CHUYN : CC HP CHT THM

Cu (A-2007). Cho s Cl2 (t l mol 1:1) NaOH (c, d) axit HCl C6 H6 (benzen) X Y Z Fe, t0 t0 cao, p cao Hai cht hu c Y, Z ln lt l: A. C6H6(OH)6, C6H6Cl6. B. C6H4(OH)2, C6H4Cl2. C. C6H5OH, C6H5Cl. D. C6H5ONa, C6H5OH. Cu (A-2007). Pht biu khng ng l: A. Axit axetic phn ng vi dung dch NaOH, ly dung dch mui va to ra cho tc dng vi kh CO2 li thu c axit axetic. B. Phenol phn ng vi dung dch NaOH, ly mui va to ra cho tc dng vi dung dch HCl li thu c phenol. C. Anilin phn ng vi dung dch HCl, ly mui va to ra cho tc dng vi dung dch NaOH li thu c anilin. D. Dung dch natri phenolat phn ng vi kh CO2, ly kt ta va to ra cho tc dng vi dung dch NaOH li thu c natri phenolat. Cu (B-2007). Cc ng phn ng vi cng thc phn t C8H10O (u l dn xut ca benzen) c tnh cht: tch nc thu c sn phm c th trng hp to polime, khng tc dng c vi NaOH. S lng ng phn ng vi cng thc phn t C8H10O, tho mn tnh cht trn l A. 1. B. 4. C. 3. D. 2. Cu (B-2007). Dy gm cc cht u lm giy qu tm m chuyn sang mu xanh l: A. anilin, metyl amin, amoniac. B. amoni clorua, metyl amin, natri hiroxit. C. anilin, amoniac, natri hiroxit. D. metyl amin, amoniac, natri axetat. Cu (B-2007). S cht ng vi cng thc phn t C7H8O (l dn xut ca benzen) u tc dng c vi dung dch NaOH l A. 2. B. 4. C. 3. D. 1. Cu (B-2007). Cho cc cht: etyl axetat, anilin, ancol (ru) etylic, axit acrylic, phenol, phenylamoni clorua, ancol (ru) benzylic, p-crezol. Trong cc cht ny, s cht tc dng c vi dung dch NaOH l A. 4. B. 6. C. 5. D. 3. Cu (B-2007). C 3 cht lng benzen, anilin, stiren, ng ring bit trong 3 l mt nhn. Thuc th phn bit 3 cht lng trn l A. dung dch phenolphtalein. B. nc brom. C. dung dch NaOH. D. giy qu tm. Cu (C-2007). Cho cc cht sau: phenol, etanol, axit axetic, natri phenolat, natri hiroxit. S cp cht tc dng c vi nhau l A. 4. B. 3. C. 2. D. 1. Cu (C-2007). Hp cht hu c X (phn t c vng benzen) c cng thc phn t l C7H8O2, tc dng c vi Na v vi NaOH. Bit rng khi cho X tc dng vi Na d, s mol H2 thu c bng s mol X tham gia phn ng v X ch tc dng c vi NaOH theo t l s mol 1:1. Cng thc cu to thu gn ca X l A. C6H5CH(OH)2. B. HOC6H4CH2OH. C. CH3C6H3(OH)2. D. CH3OC6H4OH. Cu (A-2008). Trung ho 5,48 gam hn hp gm axit axetic, phenol v axit benzoic, cn dng 600 ml dung dch NaOH 0,1M. C cn dung dch sau phn ng, thu c hn hp cht rn khan c khi lng l A. 8,64 gam. B. 6,84 gam. C. 4,90 gam. D. 6,80 gam. Cu (A-2008). S ng phn hirocacbon thm ng vi cng thc phn t C8H10 l A. 2. B. 4. C. 3. D. 5. Cu (B-2008). Cho s chuyn ho sau:
Br2 (1:1mol), Fe, t NaOH (d), t HCl (d) Toluen X Y Z
