HOCHOAHOC.

COM Chuyn trang hc ha hc

CHUYN RU PHNOL
Mt s vn ch :
1. S lng ete sinh ra khi tch nc n phn t ancol =
2
) 1 ( + n n

2. Khi t chy ancol no n
2
CO
< n
O H
2

3. Ancol no n chc tc dng vi Na n
ancol
= 2n
2
H

4. Ancol tch nc to c anken Ancol no n chc
5. Tch nc 2 ancol c 2 anken lin tip cng l 2 ancol no n chc, mch h lin tip.
6. Hai anken lin tip cng H
2
O c 2 ancol lin tip.
7. Ch qui tc Zaixep, Maccopnhicop xc nh ng sn phm tch H
2
O v cng H
2
O.
8. - Ancol b oxi ha thnh anhit l ancol bc I (t CTPT: R-CH
2
OH)
- Ancol b oxi ha thnh xeton l ancol bc II (t CTPT: R-CH(OH)-)-R
1

- Ancol khng b oxi ha l ancol bc III
9. t CTPT ancol no: C
n
H
2n+2-x
(OH)
x
. iu kin: n > 1 v x s n.
10. Phenol tc dng vi Br
2
cho kt ta trng 2,4,6-tribromphenol, tc dng vi acid nitric(HNO
3
)
vi xc tc H
2
SO
4c
cho kt ta vng 2,4,6-trinitrophenol (axit picric)
11. Ancol a chc tc dng c vi Cu(OH)
2
cho dung dch mu xanh c trng th cc nhm
OH phi k nhau.
12.Cng thc tnh s ng phn ancol n chc no, mch h : Cn H2n+2O
S ng phn Cn H2n+2O = 2
n- 2
( 1 < n < 6 )
V d : S ng phn ca ancol c cng thc phn t l :
a. C3H8O = 2
3-2
= 2
b. C4H10O = 2
4-2
= 4
c. C
5
H
12
O = 2
5-2
= 8
13.Cng thc tnh s C ca ancol no, ete no hoc ca ankan da vo phn ng chy :
S C ca ancol no hoc ankan =
2 2
2
CO O H
CO
n n
n

( Vi n
H
2
O
> n
CO
2
)
V d 1 : t chy mt lng ancol no n chc A c 15,4 gam CO
2
v 9,45 gam H
2
O . Tm
cng thc phn t ca A ?
S C ca ancol no =
2 2
2
CO O H
CO
n n
n

=
35 , 0 525 , 0
35 , 0

= 2
Vy A c cng thc phn t l C
2
H
6
O
V d 2: t chy hon ton mt lng hirocacbon A thu c 26,4 gam CO
2
v 16,2 gam H
2
O
. Tm cng thc phn t ca A ?
( Vi n
H
2
O
= 0,7 mol > n
CO
2
= 0,6 mol ) => A l ankan
S C ca ankan =
2 2
2
CO O H
CO
n n
n

=
6 , 0 7 , 0
6 , 0

= 6
Vy A c cng thc phn t l C
6
H
14
14. Cng thc tnh khi lng ancol n chc no hoc hn hp ankan n chc notheo khi
lng CO2 v khi lng H2O :
mancol = mH
2
O -
11
2
CO
m

HOCHOAHOC.COM Chuyn trang hc ha hc


V d : Khi t chy hon ton m gam hn hp hai ancol n chc no, mch h thu c 2,24 lt
CO
2
( ktc ) v 7,2 gam H
2
O. Tnh khi lng ca ancol ?
m
ancol
= m
H
2
O
-
11
2
CO
m

