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Cu 1: (CA-2007) un 12 gam axit axetic vi 13,8 gam etanol (c H 2SO4 lm xc tc) n khi phn ng t ti trng thi cn bng thu c 11 gam este. Hiu sut ca phn ng este ho l A. 50%. B. 75%. C. 55%. D. 62,5%. Cu 2: (CA-2007)Khi t chy hon ton 4,4 gam cht hu c X n chc thu c sn phm chy ch gm 4,48 lt CO2 (ktc) v 3,6 gam nc. Nu cho 4,4 gam hp cht X tc dng vi dung dch NaOH va n khi phn ng hon ton, thu c 4,8 gam mui ca axit hu c Y v cht hu c Z. Tn ca X l A. isopropyl axetat. B. etyl axetat. C. metyl propionat. D. etyl propionat Cu 3: (CA-2007)Cho cht X tc dng vi mt lng va dung dch NaOH, sau c cn dung dch thu c cht rn Y v cht hu c Z. Cho Z tc dng vi AgNO 3 (hoc Ag2O) trong dung dch NH3 thu c cht hu c T. Cho cht T tc dng vi dung dch NaOH li thu c cht Y. Cht X c th l A. CH3COOCH=CH2. B. HCOOCH=CH2. C. HCOOCH3. D. CH3COOCH=CHTCH3. Cu 4: (CA-2008)Este n chc X c t khi hi so vi CH4 l 6,25. Cho 20 gam X tc dng vi 300 ml dung dch KOH 1M (un nng). C cn dung dch sau phn ng thu c 28 gam cht rn khan. Cng thc cu to ca X l A. CH2=CH-COO-CH2-CH3. B. CH3 COO-CH=CH-CH3. C. CH2=CH-CH2-COO-CH3. D. CH3-CH2-COO-CH=CH2. Cu 5: (CA-2008)X phng ho hon ton 22,2 gam hn hp gm hai este HCOOC2H5 v CH3COOCH3 bng dung dch NaOH 1M (un nng). Th tch dung dch NaOH ti thiu cn dng l: A. 400 ml. B. 200 ml. C. 300 ml. D. 150 ml. Cu 6: (C-2008)un nng 6,0 gam CH3COOH vi 6,0 gam C 2H5OH (c H2SO4 lm xc tc, hiu sut phn ng este ha bng 50%). Khi lng este to thnh l: A. 8,8 gam. B. 6,0 gam. C. 5,2 gam. D. 4,4 gam. Cu 7: (C-2009)Cho 20 gam mt este X (c phn t khi l 100 vC) tc dng vi 300 ml dungdch NaOH 1M. Sau phn ng, c cn dung dch thu c 23,2 gam cht rn khan. Cng thc cu to ca X l A. CH2=CHCH2COOCH3. B. CH3COOCH=CHCH3. C. C2H5COOCH=CH2. D. CH2=CHCOOC2H5 Cu 8: (C-2009)Pht biu no sau y sai? A. Trong cng nghip c th chuyn ho cht bo lng thnh cht bo rn. B. Nhit si ca este thp hn hn so vi ancol c cng phn t khi. C. S nguyn t hiro trong phn t este n v a chc lun l mt s chn. D. Sn phm ca phn ng x phng ho cht bo l axit bo v glixerol. Cu9: (C-2009) S hp cht l ng phn cu to, c cng cng thc phn t C 4H8O2, tc dng c vi dung dch NaOH nhng khng tc dng c vi Na l A. 2. B. 1. C. 3. D. 4. Cu 10: (C-2010)Hn hp Z gm hai este X v Y to bi cng mt ancol v hai axit cacboxylic k tip nhau trong dy ng ng (MX < MY). t chy hon ton m gam Z cn dng 6,16 lt kh O 2 (ktc), thu c 5,6 lt kh CO2 (ktc) v 4,5 gam H2O. Cng thc este X v gi tr ca m tng ng l A. CH3COOCH3 v 6,7 B. HCOOC2H5 v 9,5 C. HCOOCH3 v 6,7 D. (HCOO)2C2H4 v 6,6 Cu 11: (C-2010) trung ho 15 gam mt loi cht bo c ch s axit bng 7, cn dng dung dch cha a gam NaOH. Gi tr ca a l A. 0,200. B. 0,280. C. 0,075. D. 0,150. Cu 12: (C-2010) Thu phn cht hu c X trong dung dch NaOH (d), un nng, thu c sn phm gm 2 mui v ancol etylic. Cht X l

