A/ Hn hp axit v hn hp baz.

Bi 1: Trn 100 ml dung dch NaOH 0,2M vi 150 ml dung dch Ba(OH)2 0,15M thu c dung dch A - Tnh nng mol/l trong dung dch A - Tnh th tch dung dch HCl cn trung ho dung dch A - Tnh V dung dch hn hp H 2SO4 0,5M v 0,2M cn trung ho dung dch A Bi 2: C 200 ml dung dch KOH 33,6% d = 1,33 g/ml. Cho dung dch ny tc dng vi hn hp 500 ml HCl 1,5M v H2SO4 0,5M. Sau phn ng thu c dung dch A. - Tnh nng mol/l ca cc ion trong dung dch A - Tnh lng kt ta khi cho dung dch A phn ng vi dung dch Cu(NO3)2 Bi 3: Trn 100 ml dung dch NaOH 0,2M v 100 ml dung dch Ba(OH)2 0,1M c dung dch A - Tnh V HCl 0,1M trung ho ht dung dch A - Cho dung dch A phn ng vi dung dch FeSO 4 d. Lc kt ta nung trong khng kh. Tnh khi lng cht rn thu c Bi 4: Trn ln dung dch HCl 0,2M V dung dch H2SO4 0,1M theo t l 1 : 1 v th tch. trung ho 100 ml dung dch thu c cn bao nhiu ml dung dch Ba(OH)2 0,02M Bi 5: Tnh nng mol/l ca dung dch H2SO4 v dung dch NaOH bit rng - 30 ml dung dch H2SO4 c trung ho ht bi 20 ml dung dch NaOH v 10 ml dung dch KOH 2M - 30 ml dung dch NaOH c trung ho bi 20 ml H2SO4 v 5 ml HCl 1M Bi 6: a) Vit phng trnh phn t v dng ion thu gn ca phn ng gia dung dch NaHCO3 vi cc dung dch H2SO4 long, KOH, Ba(OH)2 d. Trong mi phn ng , ion HCO3- ng vai tr axit hay baz b) Trn dung dch A cha NaOH v dung dch B cha Ba(OH)2 theo th tch bng nhau thu c dung

Dng bi tp 3: Gii bi ton theo phng php mol - ion

dch C. Trung ho 100 ml dung dch C cn dng ht 35 ml H2SO4 2M v thu c 9,32 g kt ta Bi 7. Dung dch A l dung dch HCl, dung dch B l dung dch NaOH. 1-Ly 10 ml dung dch A, pha long bng nc thnh 1000 ml th thu c dung dch HCl c pH=2. Tnh nng mol ca dung dch A. 2- trung ho 100 gam dung dch B cn 150 ml dung dch A. Tnh nng % ca dung dch B. Bi 8. Trn dung dch A cha NaOH v dung dch B cha Ba(OH)2 theo t l th tch bng nhau thu c dung dch C. Trung ho 100 ml dung dch C cn dng ht 35 ml dung dch H2SO4 2M v thu c 9,32 gam kt ta. - Tnh nng mol ca cc dung dch A v B. - Cn phi trn bao nhiu ml dung dch B vi 20 ml dung dch A thu c dung dch D c th ho tan va ht 10,8 gam bt Al. B/ Kim loi tc dng vi dung dch axit. Bi 1: Ho tan 1,4 g kim loi ho tr 2 vo bng 40 ml dung dch H2SO4 0,5M v 100 ml dung dch HCl 0,2M. Sau khi kim loi tan ht thu c dung dch A. trung ho dung dch A cn 50 ml dung dch KOH 0,2M - Xc nh kim loi - Tnh nng mol/l trong dung dch A. Bi 2.Cho 16 gam hn hp 2 kim loi Mg v Fe tc dng vi 400 ml dung dch hn hp gm H2SO4 2M v HCl 2M thu c dung dch A v 8,96 lit H2 (ktc). - Hy chng minh trong dung dch A cn d axit. - Tnh nng mol/l cc ion c trong dung dch A. bi 3. Cho 10,7 gam hn hp gm Mg, Al, Fe tan va trong 500 ml dung dch H2SO4thu c 7,84 lit H2(ktc) v dung dch A gm cc mui sun pht. Hy tnh khi lng mui thu c khi c cn dung dch A v nng mol/l dung dch H2SO4 dng. Bi 4: Cho 8 gam hn hp hai kim loi Mg v Fe vo 50 ml hn hp dung dch hai axit H2SO4 v HCl c nng tng ng l 1,8M v 1,2M. Dn ton b kh sinh ra qua ng cha 16 g CuO nung nng. ha tan ht cht rn

