaNO3, NaHSO4 Cu 50. Este X c cng thc phn t l C5H10O2. Thy phn X trong NaOH thu c ru Y. hirat ha ru Y thu c hn hp 3 anken. Vy tn gi ca X l A. etyl propionat B. iso-propyl axetat C. tert-butyl fomiat D. sec-butyl fomiat
0

(Cho nguyn t khi cc nguyn t Na= 23; K= 39; Ca= 40; Mg= 24; Al= 27; Ba= 137; Fe= 56;

Zn=65; Cu= 64;Ag=108; C= 12; H= 1; Cl= 35,5; Br= 80; S= 32; O= 16; N= 14; He= 4)

--- HT --GSTT Group Sharing the value!

GSTT Group su tm v gii thiu 1.A 11. 21.B 31.A 41.B 2.D 12.B 22.C 32.D 42.C 3.D 13.A 23.D 33.B 43.C 4.B 14.B 24.B 34.B 44.A S 12 5.C 6.B 15.D 16.C 25.D 26.D 35.D 36.D 45.B 46.C 7.B 17.C 27.A 37.A 47.A 8.B 18.C 28.C 38.A 48.B 9.B 19.B 29.D 39.C 49.C 10.B 20.A 30.C 40.C 50.A

S GIO DC V O TO THI BNH

THI CHN HC SINH GII LP 12 NM HC 2010-2011 Mn: HO HC nghim

Cho nguyn t khi ca cc nguyn t: H = 1; C = 12; N = 14; O = 16; S = 32; Cl = 35,5; Br = 80; P = 31; Na = 23; Mg = 24; Al = 27; K = 39; Ca = 40; Cr = 52; Mn = 55; Fe = 56; Cu = 64; Zn = 65; Ag = 108; Ba = 137; Pb = 207; Ni = 59. Cu 1: t chy hon ton 8,0 gam hn hp X gm hai ankin (th kh nhit thng) thu c 26,4 gam CO2. Mt khc, cho 8,0 gam hn hp X tc dng vi dung dch AgNO 3 trong NH3 d n khi phn ng hon ton thu c lng kt ta vt qu 25 gam. Cng thc cu to ca hai ankin trn l A. CHCH v CH3-CCH. B. CHCH v CH3-CH2-CCH. C. CHCH v CH3-CC-CH3. D. CH3-CCH v CH3-CH2-CCH. + + 2Cu 2: C 500 ml dung dch X cha Na , NH4 , CO3 v SO42-. Ly 100 ml dung dch X tc dng vi lng d dung dch HCl thu c 2,24 lt kh. Ly 100 ml dung dch X cho tc dng vi lng d dung dch BaCl2 thu c 43 gam kt ta. Ly 200 ml dung dch X tc dng vi lng d dung dch NaOH thu c 8,96 lt kh NH 3. Cc phn ng hon ton, cc th tch kh u o ktc. Tnh tng khi lng mui c trong 300 ml dung dch X ? A. 23,8 gam. B. 86,2 gam. C. 71,4 gam. D. 119 gam. Cu 3: x phng ha 1,0 kg cht bo c ch s axit bng 7, ngi ta un cht bo vi 142 gam NaOH trong dung dch. Sau khi cc phn ng xy ra hon ton, trung ha NaOH d cn va 50 ml dung dch HCl 1M. Khi lng glixerol thu c t phn ng x phng ha l A. 145,2 gam. B. 134,5 gam C. 120,0 gam. D. 103,5 gam. Cu 4: Cho cc cp cht sau: (1). Kh Cl2 v kh O2. (6). Dung dch KMnO4 v kh SO2. (2). Kh H2S v kh SO2. (7). Hg v S. (3). Kh H2S v dung dch Pb(NO3)2. (8). Kh CO2 v dung dch NaClO. (4). Kh Cl2 v dung dch NaOH. (9). CuS v dung dch HCl. (5). Kh NH3 v dung dch AlCl3. (10). Dung dch AgNO3 v dung dch Fe(NO3)2. S cp cht xy ra phn ng ha hc nhit thng l A. 8. B. 7. C. 9. D. 10. Cu 5: Cho cc cht sau: HOOC-COONa, K2S, H2O, KHCO3, Al(OH)3, Al, KHSO4, Zn, (NH4)2SO3. S cht c tnh lng tnh l A. 6. B. 5. C. 4. D. 7. Cu 6: Cho phng trnh ha hc: a FeSO4 + b KMnO4 + c NaHSO4 x Fe2(SO4)3 + y K2SO4 + z MnSO4 + t Na2SO4 + u H2O vi a,b,c,x,y,z,t,u l cc s nguyn ti gin. Tng h s cc cht trong phng trnh ha hc trn l A. 46. B. 50. C. 52. D. 28. Cu 7: nhit khng i, h cn bng no b chuyn dch theo chiu thun khi tng p sut ca h ? A. 2NO(kh) N2(kh) + O2 (kh) B. N2(kh) + 3H2(kh) 2NH3(kh) C. 2CO2(kh) 2CO(kh) + O2 (kh) D. 2SO3(kh) 2SO2(kh) + O2(kh) Cu 8: im ging nhau ca glucoz v saccaroz l A. u phn ng vi dung dch AgNO3 trong NH3 to Ag. B. u phn ng vi Cu(OH)2 to dung dch mu xanh lam. GSTT Group Sharing the value!

GSTT Group su tm v gii thiu

C. u b thu phn trong dung dch axit. D. u phn ng vi H2 c xc tc Ni nung nng cng thu c mt ancol a chc. Cu 9: Hp cht X cha vng benzen, c cng thc phn t C xHyN. Khi cho X tc dng vi dung dch HCl thu c mui Y c cng thc dng RNH3Cl (R l gc hirocacbon). Phn trm khi lng ca nit trong X l 13,084%. S ng phn cu to ca X tha mn cc iu kin trn l A. 4. B. 5. C. 3. D. 6. Cu 10: Cho s phn ng sau:
, p , xt H 2 / Ni,t H 2O Anehit no, mch h X1 Cao su buna. X2 X3 t
o
o

, p , xt H 2 / Ni,t H 2O , H 2 Anehit no mch h X4 Cao su buna. X5 X3 t Hy cho bit: khi cho X 1 v X4 vi khi lng bng nhau tc dng hon ton vi dung dch AgNO 3 trong NH3 un nng, cht no to ra lng Ag nhiu hn ? A. X1. B. bng nhau. C. X4. D. khng xc nh c. Cu 11: Nhit phn hon ton R(NO 3)2 (vi R l kim loi) thu c 8 gam mt oxit kim loi v 5,04 lt hn hp kh X gm NO2 v O2 (o ktc). Khi lng ca hn hp kh X l 10 gam. Xc nh cng thc ca mui R(NO3)2 ? A. Mg(NO3)2. B. Zn(NO3)2. C. Cu(NO3)2. D. Fe(NO3)2. Cu 12: C bao nhiu nguyn t ha hc m nguyn t ca n c electron cui cng in vo phn lp 4s ? A. 2. B. 1. C. 9. D. 12. Cu 13: Oxi ha anehit X n chc bng O 2 (xc tc thch hp) vi hiu sut phn ng l 75% thu c hn hp Y gm axit cacboxylic tng ng v anehit d. Trung ha axit trong hn hp Y cn 100 ml dung dch NaOH 0,75M ri c cn dung dch sau phn ng thu c 5,1 gam cht rn khan. Nu cho hn hp Y tc dng hon ton vi dung dch AgNO3 trong NH3 d, un nng th thu c khi lng Ag l A. 21,6 gam. B. 5,4 gam. C. 10,8 gam. D. 27,0 gam. Cu 14: Khi nung butan vi xc tc thch hp thu c hn hp T gm CH4, C3H6, C2H4, C2H6, C4H8, H2 v C4H10 d. t chy hon ton hn hp T thu c 8,96 lt CO2 (o ktc) v 9,0 gam H2O. Mt khc, hn hp T lm mt mu va ht 12 gam Br2 trong dung dch nc brom. Hiu sut phn ng nung butan l A. 45%. B. 75%. C. 50%. D. 65%. Cu 15: Cho 0,1 mol -amino axit X tc dng va vi 50 ml dung dch HCl 2M. Trong mt th nghim khc, cho 26,7 gam X vo dung dch HCl d, sau c cn cn thn dung dch thu c 37,65 gam mui khan. Vy X l: A. Alanin. B. Valin. C. Glyxin. D. Axit glutamic. Cu 16: Thy phn m (gam) xenluloz trong mi trng axit. Sau mt thi gian phn ng, em trung ha axit bng kim, sau cho hn hp tc dng hon ton vi dung dch AgNO 3 trong NH3 thu c m (gam) Ag. Xc nh hiu sut ca phn ng thy phn xenluloz ? A. 50%. B. 75%. C. 80%. D. 66,67%. Cu 17: Trong phng th nghim, hirohalogenua (HX) c iu ch t phn ng sau: NaX(rn) + H2SO4 (c, nng) NaHSO4 (hoc Na2SO4) + HX (kh). Hy cho bit phng php trn c th dng iu ch c hirohalogenua no sau y ? A. HCl, HBr v HI. B. HF v HCl. C. HF, HCl, HBr, HI. D. HBr v HI. Cu 18: Hp cht X c cng thc phn t l C5H8O2. Cho 10 gam X tc dng hon ton, va vi dung dch NaOH thu c dung dch Y. Ly ton b dung dch Y tc dng hon ton vi dung dch AgNO 3 trong NH3 un nng thu c 43,2 gam Ag. S ng phn cu to ca X tha mn cc iu kin trn l A. 2. B. 1. C. 3 D. 4. Cu 19: Cho cc trng hp sau: (1). O3 tc dng vi dung dch KI. (5). KClO3 tc dng vi dung dch HCl c, un nng. (2). Axit HF tc dng vi SiO 2. (6). un nng dung dch bo ha gm NH4Cl v NaNO2. (3). MnO2 tc dng vi dung dch HCl c, un nng. (7). Cho kh NH3 qua CuO nung nng. (4). Kh SO2 tc dng vi nc Cl2. S trng hp to ra n cht l A. 5. B. 6. C. 4. D. 3. Cu 20: Cho hn hp X gm 8,4 gam Fe v 6,4 gam Cu vo dung dch HNO3. Sau khi phn ng hon ton thu c 3,36 lt kh NO (l sn phm kh duy nht, o ktc). Khi lng mui thu c sau phn ng l A. 41,3 gam. B. 41,1gam. C. 36,3 gam. D. 42,7 gam. Cu 21: Cht A mch h c cng thc CxHyCl2. Khi cho tt c cc ng phn ca A tc dng hon ton vi dung dch NaOH un nng thu c hn hp sn phm trong c ba ancol c kh nng ha tan c Cu(OH) 2 to thnh dung dch mu xanh lam. Cng thc phn t ca A l A. C3H6Cl2. B. C4H8Cl2. C. C5H10Cl2. D. C4H6Cl2. Cu 22: Cho cc cht sau: 1) axit 2-hiroxipropan-1,2,3-tricacboxylic (c trong qu chanh)
o
o

