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1.
2.
tc2
2.1. Tnh nng sut thit b ......................................................................................... 5
2.2. Tnh lng kh tun hon cn thit ...................................................................... 6
2.3. Tnh ton phn b p sut ca cc cu t trong hn hp nguyn liu v thnh
phn kh tun hon. ...................................................................................................... 7
3.
Page 1
Tnh ton cn bng vt cht v cn bng nhit lng ca cng ngh CCR
1. Cc s liu ban u
Cng sut
Nhit
: 470 5300C.
Tc th tch
: 1,5 h-1.
p sut
T l H2/ RH
: 2,5 kmol.
293
277
3290K
50
38
12
0,7288
3480K
3850K
% khi lng
4280K
4530K
(2)
(5)
Page 2
Tnh ton cn bng vt cht v cn bng nhit lng ca cng ngh CCR
(6)
Trong :
PP : p sut ca parafin [pa].
PA: p sut ca cc hp cht thm. [pa]
PH2: p sut ca hydro [pa]
PN: p sut ca naphten [pa].
P : p sut ca h [pa].
NN, NP: Ln lt l phn mol ca hydrocacbon naphten v parafin trong nguyn
liu b chuyn ho (kmol/ kmol).
VR: i lng nghch o ca tc np liu theo mol (kg xc tc/h.nguyn liu)
K1: Hng s tc phn ng (1) c xc nh bng th (kg xc
tc/h.pa.nguyn liu).
K2: Hng s tc phn ng (2) c xc nh bng th kg xc tc/h.nguyn
liu.
K3: Hng s tc phn ng (3) c xc nh bng th kg xc tc/h.nguyn
liu.
KP1, KP2 ln lt l hng s cn bng ha hc ca phn ng (1), (2) c xc
nh theo phng trnh sau :
KP1 = 9,813 . 1012 . e46,15 - 25600/T
KP2 = 98,1-1 . 10-3 . e(4450/T)
- 7,12
H2
CH4
C2H6
C3H8
C4H10
C5H12
% mol
86
Page 3
Tnh ton cn bng vt cht v cn bng nhit lng ca cng ngh CCR
Me . yi = Mi . yi
Trong :
Me : khi lng phn t trung bnh ca nguyn liu .
Mi: khi lng phn t trung bnh ca cc hydrocacbon trong nguyn liu .
yi, yi ln lt l phn khi lng v phn mol ca cu t i trong nguyn liu
Mt khc th
M = 0,4.T50 - 45
Trong :
T50 l nhit si ti 50% th tch ca nguyn liu .
Vy ta tnh c Me = 0,4 x 385 - 45 = 109 .
Bng 3: Khi lng ca cc hydrocacbon trong nguyn liu.
Hydrocacbon
Cng thc ha hc
Parafin (P)
CnH2n +2
Mp = 14n + 2
Naphaten (N)
CnH2n
MN = 14n
Aromatic (A)
CnH2n - 6
MA = 14n - 6
Me =
YA
MA
1
YN +
MN
YP
MP
Trong :
YP,YN,YA ln lt l phn khi lng ca cc hydrocacbon trong nguyn liu
MA MN , MP l khi lng phn t ca cc hydrocacbon: Aromatic, naphten v
parafin trong nguyn liu :
Me =
YA
+
14n - 6
1
YN
YP
+
14n
14n+2
Page 4
Tnh ton cn bng vt cht v cn bng nhit lng ca cng ngh CCR
Bin i ta c phng trnh sau :
= 14 x 7,77 = 108,78,
Cn H2n + 2
110,78
0,50
0,492
Cn H2n
108,78
0,38
0,381
Cn H2n 6
102,78
0,12
0,127
Tng
---
1,000
1,000
2.1.
(kg/h)
Page 5
Tnh ton cn bng vt cht v cn bng nhit lng ca cng ngh CCR
Bng 5: Thnh phn cc cu t trong nguyn liu.
2.2.
