HI CC TRNG CHUYN

KHU VC DUYN HI BC B
HI THI HC SINH GII DUYN HI BC B
LN TH IV
THI CHNH THC
Mn: HA HC 10
Ngy thi: 23/4/2011
Thi gian lm bi: 180 pht.
(khng k thi gian giao )
Ch k gim th 1:
...............................
Ch k gim th 2:
...............................
( thi ny c 3 trang)
Cu 1:(2 im):
1. Tnh nng lng ca electron trng thi c bn trong cc nguyn t v ion
sau: H, He
+
. (Cho Z
H
= 1; Z
He
= 2).
2. Tnh nng lng ion ha ca H v nng lng ion ha th 2 ca He.
3. Mi phn t XY
2
c tng cc ht proton, ntron, electron bng 178; trong
, s ht mang in nhiu hn s ht khng mang in l 54, s ht mang in ca
X t hn s ht mang in ca Y l 12.
a, Hy xc nh k hiu ho hc ca X,Y v cng thc phn t XY
2
.
b, Vit cu hnh electron ca nguyn t X,Y v xc nh cc s lng t ca
electron cui cng c in vo.
Cu 2:(2 im):
Vit cng thc Lewis, d on dng hnh hc ca cc phn t v ion sau (c
gii thch) v trng thi lai ha ca nguyn t trung tm?
SO
2
; SO
3
; SO
4
2-
; SF
4
; SCN
-
Cu 3:(2 im):
1. Cho gi tr ca bin thin entanpi v bin thin entropi chun 300K v 1200K
ca phn ng:
CH
4
(kh) + H
2
O (kh)


CO ( kh) + 3H
2
( kh)
Bit:
H
0

(KJ/mol) S
0

J/K.mol
300
0
K - 41,16 - 42,4
1200
0
K -32,93 -29,6
a) Hi phn ng t din bin s theo chiu no 300K v 1200K?
b) Tnh hng s cn bng ca phn ng 300K
2. Nng lng mng li ca mt tinh th c th hiu l nng lng cn thit
tch nhng ht trong tinh th ra cch xa nhau nhng khong v cc.
Hy thit lp chu trnh tnh nng lng mng li tinh th CaCl
2
bit:
Sinh nhit ca CaCl
2
: H
1
= -795 kJ/ mol
Nhit nguyn t ho ca Ca: H
2
= 192 kJ / mol
Nng lng ion ho (I
1
+ I
2
) ca Ca = 1745 kJ/ mol
Nng lng phn ly lin kt Cl
2
: H
3
= 243 kJ/ mol
i lc vi electron ca Cl: A = -364 kJ/ mol
Cu 4:(2 im):
1.Tnh pH ca dung dch A gm KCN 0,120 M; NH
3
0,150 M v KOH 5,00.10
-3
M.
Cho bit pK
a
ca HCN l 9,35; ca NH
4
+

l 9,24.
2. C dung dch A cha hn hp 2 mui MgCl
2
(10
-3
M) v FeCl
3
(10
-3
M)
Cho dung dch NaOH vo dung dch A.
a) Kt ta no to ra trc, v sao?
b) Tm pH thch hp tch mt trong 2 ion Mg
2+
hoc Fe
3+
ra khi dung dch.
Bit rng nu ion c nng = 10
6
M th coi nh c tch ht.
( Cho tich s tan cua Fe(OH)
3
va Mg(OH)
2
ln lt la: 10
39
va 10
11
)
Cu 5:(2 im):
Mt pin in ha c to bi 2 in cc. in cc th nht l tm ng nhng
vo dung Cu(NO
3
)
2
0,8M. in cc 2 l mt a Pt nhng vo dung dch cha hn
hp Fe
2+
v Fe
3+
(trong [Fe
3+
] = 4[Fe
2+
]. Th in cc chun ca Cu
2+
/ Cu v
Fe
3+
/Fe
2+
ln lt l 0,34V v 0,77V.
1. Xc nh in cc dng, in cc m. Tnh sut in ng khi pin bt u lm
vic.
2. Tnh t l
] [
] [
2
3
+
+
Fe
Fe
khi pin ht in (coi th tch ca dung dch Cu(NO
3
)
2
0,8M l
rt ln).
Cu 6:(2 im):
Cho s bin ha:
A FeCl
3

