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JEE Main 2013 [1]

Part - B
61. Which of the following represents the correct order of
increasing first ionization enthalpy Ca Ba S Se , , , and
Ar ?
(1) Ba Ca Se S Ar < < < <
(2) Ca Ba S Se Ar < < < <
(3) Ca Se Ba Se Ar < < < <
(4) S Se Ca Ba Ar < < < <
Ans: [1]
62. A gaseous hydrocarbon gives upon combustion 0.72
g. of water and 3.08 g of CO
2
. The empirical formula
of the Hydrocarbon is
(1) C H
6 5
(2) C H
7 8
(3) C H
2 4
(4) C H
3 4
Ans: [2]
63. The rate of a reaction doubles when its temperature
changes form 300 K to 310 K. Activation energy of
such a rection will be:
(R = 8.314 JK
1
mol
1
and log 2 = 0.301)
(1) 585
1
. kJ mol

(2) 605
1
. kJ mol

(3) 536
1
. kJ mol

(4) 486
1
. kJ mol

Ans: [3]
64. The gas leaked from a strong tank of the Union
Carbide plant in Bhopal gas tragedy was:
(1) Ammonia (2) Phosgene
(3) Methylsocyanate (4) Methylamine
Ans: [3]
65. An organic compound Aupon reactingwith NH
3
gives
B. On heating, B gives C. Cin presence of KOHreacts
with Br
2
to give CH CH NH
3 2 2
. A is
(1)
CH CH COOH
CH
3
3

|
(2) CH CH COOH
3 2
(3) CH COOH
3
(4) CH CH CH COOH
3 2 2
Ans: [2]
66. Compound (A), C H Br
8 9
gives a white precipitate
when warmed with alcoholic AgNO
3
. Oxidation of
(A) gives an acid (B), C H O
8 6 4
. (B) easily forms an-
hydride on heating. Identify the compound (A)
(1)
CH
2
Br
CH
3
(2)
CH
2
Br
CH
3
(3)
CH
2
Br
CH
3
(4)
C
2
H
5
Br
Ans: [2]
67. Acompound with molecular mass 180 is acylated with
CH COCl
3
to get a compound with molecular mass
390. The number of amino groups present per mol-
ecule of the former compound is
(1) 4 (2) 6
(3) 2 (4) 5
Ans: [4]
68. Which one of the following molecules is expected to
exhibit diamagnetic behaviour?
(1) O
2
(2) S
2
(3) C
2
(4) N
2
Ans: [3, 4]
69. In which of the following pairs of molecules/ions, both
the species are not likely to exist?
(1) H He
2
2
2
+
, (2) H He
2 2
2 +
,
(3) H He
2 2
2 +
, (4) H He
2 2
2
,
Ans: [1]
70. Which of the following complex species is not expected
to exhibit optical isomerism?
(1)
Co NH Cl
3
3
3
b g (2) Co en NH Cl ( )
3
2
2
b g
+
(3) Co en ( )
3
3+
(4) Co en Cl ( )
2 2
+
Ans: [1]
JEE Main 2013 [2]
71. The coagulating power of electrolytes having ions
Na Al
+ +
,
3
and Ba
2+
for arsenic sulphide sol in-
creases in the order :
(1) Ba Na Al
2 3 + + +
< < (2) Al Na Ba
3 2 + + +
< <
(3) Al Ba Na
3 2 + + +
< < (4) Na Ba Al
+ + +
< <
2 3
Ans: [4]
72. Consider the following reaction :
x MnO yC O zH
4 2 4
2 +
+ +
x Mn yCO H O
z 2
2 2 2
2
+
+ +
The values of x, y and z in the reaction are, respec-
tively:
(1) 2, 5 and 16 (2) 5, 2 and 8
(3) 5, 2 and 16 (4) 2, 5 and 8
Ans: [1]
73. Which of the following exists as covalent crystals in
the solid state?
(1) Sulphur (2) Phosphorus
(3) Iodine (4) Silicon
Ans: [4]
74. A solution of () 1 chloro-1-phenylethane in
toluene racemises slowly in the presence of a small
amount SbCl
5
due to the formation of
(1) carbocation (2) free radical
(3) carbanion (4) carbene
Ans: [1]
75. An unknown alcohol is treated with eh "Lucas reagent"
to determine whether the alcohol is primary, second-
ary or tertiary. Which alcohol reacts fastest and by what
mechanism:
(1) secondary alcohol by S
N
2
(2) tertiary alcohol by S
N
2
(3) secondary alcohol by S
N
1
(4) tertiary alcohol by S
N
1
Ans: [4]
76. How may litres of water must be added to 1 litre of an
aqueous solution HCl with a pH of 1 to create an aque-
ous solution with pH of 2?
(1) 2.0 L (2) 9.0 L
(3) 0.1 L (4) 0.9 L
Ans: [2]
77. The molarity of a solution obtained by mixing 750 mL
of 0.5 (M) HCl with 250 mL of 2 (M) HCl will be
(1) 1.75 M (2) 0.975 M
(3) 0.875 M (4) 1.00 M
Ans: [3]
78. A piston filled with 0.04 mol of an ideal gas expands
reversibly from 50.0 mL of 375 mL at a constant tem-
perature of 37 0 . C . As it does so, it absorbs 208 J of
heat. The values of q and w for the process will be:
(R = 8.314 J / mol K)(ln 7.5 = 2.01)
(1) q J w J = = + 208 208 ,
(2) q J w J = + = + 208 208 ,
(3) q J w J = + = 208 208 ,
(4) q J w J = = 208 208 ,
Ans: [3]
79. Experimentally it was found that a metal oxide has for-
mula M O
0 98 .
. Metal M, is present as M
2+
and M
3+
in
its oxide. Fraction of the metal which exists as
M
3+
would be :
(1) 6.05 % (2) 5.08 %
(3) 7.01 % (4) 4.08 %
Ans: [4]
80. For gaseous state, if most probable speed is dentoed
by C*, average speed by C and mean s2quare speed
by C, then for a large number of molecules the rations
of these speeds are:
(1) C C C
*
: : : . : . =1 1128 1225
(2) C C C
*
: : : . : . =1 1228 1128
(3) C C C
*
: : . : . : =1225 1128 1
(4) C C C
*
: : . : . : =1128 1225 1
Ans: [1]
81. Arragne the following compound in order of decreas-
ing acidity:
(1) III I II IV > > > (2) IV III I II > > >
(3) II IV I III > > > (4) I II III IV > > >
Ans: [1]
JEE Main 2013 [3]
82. The order of stability of the following carbocations:
is
(1) I II III > > (2) III I II > >
(3) III II I > > (4) II III I > >
Ans: [2]
83. The first ionisation potential of Na is 5.1 eV. The value
of electron gain enthalpy of Na
+
will be
(1) 102 . eV (2) +255 . eV
(3) 255 . eV (4) 51 . eV
Ans: [4]
84. For successive members of the first rowtransition ele-
ments are listed below with atomic numbers. Which
one of themis expected to have the highest E
M M
3 2
0
+ +
/
value ?
(1) Fe Z = 26 b g (2) Co Z = 27 b g
(3) Cr Z = 24 b g (4) Mn Z = 24 b g
Ans: [2]
85. Stability of the species Li Li
2 2
,

