Sri Chaitanya IITJEE Academy

Sec:

CHEMISTRY IIT QUESTIONS IV GROUP

Single Answer Questions : 6. An inorganic compound (A) made two most occuring elements into the earth crust having polymeric tetrahedral network structure with carbon, compound (A) produces a poisonous gas (B) which is the most stable diatomic molecule compounds (A) and (B) will be a) SiO2 . CO2 b) SiO2, CO c) SiC, CO d) SiO2, N2 9. In which of the following silicates, only two corners per tetrahedron are shared i) Pyrosiciate ii) Cyclic silicate iii) Double chain silicate iv) Single chain silicate v) 3D silicate vi) Sheet silicate a) i, ii, iii b) iv and vi only c) i and vi only d) ii and iv only Select the wrong statement about silicates a) Cyclic silicate hawing three Si atoms contains SiX Si - O - Si linkages b) 2
1 corner oxygen atoms per tetraheron unit are shared in double chain silicate 2
2n-

10.

c) ( Si2O5 ) n

is formula of double chain silicate

d) SiO44- units polymerise to form silicate because Si atom has less tendency to form p bond with oxygen 11. The silicate anion in the mineral kinoite is a chain of three SiO4 tetrahedra that share corners with adjacent tetrahedra.The mineral also contains Ca 2+ ions, Cu2+ ions, and water molecules in a 1: 1: 1 ratio mineral is represented as: 1) CaCuSi3O10.H2O 2) CaCuSi3O10.2H2O 3)Ca2Cu2Si3O10.2H2O 4) none of these 6 Si2 O7 anion is obtained when: 1) no oxygen of a SiO4 tetrahedron is shared with another SiO4 tetrahedron 2) one oxygen of a SiO4 tetrahedron is shared with another SiO4 tetrahedron 3) two oxygen of a SiO4 tetrahedron are shared with another SiO4 tetrahedron 4) three or all four oxygen of a tetrahedron are shared with other SiO4 tetrahedron Select correct statement 1) Cyanamide ion CN 2 2 - is iso-electronic with CO2 and has the same linear structure 2) Mg2C3 reacts with water to form propyne 3) CaC2 has NaCl type of lattice 4) all are correct statements PbCl2 is more ionic than PbO2 because 1) The radius of Pb2+ is more than that of Pb4+ 2) Of inert pair effect 3) Chlorine is more electronegative than oxygen 4) Chlorine atom is smaller than oxygen atom The hydrolysis of dimethyl dichloro silane gives 1) Silicones 2) Silicates 3) SiO2 4) Silicic acid PbF4 is good fluorinating agent because 1) The Pb F bond is very weak 2) It is a fluoride of a heavy metal 3) It is unstable and dissociates on warm forming fluorine 4) Fluorine is highly electronegative Silicones are

12.

13.

14.

15. 16.

17.

1) 2) 3) 4) 18.

Synthetic polymers containing repeated R2SiO units Silicates with common SiO4 unit Ketones with silyl group (SiH3) similar to alkyl, (SiH3)2CO Zircon (meso silicates)

19.

20.

21. 22.

In the carbon family, the elements other then carbon do not form pp - pp bonds, because the 1) atomic orbitals are too small and diffused to undergo effective lateral overlap 2) atomic orbitals are too large and diffused to undergo effective lateral overlap 3) atomic orbitals are too large and less diffused to overlap linearly 4) atomic orbitals are too small to overlap both laterally and linearly Which of the following statements is incorrect in the context of diamond? 1) Each C atom is tetrahedrally surrounded by four other carbon atoms, each at a distance of 154 pm 2) The tetrahedral units are linked together into a three-dimensional giant molecule. 3) The unit cell has a body - centred cubic structure. 4) Strong covalent bonds extend in all directions. Even though thermondynamically favourable, the conversion of diamond into graphite does not occur normally since. 1) the activation energy of the process is high 2) the activation energy of the process is low 3) the change of entropy is zero 4) the change of enthalpy is zero. 0 Calcium carbide on heating with nitrogen at 1100 C in an electric furnace produces. 1) calcium cyanide 2) calcium nitride 3) calcium amide 4) calcium cyanamide Solid CO2 is produced as white snow by 1) cooling the gas below its inversion temperature 2) cooling the gas below boyles temperature 3) expanding the gas at a high temperature. 4) adiabatically expanding the compressed gas from the cylinder by allowing it to escape througha nozzle. The correct order of the increasing carbon- oxygen bond length of CO, CO32- and CO2 is. 1) CO32- < CO2 < CO 2) CO2 < CO32- < CO 3) CO < CO32- < CO2 4) CO < CO2 < CO32The silicate minerals are classified on the basis of the manner of linking of 1) SiO42- tetrahedral units 3) SiO72- units 2) SiO44- tetrahedral units 4) ( SiO3 )n 2) Na4 Si2O7
4 n-

23.

