SHAKUNTALAM

MITTAL SIR

III A 172, NEHRU NAGAR, GHAZIABAD, U.P.-201001, PH.:- 9868502091, 9811212090

TEST / CLASS 12th & 12th Passed

DATE : 23rd Apr 2013 Topic : G.O.C-3 Time : 30 Minutes
Name of the Candidate : ___________________________

Maximum Marks : 75
Roll No. ____________________

SECTION I (Total Marks : 75) Single Correct Answer Type(+3/-1) This section contains 25 multiple choice questions. Each question has 4 choices (a), (b), (c) and (d) for its answer, out of which ONLY ONE is correct. 1. Relation between COOH OH CH2OH CH3 is (a) Enantiomer 2.
N H H

CH3 & HOCH2 OH COOH (c) Epimer (d) Same

(b) Diasteriomer
NH
2

&

N H

(I) (II) The most acidic among these (a) i (b) ii 3. Most acidic among these OH OH (a) NO2 (b) Cl

(III) (c) iii (d) i = iii

COOH (c) (d)

COOH

Cl

4. Which will give CO2 on heating (a) Malic acid (b) Fumaric acid

(c) Malonic acid

(d) Succinic acid

SHAKUNTALAM 2013

PH. NO:- 9868502091, 9811212090 What to study is more important

12th & Drop./GOC-3

SHAKUNTALAM 5. COOH + COOH

O C

MITTAL SIR Product

COOH

P , P is

(a)
C O

(b)
COOH

(c)
C O

C=O
O

(d)
COOH

6. Among CH CH, CH3CH2OH, H2O & CH2 = CH2 which has lowest pKa (a) CH CH (b) CH3CH2OH (c) H2O (d) CH2 = CH2 7. Which has highest boiling point (a) CH3CH2CH2CH2CH3 (c) CH3COOH (b) CH3CH2 O CH2 CH3 (d) CH2 CH CH2 OH OH OH CH3 C2H5 (d) All have same value H H

8. Which has highest boiling point CH3 CH3 H H H H H (a) (b) (c) CH3 CH3 H CH3 H H CH3

9. The bad smelling substance formed by the action of alcoholic caustic potash on chloroform and aniline is (a) nitrobenzene (b) phenyl isocyanide (c) phenyl cyanide (d) phenyl isocynate 10. In the following raction
+ OH N
CH3 CH3

The organic product X is (a) 11. CH3 (CH3CO)2O NH2 What is X ?

CH3 CH3 Br NH2 CH3 CH3 COCH3 NH2

(b)
N(CH3)2

(c)
N(CH3)2

(d)

Br2/CH3COOH

H+/H2O X

(a)

(b)
Br NH2

(c)

(d)
COCH3 NH2

12. In HS, I, RNH2, NH3 order of proton accepting tendency will be

(a) I > NH3 > RNH2 > HS (c) RNH2 > NH3 > HS > I

(b) NH3 > RNH2 > HS > I (d) HS > RNH2 > NH3 > I

13. Oxidation of aniline with H2CrO4 gives

(a) phenylhydroxynamine (b) p-benzoquinone (c) nitrosobenzene (d) nitrobenzene

SHAKUNTALAM 2013

PH. NO:- 9868502091, 9811212090 What to study is more important

12th & Drop./GOC-3

SHAKUNTALAM 14. CH3CH2CONH2

(a) Pt/H2
X

MITTAL SIR
CH3CH2CH2NH2, (b) Ni/H2 X is (c) LiAlH4 (c) 3 amine (d) Zn (d) quaternary salt

15. C3H9N cannot represent (a) 1 amine (b) 2 amine

(a) Ammonium sulphate (c) Urea (a) CH3OH (b) CH3NNO H

16. Regular use of the following fertilizers increasing the acidity of soil?
(b) Potassium nitrate (d) Superphosphate of lime. (c) CH3NO2 (d) CH2

17. When methyl amine is treated with HNO2 the main product formed is : 18. Which of the following has lowest boiling point
(a) CH3CH2CH2NH2 (b) CH3 CH CH3
NH2

CH3 (c) CH3 C CH3

NH2

CH3 (d) CH3 N CH3

19.

OH
Zn canc HNO3 conc HNO3 (NH4)2S NaNO2 + HCl H2O

A
duist H2SO4

B
H2SO4

Compound F is : (a) OH
OH

(b) OH
OH

(c) OH
OH

(d) NO2
OH

20.
A

NaNO2,HCl

HBF4

NO2 + BF3 F NO2

B
NH2

Compound A is : (a)
NO2

NO2

(b)
NO2

(c)
OH

(d)

21. Which confirmer of ethylene glycol has lowest enthalpy of combustion

(a) Fully eclipsed (b) Gauche (c) Anti (d) Partially eclipsed

22. Which of the following compound will dissolve in an alkali solution after it has
undergone reaction with Hinsberg reagent? (a) (C2H5)2NH (b) CH3 N C6H5
CH3 (c) CH3NH2 (d) C6H5NHC6H5

23. A positive carbylamine test is given by

(a) N, N-dimethylaniline (c) N-methyl-o-methylaniline (b) p-hydroxyazobenzene (d) p-methylbenzylamine (c) m-NO2C6H4NH2 (d) C6H5CH2NH2

24. Among the following, the strongest base is

(a) C6H5NH2 (b) p-NO2C6H4NH2

25. The correct sequence for the complex formation of aliphatic amines with B(CH3)3 is
(a) (CH3)2NH > CH3NH2 > NH3 > (CH3)3N (c) (CH3)2NH > NH3 > CH3NH2 > (CH3)3N (b) (CH3)3N > (CH3)2NH > CH3NH2 > NH3 (d) CH3NH2 > (CH3)2NH > (CH3)3N > NH3.

SHAKUNTALAM 2013

PH. NO:- 9868502091, 9811212090 What to study is more important

12th & Drop./GOC-3

SHAKUNTALAM

MITTAL SIR

III A 172, NEHRU NAGAR, GHAZIABAD, U.P.-201001, PH.:- 9868502091, 9811212090

ANSWER SHEET
SECTION I Straight Objective type (+3/-1) 1. 2. 3. 4. 5. a a a a a b b b b b c c c c c d d d d d 6. 7. 8. 9. 10. a a a a a b b b b b c c c c c d d d d d SECTION - II Multiple Choice type (+4/0) 11. 12. 13. 14. a a a a b b b b c c c c d d d d

SECTION II Reasoning type (+4/-1) 15. 16. 17. 18. a a a a b b b b c c c c d d d d

SECTION - II Comprehension type (+4/0) 19. a 20. a b b c c d d

SHAKUNTALAM 2013

PH. NO:- 9868502091, 9811212090 What to study is more important

12th & Drop./GOC-3

SHAKUNTALAM 5

MITTAL SIR

SHAKUNTALAM 2012 2/stoic.&atomic/set-A

PH. NO:- 9868502091, 9811212090 What to study is more important

11th /Test-