Concentration methods

29. In which mode of expression the concentration of solution remains independent of

temperature
1) Molarity 2) Normality 3) Formality 4) Molality
32. A 500g tooth paste sample has 0.2g fluoride concentration. What is the concentration of
F in terms of ppm level?
1) 250 2) 200 3) 400 4) 1000
33. Increasing the temperature of an aqueous solution will cause
1) decrease in molality 2) decrease in molarity
3) decrease in mole fraction 4) decrease in % W/W
34. Which of the following solutions has the highest normality
1) 1.8g of KOH/1 lit. 2) N-Phosphoric acid 3) 6g of NaOH/100 ml4) 0.5m H
2
SO
4

35. Hydrochloric acid solutions A and B have concentrations of 0.5 N and 0.1 N respectively.
The volumes of solutions A and B required to make 2 litres of 0.2 NHCl are
1) 0.5lit of A+1.5lit of B 2) 1.5lit of A+0.5lit of B
3) 1.0lit of A+1.0lit of B 4) 0.75lit of A+1.25lit of B
36. The molarity of pure water is
1) 55.6 2) 50 3) 100 4) 18
37. The mole fraction of water in 20% aqueous solution of H
2
O
2
is
1) 77 68 2) 68 77 3) 20 80 4) 80 20
38. Volume of 0.1M K
2
Cr
2
O
7
required to oxidises 35ml of 0.5M FeSO
4
solution is
1) 29 ml 2) 87 ml 3) 175 ml 4) 145 ml
Vapour pressure
51. The vapour pressure of a liquid in a closed container depends upon
1) amount of liquid 2) surface area of the container
3) temperature 4) none of the above
52. The temperature at which the vapour pressure is equal to the external pressure is called
the
1) critical temperature 2) boiling point
3) normal point 4) saturation point

3.5 The incorrect statement is :
(A) Vapour pressure of a liquid always increases by increasing temperature.
(B) Vapour pressure only depends on temperature and not on the nature of substance.
(C) Vapour pressure does not depend on the quantity of the liquid taken and the surface area of
the liquid.
(D) Vapour pressure is not a colligative property & is independent of the concentration of the
liquid.

3.11 A sample of air is saturated with benzene (vapor pressure = 100 mm Hg at 298 K) at 298K,
750mm Hg pressure. If it is isothermally compressed to one third of its initial volume, the final
pressure of the system is
(A) 2250 torr (B) 2150 torr (C) 2050 torr (D) 1950 torr
Vapour pressure of non volatile solutes
8. The V.P. of a dilute solution of a non-volatile solute is P and the V.P. of pure solvent is
P
0
, the lowering of the V.P. is
1) + Ve 2) Ve 3)
0
P P 4)
0
P P
72. Relative lowering in vapour pressure of a solution containing one mol. K
2
SO
4
in 54gm
H
2
O is (K
2
SO
4
in 100% ionized)
1) 1 55 2) 3 58 3) 3 4 4) 1 2
81. If relative decrease in V.P is 0.4 for a solution containing 1 mol. NaCl in 3 mol. H
2
O,
NaCl is .. % ionised
1) 60% 2) 50% 3) 100% 4) 40%
82. Three soluti ons are prepared by adding ' w' gm of ' A' into 1kg of water, ' w' gm
of ' B' into another 1 kg of water and ' w' gm of ' C' in another 1 kg of water (A,
B, C are non electrol ytic). Dry air is passed from these solutions in sequence
(A B C). The loss in weight of solution A was found to be 2 gm whil e
solution B gained 0.5 gm and solution C lost 1 gm. Then the relati on
between molar masses of A, B and C is
(A) M
A
: M
B
: M
C
= 4 : 3 : 5 (B) M
A
: M
B
: M
C
=
1 1 1
: :
4 3 5

(C) M
C
> M
A
> M
B
(D) M
B
> M
A
> M
C


Vapour pressure of volatile solutes

79. An ideal binary liquid solution, the plot of P
total
versus X
A
(mole fraction of liquid A) is
linear with slope and intercept equal to
1)
0 0 0
A B A
P - P , P 2)
0 0 0
A B B
P - P , P 3)
0 0 0
B A A
P - P , P 4)
0 0 0
B A B
P - P , P
80. Mole fraction of A vapours above solution in mix of A and B
( )
A
X = 0.4 will be