Cu t
yi (phn mol)
Ni = NC . y'i (kmol/h)
Cn H2n + 2
0,492
829,735
Cn H2n
0,381
642,539
Cn H2n - 6
0,127
214,180
Tng
1,000
1686,454
Cu t
Mi
yi
Mi . yi
ni = nkth . yi
H2
0,86
1,72
4216,134
CH4
16
0,04
0,64
196,099
C 2 H6
30
0,05
1,50
245,124
C 3 H8
44
0,03
1,32
147,075
C4H10
58
0,01
0,58
49,025
C5H12
72
0,01
0,72
49,025
Tng
1,00
6,48
4902,483
Page 6
Tnh ton cn bng vt cht v cn bng nhit lng ca cng ngh CCR
-
2.3.
ni (Kmol/h)
y'i = ni/ ni
829,735
0,1259
43213,223
642,539
0,0975
33465,364
214,180
0,0325
11155,121
H2
4216,135
0,6399
219635,757
P*
686,348
0,1040
35765,035
Tng
6588,937
1,0000
343.234,500
Page 7
Tnh ton cn bng vt cht v cn bng nhit lng ca cng ngh CCR
Phn b xc tc trong cc l phn ng theo t lnh sau: 1/1,5/2,5/5.
Bng 8: S phn b xc tc trong cc l phn ng.
L phn ng
VXT ( m3 )
16,8152
10089,12
25,2228
15133,68
42,0380
25222,80
84,0760
50445,60
Tng
168,1520
100.891,20
dN1
dVR1
= K 1 . PN
K1 . PA .PH3 2
= 0,0368
KP1
10089,120 / 1686,454 =
5,9824 (kg/kmol).
Page 8
Tnh ton cn bng vt cht v cn bng nhit lng ca cng ngh CCR
Lng naphten tham gia phn ng (1) l:
nN1 = 0,2202 x 1686,454 = 371,273 (kmol/h)
Vy lng naphten cn li sau phn ng (1) l.
nN1 = ( yi - N1) x NC = ( 0,381 - 0,2202 )x 1686,454 = 271,266 (kmol/h)
Hng s tc phn ng chuyn ho naphten thnh parafin (2)T = 8030K
1000/T =
1000/803 = 1,245
- 7,12
- 7,12
= 0,0021.10-3 [pa-1].
dN12
dVR = K2. PN
K 2 . PP
KP2
- 0,00206
Page 9
Tnh ton cn bng vt cht v cn bng nhit lng ca cng ngh CCR
Bng 9: Cn bng ho hc cho l phn ng th nht.
Lng cht tham gia phn ng (kmol/h)
371,273 CnH2n
371,273 CnH2n
20,760CnH2n+2
- 6
+ 371,273x 3H2
20,760CnH2n + 20,760H2
Lng vo(kmol/h)
Lng ra (kmol/h)
829,735
642,539
214,180
Tng
1686,454
1686,454
4216,135
CH4
196,099
196,099
C2H6
245,124
245,124
C3H8
147,075
147,075
C4H10
49,025
49,025
C5H12
49,025
49,025
Tng
4902,483
6037,062
Page 10
Tnh ton cn bng vt cht v cn bng nhit lng ca cng ngh CCR
585,453x(14n - 6) + 292,026x14n + 808,975x(14n + 2) = 181564,027
suy ra
MP = 14n +2
n = 7,7703
MA = 14n - 6
= 14 x 7,7703 - 6
MN = 14n
= 14 x 7,7703
= 14 x 7,7703 + 2
= 102,784
= 108,784
= 110,784
Mi
ni (kmol/h)
H2
CH4
y'i = n'i/ni
Miy'i
5350,714
0,8863
1,773
16
196,099
0,0325
0,520
C2H6
30
245,124
0,0406
1,218
C3H8
44
147,075
0,0244
1,074
C4H10
58
49,025
0,0081
0,469
C5H12
72
49,025
0,0081
0,583
Tng
6037,062
1,0000
5,637
ni (kmol/h)
yi
Mi
Gi = M i . n i
u vo
P
829,735
0,1259
110,780
91918,043
642,539
0,0975
108,780
69895,392
214,180
0,0325
102,780
22013,420
H2
4216,135
0,6399
6,480
27320,555
P*
686,348
0,1042
6,480
4447,535
Tng
6588,937
1,0000
215594,945
110,784
89621,486
u ra
P
808,975
0,1050
Page 11
Tnh ton cn bng vt cht v cn bng nhit lng ca cng ngh CCR
N
292,026
0,0378
108,784
31767,756
585,453
0,0758
102,784
60175,201
H2
5350,714
0,6930
5,637
30161,975
P*
686,348
0,0889
5,637
3868,944
Tng
7723,516
1,0000
215594,945
3.2.