24.

triangular units 4) Zn2 [ SiO4 ]

25.

Which of the following minerals is classified as an orthosilicate? 1) CaMg ( SiO3 )2 3) Ca3 [ Si3O9 ] The length of the N - Si bond in ( SiH 3 )3 N is shorter than what is normally expected for an N- Si single bond. This is due to 1) sp 2 - sp 3s overlap between N and Si atoms 2) localized pp - d p bonding between the N atom and one of the three Si atoms

26.

3) delocalized four-centred two-electron pp - d p bonding spread over the N atom and all the three Si atoms 4) localized p- pp bonding between the N atom and one Si atom. 29. The melting point of AlF3 is 1040C and that of SiF4 is 770C (it sublimes) because : 1) There is a very large difference in the ionic character of the Al F and Si F bonds

30.

31.

32.

33.

2) In AlF3, Al3+ interacts very strongly with the neighbouring F ions to given a three dimensional structure but in SiF4 no such interaction is possible 3) the silicon ion in the tetrahedral SiF4 molecule is not shielded effectively from the fluoride ions whereas in AlF3, the Al3+ ion is shielded on ll sides 4) the attractive forces between the SiF4 molecules are strong whereas those between the AlF3 molecule are weak Sn(II) is a stronger reducing agent than Pb(II) because 1) Pb(II) is less stable than Sn(II) 2) Pb(II) is less stable than Pb(IV) 3) Sn(IV) forms more covalent compounds 4) Pb(II) forms covalent compounds The silicate anion in the mineral kinoite is a chain of three SiO4 tetrahedra that share corners with adjacent tetrahedra.The mineral also contains Ca 2+ ions, Cu2+ ions, and water molecules in a 1: 1: 1 ratio mineral is represented as: 1) CaCuSi3O10.H2O 2) CaCuSi3O10.2H2O 3)Ca2Cu2Si3O10.2H2O 4) none of these The silicate anion in the mineral kinoite is a chain of three SiO4 tetahedra, that share corners with adjaacent tetrahedra.The charge of the silicate anion is: 1) 4 2) 8 3) 6 4) 2 The geometry with respect to the central atom of the following molecules are : N(SiH3)3; (CH3)3N; (SiH3)3P 1) Planar, pyramidal, planar 2) Planar, pyramidal, pyramidal 3) Pyramidal, pyramidal, pyramidal 4) Pyramidal, planar, pyramidal The silicate minerals are classified on the basis of the manner of linking of 1) SiO42- tetrahedral units 3) SiO72- units 2) SiO44- tetrahedral units 4) ( SiO3 )n
4 n-

34.

triangular units

38.

39.

40.

41.

D H2C2O4(B) gas (A) + gas (B) + liquid (C). Gas (A) burns with a blue flame and is oxidised to gas ( B ) NH 3,D Gas (A) +Cl2 ( D ) ( E ) A,B,C and E are: 1) CO2,CO,H2 O, HCONH2 2) CO,CO2,COCI2, HCONH2 3) CO,CO2 H2O,NH2CONH2 4) CO,CO2,H2O, COCI2 6 Si2 O7 anion is obtained when: 1) no oxygen of a SiO4 tetrahedron is shared with another SiO4 tetrahedron 2) one oxygen of a SiO4 tetrahedron is shared with another SiO4 tetrahedron 3) two oxygen of a SiO4 tetrahedron are shared with another SiO4 tetrahedron 4) three or all four oxygen of a tetrahedron are shared with other SiO4 tetrahedron The structural of silicon (IV) oxide belongs to the type: 1) ionic lattice 2) macromolecular, with a layer structure 3) molecular lattice,with van der Waalsforces among the molecules 4) macromolecular, with a non-layer structure The correct order of decreasing ionic nature of lead dihalides is: 1) PbF2 > PbCl2 > PbBr2> PbI2 2) PbF2 > PbBr2 > PbCI2 > PbI2 3)PbF2 < PbCl2 > PbBr2< PBI2 4) PbI2 < PbBr2 < PbCI2 < PbF2

