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Sri Chaitanya IITJEE Academy

CHEMISTRY IIT TEST


Sec :

I,II,III,IV GROUPS

Single answer type questions : 1. Alkali metals displace hydrogen from water formating bases due to the reason that 1) They are far above the hydrogen in electrochemical series based on oxidation potential 2) They are far below the hydrogen in elctrochemical series based on oxidation potential 3) Their ionization enthalpy is less than that of other elements 4) They contain only one electron in their outermost shell The order of decreasing polarity in the compounds CaO, CsF, KCl, MgO is 1) CaO, CsF, KCl, MgO 2) MgO, KCl, CaO, CsF 3) KCl, CaO, CsF, MgO 4) CsF, KCl, CaO, MgO Which of the following statement is false? 1) Strontium decomposes water readily than beryllium 2) Barium carbonate melts at a higher temperature than calcium carbonate 3) Barium hydroxide is more soluble in water than magnesium hydroxide 4) Beryllium hydroxide is more basic than barium hydroxide Which of the following on thermal decomposition yields a basic as well as an acidic oxide? 1) KClO3 2) CaCO3 3) NH4NO3 4) NaNO3 X reacts with NaOH (aqueous solution) to form Y and H2. Aqueous solution of Y is heated to 323333 K and on passing CO2 into it, Na2CO3 and Z were formed. When Z is heated to 1200oC, Al2O3 is formed, X, Y and Z respectively are 1) Al, AlCl3, NaAlO2 2) Zn, Na2ZnO2, Al(OH)3 3) Al, Al(OH)3, AlCl3 4) Al, NaAlO2, Al(OH)3 The bond dissociation energy of BF in BF3 is 646 kJ mol1 whereas that of CF in CF4 is 515 kJ mol1. The correct reason for higher BF bond dissociation energy as compared to that of CF is 1) Stronger s bond between B and F in BF3 as compared to that between C and F in CF4 2) Significant pp pp interaction between B and F in BF3 whereas there is no possibility of such interaction between C and F in CF4 3) Lower degree of pp pp interaction between B and F in BF3 than that between C and F in CF4 4) Smaller size of B atom as compared to that of C atom The conductivity decreases from Li+ salts to Cs+ salts in aqueous solution because of 1) Increasing in no. of water molecules surrounding the ion in their primary shell from Li+ to Cs+ 2) Decrease in no. of water molecules surrounding the ion in the secondary layer from Li+ to Cs+ 3) The presence of vacant d-orbitals in the valence shells of K+, Rb+ and Cs+ 8. 4) Decrease in no. of water molecules surrounding the ion in their primary shell from Li+ to Cs+ Borax structure contains : 1) Two BO4 units and two BO3 units 2) Four BO4 units only 3) Two BO3 units only 4) Three BO4 and the BO3 units A compound X on heating gives a colourless gas. The residue is dissolved in water to obtain Y. Excess CO2 is passed through aqueous solution of Y when Z is formed. Z on gentle heating gives back X. The compound X is : 1) Na2CO3 2) CaCO3 3) Ca(HCO3)2 4) NaHCO3

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4. 5.

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9.

Assertion (A) & Reason (R) type questions : 1) Both A and R are true and R is correct explanation of A 2) Both A and R are true and R is not correct explanation of A 3) A is true and R is false 4) A is false and R is true Assertion (A) : Dilute solution of H2O2 is concentrated by distillation under reduced pressure

10.

Reason (R) : H2O2 dissociates before reaching its normal boiling point 11. Assertion (A) : Dimethyl dichloro silane on hydrolysis followed by condensation gives cross-linked silicones Reason (R) : Silicones are macromolecules containing repeating Si O Si linkage One or more than one correct answer type questions : 12. Choose the correct statement(s) 1) BeCO3 is kept in the atmosphere of CO2 since, it is least thermally stable 2) Be dissolves in an alkali solution forming [Be(OH)4]2 3) BeF2 forms complex ion with NaF in which Be goes with cation 4) BeF2 forms complex ion with NaF in which Be goes with anion Which of the following statement regarding the oxides of alkali and alkaline metals is correct? 1) The reactivity of K2O towards water is more than that of Na2O 2) The oxides of alkaline earth metals are more basic than those of alkali metals 3) MgO is used as a refractory material for lining of electric furnaces 4) The milk of lime and lime water are two different solutions Identify the correct statements regarding structure of diborane : 1) There are two bridging hydrogen atoms 2) Each boron atom forms four bonds 3) The hydrogen atoms are not in the same plane 4) Each boron atom is in sp3 hybridized state Which of the following product(s) may be formed by the reaction of diborane with ammonia? 1) (BN)x 2) B2H6. 2NH3 3) B3N3H6 4) B2H6. NH3 Rocks, clays and soils are made up of silicates of aluminium, iron, magnesium and other metals. All silicates are made up of SiO4 tetrahedral units in which Si is sp3-hybridized is surrounded by four oxygen atoms. The SiO4 tetrahedra can be linked together in several different ways. Depending on the number of corners of the SiO4 tetrahedra shared, various kinds of silicates are formed 16. 17. A fibrous mineral which can withstand red hot flames without any damage is 1) Talc 2) Glass wool 3) Soap stone 4) Asbestos Quartz watches contain 1) A crystal of quartz as an essential component 2) A coating of quartz on the outer body 3) Hands made of quartz 4) Silica coated on the number Which of the following is not a crystalline form of silica? 1) Quartz 2) Tridymite 3) Cristobalite 4) Kieselguhr

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Passage :

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Matching type questions : 19. Match the following Column I with Column II Column I D metal oxide + SO + O a) Metal sulphate 2 2 b) Metal cation + K2CrO4 yellow ppt. Column II p) Ba q) Sr r) Na s) Mg

(liquid ) blue solution c) Metal + NH3 d) MCl2 + conc. H2SO4 white ppt.

1. 2
11. 18. 4

2. 4

3. 4

4. 2 13. 1, 3, 4

5. 4

6. 2

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8. 15.

9. 16. 4

10. 17. 1

12. 1, 2, 4

14. 1, 2, 3, 4

19. a p, q, s; b p, q; c p, q, r, s; d p, q

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