0 0
A B
P 100mm, P 200mm ( = =


1) 0.4 2) 0.8 3) 0.25 4) none
12. When an ideal binary solution is in equilibrium with its vapour, molar ratio of the two
components in the solution and in the vapour phase is
1) same 2) different
3) may or may not be same depending upon volatile nature of the two components
77. Mixture of volatile component to A and B has total V.P, P = 254 119x
(x = mo. Fraction of B) Hence
0 0
A B
P and P are
1) 135, 254 2) 119, 254 3) 254, 135 4) 135, 119
68. If P
A
is the vapour pressure of a pure liquid A and the mole fraction of A in the mixture of
two liquids A and B is x the partical vapour pressure of A is
1) (1 x)P
A
2) x P
A
3)
A
x (1- x)P 4)
( )
A
1- x x P
26. For an ideal binary liquid solution with
0 0
A B
P > P , which of the following relations between
X
A
(mole fraction of A in liquid phase) and Y
A
(mole fraction A in vapour phase) is
correctly represented?
1) X
A
= Y
B
2) X
A
> Y
A
3) X
A
< Y
A

4) X
A
and Y
A
cannot be correlated with each other
24. Which of the following plots does not represent the behaviour of an ideal binary liquid
solution?
1) Plot of P
A
versus X
A
(mole fraction A in liquid phase) is linear
2) Plot of P
B
versus X
B
is linear
3) Plot of P
total
versus X
A
(or X
B
) is linear
4) Plot of P
total
versus X
A
is non linear
25. Which of the following plots correctly represents the behaviour of an ideal binary liquid
solution?
1) Plot of X
A
(mole fraction of A in liquid phase) versus Y
A
(mole fraction of A in vapour
phase) is linear
2) Plot of X
A
versus Y
B
is linear
3) Plot of
A
1 X versus
A
1 Y is linear
4) Plot of
A
1 X versus
B
1 Y is linear
70. The most likely of the following mixtures to be an ideal solution is
1) NaCl H
2
O 2) C
2
H
5
- OH C
6
H
6
3) C
7
H
16
(l) H
2
O 4) C
7
H
16
(l) C
8
H
18
(l)
27. A binary liquid solution of chloroform and acetone is prepared. Which of the following
statements correctly represents the behaviour of this liquid solution?
1) The solution formed is an ideal solution
2) The solution formed is non ideal solution with positive deviations from Raoults law
3) The solution formed is non ideal solution with negative deviations from Raoults law
4) Chloroform exhibits positive deviation whereas acetone exhibits negative
deviation from Raoults law
42. Which of the following pairs shows a positive deviation from Raoults law?
1) Water-hydrochloric acid 2) Water-nitric acid
3) Acetone-Chloroform 4) Benzene-methanol
1. An azeotropic mixture of two liquids boils at a lower temperature than either of them
when
1) it is saturated 2) it does not deviate from Raoults law
3) it shows negative deviation from Raoults law
4) it shows positive deviation from Raoults law
19. A maxima or minima obtained in the temperature composition curve of a mixture of two
liquids indicates?
1) An azeotropic mixture 2) a eutectic formation
3) that the liquids are immiscible with one another
4) that the liquids are partially miscible at the maximum or minimum
41. 100ml of a liquid A was mixed with 25ml of a liquid B to give a non-ideal solution of A-B
mixture. The volume of this mixture would be
1) 75 ml 2) 125 ml 3) just more than 125 ml
4) close to 125ml but not exceeding 125ml
82. 1 mol A+ 3 mol B (volatile liquids)
( )
0 0
A B
P = 300mm, P =100mm , mol fraction of B in
vapour state above solution is
1) 0.75 2) 0.25 3) 0.50 4) 0.66
83. Which is true about ideal solutions
1) the change in volume of mixing is zero 2) the change enthalpy of mixing is zero
3) both 1 and 2 4) none of these
84. Vapour pressure of A is 100mm and that of B is 200mm, mol. fraction of A in vapour
state in the mixture of 3 mol of A and 1 mol of B is
1) 0.4 2) 0.6 3) 1.0 4) 0.8
85. Vapour pressure of mixture of above question is
1) 125 mm 2) 50 mm 3) 200 mm 4) 300 mm

