1

1. a. 1. Al 3. FeS 4. Fe + HNO3 + O2 + H2SO4 c + H2O + H 2O

Bi tp ca Lu 1 Tun Ngha
(chienbinhpro95_1st@yahoo.com.vn)

Cn bng phn ng oxi ho - kh:

VD1. Cn bng cc phn ng sau bng phng php thng bng electron.
Al(NO3)3 +

N2O + H2O + SO2 + H 2O

2. FeSO4 + KMnO4 + H2SO4 Fe2(SO4)3 + K2SO4 + MnSO4 + H2O

to Fe2O3

Fe2(SO4)3 + H2S
H3 AsO4

5. As2S3 + HNO3 7. C6H5NO2 + Fe

+ H2SO4 + NO + Fe3O4 + H 2O

6. H2O2 + KMnO4 + H2SO4 O2 + K2SO4 + MnSO4 + H2O

C6H5NH2

8. K2SO3 + KMnO4 + KHSO4 K2SO4 + MnSO4 + H2O 9. C12H22O11 + H2SO4 c b. 1. CuFeS2 + Fe2(SO4)3+ O2 + H2O to CuSO4 + FeSO4 + H2SO4 2. CrI3 3. P 4. Al 6. FeS2 7. Cu2FeS2 9. KNO2 10.K2Cr2O7 C. + KOH + NH4ClO4 + NaNO3 + NaOH + Cl2
K2CrO4 + KIO4
H3PO4
to

to CO2
to

+ SO2

10. C6H12O6+ KMnO4+ H2SO4 CO2

+ K2SO4 + MnSO4 + H2O

+ MnCl2 + HCl + Cl2 + H 2O + H2O

+ N2

NaAlO2 + NH3
to P4

5. Ca3(PO4)2 + SiO2 + C + HNO3 + HCl + O2 + NaOH + H2SO4

+ CaSiO3+ CO + H2SO4 + NO + H2O + Fe2O3 + SO2 + HCOONa + NaI + H2O + K2SO4 + H2O

to FeCl3
to CuO

8. C2H5OH + I2 + KI

CH3I
I2 + NO

+ FeSO4+ H2SO4 + NO3- M3+

Cr2(SO4)3+ K2SO4 + Fe2(SO4)3+ H2O

1. FexOy + HCl

FeCl2y/x

+ H2O

2. M2Ox + H+ 3. H2S + SO2 4. H2O2 + Mn2+ 5. MxOy 6. FexOy 8. Fe3O4 9. HxIyOz 10. FexOy D. 2. 3. 4.

+ NO + H2O

+ OH- S2O32- + H2O + NH3 MnO2 + NH4+

+ HNO3

M(NO3)n + NO + H2O M(NO3)m + NO + CO2 + H2O Fe(NO3)3 + NxOy + H2O +S + H2O Fe(NO3)3 + NnOm + H2O

+ H2SO4 c to Fe2(SO4)3 + SO2 + H2O

7. M2(CO3)n + HNO3 + HNO3 + H 2S + HNO3

I2

1. n-C4H10 + KMnO4 + H2SO4 to CH3COOH + K2SO4 + MnSO4 + H2O C2H4 + KMnO4 + H2O C2H2 + KMnO4 CnH2n + KMnO4 + H2O
C2H4(OH)2 + KOH + MnO2
(COOK)2

+ KOH + MnO2 + H2O + MnO2

CnH2n(OH)2+ KOH

2
5. 6. 7. 8. 9. 10. 2. CnH2n-2+ KMnO4 + H2O C6H5C2H5 + KMnO4 CxHyOH + CuO

Bi tp ca Lu 2 Tun Ngha
(chienbinhpro95_1st@yahoo.com.vn)

CnH2n-2O4

+ KOH + MnO2

to C6H5COOK + K2CO3 + MnO2 + KOH + H2O

to Cx-1Hy-2CHO + Cu + H2O

CH3CH(OH)CH3 + CuO to CH3COCH3 + Cu + H2O CxHy(CHO)n+ AgNO3+ NH3 + H2O to CxHy(COONH4)n + Ag + NH4NO3 CxHyNO2 + Zn + HCl
to CxHyNH3Cl + ZnCl2