GSTT Group

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GSTT Group su tm v gii thiu

2) axit 2-hiroxipropanoic (c trong sa chua). 3) axit 2-hiroxibutanioic (c trong qu to). 4) axit 3-hiroxibutanoic (c trong nc tiu ca ngi bnh tiu ng). 5) axit 2,3-ihiroxibutanioic (c trong ru vang). Th t sp xp cc axit trn theo chiu tnh axit mnh dn t tri sang phi l A. 2,4,5,3,1. B. 4,2,3,5,1. C. 2,3,4,5,1. D. 4,3,2,1,5. Cu 23: Hn hp X gm ancol metylic v ancol A no, n chc, mch h. Cho 7,6 gam X tc dng vi Na d thu c 1,68 lt H2 (o ktc). Mt khc oxi ha hon ton 7,6 gam X bng CuO nung nng ri cho ton b sn phm thu c tc dng hon ton vi dung dch AgNO3 trong NH3 d thu c 21,6 gam kt ta. Cng thc cu to ca A l A. CH3CH(OH)CH3. B. CH3CH2CH(OH)CH3. C. CH3CH2CH2OH. D. C2H5OH. Cu 24: t chy hon ton 0,1 mol cht hu c X l dn xut ca benzen thu c CO 2 c khi lng nh hn 35,2 gam. Bit rng a (mol) X phn ng va vi 500 ml dung dch NaOH 2a(M). Cng thc cu to X l Trang 2/4 - ca M thi 132 A. HO-CH2-C6H4-COOH. B. HO-C6H4-CH2OH. C. C6H5-CH2OH. D. C6H4(OH)2. Cu 25: Cho mt ipeptit Y c cng thc phn t C 6H12N2O3. S ng phn peptit ca Y (ch cha gc -amino axit) mch h l A. 6. B. 7. C. 5. D. 4. Cu 26: Ha tan 10,65 gam hn hp gm mt oxit kim loi kim v mt oxit kim loi kim th bng dung dch HCl d c dung dch X. C cn dung dch X, ly mui khan em in phn nng chy hon ton vi in cc tr th thu c 3,36 lt kh (o ktc) anot v a (gam) hn hp kim loi catot. Gi tr ca a l A. 9,45. B. 5,85. C. 8,25. D. 9,05. Cu 27: C 49,125 gam cao su buna-S phn ng va ht vi 30 gam brom trong CCl4. T l s mt xch stiren v butaien trong loi cao su trn tng ng l A. 1: 2 B. 2: 3. C. 2: 1. D. 1: 3. Cu 28: Cho kh CO qua hn hp T gm Fe v Fe2O3 nung nng thu c hn hp kh B v hn hp cht rn D. Cho B qua dung dch Ca(OH)2 d thu c 6 gam kt ta. Mt khc, ha tan hn hp D bng dung dch H2SO4 c, nng, d thu c 0,18 mol SO2 (sn phm kh duy nht) v 24 gam mui. Phn trm s mol ca Fe trong hn hp T l A. 80%. B. 45%. C. 50%. D. 75%. Cu 29: Trong s cc loi t sau: t lapsan, t nitron, t visco, t nilon -6,6, t axetat, t capron, t nilon-7. C bao nhiu loi t thuc loi t nhn to ? A. 1. B. 3. C. 4. D. 2. Cu 30: Thc hin cc th nghim sau: Th nghim 1: Trn 0,015 mol ancol no X vi 0,02 mol ancol no Y ri cho hn hp tc dng ht vi Na c 1,008 lt H2. Th nghim 2: Trn 0,02 mol ancol X vi 0,015 mol ancol Y ri cho hn hp tc dng ht vi Na c 0,952 lt H2. Th nghim 3: t chy hon ton mt lng hn hp ancol nh trong th nghim 1 thu c 6,21 gam hn hp gm CO2 v H2O. Bit th tch cc khi o ktc v cc ancol u mch h. Cng thc 2 ancol X v Y ln lt l A. C2H4(OH)2 v C3H5(OH)3. B. C2H5OH v C3H7OH. C. C3H6(OH)2 v C3H5(OH)3. D. CH3OH v C2H5OH. Cu 31: Ha tan hn hp gm Fe v FexOy cn va 0,1 mol H2SO4 c thu c 0,56 lt kh SO2 (sn phm kh duy nht, o ktc) v dung dch X ch cha mui Fe(III). C cn dung dch X thu c khi lng mui khan l A. 20,0 gam. B. 16,0 gam. C. 8,0 gam. D. 10,0 gam. Cu 32: Cho 15,84 gam este no, n chc, mch h vo cc cha 30ml dung dch MOH 20% (d=1,2g/ml) vi M l kim loi kim. Sau phn ng hon ton, c cn dung dch thu c cht rn X. t chy hon ton X thu c 9,54gam M2CO3 v hn hp gm CO2, H2O. Kim loi M v cng thc cu to ca este ban u l A. K v CH3COOCH3. B. K v HCOO-CH3. C. Na v CH3COOC2H5. D. Na v HCOO-C2H5. Cu 33: Cho dung dch AgNO3 tc dng vi dung dch cha cht X thy to kt ta T mu vng. Cho kt ta T tc dng vi dung dch HNO 3 d thy kt ta tan. Cht X l A. KI. B. KCl. C. KBr. D. K3PO4. Cu 34: X l tetrapeptit Ala-Gly-Val-Ala, Y l tripeptit Val-Gly-Val. un nng m (gam) hn hp cha X v Y c t l s mol ca X v Y tng ng l 1:3 vi dung dch NaOH va . Phn ng hon ton thu c dung dch T. C cn cn thn dung dch T thu c 23,745 gam cht rn khan. Gi tr ca m l A. 19,455. B. 68,1. C. 17,025. D. 78,4 Cu 35: Hn hp kh X c th tch 4,48 lt (o ktc) gm H 2 v vinylaxetilen c t l mol tng ng l 3:1. Cho hn hp X qua xc tc Ni nung nng thu c hn hp kh Y c t khi so vi H 2 bng 14,5. Cho ton b hn hp Y trn t t qua dung dch nc brom d (phn ng hon ton) th khi lng brom phn ng l A. 32,0 gam. B. 3,2 gam. C. 8,0 gam. D. 16,0 gam. Cu 36: Hn hp T gm hai axit cacboxylic no mch h. GSTT Group Sharing the value!