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A. CH3COOCH2CH2Cl. B. CH3COOCH2CH3. C. ClCH2COOC2H5. D. CH3COOCH(Cl)CH3. Cu 13: (C-2010)Cho 45 gam axit axetic phn ng vi 69 gam ancol etylic (xc tc H 2SO4 c), un nng, thu c 41,25 gam etyl axetat. Hiu sut ca phn ng este ho l A. 62,50% B. 50,00% C. 40,00% D. 31,25% Cu 14: (HA-2007)Thy phn hon ton 444 gam mt lipit thu c 46 gam glixerol (glixerin) v hai loi axit bo. Hai loi axit bo l A. C15H31COOH v C17H35COOH. B. C17H33COOH v C15H31COOH. C. C17H31COOH v C17H33COOH. D. C17H33COOH v C17H35COOH Cu 15: (HA-2007)X phng ha 8,8 gam etyl axetat bng 200 ml dung dch NaOH 0,2M. Sau khi phn ng xy ra hon ton, c cn dung dch thu c cht rn khan c khi lng l A. 8,56 gam. B. 3,28 gam. C. 10,4 gam. D. 8,2 gam. Cu 16: (HA-2007)Hn hp X gm axit HCOOH v axit CH3COOH (t l mol 1:1). Ly 5,3 gam hn hp X tc dng vi 5,75 gam C 2H5OH (c xc tc H2SO4 c) thu c m gam hn hp este (hiu sut cc phn ng este ha bng 80%). Gi tr ca m l A. 10,12. B. 6,48. C. 8,10. D. 16,20. Cu 17: (HA-2007) Khi thc hin phn ng este ho 1 mol CH 3COOH v 1 mol C2H5OH, lng este ln nht thu c l 2/3 mol. t hiu sut cc i l 90% (tnh theo axit) khi tin hnh este ho 1 mol CH3COOH cn s mol C2H5OH l (bit cc phn ng este ha thc hin cng nhit ) A. 0,342. B. 2,925. C. 2,412. D. 0,456. Cu 18: (HA-2007) Mt este c cng thc phn t l C 4H6O2, khi thu phn trong mi trng axit thu c axetanehit. Cng thc cu to thu gn ca este l A. CH2=CH-COO-CH3. B. HCOO-C(CH3)=CH2. C. HCOO-CH=CH-CH3. D. CH3COO-CH=CH2. Cu 19: (HB -07) Hai este n chc X v Y l ng phn ca nhau. Khi ho hi 1,85 gam X, thu c th tch hi ng bng th tch ca 0,7 gam N2 (o cng iu kin). Cng thc cu to thu gn ca X v Y l (cho H = 1, C = 12, N = 14, O = 16) A. C2H3COOC2H5 v C2H5COOC2H3. B. C2H5COOCH3 v HCOOCH(CH3)2. C. HCOOCH2CH2CH3 v CH3COOC2H5. D. HCOOC2H5 v CH3COOCH3. Cu 20: (HB -07) X l mt este no n chc, c t khi hi i vi CH 4 l 5,5. Nu em un 2,2 gam este X vi dung dch NaOH (d), thu c 2,05 gam mui. Cng thc cu to thu gn ca X l (cho H = 1,C =12, O = 16, Na = 23) A. HCOOCH(CH3)2. B. C2H5COOCH3. C. CH3COOC2H5. D. HCOOCH2CH2CH3. Cu 21: (HB -07) Thy phn este c cng thc phn t C4H8O2 (vi xc tc