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July 2013

TAKE A CLOSER LOOK AT COLOUR ANTIMICROBIALS IN ACTION MELT FILTRATION DEVELOPMENTS THE LATEST TRENDS IN TPEs

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Having led the way with high-quality digital-only magazines for the global plastics industry, AMI is now also making its titles available free-ofcharge on the iPad, iPhone and a wide range of Android-based smartphones and tablet computers. The dedicated apps for Compounding World magazine are now ready to download from Apples App Store and iTunes or from the Google Play Store. Just search for AMI Plastics. Current and past copies are available free-of-charge and new issues will be added to the apps as soon as theyre published. If you are using Apples latest iOS 5 operating system, then the magazines will appear in your Newsstand and new editions will be added automatically if you sign up for our free subscription. The Compounding World app is sponsored by Leistritz, a leading supplier of twin-screw extruders.

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CHECK OUT OUR OTHER FREE APPS: AMI has also launched free apps for its three other digital magazines Injection World, Pipe and Profile Extrusion and Film and Sheet Extrusion. Plus theres an additional AMI Conferences app featuring brochures for our forthcoming events. Simply search for AMI Plastics in iTunes, Apples App Store or the Google Play Store.

contents
05 Industry news
PAGE 17

The latest compounding industry news including international acquisitions and alliances, plus new investments and plant openings.

17 Rethinking biocides for plastics


The phase-out of some established biocides means that compounders are turning to alternative antimicrobials. Jennifer Markarian reports.

PAGE 25

25 Monitoring colour during the compounding process


Online colour control is an emerging technology with the potential to improve compounding quality and productivity, reports Pat Toensmeier.

35 Appearance is everything: controlling colour in plastics


Ron Beck, R&D Manager at Americhem, looks at how colour works, how it is perceived, and the implications for controlling colour in plastics.
PAGE 35

43 Whats new in colours


Recent developments in colour control and monitoring, including the latest instruments and technologies for measuring and sharing colour data.

47 Keep it clean with the latest melt ltration systems


PAGE 47

Peter Mapleston reviews recent developments in screen-changers and melt ltration systems from 12 suppliers in Europe, America and Asia.

59 Innovation drives TPEs ahead


Global demand for TPEs continues to grow, fuelled by material enhancements, design innovation and regulatory opportunities. Chris Smith reports.

63 New products: polymers and additives


PAGE 59

70 Compounder of the month: GCR Group - Granic 72 Dates for your diary

coming next issue


S PVC Plasticizers S Functional llers S Getting ready for K 2013
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Applied Market Information Ltd AMI House, 45-47 Stokes Croft, Bristol, BS1 3QP, United Kingdom Tel:+44 (0)117 924 9442 Fax:+44 (0)117 989 2128 www.amiplastics.com Head of business publishing: Senior editor: Contributing editor: Designer: Advertisement manager: Andy Beevers Chris Smith Jennifer Markarian Nicola Crane Claire Bishop E-mail: abe@amiplastics.com E-mail: cs@amiplastics.com E-mail: editorial@compoundingworld.com E-mail: claire@amimagazines.com Direct tel: +44 (0)20 8686 8139

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www.compoundingworld.com July 2013 | COMPOUNDING WORLD 3

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news

PolyOne to close six Spartech units


PolyOne has announced the closure of six of the 30 manufacturing locations it acquired through its purchase earlier this year of Spartech. The company said manufacturing at the six factories, which are all located in the US and include three compounding plants, will be relocated to other PolyOne units as part of a realignment of its North American operations. The former Spartech plants that will be closed are located at Cape Girardeau in Missouri, Donora in Pennsylvania, Evanston in Illinois, Lake Charles in Louisiana, Portage in Wisconsin, and Warsaw in Indiana. Compounding is carried out at the plants in Cape Girardeau, Donora and Lake Charles. The Spartech sheet production plant in Cape Girardeau will remain in operation. The closures will result in a overall head count reduction of around 250 and will cost some US$45 million over the next 12-18 months. The company expects the move to yield a pre-tax cost saving of around US$25 million in 2015. These actions are entirely consistent with our previously announced plans to integrate PolyOne and Spartech and to accelerate our specialty transformation, said Stephen Newlin, chairman, president and CEO of PolyOne. By combining our resources, we expect to better serve our customers with a more competitive cost structure, improved product quality and on-time delivery with increasingly innovative technologies. Newlin said the company expects to deliver at least US$65 million of synergies from the acquisition of the US$1.2 billion Spartech polymer compounds, concentrates, custom sheet and packaging business, which was announced in October last year and was completed in the spring of this year. PolyOne posted revenues of US$2.9 billion in 2012. Stephen Newlin: realigning American operations

www.polyone.com

Tosaf opens new film laboratory


Israeli compounder and additive masterbatch producer Tosaf has expanded its laboratory capabilities for the development of polymer film products at its headquarters at Afula in Israel. The new additions to the facility include a multi-layer co-extrusion blown film line, cast film line, corona surface treater and printing simulator. The laboratory has also gained a low-temperature climatic chamber and a QUV test system, allowing it to provide accelerated weathering testing of products for applications such as agricultural films. The QUV system includes a special greenhouse simulation mode, which simulates the high temperatures, humidities and UV exposure in demanding agricultural applications.
www.compoundingworld.com 

Rich Yu invests in additives


Rich Yu Chemical of Taiwan is constructing a new polymer additives plant in the Chang Bing Industrial Zone, on Taiwans west coast. Scheduled for completion in mid-2014, it will be the companys third production plant and will double its total capacity. The facility will produce

Tosaf has expanded its lab capabilities for developing formulations for films These new and expanded laboratory lines provide strong support to our own development activities. We can now test products by simulating both harsh environments and all the major film packaging production steps that are commonly used in the food and non-food industry, said Tosaf development manager Yafit Moyal. Founded in 1985, Tosaf is a joint venture between Megides and Ravago.

a range of high-performance antioxidants, UV absorbers, nucleating agents and PP clarifiers. Rich Yu has an office and a warehouse in the Netherlands to manage its REACH registrations and its additives distribution in Europe.

www.tosaf.com

www.richyu.com.tw
July 2013 | compounding world 5

news

Granic continues its expansion


The Granic division of GCR is starting up a new 55,000 tonnes/year compounding line this month at its La Bisbal del Peneds plant in Tarragona, Spain. It will takes its total masterbatch capacity to 165,000 tonnes/year. The company specialises in the production of PE, PP and PS masterbatches containing 75-85% calcium carbonate or talc. It only entered the masterbatch market five years ago with the installation of its first 55,000 tonnes/year compounding line at its headquarters in Barcelona, Spain. This facility will cease production next year and the line will be transferred to the Tarragona plant. La Bisbal del Peneds is located is just 10 km from Europes largest calcium carbonate mine and 200 km from the worlds largest talc GCR is expanding capacity at its compounding plant in Tarragona, mine. The companys fourth compounding line is scheduled to be added to the plant in the first half of next year, which will take its total capacity to 220,000 tonnes/year. Granic is marketed as an eco-friendly product targeted at a wide range of film, sheet, raffia, pipe, extrusion coating, and blow and injection moulding applications. GCR also includes Ciclic, a 35,000 tonnes/year plastics recycling operation. For more details on GCR and Granic, see the profile on page 70 of this issue.

www.granic.es

Ter Hell to outsource Terez compounding


Germanys Ter Hell Plastic is to close its compounding plant at Herne and outsource production of its Terez range of engineering plastic compounds to external suppliers. Ter Hell Plastic head of marketing Eva Masthoff told Masthoff said the strategic move will have no impact on its customers, which it will continue to service directly. We are working with partners all over the world, she said. Our Terez products will continue to be made on the base of our knowledge; we are still the development partner. Ter Hells Terez products include a wide range of performance engineering plastic compounds, including ABS, PA, PC and blends.

Gabriel picks latest Automatik pelletizers


Austrian masterbatch producer Gabriel Chemie is the first customer for Automatik Plastics Machinerys newly-launched Primo 200 E strand pelletizer, taking delivery of three units. According to Automatik, Gabriel Chemie trialled the Primo 200 E pelletizer system prior to placing its order, reporting high pellet noise levels as key attributes of the equipment. The 200 E version of the established Primo line of single-side dry-cut strand pelletizers was launched in January and features a 200-mm cutting width, the largest in the range. quality, easy batch changes, fast retooling and low operating

Compounding World that the Herne compounding operation (pictured below) would close by the end of the year. She said the cost of updating the facility, which began production in 1980, was not considered viable by the company.

www.terhell.com

www.maag.com
6 compounding world | July 2013 www.compoundingworld.com

photo: Frank Vincentz

news

Emerald completes expansion


US-based Emerald Kalama Chemical has completed its latest capacity expansion for its K-Flex non-phthalate plasticisers at its facility at Kalama in Washington state. The growing demand for our K-Flex platform, coupled with the success of our latest product innovations, has fuelled the need for our most recent expansion, said Shamsi Gravel, Emerald Kalamas product line manager for the Americas. Over the last several years, we have been expanding our range of products into new applications, Gravel said. The company has doubled K-Flex production capacity at the Washington site since 2011. It also commissioned a K-Flex production unit at its site at Rotterdam in the Netherlands last year.

Nordson is acquiring Kreyenborg and BKG


Nordson of the USA is acquiring the plastics processing activities of the Kreyenborg Group of Germany. The deal include two companies - BKG, which produces pelletizing systems, and Kreyenborg GmbH, which makes screenchangers and melt pumps. The two companies employ approximately 270 people and have additional operations in China, Malaysia and the USA. Revenues for the 2102 fiscal year were approximately E62 million. Jan-Udo Kreyenborg and Theodor Bruckmann are retiring as directors of the two companies following the sale of their shares. Jan Hendrik Ostgathe and Ralf Simon who already hold managing director roles will continue in these positions after the change in ownership. Nordsons president and CEO, Michael Hilton said: These businesses are highly complementary to our other recent acquisitions in the polymer processing space and fit our strategy of providing our customers with high-value, mission-critical melt stream components that will enhance the performance of their systems. Nordson, which is a leader in dispensing systems, has recently been increasing its activities in plastics processing equipment. Nordson will establish a presence in the compounding market through its acquisition of BKG Last year, the company acquired US-headquartered Xaloy, which is best known for its screws and barrels, but also makes screen-changers, melt pumps and pelletizing systems. Nordson has also purchased two manufacturers of flat extrusion dies in recent years US-based EDI in 2012, and Belgium-based Verbruggen in 2011.

www.emeraldmaterials.com

www.nordson.com www.kreyenborg.com

Compounding World Forum: space selling fast


More than half of the available exhibition places for the Compounding World Forum 2013 have already been sold. The new conference, which is organised by AMI and Comgoing on sale, said Kelly Cressman, AMIs conference coordinator. The exhibition area will be open to conference delegates during registration, the refreshments breaks and the evening cocktail reception. Companies that have already reserved their exhibition package include Aaron Equipment, Ametek Westchester Plastics, Asahi Kasei Plastics, Brabender Technologie, Brggemann Chemical, Excaliber Mineral, ExxonMobil/Vistamaxx, ICMA San Giorgio, Maag Automatik, Mixaco, Momentive, Pelletron, PMC, Saint-Gobain and Reduction Engineering. ExxonMobil/Vistamaxx, ICMA San Giorgio and Pelletron are also sponsoring the event. The remaining exhibition spaces are being sold on a first-come, first-served basis for $1,990, including one delegate place (which is usually priced at $990). To reserve your exhibition place, contact Kelly Cressman: kc@amiplastics-na.com, tel: +1 610 478 0800. To attend the exhibition, you need to be registered as a delegate for the conference. For more details, including the full conference programme, visit http://bit.ly/CWF2013p.
www.compoundingworld.com

pounding World magazine, will


take place on 10-11 December in Philadelphia, PA, USA. We have room for 24 exhibitors at the event, and 15 of the spaces have already been booked within weeks of
8

compounding world | July 2013

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news

Schulman calls off Ferro move


A Schulman has ended its attempt to acquire Ferro, following the rejection of its offer by the Ferro board and its decision not to enter into discussions. We have decided to look elsewhere for acquisition opportunities, Schulmans chairman and CEO Joseph Gingo said in the companys Q3 2013 results conference call with analysts. Gingo said that the companys strong balance sheet, solid cash flow generation and low leverage positions it to move ahead with its strategy of bolt-on acquisitions in its specialty plastics business, and that its M&A pipeline remains active and full. He cited the agreed acquisition of US thermoplastic resin and alloys supplier Network Polymers as one recent example. Gingo described Schulmans results for the third quarter sales of US$548.6 million compared to a Q3 2012 result of US$563.1 million as disappointing and the result of lingering economic weakness in Europe in particular. We continue to face inconsistent order patterns in our European markets, he said. The full analysts conference call transcript by Seeking Alpha can be read at http://bit.ly/Gingo.

Coperion supplies lines to BASF in Shanghai


German compounding machinery maker Coperion has delivered and installed the complete turn-key compounding lines for BASFs latest expansion of its engineering plastics facility in Shanghai, China. Built around Coperions ZSK twin-screw extruders, the BASF project includes feeding, compounding and pelletizing equipment, dryers, coolers, and full conveying and packaging equipment. Coperion also handled the design and planning of the plant, including the electrical, compressed air and water cooling systems. The project was managed by Coperions Modular Turnkey System (MTS) team, which includes engineers from its sites in Stuttgart in Germany, Ferrara in Italy and Shanghai in China, where much of the engineering was carried out. As reported in last months competence of our Shanghai production site, and from the close and constructive cooperation we are receiving from the experienced engineers at BASF, said Christian Bohnet, chief project manager for compounding plant at Coperion. The new Coperion lines installed at BASFs Shanghai facility

Compounding World, Coperion has recently added a new facility for assembling modular lines at its Shanghai site. Going forward, we will benefit from the continually improved efficiency and

www.coperion.com

TPEI plans factory expansion


US compounding equipment maker Technical Process & Engineering Inc (TPEI) is to invest more than US$1.6 million in an expansion of its manufacturing operation at Leighton in Pennsylvania, USA. TPEI is planning a 6,000 ft2 (560 m2) expansion to its existing 22,000 ft2 (2,000 m2) facility. It will expand its workforce by around 16. Founded in 1975 as a spare parts manufacturer, TPEI produced it first continuous mixer in 1985. It now offers complete compounding lines for the processing of a wide range of thermoplastic and rubber materials, delivering throughputs from around 25 to 7,500 kg/hr.

www.aschulman.com
10 compounding world | July 2013

www.tpei.com
www.compoundingworld.com

news

Techmer PM acquires TP Composites


US colour and additive masterbatch maker Techmer PM has acquired TP Composites, a custom compound manufacturer based at Aston in Pennsylvania, USA. TP Composites will be renamed Techmer Engineered Solutions (TES). All management and personnel will be retained and the company will continue to operate out of its facility at Aston. TP Composites is a great fit for our engineering compounds business, which we continue to develop with our long-time partner Mitsui Plastics, and is another key step in our growth initiative for the TES business, said John Manuck, chairman & CEO of Techmer PM.