Hon thnh phn ng oxi ho - kh:

Bi 2. Hon thnh cc phng trnh phn ng sau. A. 1. F2 + H2O 2. HF + SiO2 3. Cl2 + H2O 4. MnO2 + dd HCl 5. Cl2 + dd NaOH 6. Fe + Cl2 7. KClO3 + C 8. Cl2 + dd NaBr to dp 9. dd NaCl 10 . Br + dd KOH to 2 11. F2 + dd NaCl 12. Cl2 + dd Ca(OH)2 13. NaF + dd HCl 14. Fe + I2 to dkt 15. Br2 + dd KOH 16. MnO2 + CaCl2 + dd H2SO4 17. FeSO4 + dd Br2 18. Fe3O4 + Cl2 + H2SO4 long 19. FexOy + HCl 20. FeCl2 + KMnO4 + H2SO4 21. H2S + dd Cl2 22. Cu + H2SO4 c to 23. Fe + H2SO4 c to 24. FeS2 + O2 to 25. CuS2 + H2SO4 26. FeS2 + H2SO4 c to 27. dd H2S + O2 khng kh 28. H2S + dd CuSO4 to 29. H2S + O2 30. CuS + O2 to dkt 31. dd H2S + O2 32. Fe3O4 + H2SO4 long 33. Fe3O4 + H2SO4 c 34. FexOy + H2SO4 long 35. FexOy + H2SO4 c to 36. FeS2 + H2SO4 long 37. O3 + dd KI 38. KNO2 + KMnO4 + H2SO4 39. S + dd NaOH 40. H2C2O4+ KMnO4 + H2SO4 to dkt 41. KNO3 + C + S 42. C12H22O11 + H2SO4 c to 43. Cu2FeS2 + O2 to 44. C12H22O11 + H2SO4 c to 45. FeS2 + HNO3c 46. H2S + SO2 47. H2S + H2SO4 c to 48. H2S + HNO3 c 49. S + H2SO4 c to 50. S + HNO3 c dkt 51. O3 + Ag 52. KClO3 to to dkt 53. KMnO4 54. S + Hg 55. FeSO4 + dd Br2 56. Na + dd CuSO4 57. Cu + HCl + O2 B. 1. Zn + HNO3 rt long 2. Fe3O4 + HNO3 NxOy + 3. FexOy + HNO3 c 4. NH3 + dd AlCl3 5. Zn(NO3)2 + dd NH3 d 6. NH3 + Cl2 to to , xt 7. NH3 + O2 8. NH3 + O2 t to, p 9. NH3 + CO2 10. ur + dd Ca(OH)2 11. P2O5 + HNO3 12. NO2 + dd NaOH 13. P2O5 + H2SO4 c 14. A lCl + dd Na2CO3 3 15. FeCl3 + dd CH3NH2 16. CO2 + dd NaAlO2 17. dd AgNO3 + NaOH 18. dd AgNO3 +NH3 d 19. KHSO4 + dd BaCl2 20. KHSO4+ dd KHCO3 21. AlCl3 + dd NaAlO2 22. ZnCl2 + dd NaOH 23. FeCl3 + dd Na2SO3 24. KHSO4 + NaHS 25. AlCl3 + ddNH3 d 26. NaNO3 + HCl + Cu 27. CO2 + dd NaAlO2 28. KHSO4 + Na2CO3 29. NaNO3 30. Mg(NO3)2 to to to 31. CuNO3 32. AgNO3 to
0

3
33. NH4NO3 C. 1. Na2O2 + H2O 3. NaH + H2O 5. Ba + dd NH4Cl 180 C 7. CaSO4.2H2O 9. Al + dd Ba(OH)2 11. Fe + H2O hi to 13. FexOy + CO to 15. Fe + dd AgNO3 d 17. CuSO4 + dd KI 19. Zn2P3 + H2O 21. Au + HNO3 + HCl
to
0

Bi tp ca Lu 3 Tun Ngha
(chienbinhpro95_1st@yahoo.com.vn)

34. NH4NO3 to 2. Na3N + H2O 4. Mg + H2O hi to 6. Mg + H2O hi to C 8. CaSO4.2H2O 360 10. FeCl3 + dd HI to 12. Fe2O3.MgO + H2 14. Fe + dd AgNO3 thiu 16. FeI2 + H2SO4 c 18. dd CuSO4 dp 20. CuSO4 + KCN (CN)2+..
0

3.