Page 12
Tnh ton cn bng vt cht v cn bng nhit lng ca cng ngh CCR
Tnh Q41: Gi thit nhit ti l phn ng th nht gim iT = 700K
Q41 = mXT2. CPxt .T
Trong : mxt2 lng xc tc ra khi l phn ng th nht.
CPxt: Nhit dung ring xc tc T = 803 - 70 = 7330K
CPxt = 22,08 + 8,91.10-3 x 733 - 5,225.105x(733)-2 = 28,654 (kcal/kmol.0K)
CPxt = 1,1759 (kj/kg.0K)
Q41 = mxt 1CPxt.T = 10089,12 x 1,1759 x 733 = 8696162,62 (kj/h)
Tnh Q11: Ta cn xc nh entanpi ca dng hi nguyn liu ca vo ca l
phn ng th nht.
S liu entanpi ca H2, CH4, C2H6, C3H8, C4H10, C5H12 tra s tay ho l.
xc nh entanpi ca aromatic, naphten, parafin, ta da vo trng lngphn t trung
bnh ca cc cu t
Bng 14: T trng ca cc cu t.
298
298
Cu t
u vo
u ra
0,733
0,737
0,721
0,733
0,718
0,722
Page 13
Tnh ton cn bng vt cht v cn bng nhit lng ca cng ngh CCR
Q11 = Gc . qtr1 = 1908,71x 215594,945 = 411508227,5 (kj/h)
Mi
ni
y'i =
ni/ ni
Mi.y'i
yi =
Miy'/Miy'i
Entanpi
qt
qtyi
(KJ/kg)
(KJ/h)
H2
4216,135
0,6400
1,280
0,0319
7700
301,07
CH4
16
196,099
0,0298
0,477
0,0146
1618
23,62
C2H6
30
245,124
0,0371
1,113
0,0339
1434
48,76
C3H8
44
147,075
0,0223
0,981
0,0300
1405
42,15
C4H10
58
49,025
0,0074
0,432
0,0132
1400
18,48
C5H12
72
49,025
0,0074
0,536
0,0160
1392
22,27
102,78 214,180
0,0325
3,340
0,1020
1715
174,93
108,78 642,539
0,0975
10,606
0,3240
1704
552,10
110,78 829,735
0,1226
13,958
0,4260
170,3
725,48
6588,937 1,0000
32,723
1,0000
1908,71
Tng
Page 14
Tnh ton cn bng vt cht v cn bng nhit lng ca cng ngh CCR
qtr1: hm nhit ca sn phm v kh tun hon mang ra.
Bng 16: Cn bng nhit lng ca l phn ng th nht .
Dng
Nhit (oK)
Lng (Kg/h)
Dng vo
Q11
803
Q21
803
Tng
---
215594,945
1908,710
411508227,5
9466676,8
---
---
420974904,3
1556,634
335602448,4
Dng ra
Q31
733
215594,945
Q41
733
8696162,7
Q51
733
80266543,9
Q61
4209749,3
Tng
---
---
---
420974904,3
nc (kmol/h)
yC2i = nci/nc2i
Cn H2n + 2
808,975
0,4797
Cn H2n
292,026
0,1732
Cn H2n - 6
585,453
0,3471
Tng
1686,454
1,0000
gim p sut gia cc l phn ng thng 0,15 0,35 (kg/cm2). Chn gim
p sut l phn ng th hai l 0,2 (kg/cm2). Khi p sut chung ca hn hp kh
nguyn liu vo l phn ng th hai l:
P2 = 3,5 - 0,2 = 3,3 (kg/cm2) = 3,3 x 98067 = 323621,1 (pa)
Page 15
Tnh ton cn bng vt cht v cn bng nhit lng ca cng ngh CCR
Bng 18: Thnh phn p sut.