Oxford Polymers adds its fourth compounding line


US-based technical compounder Oxford Polymers is commissioning a new US$500,000 compounding line at its plant at New Britain in Connecticut, USA. The investment includes a Crown Machine 72-mm twin-screw compounder plus materials handling, pelletizing and downstream systems. According to Oxford Polymers president Nicholas DeFelice, the line is in the late stage of commissioning with first production trials due to begin this month. We are at the final stage of debugging right now, he said. The new line the companys fourth large compounding line - will provide an additional 8 million lbs/year (3,600 tonnes/yr) of capacity, depending on product, and will take total capacity at the site to around 25 million lbs/yr (11,500 tonnes/yr). DeFelice said aside from the capacity gain, the additional line will also allow it to further optimise its production. With four lines we can specialise little bit more. It gives us more flexibility if the lines are specifically configured for colour mixing or glass feeding. The investment follows the installation of a 70-mm diameter line less than two years ago and underlines growing demand for Oxford Polymers engineered compounds. Last year we grew around 20% and this year we are on track to do the same, said DeFelice. Oxford supplies recycled PET from bottles for Pilots B2P pen Weve hit a nice sweet spot as a high-quality supplier. 80% of our sales are specified sales and we are driving into markets that are really into that: automotive, consumer goods items. The company has also won business from its decision four years ago to offer recycled products. Its highest profile application in this area to date is the B2P pen for Pilot, which uses post-consumer PET bottle waste.

www.oxfordpolymers.com

www.techmerpm.com

Compounding World app hits 5,000 downloads


The iPad/iPhone and Android apps for Compounding World magazine have exceeded 5,000 downloads in just 18 months since their launch. We continue to be delighted by the response to the In total, the five different apps for AMIs four plastics industry magazines and its conferences business have now been downloaded more than 25,000 times across the Apple and Android platforms. Our magazines are still mostly read online using computers, but more and more people are discovering the benefits of reading them on tablet computers and smartphones, especially as our apps mean that the magazines can still be read when youre offline, said Beevers. The apps for Compounding World, which are sponsored by Leistritz, provide free access to the current edition of the magazine as well as more than 20 back issues. The iPad/iPhone app can be found in iTunes or Apples App Store by searching for AMI Plastics. Alternatively visit: http://bit.ly/CWiPad. The Android app can be found in the Google Play Store by searching for AMI Plastics or by clicking on this link: http://bit.ly/AMIAndroid.

Compounding World apps, which are helping to grow the truly global audience for our magazine, said Andy Beevers, head of business publishing at AMI. European downloads account for 37% of the total, the Americas represent 33%, Asia stands at 26%, and The Middle East and Africa are at 4%.
12 compounding world | July 2013

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news

Colloids helps Duo cut costs


UK-based polyethylene packaging producer Duo UK has cut rejects while reducing its masterbatch usage by 5% through a partnership with its supplier Colloids. Duo supplies up to 125 million mailing bags each year to customers in the mail order and industrial sector, many of which demand high levels of opacity; the company guarantees a minimum 97% level. However, it was not entirely satisfied with the consistency it was achieving across its range. We produce products for likes of ASOS, J D Williams and F+F at Tesco, so providing a quality product is incredibly important, but in order to ensure our competitiveness and meet our environmental responsibilities, we also need to minimise wastage, said Duo UK operations director Dale Brimelow.
www.compoundingworld.com

Colloids carried out trials across seven colours of PE film and measured the opacity levels in correlation with Duos own opacity meters to achieved the required 97% level across seven thicknesses between 40 and 100 microns. It then developed a bespoke opacity chart which detailed the required masterbatch addition level for each colour and thickness so the company could avoid over-dosing. As a result, Duo says that it has reduced masterbatch usage by 5% and cut spool rejects by 20%. Duo is celebrating its 25th year in business this year and has just announced a E1.3 million investment in a new co-extrusion line, printing equipment and planning software.

www.colloids.co.uk www.duo-uk.co.uk

16-23 October Dsseldorf Hall 09 A60

Antimicrobials | additives feature

Rethinking biocides for plastics

Antimicrobials continue to play an important role in protecting plastics from damage by microbes, including bacteria, algae and fungi such as mould and mildew. However, the types of chemistries that are used for biocides compounded into plastics are undergoing major changes with the phase-out in Europe of the traditional workhorse biocide, OBPA (oxybisphenooxyarsine), due to concerns about the toxicity and ecotoxicity of arsine chemistry. Supply of OBPA to the EU market ended as on 31 January 2013 under the Biocidal Products Directive (BPD). Although there are several alternatives, none are equivalent to OBPA. Depending on the microorganism, the alternatives may not always be effective or may require different levels of active ingredient to be effective. Formulations using alternatives may need to be modied to ensure that they are stable and provide maximum cost efciency. Suppliers and their customers have been preparing for years for the potential need to replace OBPA, but it is still a major undertaking. Although OBPA supply is currently allowed in the United States, its use is coming up for a re-registration eligibility decision (RED) with the US Environmental Protection Agency (EPA) in 2014. This re-registration is being backed by OBPA supplier Troy Corporation. Its customers in all regions except Europe can continue to
www.compoundingworld.com

The phase-out of some wellestablished biocides means that compounders are turning to alternative antimicrobials both to protect plastics and to reduce hospital acquired infections. Jennifer Markarian reports
use OBPA without any service interruptions, says David Faherty, the companys vice president. However, the leading suppliers of OBPA, Akcros and Dow, are not supporting the RED. Akcros and Dow formed a strategic partnership on biocides in North America in November 2012. Under the agreement, Akcros is the exclusive channel partner for Dow Microbial Controls OBPA and isothiazolinones for the polymer markets in the US and Canada, promoting grades under the Intercide brand. Akcros plans to continue to supply OBPA as long as permitted into 2014 and as stock allows, says Dean Nichols, biocides
July 2013 | COMPOUNDING WORLD 17

additives feature | Antimicrobials

Other important biocide properties include heat stability, UV stability, and interaction with other additives in a formulation. To achieve the performance and especially the price/performance of OBPA is quite challenging, says Dr Heinz Katzenmeier, head of innovation at Sanitized. While no single substance is ideal for all applications, properties can be optimized for a specific applications requirements.

Improving stability
Sanitized recently introduced two new products for PVC with improved stability in specific applications. Sanitized PL 12-32 has high water resistance and UV stability, making it suitable for outdoor applications. Sanitized PL 12-33 has high thermal stability to withstand high processing temperatures while retaining transparency; it is targeted for indoor applications, such as flooring and furnishings. Both formulations are designed to reduce initial discoloration and yellowing in use. Sanitizeds new PL 12-32 has high water resistance and UV stability for outdoor PVC applications product manager for Akcros. Several chemistries can be used as alternatives to OBPA in plastics. The primary options are the wellestablished isothiazolinones, which include n-octylisothiazolinone (OIT), dichloro n-octyl-isothiazolinone (DCOIT), and others, such as butylbenzisothiazolinone (BBIT). Other alternatives include Folpet, zinc pyrithione, silver and iodo-propynlbutyl carbamate (IPBC). Katzenmeier says that these combinations of active ingredients are fully able to replace OBPA in the relevant applications. Another new product, Sanitized PL 25-36, is a clear solution with no dispersed particles that is compatible with various polymer matrices, such as PU or PVC. The patent-pending product causes no turbidity and is designed for applications where high clarity is demanded, such as PVC curtains or indoor flooring. A field test at the University of Manchester is currently underway with PVC flooring containing PL 25-36 to demonstrate efficacy under real conditions, and results to date have exceeded expectations, says Katzenmeier. In addition to efficacy and stability, formulators must consider potential interactions with other additives, such as heat stabilizers, antioxidants, and light stabilizers, says Nichols. He adds that Akcros, which produces a wide variety of additives for PVC, has carried out extensive development work to solve interaction issues. One of these solutions is a new isothiazolinonefriendly stabilizer for flexible PVC. Initially these products are available in the EU, but similar products are being rolled out for the US market, says Nichols, who notes that Akcros is also developing stabilizers that are friendly to other biocides. Katzenmeier notes that Sanitized has built up an empirical database that is used to check for expected interactions between recommended antimicrobials and the stabilizer used by a customer. Sanitized has also started a publicly funded project with an academic institution that will scientifically investigate these complex interactions. Some bio-based plasticizers, such as soybean-oil derivatives, levulinic ketals, glycerol esters, and
www.compoundingworld.com

Evaluating alternatives
When choosing a biocide, formulators need to look at the spectrum of efficacy against various types of microbes and at the cost to dose at the level needed for efficacy. One measure is minimum inhibitory concentration (MIC), which shows inherent activity of the biocide against a particular microorganism. Another measure, not shown by MIC, is the availability of the active ingredient on the plastic surface, which depends on several factors, including the dosing level and the biocides migration rate through the finished plastic part. The migration rate is affected by the water solubility of a biocide. Although it is necessary for the active ingredient to migrate to the surface to be effective, if it migrates too quickly it can lose efficacy over time. Highly water-soluble actives may show visually impressive zones in agar plate tests, but are more prone to leach out of plastics more quickly than often desired, especially in exterior and high-moisture applications, notes Nichols. Conversely, low watersoluble actives, such as silver and DCOIT, dont show such zones in agar plate tests, which, Nichols warns, can lead to improper conclusions that they cannot be effective.
18 compounding world | July 2013

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additives feature | Antimicrobials

Sciessent reports growing use of silver antimicrobials in catheters

isosorbid diesters, are more susceptible to microbial attack compared to conventional, phthalate-based plasticizers. Users who switch to natural plasticizers may require higher levels of biocide, or, in some cases, may need to introduce biocides to products that previously may have been only moderately or even unsusceptible to microbiological attack, comments Nichols. In addition, says Katzenmeier, the tendency of some bio-based plasticizers to cause discoloration is higher, and the whole system including plasticizer, stabilizer and antimicrobial additive must be fine-tuned to achieve good performance in terms of antimicrobial efficacy as well as low discoloration. It is generally understood in the industry that when a formulation is changed, the impact on all properties, including susceptibility to microbiological activity, must be considered, adds Nichols. Microbiological laboratory tests can be used to determine differences in susceptibility.

Lise Moloney, director of business development for healthcare at Sciessent, in a February 2012 article in Compounding World on Specifying silver antimicrobials for medical devices (http://bit.ly/sciessent). We continue to see interest in all the major device-related infection areas: central venous catheters and accessories to central lines (like connectors), urinary catheters, endotracheal tubes and wound dressings and closures, reports Moloney. I think the biggest use and greatest success of antimicrobials in FDA-cleared devices has been in central venous catheters, where the pathogenesis of catheter-related bloodstream infection is wellunderstood and accepted. The need to prevent microorganisms from colonizing the external and internal surfaces of the catheter is critical to preventing these infections. Data published in 2012, for example, found a 90% reduction in catheterrelated bloodstream infections using Agion-treated umbilical venous catheters in pre-term infants. There is also an increasing interest in antimicrobials for surfaces in patient-care areas. Adoption in these applications has been slower because it is harder to demonstrate the direct benefit of treating these types of surfaces and to achieve regulatory clearance for claims against human pathogens than it is with indwelling medical device, says Moloney. Purchasing groups and infection-control practitioners want to know what the benefit will be before they switch to an antimicrobial product.We will see greater demand and acceptance for these products as more data is generated to show a link between surfaces in the healthcare environment and patient outcomes, predicts Moloney. Other areas of growth for silver antimicrobials, outside of healthcare, include food and water products, she adds. BASF, which offers Irgaguard silver-ion antimicrobials for industrial applications, supplies fully compounded polymer systems containing medical-grade, silver-ion releasing HyGentic additives for medical

Silver solutions
Silver-based antimicrobials, primarily those that release silver ions, are effective against bacteria but require higher concentrations to be effective against fungi and algae, thus they are not seen as cost-effective alternatives to OBPA for traditional plastic protection. The use of silver-ion antimicrobials is, however, growing in medical applications. Awareness of hospital acquired infections (HAIs) has led to increased use of antimicrobials in medical devices and other surfaces in healthcare settings, such as masks, gowns, equipment and furnishings. Silver has a long history of efficacy against bacteria, and has been found to be effective against antibioticresistant organisms, such as MRSA. This was covered by

EU labelling requirement changes


The Biocidal Products Regulation (BPR, Regulation (EU) 528/2012 ) will replace the Biocidal Products Directive (BPD) on 1 September 2013. As in the previous directive, the approval of active substances takes place at Union level and the subsequent authorisation of the biocidal products at Member State level. This authorisation can be extended to other Member States by mutual recognition. The new regulation also allows for Union-level authorisation. The BPR includes a requirement (Article 58) that articles treated with biocides must be labelled as such and must include the chemical names of the active substances and what function they have. In addition, the regulation requires that claims must be substantiated. While some documents note an implementation date of September 2016, this date applies to yet-unregistered active ingredients, and the labelling requirements are expected to go into effect 1 September 2013 for treated articles made in or imported into the EU. For details, visit: http://bit.ly/biocide

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compounding world | July 2013

www.compoundingworld.com

Antimicrobials | additives feature

applications. Grades include HyGentic SBC (styrene butadiene copolymer), HyGentic PA (glass-filled nylon) and HyGentic SA (acrylic modified polystyrene); custom formulations can also be developed in a wide range of plastic materials. BASF is currently developing products that provide added functionality beyond antimicrobial performance, says Stephen Zlock, business development manager for medical device materials at the company. For example, a polyurethane compound with both anti-thrombotic and antimicrobial performance for vascular access devices is in advanced development. PolyOnes WithStand antimicrobial additive solutions, available since 2010, are targeted for medical devices, medical packaging, and other healthcare applications. Last year, PolyOne launched Smartbatch HC additive concentrates, which combine WithStand antimicrobials and OnColor HC colorants for healthcare applications. Last year Clariant added Sanitized MedX silver antimicrobials, which can also be combined with pigments, to its line of Mevopur masterbatches for medical applications. Targeted applications include catheters, surgical instruments, and preservative-free pharmaceutical packaging. Plastics Color Corporation (PCC) recently introduced silver-ion based MicroBlok antimicrobial compounds targeted for medical device, medical packaging, appliance and other consumer markets. Fred Jhaveri, PCCs global technical manager, says that the additive inhibits the growth of bacteria which may cause stains, odours and product deterioration. supplies, healthcare environments, housewares and others. RTP Company uses various organic and inorganic antimicrobial additives in its masterbatches and ready-to-use compounds to meet the needs of specific application requirements. Earlier this year, Sabic launched nine new antimicrobial compounds featuring silver technology. The company says that they have been tested for log reduction values according to ISO 22196-2007. Five of the grades provide a high antimicrobial effect with log reduction values above 4, representing more than a 99.99% reduction in pathogens. The other four compounds have a lower antimicrobial effect with log reduction values below 4, representing a 99.0 to 99.99% reduction in pathogens. The new grades are based on the four Sabic resins that are most commonly used in medical devices: Lexan EXL copolymer, Lexan PC, Xenoy PC/PBT, plus PP resins with and without glass fibre reinforcement. The company says that its optimised antimicrobial compounds offer advantages over adding antimicrobial masterbatch to a base resin, including more uniform distribution of the active ingredient. It also says that its expertise in colour and effects means that it can provide precise control over clarity, a property that can be impacted by antimicrobials. Target applications include fluid and drug delivery systems, surgical instruments, monitoring and imaging devices and durable medical equipment such as

RTP is using NanoBioMatters BactiBlock, which combines silver-ion technology and a nanoclay carrier