X Y

Z
T M N
Hon thnh phng trnh ha hc khc nhau trong s bin ha trn. Bit: X l
mt n cht, Y, Z, M l cc mui c oxi ca X, T l mui khng cha oxi ca X, N
l axit khng bn ca X.
Cu 7:(2 im):
Cho 6,00 gam mu cht cha Fe
3
O
4
, Fe
2
O
3
v cc tp cht tr. Ha tan mu
vo lng d dung dch KI trong mi trng axit (kh tt c Fe
3+
thnh Fe
2+
) to
ra dung dch A. Pha long dung dch A n th tch 50ml. Lng I
2
c trong 10ml
dung dch A phn ng va vi 5,50 ml dung dch Na
2
S
2
O
3
1,00M (sinh ra
2
4 6
S O

). Ly 25 ml mu dung dch A khc, chit tch I
2
, lng Fe
2+
trong dung

(5)
(6)
(1)
(3)
(7)
(4)
(2)
(8)
(10)
(11) (12)
(9)
dch cn li phn ng va vi 3,20 ml dung dch KMnO
4
1,00M trong dung
dch H
2
SO
4
.
1. Vit phng trnh ha hc ca cc phn ng xy ra (dng phng trnh ion thu
gn).
2. Tnh phn trm khi lng Fe
3
O
4
v Fe
2
O
3
trong mu ban u?
Cu 8:(2 im):
Nguyn t ca mt nguyn t X trong electron cui cng c 4 s lng t
n = 3, l = 1, m = 0, s = -
1) Xc nh tn nguyn t X.
2) Ha tan 5,91 hn hp NaX v KBr vo 100ml dung dch hn hp Cu(NO
3
)
2
0,1M v AgNO
3
cha bit nng , thu c kt ta A v dung dch B.
Trong dung dch B, nng % ca NaNO
3
v KNO
3
tng ng theo t l 3,4 :
3,03. Cho ming km vo dung dch B, sau khi phn ng xong ly ming km ra
khi dung dch, thy khi lng tng 1,1225g.
a) Tnh lng kt ta ca A?
b) Tnh C
M
ca AgNO
3
trong dung dch hn hp.
Cu 9:(2 im):
1. Mt cht thi phng x c chu k bn hy l 200 nm c cha trong thng kn
v chn di t. Phi trong thi gian l bao nhiu tc phn r gim t 6,5.10
12
nguyn t/pht xung cn 3.10
-3
nguyn t/pht.
2. Hon thnh cc phn ng ht nhn sau:
a)
12
Mg
26
+ ...?
10
Ne
23
+
2
He
4
b)
9
F
19
+
1
H
1
...? +
2
He
4
c)
92
U
235
+
0
n
1
3(
0
n
1
) +...? +
57
La
146
d)
1
H
2
+ ...? 2
2
He
4
+
0
n
1
Cu 10:(2 im):
27
0
C, 1atm N
2
O
4
phn hu theo phn ng : N
2
O
4 (kh)
2NO
2