GSTT Group su tm v gii thiu

- Th nghim 1: t chy hon ton a (mol) hn hp T thu c a (mol) H 2O. - Th nghim 2: a (mol) hn hp T tc dng vi dung dch NaHCO3 d thu c 1,6a (mol) CO2. Phn trm khi lng ca axit c phn t khi nh hn trong T l A. 40,00%. B. 46,67%. C. 31,76%. D. 25,41%. Cu 37: Cho 3,76 gam hn hp X gm Mg v MgO c t l mol tng ng l 14:1 tc dng ht vi dung dch HNO 3 th thu c 0,448 lt mt kh duy nht (o ktc) v dung dch Y. C cn cn thn dung dch Y thu c 23 gam cht rn khan T. Xc nh s mol HNO3 phn ng ? A. 0,28 B. 0,32 C. 0,36 D. 0,34 Cu 38: Este n chc X khng c nhnh, ch cha C,H,O v khng cha cc nhm chc khc. Bit t khi hi ca X so vi O2 l 3,125. Khi cho 15 gam X tc dng va vi dung dch NaOH un nng, c cn dung dch sau phn ng thu c 21 gam mui khan. Cng thc cu to ca X l A. HCOO-CH2-CH2 CH=CH2. B. CH3COO-CH2-CH=CH2. C. CH3-CH-CH2 D. CH 2 -CH2 -C=O C=O CH 2 -CH 2 -O CH2-O Cu 39: Ha tan 3 gam CH3COOH vo nc to ra 250 ml dung dch c in ly =1,4%. Nng cn bng ca axit axetic v pH ca dung dch ln lt bng: A. 0,1972M v 3,15. B. 0,0028M v 2,55. C. 0,1972M v 2,55. D. 0,0028M v 1,55. Cu 40: Ha tan 2m (gam) kim loi M bng dung dch HNO3 c, nng, d hay ha tan m (gam) hp cht X (hp cht ca M vi lu hunh) cng trong dung dch HNO3 c, nng, d th cng thu c kh NO 2 (sn phm kh duy nht) c th tch bng nhau cng iu kin nhit v p sut. Gi s nguyn t lu hunh ch b oxi ha ln mc cao nht. Kim loi M v cng thc phn t ca X ln lt l A. Mg v MgS. B. Cu v Cu2S. C. Cu v CuS. D. Fe v FeS. Cu 41: Cho s sau:
xt ,t X + H2 ancol X1.
0

xt ,t X + O2 axit hu c X2.
0

xt ,t X1 + X2 C6H10O2 + H2O.
0

Cng thc cu to ca X l A. CH3CH2CHO. B. CH2=CH-CHO. C. CH2=C(CH3)-CHO. D. CH3-CHO. Cu 42: Cho cc cht sau: phenol, kh sunfur, toluen, ancol benzylic, isopren, axit metacrylic, vinyl axetat, phenyl amin, axit benzoic. S cht phn ng c vi dung dch nc brom nhit thng l A. 3. B. 4. C. 6. D. 5. Cu 43: Dung dch X cha 14,6 gam HCl v 22,56 gam Cu(NO 3)2. Thm m (gam) bt st vo dung dch X, sau khi phn ng xy ra hon ton thu c hn hp kim loi c khi lng l 0,5m (gam) v ch to kh NO (sn phm kh duy nht ca N+5). Gi tr ca m l A. 14,88. B. 20,48. C. 9,28. D. 1,92. Cu 44: Ha tan hn hp X gm Cu v Fe2O3 trong 400 ml dung dch HCl a (M) thu c dung dch Y v cn li 1,0 gam Cu khng tan. Nhng thanh Mg vo dung dch Y, sau khi phn ng hon ton nhc thanh Mg ra thy khi lng tng thm 4,0 gam so vi khi lng thanh Mg ban u v c 1,12 lt kh H2 (o ktc) thot ra (gi thit ton b lng kim loi thot ra u bm ht vo thanh Mg). Khi lng Cu trong X v gi tr ca a ln lt l A. 3,2g gam v 0,75M. B. 3,2 gam v 2M. C. 4,2 gam v 1M. D. 4,2 gam v 0,75M. Cu 45: C bao nhiu ng phn cu to, mch h c cng thc phn t C 5H8 tc dng vi H2 d (xc tc thch hp) thu c sn phm isopentan ? A. 4. B. 2. C. 6. D. 3. Cu 46: Cho a (gam) st vo dung dch cha y mol CuSO4 v z mol H2SO4 long, sau phn ng hon ton thu c kh H2, a (gam) ng v dung dch ch cha mt cht tan duy nht. Mi quan h gia y v z l A. y = 5z. B. y = 7z. C. y = z. D. y = 3z. Cu 47: Hp cht ion G to nn t cc ion n nguyn t M2+ v X2-. Tng s ht (ntron, proton, electron) trong phn t G l 84, trong s ht mang in nhiu hn s ht khng mang in l 28 ht. S ht mang in ca ion X2- t hn s ht mang in ca ion M2+ l 20 ht. V tr ca M trong bng tun hon l A. 20, chu k 4, nhm IIA. B. 12, chu k 3, nhm IIA. C. 8, chu k 2, nhm VIA. D. 26, chu k 4, nhm VIIIB. Cu 48: Hn hp X gm mt anehit v mt ankin c cng s nguyn t cacbon. t chy hon ton a (mol) hn hp X thu c 3a (mol) CO2 v 1,8a (mol) H2O. Hn hp X c s mol 0,1 tc dng c vi ti a 0,14 mol AgNO3 trong NH3 (iu kin thch hp). S mol ca anehit trong 0,1 mol hn hp X l A. 0,03. B. 0,04. C. 0,01. D. 0,02. Cu 49: Hp th hon ton 4,48 lt CO 2 (ktc) vo 200ml dung dch cha Na 2CO3 0,5M v NaOH 0,75M thu c dung dch X. Cho dung dch BaCl2 d vo dung dch X thu c kt ta c khi lng l A. 19,7gam. B. 39,4 gam. C. 29,55 gam. D. 9,85gam. GSTT Group Sharing the value!

GSTT Group su tm v gii thiu

Cu 50: Cho cc cht sau: toluen, etilen, xiclopropan, stiren, vinylaxetilen, etanal, imetyl xeton, propilen. S cht lm mt mu dung dch KMnO 4 nhit thng l A. 4. B. 6. C. 7. D. 5. ------ HT -----

1.B 11.D 21.B 31.D 41.B

2.C 12.A 22.B 32.C 42.C

3.D 13.D 23.A 33.D 43.A

4.B 14.B 24.B 34.C 44.C

p n 2010-2011 5.B 6.C 15.A 16.B 25.C 26.A 35.C 36.D 45.D 46.B

7.B 17.B 27.C 37.C 47.A

8.B 18.A 28.A 38.D 48.D

9.A 19.A 29.D 39.C 49.D

10.A 20.B 30.A 40.B 50.D

GSTT Group

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GSTT Group su tm v gii thiu

S GIO DC & O TO

THI CHN HC SINH GII LP 12 NM HC 2011-2012

Mn: HO HC Thi gian: 90 pht (Khng k thi gian giao ) gm 04 trang; Th sinh lm bi vo Phiu tr li trc nghim M : 132

THI BNH

Cho bit khi lng mol (vC) ca cc nguyn t: H=1; C=12; N=14; O=16; F=19; Na=23; Mg=24; Al=27; P=31; S=32; Cl=35,5; K=39; Ca=40; Cr=52; Mn=55; Fe=56; Ni=59; Cu=64; Zn=65; Br=80; Ag=108; I=127; Ba=137; Au=197; Pb=207.