= 7,2

-
11
4 , 4
= 6,8
BI TP
(1). Gi tn r- u sau: CH3-CHCl-CH(CH3)-CH2OH
A. 2-metyl-3-clobutanol-1 , B. 3-clo-2-metylbutanol-1 ,
C. 2-clo-3-metylbutanol-4 D. 2-clo-3-metylpentanol-1
(2 ). B tc chui P sau: A
Cl2
B (sn phm chnh)
KOH
D
d d KMnO4
E.
Bit rng E l mt glycol c ba nguyn t C . A, B, D, E Ln l- t l:
a. C3H8, CH3-CHCl-CH3, CH3 CH=CH2, CH3-CHOH-CH2OH
b. C3H8, CH3-CHCl-CH2Cl , CH3-CHOH-CH2OH CH3-C HOH-CH2OH
c. CH3-CHCl-CH3, CH3-CHCl-CH2Cl, CH3-CH=CH2, CH3-CHOH-CH2OH.
d. CH2=C=CH2, CH2Cl-CCl2-CH2Cl, CH3-CCl-CH2OH, CH2OH-CHOH-CH2OH
(3 ). So snh tnh axt( tnh linh ng ca H trong nhm OH ) ca H2O, CH3OH , CH3-CHOH-CH3.Sp xp theo th t tnh
axit tng dn:
A. H2O < CH3OH < CH2-CHOH-CH3 B. H2O < CH3-CHOH-CH3 < CH3OH
C. CH3-CHOH-CH3 < CH3OH < H2O D. CH3OH < CH2-CHOH-CH3 < H2O
(4 ). Trong cc r- u sau: 1,CH3OH ; 2, CH3-CHOH-CH3. 3, (CH3)3COH. 4, CH3-CHOH-CH2-CH3. R- u no khi b oxi
hacho ra mt xeton,r- u no kh b oxi ha.chokt qu theo th t sau:
A. ch c 3. B. ch c 2, 3 . C. ch c 2. D. ch c 3,4.
Cu 5: Anken X c cng thc phn t l C5H10. X khng c ng phn hnh hc. Khi cho X tc dng vi KMnO4
nhit thp thu c cht hu c Y c cng thc phn t l C5H12O2. Oxi ha nh Y bng CuO d thu c
cht hu c Z. Z khng c phn ng trng gng. Vy X l
A. 2-metyl buten-2. B. But-1-en. C. 2-metyl but-1-en. D. But-2-en.
(6 ). So snh nhit si ca ben zen , phenol, paracezol sp xp th t nhit si tng dn:
A. benzen < phenol< p-crezol C. p-crezol < ben zen <phenol.
B. phenol < benzen < p-crezol D. phenol <p-crezol < benzen
(7 ). So snh tan trong n- c ca benzen, phenol, etanol sp theo th t tan tng dn:
A. Ben zen < phenol < etanol. B. Benzen < etanol < phenol.
C. Benzen < etanol < etanol. D. Etanol < benzene < phenol.
(8 ). phn bit gia phenol v r- u benzylicC6H5-CH2OH , ta c th dng thuc th no trong cc
Thuc th sau: 1.Na ; 2.d d NaOH ; 3.n- c Br2.
A. ch c 1. B. Ch c 1,2. C. Ch c 2,3. D. Ch c 2.
(9 ). Mt r- u n chc A tc dng vi HBr cho hp cht B cha C, H v 58,4% Br . Nu un nng A vi H2SO4