Cu t
y'i = ni/ ni
0,105
33980,22
0,037
11973,98
0,076
24595,20
H2
0,693
224269,42
P*
0,089
28802,28
Tng
1,000
323621,10
dN12
dVR2
= K 1 . PN
K1 . PA .PH3 = 0,01317
2
KP1
M VR2 = m2/NC
Trong :
mxt2 : lng xc tc vo l phn ng th hai; mxt2 = 15133,68 (kg)
NC: Lng nguyn liu vo l phn ng th hai (kmol/h).
VR2 =
Page 16
Tnh ton cn bng vt cht v cn bng nhit lng ca cng ngh CCR
nN12 = 0,1185 x 1686,454 = 199,845 (kmol/h)
Hng s tc phn ng chuyn ho naphten thnh parafin T = 803 0K
Tra th ph lc [2] ta cK2 = 100.10-15 (kmol/h.Pa2 kg xc tc).
KP2 = 98,1-1 . 10-3 . e(4450/T)
- 7,12
dN22
= K 2 . PN
dVR2
- 7,12
K 2 . PP
KP2
= 0,0021.10-3 [pa-1].
= - 0,0017
- 6
+ 199,845x 3H2
Lng vo(kmol/h)
Lng ra (kmol/h)
808,975
292,026
585,453
Tng
1686,454
1686,454
Page 17
Tnh ton cn bng vt cht v cn bng nhit lng ca cng ngh CCR
Bng 21: Tnh lng kh tun hon.
H2
5350,714
CH4
196,099
196,099
C2H6
245,124
245,124
C3H8
147,075
147,075
C4H10
49,025
49,025
C5H12
49,025
49,025
Tng
6037,062
6662,400
Mi
ni (kmol/h)
y'i = n'i/ni
Miy'i
H2
5976,052
0,8970
1,794
CH4
16
196,099
0,0294
0,470
C2H6
30
245,124
0,0368
1,104
C3H8
44
147,075
0,0220
0,968
C4H10
58
49,025
0,0074
0,429
C5H12
72
49,025
0,0074
0,533
Tng
6662,400
1,0000
5,299
n = 7,769
MA = 14n - 6
= 14x 7,769 - 6
= 102,766
MN = 14n
= 14 x 7,769
= 108,766
Page 18
Tnh ton cn bng vt cht v cn bng nhit lng ca cng ngh CCR
MP = 14n +2
= 14 x7,769+ 2
= 110,766
ni (kmol/h)
yi
Mi
Gi = M i . n i
u vo
P
808,975
0,105
110,784
89621,487
292,026
0,039
108,784
31767,756
585,453
0,076
102,784
60175,202
H2
5350,714
0,692
5,637
30161,976
P*
686,348
0,088
5,637
3868,944
Tng
7723,516
1,000
215594,945
0,094
110,766
86748,30
u ra
P
783,172
117,984
0,014
108,766
12832,648
785,298
0,094
102,766
80701,934
H2
5976,052
0,716
5,299
31667,099
P*
686,348
0,082
5,299
3636,956
Tng
8348,854
1,000
4.2.
215594,922
Page 19
Tnh ton cn bng vt cht v cn bng nhit lng ca cng ngh CCR
Nhit lng Q22 do xc tc mang vo l phn ng th hai chnh l nhit lng
do xc tc mang ra khi l phn ng th nht.
Q22 = Q41 = 8696162,62 (kj/h)
Tnh Q42
Gi thit nhit ti l phn ng th hai gim iT = 600K
Q42 = mXT2. CPxt .T
Trong : mxt2 lng xc tc ra khi l phn ng th hai.
CPxt: nhit dung ring xc tc T = 803 - 60 = 7430K
CPxt = 22,08 + 8,91.10-3 x 743 - 5,225.105x(743)-2 = 27,80 (kcal/kmol.0K)
CPxt = 27,80 x 4,186 /102 = 1,1409 (kcal/kg0K)
Q42 = mxt2CPxt.T = 15133,68 x 1,1409 x 743 = 12828649,53 (kj/h)
Tnh Q12: Ta cn xc nh entanpi ca dng hi nguyn liu ca vo l phn
ng th hai.