Trng nhm bin son: ThS Phan Vn Dn GV trng THPT Chun Quc gia Bc ng Quan - Thi Bnh 0912.135.401 Cu 1: Gii thch no sau y l khng ng? A. Xenluloz trinitrat hnh thnh nh phn ng: H SO c, t [C6H7O2(OH)3]n + 3nHNO3 [C6H7O2(ONO2)3]n + 3nH2O B. Rt dung dch HCl vo vi si bng, vi mn dn do phn ng: dung dch HCl (C6H10O5)n + nH2O nC6H12O6 C. Rt H2SO4 c vo vi si bng, vi b en v thng ngay do phn ng: H SO c, t (C6H10O5)n 6nC + 5nH2O D. Xenluloz triaxetat hnh thnh nh phn ng: [C6H7O2(OH)3]n + 3nCH3COOH [C6H7O2(OOCCH3)3]n + 3nH2O Cu 2: Cho Cacbon (C) ln lt tc dng vi Al, H 2O, CuO, HNO3 c, H2SO4 c, KClO3 , CO2 i u kin thch hp. S phn ng m trong C ng vai tr l cht kh? A. 4 B. 7 C. 5 D. 6 Cu 3: Thc hin phn ng crackinh butan thu c mt hn hp X gm cc ankan v cc anken. Cho ton b hn hp X vo dung dch Br2 d thy c kh thot ra bng 60% th tch X v khi lng dung dch Br2 tng 5,6 gam v c 25,6 gam brom tham gia phn ng. t chy hon ton kh bay ra thu c a mol CO2 v b mol H2O. Vy a v b c gi tr l: A. a = 0,9 mol v b = 1,5 mol B. a = 0,56 mol v b = 0,8 mol C. a = 1,2 mol v b = 1,6 mol D. a = 1,2 mol v b = 2,0 mol Cu 4: Ho tan hon ton hn hp X cha Fe3O4 v FeS2 trong 63 gam dung d ch HNO3 thu c 1,568 lt NO2 duy nht (ktc). Dung dch thu c tc dng va vi 200 ml dung dch NaOH 2M, lc kt ta ri em nung n khi lng khng i th thu c 9,76 gam cht rn. Nng % ca dung dch HNO3 ban u l: A. 47,2% B. 42,6% C. 46,2% D. 46,6% Cu 5: X phng ha hon ton 100 gam cht bo X cn dng va 100 ml dung dch NaOH 0,8M, sau phn ng thu c 100,81 gam x phng. Xc nh ch s axit ca cht bo . A. 1,4 B. 5,6 C. 11,2 D. 2,8 Cu 6: Cho cc dung dch AlCl3, NaCl, NaAlO2, HCl. Dng mt ho cht trong s cc ho cht sau: Na2CO3, NaCl, NaOH, qu tm, dung d ch NH3, NaNO3 th s ho cht c th phn bit c 4 dung dch trn l: A. 3 B. 4 C. 5 D. 6 Cu 7: Cho m gam Mg vo dung d ch cha 0,12 mol FeCl3. Sau khi phn ng xy ra hon ton thu c 3,36 gam cht rn. Gi tr ca m l: A. 2,88 gam B. 2,16 gam C. 4,32 gam D. 5,04 gam Cu 8: Cho dung dch CH3COOH 0,1M, KA = 1,8.10-5. in li ca axit axetic gim mt na so vi ban u th khi lng CH3COOH cn phi cho vo 1 lt dung dch trn l: A. 6 gam B. 12 gam C. 9 gam D. 18 gam Cu 9: ipeptit mch h X v tripeptit mch h Y u c to nn t mt -aminoaxit (no, mch h, trong phn t cha mt nhm -NH2 v mt nhm -COOH). t chy hon ton 0,1 mol Y thu c tng khi lng CO2 v H2O bng 54,9 gam. t chy hon ton 0,2 mol X, sn phm thu c cho li t t qua nc vi trong d, to ra m gam kt ta. Gi tr ca m l: A. 120 gam B. 60 gam C. 30 gam D. 45 gam Cu 10: Hp cht hu c X mch h c khi lng mol l 56 vC. Khi t chy X bng oxi thu c sn phm ch gm CO2 v H2O. X lm mt mu dung dch brm. S cng thc cu to c th c ca X l:
2 4 o
o 2 4

GSTT Group

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A. 4 B. 7 C. 6 D. 5 Cu 11: Cho dy gm cc cht: Na, Mg, Ag, O3, Cl2, HCl, Cu(OH)2, Mg(HCO3)2, CuO, NaCl, C2 H5OH, C6H5OH, C6H5NH2, CH3ONa, CH3COONa. S cht tc dng c vi dung dch axt propionic (trong iu kin thch hp) l: A. 10 B. 11 C. 9 D. 8 Cu 12: Nha phenolfomanehit c iu ch bng cch un nng phenol d vi dung dch: A. CH3COOH trong mi trng axit B. CH3CHO trong mi trng axit C. HCOOH trong mi trng axit D. HCHO trong mi trng axit Cu 13: Ha tan 3,56 gam oleum X vo nc thu c dung dch Y. trung ha dung dch Y cn dng 80 ml dung dch NaOH 1,0M. Vy cng thc ca X l: A. H2SO4.2SO3 B. H2SO4.4SO3 C. H2SO4.SO3 D. H2SO4.3SO3 Cu 14: Cho m gam bt Fe vo 200 ml dung d ch hn hp A cha H2SO4 1M, Fe(NO3)3 0,5M v CuSO4 0,25M. Khuy u cho n khi phn ng kt thc thu c 0,75m gam cht rn. Gi tr ca m l: A. 43,2 gam B. 56 gam C. 33,6 gam D. 32 gam Cu 15: Cho kim loi M vo dung d ch mui ca kim loi X thy c kt ta v kh bay ln. Cho kim loi X vo dung dch mui ca kim loi Y thy c kt ta Y. Mt khc, cho kim loi X vo dung dch mui ca kim loi Z, khng thy c hin tng g. Cho bit s sp xp no sau y ng vi chiu tng dn tnh kim loi ca X, Y, Z, M? A. Z < X < Y < M B. Y < X < Z < M C. Z < X < M < Y D. Y < X < M < Z Cu 16: H n hp kh X gm H2 v C2H4 c t khi so vi He l 3,75. Nung X vi Ni sau mt thi gian thu c hn hp kh Y c t khi so vi He l 5. Hiu sut phn ng hiro ha l: A. 50% B. 20% C. 40% D. 25% Cu 17: un nng cht H2N-CH2-CONH-CH(CH3)-CONH-CH2-COOH trong dung d ch HCl d, sau khi cc phn ng kt thc thu c sn phm l: A. H3N+-CH2-COOHCl-, H3N+-CH2-CH2-COOHClB. H3N+-CH2-COOHCl-, H3N+-CH(CH3)-COOHClC. H2N-CH2-COOH, H2N-CH2-CH2-COOH D. H2N-CH2-COOH, H2N-CH(CH3)-COOH Cu 18: Dn hn hp M gm hai cht X v Y c cng thc phn t C3H6 v C4H8 vo dung dch brom trong dung mi CCl4 thy dung dch brom b nht mu v khng c kh thot ra. Ta c cc kt lun sau: a). X v Y l 2 xicloankan vng 3 cnh b). X v Y l mt anken v mt xicloankan vng 4 cnh c). X v Y l 2 anken ng ng ca nhau d). X v Y l mt anken v mt xicloankan vng 3 cnh e). X v Y l mt xicloankan vng 3 cnh v mt xicloankan vng 4 cnh Cc kt lun ng l: A. a, c, d B. a, b, c, d C. a, b, d D. a, b, c, d, e Cu 19: em ha tan hon ton m gam Mg trong dung dch cha ng thi a mol H2SO4 v b mol HCl, sau phn ng hon ton thu c dung dch cha 2 mui c tng khi lng l 4,1667m . Thit lp biu thc lin h gia s mol ca 2 axit: A. b = 6a B. b = 4a C. b = 8a D. b = 7a HCl khan Cu 20: Cho cc phn ng sau: glucoz + CH3OH X + H2O 2X + Cu(OH)2 OH Y + 2H2O Vy cng thc ca Y l: A. (C7H14O7)2Cu B. (C7H13O7)2Cu C. (C6H12O6)2Cu D. (C6H11O6)2Cu Cu 21: t chy hon ton 1,6 gam mt este E n chc c 3,52 gam CO2 v 1,152 gam H2O. Nu cho 10 gam E tc dng vi 150 ml dung d ch NaOH 1M, c cn dung dch sau phn ng thu c 16 gam cht rn khan. Vy cng thc ca axit to nn este trn c th l: A. HOOC-CH2-CH(OH)-CH3 B. CH3-C(CH3)2-COOH C. HOOC(CH2)3CH2OH D. CH2=CH-COOH Cu 22: S sp xp no sau y ng vi chiu tng dn tnh axit? A. axit phenic < axit p-nitrobenzoic < axit p-metylbenzoic < axit benzoic B. axit p-nitrobenzoic < axit benzoic < axit phenic < axit p-metylbenzoic C. axit p-metylbenzoic < axit p-nitrobenzoic < axit benzoic < axit phenic D. axit phenic < axit p-metylbenzoic < axit benzoic < axit p-nitrobenzoic