86. An ideal mixture of liquids A and B with 2 moles of A and 2 moles of B has a total vapour
pressure of 1 atm at a certain temperature. Another mixture with 1 mole of A and 3
moles of B has a vapour pressure greater than 1 atm. But if 4 moles of C are added to
the second mixture, the vapour pressure comes down to 1 atm. Vapour pressure of C,
P
c
0
= 0.8 atm. Calculate the vapour pressures of pure A and pure B.
(A) P
A
0
= 1.4 atm, P
B
0
= 0.7 atm (B) P
A
0
= 1.2 atm, P
B
0
= 0.6 atm
(C) P
A
0
= 1.4 atm, P
B
0
= 0.6 atm (D) P
A
0
= 0.6 atm, P
B
0
= 1.4 atm

88. Based on the given diagram, which of the following
statements regarding the solutions of two miscible volatile
liquids are correct?
(1) Plots AD and BC show that Raoults law is obeyed for the solution in which B is a
solvent and A is the solute and as well as for that in which A is solvent and B is
solute
(2) Plot CD shows that Daltons law of partial pressures is observed by the binary
solutions of components A and B
(3) EF+BG=GH, and AC and BD correspond to the vapour pressures of the pure
solvents A and B respectively. Select the correct answer using the codes given
below
1) 1 and 2 2) 2 and 3 3) 1 and 3 4) 1, 2 and 3
89. An ideal liquid solution, the plot of
A A
1 X versus 1 Y (where
A
X and
A
Y are the mole
fractions of A in liquid and vapour phase) is linear with slope and intercept equal to
1)
0 0 0
B A A
0 0
B B
P - P P
,
P P
2)
0 0 0
B A B
0 0
B A
P - P P
,
P P
3)
0 0 0
A B A
0 0
B B
P P - P
,
P P
4)
0 0 0
B B A
0 0
A B
P P - P
,
P P


Vant Hoff factor
58. Which of the following correctly expresses the Vant Hoff factor?
1) Calculated osmotic pressure / Observed osmotic pressure
2) Observed molecular weight / Calculated molecular weight
3) Calculated boiling point / Observed boiling point
4) Observed colligative property / Calculated colligative property
9. The Vant Hoff factor NaCl assuming 100% dissociation is
1) 1 2 2) 2 3) 1 4) 3
59. Vant Hoff factor for an electrolyte is
1) > 1 2) < 1 3) = 1 4) none of the above
60. Acetic acid dissolved in benzene shows a molecular mass of
1) 30 2) 60 3) 120 4) 180
61. The ratio of the value of any colligative property for KCL solution to that of sugar solution
is nearly
1) 1 2) 0.5 3) 2 4) 2.5
62. The Vant Hoff factor for 0.1M Ba(NO
3
)
2
solution is 2.74. The degree of dissociation is
1) 91.3% 2) 87% 3) 100% 4) 74%
63. The molecular weight of benzoic acid in benzene as determined by depression in
freezing point method corresponds to
1) Ionisation of benzoic acid 2) Dimerisation of benzoic acid
3) Trimerization of benzoic acid 4) Solvation of benzoic acid
64. Benzoic acid undergoes dimerisation in benzene solution, the Vant Hoff factor i is
related to the degree of association x of the acid is
1) i = (1- x) 2) i = (1+x) 3)
( ) i = 1 - x 2 4)
( ) i = 1 + x 2
73. Vant Hoffs factor for
| |
3 6
K Fe(CN) (ionization 50%) will be
1) 1 2) 5.5 3) 2.5 4) none
13. The lowering of vapour pressure of 0.1 M aqueous solution of NaCl, CuSO
4
and K
2
SO
4

are
1) all equal 2) in the ratio 1 : 1 : 1.5
3) in the ratio 3 : 2 : 1 4) in the ratio 1.5 : 1 : 2.5