c 170
0
C th thu - c 3 anken. Xc nh CTCT ca A, B v cc anken.
A.C2H5OH, C2H5Br v C2H4 B. C3H7OH, C3H7Br v C3H6.
C. C4H9OH, C4H9Br v buten-1, buten-2,cisbuten-2,trans-buten-2. D.Kt qu kh
(10). So snh tnh xt ca phenol, CH3COOH, v H2CO3 bit rng c cc P sau:
2CH3COOH + Na2CO3 2CH3COONa + CO2 +H2O ; CO2 +H2O +C6H5ONa --> NaHCO3 +
C6H5OH
Sp xp theo th t axit tng dn .
A. C6H5OH < CH3COOH < H2CO3. B. C6H5OH < H2CO3< CH3COOH
C. H2CO3 < C6H5OH < CH3COOH D. CH3COOH < C6H5OH < H2CO3
Cu 11: Trong dy ng ng ancol n chc no, khi mch cacbon tng, ni chung:
A. si tng, kh nng tan trong nc tng. B*. si tng, kh nng tan trong nc gim
C. si gim, kh nng tan trong nc tng. D. si gim, kh nng tan trongb nc gim
Cu 12: Cho s phn ng sau: A
+?
A1
+?
A2
+?
A3
+?
A4
+?
A5
+?
B
A1, A2, A3, A4, A5 tng ng l:
A. CH3COOH, CH3COONa, CH4, CH3Cl, CH3OH. B. CH3COOH,CH3COONa,CH4,HCHO, CH3OH.
C. C2H5COOH, C2H5COONa, C2H6, C2H5Cl, C2H5OH. D. p n A v B.
Cu 13: Cho cc phn ng sau:
(A) + H2O -> (B) + (K) (B) -> (D) + H2O D) + (E) -> (F) + HCl (F) + (C) -> (G) + (H)
(G) + (H2)-> (B) (G) + [O] + H2O -> (I) (I) + (J) -> TNG + H2O
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Cc Cht A, D, G c th l:
A. CH3COOC2H5 ; CH2=CH2 v CHC-CH 2OH B. CH3COOC4H9 ; CH2=CH-CH2-CH3 v CH3-CH=CH-CH2-OH
C. CH3COOC3H7 ; CH2=CH-CH3 v CH2=CH-CH 2-OH D. CH3COOC3H7; CH2=CH2 v CHC-CH 2OH
Cu 14.C cc dung dch sau: NaOH; nc vi trong; natri phenolat. Phn bit 3 dung dch dng
A. dung dch HCl B. kh CO2 C. kh SO3 D. qu tm.
Cu 15. linh ng ca nguyn t hiro trong phn t cc cht sau gim dn theo th t
A. phenol > ru benzylic > axit axetic > ru etylic B. ru benzylic > ru etylic > phenol > axit axetic
C. axit axetic > phenol > ru etylic > ru benzylic D. axit axetic > ru etylic > phenol > ru benzylic
Cu 16. Trong s cc dn xut ca benzen c cng thc phn t C8H10O, c bao nhiu ng phn (X) tha mn
(X) + NaOH -> khng phn ng (X)
O H
2
(Y)
xt
polime (Z)
A. 1 B. 2 C. 3 D. 4
Cu 17. Cho s sau :
nX
0
,t OH
+ nH2O


