Chem 1332 Practice Final 2009

View Attempt https://scholar.uh.edu/webct/urw/lc261766704.tp261766721/ViewStudent...
View Attempt 1 of 2
Title: Practice Final
Started: May 4, 2009 7:24 PM
Submitted: May 4, 2009 7:24 PM
Time spent: 00:00:27
Total score: 0/34 = 0% Total score adjusted by 0.0 Maximum possible score: 34
1.
What is the solubility in moles/liter for zinc hydroxide at 25 o C given a Ksp value of 2.0 x
10-17 . Write using scientific notation and use 1 or 2 decimal places (even though this is strictly
incorrect!)
Student Response Value Correct Answer

Equals 1.71e-6 (100%)
1. not answered 0%
Equals 1.7e-6 (100%)
General Ksp = 4S3

Feedback:
Score: 0/1
2.
When 7.5 x 10-6 g of KOH is dissolved in 1.00 L of 1.0 x 10-3 M Cu(NO3)2, a precipitate of
Cu(OH)2 is formed. True or False? (Ksp of Cu(OH)2 is 2.2 x 10-20 )
Student
Value Correct Answer Feedback
Response
1. True 100%
2. False 0%
Score: 0/1
3.
Which of the following compounds will not have a different solubility with a change in pH?
Student
Response
1. AgNO3 100%
2. Ca3 (AsO4 )2 0%
3. SrCO3 0%
4. CuF 0%
5. CuS 0%
1 of 13 5/4/2009 8:03 PM
Score: 0/1
4.
Answer this question without using numbers from the book (or anywhere else!)
DS for the following reaction is negative. True or false?
C3H8(g) => C2 H6(g) + CH4 (g)
Student
Response
1. True 0%
2. False 100%
Score: 0/1
5.
Given the values of DGfo given below in kJ/mol, calculate the value of DGo in kJ for the
combustion of ammonia to forms nitrogen dioxide and water vapor. (Use the lowest possible
integers when balancing the equation).
DGfo (NO2) = 55.8
DGfo (H2 O(g)) = -225.7
DGfo (NH3 ) = -17.5

Answer not answered 0% -1,061
Score: 0/1
6.
The value of DGo for the reaction,

N2(g) + 3 H2 (g) <=> 2 NH3(g) is -32.90 kJ at 298 K.
Calculate the value of DG in kJ at 298 K if the partial pressures of N2 , H2 and NH3 are 4.500,
4.375, and 1.230 atm respectively.

Answer not answered 0% -46.6
Score: 0/1
2 of 13 5/4/2009 8:03 PM
7.
Balance the following equation in acidic solution:
Zn(s) + NO2-(aq) => Zn2+(aq) + N2(g)
What is the coefficient of water?
Student
Response
1. 1 0%
2. 2 0%
3. 4 100%
4. 6 0%
5. 8 0%
Score: 0/1
8.
Calculate the pH of a solution that results from mixing 31.7 mL of 0.148 M HCN(aq) with 22.2
mL of 0.189 M NaCN.
The Ka value for HCN is 4.9 x 10-10 .

Answer not answered 0% 9.26
Score: 0/1
9.
Calculate the pH during the titration of 20.00 mL of 0.1000 M CH3CH2 CH2COOH(aq) with
0.1000 M NaOH(aq) after 19.82 mL of the base have been added.
Ka of butanoic acid = 1.54 x 10-5 .

Score: 0/1
10.
Which indicator would be the best to use for a titration between 0.10 M HCl with 0.10 M
NaOH? You will probably need to consult the appropriate table in the book.
3 of 13 5/4/2009 8:03 PM
Student Correct
Value Feedback
Response Answer
1. phenolphthalein, 0%
color change at
pH 8-10
2. bromothymol 100%
blue, color
change at pH
6-8
3. methyl red, 0%
color change at
pH 3-5
4. alizarin yellow 0%
R, color change
at pH 10-12
5. thymol blue, 0%
color change at
pH 2-4
Score: 0/1
11.
What is the heat change in J associated with 179.1 g of ice at -5.00 ° C changing to liquid
water at +5.00 °C?
c(H2 O) (liq) = 4.184 J/(g.K)
c(H2 O) (s) = 2.09 J/ (g.K)
DHfus(H2 O) = 6.02 kJ/mol
Enter your answer in scientific format with TWO DECIMAL PLACES (that is, 3 significant figures
total): 1.23X104 =1.23E4. Do not include units. You will not get credit for the question if
you do not use the correct format!!!

Answer not answered 0% 6.54E4 (6.54 × 104)
Score: 0/1
12.
Which type of intermolecular force ("interparticle force") is the most important in CSe2 (l)?
Student
Response
4 of 13 5/4/2009 8:03 PM
1. London 100%
Dispersion
2. Dipole- 0%
dipole
forces
3. Ion-dipole 0%
forces
4. Hydrogen 0%
bonds
5. Ionic 0%
bonds
Score: 0/1
13.
Calculate the freezing point (in degrees C) of a solution made by dissolving 4.24 g of glucose
in 74.8 g of water. The Kfp of the solvent is 1.86 K/m and the normal freezing point is 273 K.