42. A student prepared a sample of silicon chloride by passing chlorine over heated silicon and collecting the condensed silicon chloride in a small specimen tube. He analysed the chloride by dissolving a known mass of it in water and titrating the solution with standared silver nitrate solution. The formula of the silicon chloride as obtained by this method was

SiCl2.6 as against a true formula SiCl4. Which of the following possible errors could have resulted in this wrong formula a) The silicon chloride contained excess dissolved chlorine b) More silicon chloride than the student supposed was actually used owing to in accurate weighing c) The small specimen tube was not dry d) The reaction between the silicon and the chloride stopped prematurely leaving some unreacted silicon in the reaction tube
45. 46. The dehydration of malenic acid CH2(COOH)2 with P4O10 and heat give 1) Carbon monoxide 2) Carbon sub oxide 3) Carbon dioxide 4) All three In which of the following silicates, only two corners per tetrahedron are shared i) Pyrosiciate ii) Cyclic silicate iii) Double chain silicate iv) Single chain silicate v) 3D silicate vi) Sheet silicate a) i, ii, iii b) iv and vi only c) i and vi only d) ii and iv only When oxalic acid is heated with conc H2SO4, two gases produced are neutral and acidic in nature respectively. Potassium hydroxide absorbs one of the two gases. The product formed during this absorption and the gas which absorbed are raspectively. a) K2CO3 and CO2 54. b) KHCO3 and CO2 c) K2CO3 and CO d) KHCO3 and CO Cu CH 3Cl + Si A 570 K A on hydrolysis followed by polymerisation gives

47.

1) Si(CH3)3 Si(CH3)3

2)

3)

4)

55.

Select incorrect statement 1) Cyanamide ion CN 2 2- is iso-electronic with CO2 and has the same linear structure 2) Mg2C3 reacts with water to form propyne 3) CaC2 has C22 and it contains one sigma and two pi type of bonds 4) Al4C3 has is an example of methanide carbide and it contains C34Name the structure of silicates in which three oxygen atoms of [SiO4]4 are shared a) Pyrosilicate b) Sheet silicate c) Linear silicate d) Three dimensional silicate Which of the following statements is not correct?

56. 57.

a) The durability and inertness of silicones is due to the high bond enthalpy of Si O bond b) Silicones are used in water - proofing textiles c) Silicone rubbers are excellent electrical insulators d) The silicones always involve cross-linked between Si and O atoms

Assertion & Reason Type Questions : 1) Both A and R are true and R is correct explanation of A 2) Both A and R are true and R is not correct explanation of A 3) A is true and R is false 4) A is false and R is true 101. Assertion (A) : In the hydrolysis of an asymmetrically substituted silicon compound such as . MeEtPhSi*Cl the walden inversion will occur. 2 Reason (R) : The hydrolysis will follow SN mechanism through trigonal bipyramidal intermediate. 102. Assertion (A) : SiF62 - is known but SiCl62 - is not known Reason (R) : Size of fluorine is small and its lone pair of electrons interacts with d-orbitals of silicon stronger Assertion (A) : Silicones are hydrophobic in nature Reason (R) : Si O - Si linkages are moisture sensitive STATEMENT 1 Sn2+ ion is a reducing agent while Pb2+ is not. because STATEMENT 2 In p-block element the ns electron pair becomes less reluctant towards bonding down a Group.

103. 106.

107.

STATEMENT 1 Unlike organic ketones, inorganic silicones exist in polymeric form because STATEMENT 2 Silicon atom being larger in size as compared to carbon atom, is unable to form effective p-bond with oxygen atom. 108. Assertion (A) : Dimethyl dichloro silane on hydrolysis followed by condensation gives cross-linked silicones Reason (R) : Silicones are macromolecules containing repeating Si O Si linkage

More Than one Answer Type Questions : 201. Select the correct statement about silicates: 1) Cyclic silicate having three Si atoms contains six SiO Si linkages.
1 2) 2 over oxygen atoms of per tetrahedron unit are shared in double chain silicate 2