GSTT Group

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GSTT Group su tm v gii thiu

Cu 23: Ha tan hon ton m gam hn hp gm Na, Na2O, NaOH v Na2CO3 trong dung dch axt H2SO4 40% (va ) thu c 8,96 lt hn hp kh c t khi i vi H2 bng 16,75 v dung dch Y c nng 51,449%. C cn Y thu c 170,4 gam mui. Gi tr ca m l: A. 37,2 gam B. 50,4 gam C. 23,8 gam D. 50,6 gam Cu 24: Ha tan hon ton 30 gam hn hp X gm Mg, Al v Zn trong dung dch HNO3, sau phn ng hon ton thu c dung dch Y v hn hp gm 0,1 mol N2O v 0,1 mol NO. C cn dung dch sau phn ng thu c 127 gam hn hp mui. Vy s mol HNO3 b kh trong phn ng trn l: A. 0,40 mol B. 0,30 mol C. 0,45 mol D. 0,35 mol Cu 25: Hn hp X gm: HCHO, CH3COOH, HCOOCH3 v CH3CH(OH)COOH. t chy hon ton hn hp X cn V lt O2 (ktc) sau phn ng thu c CO2 v H2O. Hp th ht sn phm chy vo nc vi trong d thu c 30 gam kt ta. Vy gi tr ca V tng ng l: A. 5,60 lt B. 8,40 lt C. 7,84 lt D. 6,72 lt Cu 26: Trong cc chui phn ng ha hc sau, chui no c phn ng ha hc khng th thc hin c? A. P P2O5 H3PO4 CaHPO4 Ca3(PO4)2 CaCl2 Ca(OH)2 CaOCl2 B. Cl2 KCl KOH KClO3 O2 O3 KOH CaCO3 CaO CaCl2 Ca C. NH3 N2 NO NO2 NaNO3 NaNO2 N2 Na3N NH3 NH4Cl HCl D. S H2S SO2 HBr HCl Cl2 H2SO4 H2S PbS H2S NaHS Na2S
Dung dch HCl d KMnO4 , t X1 axit terephtalic. Hy cho bit tng i s cc h s Cu 27: Cho s sau: p-xilen (1) (2)
0

cht trong phng trnh phn ng (1)? A. 8 B. 16 C. 14 D. 18 Cu 28: Cho cc nhn xt sau: (1). C th to c ti a 2 ipeptit t phn ng trng ngng hn hp Alanin v Glyxin (2). Khc vi axt axetic, axt amino axetic c th tham gia phn ng vi axit HCl hoc phn ng trng ngng (3). Ging vi axt axetic, aminoaxt c th tc dng vi baz to mui v nc (4). Axt axetic v axt -amino glutaric c th lm i mu qu tm thnh (5). Thy phn khng hon ton peptit: Gly-Phe-Tyr-Gly-Lys-Gly-Phe-Tyr c th thu c 6 tripeptit c cha Gly (6). Cho HNO3 c vo ng nghim cha anbumin thy to dung dch mu tm C bao nhiu nhn xt ng? A. 3 B. 5 C. 6 D. 4 Cu 29: X l este to t axit n chc v ancol a chc. X khng tc dng vi Na. Thy phn hon ton a gam X cn dng va 100 gam dung dch NaOH 6% thu c 10,2 gam mui v 4,6 gam ancol. Vy cng thc ca X l: A. (CH3COO)2C3H6 B. (HCOO)2C2H4 C. (HCOO)3C3H5 D. (C2H3COO)3C3H5 Cu 30: Trong m t bnh kn dung tch 10 lt nung m t hn hp gm 1 mol N 2 v 4 mol H 2 nhit t0 C v p sut P. Khi phn ng t n trong thi cn bng thu c mt hn hp trong NH3 chim 25% th tch. Xc nh hng s cn bng KC ca phn ng: N2 + 3H2 2NH3. A. 25,6 B. 1,6 C. 6,4 D. 12,8 Cu 31: Cho 2,8 gam bt st tc dng hon ton vi V ml dung dch HNO3 0,5M thu c sn phm kh NO duy nht v dung dch X. X c th tc dng va vi dung dch cha 0,03 mol AgNO3. Gi tr ca V l: A. 280 ml B. 320 ml C. 340 ml D. 420 ml Cu 32: t chy hon ton m gam hn hp X gm 2 ancol a chc, mch h, c cng s nhm -OH thu c 11,2 lt kh CO2 (ktc) v 12,6 gam H2O. Mt khc nu cho m gam hn hp X tc dng vi 10 gam Na th sau phn ng thu c a gam cht rn. Gi tr ca a v m ln lt l: A. 13,8 gam v 23,4 gam B. 9,2 gam v 13,8 gam C. 23,4 gam v 13,8 gam D. 9,2 gam v 22,6 gam Cu 33: Cho 672 ml kh clo (ktc) i qua 200 ml dung dch KOH a mol/l 1000C. Sau khi phn ng xy ra hon ton thu c dung dch X c pH = 13. Lng cht rn thu c khi c cn dung dch X l: A. 1,97 gam B. 3,09 gam C. 6,07 gam D. 4,95 gam Cu 34: Thu phn dung d ch cha 34,2 gam mantoz mt th i gian. L y ton b s n phm thu c sau phn ng thu phn cho tc dng vi lng d dung dch AgNO3 trong NH3, sau phn ng hon ton thu c 31,32 gam Ag. Hiu sut ca phn ng thu phn mantoz l: A. 50% B. 45% C. 72,5% D. 55%

GSTT Group

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GSTT Group su tm v gii thiu

Cu 35: Thm t t tng git ca 100 ml dung d ch cha Na2CO3 1,2M v NaHCO3 0,6M vo 200 ml dung dch HCl 1M, sau phn ng hon ton thu c dung dch X. Cho dung d ch nc vi trong d vo dung dch X th thu c bao nhiu gam kt ta. A. 10 gam B. 8 gam C. 12 gam D. 6 gam Cu 36: Cho cc monome sau: stiren, toluen, metylaxetat, vinylaxetat, metylmetacrylat, metylacrylat, propilen, benzen, axt etanoic, axt -aminocaproic, caprolactam, etilenoxit. S monome tham gia phn ng trng hp l: A. 5 B. 6 C. 7 D. 8 Cu 37: Hp cht X c CTPT l C5H13N. Khi cho X tc dng vi HNO2 thu c cht Y c CTPT l C5H12O. Oxi ha Y thu c cht hu c Y1 c CTPT l C5H10O. Y1 khng c phn ng trng bc. Mt khc, hirat ha Y thu c 2 anken l ng phn hnh hc ca nhau. Vy tn gi ca X l: A. pentan-3-amin B. pentan-2-amin C. 3-metylbutan-2-amin D. isopentyl amin Cu 38: X v Y l hai hp cht hu c ng phn ca nhau cng c cng thc phn t C5H6O4Cl2. Thy phn hon ton X trong NaOH d thu c hn hp cc sn phm trong c 2 mui v 1 ancol. Thy phn hon ton Y trong KOH d thu c hn hp cc sn phm trong c 1 mui v 1 anehit. X v Y ln lt c cng thc cu to l: A. HCOOCH2COOCH2CHCl2 v CH3COOCH2COOCHCl2 B. CH3COOCCl2COOCH3 v CH2ClCOOCH2COOCH2Cl C. HCOOCH2COOCCl2CH3 v CH3COOCH2COOCHCl2 D. CH3COOCH2COOCHCl2 v CH2ClCOOCHClCOOCH3 Cu 39: Cho cc nguyn t sau 13Al; 5B; 9F; 21Sc. Hy cho bit c im chung trong cu to ca nguyn t cc nguyn t . A. u l cc nguyn t thuc cc chu k nh B. Electron cui cng thuc phn lp p C. u c 1 electron c thn trng thi c bn D. u c 3 lp electron Cu 40: Khi t chy mt polime sinh ra t phn ng ng trng hp isopren vi acrilonitrin bng lng oxi va thu c hn hp kh cha 58,33% CO2 v th tch. T l mt xch isopren vi acrilonitrin trong polime trn l: A. 1:3 B. 1:2 C. 2:1 D. 3:2 Cu 41: Cho m gam kim loi M tan hon ton trong 200 ml dung d ch HCl 0,5M thu c dung dch X v 2,016 lt H2 (ktc). Cho dung dch AgNO3 d vo dung dch X th thu c bao nhiu gam kt ta? A. 23,63 gam B. 32,84 gam C. 28,70 gam D. 14,35 gam Cu 42: ng vi cng thc phn t C7H8O c bao nhiu ng phn l dn xut ca benzen v s ng phn u tc dng c vi cc cht: K, KOH, (CH3CO)2O: A. 5 v 2 B. 5 v 3 C. 4 v 2 D. 4 v 3 Cu 43: X c cng thc phn t l C4H8Cl2. Thy phn X trong dung d ch NaOH un nng thu c ch t hu c Y n chc. Hy cho bit X c bao nhiu cng thc cu to? A. 5 B. 3 C. 2 D. 4 Cu 44: Cho axeton tc dng vi HCN thu c cht hu c X. Thy phn X trong mi trng axit thu c cht hu c Y. hirat ha X thu c axit cacboxylic Y. Vy Y l cht no sau y? A. CH2=C(CH3)COOH B. CH2=CH-COOH C. CH2=CHCH2COOH D. CH3CH=CHCOOH Cu 45: Ho tan Fe3O4 trong lng d dung dch H2SO4 long thu c dung dch X. Dung dch X tc dng c vi bao nhiu cht trong s cc cht sau: Cu, NaOH, Br2, AgNO3, KMnO4, MgSO4, Mg(NO3)2, Al? A. 5 B. 6 C. 7 D. 8 Cu 46: t chy hon ton 0,1 mol cht hu c X c cng thc tng qut CxHyO2 thu c khng n 17,92 lt CO2 (ktc). trung ho 0,2 mol X cn 0,2 mol NaOH. Mt khc cho 0,5 mol X tc dng vi Na d thu c 0,5 mol H2. S nguyn t H c trong phn t X l: A. 6 B. 8 C. 10 D. 12 Cu 47: T l khi lng phn t gia oxit cao nht ca nguyn t R v hp cht kh ca n vi hiro bng
5,5 . 2

