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density
= density porosity
matrix
= matrix density, or grain density
bulk
= bulk density measurement
fluid
= fluid density
matrix
density
bulk
matrix
fluid
=
70% error
31424schD7R1.indd 42 8/10/10 10:19 PM
Summer 2010 43
Measuring Basic Properties
Porosity is a basic petrophysical measurement,
usually obtained from well logs. It is commonly
computed from bulk density data. Density poros-
ity is sensitve to both the pore uids and the
matrix, especially the matrix. There are several
methods available for computing porosity, and
these often are affected by the uids in the rock
and the mineralogy. Depending on environmen-
tal conditions and operational constraints, inte-
grating these measurements plays a role in
decoupling the effects of the matrix on the
porosity value.
Examples of porosity measurements include
those from lithology-dependent thermal neu-
tron, lithology-independent neutron, acoustic,
thermal neutron capture spectroscopy and
nuclear magnetic resonance (NMR) tools.
Neutron and NMR porosity tools are blind to the
presence of gas, and NMR measurements are
also blind to porosity lled with tar, bitumen,
microporosity-bound water and hydrates.
In contrast to the NMR and neutron tools, bulk
density tools respond to both uid and lithology.
Density porosity (
density
) is computed using two
xed inputs, matrix density (
matrix
) and uid den-
sity (
uid
), and the bulk density measured by the
tool (previous page, bottom). The uid density
used in calculating porosity is that of the uid ll-
ing the pores of the formation, typically 1.0 g/cm
3
,
while the matrix density depends on the rock type.
The matrix density of limestone is 2.71 g/cm
3
, dolo-
mite is 2.85 g/cm
3
, siderite is 3.89 g/cm
3
and sand-
stone (quartz) is 2.65 g/cm
3
.
Uncertainty in lithology translates into large
errors in computed porosity. For instance, a 10%
porosity limestone formation has a measured bulk
density of 2.539 g/cm
3
. However, a dolomite matrix
could have the same measured bulk density but its
porosity would be 17%. If the rock type is not cor-
rectly identied, this signicant discrepancy in
the computed porositya 70% errormight be
the difference between commercial viability and
the decision to abandon a well.
The matrix may be a single mineral type but is
often a mixture. Small concentrations of minerals,
if unaccounted for, can introduce considerable
error in the computed porosity. A common noncar-
bonate mineral associated with limestone reser-
voirs, the evaporite anhydrite, has a bulk density of
2.98 g/cm
3
. Dispersed within the rock matrix, a
small percentage of anhydrite can signicantly
increase the measured bulk density. When the
anhydrite is found in the form of nodules, the mea-
sured porosity will be lower than the true value
because logging tools average the response from
both rock types (above). The formation may
appear to be of poor quality, although the carbon-
ate portion may, in fact, have good porosity and
permeability but be masked by the anhydrites
effects on the measurement.
6
Low-porosity carbonates with heavy minerals,
such as anhydrite, are emerging as major sources of
bypassed hydrocarbons. Understanding the manner
in which these minerals affect porosity measure-
ments and reservoir producibility is crucial for
geologists who study carbonates. Core analysis
often becomes a major factor in determining
commerciality of a eld. Logging data lack the
ne resolution of core analysis, but they provide a
continuous record of petrophysical properties
such as porosity and lithology.
Complexity, Texture and Relative Permeability
Perhaps the most common lithology-determina-
tion method from logging data uses the photo-
electric effect (PEF) measurement, which
responds primarily to the minerals in the forma-
tion. This measurement is routinely acquired
using formation density devices, such as the
Litho-Density and LWD density tools.
7
Although
useful in differentiating pairs of minerals among
sandstone, limestone, dolomite and anhydrite,
additional measurements are required when
more than two minerals are present. Also, the
measurement is affected by barite in drilling-mud
systems, and borehole conditions such as thick
mudcake and hole rugosity may render it useless.
A better method for solving complex litholo-
gies and determining mineralogical concentra-
tions, which may vary widely across a eld
depending upon the diagenetic history and uids
percolating through the reservoir, is an elemental
thermal neutron capture spectroscopy measure-
ment. For example, the ECS elemental capture
spectroscopy and the LWD EcoScope tools offer
this type of measurement.
8
These tools measure
the concentrations of specic elements that cor-
respond to mineralogy. Various matrix properties
3. Vernon RH: A Practical Guide to Rock Microstructure.
Cambridge, England: Cambridge University Press
(2004): 3437.