(kh)
vi phn hu l 20%
1. Tnh hng s cn bng K
p
.
2. Tnh phn hu mt mu N
2
O
4 (kh)
c khi lng 69 gam, cha trong mt
bnh c th tch 20 (lt) 27
0
C
------------------------- Ht ---------------------------
(Th sinh c s dng bng HTTH-Cn b coi thi khng gii thch g thm)
H v tn th sinh: S bo danh:
HI CC TRNG CHUYN
KHU VC DUYN HI BC B
HI THI HC SINH GII DUYN HI BC B
LN TH IV
THI CHNH THC
Mn: HA HC 10
Ngy thi: 23/4/2011
Thi gian lm bi: 180 pht.
(khng k thi gian giao )
CU V P N IM
1 1. Tnh nng lng ca electron trng thi c bn trong cc
nguyn t v ion sau: H, He
+
. (Cho Z
H
= 1; Z
He
= 2).
2. Tnh nng lng ion ha ca H v nng lng ion ha th 2
ca He.
3. Mi phn t XY
2
c tng cc ht proton, ntron, electron
bng 178; trong , s ht mang in nhiu hn s ht khng mang
in l 54, s ht mang in ca X t hn s ht mang in ca Y l
12.
a , Hy xc nh k hiu ho hc ca X,Y v XY
2
.
b , Vit cu hnh electron ca nguyn t X,Y v xc nh cc
s lng t ca electron cui cng c in vo.
Hng dn
1. Nng lng ca electron trong h mt ht nhn v mt electron:
E
n
= (eV)
trng thi c bn: n = 1.
* Vi H: E
1(H)
= -13,6eV;
* Vi He
+
: E
1(He
+
)
= - 54,4 eV;
2. Nng lng ion ha ca hidro l nng lng ti thiu bt e ra
khi nguyn t hoc ion, tc l a e t trng thi c bn ra xa v cng
(khng truyn thm ng nng cho e). D thy: I
1(H)
=13,6eV; I
2(He)
= 54,4
eV.
a , K hiu s n v in tch ht nhn ca X l Zx , Y l Zy ; s ntron
(ht khng mang in) ca X l Nx , Y l Ny . Vi XY
2
, ta c cc
phng trnh:

2 Zx + 4 Zy + Nx + 2 Ny = 178 (1)
2 Zx + 4 Zy Nx 2 Ny = 54 (2)
0.5
0,25
0,75
4 Zy 2 Zx = 12 (3)
Zy = 16 ; Zx = 26
Vy X l st, Y l lu hunh. XY
2
l FeS
2
.
b, Cu hnh electron: Fe : 1s
2
2s
2
2p
6
3s
2
3p
6
3d
6
4s
2
;
S : 1s
2
2s
2
2p
6
3s
2
3p
4

B 4 s lng t cui ca X: n = 3; l = 2; ml =-2; ms= -1/2.
B 4 s lng t cui ca X: n = 3; l = 1; ml =-1; ms= -1/2.
0,25
0,25
2 Vit cng thc Lewis, d on dng hnh hc ca cc phn t v ion
sau (c gii thch) v trng thi lai ha ca nguyn t trung tm?
SO
2
; SO
3
; SO
4
2-
; SF
4
; SCN
-
Hng dn
Phn t Cng thc Lewis Cng thc
cu trc
Dng lai ha
ca NTTT
Dng hnh hc ca phn t
O
S
O
AX
2
E sp
2
Gp khc
O
S
O
O
AX
3
sp
2
Tam gic u
O
S
O
O
O
2-
AX
4
sp
3
T din
F
S
F
F F
AX
4
E sp
3
d Ci bp bnh
S C N
AX
2
Sp ng thng
Mi
ng
0,1
im
3 1.Cho gi tr ca bin thin entanpi v bin thin entropi chun
300
0
K v 1200
0
K ca phn ng:
CH
4
(kh) + H
2
O (kh)