Hy cho bit X c th tc dng vi cht no sau: Na ; NaOH ; NaHCO3 ;brom(dd) ; CH3COOH (xt H2SO4 c) ?
A. Na ; NaOH ; NaHCO3 ;brom(dd); CH3COOH (xt H2SO4 c). B. Na ; NaOH ; dd Br2; CH3COOH (xt H2SO4 c)
C. Na ; NaOH ; brom(dd); D. Na, NaOH.
Cu 18. Cho s phn ng sau: p-Xilen X1 (C8H9Br) X2 (C8H9ONa) X3 (C8H10O).
a/ Hy cho bit, X1, X2, X3 v X4 cht no c kh nng phn ng th H trong vng benzen cao hn?
A. X1 B. X2 C. X3 D. p-Xilen
b/ Khi cho X3 tc dng vi dung dch Br2, hy cho bit sn phm thu c l:
A. 2,4-imetyl-1,3-ibromphenol B. 1,3-ibrom-2,4-imetyl phenol
C. 2,4-ibrom-3,6-imetylphenol D. 2,4-ibrom-3,5-imetyl phenol
Cu 19. Cht hu c X c cha vng benzen v c cng thc phn t l C8H10O. X tc dng vi Na nhng khng tc dng
vi NaOH. Oxi ha X bng CuO thu c cht hu c c kh nng tham gia phn ng trng gng. S CTCT ca X l
A. 3 B. 4 C. 5 D. 6
Cu 20. Thc hin phn ng chuyn ha theo s sau: benzen X1 X2 X3 X4 X5
Vi X1, X2, X3 , X4, X5 u c cha vng benzen. X4 c cng thc phn t l C6H3O7N3 v X5 c cng thc l C6H2O7N3Na.
X3 khng cha Nit. Vy X2, X3, X4 v X5 ln lt l:
A. phenol, natri phenolat ; axit picric v natri picrat. B. phenyl clorua, phenol ; axit picric v natri picrat.
C. natri phenolat ; phenol,; axit picric v natri picrat. D. phenyl clorua, natri phenolat; axit picric v natri picrat.
Cu 21. C cc dung dch sau : NaOH ; C6H5ONa ; Na2CO3 , NaHCO3 v Ba(OH)2 c cng nng mol/l v c cc gi tr
pH l pH1, pH2 ; pH3 , pH4 v pH5. Hy cho bit s sp xp no sau y ng?
A. pH1 < pH2 < pH3 < pH4<pH5 B. pH4 < pH2 < pH3 < pH1 < pH5
C. pH4 <pH3 < pH2 < pH1 < pH5 D.pH4<pH1<pH2 <pH3 <pH5
Cu 22: Pht biu no sau y ng:
(1) Phenol c tnh axt mnh hn etanol v nhn benzen ht electron ca nhm -OH bng hiu ng lin hp, (H linh ng)
trong khi nhm -C2H5 li y electron vo nhm -OH (H km linh dng).
(2) Phenol c tnh axit mnh hn etanol v c minh ha bng phn ng phenol tc dng vi dung dch NaOH cn
C2H5OH th khng phn ng.
(3) Tnh axit ca phenol yu hn H2CO3 v sc CO2 vo dd C6H5ONa ta s c C6H5OH kt ta .
(4) Phenol trong nc cho mi trng axit, qu tm ha .
A. (1), (2), (3) B. (2), (3), (4) C. (3), (1), (4) D. (1), (2), (3), (4)
Cu 23: Cho s bin ho C4H9OH (X)
o
dac SO H 170 /
4 2
A
+
2
ddBr
CH3-CHBr-CHBr-CH3 Vy X l
A. CH3-CH2-CH2-CH2-OH B. CH3-CH2-CH(OH)-CH3 C. (CH3)3COH D. C A v B u ng
Cu 24: Cho s bin ho
(1): X
2 4
H SO dac
M + N (2): M
+HBr
B (3): N + Na2O Q (4): B + Q
o
t p,
X + P
Nu X l hp cht hu c c 2 nguyn t C trong phn t th X c th l
A. C2H4O B. CHCH C. CH2=CH2 D. CH3-CH2-OH E. C2H6O
Cu 25: Cho s phn ng: Buten-1
HBr
X
2
/ H O NaOH
Y
2 4
180
o
H SO d
Z
Bit X, Y, Z u l cc hp cht hu c v l nhng sn phm chnh ca tng giai on. Cng thc ca X, Y, Z ln lt l:
A. CH3-CH(Br)-CH2-CH3, CH3-CH(OH)-CH2-CH3; CH3-CH=CH-CH3
B. Br-CH2-CH2-CH2-CH3; Ho-CH2-CH2-CH2-CH3; CH2=CH-CH2-CH3
C. CH3-CH(Br)-CH2-CH3; CH3-CH(OH)-CH2-CH3; CH2=CH-CH2-CH3
CH
3
OH
CH
2
n
HOCHOAHOC.COM Chuyn trang hc ha hc


