Material Safety Data Sheet

Uniquat 10-80 HQ
Version 2.0 Revision Date 2012.03.07 Print Date 2013.01.02

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name Product Use Description : : Uniquat 10-80 HQ Corrosion inhibitor

Company

Lonza Inc. 90 Boroline Road Allendale, NJ 07401 1-201-316-9200 CHEMTREC 1-800-424-9300

Telephone Emergency telephone number

: :

SECTION 2. HAZARDS IDENTIFICATION Emergency Overview

Warning
Colour: dark amber, Odour: strong Hazard Summary : Irritating to eyes and skin. Flammable. Handle in accordance with good industrial hygiene and safety practice. OSHA Hazards : FLAMMABLE LIQUID IRRITANT Potential Health Effects Primary Routes of Entry : Eyes Skin Inhalation Ingestion : Causes skin irritation. : Causes eye irritation.

Skin Eyes

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Material Safety Data Sheet

Uniquat 10-80 HQ
Version 2.0 Revision Date 2012.03.07 Print Date 2013.01.02

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Component Pyridinium, 1-(phenylmethyl), ethyl methyl derivs., chlorides Methanol CAS-No. 68909-18-2 Weight percent 75,00 - 85,00

67-56-1

20,00

SECTION 4. FIRST AID MEASURES First aid procedures Inhalation : If breathed in, move person into fresh air. Get medical attention immediately if irritation develops and persists. : After contact with skin, wash immediately with plenty of soap and water. If skin irritation persists, call a physician. : In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice. : Do not induce vomiting without medical advice. Immediately give large quantities of water to drink. Call a physician immediately. Never give anything by mouth to an unconscious person.

Skin contact

Eye contact

Ingestion

SECTION 5. FIREFIGHTING MEASURES Flammable properties Flash point : 75 F (24 C) Method: Setaflash Closed Tester D3828

Fire fighting Suitable extinguishing media : Dry powder Water spray Foam : Use water spray to cool unopened containers.

Further information

Protective equipment and precautions for firefighters 24642.3 / 000000008861 Page 2 / 9

Material Safety Data Sheet

Uniquat 10-80 HQ
Version 2.0 Specific hazards during firefighting Special protective equipment for firefighters Revision Date 2012.03.07 : Heating or fire can release toxic gas. : In the event of fire, wear self-contained breathing apparatus. Print Date 2013.01.02

SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions : Use respirator when performing operations involving potential exposure to vapour of the product. : Do not flush into surface water or sanitary sewer system. : Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13).

Environmental precautions Methods for containment / Methods for cleaning up

SECTION 7. HANDLING AND STORAGE Handling Handling : Provide sufficient air exchange and/or exhaust in work rooms. In case of insufficient ventilation, wear suitable respiratory equipment. Avoid contact with skin and eyes. : Highly flammable. Keep away from sources of ignition - No smoking. Take precautionary measures against static discharges.

Advice on protection against fire and explosion

Storage Requirements for storage areas and containers : Keep container tightly closed. To maintain product quality, do not store in heat or direct sunlight. Keep in a dry, cool and well-ventilated place. : Store containers in compliance with the most recent NFPA Code (NFPA 30). Ground all containers prior to pouring.

Further information on storage conditions

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Components with workplace control parameters Components CAS-No. Value Control parameters Update Basis

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Material Safety Data Sheet

Uniquat 10-80 HQ
Version 2.0 Methanol 67-56-1 TWA Revision Date 2012.03.07 200 ppm 2009 Print Date 2013.01.02 ACGIH

STEL

250 ppm

2009

ACGIH

REL

200 ppm 260 mg/m3 250 ppm 325 mg/m3

2005

NIOSH/GUIDE

STEL

2005

NIOSH/GUIDE

Engineering measures

Personal protective equipment Eye protection Hand protection : Tightly fitting safety goggles : Suitable material : Nitrile rubber Break through time : > 480 min Take note of the information given by the producer concerning permeability and break through times, and of special workplace conditions (mechanical strain, duration of contact). Skin and body protection : Choose body protection according to the amount and concentration of the dangerous substance at the work place. No special protective equipment required. : In the case of vapour formation use a respirator with an approved filter. : Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product.

Respiratory protection

Hygiene measures

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Physical state Colour Odour : liquid : dark amber : strong

Safety data 24642.3 / 000000008861 Page 4 / 9

Material Safety Data Sheet

Uniquat 10-80 HQ
Version 2.0 Flash point : Revision Date 2012.03.07 75 F (24 C) Method: Setaflash Closed Tester D3828 3-5 Print Date 2013.01.02

pH Melting point/range Boiling point/boiling range Density

: Note: no data available : Note: no data available : 1,02 g/cm3 at 77 F (25 C) : Note: soluble : ca.200 Pas

Water solubility Viscosity, dynamic

SECTION 10. STABILITY AND REACTIVITY Conditions to avoid Materials to avoid : Remarks: no data available : Remarks: Strong oxidizing agents Reducing agents

SECTION 11. TOXICOLOGICAL INFORMATION Further information : There is no data available for this product.