CO ( kh) + 3H
2
( kh)
Bit l
H
0

(KJ/mol) S
0

J/K.mol
300
0
K - 41,16 - 42,4
1200
0
K -32,93 -29,6
a) Hi phn ng t din bin s theo chiu no 300
0
K v
1200
0
K?
b) Tnh hng s cn bng ca phn ng 300
0
K
2. Nng lng mng li ca mt tinh th c th hiu l nng lng
cn thit tch nhng ht trong tinh th ra cch xa nhau
nhng khong v cc.
Hy thit lp chu trnh tnh nng lng mng li tinh th
CaCl
2
bit:
Sinh nhit ca CaCl
2
: H
1
= -795 kJ/ mol
Nhit nguyn t ho ca Ca: H
2
= 192 kJ / mol
Nng lng ion ho (I
1
+ I
2
) ca Ca = 1745 kJ/ mol
Nng lng phn ly lin kt Cl
2
: H
3
= 243 kJ/ mol
i lc vi electron ca Cl: A = -364 kJ/ mol
Hng dn
1.
a) Da vo biu thc: G
0
= H
0
- TS
0
300
0
K ; G
0
300
= (- 41160) - [ 300.(- 42,4)] = -28440J = -28,44
kJ
1200
0
K ; G
0
1200
= (- 32930) - [ 1200.(- 29,6)] = 2590 = 2,59 kJ
G
0
300
< 0, phn ng cho t xy ra 300
0
K theo chiu t tri
sang phi.
G
0
1200
> 0, phn ng t din bin theo chiu ngc li 1200
0
K
b) + Tnh hng s cn bng ca phn ng 300
0
K
G
0
= -2,303RT lgK
(-28440) = (-2,303).8,314. 300.lgK
lgK = 28440/ 2,303.8,314.300 = 4,95
K = 10
4,95
2. Thit lp chu trnh
Chu trnh Born - Haber
Ca(tt) + Cl
2
(k) CaCl
2
(tt)
Ca (k) 2Cl (k)
Ca
2+
(k) + 2Cl
-
(k)
Ta c:
U
ml
= H
2
+ I
1
+ I
2
+ H
3
+ 2A - H
1
U
ml
= 192 + 1745 + 243 (2 x 364) - (-795)
U
ml
= 2247 (kJ/.mol)
0,5
0,5
0,5
0,
5
H
1
H
2
H
3
I
1
+I
2
2A
-U
ml
4 1.Tnh pH ca dung dch A gm KCN 0,120 M; NH
3
0,150 M v
KOH 5,00.10
-3
M.Cho bit pK
a
ca HCN l 9,35; ca NH
4
+

l
9,24
2.C dung dch A cha hn hp 2 mui MgCl
2
(10
-3
M) v FeCl
3
(10
-
3
M)
Cho dung dch NaOH vo dung dch A.
a) Kt ta no to ra trc, v sao?
b) Tm pH thch hp tch mt trong 2 ion Mg
2+
hoc Fe
3+
ra
khi dung dch.
Bit rng nu ion c nng = 10
6
M th coi nh c tch
ht.
( Cho tich s tan cua Fe(OH)
3
va Mg(OH)
2
ln lt la: 10
39
va 10
11
)
Hng dn
1) Tnh pH ca dung dch:
CN
-
+ H
2
O HCN + OH
-
K
b1
= 10
- 4,65
NH
3
+ H
2
O NH
4
+
+ OH
-
K
b2
= 10
- 4,76
KOH -> K
+
+ OH
-
H
2
O H
+
+ OH
-
[OH
-
] = C
KOH
+ [HCN] + [NH
4
+
] + [H
+
]
t [OH
-
] = x
x = 5.10
-3
+ K
b1
[CN]/x + K
b2
[NH
3
]/x + K
H2O
/x
x
2
- 5.10
-3
x - (K
b1
[CN
-
] + K
b2
[NH
3
] + K
H2O
) = 0
Tnh gn ng coi [CN
-
] bng C
CN
- = 0,12M ; [NH
3
] = C
NH3
= 0,15 M .
Ta c: x
2
- 5.10
-3
. x - 5,29 . 10
-6
= 0 -> x = [OH
-
] = 5,9.10
-3
M.
Kim li [HCN] / [CN
-
] = 10
-4,65
/ 5,9.10
-3
= 3,8.10
-3
-> [HCN] << [CN
-
]
[NH
4
+
] / [NH
3
] = 10
-4,76
/ 5,9.10
-3
= 2,9.10
-3
-> [NH
4
+
] << [NH
3
]
Vy cch gii gn ng trn c th chp nhn -> pH = 11,77.
2) MgCl
2
Mg
2+
+ 2Cl

v Mg
2+
+ 2OH

Mg(OH)
2
(1)
FeCl
3
Fe
3+
+ 3Cl

v Fe
3+
+ 3OH

Fe(OH)
3
(2)
a) to Fe(OH)
3
th [OH

]
3
3
39
10
10

= 10
-12
M (I)
to Mg(OH)
2
[OH

]
3
11
10
10

= 10
-4
M (II)
So snh (I) < (II) thy Fe(OH)
3
to ra trc.
b) to Mg(OH)
2
: [OH

] = 10
-4
[H
+
] = 10
-10
pH = 10 (nu
pH < 10 th khng )
hon ton Fe(OH)
3
: [Fe
3+
] 10
-6
M [OH