3) ( Si O ) 2 n- is formula of double chain silicate 2 5 n 4) SiO44- units polymerize to form silicate because Si atom has less tendency to form p-bond with oxygen 202. Which of the following statements are correct about silicons 1) They are formed by the hydrolysis of R2SiCl2 2) They are polymers made up of R2SiO2 units

43) They are made up of SiO4 units 4) They are macro molecules 203. Which of the following statement(s) is/are correct 1) PbI4 is not known because of the oxidising power of Pb(+ IV) and the reducing power of I 2) SnCl2 does not hydrolyse 3) SnCl2 is reducing agent 4) Tin (II) chloride is linear in shape 204. Which of the following statements is/are correct 1) Trisilyl amine (SiH3)3 N is a weaker base than trimethyl amine (CH3)3N 2) Silicon has more tendency to form p bonds with oxygen than phosphorous 3) Structure of silicon is same as that of dimond 4) SiO2 is a high melting solid

205. When SO2 is passed through sodium carbonate solution, then CO2 gas is liberated. This is because 1) CO2 is more volatile than SO2 2) CO2 has a lower molecular weight than SO2 3) SO2 is a stronger acid than CO2 4) CO2 is a stronger acid than SO 206. Identify A,B,C and D in the following reaction sequence.

1) The compound A is (CH3)2 SiCl2 2) The compound C and D are SiO2 and SiC respectively 3) The compound B is (CH3)2Si(OH)2 4) The compound B is (CH3)2S == O 207.

Hence 1) A = Na2SiO3 2) B = SiF4 3) C and D are H2SiO3 andd H2SiF6 respectively 4) C and D are F2 and H2O2 respectively 208. C(OH)4 is unstable because a carbon atom cannot hold more then one -OH but Si(OH)4 is a stable compound because a) Carbon can form strong pp - pp bonds with oxygen by eliminating water b) Silicon atom due to bigger size cannot form strong pp - pp bonds with oxygen by eliminating water. c) Silicon can form strong d p - pp bonds with lone pairs on oxygen d) Silicon being more electronegative than carbon can hold four OH groups 214. Which of the following is are correct for group 14 elements?

1) The stability of dihalides are in the order CX2 < SiX2 < GeX2 < SnX2 < PbX2 2) The ability to form p p-pp multiple bonds among themselves increases down the group 3) The tendency for catenation decreases down the group 4) They alll form oxides with the formula MO2 219. SiO2 reacts with: 1) Na2 CO3 2) CO2 3) HF 220. Which of the following statement (s) is/are true? 1) The lattice structure of diamond and graphite are different 2) Graphite is an impure form of carbon while diamond is a pure form 3) Graphite is harder than diamond 4) Graphite is thermally more stable than diamond

4) HCI

221. When SO2 is passed through sodium carbonate solution, then CO2 gas is liberated. This is because 1) CO2 is more volatile than SO2 2) CO2 has a lower molecular weight than SO2 3) SO2 is a stronger acid than CO2 4) CO2 is a stronger acid than SO 227. Select the correct statements about silicates a) Cyclic silicate hawing three Si atoms contains SiX Si - O - Si linkages b) 2
1 corner oxygen atoms per tetraheron unit are shared in double chain silicate 2
2n-

c) ( Si2O5 ) n

is formula of double chain silicate

d) SiO44- units polymerise to form silicate because Si atom has less tendency to form p bond with oxygen 228. Which of the following statement is correct? a) Organo silicon polymers are known as silicones b) Silicones have the general formula (R2SiO)n where R is CH3, C2H5, C6H5 etc. c) Hydrolysis of dialkyl dichlorosilane produces cross-linked silicone polymer d) Hydrolysis of alkyl trichlorosilane produces cross-linked silicone polymer 229. In which of the following all the atoms are in sp3 hybridization a) Diamond b) Carborundum c) Crystalline silicon d) Quartz

Comprehension Type Questions : Passage - I Read the following passage and answer the questions followed by is The name silica covers an entire group of minerals which name the general formula SiO2, the most common of which is quartz. Quartz is a frame work silicate with SiO4 tetrahera arranged in spirals. The spirals can turn in clock wise or anticlockwise direction a feature that results in there being two mirror images optically active varieous of quartz 301. The following represents various silicate anions. There formulae are respectively