cn li trong ng cn bao nhiu ml dung dch HNO3 c 42% d = 1,2 g/ml? Bit phn ng ha tan sinh ra NO2 Bi 5: Cho 3,87 g hn hp gm Mg v Al tc dng vi 250 ml dung dch X gm HCl 1M v H 2SO4 2,5 M thu c dung dch B v 4,368 l H2 (ktc) 1) Chng minh rng dung dch B cn d axit 2) Tnh thnh phn % v khi lng cc kim loi trong hn hp A 3) Cho dung dch C gm hn hp NaOH 0,02M v Ba(OH)2 0,01M. Trung ha va axit trong dung dch B. Hy tnh th tch dung dch C cn dng 4) Tnh th tch dung dch C vi nng trn tc dng vi dung dch B thu c lng kt ta nh nht, tnh khi lng kt ta Bi 6: Mt hn hp A gm Ba & Al.
Cho m gam A tc dng vi H2O d, thu c 1,344 lt kh, dung dch B v phn khng tan C. Cho 2m gam A tc dng vi dung dch Ba(OH) 2 d thu c 20,832 lt kh. Bit cc phn ng xy ra hon ton, cc kh u o ktc. 1- Tnh khi lng ca tng kim loi trong m gam A. Cho 50 ml dung dch HCl vo dung dch B. Sau khi phn ng xong, thu c 0,78 gam kt ta. Xc nh nng mol/l ca dung dch HCl Bi 7: Hn hp E gm 3 kim loi dng bt l K, Al, Fe c chia thnh 3 phn bng nhau: - Phn 1: Cho tc dng vi H2O ly d to ra 4,48 lt kh. - Phn 2: Cho tc dng vi dung dch KOH d to ra 7,84 lt kh. - Phn 3: Ho tan hon ton trong 0,5 lt dung dch H 2SO4 1,2M to ra 10,08 lt kh v dung dch A. 1- Tnh s gam mi kim loi trong hn hp E. 2- Cho dung dch A tc dng vi 240 gam dung dch NaOH 20% thu c kt ta, lc ra kt ta ri nung trong khng kh ti khi lng khng i thu c m gam cht rn. Tnh m. ( Bit th tch cc kh o KTC) Bi8: Cho mu hp kim A dng bt bao gm Ba, Mg, Al. - Ly m gam A cho vo H 2O ti khi kh ngng thot ra th c 0,82 lt kh H2 .

C/ Hn hp mui vi Baz kim - hn hp mui vi hn hp mui Bi 1. Cho 200 ml dung dch gm MgCl 2 0,3 M, AlCl3 0,45M, HCl 0,55M tc dng hon ton vi V(lt) dung dch C gm NaOH 0,02 M v Ba(OH) 2 0,01 M. Tnh V thu c lng kt ta ln nht v b nht, tnh khi lng kt ta . Cho rng khi Mg(OH)2 kt ta hon ton th Al(OH)3 tan trong kim khng ng k. Bi 2. Dung dch X cha cc ion Ca2+ , Al3+ , Cl-. lm kt ta ht ion Cl- trong 10 ml dung dch phi dng ht 70 ml dung dch AgNO3 1M. Khi c cn 100 ml dung dch X thu c 35,55 g hn hp 2 mui khan. Tnh nng mol/l ca mi mui trong dung dch X Bi 3.Dung dch X gm Zn2+; Fe3+; SO42-. kt ta ht ion Zn2+ v Fe3+ trong 100 ml dung dch X cn 350 ml dung dch NaOH 2M. Nu thm 200 ml dung dch NaOH 2M th c 1phn6 kt ta tan ra, ng thi thu c m g kt ta duy nht - Tnh nng ion trong dung dch X - Tnh khi lng kt ta Bi 4. Cho 43 gam hn hp 2 mui CaCl 2 v BaCl2 vo 1 lit dung dch hn hp Na 2CO3 0,1 M v (NH4)2CO3 0,25 M. Sau khi cc phn ng kt thc ta thu c 39,7 gam kt ta A v dung dchB. Tnh % khi lng cc cht trong hn hp A. Bi 5. Cho 50 ml dung dch A gm: Na + , NH4+, SO42- , CO32- . Cho t t n d dung dch Ba(OH) 2 vo dung dch A v un nng thu c 0,34 gam kh c th lm xanh giy qu m v c 4,3 gam kt ta, cn khi cho A

Ly m gam A cho vo dung dch NaOH d ti phn ng hon ton thu c 6,355 lt kh H2. - Ly m gam A ho tan bng mt lng va dung dch HCl thu c dung dch B v 8,405 lt kh H2. 1- Tnh m v hm lng ca mi kim loi trong mu A. 2- Thm 10 gam dung dch H2SO4 9,8% vo dung dch B sau thm tip 210 gam dung dch NaOH 20%. Sau khi kt thc tt c cc phn ng, ly kt ta thu c nung nhit cao ti phn ng hon ton. Tnh khi lng cht rn thu c sau khi nung. Bit cc kh u o 27 oC v 1,2 atm. -

tc dng vi dung dch H2SO4 long d th thu c 0,224 lt kh ktc. 1-Tm nng mol ca mi ion trong A. 2-Tnh khi lng mui khan thu c khi c cn dung dch A. Bi 6 Ho tan a gam hn hp Na2CO3 & KHCO3 vo H2O c 400 ml dung dch A. Cho t t 100 ml dung dch HCl 1,5M vo dung dch A, thu c dung dch B v 1,008 lt kh ( ktc ) cho B tc dng vi Ba(OH) 2 d thu c 29,55 gam kt ta. 1-Tnh a. 2-Tnh nng mol ca cc ion trong dung dch A ( b qua s cho nhn proton ca cc ion HCO3- , CO3 2- ). 3-Ngi ta li cho t t dung dch A vo bnh ng 100 ml HCl 1,5 M. Tnh th tch kh CO2 c to ra ktc.

Bi 7: C 1 lt dung dch hn hp Na2CO3 0,1 mol/l v (NH4)2CO3 0,25 mol/l. Cho 43 gam hn hp bari clorua v canxi clorua vo dung dch . Sau khi cc phn ng kt thc thu c 39,7 gam kt ta A v dung dch B. a) Tnh % khi lng cc cht trong A. b) Chia dung dch B thnh 2 phn bng nhau: c) Cho axit HCl d vo mt phn, sau c cn dung dch v nung cht rn cn li ti khi lng khng i c cht rn X. Tnh % khi lng cc cht trong X. d) un nng phn th hai ri thm t t 270ml dung dch Ba(OH)2 0,2M vo. Hi tng khi lng ca 2 dung dch gim ti a bao nhiu gam? (Gi s nc bay hi khng ng k)