]
3
> 10
-33
[H
+
]
<10
-3
pH > 3
2 im
0,5
0,5
0,5
0,5
Vy tch Fe
3+
ra khi dd th: 3 < pH < 10
5 Mt pin in ha c to bi 2 in cc. in cc th nht l
tm ng nhng vo dung Cu(NO
3
)
2
0,8M. in cc 2 l mt a Pt
nhng vo dung dch cha hn hp Fe
2+
v Fe
3+
(trong [Fe
3+
] =
4[Fe
2+
]. Th in cc chun ca Cu
2+
/ Cu v Fe
3+
/Fe
2+
ln lt l
0,34V v 0,77V.
1. Xc nh in cc dng, in cc m. Tnh sut in ng khi
pin bt u lm vic.
2. Tnh t l
] [
] [
2
3
+
+
Fe
Fe
khi pin ht in (coi th tch ca dung dch
Cu(NO
3
)
2
0,8M l rt ln).
Hng dn
1.E(Fe
3+
/Fe
2+
) = 0,77 + 0,059/1 . lg4 = 0,8055 V
E(Cu
2+
/Cu) = 0,34 + 0,059/2 . lg0,8 = 0,3371 V
Vy in cc dng l in cc Pt; in cc m l in cc Cu
E
pin
= 0,8055 - 0,3371 = 0,4684 V
2. Pin ht in tc l E
pin
= 0. Khi E (Cu
2+
/Cu) = E (Fe
3+
/Fe
2+
)
V th tch dung dch Cu(NO
3
)
2
rt ln => nng Cu
2+
thay i khng
ng k
=> E (Cu
2+
/Cu)=0,3371 V
E (Fe
3+
/Fe
2+
) = 0,77 + 0,059/1 . lg ([Fe
3+
]/[Fe
2+
]) = 0,3371
=> [Fe
3+
]/[Fe
2+
] = 4,5995.10
-8
.
2 im
1,0
1,0
6
Cho s bin ha :
A FeCl
3

X Y

Z
T M N
Hon thnh phng trnh ha hc khc nhau trong s bin ha
trn. Bit: X l mt n cht, Y, Z, M l cc mui c oxi ca X, T l
mui khng cha oxi ca X, N l axit khng bn ca X.

(5)
(6)
(1)
(3)
(7)
(4)
(2)
(8)
(10)
(11) (12)
(9)
Hng dn: S bin ha tha mn l:
HCl FeCl
3

X KClO
3
KClO
4
KCl KClO HClO
C cc phng trnh phn ng:
H
2
+ Cl
2
2HCl (1)
(X) (A)
6HCl + Fe
2
O
3
2FeCl
3
+ 3H
2
O (2)
(A) (Fe
3
O
4
,)
2Fe + 3Cl
2
2FeCl
3
(3)
3Cl
2
+ 6KOH 5KCl + KClO
3
+ 3H
2
O (4)
(Y)
6HCl + KClO
3
3Cl
2
+ KCl + 3H
2
O (5)
Cl
2
+ 2KOH KCl + KClO + H
2
O (6)
(T)
2KClO
3
2KCl + 3O
2
(7)
KCl + 3H
2
O KClO
3
+ 3H
2
(8)
4KClO
3
3KClO
4
+ KCl (9)
KClO
4
KCl + 2O
2
(10)
KCl + H
2
O KClO + H
2
(11)
(M)
KClO + CO
2
+ H
2
O HClO + NaHCO
3
(12)
(N)
7 Cho 6,00 gam mu cht cha Fe
3
O
4
, Fe
2
O
3
v cc tp cht tr.
Ha tan mu vo lng d dung dch KI trong mi trng axit
(kh tt c Fe
3+
thnh Fe
2+
) to ra dung dch A. Pha long dung
dch A n th tch 50ml. Lng I
2
c trong 10ml dung dch A
phn ng va vi 5,50 ml dung dch Na
2
S
2
O
3
1,00M (sinh ra
2
4 6
S O

). Ly 25 ml mu dung dch A khc, chit tch I
2
, lng Fe
2+
trong dung dch cn li phn ng va vi 3,20 ml dung dch
KMnO
4
1,00M trong dung dch H
2
SO
4
.
2 im
t
o
(5)
(6)
(1)
(3)
(7)
(4)
(2)
(8)
(10)
(11) (12)
t
o
p dung dch(80
o
C)
Khng c mnx
300
o
p dung dch
Khng c mnx
t
o
cao
(9)
1. Vit phng trnh ha hc ca cc phn ng xy ra (dng phng
trnh ion thu gn).
2. Tnh phn trm khi lng Fe
3
O
4
v Fe
2
O
3
trong mu ban u?
Hng dn
1.