4. There is disagreement on how dolomite forms in nature;
some scientists suggest that biogenic origins are the
primary source. For more on dolomite: Al-Awadi M,
Clark WJ, Moore WR, Herron M, Zhang T, Zhao W,
Hurley N, Kho D, Montaron B and Sadooni F: Dolomite:
Perspectives on a Perplexing Mineral, Oileld Review 21,
no. 3 (Autumn 2009): 3245.
5. For more on difculties with carbonate reservoir
evaluation: Ramamoorthy R, Boyd B, Neville TJ,
Seleznev N, Sun H, Flaum C and Ma J: A New
Workow for Petrophysical and Textural Evaluation
of Carbonate Reservoirs, Petrophysics 51, no. 1
(February 2010): 1731.
>
Mineralogical effects. Anhydrite is just one of many minerals found within
carbonate reservoir rocks. The manner in which this mineral is dispersed may
affect uid ow in the reservoir. It may also impact the porosity measurement.
In the case of anhydrite nodules, the porosity of the reservoir rocks tends to
be underestimated and uid ow is not greatly affected (core photograph,
right). If the anhydrite is dispersed within the pore structure (micrograph, left),
the porosity measurement will be reduced, as will uid ow. (Adapted from
Ramamoorthy et al, reference 5.)
TSFigure 04
Pore-filling anhydrite
Anhydrite nodule
6. Ramamoorthy et al, reference 5.
7. The PEF is a log of photoelectric absorption (P
e
) properties
of the rock matrix that is acquired along with formation
density measurements. Common minerals encountered in
oil and gas wells have specic P
e
values: sandstone (1.9),
dolomite (3.1), limestone (5.1) and anhydrite (5.0).
8. Japan Oil, Gas and Metals National Corporation (JOGMEC),
formerly Japan National Oil Corporation (JNOC), and
Schlumberger collaborated on a research project to
develop LWD technology that reduces the need for
traditional chemical sources. Designed around the
pulsed neutron generator (PNG), EcoScope service uses
technology that resulted from this collaboration. The
PNG and the comprehensive suite of measurements in
a single collar are key components of the EcoScope
service that deliver game-changing LWD technology.
31424schD7R1.indd 43 8/10/10 10:19 PM
44 Oileld Review
can also be computed from the yields, including
grain density.
9
Grain density represents an effec-
tive matrix density and varies according to the
elements present in the formation. It yields more-
accurate density porosity than when computed
using a xed-value matrix density.
Texture and pore geometry are also important
properties for identifying reservoir-quality rock
because knowledge of correct mineralogy and
porosity measurement alone is not sufcient to
infer ow characteristics in carbonate reservoirs.
In fact, some experts believe that characteriza-
tion of pore geometry is the most important com-
ponent in carbonate evaluation.
10
Complex pore
shapes and sizes often result from reservoir depo-
sition and the ensuing processes of dissolution,
precipitation and recrystallization. Although
time-consuming, core analysis can reliably iden-
tify and quantify pore geometry. The standard
resistivity and porosity measurements of a triple-
combo logging suite often do not respond to
changes in pore size and texture. NMR data, how-
ever, have been shown to identify changes in pore
size distribution not detectable by these conven-
tional logs (left).
To better evaluate reservoir rock quality using
logging data, experts developed a technique for
characterizing carbonate pore geometry by parti-
tioning the total porosity measurement into three
classes of pore spaces based on sizemicro-
(less than 0.5 microns), meso- (0.5 to 5 microns)
and macroporosity (larger than 5 microns). From
these partitions, reservoir quality and uid-ow
properties are inferred.
11
Partitioning of forma-
tion porosity by pore size uses specic ranges of
transverse relaxation times, T
2
, from NMR data.
12
Core data are often used to rene T
2
measure-
ment ranges (left).
Another partitioning method maps relative
pore geometry into eight rock classes (next page,
bottom left).
13
The resulting ternary diagram was
rst developed through systematic analysis of
texture-sensitive borehole logs, which included
NMR data, borehole images, full-waveform acous-
tic logs and dielectric data.
14
A similar ternary
diagram has been derived from mercury injection
capillary pressure (MICP) tests on core.