Bi tp v phn ng oxi ho - kh:

1. Ly v d minh ho axit c th ng vai tr l cht kh, cht oxi ho hoc ch l mi trng trong cc phn ng oxi ho - kh. 2. Cc cht v cc ion sau ng vai tr g trong cc phn ng oxi ho - kh: Zn, S, Cl2, FeO, SO2, CuO, Fe2+, Fe3+, Cl-, NH3, NO3-, SO32-, H+, H2O. 3. Dng phn ng ho hc chng minh H c tnh kh mnh hn H 2 v O3 c tnh oxi ho mnh hn O2. 4. Vit phng trnh phn ng xy ra di dng ion khi cho: 5. - Mg d vo dung dch cha Cu(NO3)2 v HCl bit sau phn ng thu c hn hp kh gm N2 v H2. 6. - Dung dch cha H2SO4 v FeSO4 tc dng vi dung dch cha NaOH v Ba(OH) 2 d. 7. - Cho NO2 tc dng vi dung dch KOH d. Sau ly dung dch thu c cho tc dng vi Zn sinh ra hn hp kh NH 3 v H2. 8. - Cho Na tan ht trong dung dch AlCl 3 thu c kt ta. 9. Ho tan Fe3O4 trong dung dch H 2SO4 long d c dung dch A. Cho 1 lng Fe va vo dung dch A thu c dung dch B. Cho dung dch B tc dng vi dung dch Ba(OH)2 d, lc kt ta ra sch v nung trong khng kh c hn hp rn. Vit cc PTP xy ra. 10. Ho tan hn hp FeS2 v FeCO3 vo dung dch HNO 3 c, nng thu c dung dch A v hn hp kh. Cho dung dch A tc dng vi BaCl 2 d to kt ta trng v dung dch B. Cho dung dch B tc dng vi NaOH c kt ta nu . 11. Vit phng trnh phn ng dng phn t v ion thu gn H Bch Khoa 1998 12. Cho hn hp gm FeS2 v FeCO3 tc dng ht vi dung dch HNO 3 c, nng thu c dung dch A v hn hp kh B gm NO 2, CO2. Thm dung dch BaCl2 vo dung dch A. Hp th hn hp kh B bng dung dch NaOH d. Vit phng trnh phn t v phng trnh ion rt gn ca cc phn ng xy ra. thi H v C khi B-2003 13. Cho bt nhm tc dng vi dung dch HNO 3 long, d c dung dch A, kh N2O. Cho dung dch NaOH d vo A c dung dch B, kh C. Cho dung dch H 2SO4 long vo B n d. Vit cc phng trnh phn ng. thi H Cng on 2001 14. Vit phng trnh phn ng ca cc cht : KMnO 4, Mg, FeS, Na2SO3 vi dung dch HCl. Cc kh thu c th hin tnh oxi ho - kh nh th no? thi H Cng on2001 15. Cho kalipemanganat tc dng vi axit clohiric c thu c mt cht kh mu vng lc. Dn kh thu c vo dung dch KOH nhit thng v vo dung dch KOH c un nng 1000C. Vit phng trnh phn ng xy ra. thi H v C khi A 2003 16. X l hp cht ho hc to ra trong hp kim gm Fe v C trong c 6,67% cacbon v khi lng. Thit lp cng thc ca X. Ho tan X trong HNO3 c nng thu c dung dch A v hn hp kh B. Cho A, B ln lt tc dng