D. CH3-CH(Br)-CH2-CH3; CH3-CH(OH)-CH2-CH3; CH3-CH2-CH(CH3)-O-CH(CH3)-CH2-CH3
Cu 26: ng phn no ca C4H9OH khi tch nc s cho ba olefin?
A. Ancol butylic B. Ancol isobutylic C. Ancol sec-butylic D. Ancol tert-butylic

Dng 1:Bi tp tm cng thc phn t ru phnol
Loi I:Bi tp t lun
Bi 1:t chy hon ton mt ru n chc A ri dn ton b sn phm chy i qua bnh ng nc vi trong d
thy khi lng bnh tng 14,2 gam ng thi sut hin 20gam kt ta .Xc nh cng thc phn t ca ru A
(C2H6O)
Bi 2 : t chy hon ton 9,2 gam mt ru no n chc A cn va 13,44 lt O2 (ktc)
Xc nh cng thc phn t ca A .(C2H6O)
Bi 3 : t chy hon ton 2,82 gam mt hp cht hu c A ch cha (C,H,O) .Cho ton b sn phm chy vo
bnh ng dung dch nc vi trong d thy khi lng bnh tng 9,54gam v c 18 gam kt ta.xc nh cng
thc phn t ca A bit t khi hi ca A so vi khng kh l 3,241 (C6H6O)
Bi 4:t chy hon ton 5,8 gam mt cht hu c A th thu c 2,65gam xa ;2,25gam H2O v 12,1 gam
CO2.Xc nh cng thc phn t A bit A c mt nguyn t Na . (C6H5ONa).
Bi 5: t chy hon ton 2,7gam mt hp cht hu c A phi dng va ht 4,76 lt O2 (ktc).Sn phm ch c
CO2 v H2O trong khi lng CO2 hn khi lng H2O l 5,9 gam .
a.Xc nh CNG thc n gin ca A (C7H8O)
b.Xc nh cng thc phn t ca A bit khi lng phn t ca A nh hn glucozo (C6H12O6)
c.Hy vit cng thc cu to c th c ca A bit A c vng thm (5 ng phn)
d.Trong cc ng phn cu c ng phn no c phn ng vi NaOH (3 ng phn)
Loi 2: Bi tp trc nghim
Bi 1: t chy hon ton 2,3 gam mt ru A thu c 3,3 g CO2 v 1,8 g H2O. Xc nh cng thc phn t A
a. C3H8O b. C3H8O2 c. C3H8O3 d. p n khc
Bi 2*: C mt ru n chc Y, khi t chy Y ta ch thu c CO2 v H2O vi s mol nh nhau v s mol oxi
tiu tn gp 4 ln s mol ca Y. Bit rng: Y lm mt mu dung dch brom v khi Y cng hp hiro th c ru
n chc. Cng thc cu to mch h ca Y l:
A. CH3-CH2-OH B. CH2=CH-CH2-CH2-OH
C. CH3-CH=CH-CH2-OH D. CH2=CH-CH2-OH
Bi 3: thi cao ng 2008: t chy hon ton mt ru (ancol) a chc, mch h X, thu c H2O v CO2
vi t l s mol tng ng l 3:2. Cng thc phn t ca X l
A. C3H8O2. B. C4H10O2. C C2H6O. D. C2H6O2
Bi 4: t chy hon ton hn hp 2 ru no n chc lin tip nhau trong dy ng ng ta thu c 4,5 gam
H2O v 3,36 lt CO2 (ktc).Xc nh cng thc phn t hai ru
A. CH4O v C3H8O C. B. C2H6O v C3H8O
B. C2H6O v CH4O D. C4H10O v C3H8O
Bi 5: Mt ru X mch h, khng lm mt mu nc brom. t chy a lt hi ru X th cn 2,5a lt oxi
cng iu kin. Cng thc cu to ca X l:
A. C2H4(OH)2 B. C3H6(OH)2
C. C3H7OH D. C2H5OH
Bi 6:Mt ru no n chc A c % oxi theo khi lng l 34,78% .Tm cng thc phn t ca ru A
A. C2H5OH B. C3H7OH C.CH3OH D.C4H9OH
Bi 7: thi i hc khi A 2008: Khi phn tch thnh phn mt ru (ancol) n chc X th thu c kt qu:
tng khi lng ca cacbon v hiro gp 3,625 ln khi lng oxi. S ng phn ru (ancol) ng vi cng thc
phn t ca X l
A. 3. B.4. C.2. D. 1.
Bi 8:t chy han ton 1 mol ancol no X cn 3,5 mol oxi. Xc nh CTCT ca X?
A. C2H4(OH)2B. C3H6(OH)2 C. C3H5(OH)2 D. C3H6(OH)3
CHUYN RU PHNOL
Dng 2:Phn ng ca ru vi kim loi kim
HOCHOAHOC.COM Chuyn trang hc ha hc