Khi lng mol nguyn t ca R l: A. 32 B. 12 C. 28 D. 19 Cu 48: Cho 100 gam glixerol tc dng vi 3 mol HNO3 c (xt: H2SO4 c). Tnh khi lng sn phm cha nhm nitro thu c. Bit rng c 80% glixerol v 70% HNO3 phn ng. A. 174,5 gam B. 197,9 gam C. 213,2 gam D. 175,4 gam
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GSTT Group su tm v gii thiu

Cu 49: Cho s sau: etanol X. Hy cho bit trong cc cht sau: etilen, etylclorua, etanal, axit etanoic, etylaxetat, buta-1,3-ien, glucoz. Bao nhiu cht c th l cht X? A. 6 B. 5 C. 4 D. 3 Cu 50: Nung hn hp gm 3,2 gam Cu v 17 gam AgNO3 trong bnh kn, chn khng. Sau phn ng hon ton thu c hn hp kh X. Cho X phn ng ht vi nc thu c 2 lt dung dch Y. pH ca dung dch Y l: A. 0,523 B. 0,664 C. 1 D. 1,3
Th sinh khng c dng bt c ti liu no (k c Bng h thng tun hon)

p n 2011-2012 1.D 11.A 21.C 31.B 41.A 2.D 12.D 22.D 32.C 42.B 3.B 13.C 23.D 33.C 43.B 4.D 14.A 24.D 34.B 44.A 5.D 15.B 25.D 35.D 45.C 6.D 16.A 26.D 36.C 46.B 7.A 17.B 27.C 37.A 47.B 8.D 18.A 28.A 38.B 48.A 9.A 19.C 29.C 39.C 49.B 10.C 20. 30.D 40.A 50.D

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GSTT Group su tm v gii thiu S GIO DC V O TO THI BNH

THI CHN HC SINH GII LP 12 NM HC 2012-2013

Mn: HO HC Thi gian: 90 pht (Khng k thi gian giao ) gm 04 trang; Th sinh lm bi vo Phiu tr li trc nghim M : 195

Cho nguyn t khi: H=1; C=12; N=14; O=16; Na=23; Mg=24; Al=27; Si=28; P=31; S=32; Cl=35,5; K=39; Ca=40; Mn=55; Fe=56; Cu=64; Br=80; Ag=108; I=127; Ba=137. Cu 1: Cho 300 ml dung dch Ba(OH)2 0,1M vo 250 ml dung dch Al2(SO4)3 x(M) thu c 8,55 gam kt ta. Thm tip 400 ml dung dch Ba(OH)2 0,1M vo hn hp phn ng th lng kt ta thu c l 18,8475 gam. Gi tr ca x l A. 0,06. B. 0,09. C. 0,12. D. 0,1. Cu 2: Cho Fe tc dng ht vi dung dch H2SO4 c nng thu c kh SO2 (sn phm kh duy nht) v 8,28 gam mui. Bit s mol Fe bng 37,5% s mol H2SO4 phn ng. Khi lng Fe tham gia phn ng l A. 1,68 gam. B. 1,12 gam. C. 1,08 gam. D. 2,52 gam. Cu 3: Cho 0,1 mol cht X (C2H8O3N2) tc dng vi dung dch cha 0,2 mol NaOH un nng thu c cht kh lm xanh giy qu tm tm t v dung dch Y. C cn dung dch Y c m gam cht rn khan. Gi tr ca m l A. 5,7. B. 12,5. C. 15,5. D. 21,8. Cu 4: Cho 2,16 gam hn hp gm Al v Mg tan ht trong dung dch axit HNO3 long, un nng nh to ra dung dch X v 448 ml (o 354,90 K v 988 mmHg) hn hp kh Y kh gm 2 kh khng mu, khng i mu trong khng kh. T khi ca Y so vi oxi bng 0,716 ln t khi ca kh cacbonic so vi nit. Lm khan X mt cch cn thn thu c m gam cht rn Z, nung Z n khi lng khng i thu c 3,84 gam cht rn T. Gi tr ca m l A. 15,18. B. 17,92. C. 16,68. D. 15,48. Cu 5: Oxi ha 4,6 gam ancol etylic bng O 2 iu kin thch hp thu c 6,6 gam hn hp X gm anehit, axit, ancol d v nc. Hn hp X tc dng vi natri d sinh ra 1,68 lt H 2 (ktc). Hiu sut ca phn ng chuyn ha ancol thnh anehit l A. 75%. B. 50%. C. 33%. D. 25%. Cu 6: Hn hp X gm a mol Fe, b mol FeCO 3 v c mol FeS2. Cho X vo bnh dung tch khng i cha khng kh (d), nung n khi cc phn ng xy ra hon ton, sau a v nhit ban u thy p sut trong bnh bng p sut trc khi nung. Quan h ca a, b, c l A. a = b+c. B. 4a+4c=3b. C. b=c+a. D. a+c=2b. 0 Cu 7: ho tan ht mt mu Al trong dung dch axit HCl 25 C cn 36 pht. Cng mu Al tan ht trong dung dch axit ni trn 450C trong 4 pht. Hi ho tan ht mu Al trong dung dch axit ni trn 60 0C th cn thi gian bao nhiu giy? A. 45,465 giy. B. 56,342 giy. C. 46,188 giy. D. 38,541 giy. Cu 8: Cho cc pht biu sau : (1) Trong hp cht vi oxi, nit c cng ha tr cao nht bng V. (2) Trong cc hp cht, flo lun c s oxi ha bng -1. (3) Lu hunh trong hp cht vi kim loi lun c s oxi ha l -2. (4) Trong hp cht, s oxi ha ca nguyn t lun khc khng. (5) Trong hp cht, mt nguyn t c th c nhiu mc s oxi ha khc nhau. (6) Trong mt chu k, theo chiu tng in tch ht nhn, bn knh nguyn t ca cc nguyn t tng dn. S pht biu ng l A. 3. B. 5. C. 2. D. 4. Cu 9: Hp cht hu c C4H7O2Cl (X), khi thy phn trong mi trng kim c cc sn phm, trong c hai cht c kh nng phn ng trng gng. Cng thc cu to ng ca (X) l A. HCOO-CH2-CHCl-CH3. B. CH3COO-CH2-CH2Cl. C. HCOOCHCl-CH2-CH3. D. ClCH2COO-CH2-CH3. Cu 10: Cho cc phn ng sau: (1) dung dch Na2CO3 + dung dch H2SO4. (2) dung dch Na2CO3 + dung dch FeCl3. (3) dung dch Na2CO3 + dung dch CaCl2. (4) dung dch NaHCO3 + dung dch Ba(OH)2. (5) dung dch (NH4)2SO4 + dung dch Ba(OH)2. (6) dung dch Na2S + dung dch AlCl3. S phn ng to ng thi c kt ta v kh bay ra l A. 3. B. 6. C. 4. D. 5. Cu 11: Cht hu c X cha vng benzen c cng thc phn t l CxHyO. Bit % O = 14,81% (theo khi lng). S cng thc cu to ph hp ca X l A. 8. B. 6. C. 7. D. 5. GSTT Group Sharing the value!