O = oxygen = silicon

O
8b) SiO44 - , Si3O10 2c) SiO4 , Si3O928d) SiO34 - , Si3O7

a) SiO32 - , Si3O72-

302. SiO96 - (having three tetraheral units) is repregented as

O
O O

a) O

b)
O O O

O c) Both d) none 303. The silicates anion in the mineral kaionite is a chain of three SiO4 tetrahera that share corners with adjacent tetrahedra. The mineral also contain Ca2+ acid Cu2+ ions and water molecules in a 1 : 1 : 1 ratio. The mineral is represented as a) Ca Cu Si3 O10 . H2O b) Ca Cu Si3 O10 . 2H2O c) Ca2 Cu2 Si3 O10 . 2H2O d) Ca2 Cu Si3 O10 . 4H2O Passage - II Read the following passage and answer the questions followed by is Silicones are synthetic polymers containing repeated R2SiO2 units. Since the empirical formula is that of a ketone (R2CO) the name silicone has been givwen to these materials silicones can be made into oils, rubbery elastomers and resins. They find a variety of applications because of their chemical inertness, water repelling nature, heat - resistance and good electrical insulating properly. Commerical silicon polymers are usually methyl derivatives and to a legger extent phenyl derivatives and are synthesised by the hydrolysis of

R2 SiCl2 R = methyl ( Me) or phenyl ( f )

Me Me Me

H 2O Me2 SiCl2 -O - Si - O - Si - O - Si -

Me

Me

Me

is mixed 304. If Me3SiCl is mixed with Me2SiCl2 the silicones formed of the type

Me
Me Me Me Me

Me

-O - Si - O - Si - O

a) Me2 - Si - O - Si - O - Si - O - Si - Me
Me Me Me Me

b)

-O - Si - O - Si - O
Me Me

c) Both d) cross linked or three dimensional silicones 305. If Me SiCl3 alone is taken as stating material, the silicone formed is a) a linear silicone c) cyclic cilicone a) linear silicone c) cross linked silicone Passage I : Although stoichiometry similarities exists between the compounds of carbon and those of the remaining elements of group IV B, there is no structural or chemical similarity between them. Ex : CO2 is gas SiO2 is solid. Reaction of the compounds of silicon and the lower elements of group donot give products analogous to those for carbon . For example the dehydration of alcohols gives alkene but the dehydration of silanols give different products accompained by condensation. In carbon multiple bonds involve overlap of the p - p variety mulitple bonding for silicon and germanium usually arise from p - d component especially in bonds to O and N. It is important to note that this does not usually lead to conjugation as is so prevalent for carbon. The p - d bonding character decreases with increase the atomic size down the group. 307. Among trisylylamine (H3Si)3N and trimethyl amine (CH3)3N 1) (H3Si)3N and (CH3)3N both are pyramidal in shape and equally basic. 2) (H3Si)3N and (CH3)3N both are pyramidal in shape but (H3Si)3N is more basic than (CH3)3N 3) (H3Si)3N is planar while (CH3)3N is pyramidal and (H3Si)3N is more basic than (CH3)3N 4) (H3Si)3N is planar while (CH3)3N is pyramidal and (H3Si)3N is less basic than (CH3)3N 308. Among (H3Si)3 P and (H3Si)3 N 1) Both are pyramidal in which P and N are involved in sp3 hybridisation. 2) Both are planar in which P and N are involved in sp2 hybridisation. 3) (H3Si)3 P is planar while (H3Si)3 N is pyramidal where P is involved in sp2 and N is involved in sp3 hybridisation. 4) (H3Si)3 P is pyramidal with P is involved in sp3 hybridisation while (H3Si)3 N is planar with N is involved in sp2 hybridisation. 309. Among H3Si NCO and H3C NCO 1) Both are linear 2) Both are angular 3) H3Si NCO is linear while H3CNCO is angular 4) H3SiNCO is angular while H3CNCO is linear Passage : I A white precipitate (X) is formed when a mineral (A) is boiled with Na2CO3 solutions. The precipitate is filtered and filtrate contains two compounds (Y) and (Z). The compound (Y) is removed by crystalization and when CO2 is passed through the filterate obtained after crystal b) dimeric silicone d) three dimentional silicone b) cyclic silicone d) both A and B