3 2
Fe O 8H 2Fe Fe 4H O
3 4 2
+ + +
+ + +
(1)
3
Fe O 6H 2Fe 3H O
2 3 2
+ +
+ +
(2)
3 2
2Fe 3I 2Fe I
3
+ +
+ +
(3)
2 2
2S O I S O 3I
2 3 3 4 6

+ +
(4)

2 3 2
5Fe MnO 8H 5Fe Mn 4H O
4 2
+ + + +
+ + + +
(5)
2.
Trong 25 ml:
2
4
3
Fe MnO
n 5n 5x3, 2x1x10
+

=0,016 (mol)
trong 10ml 2
Fe
n
+ = 6,4x10
-3
(mol)
T (3) v (4): 2
Fe
n
+ =
2
2 3
S O
n

= 5,5x1x10
-3
= 5,5x10
-3
(mol)
T (3): 3
Fe
n
+ = 2
Fe
n
+ =5,5x10
-3
(mol) =2(
3 4
Fe O
n
+
2 3
Fe O
n
)
C th xem Fe
3
O
4
nh hn hp Fe
2
O
3
.FeO
FeO
n
=
3 4
Fe O
n
= 6,4x10
-3
5,5x10
-3
= 9x10
-4
(mol)
2 3
Fe O
n
= 3
Fe
1
n
2
+

3 4
Fe O
n
=1,85x10
-3
(mol).
Trong 50 ml :
3 4
Fe O
n
=4,5x10
-3
(mol)
3 4
Fe O
m
=1,044 gam
% khi lng Fe
3
O
4
= 1,044/6 x 100% = 17,4%
2 3
Fe O
n
= 9,25x10
-3
(mol)
2 3
Fe O
m
=1,48 gam
% khi lng Fe
2
O
3
= 1,48/6 x 100% = 24,67%
1.0
0,25
0,25
0,5
8
Cu 8: Bai tp tng hp(2 )
Nguyn t ca mt nguyn t X trong electron cui cng c 4 s
lng t n = 3, l = 1, m = 0, s = -
2 im
1. Xc nh tn nguyn t X.
2. Ha tan 5,91 hn hp NaX v KBr vo 100ml dung dch hn hp
Cu(NO
3
)
2
0,1M v AgNO
3
cha bit nng , thu c kt ta A v
dung dch B.
Trong dung dch B, nng % ca NaNO
3
v KNO
3
tng ng theo
t l 3,4 : 3,03. Cho ming km vo dung dch B, sau khi phn ng xong
ly ming km ra khi dung dch, thy khi lng tng 1,1225g.
a, Tnh lng kt ta ca A?
B,Tnh C
M
ca AgNO
3
trong dung dch hn hp.
(cho Na = 23, N = 14, K = 39, Ag = 108, Br = 80, Zn = 65, Cu = 64)
Hng dn
1(0,75) Nguyn t ca nguyn t X c:
n = 3
l = 1
m = 0
s = -
Cu trc hnh e ca X : 1s
2
2s
2
2p
6
3s
2
3p
5
-> Z
x
= 17 X l clo
2(1,25).
a/ NaCl + AgNO
3
= AgCl + NaNO
3
KBr + AgNO
3
= AgBr + KNO
3
Khi cho Zn vo dd B, khi lng ming Zn tng, chng t AgNO
3
d.
Zn + 2AgNO
3
= Zn(NO
3
)
2
+ 2Ag
Zn + Cu(NO
3
)
2
= Zn(NO
3
)
2
+ Cu
NaCl : x mol
KBr : y mol
01 , 0
000 . 1
1 , 0 . 100
2
)

