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Figure 1 - A Sales pitch on how to understand redox. Image taken from http://www.redoxmarketing.com/red-oxmarketing.html.
Table of Contents
IONIC EQUATIONS ............................................................................................................ 3
Precipitate reactions ....................................................................................................................... 3 Metal and acid reactions................................................................................................................. 3 Metal and carbonate reactions ....................................................................................................... 3 Acid and Base reactions .................................................................................................................. 3 Displacement Reactions .................................................................................................................. 3
IONIC EQUATIONS
Ionic Equations are short hand equations which can summarise a general reaction in very simple terms. Precipitate reactions In precipitate reactions the ions which form the precipitate are the only ions that are named e.g. Pb2+(aq) + 2Cl-(aq) PbCl2(s)
Metal and acid reactions The metal which is used is important, but the acid used can be any acid, but it is important to recognise that a salt and hydrogen are produced. Magnesium + hydrochloric acid magnesium chloride + hydrogen Magnesium + nitric acid Magnesium + sulphuric acid Magnesium nitrate + hydrogen Magnesium sulphate + hydrogen
Any acid can be represented by H+ because an acid by definition is a proton donor. Mg(s) + 2H+(aq) Mg2+(aq) + H2(g)
This ionic equation represents an acid reaction with a metal. Metal and carbonate reactions In this reaction the common facts are carbonates (carbonate ion CO3-) and hydrogen ions (H+) from the acids. Calcium carbonate + hydrochloric acid calcium chloride + carbon dioxide + water CO32-(aq) + 2H+(aq) CO2(g) + H2O(l)
Acid and Base reactions A neutralisation reaction is one in which the H+ (hydrogen ion) from an acid, combines with the OHions from the base to form water. Potassium hydroxide + hydrochloric acid salt + water OH- (aq) + H+(aq) H2O(l)
Displacement Reactions It is important to be able to understand the reactivity of metals, as one of the determining factors is that a more reactive metal will displace or push out) a less reactive metal from a solution of its salt. e.g. magnesium is more reactive than copper. Magnesium in copper sulphate solution pushes the copper out of solution and takes its place in the solution, e.g. magnesium + copper sulphate copper + magnesium sulphate Mg(s) + Cu2+(aq) Cu(s) + Mg2+(aq)
Reduction reactions are represented by: Loss of oxygen Gain of electrons Gain of hydrogen Decrease in oxidation number
Mg2+
H2
You can break this reaction into two half reactions. Mg Mg2+ + 2 Can you apply the rules with oxidation numbers? Can you apply the rules with loss and gain of electrons? 2H+ + 2 H2 Can you apply the rules with oxidation numbers? Can you apply the rules with loss and gain of electrons? OIL RIG is the acronym Oxidation is losing electrons; reduction is gaining electrons. (a) Which is oxidised? (b) Which is reduced? (c) Which is the oxidant? (d) Which is the reductant? More complex redox reactions REDOX reactions can become more complex. There are two important oxidising agents that you need to understand. The strongest oxidising agents (which in turn are reduced) are potassium dichromate (Cr2O72-) and potassium permanganate (MnO4-). There is a process to be followed and it uses the acronym KOHES When Cr2O72- is reduced it produces Cr3+ and MnO4- produces Mn2+ Cr2O72MnO42 Cr3+ Mn2+
It is important for you to understand that this is only a half equation where a substance is reduced. There will be another half equation for an oxidation reaction.
Using KOHES
K Balance the key element. Cr is the key element Cr2O72 2Cr3+
O Balance the oxygen on the LHS by adding enough water to the right hand side. Cr2O72 2Cr3+ + 7H2O
H Balance the hydrogen in the water on the RHS by adding enough H+ to the LHS Cr2O72- + 14H+ 2Cr3+ + 7H2O
E Balance it electrically by adding electrons to one of the sides. Cr2O72- + 14H+ + 6 (-2) S Add the states Cr2O72- (aq) + 14H+(aq) + 6 2Cr3+(aq) + 7H2O(l) (14+) 2Cr3+ + 7H2O (6+)
This is only one equation representing a reduction reaction. Now for the oxidation reaction. We know this is an oxidation reaction as there is an increase in oxidation number. Fe2+(aq) Fe3+(aq) +
You do not need to use the O and the H of KOHES as there is no oxygen present. Then you need to add the simultaneous equations together and eliminate the electrons Cr2O72- + 14H+ + 6 6Fe2+ Total equation: Cr2O72-(aq) + 6Fe2+(aq) + 14H+(aq) 2Cr3+(aq) + 6Fe3+(aq) + 7H2O(l) 2Cr3+ + 7H2O 6Fe3+ + 6
Hence there are two half reactions occurring. Zinc zinc sulfate Copper sulfate copper Zn2+(aq) + 2 ( oxidation) Cu (s) ( reduction)
Zinc is oxidised, but at the same time it is also the REDUCING AGENT or the REDUCTANT Copper sulfate is reduced to copper, however it then becomes the OXIDISING AGENT or the OXIDANT. Then add the two half equations together. The electrons cancel each other out and in every case you must ensure that this happens. Zn (s) + Cu2+(aq) Zn2+(aq) + Cu(s)
You can always refer to the reactivity series of metals to determine whether or not a displacement reaction will occur. This is a spontaneous reaction and can produce energy. The energy generated by such reactions can be harnessed and this is the basis for the working of batteries. One needs to make use of the moving electrons to produce electricity. Chemical energy can be harnessed to produce electricity.
Figure 3 Standard Electrode Oxidation and Reduction Potentials Values A Colley Original
The components then of this simple cell are: Two metals of different reactivity A connecting wire An electrolyte
A small electric current will be produced and oxidation will occur at the zinc electrode and reduction will occur at the copper electrode. Unfortunately this simple cell cannot be used to provide light on your bicycle in the dark. And hence the simple electric cell can be modified to produce a much more sustainable galvanic cell.
Most half cells contain a metal strip (the electrode) dipped into a solution of its ions. The wire connects the two electrodes provides a pathway for the electrons, which are able to move only along the electrodes and the wire. They cannot move in the solution. The electrodes and the wire form the EXTERNAL CIRCUIT. The two half cells are also connected by the SALT BRIDGE which contains another electrolyte. The purpose of the salt bridge is to provide ions for those lost or gained in the half cell. The movement of these ions within the electrolyte is called the INTERNAL CIRCUIT. The electrochemical series is strictly valid only for the conditions under which it was determined: A temperature of 25oC Pressure of 1 atmosphere 1M concentrations of solutions
In a galvanic cell, the stronger reductant is in the half cell with the negative electrode (anode). The stronger oxidant is in the half cell with the positive electrode (cathode). Another way to predict the electrode reactions is to remember that the higher of the two half cell reactions in the electrochemical series goes forward and the lower one is reversed. The higher half reaction occurs at the positive electrode and the lower reaction occurs at the negative one. In order to predict the voltage available from this cell, the formula that is used us as follows Eo = Eo - ER Where Eo is the oxidant and ER is the reductant. The answer will then be in VOLTS.
Electronic conductors
Electrodes are electronic conductors they conduct current by the flow of electrons. They may be made of a metal or graphite. Where a half cell contains a metal reductant, the metal serves as the electrode, for example a zinc electrode in the Zn2+/ Zn half cell. Where the reductant is not a metal the electrode is either graphite or a non reactive metal such as platinum, for example a graphite electrode in a Fe3+/ Fe2+ half cell or a platinum electrode in a Cl2 /Cl- half cell.
Further Examples
Can you determine the Eo values for the examples below?