Nano-technology options
NanoBioMatters BactiBlock additive is a silver-ion based technology in a nanoclay carrier. The antimicrobial has been used in Europe commercially since 2010 and received EPA registration for use in the US in 2011. The primary difference between BactiBlock and other silver-based solutions is the clay carrier, which has a synergistic effect and works as an efficient delivery system with long-term durability, says Paul Kennedy, business development manager for North America at NanoBioMatters. The ionic silver is linked to the clay surface, which creates a uniform distribution of the active species and prevents platelet agglomeration to ensure additive dispersion throughout the polymer matrix. Several BactiBlock grades are available for a range of polymers and applications. Last year, compounder RTP Company announced that it would use BactiBlock in antimicrobial compounds targeted for applications including furniture, athletic equipment, personal-care items, office
www.compoundingworld.com 

July 2013 | compounding world

21

additives feature | Antimicrobials

Sabics new antimicrobial compounds can be used for medical equipment like healthcare scanners

hospital beds and operating tables. Other potential applications outside of healthcare include consumer electronics, automobile interiors, business equipment, or any other surface where there is a desire to reduce the potential transfer of pathogens. Americhem introduced nShield masterbatches in 2012 for inhibiting odourcausing bacteria growth in fibre and plastics for applications including synthetic turf and automotive interiors. Americhem says that the additive is non-migratory and resists discoloration for long-lasting aesthetic appeal. Troys Faherty says that the company has seen some migration away from silver and that it has introduced alternatives, with more in development. Troys Micropel 1000, for example, is designed to impart surface antibacterial properties and offer comparable performance to silver but in a more cost-efficient manner, says the company. Foster Corporation supplies custom formulations of medical-grade polymers containing either silver or polymeric-based antimicrobial compounds that reduce bacterial infection in catheters and sustained bodily fluid contact applications. Last year, Foster announced a partnership with Biosafe to develop and market Biosafes polymeric additive technology based on cationic quaternary ammonium salt, which is seen as a cost-effective alternative to silver additives for infection-resistant medical devices.

selecting and applying antimicrobial additives at the Compounding World Forum 2013, which is being held in Philadelphia, PA, USA on 10-11 December. In addition, Dr Larry Acquarulo, CEO of Foster Corporation, will give a paper at the event entitled Adding functionality and value to medical compounds with novel reinforcements, fillers and additives. For more information on the conference, visit http://bit.ly/CWF2013p. Dr Manish Nandi and Lynn Colucci-Mizenko of Sabic will discuss a multi-pronged approach to meeting HAI challenges with specialty engineered thermoplastics at the Medical Grade Polymers 2013 conference, which takes place in Boston/Woburn, MA, USA, on 17-18 September. For details, visit http://bit.ly/MGP13. Click on the links for more information:

More information
Lise Moloney, director of business development for healthcare at Sciessent, will present a paper on

www.akcros.com www.americhem.com www.basf.com www.biosafe.com www.clariant.com www.fostercomp.com www.nanobiomatters.com www.plasticscolor.com www.polyone.com www.rtpcompany.com www.sabic.com www.sanitized.com www.sciessent.com www.troycorp.com

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Colour monitoring | process feature

Online colour control is an emerging technology with the potential to improve the quality and productivity of compounding, reports Pat Toensmeier

Monitoring colour during the compounding process


Maintaining colour control during compounding is time-consuming and labour-intensive. The conventional process of taking samples, creating plaques, running laboratory tests and adjusting colour when it goes off-spec can easily take two or more hours, which limits the number of times it can be done during production. As a result, there is growing interest in online colour control for the potential advantages it provides in speed, productivity and savings. At least two companies, assisted by one university and several manufacturers of compounding lines, are promoting developments in this area. The suppliers of these systems are Equitech International in the US and ROC Rapid Optical Control of Germany. Equitech supplies the Equispec Online Color Spectrophotometer (OCS), a closed-loop control system that works by inserting reection or transmission bre-optic probes into the melt, typically through a standard transducer port located right after the die. The reection probe analyses opaque resins and the transmission probe measures transparent polymers. The system can be congured to measure colour every 5 seconds, says the companys sales manager, Bob Furlan.
www.compoundingworld.com

ROC provides the ColorControl System, a remote unit with several components that collect pellets, transport them pneumatically to the unit for measurement, analyse them with an image-processing spectrophotometer in a test cycle of 2.5 minutes, and restores colour to spec in as little as 30 minutes, says Peter Dietrich, board member of the company. Colour correction in both systems is done with miniature feeders that dose the necessary amounts of colour to bring a compound in spec. Though the technologies differ, the companies cite similar advantages from the use of their equipment. The main benet is the time it takes to detect and begin correcting off-spec colour minutes compared with 2-3 hours using conventional procedures. Other advantages include precision analysis. Both systems have software that correct for process-related inuences on colour, whether thermochromatic, as with the Equispec OCS, or stress whitening and other cutting defects caused by pelletizing, as with ColorControl. The ability to rapidly detect and x colour problems means that less compound is lost to waste, reducing scrap and material cost. Fast detection and resolution

Teknor Color uses a special pre-production process to predict how well masterbatches will turn out

July 2013 | COMPOUNDING WORLD

25

process feature | Colour monitoring

A KraussMaffei Berstorff twin-screw compounder fitted with three Equitech colour spectrometers. Two are side-by-side in the die plate: a reflection probe (foreground) and a transmission probe. A second transmission probe is on the side of the die plate

of colour problems improve productivity, which means that compounders complete runs faster and thus free machine time for more jobs, increasing revenue and profitability, and perhaps even the need to invest in a new line to expand capacity. Reducing the time required to compound materials lowers energy use and contributes to reductions in electricity and other process-related expenses. Both systems can also be used as diagnostic and process-control tools for compounding lines. The companies say that their equipment develops data about feeder stability, screw wear, temperature profiles, screw speed and other parameters. Colour measurement with both systems can, moreover, be done with one operator, which cuts back on labour expense. KraussMaffei Berstorff in the US promotes the Equispec OCS system to customers, and has installed demonstrators on some of its compounding lines. The system is about as accurate as you can get, says Martin Mack, vice president of research and development for the compounding machine maker. He says that interest in online colour measurement and control is growing among compounders. There is a learning curve involved with the system, as with any technology, he acknowledges. But once compounders understand the operation and are comfortable with it, they see the positive impact of online control. Online monitoring opens up every inconsistency in colour, no matter how slight, and sometimes surprises operators, he adds. Masterbatch compounders in particular find both systems extremely sensitive to variations, especially when transitioning from one colour, such as yellow, to another one, like blue. In a case such as this, both companies say that traces of yellow that would be undetectable to the eye can be measured with the
26 compounding world | July 2013

Equispec OCS or ROC ColorControl for as long as 30 minutes after a changeover. The systems also perform well when compounding recyclate, a material that can have a lot of inconsistency when loaded into a hopper. The closed-loop monitoring and control of the Equispec OCS detects colour shifts immediately in compounded recyclate and automatically corrects them to assure uniform pellets. The ROC ColorControl does this as well, though after colour measurement of pellets. Even polymerization lines use systems from both companies for colour control, including transparent resins such as polyethylene terephthalate, polystyrene and polycarbonate. With the transparent materials the benefit is in making certain no yellowing or other discolorations occur. The advantages are also economic. Dietrich points to one major resin producer that installed two ColorControl systems on its compounding lines in Europe. The company, which he declines to identify for reasons of confidentiality, substantially improved colour control, along with the productivity and profitability of operations. Two other European resin producers that use the system were able to increase compounding capacity 40-60% entirely through the productivity gains of the technology, he says. Clearly, there are compelling reasons to consider online colour control, though many compounders, notably those that specialize in masterbatches and other small runs, are currently unconvinced. One is John Wood, technical manager at Teknor Color in the US. Wood believes that online colour control is practical for large-run compounding, but doesnt think it suits the tight tolerances, specialty colours and small volumes that Teknor specializes in with its masterbatches. You would need larger production runs than we do for it to be effective, he
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process feature | Colour monitoring

says, adding that other concentrate houses probably think the same way. Wood says that Teknor uses conventional test methods to measure colour, as well as a special pre-production process the company developed that has been successful in predicting how well masterbatches will turn out. He declines to reveal details about the process, calling it a competitive advantage, but notes that its success rate is high. Furlan says Wood voices concerns he hears from others. Though online colour control technology has been around for a while, it is still not well understood by most compounders. His companys technology is suitable for all processes and colours, he insists, while continuous measurement has benefits in colour consistency and how well a process runs. The Equitech and ROC technologies produce the same result colour control but in markedly different ways. The Equispec OCS system calculates the black and white ratios in a compound (L*), then how much red and green (a*) and blue and yellow (b*) it contains, based on an optical signal transmitted to the spectrophotometer from the melt probe. The resulting numbers are used to determine if colour is in spec. The system compares these values with a pre-programmed colour formulation, expressing them in L*a*b*, L*c*h, Hunter Lab or XYZ units, and provides a trend plot and 2-D colour space plot. Furlan says the technology is accurate to less than one half of one unit. Most people are unable to distinguish between a colour drift of one and two units. The systems Millennium 3 UV-VIS spectrophotometer has a wavelength range of 380-780 nanometres The ROC ColorControl system measures pellet colour in 2.5-minutes cycles

(nm) for reflected colour, and 230-820 nm for transmission. It uses a xenon flash lamp that generates up to 250 pulses in 500 milliseconds. Colour data is stored in the PC-based computing system, which runs Equicolor for Windows software. Stored data lets users develop process archives and run trend histories. The computer has a 12.1-inch touchscreen, Ethernet port, and comes with OPC tags that allow communication to the process control system. Colour control is maintained by the use of special gravimetric feeders, which selectively add colours to a compound based on the closed-loop data to correct imbalances. Furlan says the closed-loop control is a huge benefit for its immediate feedback. He declines to discuss specifics about system price, but says the return on investment for most compounders could be as little as 4-6 months. ROCs colour control technology samples compounds in pellet form. The measuring unit is set up in a clean, air-conditioned location, which can be up to 300 metres (1,000 ft) from the compounding line owing to the length of its pneumatic transport line. The process begins with collection of a small amount of pellets. Samples are continuously collected over a programmed period of time, typically 1-20 minute. The pellets are automatically homogenized within the ContiSampling unit, after which 35 ml (about 1,000 pellets) are sent to the ColorControl unit in a special transport carrier. Each sample represents the average production for a specific period of sampling time. Because the ColorControl operates in a stable measurement environment, the pellets are the only variables. Since pellets and colour are solidified, no changes to colour development need to be calculated. At the ColorControl unit, pellets are unloaded onto a vibratory table, which spreads them out for analysis. When the vibration stops pellets are analysed by the image-processing spectrophotometer, in a process that takes 2.5 minutes. Before every measurement cycle the instrument is calibrated for white and black balance. Afterwards, the software analyses images. Every measured pellets colour is based on up to 1,500 pixels. Each pixel contains a full-spectrum colour wavelength ranging from 500-700 nm in 10-nm intervals. This data, expressed as CIELAB L-a-b values, is used to determine if the colour is in spec. Dietrich says that the self-calibrating software is programmed to filter out stress whitening on the edges of pellets and cutting defects from the pelletizer, along with the surface of the table. The repeatable measuring accuracy of strand- or underwater-cut pellets is high,

28

compounding world | July 2013

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process feature | Colour monitoring

formulation, Dietrich says. ROCs experience shows that 8-12 SPCs correct 90% of colour-control problems. The amount of colour used to bring a run back on spec, moreover, is small: 0.5-2 kg (1.1-4.4 lb) per hour for a line running 900-1,000 kg (1,980-2,200 lb) of compound hourly. Importantly, an operator monitors the effect of a correction in real time. Each ColorControl unit can be used on up to six compounding lines simultaneously. CEO Jens Dietrich stresses the economic benets of the ColorControl system. He cites major savings in manpower and electricity (since stop time is drastically reduced owing to fast colour measurement results), and signicant increases in productivity. Operators also acquire skills through use of the system that enable them to more precisely monitor, Equitechs reection probe accesses melt through a standard adapter opening and is used to analyse the colour of opaque resins with an average of less than 0.1 CIE-Lab points. This degree of precision cannot be achieved with most standard laboratory test processes, he adds. Once an operator receives the measurement results, he corrects off-spec colour by using the ColorDosage system, which comprises six small gravimetric extruders per production line, each containing singlepigment concentrates (SPC) with concentrations of 1-60%. The SPCs represented by the six feeders are usually black and white (for the L value), red and green (for the a value), and blue and yellow (for the b value). Other concentrates can be used depending on Click on the links for more information: adjust and control production. ROC has found that with the system, compounders achieve greater product acceptance rates by customers, due to fewer colourquality errors. ROC works with pelletizing systems maker Gala Industries and the University of Darmstadt in Germany in testing the technology. Dietrich says that 26 compounding lines running 100,000 tonnes/year currently use the system. Online colour control is an emerging technology for compounders. While it requires more promotion throughout the industry and a clear understanding by users of its benets, the competitive advantages and bottom-line protability the technology provides should be an easy sell. The technology may, in fact, become a requirement as compounders look to expand business by enhancing their capabilities.

S www.equitechintl.com S www.roc-gmbh.com S www.kraussmaffei.com S www.teknorapex.com

AMI Strategy Seminars


These one-day seminars are given by an AMI director and provide invaluable insights into market trends and industry strategies. They are held in small groups and provide ample opportunities for questions and discussions.

15 October 2013: Cologne, Germany 9 December 2013: Dubai, UAE


Contact: Katy Cheng, kb@amiplastics.com, +44 117 924 9442

www.amiplastics.com/seminars

Turn page for the full programme

The international conference on business strategies and new technologies for compounders

December 10-11, 2013


Hilton Philadelphia City Avenue, Philadelphia, Pennsylvania, USA
Images courtesy of: Coperion, Foster Corporation, PolyOne, Renault, and Teknor Apex

SPECIAL OFFER: Save $200 if you register before November 1, 2013


Organized by: Applied Market Information LLC & Compounding World Sponsored by:


Tuesday, December 10, 2013 8:00 9:00 Registration and welcome coffee Opening announcements

C O N F E R E N C

SESSION 1 THE CHANGING BUSINESS OF COMPOUNDING

December 10-11, 2013 Hilton Philadelphia City Avenue, Philadelphia, PA, USA
Applied Market Information and Compounding World magazine are pleased to announce the Compounding World Forum, taking place December 10-11, 2013 at the Hilton Philadelphia City Avenue, in Philadelphia, PA, USA. This new conference features a high-level program brought together by the editorial team of Compounding World, exploring and developing many of the magazines most popular themes in a live event. It will provide an excellent opportunity for discussion and networking between the international panel of speakers and delegates. The conference will cover business strategies and new materials technologies, as well as providing practical advice on getting the most from compounding lines. The primary focus will be on the production of technical compounds based on engineering thermoplastics, performance polyolefins and thermoplastic elastomers. Key end-use markets that will be addressed include the automotive, medical, electrical/electronic and consumer goods sectors. A wide range of polymer and additives technologies will be covered including electrically and thermally conductive compounds, antimicrobial formulations, fillers and reinforcements, flame retardants, bio-based materials, and anti-counterfeiting techniques. Strategic business and production issues will also be addressed, including growing a compounding business in a global marketplace, improving sustainability, clean compounding for medical markets, and responding to emerging regulations. In addition, leading experts will discuss how to get the very best from compounding lines with a wide range of practical tips and advice.