0 0,p

Trong X, Y, Z u l hn hp ca cc cht hu c. Z c thnh phn chnh gm A. m-metylphenol v o-metylphenol. B. benzyl bromua v o-bromtoluen. GV: Nguyn Ph Hot Trng THPT Nguyn Ch Thanh

C. o-bromtoluen v p-bromtoluen. D. o-metylphenol v p-metylphenol. Cu (B-2008). nh hng ca nhm -OH n gc C6H5- trong phn t phenol th hin qua phn ng gia phenol vi A. dung dch NaOH. B. Na kim loi. C. nc Br2. D. H2 (Ni, nung nng). Cu (B-2008). Cho dy cc cht: CH4, C2H2, C2H4, C2H5OH, CH2=CH-COOH, C6H5NH2 (anilin), C6H5OH (phenol), C6H6 (benzen). S cht trong dy phn ng c vi nc brom l A. 6. B. 8. C. 7. D. 5. Cu (C-2008). Cho dy cc cht: phenol, anilin, phenylamoni clorua, natri phenolat, etanol. S cht trong dy phn ng c vi NaOH (trong dung dch) l A. 3. B. 2. C. 1. D. 4. Cu (A-2009). Hirocacbon X khng lm mt mu dung dch brom nhit thng. Tn gi ca X l A. etilen. B. xiclopropan. C. xiclohexan. D. stiren. Cu (A-2009). Mt hp cht X cha ba nguyn t C, H, O c t l khi lng mC: mH: mO = 21 : 2 : 4. Hp cht X c cng thc n gin nht trng vi cng thc phn t. S ng phn cu to thuc loi hp cht thm ng vi cng thc phn t ca X l A. 5. B. 4. C. 6. D. 3. Cu (A-2009). Hp cht hu c X tc dng c vi dung dch NaOH v dung dch brom nhng khng tc dng vi dung dch NaHCO3. Tn gi ca X l A. metyl axetat. B. axit acrylic. C. anilin. D. phenol. Cu (A-2009). C ba dung dch: amoni hirocacbonat, natri aluminat, natri phenolat v ba cht lng: ancol etylic, benzen, anilin ng trong su ng nghim ring bit. Nu ch dng mt thuc th duy nht l dung dch HCl th nhn bit c ti a bao nhiu ng nghim? A. 5. B. 6. C. 3. D. 4. Cu (A-2009). Cho dy chuyn ho sau: X NaOH (d) Phenol Phenyl axetat Y (hp cht thm) t0 Hai cht X, Y trong s trn ln lt l: A. anhirit axetic, phenol. B. anhirit axetic, natri phenolat. C. axit axetic, natri phenolat. D. axit axetic, phenol. Cu (B-2009). Khi cho a mol mt hp cht hu c X (cha C, H, O) phn ng hon ton vi Na hoc vi NaHCO3 th u sinh ra a mol kh. Cht X l A. etylen glicol. B. axit aipic. C. ancol o-hiroxibenzylic. D. axit 3-hiroxipropanoic. Cu (B-2009). Cho X l hp cht thm; a mol X phn ng va ht vi a lt dung dch NaOH 1M. Mt khc, nu cho a mol X phn ng vi Na (d) th sau phn ng thu c 22,4a lt kh H2 ( ktc). Cng thc cu to thu gn ca X l A. HO-C6H4-COOCH3. B. CH3-C6H3(OH)2. C. HO-CH2-C6H4-OH. D. HO-C6H4-COOH. Cu 36 (B-09). Ngi ta iu ch anilin bng s sau: HNO3 (c) Fe + HCl Nitrobenzen Anilin Benzen H 2SO4 (c) t0 Bit hiu sut giai on to thnh nitrobenzen t 60% v hiu sut giai on to thnh anilin t 50%. Khi lng anilin thu c khi iu ch t 156 gam benzen