For macroporosity evaluation, geophysicists
have recently begun to use acoustic data, such as
those from the Sonic Scanner tool, to estimate
the fraction of vuggy porosity. One application of
these data is to ne-tune the cementation expo-
nent, m, in Archies water saturation equation.
Vugs tend to increase the cementation exponent,
while large intergranular pores do not. Use of
macroporosity fractions from NMR data alone
>
Pore size and geometry. Measurements from NMR logging tools are more
sensitive to pore size and geometry than are resistivity and other porosity
measurements. The gamma ray log (Track 1), resistivity logs (Track 2) and
porosity measurements (Track 3) are consistent throughout the interval shown.
The NMR data (Track 4) indicate a large increase in pore size above X,040 ft
that is not seen in the other measurements. (Adapted from Ramamoorthy et al,
reference 5.)
T
2
Distributions
Depth,
ft
X,050
X,000
0 100 gAPI
Gamma Ray
6 16 in.
Caliper
6 16 in.
Bit Size
0.1 1,000 ohm.m
Array 1
Array 2
Array 3
Array 4
Array 5
R
xo
Resistivity
45 15 %
Neutron Porosity
45 15 %
Array Porosity
3 13
PEF
1.95 2.95 g/cm
3
Bulk Density
0.3 6,000 ms
T
2
Log Mean
>
NMR porosity partitioning. When NMR logging tools were introduced to
the oil industry, the T
2
distributions were scaled as pore sizes. For a number
of reasons, this practice was abandoned. However, the concept works fairly
well for carbonates. Pore sizes are determined according to a range of T
2
distributions, and then the porosity is partitioned into macro-, meso- and
microporosity based on these measurements. The longest T
2
distributions
correspond to macroporosity, large pores and vugs. The shortest T
2
distributions respond to microporosity. Oil migrating into water-lled rock
displaces water in macro- and mesopores rst. Micropores generally remain
water lled.
TSFigure 07
Total porosity
Oil in place
0.5
microns
5
microns
Mesoporosity Macroporosity Microporosity
Porosity
below short
T
2
cutoff
NMR T
2
response
Porosity
above long
T
2
cutoff
31424schD7R1.indd 44 8/10/10 10:19 PM
Summer 2010 45
can result in elevated estimates of m because the
measurement is based on pore size, not shape.
Combining vuggy porosity estimates from full-
waveform acoustic data improves log-derived
estimations of the m exponent.
NMR data are also used to compute permea-
bility. The technique evolved from empirically
derived relationships, which work well in sand-
stones but are not always relevant in carbonates
because the pores may not be connected.
Relative permeabilities and fractional ow in
hydrocarbon zones may, however, be derived
from array resistivity log data when the well is
drilled with water-base mud.
15
The invading mud
ltrate acts as an uncontrolled two-phase ow
experiment that can be analyzed in a manner
similar to relative permeability measurements
conducted on core.
This mud-ltrate invasion method not only
provides information about in situ fractional ow
and relative permeabilities, it also improves the
accuracy of formation resistivity measurements
and water saturation estimates. The processing
involves forward modeling based on relative
permeability parameterization, radial invasion
models, petrophysical models and tool response
to specic conditions. The inputs required for
computing water saturations using Archies equa-
tionformation water and bulk formation resis-
tivitiesare more accurate when obtained using
this method, as are the ultimate computed uid
volumes. Even so, log analysts have discovered
that Archies equation may not be as reliable for
characterizing uids in carbonate reservoirs as it
is in sandstones.
Whats Wrong with Archie?
In 1942 Gus Archie laid the foundation for mod-
ern log interpretation by introducing a relation-
ship linking water resistivity, formation porosity
and formation resistivity to uid saturation
(right). Variables in the equationa, m and n
are empirically t based on reservoir characteris-
tics. In the absence of specic data they are
generally assumed to equal 1, 2 and 2, respec-
tively.
16
Assumptions in the formulamorphol-
ogy of the pore space, connectivity of the pores
and wettability of the rockare best suited to
>
A ternary diagram based on pore size. Carbonate pore geometry and size are
inputs to this ternary diagram, which indicates reservoir quality. On the lower left
side of the triangle, permeability is a function of grain size. For the upper section,
permeability is controlled by the volume of macropores. On the lower right, the
permeability is a function of both grain and pore size.