axit), thu c 2 sn phm hu c X v Y. T X c th iu ch trc tip ra Y. Vy cht X l A. axit fomic. B. etyl axetat. C. ru metylic. D. ru etylic. DHA-08 Cu 6: S ng phn este ng vi cng thc phn t C4H8O2 l A. 5. B. 2. C. 4. D. 6. Cu 22: (HB -07) Pht biu ng l: A. Phn ng gia axit v ru khi c H2SO4 c l phn ng mt chiu. B. Tt c cc este phn ng vi dung dch kim lun thu c sn phm cui cng l mui v ru (ancol). C. Khi thy phn cht bo lun thu c C2H4(OH)2. D. Phn ng thy phn este trong mi trng axit l phn ng thun nghch. Cu 23: (HB-2008) Hp cht hu c no, a chc X c cng thc phn t C7H12O4. Cho 0,1 mol X tc dng va vi 100 gam dung dch NaOH 8% thu c cht hu c Y v 17,8 gam hn hp mui. Cng thc cu to thu gn ca X l A. CH3OOC-(CH2)2-COOC2H5. B. CH3COO-(CH2)2-COOC2H5. C. CH3COO-(CH2)2-OOCC2H5. D. CH3OOC-CH2-COO-C3H7.

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Cu 24: (HB-2008) X phng ho hon ton 17,24 gam cht bo cn va 0,06 mol NaOH. C cn dung dch sau phn ng thu c khi lng x phng l A. 17,80 gam. B. 18,24 gam. C. 16,68 gam. D. 18,38 gam. Cu 25: Khi t chy hon ton mt este no, n chc th s mol CO 2 sinh ra bng s mol O2 phn ng. Tn gi ca este l A. metyl fomiat. B. etyl axetat. C. n-propyl axetat. D. metyl axetat. Cu 25: (HB-2008)Cho hn hp X gm hai hp chthu c no, n chc tc dng va vi 100 ml dung dch KOH 0,4M, thu c mt mui v 336 ml hi mtt ancol (ktc). Nu t chy hon ton lng hn hp X trn, sau hp th ht sn phm chy vo bnh ng dung dch Ca(OH)2 (d) th khi lng bnh tng 6,82 gam. Cng thc ca hai cht hu c trong X l A. CH3COOH v CH3COOC2H5. B. C2H5COOH v C2H5COOCH3. C. HCOOH v HCOOC2H5. D. HCOOH v HCOOC3H7. Cu 26: (HB-2008)Este X (c khi lng phn t bng 103 vC) c iu ch t mt ancol n chc (c t khi hi so vii oxi ln hn 1) v mt amino axit. Cho 25,75 gam X phn ng ht vi 300 ml dung dch NaOH 1M, thu c dung dch Y. C cn dung dch Y thu c m gam cht rn. Gi tr m l A. 27,75. B. 24,25. C. 26,25. D. 29,75. Cu 27: (HA-2008)Este X c cc c im sau: - tchy hon ton X to thnh CO2 v H2O c s mol bng nhau; - Thy phn X trong mi trng axit c cht Y (tham gia phn ng trng gng) v cht Z (c s nguyn t C bng mt na s nguyn t C trong X). Pht biu khng ng l: A. t chy hon ton 1 mol X sinh ra sn phm gm 2 mol CO2 v 2 mol H2O. B. Cht Y tan v hn trong nc. C. Cht X thuc lai este no, n chc. D. un Z vi dung dch H2SO4 c 170oC thu c anken Cu 28 : (HA-2009)X phng ha hon ton 66,6 gam hn hp hai este HCOOC 2H5 v CH3COOCH3 bng dung dch NaOH, thu c hn hp X gm hai ancol. un nng hn hp X vi H 2SO4 c 1400C, sau khi phn ng xy ra hon ton thu c m gam