9:10 9:40 10:10

Analyzing changes in the global compounding industry Mr. Andy Beevers, Publisher/Editor, Compounding World magazine, APPLIED MARKET INFORMATION Ltd., United Kingdom Growing a profitable formulating and compounding business in a dynamic, global economy Mr. Roger Avakian, Vice President, Scientific Development, POLYONE CORPORATION, United States Implementing clean compounding to meet the needs of the medical market Mr. Paul Burke, Vice President of Manufacturing, TEKNOR APEX, United States

10:40-11:10 Coffee break sponsored by: 11:10 11:40 Metal replacement: Finding practical solutions with technical compounds Mr. Jeffrey McCoy, Manager, Marketing & Business Development, A. SCHULMAN INC., United States Responding to changing regulations in America and beyond Ms. Melissa Hockstad, Vice President - Science, Technology & Regulatory Affairs, SPI: THE PLASTICS INDUSTRY TRADE ASSOCIATION, United States

SESSION 2 ADDING VALUE TO TECHNICAL COMPOUNDS 12:10 Combating piracy with innovative anti-counterfeiting additives for thermoplastics Mr. Stuart Swain, Director of Sales and Marketing, CHROMA CORPORATION, United States

12:40-2:10 Lunch sponsored by: 2:10 2:40 3:10 Selection and application of antimicrobial additives in thermoplastic compounds Ms. Lise Moloney, Director Business Development, Healthcare, SCIESSENT, United States Pushing the limits of polypropylene developing the worlds first all-plastic, mono-material automotive tailgate Mr. Anis Tebib, Marketing Manager Automotive, STYRON, Germany Flame retardancy of engineering plastics Dr. Martin Klatt, Senior Manager Research, BASF SE, Germany

CONFERENCE HOTLINE Contact: Ms. Kelly Cressman, Conference Coordinator Tel: +1 610 478 0800 Fax: +1 610 478 0900 Email: kc@amiplastics-na.com

FIVE GOOD REASONS WHY YOU SHOULD ATTEND: 1. Hear leading experts discuss key trends in technical compounding 2. Discover new additive and materials technologies 3. Learn practical tips for getting the most from compounding lines 4. Gain insights into global market trends and business strategies 5. Network with other professionals in the compounding industry

3:40-4:10 Coffee break SESSION 3 IMPROVING SUSTAINABILITY 4:10 4:40 5:10 A profitable path to sustainable compounding Mr. Jack Leahy, Vice President of Manufacturing, TECHMER PM LLC, United States Engineered wood fibers for a new generation of biocomposites Mr. Christophe Chambonnet, Global Manager, Woodforce, SONAE INDUSTRIA (WOODFORCE), Canada Compounding of bio-based plastics and natural fibers Mr. Dean Elliott, Lab Manager, ENTEK EXTRUDERS, United States

5:40-7:00 Cocktail Reception

P R O G R A M
Wednesday, December 11, 2013 8:30 9:00 Welcome coffee Opening announcements

Turn page for booking details

Save $200
Register before November 1, 2013 and save $200
CONFERENCE VENUE Located on the East Coast of the United States, Philadelphia has a major international airport and is just hours away from New York and Washington DC. The city sights include historic buildings, museums, shopping malls and beautiful parks. Philadelphia offers its visitors a multicultural experience with many different types of dining and entertainment. SPONSORSHIP & EXHIBITION SPACE With an exhibition running alongside the conference as well as a range of sponsorship opportunities, there are ample ways to make sure your company stands out at the conference. All options have proven to be successful marketing tools and will effectively increase brand awareness. The table top package includes one complimentary delegate space and allows companies to display their products and services to a highly targeted audience. Sponsorships will guarantee your company logo will be included on all conference promotions and the event website. To book your table top or secure your sponsorship for the Compounding World Forum 2013 please contact the Conference Coordinator. ORGANISED BY: APPLIED MARKET INFORMATION LLC Applied Market Information LLC is the North American operation of Applied Market Information Ltd., Europes leading supplier of plastics consultancy and information services to the global plastics industry. AMI LLC can offer the full range of AMI services and products to North American clients.Together with our well-established European-based operations this means AMI is well placed to provide a truly global research capability to our clients. Based in Reading PA, Applied Market Information LLC can supply all of AMIs European directories and CDs and is developing a whole new range of products for the North American market. Its range of specialized services cover individual consulting services, multi-client reports, conferences and publishing. To find out more about AMIs conference program or any of our other services and products visit our web site at: www.amiplastics-na.com or call the AMI LLC office at: +1 610 478 0800 or email: consult@amiplastics-na.com COMPOUNDING WORLD MAGAZINE Compounding World is the monthly digital magazine for the global plastics compounding industry. Published by AMI, it is available free-of-charge online and via free apps for iPads, iPhones and Android-based devices. www.compoundingworld.com

SESSION 4 ADDING ELECTRICAL AND THERMAL CONDUCTIVITY 9:10 9:40 Adding electrical and thermal conductivity to plastics compounds Ing. Christine Van Bellingen, Product Manager, Carbon Black & Graphite for Polymers, TIMCAL GRAPHITE & CARBON, Belgium Advanced functional fillers for thermally conductive compounds: Key technology for cost reduction in electronic thermal management Mr. Armin Kayser, Director of Business Development, ESK CERAMICS GmbH & Co KG, Germany

SESSION 5 REINFORCEMENTS AND FILLERS 10:10 Adding functionality and value to medical compounds with novel reinforcements, fillers and additives Dr. Larry Acquarulo, CEO, FOSTER CORPORATION, United States

10:40-11:10 Coffee break 11:10 11:40 Integration of design, materials and manufacturing in long fiber thermoplastic composites Dr. Raj Mathur, V.P. Technology & Business Development, PLASTICOMP INC., United States New mineral opportunities in polymers Dr. Saied Kochesfahani, Development Manager, Polymers, IMERYS, United States

SESSION 6 GETTING THE MOST FROM YOUR COMPOUNDING PLANT 12:10 Tips for optimizing twin-screw extrusion Mr. Bert Elliott, Engineering Manager, LEISTRITZ EXTRUDER CORP., United States

12:40-2:10 Lunch 2:10 2:40 3:10 3:40 4:00 Optimizing screw configurations for twin-screw compounding extruders Mr. Adam Dreiblatt, Director, Process Technology, CPM CENTURY EXTRUSION, United States System engineering: The global rise of turn-key compounding lines Mr. Matt Sieverding, General Manager, KRAUSSMAFFEI BERSTORFF NA, United States Taming hard-to-handle ingredients, and increasing loading levels Dr. Paul Andersen, Director, Process Technology, COPERION CORPORATION, United States Afternoon wrap up and questions Conference ends Conference bag sponsored by:

AMI reserves the right to alter the program without notice. The latest program including any new speakers or changes to schedules can be viewed on our website www.amiplastics-na.com

Click here for a PDF of the brochure


CONFERENCE DETAILS
Date and location: December 10-11, 2013 Hilton Philadelphia City Avenue 4200 City Avenue Philadelphia, PA 19131, USA Tel: +1 215 879 4000 Image courtesy of: Hilton Philadelphia City Avenue HOTEL ACCOMMODATION The conference fee does not include lodging. We have negotiated a special rate of $150 per night for a single or double occupancy at the Hilton Philadelphia City Avenue. Please contact the hotels reservation department directly and be sure to mention the "AMIs Compounding World Forum 2013 conference" to qualify for the special room rate. The hotel rate is guaranteed for a limited number of rooms so do not delay in making your reservation for a room at the conference location. REGISTRATION FEE Register before November 1, 2013 for only $990. Thereafter the fee will be $1190. Registration includes all sessions, conference proceedings, the cocktail reception, luncheons, and break refreshments. GROUP RATES For companies wishing to register two or more delegates, group discounts are available. Please contact the Conference Coordinator for more details. SPONSOR THIS EVENT AND PROMOTE YOUR COMPANY AMI events are more than just arenas for listening and networking. They also represent highly targeted opportunities to enhance your image and promote your products and services to an international audience. Each event offers the following unique awareness building opportunities: sponsorship of the welcome cocktail reception, lunches, coffee breaks, and much more. For further information please contact the Conference Coordinator at +1 610 478 0800. EXHIBITION PACKAGE This package includes an exhibition space in the conference room where we will be hosting registration, the cocktail reception and coffee breaks, giving exhibitors maximum exposure. It also includes 1 free delegate place. Exhibitors may either use tables provided by the hotel or bring their own stand or display. A limited number of tables are available and are assigned on a first come, first serve basis. The cost of this package is $1990. Please note: When applicable, exhibitors are responsible for any electricity and/or handling fees involved with their booth. For further information please contact the Conference Coordinator. SOCIAL EVENTS The social events organized for AMIs Compounding World Forum 2013 conference will provide an ideal setting for delegates and speakers to mix business with pleasure. On the first evening, everyone is warmly invited to attend the welcome cocktail reception. SUBSTITUTIONS / CANCELLATIONS Delegates may be substituted at any time at no charge. We ask that you provide ample notification of substitution in order that materials can be prepared. Full refunds, less an administrative charge of $200 will only be made on cancellations received prior to November 1, 2013. We regret that we cannot make refunds on cancellations received after this date or for no-shows at the conference. Please note that refunds cannot be made on table top bookings.

Registration Form
Compounding World Forum 2013 December 10-11, 2013 Hilton Philadelphia City Avenue Philadelphia, PA, USA Company: ______________________________________________ Address: _______________________________________________ _______________________________________________________ Tel:_______________________ Fax: _________________________ Company activity: _______________________________________

Delegate Details:
(if more than one delegate please photocopy form)

Title: _______________First name:__________________________ Surname: ______________________________________________ Position: _______________________________________________ Email: __________________________________________________ Special dietary requirements: ______________________________

Payment Details:
Please make payments in US Dollars ($) q Delegate fee $990 ___________ (before November 1, 2013) q Delegate fee (thereafter) q $1190 ___________ $1990 ___________

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Total: ___________

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FAX FORM TO: +1 610 478 0900


CONFERENCE HOTLINE Ms. Kelly Cressman, Conference Coordinator Applied Market Information LLC Tel: +1 610 478 0800 1210 Broadcasting Road, Suite #103, Fax: +1 610 478 0900 Wyomissing, PA 19610, USA Email: kc@amiplastics-na.com Please make copies of this registration form for others to use or download a PDF file copy of the brochure from our web site at www.amiplastics-na.com

Name of cardholder: _____________________________________ Expiration date: _________________________________________ Cardholders signature: ___________________________________ Date: __________________________________________________ Invoice email (if different from above):________________________

Understanding colour | materials feature

Ron Beck, R&D manager at Americhem, looks at how colour works, how it is perceived, and the implications for specifying, controlling and measuring colour in plastics

Appearance is everything: controlling colour in plastics


Beauty is in the eye of the beholder. And so is the perception of colour. By denition colour is what we see the physical modication of light by an object as observed by the human eye and interpreted by the brain. With all of these variables at play, one thing is clear. Not all people see, or feel, colour the same. Polymer engineers have a unique challenge when picking just the right colour that will broadly appeal to their end users. Colour is a powerful tool that is proven to affect mood, initiate action or even cause physiological reactions. Through our eyes, our brains take in information about colour and integrate it into a concept or feeling. In fact, colour can be mood altering and has been used as a therapeutic tool as far back as ancient civilizations in Egypt, China and Greece. Much goes into choosing just the right colour to convey a message or feeling about a plastic product. However, much more goes into how to actually achieve that colour. In this article, we will examine the physics of colour, discuss the factors that dene appearance and take a closer look at best practices in colour measurement

and polymer design.

Figure 1: Three examples of light energy with their spectral power distribution: Illuminant A (Incandescent) has a colour temperature at 2,856 K; Illuminant D65 (Daylight) has a colour temperature at 6,500 K; and Illuminant F2 (Fluorescent) has a colour temperature at 4,200 K
www.compoundingworld.com July 2013 | COMPOUNDING WORLD 35

materials feature | Understanding colour

using the same pigment. This is because the two materials have completely different refractive indexes. Diffuse reection, on the other hand, dictates how an object selectively absorbs (or hides) some colour. Start with a white pigmented lm and gradually add colour. For a while the lm will not change in appearance, effectively absorbing the colour. The moment in which the colour begins to be visible is known as the percolaFigure 2: When a green pigment is added to an object it will only reect the green colour, while other colours are absorbed Well begin by looking at the four elements of colour: light, object, human eye (observer), and human brain. Light: Light is a continuum of electromagnetic energy and can be broken into two categories. The rst is source, a device serving to illuminate, while the second is illuminant, a theoretical source of visible light with documented attributes that are used as a basis for comparing colours. Illuminants can represent average incandescent light, direct sunlight, daylight, and more. For example, Illuminant D65 is the standard daylight illuminant that represents average illumination conditions throughout the world. The D stands for daylight and 65 is the temperature, which happens to be 6,500 degrees Kelvin. Illuminant D65, and its counterparts, are represented by a set of tables that can be used to simulate conditions and to view objects, and colour, in controlled lighting. Further, Illuminant F2 represents average illumination conditions for cool white uorescent light (See Figure 1). Object: Now, well move on to what objects do to light. For starters, all objects interact with light in the same ways: G Specular reection refractive index, which is responsible for gloss; G Diffuse reection scattering of light, which is responsible for opacity and hiding; Figure 3: Colour perception is an extremely complex process involving the interaction of the eye, optic nerves and brain G Absorption of light mainly responsible for colour; G Transmission how light passes through the object. Every material reacts with light in these ways. But its to what extent light reects, diffuses, absorbs and transmits with the object that gives it its appearance. Light absorption has a great impact on the colour of a plastic object. For example, when a green pigment is added to an object it will only reect the green colour and all other colours are absorbed by the object (Figure 2). Specular reection is to what extent the light scatters. Imagine you have an object made of polypropylene and an object made of polyester and you use the exact same pigment in both. You will likely nd that the two objects are completely different colours, despite
36 COMPOUNDING WORLD | July 2013 www.compoundingworld.com

tion point. For polymer engineers, this is an important moment. Slight changes in the objects make-up or the pigment can change the percolation point, creating a teetertotter effect when a product is produced. One time the colour is there, the next time it isnt. This is caused by the scattering of light. Light absorption is what truly provides visible colour, which is what is reected back from an object when it is exposed to a light source therefore, the type of light source directly impacts the appearance of the object. Human Eye: Perception of colour is the result of an extremely complex process. While we still do not fully understand how it works, we do know that it involves the interaction of three separate areas: the eye, the optic nerves and the brain. There are two kinds of light-sensitive cells in the eye rods and cones. Rods control sensitivity to light and are responsible for night vision. They are so sensitive that during daylight they turn off. This is why you might feel blind when you enter a movie theatre from a brightly lit street. When the light level falls below their overload threshold, they slowly regain their sensitivity, a process that takes about 30 minutes to complete. Where rods are colour blind, cones step in and are responsible for distinguishing colour. Approximately 7 million cones are packed into the area of the retina called the fovea. They are not nearly as sensitive to light as rods, but are able to distinguish between colour wavelengths.