Loi I :Bi tp t lun
Bi 1:Cho 3,7 gam mt ru n chc tc dng vi Na d thu c 700 cm
3
H2 (o 27,3
0
C v 0,88 atm
).Xc nh cng thc tng qut v cng thc cu to ca ru (C4H9OH)
Bi 2: Cho m gam ru n chc X tc dng vi Na d th thu c 1,12 lt H2 .Nu t chy lng ru
trn th cn va 10,08 lt CO2 v to thnh 6,72 lt CO2 cc kh u o ktc
a.Tnh m (6 gam)
b.Tm cng thc phn t v cng thc cu to ca X (C3H8O v c 2 ru c cng thc ny )
Bi 3:Mt hp cht hu c A ch cha (C,H,O) .Khi ha hi 0,31gam A th thu c th tch bng th tch
ca 0,16 gam O2 trong cng iu kin nhit v p sut . Mt khc cng 0,31 gam A tc dng vi Na d
th thu c 112 ml H2 (ktc) .Tm cng thc phn t ca A (C2H6O2)
Bi 4: Khi t chy hon ton 6,44 gam mt r A th thu c 9,24 gam CO2 .Mt khc khi cho 0,1 mol
A tc dng hon ton vi Na thi thu c 3,36 lt kh (ktc) .
Tm cng thc phn t v gi tn A (C3H5(OH)3)
Bi 5 : X l ru no, Khi dt chy hon ton 1 mol X cn 3,5 mol O2 .Mt khc 1 mol X tc dng hon
ton vi Na thu c 1,5 mol O2 .Tm cng thc phn t ca X (C3H8O)
Bi 6 :Cho 0,05 mol mt ru A Tc dng vi Na d sinh ra 1,12 lt H2 (ktc).Nu cho 7,6 gam ru ny
tc dng vi K th thu c 2,24 lt kh H2 (ktc).
a.Xc nh cng thc phn t v vit cc cng thc cu to c th c ca ru A .S: C3H6(OH)2
b.Xc nh cng thc cu to ng ca A bit A c phn ng vi Cu(OH)2 cho dung dch xanh lam
Bi 7:Cho 11,95gam hn hp gm ancol etylic v etylenglicol tc dng hon ton vi Na d thu c
3,64 lt H2 ktc .Tnh phn trm khi lng mi cht trong hn hp
(0,125 mol C2H5OH v 0,1 mol C2H4(OH)2 0,1 mol )
Bi 8:Cho 15,2 gam hn hp glixerol v mt ru no n chc A tc dng vi Na thu c 4,48 lt kh H2
ktc .Nu cho hn hp trn tc dng vi Cu(OH)2 th ha tan c 4,9 gam Cu(OH)2
Xc nh cng thc phn t ca ru A (C3H7OH)
Bi 9: Cho 20,3 gam hn hp glixerol v mt ru no n chc A tc dng vi Na thu c 5,04 lt kh
H2 ktc .Mt khc 8,12 gam A hon tan va ht 1,96 gam Cu(OH)2
a. Xc nh cng thc phn t ca ru A (C4H9OH)
b.Tnh phn trm khi lng mi cht trong hn hp (54,68% v 45,32% )
Bi 10: Cho A v B l hai ru n chc, mch h .A l ru no, B l ru khng no trong phn t c
mt ni i .Cho hn hp X gm 3 gam A v 2,9 gam B tc dng vi Na d sinh ra 1,12 lt kh H2 ktc
Xc nh 2 ru A v B (C3H7OH v CH2=CH-CH-CH2-OH)
Bi 11: Cho 11 gam hn hp 2 ru no n chc tc dng hon ton vi Na d th thu c 3,36 lt kh
H2 ktc.
a.Xc nh cng thc phn t ca hai ru (C2H5OH v CH3OH)
b.Tnh phn trm khi lng mi cht trong hn hp ( 58,18% v 41,82%)
Bi 12: i hc Nng Nghip -1998
Cho 2,84 gam hn 2 ru no n chc k tip nhau trong dy ng ng tc dng vi mt lng Na va
th thu c 4,6 gam cht rn v V lt kh (ktc)
a.Tnh V (0,896 lt )
b.Xc nh cng thc phn t 2 ru trn (CH3OH v C2H5OH )
Bi 13:i hc Nng Nghip I-2001
Hn hp X gm 2 ru n chc k tip nhau trong dy ng ng .Chia X lm 2 phn bng nhau
-Phn 1:t chy hon ton, ri cho ton b sn phm chy vo bnh ng nc vi trong d th thu c
7 gam kt ta v bnh ng nc vi tng 5,24 gam .
-Phn 2: Tc dng vi Na d thu c V lt H2 ( 27,3
0
C v 1,25 atm )
a.Xc nh cng thc pt v phn trm mi ru trong hn hp (CH3OH :0,03 mol v C2H5OH : 0,02 mol)
Bi 14: t chy hon ton 23 gam mt ru A thu c 44 gam CO2 v 27 gam H2O
a.Cho 23 gam Na tc dng vi Na Tnh th tch kh thu c (ktc) :5,6 lt
HOCHOAHOC.COM Chuyn trang hc ha hc


b.Mt hn hp X gm A v B mt ng ng ca A c khi lng l 18,8 gam tc dng hon ton vi
Na to ra 5,6 lt kh ktc .Xc nh cng thc phn t ca A v B v tnh phn trm mi ru trong hn
hp (CH3OH :0,3 mol v C2H5OH : 0,2 mol)
Loi II:Bi tp trc nghim