GSTT Group su tm v gii thiu

Cu 12: Thc hin tng hp tetrapeptit t 3,0 mol glyxin; 4,0 mol alanin v 6,0 mol valin. Bit phn ng xy ra hon ton. Khi lng tetrapeptit thu c l A. 1510,5 gam. B. 1120,5 gam. C. 1049,5 gam. D. 1107,5 gam. Cu 13: un nng m gam cht hu c (X) cha C, H, O vi 100 ml dung dch NaOH 2M n khi phn ng xy ra hon ton. trung ha lng NaOH d cn 40 ml dung dch HCl 1M. Lm bay hi cn thn dung dch sau khi trung ha, thu c 7,36 gam hn hp 2 ancol n chc (Y), (Z) v 15,14 gam hn hp 2 mui khan, trong c mt mui ca axit cacboxylic (T). Kt lun no sau y ng? A. Axit (T) c cha 2 lin kt i trong phn t. B. S nguyn t cacbon trong axit (T) bng mt na s nguyn t cacbon trong cht hu c X. C. Ancol (Y) v (Z) l 2 cht ng ng lin tip vi nhau. D. Cht hu c X c cha 14 nguyn t hiro. Cu 14: Thy phn 4,3 gam poli(vinyl axetat) trong mi trng kim thu c 2,62 gam polime. Hiu sut ca phn ng thy phn l A. 60%. B. 80%. C. 75%. D. 85%. Cu 15: t chy hon ton 24,8 gam hn hp X gm (axetilen, etan v propilen) thu c 1,6 mol nc. Mt khc 0,5 mol X tc dng va vi dung dch cha 0,645 mol Br2. Phn trm th tch ca etan trong hn hp X l A. 5,0%. B. 3,33%. C. 4,0 %. D. 2,5%. Cu 16: Cho m gam hn hp tinh th gm NaBr, NaI tc dng va vi H 2SO4 c iu kin thch hp, thu c hn hp kh X iu kin thng. iu kin thch hp hn hp X tc dng va vi nhau to thnh 9,6 gam cht rn mu vng v mt cht lng khng lm i mu qu tm. Gi tr ca m l A. 260,6. B. 240. C. 404,8. D. 50,6. Cu 17: Cho m gam butan qua xc tc ( nhit thch hp), thu c hn hp gm 5 hirocacbon. Cho hn hp kh ny sc qua bnh ng dung dch nc brom d th lng brom tham gia phn ng l 25,6 gam v sau th nghim bnh brom tng 5,32 gam. Hn hp kh cn li sau khi qua dung dch nc brom c t khi so vi metan l 1,9625. Gi tr ca m l A. 17,4. B. 8,7. C. 5,8. D. 11,6. Cu 18: Hp th ht 4,48 lt CO2 (ktc) vo dung dch cha x mol KOH v y mol K2CO3 thu c 200 ml dung dch X. Ly 100 ml dung dch X cho t t vo 300 ml dung dch HCl 0,5M thu c 2,688 lt kh (ktc). Mt khc, 100 ml dung dch X tc dng vi dung dch Ba(OH) 2 d thu c 39,4 gam kt ta. Gi tr ca x l A. 0,15. B. 0,2. C. 0,1. D. 0,06. Cu 19: Dung dch CH3COOH (dung dch A) c pH = 2,57. Nu trn 100 ml dung dch A vi 100 ml dung dch NaOH (dung dch B) c pH = 13,3 c 200 ml dung dch C. Bit Ka(CH3COOH) = 1,85.10-5. pH ca dung dch C l A. 3,44. B. 4,35. C. 5,47. D. 4,74. Cu 20: Cho cc pht biu sau: (1) Trong 3 dung dch c cng pH l HCOOH, HCl v H2SO4 th dung dch c nng mol ln nht l HCOOH. (2) Phn ng trao i ion khng km theo s thay i s oxi ha ca nguyn t. (3) C th phn bit trc tip 3 dung dch: KOH, HCl, H2SO4 (long) bng mt thuc th l BaCO3. (4) Axit, baz, mui l cc cht in li. (5) Dung dch CH3COONa v dung dch C6H5ONa (natri phenolat) u l dung dch c pH >7. (6) Theo thuyt in li, SO3 v C6H6 (benzen) l nhng cht in li yu. S pht biu ng l A. 5. B. 3. C. 2. D. 4. Cu 21: t chy hon ton 4,02 gam hn hp gm axit acrylic, vinyl axetat v metyl metacrylat ri cho ton b sn phm chy vo bnh 1 ng dung dch H 2SO4 c, bnh 2 ng dung dch Ba(OH) 2 d thy khi lng bnh 1 tng m gam, bnh 2 xut hin 35,46 gam kt ta. Gi tr ca m l A. 2,70. B. 2,34. C. 3,24. D. 3,65. Cu 22: Cho cc pht biu sau: (1) CaOCl2 l mui kp. (2) Lin kt kim loi l lin kt c hnh thnh gia cc nguyn t v ion kim loi trong mng tinh th do s tham gia ca cc electron t do. (3) Supephotphat kp c thnh phn ch yu l Ca(H2PO4)2. (4) Trong cc HX (X: halogen) th HF c tnh axit yu nht. (5) Bn nhiu phn m amoni s lm cho t chua. (6) Kim loi c nhit nng chy thp nht l thy ngn (Hg). (7) CO2 l phn t phn cc. S pht biu ng l A. 7. B. 4. C. 6. D. 5. Cu 23: Cho phn ng: GSTT Group Sharing the value!

GSTT Group su tm v gii thiu

CH3COCH3 + KMnO4 + KHSO4 CH3COOH + MnSO4 + K2SO4 + CO2 + H2O Tng h s ca cc cht (l nhng s nguyn, ti gin) trong phng trnh phn ng l A. 68. B. 97. C. 88. D. 101. Cu 24: C 4 cht: isopropyl benzen (1), ancol benzylic (2), benzanehit (3) v axit benzoic (4). Th t tng dn nhit si ca cc cht trn l A. (2) < (3) < (1) < (4). B. (2) < (3) < (4) < (1). C. (1) < (2) < (3) < (4). D. (1) < (3) < (2) < (4). 0 0 Cu 25: Bit tan ca NaCl trong 100 gam nc 90 C l 50 gam v 0 C l 35 gam. Khi lm lnh 600 gam dung dch NaCl bo ha 900C v 00C lm thot ra bao nhiu gam tinh th NaCl? A. 45 gam. B. 55 gam. C. 50 gam. D. 60 gam. Cu 26: Cho hn hp (HCHO v H2 d) i qua ng ng bt Ni un nng thu c hn hp X. Dn ton b sn phm thu c vo bnh nc lnh thy khi lng bnh tng 5,9 gam. Ly ton b dung dch trong bnh cho tc dng vi dung dch AgNO 3/NH3 d thu c 10,8 gam Ag. Khi lng ancol c trong X l gi tr no di y? A. 8,3 gam. B. 5,15 gam. C. 9,3 gam. D. 1,03 gam. Cu 27: Cho cc nguyn t sau: 13Al; 5B; 9F; 21Sc. Hy cho bit c im chung ca cc nguyn t . A. Electron cui cng thuc phn lp p. B. u c 1 electron c thn trng thi c bn. C. u c 3 lp electron. D. u l cc nguyn t thuc chu k nh. Cu 28: Ho tan hon ton 0,775 gam n cht (X) trong dung dch HNO 3 c thu c 5,75 gam hn hp gm hai kh (c thnh phn % theo khi lng ca oxi nh nhau) v dung dch (Y). Bit t khi hi ca hn hp kh so vi hiro l 115/3. trng thi c bn nguyn t X c s electron c thn l A. 3. B. 4. C. 2. D. 1. Cu 29: Cho cc cht: Glixerol, etylen glicol, gly-ala-gly, glucoz, axit axetic, saccaroz, anehit fomic, anilin. S cht tc dng c vi Cu(OH)2 ( iu kin thch hp) l A. 7. B. 8. C. 6 . D. 5. Cu 30: Nguyn t X c cu trc mng lp phng tm din (hnh bn). Phn trm th tch khng gian trng trong mng li tinh th ca X l A. 32 %. B. 26 %. C. 74 %. D. 68 %. Cu 31: Tch nc hon ton t 25,8 gam hn hp A gm 2 ancol X v Y (M X<MY), sau phn ng thu c hn hp B gm 2 anken k tip nhau trong dy ng ng. t chy hon ton B cn va 1,8 mol O 2. Mt khc nu tch nc khng hon ton 25,8 gam A ( 1400C, xc tc H2SO4 c), sau phn ng thu c 11,76 gam hn hp cc ete. Bit hiu sut ete ha ca Y l 50%. Hiu sut ete ha ca X l A. 35%. B. 65%. C. 60%. D. 55%. Cu 32: Mt khong cht c cha 20,93% nhm; 21,7% silic (theo khi lng), cn li l oxi v hiro. Phn trm khi lng ca hiro trong khong cht l A. 2,68%. B. 5,58%. C. 1,55%. D. 2,79%. Cu 33: Cho cc cht sau: Tristearin, hexan, benzen, glucoz, xenluloz, metylamin, phenylamoni clorua, triolein, axetilen, saccaroz. S cc cht khng tan trong nc l A. 6. B. 9. C. 8. D. 7. Cu 34: Khi thy phn 500 gam protein A thu c 170 gam alanin. Nu phn t khi ca A l 50.000, th s mt xch alanin trong phn t A l bao nhiu? A. 191. B. 189. C. 196. D. 195. Cu 35: C cc dung dch ring bit sau: H2N-CH2-CH2-CH(NH2)-COOH, HOOC-CH2-CH2-CH(NH2)-COOH, H2N-CH2-COONa, ClH3N-CH2-COOH, C6H5-NH3Cl (phenylamoni clorua). S lng cc dung dch c pH < 7 l A. 2. B. 5. C. 4. D. 3. Cu 36: Hirocacbon thm C9H8 (X) lm mt mu nc brom, cng hp c vi brom theo t l mol 1:2, khi oxi ha to thnh axit benzoic, khi tc dng vi dung dch AgNO3 trong NH3 to kt ta c trng. Pht biu no sau y khng ng? A. X c 3 cng thc cu to ph hp. B. X c tn gi l benzyl axetilen. C. X c bt bo ha bng 6. D. X c lin kt ba u mch. Cu 37: Mt hn hp Y gm 2 este A, B mch h (MA< MB). Nu un nng 15,7 gam hn hp Y vi dung dch NaOH d th thu c mt mui ca axit hu c n chc v 7,6 gam hn hp 2 ancol no n chc k tip nhau trong dy ng ng. Nu t chy 15,7 gam hn hp Y cn dng va ht 21,84 lt O 2 v thu c 17,92 lt CO2. Cc th tch kh o ktc. Phn trm khi lng ca A trong hn hp Y l A. 63,69%. B. 40,57%. C. 36,28%. D. 48,19%. Cu 38: Qu trnh iu ch t no di y l qu trnh trng hp? A. T lapsan t etylen glicol v axit terephtalic. B. T capron t axit -amino caproic. C. T nilon-6,6 t hexametyleniamin v axit aipic. D. T nitron (t olon) t acrilonitrin. GSTT Group Sharing the value!