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Understanding colour | materials feature

It is generally accepted that there are three types of cone receptors with each responding to a different range of wavelengths: one is sensitive to the blue region of the visible spectrum, another is sensitive to wavelengths in the green region and the third responds to wavelengths in the red region. Designers are familiar with these colour spectrums as the RGB colour model, which can be used to create an array of other colours. Between the light sensing abilities of rods and the colour distinguishing abilities of cones, the perception of colour begins. Human Brain: All visual data processing is done in an area of the brain known as the visual cortex located at the rear of the skull. Here, all of the signals coming through the optic nerve bundle are sorted and organized. The rst thing it looks for are edges, or discernible differences in colour or brightness. Once it has detected edges, it organizes the edges into patterns. Then, it searches its memory banks to see if any of these patterns are identiable. This is how you can determine if you are looking at a red apple or your Aunt Helen who you havent seen in 15 years. Unlike a shape, a colour cannot be dened. It has no pattern with edges that can be catalogued and later recognized. While the brain has difculty remembering precise colours, it is excellent at comparing colours. If you examine two colours side-by-side, the brain can easily tell whether they are identical. If they are not identical, the brain again has a problem with accurately quantifying the degree of the difference. The brain analyses the signals it receives from the eye, searches for edges, and then considers each

Figure 4: How Many Colours Do You See? Answer: There are only three colours white, green and pink. There seem to be two different shades of pink, but they are really the same. This shows how surroundings can greatly impact appearance

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materials feature | Understanding colour

and metamerism. The latter is a phenomenon in which two objects have a given relationship under one set of viewing conditions and a different relationship under another. This happens because the two objects are spectrally different. Preventing metamerism is dependent on making sure the two examples have the same spectral curve. Figures 5 and 6 illustrate and explain metamerism.

Measuring colour
Figure 5: An example of metamerism There are two ways to measure colour. One is by a visual examination, relying on the human eye. The other is via instruments and equipment. Samples must be pre-qualied to: represent the batch; be free from contamination; be in the same form as the target; and be reproducible within acceptable limits of repeatability. Then, a single sample is chosen as the standard by which all others will be judged. Visual examination: Because visual colour measurement depends on consistent judgment, the observer would need to provide repeatable judgments. Examination by instrument: First and foremost, you must understand the instrument, how it works and its specications. Choose an instrument that gives you the best mix of functions to meet your design needs: Figure 6: Why metamerism happens G Spectral data, including absolute coordinates and metamerism; G Geometry; individually. It is the brains ability to detect edges that makes visual examinations of product designs so valuable. Our optical system can discern specs, streaks and blotches that no spectrophotometer could ever detect. The spectrophotometer would simply average the specs into the overall colour. It also allows us to evaluate surface textures and recognizes specular reections. With all of these factors considered light, object, the human eye and the human brain do all people see colour the same? We most denitely do not. We all have different spectral response curves even with normal colour vision. Then there are also other factors, such as individual colour deciencies and colour blindness that make our perceptions of colour vast and unique person-to-person. What we see is not all about colour. Its all about appearance. Colour, gloss, scattering, light sources, surroundings and temperature all impact appearance. For example, Figure 4 shows the impact of surrounding colours. For one to understand how the human observer sees and evaluates colour, one must have a clear understanding of the light source, how the object modies light, and how the human observer responds to light
40 COMPOUNDING WORLD | July 2013

G Precision and accuracy; G Software, including the ability to complete the necessary calculations, as well as the user interface; It is also important to remember that no instrument can replace the importance of the human eye. An instrument may indicate a fractional difference in colour that may not be discernible to the observer, so allow for some margin of difference to avoid unnecessarily scrapping an entire lot for a difference no one would ever notice.

Possibilities are limitless


The colour match is only one component of product design. The nal products end use creates a list of attributes that must also be met to have a successful product design. Depending on where the product will be stored, factors that might need to be considered include: bleach resistance, light stability, weathering and chemical resistance, among others. After all, what good is the right colour that provides just the right feeling if the product itself fails to stand up to its environment? With assistance from experts in colour and product design, theres virtually no limit to what designers can accomplish.

S www.americhem.com
www.compoundingworld.com

Whats new in colours | update

RAL App receives updates


Germany-based RAL and Switzerlands Colorix have updated RALs iColours App, which is available for the iOS and Android smartphone platforms and allows users to colour images of objects taken using the smartphones built-in camera in any of 2,328 RAL colours. New features in the App include the ability to save a project or to share them via Facebook or Twitter. The App has also been updated to include the latest issue of the RAL Design fan deck RAL D2 and box RAL D8. The full colour palette, which also includes the RAL Classic and Effect collections are listed with corresponding L*a*b*, sRGB, CMYK and brightness values. RAL iColours is compatible with the ColorCatch 3 colorimeter from Colorix, billed as the first colorimeter to be designed specifically for use with Apples iPhone.

X-Rite adds compact spectrophotometer


X-Rite has launched its new Ci4200 bench-top spectrophotometer for improving colour quality assurance programs in industrial settings. The new instrument is an easy-to-use, 31-point spherical spectrophotometer that can quickly assess the colours of plastics and other materials. The Ci4200 accurately measures colours in the 400 to 700 nm range, with an option to include calibrated UV illumination. With a correlated 60 gloss configuration, the instrument gives specular and aspecular measurements. It has a small footprint and can be rotated to measure test surfaces presented horizontally or vertically. X-Rite says that the spectrophotometer produces simultaneous SCI/SCE measurements in 2 seconds and the resulting data is compatible with its hand-held spherical devices.

www.xrite.com

PolyOne enhances colour selection


PolyOne has introduced its InVisiO portfolio of colour and design services to assist product development teams and brand managers identify and respond to trends in colour and effects. The three key elements of the programme include Insight, Vision and Intelligent Operations. Insight is focused on colour forecasting and trend prediction. Vision looks at how texture, colour and special effects interact within a design. Intelligent Operations includes the support tools for identifying colorant type and assisting with prototyping, tooling and process optimisation. InVisiO colour and design services have been expressly developed to allow brand managers and creative teams to easily tap into leading-edge trends through an all-inclusive range of specialty colour development and design support services, says Fernando Sanchez, global marketing director for PolyOne Color and Additives. The InVisiO services are pitched at markets including packaging, healthcare, electronics, appliances and consumer goods. They are provided via PolyOnes global network of 12 Innovation Centres.

www.ral-farben.de

www.polyone.com

Konica Minolta launches in-line system


Konica Minolta Sensing has launched a new non-contact, in-line measurement system to provide real-time analysis of colour for quality and process control. The NC-1 provides high-speed monitoring at up to 20 readings per second, quickly detecting when colour is out of specification. The system is designed to withstand harsh production environments, and target markets include closed-loop applications in the plastics industry. By using multi-directional illumination
www.compoundingworld.com 

and non-contact sensing, the system can be used with textured, uneven, and multi-dimensional materials. It can measure reflected light for solid and semi-solid products, and transmitted light for clear plastics and films. The NC-1 is capable of controlling up to five colour sensors per controller, extending measurements across wide line applications.

www.konicaminolta.com
July 2013 | compounding world 43

EXHIBITING AT K 2013?
Promote your presence at the global plastics show using our global plastics magazines The great thing about the K show in Dsseldorf is that it attracts visitors from every corner of the world. Make sure that these international attendees know where to nd your booth among the 3,000 other exhibitors at this years show by advertising in our targeted magazines. These have a truly global readerships, both online and through our apps for the iPad/iPhone and Android devices (full details in our media packs use the relevant links). Take your pick from these 17 dedicated issues:
August: K 2013 rst look September: K 2013 preview October: K 2013 show issue November: News from K 2013 December: K 2013 review Click here to download the full media pack August: K 2013 rst look September: K 2013 preview October: K 2013 show issue November/December: K 2013 review Click here to download the full media pack July/August: K 2013 rst look September: K 2013 preview October: K 2013 show issue November/December: K 2013 review Click here to download the full media pack July/August: K 2013 rst look September: K 2013 preview October: K 2013 show issue November/December: K 2013 review Click here to download the full media pack

We will be exhibiting at K ourselves, with a well-positioned booth in the North Entrance, plus our highly-experienced and technically-qualied editors will be back in Dsseldorf to report direct from the show. Our special K issues are always very popular, so reserve your advertisement space now by contacting Claire Bishop on +44 20 8686 8139 or at claire@amimagazines.com www.amimagazines.com

Whats new in colours | update

P&G stores colours in the cloud


Procter & Gamble has implemented PantoneLive, a cloud-based colour service, to improve the efciency of its packaging operations. Maintaining colour consistency on product packaging is essential for the company behind consumer brands such as Gillette, Tide and Pampers. PantoneLive is an efcient, effective and seamless technology that saves time and money, and helps ensure design intent makes it to shelf, whether we are creating a new Charmin package design, proong an Olay label, mixing ink for Tide packaging or assessing the quality of Gillette packaging on press, says Phil Duncan, global design ofcer at P&G. To facilitate colour standardisation across all materials in the production process, P&G now has the ability to upload proprietary colour palettes onto PantoneLives secure, cloud-based portal, which suppliers can instantly access from around the world. This centralised colour communication process helps to minimise colour revisions and reduce approval times. With supply chains located around the world, it is extremely difcult for large corporations to maintain universal colour consistency, explains Dr Sonia Megert, vice president of the Pantone Digital business unit. The PantoneLive system is ideal for an innovative, global corporation like P&G because it provides a centralised online repository for managing, controlling and accessing ofcial brand colour criteria. In addition, PantoneLive helps to promote best practices and protocols to ensure that the correct colours are maintained. Measurement and verication is based on scientic, rather than subjective, evaluation.

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Order online or by telephone, fax or email. Contact Matt Wherlock, Tel: +44 (0)117 924 9442 Fax: +44 (0)117 9892128 email: mjw@amiplastics.com All prices are correct at the time of publication but may be subject to change. Please check the Plastics Information Direct website for current prices and shipping charges.

Melt ltration | processing feature

Peter Mapleston reviews recent developments in screen-changers and melt ltration systems from 12 leading suppliers in Europe, America and Asia

Keep it clean with the latest melt ltration systems


Melt ltration plays a vital role in keeping compounding equipment running consistently and protably for a wide range of applications. These can include giant lines run by polymer makers with outputs of several tonnes per hour, more modest masterbatch compounding lines with frequent formulation changes, or recycling equipment handing post-consumer material full of contaminants. Filtering of melts in high-volume polyolen compounding and pelletizing operations is an important process task that serves two purposes, says Klaus Kapfer, head of Coperions business unit Extrusion Systems, Polyolens. One is to remove contaminants that are introduced along the process chain: these can include catalyst residues, polymer gels, metal shavings from piping, feeding and extrusion equipment, and even such things as fragments of paper from carelessly opened additive bags which enter the feed system. Depending on the polymer type and grade, the screen mesh size can vary from 20 up to 320 mesh, or even ner for very special applications. Coarse screens are installed to protect the expensive die plate from getting clogged with foreign particles to prevent subsequent improper extrusion and pelletizing. The second purpose is a function in the processing
www.compoundingworld.com July 2013 | COMPOUNDING WORLD 47

task, Kapfer explains. Passage through a pack of screens will provide elongational ow of the polymer melt, and such ow will deform and eventually break up the elongated particles or viscosity inhomogenities into individual droplets. These droplets are then mixed into the polymer melt stream. Screen pack changers have to cater not only for ever-increasing capacity requirements, but also for increases in polymer melt viscosity, says Kapfer. Larger screening areas are needed to accommodate higher line capacities in polymer plants. Increasing only

Coperions high capacity screen candle systems (above) are developed using computerbased ow simulation tools (below)

processing feature | Melt filtration

Nordson Xaloy offers SPC Extended Area systems with cylindrical screens to handle very high throughputs

screen-changer diameters will lead to significantly diverging and converging flow, with serious implications for flow stagnation; the screen area needs to be extended in the flow direction and elongated screen candles are used. Larger screening area has also been accomplished by routing the flow now from outside to inside of the individual screen candles. Today, screen pack changers with screening areas as high as 21,000 mm are in use, Kapfer notes. Such large areas can be achieved with a dual bar design with two screen holder cavities each. Another supplier of filtration equipment for large compounding operations, Nordson Xaloy, says that it has supplied several big producers with its SPC1200EA and SPC1500EA units for lines with outputs from 3 to 30 tonnes/hour. The design is based on a heavy one-piece body, with candles to provide the necessary extended filter area. Cylindrical screens create a low pressure drop, resulting in higher throughputs and longer on-line time between screen-changes, says accounts manager Walter Pieters. He also notes that fast screen changes between the production of different batches can yield important cost savings on such big lines.

ADG Solutions, which is the exclusive North American importer of Fimic equipment, says it now offers filter screens with a size of only 200 microns, and should have a 150-micron screen available later this year. Company president Sandy Guthrie says that this ultra-fine filtration enhances product quality, while the large surface area of the screen compared to that of other screen-changers facilitates polymer flow and ensures a high level of productivity. Another new option is the model SCF-700 screenchanger, which extends the applicability of the Fimic system to recycling operations requiring throughput rates from around 2,700 to over 4,500 kg/hour. The Fimic screen-changer can handle scrap with up to 3% loadings of contaminants without a slowdown or stoppage of the process, and even contaminants close to 2.5 cm in diameter do not pose a problem, according to Guthrie. Purgings average less than 1.13 kg per cleaning cycle and there is minimal discharge of good material along with contaminants, he says. The self-cleaning cycles are subject to automatic PLC control. In each cycle, as molten polymer enters the screen-changer, contaminant accumulates on the screen-plate until back pressure reaches a preset level. This actuates a rotating blade which sweeps the screen and purges the contaminant through a central discharge port. Typically the screen does not need to be touched or changed more often than every week or two, depending on the material being processed. Guthrie cites a recently commissioned installation recycling highly contaminated material with very low melt index. He says the Fimic system is efficiently handling highly contaminated HDPE with a fractional melt index of 0.012 to 0.015 something that apparently other filtration systems were unable to do. Contaminants include dirt, wood, and pieces of aluminium. Austrian company Ettlinger says that operators employ its ERF melt filtration system to efficiently process recycled plastics whose contamination levels reach 18%, a task that it says used to be accomplished using more elaborate means. The filters are available in two variants, with throughput volumes ranging from 1,000 to 2,200 kg/hour depending on the type of material, level of contamination, and filter mesh. Melt passes through a rotating filter drum, and the particles trapped in the melt are removed by an angled

Fimic offers filter screens with a size of 200 microns to increase product uniformity and cleanliness

Handling contaminated recyclate


Fimic Officine Meccaniche in Italy has been focusing on plastics recycling applications involving highly contaminated raw material. New options for its self-cleaning continuous screen-changer are designed to increase product uniformity and cleanliness without sacrificing productivity.