Bi 1:Cho Na d tc dng hon ton vi 21,2 gam hn hp hai ru no n chc sinh ra 4,48 lt kh H2
ktc . Bit ru ny c s nguyn t gp i ru kia .Cng thc cu to 2 ru l
A .CH3OH v C2H5OH B.C2H5OH v C4H9OH
C.C3H7OH v C6H13OH C.C4H9OH v C8H17OH
Bi 2:Cho 1,24 gam hn hp 2 ru n chc tc dng vi Na va thy thot ra 336ml H2 ktc .Khi
lng mui thu c l
A.1,93 gam B.2,93 gam C.2,9 gam D.1,47 gam
Bi 3:Cho 4,6 gam hn hp gm Ru mtylic v prpylic (t l s mol l 1:1) tc dng hon ton vi Na
thu c V lt kh .Gi tri ca V l
A. 2,24 lt B. 1,12 lt C. 22,4 lt D. 11,2 lt
Bi 4: Cho 2,84 gam mt hn hp hai ru no n chc l ng ng lin tip nhau tc dng vi mt
lng Na va , to ra 4,6 gam cht rn v V lt kh H2 ktc. Xc nh cng thc phn t ca hai ru
trn.
A. CH3OH v C2H5OH B. C2H5OH v C4H9OH
C. C3H5OH v C4H9OH D. Cc cu A, B, C u sai
Bi 5: Cho natri kim loi tc dng vi 1,06gam hn hp hai ru ng ng lin tip ca ru metylic
thy thot ra 224ml hiro (o ktc). Xc nh cng thc phn t mi ru.
A. CH3OH v C2H5OH B. C2H5OH v C3H7OH
C. C4H9OH v C5H11OH D. Kt qu khc
Bi 6: Cho 11 gam hn hp 2 ru no n chc k tip nhau trong dy ng ng, tc dng ht vi Na th
thu c 3,36 lt kh H2 (ktc). Cng thc cu to 2 ru l:
A. CH3OH v C2H5OH B. CH3OH v C3H7OH
C. C2H5OH v C3H7OH D. C4H7OH v C5H11OH
Bi 7: Cho 9,2 gam h
2
2 ancol propylic v ancol n chc B tc dng vi Na d, sau phn ng thu c
2,24 lt H2 (ktc). B l ancol no di y?
A.CH3OH B. C2H5OH C. C3H5OH D. p n khc
Bi 8: Cho 15,2 gam hn hp 2 ancol n chc tc dng vi Na va , sau phn ng thu c 21,8 gam
cht rn v bao nhiu lt hiro (ktc)?
A. 1,12 B. 2,24 C. 3,36 D. 4,48
Bi 9: Cho 18,8 gam hn hp 2 ancol no, n chc, mch h, k tip nhau trong dy ng ng tc dng
vi Na d, to ra 5,6 lt kh hiro (ktc). Cng thc phn t ca 2 ancol l
A.C2H5OH v C3H7OH B. C3H7OH v C4H9OH
C. CH3OH v C2H5OH D. p n khc
Bi 10: thi cao ng 2008 :t chy hon ton hn hp M gm hai ru (ancol) X v Y l ng ng
k tip ca nhau, thu c 0,3 mol CO2 v 0,425 mol H2O. Mt khc, cho 0,25 mol hn hp M tc dng
vi Na (d), thu c cha n 0,15 mol H2. Cng thc phn t ca X, Y l:
A. C2H6O, CH4O. B. C3H6O, C4H8O. C. C2H6O, C3H8O. D. C2H6O2, C3H8O2
Bai11: Cho 7,6g mt ancol no 2 chc Xtc dng vi Na d h thot ra 1,12 lt H2(0
0
C, 2atm). X nh CTPT ca X?
A. C2H4(OH)2 B. C3H6(OH)2 C. C3H5(OH)2 D. C3H6(OH)3

CHUYN RU PHNOL
Dng 3:Phn ng tch nc ca ru v hp nc ca anken
Bi 1: Hydrat ha 14,8 gam mt ru th thu c 11,2 gam anken .Cng thc tng qut ca ru l
HOCHOAHOC.COM Chuyn trang hc ha hc