Bng 24: Entanpi ca hn hp hi vo l phn ng th hai .
Cu t
Mi
ni
y'i =
ni/ ni
Mi.y'i
Entanpi
yi =
Miy'/Miy'i
qt
qtyi
(KJ/kg)
(KJ/h)
H2
5350,714
0,6928
1,387
0,0497
7700
382,69
CH4
16
196,099
0,0254
0,406
0,0146
1618
23,62
C2H6
30
245,124
0,0317
0,951
0,0341
1434
48,90
C3H8
44
147,075
0,0190
0,836
0,0299
1405
42,01
C4H10
58
49,025
0,0063
0,359
0,0129
1400
18,06
C5H12
72
49,025
0,0063
0,454
0,0163
1392
22,69
102,784 585,453
0,0758
7,791
0,2793
1715
479,00
108,784 292,026
0,0378
4,112
0,1474
1704
251,17
110,784 808,975
0,1047
11,599
0,4158
1703
708,11
1,0000
27,894
1,0000
Tng
7723,516
1976,25
Page 20
Tnh ton cn bng vt cht v cn bng nhit lng ca cng ngh CCR
qP = - 355.b
Trong : b. hiu sut to hydro tinh khit theo khi lng nguyn liu ban u (%
kl).
NH2 = 5976,052 - 5350,714 = 625,338 (kmol/h)
GH2 = MH2 . 625,338 = 2 x 625,338 = 1250,676 (kg/h)
b = GH2 100%/GC = (1250,676 x100%)/183823,529 = 0,68%
Vy qp = - 355 . b = - 355 x 0,68 = - 241,40 (KJ/kg)
Nhit do hm hp nguyn liu v kh tun hon mang vo l phn ng th hai.
Q12 = 216538,301 x 1976,25 = 426069508,10 (kj/h)
Tnh Q62. Nhit mt mt ra mi trng bn ngoi.
Q62 = 0,01 x(Q22 + Q 21) = 0,01x (426069508,10 + 8696162,62)
= 5130356,71 (kj/h)
Tnh Q52. Nhit lng tiu tn do phn ng reforming.
Q52 = Gc.qP = 183823,529 x 241,40 = 44374999,90 (kj/h).
Tnh Q32 . Nhit lng do sn phm v kh tun hon mang ra.
Q32 = Q12 + Q22 - Q42 - Q52 - Q62
Q32 = 426069508,10 + 8.696.162,62 - 12828649,53 - 44374999,90
- 5130356,71 = 326258455,6 (kj/h)
Q32 = 215594,922 qtr2
qtr2 = 1513,294 (kj/h)
qtr2: hm nhit ca sn phm v kh tun hon mang ra.
Bng 25: Cn bng nhit lng ca l phn ng th hai .
Dng
Nhit (oK)
Lng (Kg/h)
Entanpi (KJ/kg)
Dng vo
Q12
803
Q22
803
Tng
BTL Cng ngh Ch bin du
215594,945
1976,25
426069508,10
8696162,62
434765670,70
Page 21
Tnh ton cn bng vt cht v cn bng nhit lng ca cng ngh CCR
Dng ra
Q32
743
215594,922
1513,294
326258455,6
Q42
743
12828649,53
Q52
743
44374999,90
Q62
743
5130356,71
Tng
434765670,70
nc (kmol/h)
Cn H2n + 2
783,172
0,464
Cn H2n
117,984
0,070
Cn H2n - 6
785,298
0,466
Tng
1686,454
1,000
yC2i = nci/nc2i
gim p sut gia cc l phn ng thng 0,15 0,35 (kg/cm2). Chn gim
p sut l phn ng th ba l 0,2 (kg/cm2). Khi p sut chung ca hn hp kh
nguyn liu vo l phn ng th ba l:
P3 = 3,3 - 0,2 = 3,1 (kg/cm2) = 3,1 x 98067 = 304007,7(pa)
Bng 27: Thnh phn p sut.