nc. Gi tr ca m l A. 18,00. B. 8,10. C. 16,20. D. 4,05. Cu 29: (HA-2009)X phng ho mt hp cht c cng thc phn t C 10H14O6 trong dung dch NaOH (d), thu c glixerol v hn hp gm ba mui (khng c ng phn hnh hc). Cng thc ca ba mui l: A. CH2=CH-COONa, CH3-CH2-COONa v HCOONa. B. CH3-COONa, HCOONa v CH3-CH=CH-COONa. Cu 30: (HA-2009) X phng ha hon ton 1,99 gam hn hp hai este bng dung dch NaOH thu c 2,05 gam mui ca axit cacboxylic v 0,94 gam hn hp hai ancol l ng ng k tip nhau. Cng thc ca hai este l A. HCOOCH3 v HCOOC2H5. B. C2H5COOCH3 v C2H5COOC2H5. C. CH3COOC2H5 v CH3COOC3H7. D. CH3COOCH3 v CH3COOC2H5. Cu 31: (HA-2009)Cht hu c X c cng thc phn t C 5H8O2. Cho 5 gam X tc dng va ht vi dung dch NaOH, thu c mt hp cht hu c khng lm mt mu nc brom v 3,4 gam mt mui. Cng thc ca X l A. CH3COOC(CH3)=CH2. B. HCOOC(CH3)=CHCH3. C. HCOOCH2CH=CHCH3 D. HCOOCH=CHCH2CH3. Cu 32: (HA-2009)Thu phn hon ton 0,2 mol mt este E cn dng va 100 gam dung dch NaOH 24%,thu c mt ancol v 43,6 gam hn hp mui ca hai axit cacboxylic n chc. Hai axit l A. HCOOH v CH3COOH. B. CH3COOH v C2H5COOH.

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C. C2H5COOH v C3H7COOH. D. HCOOH v C2H5COOH Cu 33: (HA-2011) t chy hon ton 0,11 gam mt este X ( to nn t mt axit cacboxylic n chc v mt ancol n chc) thu c 0,22 gam CO2 v 0,09 gam H2O. S este ng phn ca X l: A. 2 B. 5 C. 6 D.4 Cu 34: (HA-2011) Este X c to thnh t etylen glicol v hai axit cacboxylic n chc. Trong phn t este, s nguyn t cacbon nhiu hn s nguyn t oxi l 1. Khi cho m gam X tc dng vi dung dch NaOH (d) th lng NaOH phn ng l 10 gam. Gi tr ca m l A. 14,5. B. 17,5. C. 15,5. D. 16,5. Cu 35: (HA-2011) x phng ho hon ton 52,8 gam hn hp hai este no, n chc, mch h l ng phn ca nhau cn va 600 ml dung dch KOH 1M. Bit c hai este ny u khng tham gia phn ng trng bc. Cng thc ca hai este l A. C2H5COOC2H5 v C3H7COOCH3. B. C2H5COOCH3 v CH3COOC2H5. C. HCOOC4H9 v CH3COOC3H7. D. CH3COOC2H5 v HCOOC3H7. Cu 36: (HB-2010)Hp cht hu c mch h X c cng thc phn t C 6H10O4. Thy phn X to ra hai ancol n chc c s nguyn t C trong phn t gp i nhau. Cng thc ca X l A. CH3OCO-CH2-COOC2H5. B. C2H5OCO-COOCH3. C. CH3OCO-COOC3H7. D. CH3OCO-CH2-CH2-COOC2H5. Cu 37: (HB-2010) Hn hp X gm axit panmitic, axit stearic v axit linoleic. trung ha m gam X cn 40 ml dung dch NaOH 1M. Mt khc, nu t chy hon ton m gam X th thu c 15,232 lt kh CO2 (ktc) v 11,7 gam H2O. S mol ca axit linoleic trong m gam hn hp X l A. 0,015. B. 0,010. C. 0,020. D. 0,005. Cu 38: (HA-2010) t chy hon ton mt