TSFigure 06
k = 0.35
2
( T2LM
)
2
Carbonate rocks with intergranular
T2LM is the
logarithmic mean of
the T
2
measurement.
porosity (no macroporosity)
Permeability, k, is controlled by
porosity and the average pore
(grain) size. k = 1.0 V
macro
/(V
meso
+ V
micro
) ] [
2
Carbonate rocks with abundant
macroporosity
We
pore throats)
ll-connected pores (large
Permeability is controlled by
porosity and the volume of
macroporosity (V
macro
).
100%
microporosity
100%
mesoporosity
Carbonate Pore System Classes and Permeability
100%
macroporosity
2
>
Archies water saturation equation (bottom).
Porosity and R
t
are log-derived measurements.
R
w
is either derived from water salinity or
measured from produced water and converted to
downhole temperature. Variables a, m and n are
empirically t based on reservoir characteristics.
They are assumed equal to 1, 2 and 2, respectively,
in the absence of specic data. A sensitivity
analysis (top) demonstrates the effects of varying
m and n on computed water saturation. First, n
is set to 2 and m is varied from 2.3 to 1.7 (Track
1). Next, m is xed and n is varied from 2.5 to 1.0
(Track 2). The baseline water saturation curve
using default inputs for m = n = 2 is presented in
both tracks (red curve). (Adapted from Grifths et
al, reference 17.)
TSFigure 06A
S
w
= Archies water saturation
R
w
= resistivity of formation water
R
t
= true formation resistivity
a = formation-factor multiplier
= porosity
m = cementation exponent
n = saturation exponent
%
n = 2,
m = 2.3 to 1.7
100 0 %
m = 2,
n = 2.5 to 1.0
100 0
Water Saturation Water Saturation
S
R
R a
m
=
t
w
w
n
9. For a thorough review of neutron capture spectroscopy:
Barson D, Christensen R, Decoster E, Grau J, Herron M,
Herron S, Guru UK, Jordn M, Maher TM, Rylander E
and White J: Spectroscopy: The Key to Rapid, Reliable
Petrophysical Answers, Oileld Review 17, no. 2
(Summer 2005): 1433.
10. Archie GE: Classication of Carbonate Reservoir Rocks
and Petrophysical Considerations, AAPG Bulletin 36,
no. 2 (1952): 278298.
11. Hassall JK, Ferraris P, Al-Raisi M, Hurley JF, Boyd A and
Allen DF: Comparison of Permeability Predictors from
NMR, Formation Image and Other Logs in a Carbonate
Reservoir, paper SPE 88683, presented at the Abu Dhabi
International Petroleum Conference and Exhibition,
Abu Dhabi, UAE, October 1013, 2004.
12. In NMR logging, transverse relaxation time, T
2
, results
from interactions of hydrogen atoms with their
surroundings, including effects of bulk uids, pore
surfaces and diffusion in magnetic eld gradients.
Short T
2
times correspond to small pores, and longer
T
2
times correspond to larger pores.
13. Hassall et al, reference 11.
14. Ramamoorthy et al, reference 5.
15. For more on this technique: Ramakrishnan TS,
Al-Khalifa J, Al-Waheed HH and Cao Minh C:
Producibility Estimation from Array-Induction Logs
and Comparison with MeasurementsA Case Study,
Transactions of the SPWLA 38th Annual Logging
Symposium, Houston, June 1518, 1997, paper X.
16. The a constant, a tortuosity or consolidation factor,
was not in Archies original equation but was added
later as a means of correcting for saturation in known
water-lled reservoir rocks. For more on this subject:
Archie GE: The Electrical Resistivity Log as an Aid in
Determining Some Reservoir Characteristics,
Petroleum Transactions of AIME 146 (1942): 5462.
Winsauer WO, Shearin HM, Masson PH and Williams M:
Resistivity of Brine Saturated Sands in Relation to Pore
Geometry, AAPG Bulletin 36, no. 2 (1952): 253277.
31424schD7R1.indd 45 8/10/10 10:19 PM
46 Oileld Review
siliciclastic rocks.
17
Although most water satura-
tion methods utilize some form of Archies equa-
tion, it is generally recognized that there are
problems with this approach when applied to
carbonates. Even Gus Archie stated that he
doubted the applicability of his equation in car-
bonate evaluation.
18
In addition, the complex nature of carbonates
makes determination of the a, m and n variables
difcult, and these values may change rapidly
throughout the reservoir.