306. If Me2 SiCl2 alone is taken as starting material, the silicone formed is

lization then (Z) changes to (Y). When compound (Y) is heated it gives twocompounds (Z) and (T).compound (T) on heating with cobalt oxide produced blue coloured substance(S). 310. The mineral (A) is 1) Na2B6O11 2) Na2B4O7 3) Ca2B6O11 . 5 H2O 4) B2O3 311. The compound (Y) in the filterate when (A) is boiled with Na2CO3 is 1) Na2BO2 2) CaCO3 3) Na2B4O7 4) CaO 312. When cobalt oxide is heated with (Y) then a bead (S) is formed which is blue in colour. The bead (S) is 1) CoCO3 2) Co(BO2)2 3) CoO 4) B2O3 Passage : Rocks, clays and soils are made up of silicates of aluminium, iron, magnesium and other metals. All silicates are made up of SiO4 tetrahedral units in which Si is sp3-hybridized is surrounded by four oxygen atoms. The SiO4 tetrahedra can be linked together in several different ways. Depending on the number of corners of the SiO4 tetrahedra shared, various kinds of silicates are formed 313. A fibrous mineral which can withstand red hot flames without any damage is 1) Talc 2) Glass wool 3) Soap stone 4) Asbestos 314. Quartz watches contain 1) A crystal of quartz as an essential component 2) A coating of quartz on the outer body 3) Hands made of quartz 4) Silica coated on the number 315. Which of the following is not a crystalline form of silica? 1) Quartz 2) Tridymite 3) Cristobalite 4) Kieselguhr Passage - I: Carbides are three types ; ionic, covalent and interstitial. CaC2 is one of the commercially important ionic carbide. D x + C CaC2 + CO
11000 C CaC2 + y z + C

Z + H2O NH3 + CaCO3 Z is an important nitrogenous fertiliser 316. X is 1) CaO 2) CaCO3 3) Ca(OH)2 4) CaCl2 317. Y and Z respectively are 1) N2O and Ca(CN)2 2) (CN)2 and CaCN2 3) N2 and Ca(CN)2 4) N2 and CaCN2 318. Covalent carbide among the following is 1) Mg2C3 2) SiC 3) WC 4) Fe3C Passage: Following flowsheet is used to prepare pure silicon. Answer the question based on it Direction: Q.Nos. (13 15)

319.

320.

321.

Step A is 1) fractional distillation 3) ultra-filtration Step B involves 1) thermal decomposition 3) reduction with Na or Mg Pure quartz glass contains 1) SiO2 2) Si

2) zone-refining 4) none of these 2) reduction with H2 4) hydrolysis 3) SiO2, B2O3 4) SiO2, Al2O3

Passage: Although stoichiometry similarities exists between the compounds of carbon and those of the remaining elements of group IV B, there is no structural or chemical similarity between them. Ex : CO2 is gas SiO2 is solid. Reaction of the compounds of silicon and the lower elements of group donot give products analogous to those for carbon . For example the dehydration of alcohols gives alkene but the dehydration of silanols give different products accompained by condensation. In carbon multiple bonds involve overlap of the p - p variety mulitple bonding for silicon and germanium usually arise from p - d component especially in bonds to O and N. It is important to note that this does not usually lead to conjugation as is so prevalent for carbon. The p - d bonding character decreases with increase the atomic size down the group. 322. Among trisylylamine (H3Si)3N and trimethyl amine (CH3)3N 1) (H3Si)3N and (CH3)3N both are pyramidal in shape and equally basic. 2) (H3Si)3N and (CH3)3N both are pyramidal in shape but (H3Si)3N is more basic than (CH3)3N 3) (H3Si)3N is planar while (CH3)3N is pyramidal and (H3Si)3N is more basic than (CH3)3N 4) (H3Si)3N is planar while (CH3)3N is pyramidal and (H3Si)3N is less basic than (CH3)3N 323. Among (H3Si)3 P and (H3Si)3 N 1) Both are pyramidal in which P and N are involved in sp3 hybridisation. 2) Both are planar in which P and N are involved in sp2 hybridisation. 3) (H3Si)3 P is planar while (H3Si)3 N is pyramidal where P is involved in sp2 and N is involved in sp3 hybridisation. 4) (H3Si)3 P is pyramidal with P is involved in sp3 hybridisation while (H3Si)3 N is planar with N is involved in sp2 hybridisation. 324. Among H3Si NCO and H3C NCO 1) Both are linear 2) Both are angular 3) H3Si NCO is linear while H3CNCO is angular 4) H3SiNCO is angular while H3CNCO is linear