A.C2H5OH B.C3H7OH C.CH3OH D.C4H9OH
Bi 2: Thc hin phn ng tch nc vi mt ru n chc A iu kin thch hp sau khi phn ng xy ra hon
ton c cht hu c B (c t khi hi so vi A bng 1,6. Xc nh cng thc phn t ru A
A. C2H5OH B. C4H9OH C. CH3OH D. C3H7OH
Bi 3: un nng m1 gam ancol no, n chc A vi H2SO4 c nhit thch hp thu c m2 gam cht hu c
B. T khi hi ca B so vi A bng 1,4375. Hiu sut ca phn ng t 100%. Cng thc phn t ca A l
A.CH3OH B.C2H5OH C.C3H7OH D.C4H9OH
Bi 4: Hydrat ha 6 gam mt ru th thu c 1.68 lt anken vi hiu sut phn ng l 75% .Cng thc tng
qut ca ru l
A.C2H5OH B.C3H7OH C.CH3OH D.C4H9OH
Bi 5:Hydrat ha mt ru A ch thu c mt anken duy nht c t khi so vi Nit l 2 .Tn gi ca A
A.Etanol B.Metanol C.Propan -1-ol D.Butan-1-ol
Bi 6:Ru no n chc X mch h c t khi vi H2 l 37 .Cho X tc dng vi H2SO4 c nung nng 180
0
C
.Thu dc 1 anken mch thng duy nht .X l
A.Etanol B.2-metyl propanol-2 C.Propan -1-ol D.Butan-1-ol
Bi 7:un nng V ml ru etylic 95
0
vi H2SO4 c 180
0
C thu c 3,36 lt etilen ktc. Bit hiu sut phn
ng l 60% v khi lng ring ca ru l 0,8 gam/ml .Gi tr ca V l
A.10,18 ml B.15,13 ml C.8,19 ml D.12 ml
Bi 8:Chia m gam hn hp 2 ru thnh 2 phn bng nhau
-Phn 1:t chy hon ton thu c 2,24 lt CO2 ktc
-Phn 2 : Hydrat ha th thu c hn hp 2 anken .Nu t chy hon ton 2 anken th thu c bao nhiu
gam nc
A.0,36 gam B.0,9 gam C.0,54 gam D.1,8 gam
Bi 9 :Tch nc hon ton mt hn hp ru X ta thu c hn hp Y gm cc anken .Nu t chy X th thu
c 1,76 gam CO2, cn khi t chy Y th khi lng CO2 v H2O thu c l bao nhiu
A.2,94 gam B.2,48 gam C.1,76 gam D.2,76 gam
Bi 10: thi i hc khi B 2008: un nng mt ru (ancol) n chc X vi dung dch H2SO4 c trong iu
kin nhit thch hp sinh ra cht hu c Y, t khi hi ca X so vi Y l 1,6428. Cng thc phn t ca Y l
A. C3H8O. B. C2H6O. C. CH4O. D. C4H8O.
Bi 11: thi i hc khi B 2008 : un nng hn hp gm hai ru (ancol) n chc, mch h, k tip nhau
trong dy ng ng vi H2SO4 c 140oC. Sau khi cc phn ng kt thc, thu c 6 gam hn hp gm ba ete
v 1,8 gam nc. Cng thc phn t ca hai ru trn l
A. CH3OH v C2H5OH. B. C2H5OH v C3H7OH.
C. C3H5OH v C4H7OH. D. C3H7OH v C4H9OH.
Bi 12: thi cao ng 2008: Khi un nng hn hp ru (ancol) gm CH3OH v C2H5OH (xc tc H2SO4
c, 140oC) th s ete thu c ti a l
A. 1. B.3. C. 4. D. 2.
Bi 13: thi i hc khi A 2008 : Khi tch nc t ru (ancol) 3-metylbutanol-2
(hay 3-metylbutan-2-ol), sn phm chnh thu c l
A. 2-metylbuten-2 (hay 2-metylbut-2-en). B. 3-metylbuten-1 (hay 3-metylbut-1-en).
C. 3-metylbuten-2 (hay 3-metylbut-2-en). D. 2-metylbuten-3 (hay 2-metylbut-3-en).