and Li
2
+
increases in
the order of
(1) Li Li Li
2 2 2
< <
+
(2) Li Li Li
2 2 2
+
< <
(3) Li Li Li
2 2 2
< <
+
(4) Li Li Li
2 2 2
+
< <
Ans: [4]
86. Energy of an electron is given by
E J
Z
n
=
F
H
G
I
K
J

2178 10
18
2
2
.
. Wavelength of light
required to excite an electron in an hydrogen atomform
level n = 1 to n = 2 will be:
( h Js =

662 10
34
. and c ms =

30 10
8 1
. )
(1) 6500 10
7
.

m (2) 8500 10
7
.

m
(3) 1214 10
7
.

m (4) 2816 10
7
.

m
Ans: [3]
87. Synthesis of each molecule of glucose in photosynthe-
sis involves:
(1) 8 molecules of ATP
(2) 6 molecules of ATP
(3) 18 molecules of ATP
(4) 10 molecules of ATP
Ans: [3]
88. Which of the following is the wrong statement?
(1) Ozone is violet - black in solid state
(2) Ozone is diamagnetic gas
(3) ONCl and ONO

are not isoelectronic


(4) O
3
molecule is bent
Ans: [ All given statements are correct]
89. Which of the following arrangements does not repre-
sent the correct order of the property stated against is
(1) Co Fe Cr Sc
3 3 3 3 + + + +
< < < : stability in aqueous
solution
(2) Se Ti Cr Mn < < < : number of oxidation states
(3) V Cr Mn Fe
2 2 2 2 + + + +
< < < paramagnetic behav-
iour
(4) Ni Co Fe Mn
2 2 2 2 + + + +
< < < : ionic size
Ans: [3]
90. Give
E V
Cr Cr
3
0
0 74 + =
/
. ;
E V
MnO Mn
4
2
0
151 + =
/
.
E V
Cr O Cr
2 7
2 3
0
133
+
=
/
.
; E V
Cl Cl /
. =
0
136
Based on the data given above, strongest oxidising
agent will be :
(1) Mn
2+
(2) MnO
4

(3) Cl

(4) Cr
3+
Ans: [2]

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