Answer not answered 0% -0.59
Score: 0/1
14.
Assuming complete dissociation, calculate the boiling point (in degrees C) of a solution made
by dissolving 2.43 g of potassium chloride in 92.2 g of water. The Kfp of the solvent is 0.512
K/m and the normal boiling point is 373 K.

Score: 0/1
15.
A 3.39 mass % aqueous solution of ethylene glycol (HOCH2 CH2OH) has a density of 1.03
g/mL. Calculate the molality of the solution.

Score: 0/1
5 of 13 5/4/2009 8:03 PM
16.
When 1.25 g of an unknown non-electrolyte is dissolved in 50.0 g of cyclohexane, the freezing
point decreased by 5.45 degrees C. If the Kfp of the solvent is 20.1 K/m, calculate the molar
mass of the unknown solute.

Answer not answered 0% 92
Score: 0/1
17.
What is the strongest form of intermolecular force between solute and solvent in a solution of
KCl(s) in CH3 OH(l)?
Student
Response
1. ion-dipole 100%
2. dipole- 0%
dipole
3. hydrogen 0%
bonding
4. dipole- 0%
induced
dipole
5. dispersion 0%
Score: 0/1
18.
For the reaction, 4 A(g) + 3 B(g) => 2 C(g), the following data were obtained at constant
temperature.
Experiment Initial [A], mol/L Initial [B], mol/L Initial Rate, M/min
1 0.200 0.150 5.00
2 0.400 0.150 20.0
3 0.200 0.300 20.0
4 0.400 0.300 80.0
Determine the value of k for the reaction. Give answer to 3 significant figures.

Equals 5556 (100%)
1. not answered 0% Equals 5560 (100%)
Equals 5555.6 (100%)
6 of 13 5/4/2009 8:03 PM
Equals 5.56E3 (100%)

Equals 5.55E3 (100%)
Score: 0/1
19.
A first order reaction has a rate constant of 0.558 sec-1 at 38.9 o C. If the activation energy is
64 kJ, calculate the temperature in o C at which the rate constant is
0.504 sec-1.

Score: 0/1
20.
In a first order decomposition in which the rate constant is 0.0528 sec-1 , how long will it take
(in minutes) until 0.471 mol/L of the compound is left, if there was 0.830 mol/L at the start?
(give answer to 3 sig figs using E notation)?

Score: 0/1
21.
Consider the reaction with the rate law, Rate = k[BrO3 -][Br -][H+]2
By what factor does the rate change if the concentration of BrO3- is quadrupled and that of Br-
is is decreased by a factor of 2? Just put in the number as a whole number or fraction.

Equals 2 (100%)
1. not answered 0%
Equals 2/1 (100%)
Score: 0/1
22.
The proposed mechanism for a reaction is
1. ClO-(aq) + H2 O(l) => HClO(aq) + OH-(aq) SLOW

2. I-(aq) + HClO(aq) => HIO(aq) + Cl-(aq) FAST
7 of 13 5/4/2009 8:03 PM
3. OH-(aq) + HIO(aq) => H2O(l) + IO-(aq) FAST
Which of the following would be a rate law for the reaction?
Student Correct
Value Feedback
Response Answer
1. rate = 100%
k[ClO-][H2 O]
2. rate = 0%
k[I-][HClO]
3. rate = 0%
k[OH-][HIO]
4. rate = k[ClO-] 0%
[H2 O][I-]
5. rate = k[ClO-] 0%
[H2 O][I-][OH-]
Score: 0/1
23.
An atom of 186 Ta has a mass of 185.958540 amu. Calculate the binding energy per MOLE in
kJ. Use the values:
mass of 1 H atom = 1.007825 amu

mass of a neutron = 1.008665 amu
c = 2.99792 x 108 m/s
Give your answer to 3 significant figures and USE E notation. No charity points will be
awarded.......

Equals 1.43E11 (100%)
1. not answered 0%
Equals 1.44E11 (100%)
Score: 0/1
24.
Pa-233 undergoes beta decay. What is the product nucleus? Enter your answer using the same
format, i.e, symbol-mass number