48

compounding world | July 2013

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processing feature | Melt filtration

Ettlingers ERF system features a rotating filter drum where trapped particles trapped are removed by an angled scraper

scraper across the entire width of the drum and fed to a high-speed delivery worm. The pressure applied by the scraper and the filter processing speed are regulated in accordance with the melt pressure. The self-cleaning action of the drum as it rotates provides for a large, open filter area that Ettlinger claims exceeds the performance of any disk-type filter. Only minimal quantities of plastic melt are required to remove the particles, and the higher the contamination level, the more efficient the system becomes. Processing a mixture with 18% aluminium flakes, for example, uses 10-12% of the melt. The large filter area also minimizes pressure fluctuations to +/- 2 bar at the exit point of the system, thus eliminating the need for a downstream melt pump in some extrusion systems. Eight filter screens are available, with sizes ranging from 80 to 1,000 microns, and can be used to filter all non-mineral-based contaminants. Kreyenborg describes an application in a recycling plant with strand pelletizing, which is benefiting from the use of one of its V-type screen-changers with integrated self-cleaning function of the screens. Strand breaks are things of the past when using the V-type, Kreyenborg claims, owing to its constant melt pressure. The customer mainly processes film remnants from PS and PP that contain a high level of contamination. The system was installed over three years ago, but despite the high mechanical demands on the screenchanger, there are no signs of fatigue after more than 51,000 back-flush cycles. One cycle comprises the flushing of all four screen cavities, of which there are always at least three in production. An overhaul due to rework or wear of the seals is not necessary when using a piston screen-changer because there is no leakage, says Kreyenborg. The screen-changer makes more than one hundred back-flush cycles with the same screen pack. Then the screens are changed as a precaution to avoid fatigue of the mesh, and to prevent the bypass of dirt particles around the boundary edge of the screen packs.

Continuous belt systems


Parkinson Technologies has a new machine in its Key Filters brand line-up, the KCH continuous belt melt filter, which it reckons could be a big step in improving compounding process technology. The filter was initially targeted at low viscosity materials, but John Whaley, business manager for Key Filters products, says that it has since proven effective on a wide range of polymers. The KCH was developed as a bridge between our KCN and KC lines, says Whaley. The result is a machine that is extremely flexible and responsive. He also says that the KCH machine addresses many industry concerns regarding traditional continuous belt melt filters: it has a much lower energy

Kreyenborg says that strand breaks are things of the past at a recycling plant that is now using its V-type screen-changer

consumption and lower material removal, yielding a much higher return on capital investment. The KC (Key Continuous), originally developed for TPEs and also hot melts, employs an external hydraulic screen puller to move a proprietary screen across the melt channel. The KCN (Key Continuous, Non-actuated) is based, like several machines from other suppliers, on the design principle of the original Autoscreen developed by Dr Peter Kalman in the UK. It is simple to use and uses widely available RDW filter belts, but the operating window is quite narrow. It does not work on TPEs and hot melts. In developing the KCH (Key Continuous Hybrid)

50

compounding world | July 2013

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Melt filtration | processing feature

the goal was to combine the best properties of the KC machine, the external puller and instant operation, with the best properties of the KCN, the better flow channel and RDW screen use, into one machine, says Whaley. Our target was the growing TPE/TPO market and its need for continuous filters that offer constant and uniform control of extrusion pressure. The KCH uses a dedicated PLC to monitor extrusion pressure and quickly react by moving the screen to keep the extrusion pressure constant and uniform. With the same machine and the same screen, the KCH has demonstrated the ability to process polymers from TPEs as low as 25 Shore A scale through to acrylics with hardness up to 125 Rockwell R, all with leak-free, uniform pressure operation. In compounding, uniform extrusion pressure is paramount to quality mixing as well as rate control in the extruder, Whaley says. Because the KCH can move the screen very slowly across the melt stream, there is no pressure disruption throughout the entire production run. The unit also can be adapted to match the configuration of a twin-screw extruder to maximize the flow area. With the twin-screw configuration, the flow path is minimized, making the 8-o cross-section transition through the screen-changer such that the dwell time between screw tips and die is very short. Also highlighting the advantages of screen changes that can keep the compounding process constant is Melt Filtration Products. Its new AutoScreen Max is designed to provide compounders with uninterrupted extrusion during screen changes. It incorporates AutoScreens Extrusion Pressure Control (EPC) system that automatically maintains a selected melt pressure

delta. This feature keeps the melt pressure entering the pelletizing die within a selectable pressure range, regardless of changes in material bulk density or contamination levels. The result is a continuous, stable and uninterrupted compounding process. The AutoScreen Max has a small footprint and requires no hydraulics or pneumatics, plus there are no breaker plates or screen packs to replace.

Parkinson Technologies says that its Key Filters KCH continuous belt filter offers several advantages for compounders

New technologies lined up for K2013


Berhalter will use the K 2013 exhibition in Dsseldorf to introduce its new back-flush screen-changer, based on its existing Becoscreen system. Berhalter claims that, unlike other back-flush systems, the new screen-changer is designed to keep output constant during a cassette change. The company does not want to explain how it works before the big show, but it will say that the new screen-changer is characterized by its high scavenging efficiency, long screen life and constant process, pressure and volume flow during backwash. In Becoscreen screen-changers, juxtaposed sliding cassettes serve as the filtration medium. Cassettes with the filter inserts are introduced on one side and

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processing feature | Melt filtration

enable material colour and grade changes to take place as fast as possible. However, in order to take account of these additional requirements, Gneuss has developed special versions, with the design individually tailored so that inlet and outlet configurations are exactly matched to the extruder and the die, he says. For example, the inlet of the screen-changer can be designed effectively as an extension of the extruder The pre-flood system on Berhalters Becoscreen screen-changer redirects the flow of material into the awaiting cassette removed for cleaning on the other. The material flow is directly through the screen-changer, without division of the melt into multiple channels. This way, Berhalter says, there are no dead spots. Berhalter claims the Becoscreen is the only system on the market that can bring a 100% clean filter medium into the melt stream at each change. The function of our continuous screen-changer is not restricted, the company says. This is made possible by a pre-flood system, which redirects the flow of material into the awaiting cassette. The Becoscreen is said to work completely maintenance-free and leak-free, and can be used for almost all polymers. Econ will present a screen-changer with what it says is a brand new sealing technology at K2013. Again, it is not giving many details away prior to the show, but does say that high availability of the screen area (at least 75% is always in the melt flow, while 25 % is being back-flushed) leads to less back pressure and reduced energy consumption. The pistons are leak-proof, even with low viscosity materials, while blockages are prevented even with highly viscous material due to the prevention of abrasion and deposits. Blockages resulting from thermal expansion are also prevented. Dead volume is minimal, so quick material changes are possible. Econ also claims that the risk of spattering hot melt has been reduced, improving safety. screw barrel with the screws running inside it and the outlet side can be directly integrated with the strand die. In this way, the volume of material inside the screenchanger is minimised and colour / material or material grade changes can be carried out extremely quickly. For extreme cases where the types of materials processed mean that there is no alternative to periodically cleaning inside the screen-changer manually, Gneuss has devised a version in which all parts in contact with the melt can easily be removed for cleaning (for example in a pyrolysis cleaning furnace). It is even possible to supply the screen-changer with a second set of clean parts so that these can be ready for swapping, Prangnell notes.

Chinaplas unveilings
Chinaplas in May was the scene for several new product introductions. Exhibiting on home soil was leading Chinese screen-changer producer Anji. It announced two new product lines for compounding lines: a drum screen-changer with a very high filtration area, and a single-plate unit with back-flush. The first of these features what company representative Cao Wang calls a unique design of flow channels to achieve a greatly increased filtration area in the range of 1,800-5,650 cm2 in a compact design. Two drum-type filters with large filtration areas ensure continuous production during screen changing. A built-in static mixer improves product stability, while a superior sealing system is claimed to eliminate polymer

Fine-tuning rotary screen-changers


Gneuss Kunststofftechnik continues to cater more for Gneuss continues to fine-tune its RSFgenius rotary melt filtration systems to allow faster material changeovers the high end of the market with its RSFgenius and SFXmagnus rotary melt filtration systems. Although they have been on the market for many years now, Gneuss continues to fine-tune them. Technical sales manager Andrew Prangnell says that with compounders in western Europe and the USA tending to develop more specialised, high quality compounds for technical applications, there is an increasing need in these areas for very flexible production with small charges and fast turnaround times. This means that the screen-changer, in addition to carrying out its basic functions, needs to be designed to
54 compounding world | July 2013

leakage. A back-flush system is optional.

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FIRE RESISTANCE IN PLASTICS 2013


Trends and technical developments in the international ame retardant industry
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12-14 November 2013


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processing feature | Melt filtration

Maag has developed filtration units with arched filters to maximize the surface area

The new single-plate screen-changer with back-flush is an improved version of an existing Anji unit. A special sealing system design is said to enable automatic compensation on the sealing gap during screen changing to eliminate polymer leakage. Wang says that Anji, which holds around 20 Chinese patents on screen-changers, has compounding customers all over the world, although not surprisingly China is still its most important market. Our customers are demanding even higher efficiency and production quality, says Wang. Trends we see in screen-changers include larger filtration area, more automatic operation, and minimum polymer flow fluctuation during the screen changing process, and also self-cleaning capability. Normally, our customers will take screen-changers with automatic control system and a larger filtration area to reduce the labour cost and increase productivity. Also at Chinaplas was Maag, with a system combining a SSC 076 screen-changer and an Extrex 45-5GP gear pump. Maag describes its screen-changers and melt pumps as work horses optimized for the application requirements for which they are built. SSC continuous single-piston screen-changers have two screen cavities and operate without any mechanical seals. The SSC 076 has a screen diameter of 76 mm, Click on the links for more information: and a filter area of 45 cm2. It can handle throughputs of up to 300 kg/h. Other SSC models have filter areas of up to 572 cm2, for maximum throughput of 4.7 tonnes/hour. Earlier this year, Maag announced that it had supplied an innovative screen-changer filter design for the worlds largest PET production line based on Uhde Inventa-Fischers MTR Melt-to-Resin process, which is located in the Middle East. Maag developed tailor-made filtration units with arched filters to maximize the filtration surface area while maintaining a compact footprint. The patentpending design guarantees a very low melt residence time, especially for high viscosity resin applications.

Anji now offers a single-plate screen changer with back-flush

www.coperion.com www.xaloy.com www.fimic.it www.adgs.net www.ettlinger.com www.kreyenborg.com www.parkinsontechnologies.com www.meltfiltrationproducts.com www.berhalter.ch www.econ.eu www.gneuss.com www.anjiplast.com www.maag.com

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AMIs Directory

New 2013

PLASTICS PROCESSORS IN POLAND


LOCATION & PRODUCTION DETAILS OF 1100 PLASTICS PROCESSING PLANTS
6th edition

AMIs Directory

PLASTICS PROCESSORS IN POLAND


LOCATION & PRODUCTION DETAILS OF PLASTICS PROCESSING PLANTS
Address Listing AMIs Directory of Plastics Processing in Poland

AMIs Directory of Plastics Processing in Poland

Injection moulders

3E SP. Z O.O.

Type: Custom, Proprietary Products Polymers processed: PS, ABS, LDPE, HDPE, PP, PMMA, PC, ASA. Polymer throughput: Less than 50 tonnes Markets served: Automotive, Electrical, Alarm Cases. Services offered: Pad Printing, Silk Screen Printing Number of machines: 4 Minimum lock: 120 Maximum lock: 268 Minimum shot: 5 Maximum shot: 600

Polymers, products & machinery


ACAR S.A.
Type: Custom Polymers processed: PVC Polymer throughput: No Polymer consumption available Markets served: Electrical, Sockets and Plugs.

ACE LUXE
Type: Custom, Proprietary Products Polymers processed: ABS, PC, Elastomers. Polymer throughput: Between 1001 - 1500 tonnes Markets served: Telectron Services offered: Assembly Number of machines: 13 Minimum lock: 270 Maximum lock: 850 Maximum shot: 2500

A KAYSER AUTOMOTIVE SYSTEMS POLSKA SP. Z O.O.


Type: Custom Polymers processed: PS, HDPE, PP, PA Polymer throughput: Between 251 - 500 tonnes Markets served: Automotive, Very Small Car Components (Fuel & Air Ducts; Filters & Valves). Services offered: U/S Welding, Friction Welding, Assembly Number of machines: 15 Minimum lock: 60 Maximum lock: 200 Minimum shot: 15 Maximum shot: 427

3E SP. Z O.O.
ul. Okrna 1B 19-300 Ek Tel: 087 620 1630 Fax: 087 620 1630 E-mail: a.sznelinska@3E.net.pl Website: www.3E.net.pl Contact: Mr. Z. Hodyk, Plant Manager Parent company: Privately Owned Processes operated: Injection moulding

A. SCHULMAN POLSKA Sp. z o.o.


ul. Nowa Biaa 37 09-411 Biaa k/Pocka Tel: 024 364 0012 Fax: 024 364 0011 E-mail: aschulman@pl.aschulman.com Website: www.aschulman.com Contact: Mr. A. Rozalski, General Manager Parent company: A. Schulman Inc., OH Processes operated: Compounding

AC-WYTWRNIA CZCI SAMOCHODOWYCH S.C.


Type: In House Polymers processed: PS, ABS, LDPE, HDPE, PP, PVC, PA Polymer throughput: Less than 50 tonnes Markets served: Automotive, Car Components. Services offered: Tool Design, Tool Manufacture, Pad Printing, Assembly, Machining Number of machines: 6 Minimum lock: 25 Maximum lock: 90 Maximum shot: 500

ABA PPH SP. Z O.O.


Type: Custom Polymers processed: LDPE, HDPE, PP Polymer throughput: Between 251 - 500 tonnes Markets served: Medical/Pharmaceutical, Caps and Closures, Medication Measuring Spoons. Services offered: Printing on Closures.

3P SYSTEM SP. Z O.O.


ul. Aleja Jana Pawa II 94 Supno 05-250 Radzymin Tel: 022 786 6149/763 2820 Fax: 022 786 5357 E-mail: 3psystem@3psystem.com.pl Website: www.3psystem.com.pl Contact: Mr. W. Gobiowski, Chairman Parent company: Privately Owned ISO registration: ISO 9001v2000 Processes operated: Sheet extrusion

ABA PPH SP. Z O.O.


ul. Poznaska 132 62-052 Komorniki Tel: 061 810 7785 Fax: 061 810 8276 E-mail: biuro@aba.pl Website: www.aba.pl Contact: Mr. S. Zielaskowski, Owner Parent company: Privately Owned ISO registration: ISO 9001v2008 Processes operated: Injection moulding

AGD PASTERSKI SP. J.


Type: Proprietary Products Polymers processed: PS, LDPE, HDPE, PP, PET Polymer throughput: Between 101 - 250 tonnes Markets served: Household, Chopping Boards; Brushes. Number of machines: 20

Addresses & contacts


ABET SP. Z O.O. ABEX SP. Z O.O.

A I B. SPOLKA Z OGRANICZONA ODPOWIEDZIALNOSCIA S.K.A.


ul. Przemysowa 22 44-190 Knurw Tel: 032 335 7900/10 Fax: 032 335 7905 E-mail: firma@aibsc.com.pl Website: www.aibsc.com.pl Contact: Mr. M. lczka, Co-owner Parent company: Privately Owned ISO registration: ISO 9001. Processes operated: Profile extrusion

ABET SP. Z O.O.


ul. Klonowa 3 05-806 Komorw k/ Warszawy Tel: 022 759 1140 Fax: 022 759 1140 E-mail: info@bet.com.pl Website: www.bet.com.pl Contact: Mr. A. Bieluszko, Owner Parent company: Privately Owned Processes operated: Injection moulding

Type: Custom Polymers processed: PS, LDPE, PP Polymer throughput: Less than 50 tonnes Markets served: Household, Clothes Hangers. Services offered: Hot Foil Stamping Number of machines: 10 Maximum lock: 20 Minimum shot: 30 Maximum shot: 200

AGFOL PRZETWRSTWO TWORZYSZ SZTUCZNYCH S.C.