The following toxicological data refer to:

Methanol (CAS-No.: 67-56-1) Acute oral toxicity : LD50 rat Dose: 5 628 mg/kg : LD50 rabbit Dose: 15 800 mg/kg : LC50 rat Exposure time: 4 h Dose: 84 g/m3 : rabbit Result: irritating Page 5 / 9

Acute dermal toxicity

Acute inhalation toxicity

Eye irritation

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Material Safety Data Sheet

Uniquat 10-80 HQ
Version 2.0 Revision Date 2012.03.07 Exposure time: 24 h Sensitisation : guinea pig Result: not sensitizing Print Date 2013.01.02

SECTION 12. ECOLOGICAL INFORMATION Additional ecological information : There is no data available for this product.

The following ecotoxicological data refer to:

Methanol (CAS-No.: 67-56-1) Biodegradability : Respirometer test Exposure time: 5 d Result: Readily biodegradable. 83 % : Acute toxicity LC50 Species: Leuciscus idus (Golden orfe) Concentration: > 10 000,00 mg/l Exposure time: 48 h : Immobilization EC50 Species: Daphnia magna (Water flea) Concentration: > 10 000,00 mg/l Exposure time: 24 h : Cell multiplication inhibition test ErC10 Species: Desmodesmus subspicatus (green algae) Dose: 8 000,00 mg/l Exposure time: 8 d Method: : Cell multiplication inhibition test EC10 Species: Pseudomonas putida Dose: 6 600,00 mg/l Exposure time: 16 h Method:

Acute Fish toxicity

Toxicity to daphnia and other aquatic invertebrates

Toxicity to algae

Toxicity to bacteria

SECTION 13. DISPOSAL CONSIDERATIONS 24642.3 / 000000008861 Page 6 / 9

Material Safety Data Sheet

Uniquat 10-80 HQ
Version 2.0 Further information Revision Date 2012.03.07 Print Date 2013.01.02 : Dispose of in accordance with local regulations. Contact waste disposal services.

SECTION 14. TRANSPORT INFORMATION DOT UN number Description of the goods Class Packing group Labels Emergency Response Guidebook Number

: : : : : : :

1993 Flammable liquids, n.o.s. (Methanol) 3 III 3 128

IATA UN number Description of the goods Class Packing group Labels Packing instruction (cargo aircraft) Packing instruction (passenger aircraft) Packing instruction (passenger aircraft) IMDG-CODE UN number Description of the goods Class Packing group Labels EmS Number 1 EmS Number 2

: 1993 : Flammable liquid, n.o.s. (Methanol) : 3 : III : 3 : 366 : 355 : Y344

: 1993 : FLAMMABLE LIQUID, N.O.S. (Methanol) : 3 : III : 3 : F-E : S-E

RID UN number Description of the goods Class Packing group 24642.3 / 000000008861

: 1993 : FLAMMABLE LIQUID, N.O.S. (Methanol) : 3 : III Page 7 / 9

Material Safety Data Sheet

Uniquat 10-80 HQ
Version 2.0 Classification Code Hazard identification No Labels Revision Date 2012.03.07 : F1 : 30 : 3 Print Date 2013.01.02

SECTION 15. REGULATORY INFORMATION OSHA Hazards WHMIS Classification : Flammable liquid, Irritant : D2B Toxic Material Causing Other Toxic Effects B2 Flammable liquid : All components of this product are listed on the EPA TSCA 8(b) inventory list. : Fire Hazard Acute Health Hazard

TSCA Status SARA 311/312 Hazards

EPCRA - EMERGENCY PLANNING COMMUNITY RIGHT - TO - KNOW SARA 302 Components : SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.

SARA 313 Components

: Methanol

67-56-1

US State Regulations Massachusetts Right To Know Components Pennsylvania Right To Know Components New Jersey Right To Know Components California Prop. 65 Components : Methanol Listed : Methanol Listed : Methanol Listed 67-56-1

67-56-1

67-56-1

: WARNING! This product contains a chemical known to the State of California to cause cancer. WARNING! This product contains a chemical known to the State of California to cause birth defects or other reproductive harm.

This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR. SECTION 16. OTHER INFORMATION Further information 24642.3 / 000000008861 Page 8 / 9

Material Safety Data Sheet

Uniquat 10-80 HQ
Version 2.0 HMIS Classification Revision Date 2012.03.07 : Health hazard: 3 Flammability: 2 Reactivity: 0 Print Date 2013.01.02

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportat ion, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Prepared by: : Product Safety Americas Email: regcomamer@lonza.com

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