3
Cu(NO
n
mol
03 , 3
4 , 3

3
3
C%KNO
C%NaNO
->
03 , 3
4 , 3

3
3
KNO
NaNO
m
m
x y 75 , 0
03 , 3
4 , 3
>
101y
85x
(1)
58,5x + 119y = 5,91 (2)
0,75
0,25
electron cui cng phn lp 3p
electron ny l e th 5 ca phn lp 3p
Gii h pt (1), (2)

'

03 , 0
04 , 0
y
x
m
A
= 0,04 . 143,5 + 0,03 . 188 = 11,38g
b/ 1 mol Zn -> 2 mol Ag khi lng tng 151g
a mol Zn -> 151a
1 mol Zn -> 1 mol Cu khi lng gim 1g
0,01 mol -> 0,01g
151a 0,01 = 1,1225
a = 0,0075

AgNO
3
n
b
0,04 + 0,03 + 0,015 = 0,085 mol
M 85 , 0
100
1000
. 085 , 0
)

3
M(AgNO
C
0,5
0,5
9
1. Mt cht thi phng x c chu k bn hy l 200 nm c cha
trong thng kn v chn di t. phi trong thi gian l bao nhiu
tc phn r gim t 6,5.10
12
nguyn t/pht xung cn 3.10
-3
nguyn t/pht.
2. Hon thnh cc P ht nhn sau:
a)
12
Mg
26
+ ...?
10
Ne
23
+
2
He
4
b)
9
F
19
+
1
H
1
...? +
2
He
4
c)
92
U
235
+
0
n
1
3(
0
n
1
) +...? +
57
La
146
d)
1
H
2
+ ...? 2
2
He
4
+
0
n
1
Hng dn
1.
/ 00347 , 0
200
693 , 0 693 , 0
2 / 1

t
k
nm
Ap dung cng thc: ln
0
N
kt
N

ln
12
3
6, 5.10
0, 00347
3.10
t

t = 1,0176.10
4
nm hay 10.176 nm
2. T nh lut bo ton in tch v s khi cc ht cn thiu:

a.
0
n
1
b.
8
O
16
c.
35
Br
87
d.
3
Li
7
2 im
0,25

0,25
0,5
0,25x
4
10 27
0
C, 1atm N
2
O
4
phn hu theo phn ng :
N
2
O
4 (kh)
2NO
2

(kh)
vi phn hu l 20%
1. Tnh hng s cn bng K
p
.
2. Tnh phn hu mt mu N
2
O
4 (kh)
c khi lng 69 gam, cha
trong mt bnh c th tch 20 (lt) 27
0
C
Hng dn
1.Gi phn hu ca N
2
O
4
27
0
C, 1 atm l

, s mol ca N
2
O
4
ban
u l n
Phn ng: N
2
O
4 (k)
2NO
2

(k)
Ban u: n 0
Phn ly: n

2n

Cn bng n(1-

) 2n

Tng s mol hn hp lc cn bng: n = n(1+

)
Nn p sut ring phn ca cc kh trong hn hp lc cn bng:
P p
O N

1
1
4 2
;
P P
NO

1
2
2

4 2
2
2
O N
NO
P
P
P
K
=

,
_

,
_

+
P
P

1
1
1
2
2
= P
2
2
1
4

vi P = 1atm, = 20% hay = 0,2

K
P
= 1/6 atm

2.
4 2
O N
n
= 69/92 = 0,75mol
Gi phn hu ca N
2
O
4
trong iu kin mi l

Phn ng: N
2
O
4 (k
2NO
2

(k)
Ban u: 0,75 0
Phn ly: 0,75

1,5

Cn bng 0,75(1-

) 1,5

Tng s mol hn hp lc cn bng: n = 0,75(1+

)
2 im
1,0
1,0
p sut hn hp kh lc cn bng:

V
RT n
P
' '
'
=
20
300 . 082 , 0 ). 1 ( 75 , 0
'
+
= 0,9225(1+

)
K
P
= P
2 '
2 '
1
4

= 1/6
V K
P
= const nn: 6 / 1 ) 1 ( 9225 , 0 .
1
4
'
2 '
2 '
+

0,19