Type: Custom, In House Polymers processed: LDPE, HDPE, PP Polymer throughput: Less than 50 tonnes Markets served: Household, Furniture Components; Components for Candle Lamps. Number of machines: 3 Minimum lock: 100 Maximum lock: 160 Minimum shot: 80 Maximum shot: 240

Type: Custom, Proprietary Products Polymers processed: PS, ABS, PP, PA, PC, PET Polymer throughput: Between 101 - 250 tonnes Markets served: Electrical, Electrical Connectors Services offered: Assembly Number of machines: 11 Minimum lock: 60 Maximum lock: 160 Maximum shot: 200

ABEX SP. Z O.O.


ul. 1 Maja 14a 78-400 Szczecinek Tel: 094 374 0114 Fax: E-mail: abex@abex.pl Website: www.abex.pl Contact: , Parent company: Privately Owned Processes operated: Injection moulding

A KAYSER AUTOMOTIVE SYSTEMS POLSKA SP. Z O.O.


ul. Skona 16 Batorowo 62-080 Tarnowo Podgrne Tel: 061 665 0300/308/314/315 Fax: 061 665 0317 E-mail: polen@kayser-automotive.com Website: www.kayser-automotive.de Contact: Mr. R. Jakubiak, Managing Director Parent company: A Kayser Automotive GmbH, Germany ISO registration: ISO 9001v2000 Processes operated: Injection moulding

197

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Companies included: Injection moulders Blow moulders Rotational moulders PE lm extruders Sheet extruders Cable extruders Pipe extruders Prole extruders Tube and hose extruders Compounders and masterbatch producers

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POLYMER F O A M 2013
International conference on blowing agents and foaming technology for polymer materials
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Market trends | TPE

Innovation drives TPEs ahead


The signicant growth in global demand for thermoplastics elastomers (TPEs) is being driven by a number of important factors. When discussing market trends with some leading TPE compounders and suppliers, several common themes emerge. These include growing demand for applications in automotive components and consumer goods, particularly in Asia. Changing regulatory and environmental demands are also opening up new opportunities. In addition, innovations in materials technology are enabling TPEs to substitute other polymers and rubbers in increasingly demanding applications. While there is excitement about the prospects for TPEs overall, there are signicant differences in the scale and types of opportunities in the different regions of the world. For example, Sachin Sakhalkar, director of strategic marketing and business development for the Thermoplastic Elastomer Division of Teknor Apex, emphasises that the growth has to be viewed on a regional basis. Its important to note that there are signicant differences from region to region. We believe that Asia-Pacic will continue to lead in TPE growth. For example, the automotive industry is very strong in the Asia-Pacic region, and half of the overall TPE market is accounted for by automotive, he says.
www.compoundingworld.com

Global demand for TPEs continues to grow, fuelled by material enhancements, design innovation and regulatory opportunities. Chris Smith reports
Coming from a background in custom compounding, Teknor Apex works in a wide range of application areas and its TPE division supplies all major end-use markets. Salkahar says the company currently sees the most promising growth prospects in the transport, medical and consumer sectors. A key factor in the growth in TPE applications has been substitution of thermoset rubbers. To take one example, our Sarlink TPEs are well established as replacements for EPDM rubber in sealing applications, but more of this replacement business remains to be captured, says Sakhalkar. While substitution of traditional rubbers will continue to present opportunites for TPEs, he also sees substitution of thermoplastics as a developing trend. Much of the future growth will involve TPEs replacing other thermoplastics or even making possible altogether new applications, as in some of the soft-touch products, he says. Teknor Apex also sees considerLeft: The Vapur closure is moulded in Thermolast K TFBNB, a 45 Shore A grade
59

Main image: Kraiburgs Thermolast K TPE is used to produce the closure for US-based Vapurs Anti-Bottle water bottle

July 2013 | COMPOUNDING WORLD

TPE | Market trends

service. Earlier this year, the company announced it is working with Shell to incorporate the latters Risella X synthetic process oil into its TPEs. Produced from natural gas, the chemical structure of Risella X is said to differ from mineral oil-based alternatives and the process oil is claimed to display improved compatibility with the TPE matrix. At the moment we are in an early phase creating samples, says Goldman, who adds that the chemistry is expected to be particularly beneficial in the formulation of non-polar TPEs. We expect a positive influence on the hardness and haptics of our products. TPE suppliers put a great deal of effort into developing products for specific applications, but they also benefit from changes beyond their direct control. Goldman cites the example of the move in the automotive industry from toughened to laminated glazing, which is more susceptible to damage during encapsulaAbove: Phillips used a GLS TPE formulated to meet demanding fatty food contact regulations for the seals in its Avent breast milk storage containers able opportunity in high performance TPEs delivering the performance currently expected of TPVs. Sakhalkar says the company will introduce a number of new SBC grades to its Sarlink TPV product line over the coming months. These will include grades for automotive applications such as glass encapsulation, corner mouldings, airbag covers and mats. Environmental issues are also likely to play a growing part in TPE selection in the future, according to Sakhalkar. We are engaged in developing TPEs based on renewable resources. The challenge is to produce compounds that provide cost-performance profiles comparable to standard TPEs. We expect to reach that goal, he says. tion. The companys high flow grades allow mould pressures to be kept low to avoid unacceptable breakage rates, he says. While Hexpol TPE sees the European market going through a period of consolidation over the next few years, this is compensated for by activity elsewhere in the world, according to European sales coordinator Sven M Drewen. Asia-Pacific, the US and South and Central America are all forecasting good growth, he says. With an increasingly sophisticated consumer market in Asia, demand is rising for TPE compounds that provide the right combination of functional performance attributes as well as soft-touch aesthetics, says Drewen. While there is some evidence of re-shoring in certain sectors, we feel Chinas economy will continue to be a global driver. Hexpols history is in the rubber industry, so its decision to invest in TPEs through the acquisition of first Elasto (formerly Vita Thermoplastic Polymers) and then Mller Kunststofftechnik could be viewed as acceptance that the days of traditional rubbers are numbered. However, Drewen says the company sees the two materials as essentially complementary. We were very aware of the rubber versus TPE debate. However, we quickly realised with the Elasto acquisition, and further when Mller Kunststoffe joined our family, that TPEs are used in a diverse variety of applications that would never be made from rubber, particularly in the consumer, packaging and medical sectors. Likewise there are many applications where TPE
www.compoundingworld.com

Regional attractions
While the growth expectations for the major world regions differs, Kraiburg-TPE head of corporate marketing Lars Goldman says each has a specific attraction to the company, which supplies into almost all end use markets. All three regions have their driving forces and are of similar interest, he says. In Europe the demands for Right: The Happy Ears earplugs are moulded in a Mediprene TPE developed for medical industry requirements by Hexpol TPEs Elasto division
60

quality 2-K component parts will still increase and in the other regions the demand for TPE will grow in general. Both customer demands are very interesting for us. Goldman says there is a clear requirement from customers for materials with higher levels of mechanical performance and temperature or oil resistance. While demand for these special grades may currently be relatively small, it is an area Kraiburg believes it is well positioned to

compounding world | July 2013

Market trends | TPE

Drewen says rst generation polyolen TPEs were able to replace rubber at service temperatures between -50C and 130C and in non-oily and non-fatty environments, then second generation products lifted the limits to 200C and to oily and fatty environments. But the mechanical properties will never reach the level of thermoset rubber so there will be always a need for a smart part design if you want to make use of the benets of TPEs, he says. We continue to work on the advancement of properties, be it temperature resistance, compression set or new processing techniques. But growth is also being driven by trends in product design and end-use application performance, he says. Drewen cites the increased use of TPEs in packaging caps and closures applications, where manufacturers are looking to innovate by including soft-touch areas to their packaging, as just one of many examples of this design innovation trend. new attributes to designers. TPE use in entirely new applications remains a strong driver for growth. As designers in consumer and packaging industries look to differentiate themselves in the market place they look to TPEs to enable new solutions, from haptic and appearance to functional performance, says Page. Novel TPE formulations continue to expand the boundaries of possibilities. New smart materials are being developed including shape memory TPEs that are able to x a deformation semi-permanently, and retake their original shape after exposure to hot water, he says. And the performance of vibration damping and barrier materials has been expanded with low compression set TPE products that increase the number and type of applications they can be selected for. Click on the links for more information: Above: High ow TPEs can minimise glass breakage during encapsulation of laminated automotive glazing elements

Regulatory impact
Regulatory change can also act as a driver for TPE growth. TPEs are being selected to replace traditional materials in packaging and healthcare applications for improved regulatory compliance, patient and consumer safety and design exibility, says Charles Page, global marketing director with PolyOnes GLS Thermoplastic Elastomers business. For example, GLS was able to fulll Philips Consumer Lifestyles requirements for its breast pump application, including compliance with the US Food and Drug Administrations rigorous 21 CFR 177.2600 standard governing the use of TPE materials intended for repeated contact with fatty foods, he says. Page says that TPEs also continue to rise to the performance requirements of industries such as the automotive industry, where higher efciency levels have driven up temperatures under the hood, and to deliver

S www.teknorapex.com S www.kraiburg-tpe.com S www.hexpoltpe.com S www.glstpes.com

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will not be able to replace rubber, Drewen says.

AGRICULTURAL FILM 2013


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Polymers and additives | products

flame retardants

Addivant extends halogen-free options


Addivants Polybond range of polymer modifiers are claimed to allow halogen-free polyolefin compounds to be used in place of PVC in flame retardant wire and cable applications. Addivants LLDPE-based range of Polybond polymer modifiers are used in conjunction with halogen-free flame retardants such as alumina trihydrate (ATH) or magnesium hydroxide to improve flame retardance characteristics and enhance physical properties, according to the company. Polybond 3149 is a general purpose LLDPE-based polymer modifier, while the 3249 and 3349 grades are better suited to applications requiring higher elongation values with reduced gel formation during mixing. The new formulations complement Addivants existing Polybond PP and HDPE polymer modifiers. Addivant was formerly the antioxidant and UV stabiliser business of Chemtura, which was acquired by SK Capital in May this year.

www.addivant.com
compatibilisers stabilisers

Wacker enhances biopolymers


Wacker has developed a new vinyl acetate-based binder product line designed to improve compatibility and enhance physical properties in bioplastic polymer blends. The Vinnex binder system is said to offer compatibility with a wide variety of biopolymers, including PLA, PHA, PBS and thermoplastic starch. Typical improvements in material performance are claimed to include higher impact strength, improved flexibility, and better melt strength. The company says some Vinnex products are already certified compliant with EU and US FDA food contact regulations. Wackers Vinnex vinyl acetate binder system can enhance the properties of bioplastics blends

Teijin is targeting hydrolysis


Japans Teijin has introduced a new carbodiimide antihydrolysis agent that is said to generate no isocyanate gas and is suitable for use in a variety of polyester, polyamide and polyurethane polymers. The new additive is based on a product already used in Teijins Biofront heat-resistant PLA bioplastic. It is said to provide hydrolysis protection at lower addition levels than current products while thermal stability to at least 300C simplifies processing.

www.wacker.com

nucleation

Ferro improves polyolefin foams


The Specialty Plastics Division of Ferro has introduced a new nucleating agent for polyolefin foams under the trade name of Innovex.
www.compoundingworld.com 

Samples quantities are available now, although Teijin says it will not have commercial quantities until 2015. The additive is said to already comply with current Japanese and European harmful substance regulations.

The new masterbatch is designated LD-0392NU and uses proprietary Ferro technology, which is claimed to enhance the cellular

structure and the thermal and mechanical compression behaviour of low density polyethylene foams.

www.ferro.com

www.teijin.com
July 2013 | compounding world 63

products | Polymers and additives

polyamide compounds

Interstuhl finds a perfect surface


German office furniture maker Interstuhl is using BASFs Ultramid SI polyamide 66 compound the SI stands for Surface Improved to manufacture the sleek seat back frame moulding for its MOVYis3 office chair. Interstuhls requirements for this application were demanding; it wanted a polymer that could be easily processed using gas-assisted moulding, provided high mechanical strength, and delivered a high quality cosmetic finish direct from the mould. Analysis of the seat back design using BASFs Ultrasim software resulted in the selection of Ultramid B3EG4 SI. This 20% glassreinforced grade uses a special additive pack that results in very high quality aesthetic finish with no need for painting or post-mould treatments. Interstuhl produces the seat back frames in black or white, with colour provided by the customers choice of fabric. However, Ultramid SI resins can also be coloured The Interstuhl seat back is moulded using BASFs improved aesthetic Ultramid SI PA 66 using masterbatches. BASF offers three other Ultramid SI grades, including 30% and 50% glass reinforced compounds, plus a flame retardant grade for use in seating for public places such as airports and railway stations. The standard fire resistance tests for chairs for public places include setting fire to a paper cushion placed on the seat of the chair and igniting a Crib 5 test specimen of 20 standardised stacked wooden sticks soaked with 1.5cm3 of propanol. Either test is considered to have been successfully passed if open flames have extinguished within 10 minutes and all glowing or smoke within 60 minutes. Seat shells made of the flame-retardant Ultramid SI grade perform very well in these tests, says BASF. In addition, because the flame retardant system contains no red phosphorous, it is possible to produce light coloured grades.

www.basf.com

clarifiers

Roquette re-enters clarifiers market


French plant-derivatives producer Roquette is to resume production of sorbitolbased polymer clarifiers and is introducing Disorbene 3, a bis-DMBS third generation sorbitol clarifier that will be sold as a direct equivalent to Milliken Chemicals Millad 3998. The new product will be manufactured at Roquettes facility at Lestrem in France and will be distributed directly by the company. The company says that Disorbene 3 matches Millad 3988 in terms of quality and granulometry (particle size distribution).
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According to Thierry Laurent, who heads up Roquettes plant-based chemicals business unit, polypropylene producers in Europe will welcome its decision to re-enter the clarifier business as it presents them with an alternative source of supply. Roquette has in the past supplied first and second generation clarifier products and until 2004 had a distribution agreement with Ciba, which supplied Roquette-manufactured products under the IrgaClear name. Milliken, meanwhile, has

announced that it has filed lawsuits against a number of Asian producers that it claims are infringing its patents relating to third generation DMBS clarifiers. The company says that while some of its manufacturing patents have recently expired it still holds IP covering specific areas, including certain blends. While Milliken has made it clear it will take steps to enforce its Millad 3998 intellectual property, the company has also told

NX8000 fourth generation nonitol-based clarifier, which maintains solubility at lower processing temperatures and is less dependent on polymer orientation. Millikens market manager for plastic additives for the EMEA region (Europe, Middle East and Africa) Sami T K Palanisami says that more than 200 PP grades are available worldwide already using the NX8000 product and the company estimates the product already accounts for 70% of the clarified PP market.

Compounding World that the


third generation product is fast being superseded by its

www.roquette.com
www.compoundingworld.com

compounding world | July 2013

Medical Grade Polymers 2013


International business and technical conference on design, materials and manufacturing of medical devices
CLICK HERE FOR DETAILS

Photo courtesy of HTP-Meds, LLC.