este n chc mch h X (phn t c s lin kt nh hn 3), thu c th tch kh CO 2 bng 6/7 th tch kh O 2 phn ng (cc th tch kh o cng iu kin). Cho m gam X tc dng hon ton vi 200 ml dung dch KOH 0,7M thu c dung dch Y. C cn Y thu c 12,88 gam cht rn khan. Gi tr ca m l A. 10,56. B. 7,20. C. 8,88. D. 6,66. Cu 39: C-07 Este X khng no, mch h, c t khi hi so vi oxi bng 3,125 v khi tham gia phn ng x phng ho to ra mt anehit v mt mui ca axit hu c. C bao nhiu cng thc cu to ph hp vi X? (Cho H = 1; C = 12; O =16) A. 5. B. 4. C. 3. D. 2. Cu 40: C-07 un 12 gam axit axetic vi 13,8 gam etanol (c H2SO4 c lm xc tc) n khi phn ng t ti trng thi cn bng, thu c 11 gam este. Hiu sut ca phn ng este ho l (Cho H = 1; C = 12; O = 16) A. 55%. B. 50%. C. 62,5%. D. 75%. Cu 41: C-07 trung ho lng axit t do c trong 14 gam mt mu cht bo cn 15ml dung dch KOH 0,1M. Ch s axit ca mu cht bo trn l (Cho H = 1; O = 16; K = 39) A. 5,5. B. 4,8. C. 6,0. D. 7,2. Cu 42: C-08 Cht hu c X c cng thc phn t C4H6O4 tc dng vi dung dch NaOH (un nng) theo phng trnh phn ng: C4H6O4 + 2NaOH 2Z + Y. oxi ho ht a mol Y th cn va 2a mol CuO (un nng), sau phn ng to thnh a mol cht T (bit Y, Z, T l cc hp cht hu c). Khi lng phn t ca T l A. 58 vC. B. 82 vC. C. 44 vC. D. 118 vC. Cu 43: HB-11 Cho dy cc cht: phenyl axetat, anlyl axetat, metyl axetat, etyl fomat, tripanmitin. S cht trong dy khi thy phn trong dung dch NaOH (d), un nng sinh ra ancol l: A. 4 B. 2 C. 5 D. 3 Cu 44: HB-11 Cho 200 gam mt loi cht bo c ch s axit bng 7 tc dng va vi mt lng NaOH, thu c 207,55 gam hn hp mui khan. Khi lng NaOH tham gia phn ng l: A. 31 gam B. 32,36 gam C. 30 gam D. 31,45 gam

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Cu 45: HB-11 Khi cho 0,15 mol este n chc X tc dng vi dung dch NaOH (d), sau khi phn ng kt thc th lng NaOH phn ng l 12 gam v tng khi lng sn phm hu c thu c l 29,7 gam. S ng phn cu to ca X tha mn cc tnh cht trn l: A. 4 B. 5 C. 6 D. 2 Cu 46: HB-11 Triolein khng tc dng vi cht (hoc dung dch) no sau y? A. H2O (xc tc H2SO4 long, un nng) B. Cu(OH)2 ( iu kin thng) C. Dung dch NaOH (un nng) D. H2 (xc tc Ni, un nng) Cu 47: HB-11 Thy phn hn hp gm 0,02 mol saccaroz v 0,01 mol mantoz mt thi gian thu c dung dch X (hiu sut phn ng thy phn mi cht u l 75%). Khi cho ton b X tc dng vi mt lng d dung dch AgNO3 trong NH3 th lng Ag thu c l A.0,090 mol B. 0,095 mol C. 0,12 mol D. 0,06 mol Cu 48: C-11 x phng ho hon ton 52,8 gam hn hp hai este no, n chc, mch h l ng phn ca nhau cn va 600 ml dung dch KOH 1M. Bit c hai este