GSTT Group su tm v gii thiu

Cu 39: Trong cht bo lun c mt lng axit bo t do. Khi thy phn hon ton 2,145 kg cht bo cn dng 0,3 kg NaOH, thu c 0,092 kg glixerol v m (kg) hn hp mui natri. Gi tr ca m l A. 3,765. B. 2,610. C. 2,272. D. 2,353. Cu 40: Hai hp cht thm X v Y c cng cng thc phn t l C nH2n-8O2. Bit hi cht Y c khi lng ring 5,447 gam/lt (ktc). X c kh nng phn ng vi Na gii phng H 2 v c phn ng trng bc. Y phn ng c vi Na2CO3 gii phng CO2. Tng s cng thc cu to ph hp ca X v Y l A. 4. B. 5. C. 7. D. 6. Cu 41: Cho cc pht biu sau: (1) Cc tiu phn Ar, K+, Cl- u c cng s n v in tch ht nhn. (2) Trong nguyn t s proton lun bng s ntron. (3) ng v l hin tng cc nguyn t c cng s khi. (4) Bn knh ca cation nh hn bn knh ca nguyn t tng ng. (5) Nc thuc loi tinh th nguyn t. (6) Kim cng c cu trc tinh th phn t. S pht biu ng l A. 4. B. 2. C. 3. D. 1. Cu 42: Cho cc cht sau: Glixerol, ancol et ylic, p-crezol, phenylamoni clorua, valin, lysin, anilin, ala-gly, phenol, amoni hirocacbonat. S cht tc dng c vi dung dch NaOH l A. 10. B. 9. C. 7. D. 8. Cu 43: Cho 1,0 mol axit axetic tc dng vi 1,0 mol ancol isopropylic th cn bng t c khi c 0,6 mol isopropyl axetat c to thnh. Lc ngi ta cho thm 2,0 mol axit axetic vo hn hp phn ng, cn bng b ph v v chuyn n trng thi cn bng mi. S mol ca isopropyl axetat trng thi cn bng mi l A. 1,25 mol. B. 0,25 mol. C. 0,85 mol. D. 0,50 mol. Cu 44: Khi un nng 25,8 gam hn hp ru (ancol) etylic v axit axetic c H2SO4 c lm xc tc thu c 14,08 gam este. Nu t chy hon ton lng hn hp ban u thu c 23,4 ml nc. Hiu sut ca phn ng este ha l A. 70%. B. 80%. C. 75%. D. 85%. Cu 45: Trong phng th nghim c cc dung dch v cht lng ng trong cc bnh mt nhn ring bit gm NH4HCO3, Ba(HCO3)2, C6H5ONa (natri phenolat), C6H6 (benzen), C6H5NH2(anilin) v KAlO2 hoc K[Al(OH)4]. Hy chn mt thuc th nhn bit trc tip c cc dung dch v cht lng trn? A. Dung dch NaOH. B. Dung dch H2SO4. C. Dung dch BaCl2. D. Qu tm. Cu 46: Cho 2,5 kg glucoz cha 20% tp cht ln men thnh ru (ancol) etylic. Tnh th tch dung dch ru 40 0 thu c? Bit ru nguyn cht c khi lng ring 0,8 g/ml v trong qu trnh ch bin, ru b hao ht mt 10%. A. 2300,0 ml. B. 2875,0 ml. C. 3194,4 ml. D. 2785,0 ml. Cu 47: Cho 30,1 gam hn hp X gm Cu v Fe3O4 tc dng vi dung dch HNO 3 long, un nng v khuy u. Sau khi cc phn ng xy ra hon ton thu c 1,68 lt NO (sn phm kh duy nht, ktc), dung dch Y v cn d 0,7 gam kim loi. C cn dung dch Y, khi lng mui khan thu c l A. 54,45 gam. B. 68,55 gam. C. 75,75 gam. D. 89,70 gam. Cu 48: Cho cc cht: H2S, S, SO2, FeS, Na2SO3, FeCO3, Fe3O4, FeO, Fe(OH)2. C bao nhiu cht trong s cc cht trn tc dng c vi H2SO4 c nng? A. 6. B. 8. C. 5. D. 7. Cu 49: Nhit phn hon ton 83,5 gam mt hn hp hai mui nitrat: A(NO3)2 v B(NO3)2 (A l kim loi h s v tc dng c vi nc iu kin thng, B l kim loi h d) ti khi to thnh nhng oxit, th tch hn hp kh thu c gm NO2 v O2 l 26,88 lt (0oC v 1atm). Sau khi cho hn hp kh ny qua dung dch NaOH d th th t ch ca hn hp kh gim 6 ln. Thnh phn % theo khi lng ca A(NO 3)2 v B(NO3)2 trong hn hp ln lt l A. 78,56% v 21,44%. B. 40% v 60%. C. 33,33% v 66,67%. D. 50% v 50%. Cu 50: Cho cc pht biu sau y: (1) Amilopectin c cu trc dng mch khng phn nhnh. (2) Xenluloz c cu trc dng mch phn nhnh. (3) Saccaroz b kh bi AgNO3/dd NH3. (4) Xenluloz c cng thc l [C6H7O2(OH)3]n. (5) Saccaroz l mt isaccarit c cu to t mt gc glucoz v mt gc fructoz lin kt vi nhau qua nguyn t oxi. (6) Tinh bt l cht rn, dng v nh hnh, mu trng, khng tan trong nc lnh. S pht biu ng l A. 4. B. 3. C. 5. D. 6.
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HT -----( p n trang tip) Sharing the value!

GSTT Group

GSTT Group su tm v gii thiu

Cu 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 M 195 B D B D D C C C C A D D B B A A D C D A B D C D D B B A A B C C A A D A A D C A D C C B B B C B A B

Cc em hc sinh lu : Ngoi hot ng tnh nguyn cc tri tr m ci, k t 7h30 23/12/2012 GSTT Group s trin khai chng trnh Tip sc ma thi cho cc em hc sinh lp 12 cc khi trn din n GSTT.VN. Mi thc mc ca cc em s c cc anh ch
GSTT Group Sharing the value!

GSTT Group su tm v gii thiu

h tr ngay v lun! Ngoi ra cc anh ch cng su tm v nh hng nhng ti liu hay cho cc em hc. i ng h tr gm cc anh ch sinh vin xut s c. in hnh c cc anh/ ch th khoa i hc 2012 tham gia: 1. Anh Nguyn Thanh Long ( th khoa dc) 2. Anh Dng Cng Trng ( th khoa Kinh t quc dn) 3. Anh Don Trung San ( th khoa Dc) 4. Anh V Hng i ( th khoa H quc gia HN) 5. Anh Hong nh Quang ( khoa Ngoi Thng) 6. Anh Trn Vn ng ( Khoa Y H Ni, 28 im khi A) 7. Ch Ph m Th Huyn Quyn ( th khoa Lut H Ni) 8. Ch V Thu Tho ( Th khoa S phm) 9. Nguyn Vn Tin ( Th khoa s phm) Cc em lu theo di!

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