l A. 186,0 gam. B. 55,8 gam. C. 93,0 gam. D. 111,6 gam. Cu (C-2009). Trong thc t, phenol c dng sn xut A. nha poli(vinyl clorua), nha novolac v cht dit c2,4-D. B. nha rezol, nha rezit v thuc tr su 666. C. poli(phenol-fomanehit), cht dit c 2,4-D v axit picric. D. nha rezit, cht dit c 2,4-D v thuc n TNT. Cu (C-2009). Cho cc cht HCl (X); C2H5OH (Y); CH3COOH (Z); C6H5OH (phenol) (T). Dy gm cc cht c sp xp theo tnh axit tng dn (t tri sang phi) l: A. (X), (Z), (T), (Y). B. (Y), (T), (Z), (X). C. (Y), (T), (X), (Z). D. (T), (Y), (X), (Z). Cu (A-2010). Trong s cc pht biu sau v phenol (C6H5OH): GV: Nguyn Ph Hot Trng THPT Nguyn Ch Thanh

(1) Phenol tan t trong nc nhng tan nhiu trong dung dch HCl. (2) Phenol c tnh axit, dung dch phenol khng lm i mu qutm. (3) Phenol dng sn xut keo dn, cht dit nm mc. (4) Phenol tham gia phn ng th brom v th nitro d hn benzen. Cc pht biu ng l: A. (1), (2), (4). B. (2), (3), (4). C. (1), (2), (3). D. (1), (3), (4). Cu (B-2010). Cho 13,74 gam 2,4,6-trinitrophenol vo bnh kn ri nung nng nhit cao. Sau khi phn ng xy ra hon ton, thu c x mol hn hp kh gm: CO2, CO, N2 v H2. Gi tr ca x l A. 0,60. B. 0,36. C. 0,54. D. 0,45. Cu (B-2010). Trong cc cht: xiclopropan, benzen, stiren, metyl acrylat, vinyl axetat, imetyl ete, s cht c kh nng lm mt mu nc brom l A. 5. B. 4. C. 6. D. 3. Cu (B-2010). Cho cc cht: (1) axit picric; (2) cumen; (3) xiclohexanol; (4) 1,2-ihiroxi-4metylbenzen; (5) 4-metylphenol; (6) -naphtol. Cc cht thuc loi phenol l: A. (1), (3), (5), (6). B. (1), (2), (4), (6). C. (1), (2), (4), (5). D. (1), (4), (5), (6). Cu (B-2010). Cho s phn ng: H2 O Br2 CuO Stiren X Y Z H H , t0 t0 Trong X, Y, Z u l cc sn phm chnh. Cng thc ca X, Y, Z ln lt l: A. C6H5CHOHCH3, C6H5COCH3, C6H5COCH2Br. B. C6H5CH2CH2OH, C6H5CH2CHO, C6H5CH2COOH. C. C6H5CH2CH2OH, C6H5CH2CHO, m-BrC6H4CH2COOH. D. C6H5CHOHCH3, C6H5COCH3, m-BrC6H4COCH3. Cu (C-2010). Pht biu ng l: A. Vinyl axetat phn ng vi dung dch NaOH sinh ra ancol etylic. B. Thu phn benzyl clorua thu c phenol. C. Phenol phn ng c vi nc brom. D. Phenol phn ng c vi dung dch NaHCO3. Cu (A-2011). Cho axit salixylic (axit o-hiroxibenzoic) phn ng vi anhirit axetic, thu c axit axetylsalixylic (o-CH3COO-C6H4-COOH) dng lm thuc cm (aspirin). phn ng hon ton vi 43,2 gam axit axetylsalixylic cn va V lt dung dch KOH 1M. Gi tr ca V l A. 0,24. B. 0,96. C. 0,72. D. 0,48. Cu (A-2011). Cho dy cc cht: phenylamoni clorua, benzylclorua, isopropyl clorua, mcrezol, ancol benzylic, natri phenolat, anlyl clorua. S cht trong dy tc dng c vi