Cu t
y'i
Pi = 304007,7y'i (Pa)
0,0938
28515,922
0,0141
4286,509
0,0941
28607,125
H2
0,7158
217608,712
P*
0,0822
24989,433
Tng
1,0000
304007,700
Page 22
Tnh ton cn bng vt cht v cn bng nhit lng ca cng ngh CCR
dN13
= K 1 . PN
dVR3
3
K1 . PA .PH
2
= 0,004715
KP1
M VR3 = mxt3/NC
Trong :
mxt3 : lng xc tc vo l phn ng th ba; mxt3 = 25222,8 (kg)
NC: Lng nguyn liu vo l phn ng th ba (kmol/h).
VR3 = 14,956 (kg/kmol).
Vy N13 = 14,956 x 0,004715 = 0,07052 (kmol/h)
Lng naphten tham gia phn ng (1) l:
nN13 = NC x 0,07052 = 0,07052 x 1686,454 = 118,929 (kmol/h)
Hng s tc phn ng chuyn ho naphten thnh parafin T = 803 0K
Tra th ph lc [2] ta cK2 = 100.10-15 (kmol/h.Pa2 kg xc tc).
KP2 = 98,1-1 . 10-3 . e(4450/T)
- 7,12
- 7,12
= 0,0021.10-3 [pa-1].
Page 23
Tnh ton cn bng vt cht v cn bng nhit lng ca cng ngh CCR
Suy ra
118,929 CnH2n
118,929 CnH2n
34,235 CnH2n+2
- 6
+118,929 x 3H2
Lng vo(kmol/h)
Lng ra (kmol/h)
783,172
117,984
785,298
Tng
1686,454
1686,454
Page 24
Tnh ton cn bng vt cht v cn bng nhit lng ca cng ngh CCR
suy ra
n = 7,774
5976,052
CH4
196,099
196,099
C2H6
245,124
245,124
C3H8
147,075
147,075
C4H10
49,025
49,025
C5H12
49,025
49,025
Tng
6662,400
7053,422
Mi
ni (kmol/h)
y'i = n'i/ni
Miy'i
H2
6367,074
0,9030
1,806
CH4
16
196,099
0,0277
0,443
C2H6
30
245,124
0,0347
1,041
C3H8
44
147,075
0,0208
0,915
C4H10
58
49,025
0,0069
0,400
C5H12
72
49,025
0,0069
0,497
Tng
7053,422
1,0000
5,102
Page 25
Tnh ton cn bng vt cht v cn bng nhit lng ca cng ngh CCR
Bng 32: Cn bng vt cht ca l phn ng th ba.
Cu t
ni (kmol/h)
yi
Mi
Gi = Mi . ni
u vo
P
783,172
0,094
110,766
86748,30
117,984
0,014
108,766
12832,648
785,298
0,094
102,766
80701,934
H2
5976,052
0,716
5,299
31667,099
P*
686,348
0,082
5,299
3636,956
Tng
8348,854
1,000
215594,922
u ra
P
748,937
0,0857
110,836
83009,181
33,29
0,0037
108,836
3623,150
904,227
0,1035
102,836
92987,088
H2
6367,074
0,7285
5,102
32484,812
P*
686,348
0,0785
5,102
3439,976
Tng
8739,874
1,0000
5.2.
215594,207
Page 26
Tnh ton cn bng vt cht v cn bng nhit lng ca cng ngh CCR
Tnh Q23: Nhit lng Q23 do xc tc mang vo l phn ng th ba chnh l
nhit lng do xc tc mang ra khi l phn ng hai.
Q23 = Q42 = 12828649,53 (kj/h)
Tnh Q43 Gi thit nhit ti l phn ng th ba gim iT = 500K
Q43 = mXT3. CPxt .T
Trong : mxt3 lng xc tc ra khi l phn ng th ba.
CPxt: nhit dung ring xc tc T = 803 - 50 = 7530K
CPxt = 22,08 + 8,91.10-3 x 753 - 5,225.105x(753)-2 = 27,9137 (kcal/kmol.0K)
CPxt = 27,91370 x 4,186 /102 = 1,1456 (kcal/kg0K)
Q43 = mxt3CPxt.T = 753x 1,1456 x 25222,8 = 21758115,48 (kj/h)
Tnh Q13: Ta cn xc nh entanpi ca dng hi nguyn liu ca vo ca l
phn ng th ba.