ny u khng tham gia phn ng trng bc. Cng thc ca hai este l A. C2H5COOC2H5 v C3H7COOCH3. B. C2H5COOCH3 v CH3COOC2H5. C. HCOOC4H9 v CH3COOC3H7. D. CH3COOC2H5 v HCOOC3H7 Cu 49: C-11 Cho m gam cht hu c n chc X tc dng va vi 50 gam dung dch NaOH 8%, sau khi phn ng hon ton thu c 9,6 gam mui ca mt axit hu c v 3,2 gam mt ancol. Cng thc ca X l A. CH3COOCH=CH2. B. CH3COOC2H5. C. C2H5COOCH3. D. CH2=CHCOOCH3. Cu 50: C-11 Este X no, n chc, mch h, khng c phn ng trng bc. t chy 0,1 mol X ri cho sn phm chy hp th hon ton vo dung dch nc vi trong c cha 0,22 mol Ca(OH) 2 th vn thu c kt ta. Thu phn X bng dung dch NaOH thu c 2 cht hu c c s nguyn t cacbon trong phn t bng nhau. Phn trm khi lng ca oxi trong X l A. 37,21%. B. 36,36%. C. 43,24%. D. 53,33%. Cu 51:H A -12 t chy hon ton 7,6 gam hn hp gm mt axit cacboxylic no, n chc, mch h v mt ancol n chc (c s nguyn t cacbon trong phn t khc nhau) thu c 0,3 mol CO 2 v 0,4 mol H2O. Thc hin phn ng este ha 7,6 gam hn hp trn vi hiu sut 80% thu c m gam este. Gi tr ca m l A. 4,08. B. 6,12. C. 8,16. D. 2,04. Cu 52: Cho cc pht biu sau: (a) Cht bo c gi chung l triglixerit hay triaxylglixerol. (b) Cht bo nh hn nc, khng tan trong nc nhng tan nhiu trong dung mi hu c. (c) Phn ng thy phn cht bo trong mi trng axit l phn ng thun nghch. (d) Tristearin, triolein c cng thc ln lt l: (C17H33COO)3C3H5, (C17H35COO)3C3H5. S pht biu ng l A. 2. B. 1. C. 3. D. 4. Cu 53 HB-12 t chy hon ton m gam hn hp X gm hai este ng phn cn dng 27,44 lt kh O 2, thu c 23,52 lt kh CO2 v 18,9 gam H2O. Nu cho m gam X tc dng ht vi 400 ml dung dch NaOH 1M, c cn dung dch sau phn ng th thu c 27,9 gam cht rn khan, trong c a mol mui Y v b mol mui Z (MY < MZ). Cc th tch kh u o iu kin tiu chun. T l a : b l A. 2 : 3. B. 4 : 3. C. 3 : 2. D. 3 : 5. Cu 54: HB-12 Thy phn este X mch h c cng thc phn t C4H6O2, sn phm thu c c kh nng trng bc. S este X tha mn tnh cht trn l A. 4. B. 3. C. 6. D. 5. Cu 55 C-12 Cho cc este : etyl fomat (1), vinyl axetat (2), triolein (3), metyl acrylat (4), phenyl axetat (5). Dy gm cc este u phn ng c vi dung dch NaOH (un nng) sinh ra ancol l A. (1), (2), (3). B. (1), (3), (4). C. (2), (3), (5). D. (3), (4), (5). Cu 56. C-12 Ha hi hon ton 4,4 gam mt este X mch h, thu c th tch hi bng th tch ca 1,6 gam kh oxi (o cng iu kin). Mt khc, thy phn hon ton 11 gam X bng dung dch NaOH d, thu c 10,25 gam mui. Cng thc ca X l

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A. C2H5COOCH3.

B. CH3COOC2H5.

C. C2H5COOC2H5.

D. HCOOC3H7.