Matching Type Questions : 401. Column- I (A) Sheet silicate (B) Pyroxene chain (C) Pyro silicate ( D ) Amphibole chain 402. List - I a) ( SiO3 )n c) Si2O
67

Column II (P) ( SiO3)n2n

n ( Q) ( Si4O11 ) 6 n (R ) 3 corner oxygen atom are shared (S) Non planar List - II

2 n-

p) Cyclic silicate q) Chain silicate r) Contain Si-O-Si bond

b) Silicone d) ( Si4O 11)n

6n-

s) Pyrosilicate.

403. Match the following Column I with Column II Column I a) Absestos b) Willemite c) Anglesite d) Diaspore Column II p) Calcium q) Lead r) Silicate s)Aluminium t) Sulphate

404. Match the following Column I with Column II Column I a) Orthosilicate b) Pyrosilicate c) Single chain silicate d) Ring silicate Column II p) Oxygen atoms shared < 2 q) Oxygen atoms shared > 2 r) Net charge = 2 s) Net charge = 6

406. Match the following Column I with Column II Column I Column II a) CO b) PbO2 c) GeO d) SnO p) Neutral q) Amphoteric r) Reducing agent s) Oxidising agent

Integer type questions: 502. The covalency of silicon in hydro fluoro silicic acid is 503. In the formation of cyclic silicones number of oxygen atoms belonging to each silicon atom in the ring is

CHEMISTRY KEY IV GROUP (11-11-11) IIT TEST Sec :

1.3 11. 21.4 31.1 41. 51. 2.2 12. 22.4 32.3 42. c 52. 3.3 13. 23. 4 33.2 43. 53. 4.2 14. 24.2 34.2 44. 54.2 5.1 15. 25. 4 35.3 45. 55.4 6.2 16. 26.3 36. 46.4 56.b 7.1 17. 27.4 37. 47.1 8.2 9.4 19. 3 29.2 39. 49. 10.1 20.1 30.4 40. 50.

18. 2
28.2 38. 48.

57.d

101.

102.

103.

104.

105.

106. 3

107.1

108.

109

110.

111.4

112.

201. 214.1,2,3 222.

202.

203. 215.1,2

204. 216.1,2,3 225.

205. 3

206. 1, 2, 3 212. 1, 3, 4 218. 217.

207. 1, 2, 3 213. 1, 2 3 219. 220.

208.1,2 221.

209.1, 2, 4 223.

210. 1, 2, 3 224.

211. 1, 2, 3, 4 226. 227.2,3,4

228.a, b, d 229.a, b, c, d

251.

301.2 311. 3 321.

302.2 312. 2 322.4

303.3 313.4 323.

304.1 314.1 324.3

305.4 315.4 325.a

306.4 316. 1 326.d

307.4 317. 4 327.d

308.3 318.2

309.2 319.

310.3 320.

401. a q, r, s; b p, s; c s; d p, s 402. a p, q, r; b r; c r, s; d q, r p; b p, s; c q, r; d q, r 405. 406.A - p, r; B - q, s; C - q, r ; D - q, r

403.

404.a

501.0

502.6

503.1

1.

Sol :c

O O

O O

HO - S - S - OH
O O I

HO - S - OH
O II

HO - S - S - OH
O III

2.

From these structures the number of p bonds in I, II and III are 4, 2 and 3 respectiively. So increasing order of no of p bonds is II III and I. Sol :b Structure of H2SnO6 is
O O

HO - S - Sn - 2 - S - OH
O O

3.

So n - 1 Sol : c In polythionic acids the oxidation states of two terminal sulphur atoms is +V. resulting in a total of 10. The average oxidation state of S decreases with increase in number of sulphur atoms (10/n) Sol :b In O2F2 bluorine being more electronegative than oxygen, it withdraws the electron density from oxygen atoms so that the repulsion between lone pairs on oxygen atoms decreases. So bond length decreases In H2O2, oxygen being more electronegative than oxygen the electron density on oxygen atoms increases. So the repulsion between lone pairs increases. Hence O-O bond length in H2O2 will become more than in O2F2

4.

5. 6.

Sol :a Sol :b Compound (A) is SiO2

D SiO2 + 2C Si + 2CO

7.