Bng 34: Entanpi ca hn hp hi vo l phn ng th ba.
Cu t
Mi
y'i =
ni
ni/ ni
Mi.y'i
Entanpi
yi =
Miy'/Miy'i
qt
qtyi
(KJ/kg)
(KJ/h)
H2
5976,052
0,7158
1,4344
0,0558
7700
429,66
CH4
16
196,099
0,0235
0,3728
0,0145
1618
23,46
C2H6
30
245,124
0,0294
0,8760
0,0342
1434
49,04
C3H8
44
147,075
0,0176
0,7700
0,0299
1405
42,01
C4H10
58
49,025
0,0059
0,3422
0,0133
1400
18,62
C5H12
72
49,025
0,0059
0,4248
0,0165
1392
22,97
102,766
785,298
0,094
9,7853
0,3807
1709
650,62
108,766 117,984
0,0141
1,4034
0,0546
1702
92,93
110,766 783,172
0,0938
10,292
0,4005
1698
680,05
1,0000
25,701
1,0000
2009,36
Tng
8348,854
Page 27
Tnh ton cn bng vt cht v cn bng nhit lng ca cng ngh CCR
Trong : b. hiu sut to hydro tinh khit theo khi lng nguyn liu ban u (% kl).
NH2 = 6019,750 - 5976,052 = 43,698 (kmol/h)
GH2 = MH2 . 43,698 = 2x 43,698 = 87,396 (kg/h)
b = GH2 100%/G = (87,396 x100%)/183823,529 = 0,0475%
Vy
Nhit (oK)
Lng (Kg/h)
Dng vo
Q13
803
Q23
803
Tng
215594,922
2009,36
433207858,70
12828649,53
446036508,20
1932,88
416718211,50
Dng ra
Q33
753
215594,207
Page 28
Tnh ton cn bng vt cht v cn bng nhit lng ca cng ngh CCR
Q43
753
21758115,48
Q53
753
3099816,14
Q63
753
4460365,08
Tng
446036508,20
nc (kmol/h)
YC2i = nci/nc2i
Cn H2n + 2
748,937
0,4441
Cn H2n
33,290
0,0197
Cn H2n - 6
904,227
0,5362
Tng
1686,454
1,0000
gim p sut gia cc l phn ng thng 0,15 0,35 (kg/cm2). Chn gim
p sut l phn ng th t l 0,2 (kg/cm2). Khi p sut chung ca hn hp kh
nguyn liu vo l phn ng th t l:
P4 = 3,1 - 0,2 = 2,9 (kg/cm2) = 2,9 x 98067 = 284394,3(pa)
y'i
0,0857
24372,59
0,0038
1080,76
0,1035
29434,81
H2
0,7285
207181,25
P*
0,0785
22324,96
Tng
1,0000
284394,30
Page 29
Tnh ton cn bng vt cht v cn bng nhit lng ca cng ngh CCR
Hng s tc phn ng chuyn ho naphten thnh aromatic.
Ta c nhit u vo l phn ng th t l T= 8030K
T = 8030K
dN14
dVR4
= K 1 . PN
K1 . PA .PH3
2
= 0,00119
KP1
M VR4 = mxt4/NC
Trong :
mxt4 : lng xc tc vo l phn ng th t; mxt4 = 50445,60 (kg)
NC: Lng nguyn liu vo l phn ng th t (kmol/h).
VR4 = 50445,60 /1686,454 = 29,912 (kg/kmol).
Vy
- 7,12
- 7,12
= 0,0021.10-3 [pa-1].
Page 30
Tnh ton cn bng vt cht v cn bng nhit lng ca cng ngh CCR
Do KP2 << 1 nn hm lng naphten tng do phn ng nghch xy ra chim u
th.
dN24
= K 2 . PN
dVR4
Suy ra
K 2 . PP
KP2
= - 0,00116
dN N34
dVR4
K 3 . PP
P
= 0,00326
- 6
+ 60,038x3H2
58,520 CnH2n+2
Page 31
Tnh ton cn bng vt cht v cn bng nhit lng ca cng ngh CCR
NH2 = 164,429 x n/3 =164,429 x(7,774 - 3)/3 = 261,661 (kmol/h).
