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CHM 1045-A11 Sections

Exam 3B

Fall 2012

Unit3

Thermochemistry, Atomic Structure, & Bonding

Chapters 6-10

1 . From the following enthalpies of reaction: H2 (g) + F2 (g) -> 2HF (g) AH = -537 kJ C (s) + 2F2 (g) > CF4 (g) AH = -680 kJ 2C (s) + 2H2 (g) > C2H4 (g) AH = +52.3 kJ calculate the AH for the reaction of tetrachloromethane with hydorgen fluoride gas 2CF4 (g) + 4HF (g) -.-> C2H4 (g) + 6F2 kJ 7+1949 kJ C. -1545 kJ D. +1649 kJ E. +1164kJ

J-%1* )

at
- f

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tf>

C'

G,

I
it. nt.

BBBP VRHk

2. Consider the figure above. Which of the following statements regarding quantum number sets {n, 1, mj} is/are true regarding the orbitals shown in the diagram. ^^(a) A quantum number set {4,3,3} could represent the orbital shown in figure (i) r^b) A quantum number set {5,4,2} could represent the orbital shown in figure (iii) A quantum number set {6, 3, -1} could represent the orbital shown in figure (iv) A: /TO C. D. E. (c) only (a) only (a) and (b) only (b) and (c) only (a) and (c) only

(X
Na Rb

3. Arrange the following 4$flsfbased on size from the smallest to the largest. K P

W aoi^AoAin
J V )

P,Na,AI,K,Rb .)P,Al,Na,K,Rb T Na,P,K,Rb,Al D. Al,K,Rb,Na,P E. Na,Al,P,K,Rb 4. Which of the following statements is/are true? v/i. ^he electron configuration of copper is Cu:[Ar] 4s 13d 10 ie electron configuration of iron is Fe: [Ar]4s^3d" ii. the electron configuration of molybdenum is Mo:[Kr]5s24d4 A. i only B. ii only iii only i andii ii and iii

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5. Which atom would have the following ground state electron configuration:

6. Which element could be represented by the following ionization energies:


IJOOO

10CKO

ifj

IFi

if-,1

C. Be D. C E. Li 7. When ethanol burns, AHrxn = -2555.2 kJ for the following reaction: 2 C2H5OH (g) + 6 02 (g) -> 4 C02 (g) + 6 H2O (g)

AHf = -393.5 kJ/mol for CO2(g) and AHf = -241.8 kJ/mol for H2O(g). What is the value of AHf for ethanol
1

-469.6kJ - 234.8 kJ

D. 235.OkJ E. -5580.OkJ

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X = -

8. Which of the following best represents the orbital diagram showing the valence orbitals for a Ni2+ ion?

A.

t
<<

t t
D.

t t t t
Ni :

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9. Which of the following statements about quantum numbers is/are correct: i. n=2, 1=1 , mj = -2 would be a 2p orbital -jrf-n=3 , 1=0, mi = 0 would be a 3p orbital iii. n=4, 1=3 , mj = +2 would be a 4f orbital U r, A. ionly B. iionly C. iii only i and ii E: i and iii
* O ' w ,
*
I I

**

10. The figure above shows one of the possible resonance structures for sulfurous acid. Determine the formal charge on the sulfur atom in this structure. A. +2 B. -1 C. 0 -2 1 11. A photon from a burst of X-ray radiation has a wavelength of 0.11 nm. Calculate the energy released by a mole of photons from this burst of X-ray radiation -*-^ A. 3.00xlO- 4 2 kJ B. 1.81x10-18 k iOm

< n . 1.09x!06kJ

U, 1 X

12. The Lymen Series is a series of bands in the ultraviolet region of the electromagnetic spectrum emitted by a hydrogen atom. Calculate the frequency of a photon emitted by a hydrogen atom when the electron falls from the n=9 energy level to the n=l energy level. A 3.25xl0 1 5 Hz C. l.OSx 107Hz D. 2.93x1015 Hz E. 9.23 x 10-8 Hz
-IS J

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= 3.3.SY(0|S

1 3 . Which of the following statements is/are true? i. The bond between beryllium and oxygen will be a metallic bond ii. The bond between two bromine atoms will be a non-polar covalent bond l^ iii. The bond between carbon and chlorine will be an ionic bond

Y\d ii ii and iii E. i and iii

J)
Table I Specific Heats
use this table for the following question Metal Copper Gold Iron Silver Antimony (Sb) Magnesium Specific Heat (J/gO 0.387 0.129 0.449 0.235 0.207 1.02

>**

14. A 18.394 g piece of silver is heated to a temperature of 89.36 C and thrown into a cup of cold water. When the temperature stabilizes, the temperature of the metal and the water is .96 C. Calculate the change in heat for the piece of silver. A. -194.3 J B. 386.3 J

- a

< -1.14 J
15. Which of the following molecules would have T-shaped molecular geometry? A. B. C. D. E. IBr3 I3SF4 BF3 SO32* *

/ y

2~

\.
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:f

: o'

16. Identify which of the following would have a heat of formation of 0, AHf = 0. (g) B. CH4(g) C. F-(aq) D. H2O (s) 17. A reaction is allowed to take place in a closed system with a moveable piston that is immersed in a water bath at 25.0C. The temperature of the water bath increased to 28.3C and the volume of the system decreased from 7.75 L to 5.00 L. Predict the signs for heat and work for the system.

C. D. E.

18. A piece of aluminum metal weighing 261.98 g is heated to 61.9 C and then dropped into cold water. What would the temperature of the metal be if 8.32 kJ of energy is released in the j f process. The specific heat of aluminum is 0.903 J/gC? A. 33.5C
T> Qf\ O/"i

(c) 26.1 C D. 97.1 C E. 61.9C -Ar-PHs i^fi. ScQ?vJ77~ Etr^

19. Which of the following compounds will violate the octet rule?

_IL_LE2* ^)C1F3 20. Ammonia burns in excess oxygen according to the following equation:
4 NH3 (g) + 5 O2(g) -> 4 NO (g) + 6 H2O(1) AH = - 904 kJ How much heat would be released if 14.358 g of nitrogen monoxide were produced?

E. 77.85 kJ

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