Sol :a
conc H 2 SO4 H 2C2O4 CO + CO2 - H 2O

2 KOH + CO2 K 2CO3 8. Sol :b Scarlet red compund is Pb3O4 Pb3O4 + 4 HNO3 2 Pb ( NO3 ) 2 + PbO2 + 2 H 2O

(X) (Z)

(Y )

PbO2 + 4 HCl PbCl2 + 2 H 2O + Cl2

( A)

9. 10. 27.

Sol :d In cyclic and simple chain silicates only two oxygen atoms of per tetraheron are shared Sol :a Cyclic silicate hawing Si atoms contains three Si - O - Si linkages only. Other statements are correct. Sol :d Al2O3 + 6 Na 2 Al + 3Na2O

Na2O + H 2O 2 NaOH
2 NaOH + CO2 Na2CO3 + H 2O 28. Sol :b Compound (A) is SiO2
D SiO2 + 2C Si + 2CO

46. 47.

Sol : d Sol : a
conc H 2 SO4 H 2C2O4 CO + CO2 - H 2O

2 KOH + CO2 K 2CO3 56. In pyrosilicate only one oxygen atom, in linear silicate two oxygen atoms, in three dimensional silicate all
4- ion are shared. In sheet silicate only three oxygen atoms are shared. four oxygen atoms of SiO4

57.All silicones do not contain cross-linkages 106. Down any group of p-block element, ns e pair becomes more and more reluctant towards bonding called inert pair effect. ns e-pair in Pb2+ is more inert than in Sn2+ since they lie in the same group of periodic table and Pb lies below Sn.

R
107.

O R pp - pp overlap between C and O is effective and hence is monomeric.

R Si O R

exists as polymeric (as given below)

R O Si O R R Si O R R Si O R

111.Statement I is wrong. Dimethyl dichloro silane on hydrolysis followed by condensation gives either linear or cyclic silicones but not cross linked silicones statement II is correct

208. Sol :a,b Statements a & b are correct but Statements c and d are false 227. Sol : b, c, d Cyclic silicate having Siatoms contains three Si - O - Si linkages only. Other statements are correct. 228. Hydrolysis of dialkyl dichlorosilane produces linear or cyclic silicone polymer not the corss linked silicone. The remaining are correct 301. Sol :b In the first there are one Si and four O atoms and all the O atoms are censhared carrying negative charges SO is is SiO44- . In the second case there are three Si atoms and ten O atoms of which two
8atoms are share while 8 O atoms are unshared carrying negative charges. So it is Si3O10

302. b In Si3O96 - there are 6 negative charges indicating 6 oxygen atoms are unshared and three oxygen atoms are shared which gives cyclic silicate ion 303. c The chain silicate containing three SiO4 tetrahedra will have two oxygen atoms shared while 8 oxygen atoms are unshared carrying 8 negative charges which are neutralised by 8 positive charges on Ca2+ , Cu2+ and water are in 1 : 1 : 1 ratio the formula must be Ca2 Cu2 Si3 O10 . 2H2O Sol : 304. a When Me3SiCl is mixed with Me2SiCl2 the growth of linear silicone due to hydrolysis and condensation of Me2SiCl2 will be terminated by the addition of Me3SiCl 305. d The hydrolysis and condensation of Me SiCl3 alone gives three dimensional silicone 306. d The hydrolysis and condensation of Me2 SiCl2 gives both linear and cyclic silicones 325 to 326 325. a When Me3SiCl is mixed with Me2SiCl2 the growth of linear silicone due to hydrolysis and condensation of Me2SiCl2 will be terminated by the addition of Me3SiCl 326. d The hydrolysis and condensation of Me SiCl3 alone gives three dimensional silicone 327. d The hydrolysis and condensation of Me2 SiCl2 gives both linear and cyclic silicones 401. a) Its basic unit is ( Si4O11 )n planar. so q, r, s
6 n-

. In which the corners of silicate ion are shared. Silicate ions are non

b) Pyroxene is a linear silicate in which the basic unit is ( ( SiO3 )n d) Cyclic silicate has basic unit ( SiO3 )n
2 n-

2 n-

so p, s

2- in which only two tetrahedra are present. It is non-planar so s c) Pyrosilicate is Si2O7

. It is also non-planar so p, s

501. Boric acid acts as OH acceptor but it cannot acts as H+ donar