Bi tp ca Lu 4 Tun Ngha
(chienbinhpro95_1st@yahoo.com.vn)

vi NaOH d. 4. Bi tp nh lng v phn ng oxi ho - kh: 1. Cho 4,59g Al tc dng vi HNO3 (gii phng ra hn hp kh NO, N2O) c t khi hi so vi H2 l 16,75. a) Tnh th tch kh NO v th tch ca kh N2O ktc. b) Tnh khi lng HNO3 tham gia phn ng. Bi 23-66-GTH11 2. Cho 28,2g hp kim (Al, Mg, Ag) tan ht vo dung dch HNO 3 thu c hn hp kh (N2, NO, NO2) c th tch 8,96 lt (ktc) v dhh/H2= 16,75. Tnh phn trm khi lng mi kim loi trong hn hp (bit khi tc dng vi HNO 3 th Mg cho ra N2, Al cho ra NO v Ag cho ra NO2). Bi 15. 3. Ho tan hon ton 8,32g Cu vo 3 lt dung dch HNO3 thu c dung dch A v 4,928 lt hn hp kh NO v NO2 (ktc). Hi ktc 1 lt hn hp kh ny c khi lng bao nhiu gam. 1. Cho 16,2g bt Al phn ng ht vi dung dch A to ra hn hp kh NO, N 2 v thu c dung dch B. Tnh th tch NO v N2 trong hn hp. Bit t khi ca hn hp kh so vi H2 l 14,4. trung ho hn hp B phi dng 100 ml dung dch Ba(OH)2 1,3M. Tnh CM dung dch HNO3 ban u. 4. t 5,6g bt Fe trong bnh O2 thu c 7,36g hn hp A gm Fe2O3, Fe3O4, FeO v mt phn Fe d. Ho tan hon ton hn hp A bng dung dch HNO 3 thu c V lt hn hp kh B gm NO2 v NO c t khi so vi H2 l 19. a) Tnh V ktc. b) Cho mt bnh kn dung tch khng i 4 lt cha 640ml H 2O, phn cn li cha khng kh. Bm tt c kh B vo bnh v lc k n khi phn ng xy ra hon ton ta c dung dch X trong bnh, gi s p sut hi nc trong bnh l khng ng k. Tnh C% v khi lng ca dung dch X. 5. Mt hn hp X gm 2 kim loi A, B (u ho tr 2) vi M A MB , mX = 9,7g. Hn hp X tan ht trong 200ml dung dch Y cha H2SO4 1,2M v HNO3 2M to ra hn hp Z gm 2 kh SO2v NO c t khi ca Z i vi H2bng 23,5 v V=2,688 lt (ktc) v dung dch T a) Tnh s mol SO2 v NO trong hn hp Z. b) Xc nh A, B v khi lng mi kim loi trng hn hp X. c) Tnh th tch dung dch NaOH phi thm vo dung dch T bt u c kt ta, kt ta cc i v kt ta cc tiu. 6. Mt hn hp X c khi lng l 18,2g gm 2 kim loi A (ho tr 2) v B (ho tr 3). A v B l 2 kim loi thng dng. Hn hp X tan ht trong 200ml dung dch Y cha H 2SO4 10M v HNO3 8M cho ra hn hp kh Z gm SO2 v kh D (oxit nit) c t khi so vi CO 2 bng 1. Hn hp Z c V= 4,48 lt (ktc) v t khi so vi H2 l 27. a) Xc nh kh D, s mol SO2 v D trong hn hp Z. b) Xc nh 2 kim loi A, B bit rng s mol 2 kim loi bng nhau v tnh % mi kim loi trong hn hp X. c) Chng minh rng 200ml dung dch Y ho tan ht hn hp X trn. Tm gii hn trn v di ca khi lng mui khan thu c khi ho tan X trong Y. 7. Cho ag hn hp A gm oxit FeO, CuO, Fe2O3 c s mol bng nhau tc dng hon ton vi lng va l 250ml dung dch HNO3 khi un nng nh, thu c dung dch B v 3,136 lt (ktc) hn hp kh C gm NO2 v NO c t khi so vi hiro l 20,143. Tnh a v nng mol ca dung dch HNO3 dng.