1. not answered 0% Equals U-233 (100%)
Score: 0/1
8 of 13 5/4/2009 8:03 PM
25.
F-21 is radioactive. Which mode of decay would be expected for this nucleus?
Student Correct
Value Feedback
Response Answer
1. Alpha decay 0%
2. Beta decay 100%
3. Positron 0%
decay/electron
capture
4. Neutron decay 0%
5. Proton decay 0%
Score: 0/1
26.
Consider the reaction Br2 (g) <=> 2 Br(g), which is endothermic as written. What would be the
effect on the equilibrium position of decreasing the volume of the reaction container?
Student
Response
1. Reaction 0%
would go
to the
right,
making
more
"products"
2. Reaction 100%
would go
to the left,
making
more
"reactants"
3. Reaction 0%
would go
to the left,
making
more
"products"
4. Reaction 0%
would go
to the
right,
making
9 of 13 5/4/2009 8:03 PM
more
"reactants"
5. No change 0%
on the
equilibrium
position
Score: 0/1
27.
Consider the gas-phase reaction, N2 (g) + 3 H2 (g) <=> 2 NH3 (g), for which Kp = 43 at 400 K.
If the mixture is analyzed and found to contain 2.0 bar of N2 , 2.0 bar of H2 and 26.0 bar of
NH3 , describe the situation:
Student
Response
1. Q < K and 0%
more
reactants
will be
made to
reach
equilibrium.
2. Q < K and 100%
more
products
will be
made to
reach
equilibrium.
3. Q > K and 0%
more
reactants
will be
made to
reach
equilibrium.
4. Q > K and 0%
more
products
will be
made to
reach
equilibrium.
5. Within 1 0%
decimal
place, Q =
K and the
reaction is
at
10 of 13 5/4/2009 8:03 PM
equilibrium
Score: 0/1
28.
What is the value of the equilibrium constant at 25 o C for the reaction between the pair:
Cr(s) and Fe2+(aq) to give Fe(s) and Cr3+(aq)
Use the reduction potential values for Cr3+(aq) of -0.74 V and for Fe2+(aq) of -0.44 V
Give your answer using E-notation with NO decimal places

(e.g., 2 x 10-2 would be 2E-2; and
2.12 x 10-2 would also be 2E-2.).
Do NOT include spaces, units, punctuation or anything else silly!

1. not answered 0% Equals 3E30 (100%)
Score: 0/1
29.
What product(s) forms at the anode in the electrolysis of an aqueous solution of Na3 PO4 ?
Student
Response
1. O2 and H+ 100%
2. H2 and OH- 0%
3. Na 0%
4. Phosphorus 0%
Score: 0/1
30.
How many grams of sodium may be formed by the passage of 38.4 amps for 3.36 hours
through an electrolytic cell that contains a molten sodium salt.

Score: 0/1
11 of 13 5/4/2009 8:03 PM
31.
A voltaic cell consists of an Al/Al3+ half-cell and a Cd/Cd2+ half-cell. Calculate [Cd2+] when
[Al3+] = 0.74572 M and Ecell = 1.226.
Use reduction potential values of Al3+ = -1.66 V and for Cd2+ = -0.40 V.
Use scientific (E) notation with 2 numbers after the decimal point.

Answer not answered 0% 5.82E-2 (5.82 × 10-2 )
Score: 0/1
32.
Classify CH3 COOH
Student
Response
1. strong 0%
acid
2. weak 100%
acid
3. strong 0%
base
4. weak 0%
base
Score: 0/1
33.
What is the pH of 0.788 M quinolinium iodide, C9 H7NHI? The Kb of quinoline, C9 H7N is 6.3 x
10-10 .

Score: 0/1
34.
Hydrofluoric acid has a Ka of 6.8 x 10-4. Calculate the pH of a 0.349 M solution of HF? Do not
worry about using the quadratic.
12 of 13 5/4/2009 8:03 PM

Score: 0/1
Done
13 of 13 5/4/2009 8:03 PM

Chem 1332 Practice Final 2009

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View Attempt https://scholar.uh.edu/webct/urw/lc261766704.tp261766721/ViewStudent...

Student Response Value Correct Answer

General Ksp = 4S3

DS for the following reaction is negative. True or false?

C3H8(g) => C2 H6(g) + CH4 (g)

Student Response Value Correct Answer

The value of DGo for the reaction,

Student Response Value Correct Answer

Zn(s) + NO2-(aq) => Zn2+(aq) + N2(g)

What is the coefficient of water?

Student Response Value Correct Answer

Student Response Value Correct Answer

c(H2 O) (liq) = 4.184 J/(g.K)

c(H2 O) (s) = 2.09 J/ (g.K)

DHfus(H2 O) = 6.02 kJ/mol

Student Response Value Correct Answer

Student Response Value Correct Answer

Student Response Value Correct Answer

Student Response Value Correct Answer

Student Response Value Correct Answer

Student Response Value Correct Answer

Equals 5.56E3 (100%)

Student Response Value Correct Answer

Student Response Value Correct Answer

Student Response Value Correct Answer

1. ClO-(aq) + H2 O(l) => HClO(aq) + OH-(aq) SLOW

3. OH-(aq) + HIO(aq) => H2O(l) + IO-(aq) FAST

Which of the following would be a rate law for the reaction?

mass of 1 H atom = 1.007825 amu

Student Response Value Correct Answer

Student Response Value Correct Answer

Cr(s) and Fe2+(aq) to give Fe(s) and Cr3+(aq)

Give your answer using E-notation with NO decimal places

Student Response Value Correct Answer

Student Response Value Correct Answer

Student Response Value Correct Answer

Student Response Value Correct Answer

Student Response Value Correct Answer

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