Lng kh hydrocacbon sinh ra trong l phn ng th t l.
RH = 164,429 x n/15 = 164,429 x 7,774 /15 = 85,218 (kmol/h).
Bng 39: Tnh lng cht dng vo v dng ra ca l phn ng th t.
Cu t
Lng vo(kmol/h)
Lng ra (kmol/h)
748,937
33,290
904,227
Tng
1686,454
1526,025
6367,074
6367,074+60,038x3+58,520-261,661 = 6344,047
CH4
196,099
C2H6
245,124
C3H8
147,075
C4H10
49,025
C5H12
49,025
Tng
7053,422
7456,485
Mi
ni (kmol/h)
y'i = n'i/ni
Miy'i
H2
6344,047
0,851
1,702
CH4
16
281,317
0,038
0,608
C2H6
30
330,342
0,044
1,320
C3H8
44
330,342
0,0311
1,364
C4H10
58
232,293
0,018
1,044
C5H12
72
134,243
0,018
1,296
Page 32
Tnh ton cn bng vt cht v cn bng nhit lng ca cng ngh CCR
Tng
7456,485
1,0000
7,334
n = 7,7528
MA = 14n - 6
= 14 x 7,7528 - 6 = 102,529
MN = 14n
= 14 x7,7528
= 108,529
MP = 14n +2
= 14 x7,7528 + 2
= 110,529
ni (kmol/h)
yi
Mi
Gi = Mi . ni
u vo
P
748,937
0,0857
110,836
83009,181
33,29
0,0037
108,836
3623,150
904,227
0,1035
102,836
92987,088
H2
6367,074
0,7285
5,102
32484,812
P*
686,348
0,0785
5,102
3439,976
Tng
8739,874
1,0000
215594,207
u ra
P
529,988
0,0591
110,529
58584,344
31,772
0,0035
108,529
3448,501
964,265
0,1073
102,529
98874,769
H2
6344,047
0,7063
7,334
46527,241
P*
1112,438
0,1238
7,334
8158,620
Tng
8982,510
1,0000
215593,475
Page 33
Tnh ton cn bng vt cht v cn bng nhit lng ca cng ngh CCR
6.2.
Cu t
Mi
ni
Y'i =
ni/ ni
Mi.y'i
yi =
Miy'/Miy'i
Entanpi
qt
qtyi
(KJ/kg)
(KJ/h)
H2
6367,074
0,7285
1,457
0,059
7700
454,30
CH4
16
196,099
0,0224
0,358
0,0145
1618
23,46
Page 34
Tnh ton cn bng vt cht v cn bng nhit lng ca cng ngh CCR
C2H6
30
245,124
0,0281
0,843
0,0342
1434
49,04
C3H8
44
147,075
0,0168
0,739
0,0299
1405
42,01
C4H10
58
49,025
0,0056
0,325
0,0132
1400
18,48
C5H12
72
49,025
0,0056
0,403
0,0162
1392
22,69
102,836
904,227
0,1035
10,644
0,4312
1700
733,04
108,836
33,29
0,0038
0,414
0,0168
1695
28,48
110,836 748,937
0,0857
9,499
0,3849
1690
650,48
1,0000
24,682
1,0000
2021,98
Tng
8739,874
Page 35
Tnh ton cn bng vt cht v cn bng nhit lng ca cng ngh CCR
qtr4: hm nhit ca sn phm v kh tun hon mang ra.
Bng 44: Cn bng nhit lng ca l phn ng th t.
Dng
Nhit (oK)
Lng (Kg/h)
Entanpi (KJ/kg)
Nhit lng(KJ/h)
Dng vo
Q14
803
Q24
803
215594,207
2021,98
435925694,6
21758115,48
Tng
457683810,00
Dng ra
Q34
763
Q44
763
46599834,28
Q54
763
16966911,73
Q64
763
4576838,10
Tng
215593,475
1806,83
389540226
457683810,00
Page 36