19
Other problems with
using Archies saturation equation in carbonates
include matrix complexity, pore size heterogene-
ity, pore shape and distribution, variability in for-
mation water salinity and uncertainty in the true
formation resistivity measurement.
The process of lling the reservoir creates
some of the difculties encountered when using
Archies water saturation equation: Water lls
the pores initially and then hydrocarbons enter,
charging the complex carbonate structure. The
macropores ll rst, because they have the low-
est capillary entry pressure. A proportion of the
mesopores ll next and, because of capillary
pressure, micropores may remain water lled. As
a result of the basic nature of carbonate grain
surfaces, there is an afnity for crude oil, which
typically contains acidic components. Hence, the
pores that ll with oil may become oil wet, while
micropores that never ll with oil remain water
wet. This results in a mixed-wettability rock.
Moved by natural or injected water sweeping
through producing elds or by ltrate during
drilling, reservoir uids are displaced in the larg-
est pores rst. Because of the altered wettability
in the rock, these pores present the least resis-
tance to the ingress of the uids. Fluid capillary
effects and differences between the original
charging pressure and reservoir pressure during
production may result in some of the mesopores
remaining oil lled even as the macro- and micro-
pores are water lled. This creates a complex
uid distribution inside the pore network. Thus,
Archie parameters are different for the invaded
rock of the near-wellbore area than for the unin-
vaded zones of the same rock (above).
The complex wettability of carbonates makes
use of Archies saturation equation problematic
as well. Unlike sandstone reservoirs that are usu-
ally strongly water wet, most carbonate reservoir
rocks have some degree of moderate oil-wet char-
acter. Preferentially oil-wet surfaces, located on
the walls of meso- and macropores, have been in
contact with oil. This reduces the connectivity of
the water phase in the porous rock and contrib-
utes to an increase in the resistivity compared
with the value predicted by Archies equation.
On the other hand, micritic grainstightly
packed micron-size calcite crystals with sub-
micron poresare fully water saturated and
water wet and dramatically enhance the connec-
tivity of water in the medium. The effect of
micrite counteracts the effect of oil-wetness on
the rocks electrical properties. Carbonate rocks
with a large volume fraction of micrite may have
a resistivity similar to that of shaly sandstone
rocks. Carbonate rocks with little or no micritic
content, such as dolomite, may have a pro-
nounced opposite response typical of oil-wet
rocks. These resistivity behaviors can be modeled
by the connectivity equation.
20
In Archies saturation equation, the term for
formation water, R
w
, assumes a simple uid distri-
bution with a single value of formation water resis-
tivity. Complex uid distributions, such as mixed
ltrate or injection waters, are a departure from
>
Carbonate reservoir lling and resistivity measurements. Water (blue) originally lls the pore spaces of carbonate
reservoirs (left). As oil (green) migrates into the rock, large pores ll rst. If there is no connectivity, some pores may remain
water lled (center). Because resistivity tools measure through a path of least resistance (red line), the current may bypass
oil-lled pores (right), which will increase the measured resistivity. Thus the resistivity values may be substantially lower
than expected and not be representative of the true bulk resistivity.
TSFigure 08
density
, is the density porosity
matrix
, is the matrix density, or grain density
bulk
, is the tool measurement
fluid
, is the fluid density
matrix
density
bulk
matrix
fluid
=
Micropores
Mesopores Macropores Water-filled vug Path of least resistance
>
Sigma equation for water saturation. Standard values for the matrix sigma,
grain
, are shown (top),
although the measurement can be rened with spectroscopy data. Values for
water
can be calculated
using uid salinity, computed from log responses or directly measured from produced water samples.
This equation (bottom) provides a water saturation value that is not based on resistivity measurements.
TSFigure 09
Lithology
Sandstone = 4.3
Dolomite = 4.7
Calcite = 7.1
Anhydrite = 12
, cu 0 5 10 15 20 25 30 35
Clays
40 45 50
Fluid Gas Oil Fresh water Increasing salinity
density
, is the density porosity
matrix
, is the matrix density, or grain density
bulk
, is the tool measurement
fluid
, is the fluid density
S
w
= formation water saturation
= formation porosity
bulk
= measured formation capture cross section
water
= capture cross section of the water
grain
= formation grain capture cross section
HC
= hydrocarbon capture cross section
matrix
density
bulk
matrix
fluid
=
bulk
grain
w =
( )
grain
HC
( )
water
HC
( )