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1,3-dibromopropane
125903 -
1.2 2. 2.1
109-64-8 Relevant identified uses of the substance or mixture and uses advised against
Identified uses Laboratory chemicals, Manufacture of substances
HAZARDS IDENTIFICATION Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP]
Flammable liquids (Category 3) Acute toxicity, Oral (Category 4) Skin irritation (Category 2) Chronic aquatic toxicity (Category 2)
2.2
Statements - - 125903
Flammable. Harmful if swallowed. Irritating to skin. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Keep away from sources of ignition - No smoking. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear suitable protective clothing. Avoid release to the environment. Refer to special instructions/ Safety data sheets.
2.3 3. 3.1
: :
1,3-Dibromopropane
CAS-No. EC-No.
4. 4.1
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
If swallowed
Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
4.2 4.3
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5. 5.1
Further information
Use water spray to cool unopened containers.
ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas.
6.2
Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.
7.2
7.3
no data available
8. 8.1 8.2
EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Components with workplace control parameters Exposure controls Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.
Skin protection
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Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.
Body Protection
Complete suit protecting against chemicals, Flame retardant antistatic protective clothing, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).
9. 9.1
PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties
a) Appearance b) c) d) e) f) Odour Odour Threshold pH Melting point/freezing point Initial boiling point and boiling range Form: clear, liquid Colour: light yellow no data available no data available no data available Melting point/range: -34 C - lit. 167 C - lit.
g) Flash point no data available h) Evaporation rate no data available i) Flammability (solid, gas) no data available j) Upper/lower flammability or explosive limits k) Vapour pressure l) Vapour density m) Relative density n) Water solubility o) Partition coefficient: noctanol/water p) Autoignition temperature q) Decomposition temperature r) Viscosity s) Explosive properties t) Oxidizing properties no data available
no data available 6,97 - (Air = 1.0) 1,989 g/cm3 at 25 C no data available log Pow: 2,02 no data available no data available no data available no data available no data available
9.2
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Skin corrosion/irritation
no data available
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
no data available
Aspiration hazard
no data available
Potential health effects Inhalation May be harmful if inhaled. Causes respiratory tract irritation. Ingestion Harmful if swallowed. Skin May be harmful if absorbed through skin. Causes skin irritation. Signs and Symptoms of Exposure
Nausea, Dizziness, Headache, narcosis
Additional Information
RTECS: TX8575000
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12. ECOLOGICAL INFORMATION 12.1 Toxicity Toxicity to fish LC50 - Pimephales promelas (fathead minnow) - 1,79 mg/l - 96,0 h 12.2 Persistence and degradability
no data available
Contaminated packaging
Dispose of as unused product.
15.
REGULATORY INFORMATION
This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
no data available
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16.