dung dch NaOH long, un nng l A. 4. B. 5. C. 3. D. 6. Cu (A-2011). Hp cht hu c X cha vng benzen c cng thc phn t trng vi cng thc n gin nht. Trong X, t l khi lng cc nguyn t l mC: mH: mO= 21 : 2 : 8. Bit khi X phn ng hon ton vi Na th thu c s mol kh hiro bng s mol ca X phn ng. X c bao nhiu ng phn (cha vng benzen) tha mn cc tnh cht trn? A. 7. B. 10. C. 3. D. 9. Cu (A-2011). Cho dy chuyn ho sau: C 2 H4 Br2 , as KOH/C 2 H 5OH Benzen X Y Z (trong X, Y, Z l sn phm chnh). t l mol 1:1 xt, t 0 t0 Tn gi ca Y, Z ln lt l A. 2-brom-1-phenylbenzen v stiren. B. 1-brom-2-phenyletan v stiren. C. 1-brom-1-phenyletan v stiren. D. benzylbromua v toluen. Cu (B-2011). Ho tan cht X vo nc thu c dung dch trong sut, ri thm tip dung dch cht Y th thu c cht Z (lm vn c dung dch). Cc cht X, Y, Z ln lt l: A. phenol, natri hiroxit, natri phenolat. B. phenylamoni clorua, axit clohiric, anilin. C. anilin, axit clohiric, phenylamoni clorua. D. natri phenolat, axit clohiric, phenol. GV: Nguyn Ph Hot Trng THPT Nguyn Ch Thanh

Cu (B-2011). Cho cc pht biu sau: (a) Anehit va c tnh oxi ho va c tnh kh. (b) Phenol tham gia phn ng th brom kh hn benzen. (c) Anehit tc dng vi H2 (d) c xc tc Ni un nng, thu c ancol bc mt. (d) Dung dch axit axetic tc dng c vi Cu(OH)2. (e) Dung dch phenol trong nc lm qutm ho . (g) Trong cng nghip, axeton c sn xut t cumen. S pht biu ng l A. 4. B. 2. C. 5. D. 3. Cu (C-2011). Sn phm ch yu trong hn hp thu c khi cho toluen phn ng vi brom theo t l s mol 1:1 (c mt bt st) l A. p-bromtoluen v m-bromtoluen. B. benzyl bromua. C. o-bromtoluen v p-bromtoluen. D. o-bromtoluen v m-bromtoluen. Cu (C-2011). Cho m gam hn hp X gm phenol v etanol phn ng hon ton vi natri (d), thu c 2,24 lt kh H2 (ktc). Mt khc, phn ng hon ton vi m gam X cn 100 ml dung dch NaOH 1M. Gi tr ca m l A. 7,0. B. 21,0. C. 14,0. D. 10,5. Cu (C-2011). Cho cc cht: axetilen, vinylaxetilen, cumen, stiren, xiclohexan, xiclopropan v xiclopentan. Trong cc cht trn, s cht phn ng c vi dung dch brom l A. 6. B. 4. C. 5. D. 3. Cu (C-2011). S hp cht ng phn cu to ca nhau c cng thc phn t C8H10O, trong phn t c vng benzen, tc dng c vi Na, khng tc dng c vi NaOH l A. 7. B. 6. C. 4. D. 5. Cu (C-2011). Cht X tc dng vi benzen (xt, t) to thnh etylbenzen. Cht X l A. C2H4. B. C2H2. C. CH4. D. C2H6. Cu (A-2012). Cho dy cc cht: stiren, ancol benzylic, anilin, toluen, phenol (C6H5OH). S cht trong dy c kh nng lm mt mu nc brom l A. 5. B. 4. C. 3. D. 2. Cu (A-2012). Cho cc pht biu sau v phenol (C6H5OH): (a) Phenol tan nhiu trong nc lnh. (b) Phenol