September 17-18, 2013


Images courtesy of: HTP-MEDS LLC and POLYONE CORPORATION

Crowne Plaza Boston/Woburn, Woburn, Massachusetts, USA

SPECIAL OFFER: Save $200 if you register before August 9, 2013


Organized by: Applied Market Information LLC Media supporter:

Stephanie Berchem Conference Coordinator sb@amiplastics-na.com Ph: +1 610 478 0800 Fx: +1 610 478 0900

products | Polymers and additives

RTP applies laser marking expertise


Cable tie manufacturer Hellermann Tyton is using a specially formulated lasermarkable ABS compound from RTP Company to produce the tension knob in its latest application/tensioning tool. Hellermann Tyton opted to use laser marking technology after detailed project discusHellermann Tyton has selected a laser-markable ABS compound from RTP for this tension knob sions with its manufacturing partner, US-based moulder New Berlin Plastics. The tie manufacturer had considered printing the numbers directly on the plastic, using in-mould decorating, or attaching a printed adhesive sticker to the part. However, New Berlin advised none of these was suitable for this application. Laser-marking the numeric scale was a much better solution, avoiding the time consuming challenge of printing, the high scrap rates that would have been associated with in-mould decoration, and the physical challenge of precisely affixing a small, 0.25 masterbatch antimicrobials inch [6 mm] wide sticker, says New Berlin director of engineering Mike Miller. He adds that the company worked with RTP to develop a laser-markable compound which met the tensile strength and white-on-black printing requirements of the application. It developed a special glass-reinforced compound based on its RTP 600 ABS Series, matching it with an RTP 6042 Series TPE for production of the over-moulded grip. The laser-marked numbers are very durable and will hold up for the life of the product, says Miller.

laser marking

www.rtpcompany.com

Tosaf adds anti-fog solution


Tosaf has launched a new anti-fog/anti-drip masterbatch for greenhouse films. The AF0406PE grade has been specially developed for hot climates and its effectiveness has been successfully demonstrated in extensive field experiments. Compared to existing anti-fog solutions, AF0406PE is claimed to offer significant benefits due to its long-lasting and consistent effectiveness. Tosaf says that it has received positive feedback from customers who are very satisfied with its long-term, stable performance.

Infinity battles bacteria

Infinity Compounding launched its new line of Inhibit antimicrobial concentrates and compounds at the MD&M East show last month. The new grades are based on silver functionalized clay and are claimed to prevent the growth of bacteria, fungus and other microorganisms in a variety of applications. The silver/clay platelets are designed to release their antimicrobial effect to the surface of a moulded or extruded part at a controlled rate for several years. Current tests of the products efficacy against staphylococcolour or surface appearance. Concentrates up to 25% nominal additive loading are available in many engineering resins, including PP, PE, ABS, PC, PC/ABS, PA, PBT, POM, PEI, PES and PEEK. With the ability to add antimicrobial functionality to any structural, lubricated, electrically active or coloured custom compound, we are able to help our customers achieve a fully functional antimicrobial product, says Tim Carroll, the companys vice president. Infinitys new Inhibit antimicrobial formulations are effective against staphylococcus aureus

www.tosaf.com
66

cus aureus indicate very strong antimicrobial activity at loadings as low as 1% by weight with no effect on

www.infinitycompounding.com
www.compoundingworld.com

compounding world | July 2013

PLASTICS IN PHOTOVOLTAICS
2 0 1 3
International conference on backsheets, encapsulants and other polymer materials in photovoltaic systems
CLICK HERE FOR DETAILS

September 10-11, 2013


Images courtesy of: EVONIK INDUSTRIES AG and SBM SOLAR INC.

Hilton Philadelphia City Avenue, Philadelphia, Pennsylvania, USA

SPECIAL OFFER: Save $200 if you register before August 2, 2013


Organized by: Applied Market Information LLC Media supporters:

Amanda Schaeffer Conference Coordinator as@amiplastics-na.com Ph: +1 610 478 0800 Fx: +1 610 478 0900

Download the programmes for these forthcoming conferences


Simply click on the brochure cover or link to download a PDF of the full publication

Polyolen Additives
PolyolefinAdditives2013
International conference on compounding of polyolefins focusing on PP and PE materials and applications

Medical Grade Polymers


Medical Grade Polymers 2013
Technical conference debating material selection, safety and manufacturing of medical devices

10-12 September 2013


Hotel Nikko, Dsseldorf, Germany
Images courtesy of: songwon International aG
* + 19% German VAT

speCIal OFFeR: Save 100* if you register before 19th July 2013
Organised by: Applied Market Information Ltd. Sponsored by: Media supporters:

The sixth Polyolen Additives conference is being organised by AMI in Dsseldorf, Germany on 10-12 September. The programme covers the latest developments in a variety of additives for improving the properties, durability and appearance of PE and PP.

Photo courtesy of HTP-Meds, LLC.

AMIs next conference on Medical Grade Polymers takes place in Woburn/ Boston, Massachusetts, USA, on 17-18 September. Download the brochure, which has the full programme with its impressive selection of expert speakers.

September 17-18, 2013


Images courtesy of: HTP-MEDS LLC and POLYONE CORPORATION

Crowne Plaza Boston/Woburn, Woburn, Massachusetts, USA

SPECIAL OFFER: Save $200 if you register before August 9, 2013


Organized by: Applied Market Information LLC Media supporter:

1 1534 or email to: ge@amiplastics.com

Click here to download

Click here to download

Fire resistance in Plastics


FIRE RESISTANCE IN PLASTICS 2013
Trends and technical developments in the international flame retardant industry

Flexible Packaging Middle East


Flexible Packaging Middle East 2013
Market opportunities for films driven by technical sophistication

12-14 November 2013


Maritim Hotel, Cologne, Germany
Images courtesy of: chemische fabrik Budenheim KG and international antimony association
* + 19% German VAT

AMI is running the eighth international Fire Resistance in Plastics conference on 12-14 November in Cologne, Germany. The high-level programme covers the latest technology developments, market trends and regulatory changes.

HEADLINE SPONSOR

9-11 December 2013


Images courtesy of: Borouge Pte Ltd., Norner AS, Innovia Films

Sofitel Hotel, Abu Dhabi, United Arab Emirates

The fth Flexible Packaging Middle East conference is being held in Abu Dhabi, UAE on 9-11 December. Download the brochure to see the full programme, which features expert speakers covering the latest materials and processing technologies.

SPECIAL OFFER: Save 200 if you register before 25th October 2013

Special offer: Save 210* if you register before 4th October 2013
Organised by: Applied Market Information Ltd. Sponsored by: Media supporter:

Click here to download

Organised by: Applied Market Information Ltd.

Also sponsored by:

Media supporter:

Fax back to: +44 (0) 117 311 1534 or Email: sp@amiplastics.com

Click here to download

11 1534 or email: ab@amiplastics.com

Thin Wall Packaging


Thin Wall Packaging 2013
International conference on market trends and developments in plastics tubs, cups and tray packaging

Compounding World Forum


AMI and Compounding World magazine are holding the rst Compounding World Forum in Philadelphia on 10-11 December. It will cover technical compounding developments, including market trends, new additive technologies and getting the most from twin-screw extruders.

3-5 December 2013


Maritim Hotel, Cologne, Germany

AMIs eighth international conference on Thin Wall Packaging takes place on 3-5 December in Cologne, Germany. The programme includes speakers from throughout the supply chain for thermoformed and injection moulded packaging.

The international conference on business strategies and new technologies for compounders

December 10-11, 2013


Hilton Philadelphia City Avenue, Philadelphia, Pennsylvania, USA
Images courtesy of: Coperion, Foster Corporation, PolyOne, Renault, and Teknor Apex

Images courtesy of: Faech Plast As, Micvac, saentis Packaging AG and silgan Plastic Food Containers

* + 19% German VAT

sPECIAL OFFER: Save 150* if you register before 1st November 2013
Organised by: Applied Market Information Ltd. Sponsored by: Media supporters:

SPECIAL OFFER: Save $200 if you register before November 1, 2013

11 1534 or Email: ml@amiplastics.com

Click here to download

Organized by: Applied Market Information LLC & Compounding World

Sponsored by:

Click here to download

To see our full line-up of more than 25 plastics industry events over the next 12 months, please visit www.amiconferences.com

This months free brochure downloads


Simply click on the brochure cover or link to download a PDF of the full publication

Reduction Engineering: pelletizers


This Reduction Engineering brochure features the S3500 Series strand pelletizers that are designed to substantially reduce maintenance and cleaning times. Four models are available with capacities up to 11,750 lb/h (5,330 kg/h).
Strand Pelletizer S3500 Series Granulador de Hebra Serie S3500

B&P: Trivolution Tri-Kneader


This new eight-page brochure from B&P Process Equipment has full details of the revolutionary Trivolution Series Tri-Kneader that can deliver signicant processing benets for a range of compounding applications.

Click here to download

Click here to download

ICMA: compounding systems


This 20-page brochure from ICMA San Giorgio covers the companys advanced compounding and extrusion systems. These include special lines for recycling, direct extrusion, reactive compounding, and processing natural bres.

Steer: SPL40 turn-key lines


This eight-page brochure covers Steer Engineerings new SPL40 compounding pelletizing systems that include feeders, extruders, strand die heads, water troughs, air knives, pelletizers and classiers.

ONE CO-ROTATING HEART IS BEATING IN OUR SYSTEMS

CO-ROTATING TWIN SCREW EXTRUDERS

COMPOUNDING

ADVANCED RECYCLING

NATURAL FIBERS

DIRECT EXTRUSION

LAB SYSTEM

OUR PEOPLE MAKE THE DIFFERENCE

www.icmasg.it

Click here to download

Click here to download

ADG: Fimic lter changer


This brochure from ADG Solutions has full information on the Fimic self-cleaning lter changer, which uses patented technology to ensure uninterrupted production when extruding highly contaminated materials.

Entek: extrusion solutions


Extrusion Solutions for Compounding

This brochure focuses on Enteks extrusion solutions for compounding. It covers the companys E-Max twin-screw extruders, its ability to offer complete turn-key systems, and its comprehensive spare parts service.

Click here to download

Click here to download

If you would like your brochure to be included on this page, please contact Claire Bishop. claire@amimagazines.com. Tel: +44 (0)20 8686 8139

compounder of the month

GCR Group - Granic


Head ofce location: Date founded: Ownership: No. of employees: Sales 2012: Plant locations: Capacity/production 2012: Prole: Barber del Valls (Barcelona), Spain 2001 Privately owned 95 50-100 million Barber del Valls (Barcelona), La Bisbal del Peneds (Tarragona) 110,000 tonnes/85,000 tonnes GCR, formerly Gestora Catalana de Residuos, is a family owned business that includes three business units: Ciclic (plastics recycling), Granic (compounding) and Irtion (technology). The company installed its rst 55,000 tonnes/year compounding line in Barcelona in 2008, and commissioning a second line of the same size at a new plant in Tarragona in 2011. The third 55,000 tonnes/year line becomes operational this month and a fourth will be commisioned next year. By the end of 2014, GCRs compounding capacity will be 220,000 tonnes/year, in addition to 35,000 tonnes/year for plastics recycling. Granic PE, PP and PS masterbatches (with virgin or recycled carrier resin) contain 75-85% calcium carbonate or talc and are used in lm, sheet, rafa, pipe, extrusion coating, and blow and injection moulding applications. Granic is marketed as an eco-friendly product. The claimed benets include 100% recyclability, CO2 emission reduction, energy saving, material cost saving and improved mechanical properties. In addition, Granic works with really low MFI, is compatible with degradable agents and is price stable given the high ller content and therefore low dependency on oil.

Product line:

Product strengths:

Forthcoming features
The next issues of Compounding World magazine will have special reports on the following subjects: August PVC plasticizers Functional llers First look at K 2013 September Pigments and colorants Materials testing and analysis K 2013 show preview

Editorial submissions should be sent to Andy Beevers: abe@amiplastics.com For information on advertising in these issues, please contact Claire Bishop: claire@amimagazines.com Tel: +44 (0)20 8686 8139

Catch up on our recent issues for FREE


Simply click on the cover to see the full magazine, or download the issue in the relevant Apple or Android app
Compounding World June The June edition of Compounding World looks at additives for the production of bioplastic compounds as well as the latest developments in stabilizers for PVC. It also considers the options for accelerating weathering resistance tests. Click here to view Compounding World May Compounding Worlds May issue has special features on: electrically-conductive additives and compounds; the latest wood-plastic composite technologies; and, developments in clariers, nucleating agents and processing aids. Plus it includes Chinaplas 2013 highlights. Click here to view

Injection World July/Aug The July/August edition of Injection World has special features on: durable applications for bioplastics; the latest automation systems; optimising hot runners; developments in claried PP; and getting ready for K 2013. Click here to view

Injection World June The June issue of Injection World is packed with information on the latest trends in caps and closures, in-mould labelling and polymer distribution. In addition, it has useful tips on hot-runner control, cold-runner design and colour measurement techniques. Click here to view

Pipe and Prole July/August This issue of Pipe and Prole Extrusion examines the latest developments in recycling technology, window proles, testing procedures for pipes, and control and instrumentation systems. It also has useful links to prepare for your visit to K 2013 Click here to view

Film and Sheet June The June issue of Film and Sheet Extrusion is lled with features on the following: barrier materials for boosting shelf life; recent developments in bioplastics; sustainability trends in thermoforming; and the latest control and instrumentation systems. Click here to view

Take out your own FREE subscriptions to any of the magazines. Click on the logos below to simply register on-line.

dates for your diary

Global exhibition guide


3-6 September 5-7 September Applas, Shanghai, China Plasti & Pack, Lahore, Pakistan Plastec Midwest, Chicago, USA Mediplas, Birmingham, UK PPP Africa, Nairobi, Kenya K 2013, Dsseldorf, Germany Yiwu Packaging, Printing & Plastics, China Plastics & Rubber Indonesia, Jakarta Plast Eurasia, Istanbul, Turkey Plastivision, Mumbai, India Swiss Plastics, Lucerne, Switzerland Interplastica, Moscow, Russia Plastec West, Anaheim, CA, USA Saudi Plastics & Petrochem, Riyadh Plastics & Rubber Vietnam, Ho Chi Minh Plastivision Arabia, Sharjah, UAE www.applas.com www.pk-plastipack.com www.plastecmidwest.com www.mediplasuk.com www.pppexpo.expogr.com www.k-online.de www.yiwuppp.com www.pamerindo.com www.plasteurasia.com www.plastivision.org www.swissplastics.ch www.interplastica.de www.plastecwest.com www.saudipp.com www.plasticsvietnam.com www.plastivision.ae 10-12 September 25-26 September 4-6 October 16-23 October

19-22 November 20-23 November 2014 21-23 January 28-31 January 11-13 February 16-19 February 4-6 March 7-10 April 5-8 December 12-16 December

AMI conferences
10-12 September 16-18 September 17-18 September 12-14 November 19-21 November 10-11 December 28-30 January 18-20 February 24-26 February 11-13 March 18-20 March Polyolefin Additives Agricultural Film, Madrid, Spain Medical Grade Polymers Fire Resistance in Plastics, Cologne, Germany Polymer Foam, Hamburg, Germany Compounding World Forum, Philadelphia, PA, USA Thermoplastic Concentrates, Coral Springs, FL, USA Grass Yarn & Tufters Forum, Barcelona, Spain PVC Formulation, Dsseldorf, Germany Cables, Cologne, Germany Green Polymer Chemistry, Cologne, Germany

2014

For information on all these events and other conferences on film, sheet, pipe and packaging applications, see

www.amiplastics.com

Dont miss a single issue


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