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ABSTRACT: Electric Arc Furnace Slag, which is highly crystalline and rich in iron content, does not find much
use as an additive in cements. For improving its cementitious properties, heat treatment was done. There was a
remarkable reduction in the iron content but the crystallinity was not much affected. Both untreated and treated
slag samples were then hydrated for 3,7,14 and 28 days. The pH of the pore water and the TGA/DTA curves
showed that the treated slag sample exhibited better hydraulic properties. The slag samples were then mixed with
30% Ground Granulated Blast Furnace Slag (GGBFS) and 50% Clinker for compressive strength measurements.
GGBFS was used to provide a reactive media for the slag to hydrate. It was seen that the 28-day strength of the
treated slag exceeded the corresponding strength of the control mix (50% GGBFS and 50% Clinker). This
substantiated the fact that the treated slag samples had better hydraulic properties compared to that of the
untreated slag.
Intensity (Counts)
900 W M - Merwinite
(Hitachi S3400N)-EDX (Thermo Noran 800 M
G - Gehlenite
NSS200). 700
G
1
M - Magnesioferrite
L M1W W L - Larnite
600 M
1
Analysis 400
300
1600 M
600
L
M
Position (2 Theta)
The untreated EAFS was seen to have high iron The compositional analysis (Table 1) showed that
content. Figure 3 shows the XRD pattern of the there was a substantial reduction in the weight
slag sample. From the phase analysis, it was seen percentage of iron oxide in the slag. From the
that a majority of the phase was contributed by analysis of the XRD patterns it was also obvious
wuestite (FeO). Here the iron is in the Fe2+ state that the wuestite phase of the untreated slag
and hence forms crystalline compounds. Traces reduced to a considerable extent.
of larnite (Ca2SiO4) were also seen. Table 1 Table 1: Composition of Clinker and Slag
samples
An Investigation into the use of Electric Arc Furnace Slag as… 180
Others untreated slag. This substantiates the phenomena
Sample CaO SiO2 Al2O3 MgO FeO MnO SO3 P2O5 TiO2
* of iron oxide reduction during heat treatment.
Untreated
EAFS
30.8 23.3 6.1 12 24.1 1.5 0.4 0.6 0.9 0.4 Hydration of the slag samples was done. The pH
Treated
of the pore water that gives the extent of
30.6 26.4 5.9 33.6 0.3 1.4 0.1 0.5 0.7 0.6
EAFS hydration of the sample was measured. Figure 7
shows that the pH of the untreated slag was less
* Cr2O3, V2O5 compared to that of the treated slag.
Clinker
Figure 5 shows the microstructure of the 15.0 EAFS (Treated)
untreated slag sample. A predominant presence of 14.5 EAFS (Untreated)
14.0
wuestite and magnesioferrite was seen, both of 13.5
which contributed to the high reflectivity of the 13.0
pH of pore water
12.5
12.0
observed to be Merwinite. Larnite was seen to 11.5
EAFS (Untreated)
EAFS (Treated)
9
8
Weight gain (%)
28 DAY
OPC % (Including
50 50 50
Gypsum)
3 DAY
GGBFS % 50 30 30
EAFS % 0 20 20
Std. Consistency 29.5 26.5 26.5
0 200 400 600 800 1000
Setting Time (min)
Temperature (degree celcius)
Initial 120 130 120
Fig. 10: DTA curve of hydrated untreated EAFS Final 210 220 220
Compressive
One of the striking features of the steel slag Strength (Mpa)
@27°C
incorporation was the noticeable reduction in
water demand for the standard consistency. No 1-Day 14.1 13.8 14.1
significant change in setting time was observed 3-Day 32.2 28 31
with respect to control sample. Though there was 7-Day 47 45 44.8
a marginal reduction in the early age strength up 28-Day 58.6 58 61
to 7 days, the strength became equal at 28-days.
The sample containing treated EAFS superseded
the control mix at 28 days. This is due to the 4. CONCLUSIONS
presence of the dicalcium slicate, which shows From the experiments conducted, it is clearly
later strength. visible that the treated EAFS was more hydraulic
than the untreated slag. The increase of the
hydraulicity of the treated slag may be due to the
reduction in iron, which is one of the major
hindrances to the reactivity of the slag. The
An Investigation into the use of Electric Arc Furnace Slag as… 182
refinement of the crystalline phase enhanced the REFERENCES
formation of dicalcium silicate that contributed to
the strength after 28 days of hydration. One of [1] D. Venkateswaran, D. Sharma, L. Muhmood,
S.Vitta, “Treatment and Characterization of
the striking features of the steel slag
Electric Arc Furnace Slag for its Effective
incorporation was the noticeable reduction in Utilization in Cementitious Products”,
water demand for the standard consistency. The Proceedings of the Second Global Slag
study confirms that EAFS when suitably treated Conference, Bangkok, November 2006.
could be used as an additive in cements. [2] V.S. Ramachandran, “Applications of Differential
Thermal Analysis in Cement Chemistry”, 1969,
Chemical Publishing Company, New York.