c tnh axit nhng dung dch phenol trong nc khng lm i mu qutm. (c) Phenol c dng sn xut phm nhum, cht dit nm mc. (d) Nguyn t H ca vng benzen trong phenol d b thay th hn nguyn t H trong benzen. (e) Cho nc brom vo dung dch phenol thy xut hin kt ta. S pht biu ng l A. 4. B. 2. C. 5. D. 3. Cu (A-2012). Cho dy cc hp cht thm: p-HO-CH2-C6H4-OH, p-HO-C6H4-COOC2H5, pHO-C6H4-COOH, p-HCOO-C6H4-OH, p-CH3O-C6H4-OH. C bao nhiu cht trong dy tha mn ng thi 2 iu kin sau? (a) Ch tc dng vi NaOH theo t l mol 1 : 1. (b) Tc dng c vi Na (d) to ra s mol H2 bng s mol cht phn ng. A. 3. B. 4. C. 1. D. 2. Cu (A-2012). Cho dy cc cht: cumen, stiren, isopren, xiclohexan, axetilen, benzen. S cht trong dy lm mt mu dung dch brom l A. 5. B. 4. C. 2. D. 3. Cu (B-2012). C bao nhiu cht cha vng benzen c cng cng thc phn t C7H8O? A. 3. B. 5. C. 6. D. 4. Cu (B-2012) Cho phenol (C6H5OH) ln lt tc dng vi (CH3CO)2O v cc dung dch: NaOH, HCl, Br2, HNO3, CH3COOH. S trng hp xy ra phn ng l A. 3. B. 4. C. 2. D. 1. Cu (A-2013). Phenol phn ng c vi dung dch no sau y? A. NaCl. B. HCl. C. NaHCO3. D. KOH. Cu (A-2013). Hp cht X c thnh phn gm C, H, O, cha vng benzen. Cho 6,9 gamX vo 360 ml dung dch NaOH 0,5M (d 20% so vi lng cn phn ng) n phn ng hon ton, GV: Nguyn Ph Hot Trng THPT Nguyn Ch Thanh

thu c dung dch Y. C cn Y thu c m gam cht rn khan. Mt khc, t chy hon ton 6,9 gam X cn va 7,84 lt O2 (ktc), thu c 15,4 gam CO2. Bit X c cng thc phn t trng vi cng thc n gin nht. Gi tr ca m l A. 13,2. B. 11,1. C. 12,3. D. 11,4. Cu (B-2013). Trong cc cht: stiren, axit acrylic, axit axetic, vinylaxetilen v butan, s cht c kh nng tham gia phn ng cng hiro (xc tc Ni, un nng) l A. 4. B. 2. C. 5. D. 3. Cu (B-2013). S ng phn amin bc mt, cha vng benzen, c cng cng thc phn t C7H9N l A. 3. B. 2. C. 5. D. 4. Cu (B-2013). Cho cc pht biu sau: (a) Cc cht CH3NH2, C2H5OH, NaHCO3 u c kh nng phn ng vi HCOOH. (b) Phn ng th brom vo vng benzen ca phenol (C6H5OH) d hn ca benzen. (c) Oxi ha khng hon ton etilen l phng php hin i sn xut anehit axetic. (d) Phenol (C6H5OH) tan t trong etanol. Trong cc pht biu trn, s pht biu ng l A. 4. B. 2. C. 3. D. 1. Cu (B-2013). Cho dy cht sau: isopren, anilin, anehit axetic, toluen, pentan, axit metacrylic v stiren. S cht trong dy phn ng c vi nc brom l A. 6. B. 4. C. 7. D. 5. Cu (C-2013). Dung dch phenol (C6H5OH) khng phn ng c vi cht no sau y? A. NaOH. B. NaCl. C. Br2. D. Na. Cu (C-2013). S ng phn cha vng benzen, c cng thc phn t C7H8O, phn ng c vi Na l A. 3. B. 5. C. 4. D. 2.

GV: Nguyn Ph Hot

Trng THPT Nguyn Ch Thanh