CAU 1: Tron ba dd H2SO4 0,1M ; HNO3 0,2M ; HCl 0,3M vi the tch bang

nhau thu c ddA. Lay 300ml ddA cho tac dung vi ddB gom NaOH 0,2M
va KOH 0,29M. Tnh the tch ddB e dd thu c co pH = 12.
CAU 2: Mot dd cha 0,2 mol Fe3+ ; 0,1 mol Al3+ ; x mol SO42 ; y mol NO3 .
Co can dd thu c 61,3g muoi. Tnh x, y.
CAU 3: Hoa tan 26g CaCO3 bang dd HCl d. Cho kh sinh ra hap thu
vao 400ml dd NaOH a% (D = 1,18 g/ml) thu c ddX. Them lng d dd
BaCl2 vao dd X, sau phan ng thu c 18,715g ket tua. Tnh a.
CAU 4: a) Dung dch CH3COOH 0,1M co = 1%. Tnh pKa cua CH3COOH
va pH dung dch.
b) A la dd HCl 0,2M. B la dd H 2SO4 0,1M. Tron A va B theo the tch bang
nhau, tnh pH dung dch thu c.
CAU 5: Cho 1,92g ong vao 100ml dd ong thi cha KNO 3 0,16M va
H2SO4 0,4M thay sinh ra mot chat kh co t khoi hi so vi hidro la 15
va ddA. Tnh the tch kh ktc, the tch dd NaOH 1M toi thieu e ket
tua toan bo Cu2+ trong ddA.
CAU 6: a) Them t t 100g dd H2SO4 98% vao nc thu c 1 lit
ddA. Tnh pH ddA.
b) Them bao nhieu lit dd NaOH 1,8M vao 1 lit ddA e thu c
dd co pH 1 va pH 13.
CAU 7: Cho dd pH 4. Phai them mot the tch nc gap bao nhieu
lan the tch dd ban au e thu c dd pH 5.
CAU 8: Tron 1 lit dd H2SO4 0,005M vi 4 lit dd NaOH 0,005M. Tnh pH.
CAU 9: Cho phan ng :
A + B AB . Viet bieu thc tnh toc
o phan ng. Xac nh biet neu tang nong o A,B len hai lan
th toc o phan ng tang 16 lan.
CAU 10: Dung dch cha Cu2+, Na+, Cl-, SO42.Hoi dd nay c tao
thanh khi hoa tan muoi nao vao nc? Khi co can dung dch nay co
the thu c muoi nao?
CAU 11: Tnh the tch dd KOH 14% (D = 1,12g/ml) cha so mol OH bang so mol OH- co trong 200ml dd co pH = 12.
CAU 12: Hoa tan 12,5 g CuSO4.5H2O vao nc thu c 300ml dd. Tnh
the tch dd KOH 2M e ket tua het Cu2+ trong 100ml dd tren.
CAU 13: Tnh nong o mol/l cua dd HNO3 va dd KOH biet :20ml dd
HNO3 trung hoa het bi 60 ml dd KOH, 20ml dd HNO 3 sau khi tac dung
vi 2 g CuO th trung hoa het bi 10ml dd KOH.
CAU 14: Co bon dd NH3 , FeSO4 , BaCl2 , HNO3 . Viet cac phng trnh
phan ng (dang phan t va ion) xay ra khi tron Lan lt cac dd vi
nhau.
CAU 15: Co hai dd A , B. Moi dd cha hai loai cation va hai loai anion
NH
trong so cac ion sau : K + : 0,15
mol ; Mg2+ : 0,1mol ;
: 0,25 mol; H + : 0,2
mol
;
Cl:
0,1
mol;
2

2
SO4 : 0,075 mol ; NO3 : 0,25 mol ; CO3 : 0,15mol. Xac nh A,B.
CAU 16: Dung dch A cha NaHCO3 va Na2CO3. Trung hoa 300 ml dd A
can 100ml dd NaOH 1M thu c dd B. Cho dd CaCl 2 d vao ddB thu c
30g ket tua. Xac nh nong o mol/l cac chat trong ddA.
CAU 17: Co dd D cha Zn2+, Fe2+ va Cl-. Them t t dd NaOH 1,5M
vao 50ml ml dd D khi lng ket tua cc ai th thay ton 40ml. Mat
khac neu them dd KOH 2M vao 500ml dd D en khi lng ket tua
+
4

VC-11.1.2008

khong thay oi th can dung 500ml. Xac nh nong o mol/l cua moi
muoi trong ddD.
CAU 18: Viet phng trnh phan ng xay ra khi :
a) Cho NH3 d vao dd CuSO4 .
b) Tron dd FeCl 3 vi dd
Na2CO3.
c) Cho t t dd KOH vao dd AlCl3 .
d) Cho kh CO2 loi t t
qua dd Ba(OH)2.
CAU 19: Nhan biet cac lo mat nhan sau:
a) NaCl, KBr, Na2CO3, NH4Cl, H2SO4, HCl, Na3PO4.
b) CaCO3, BaCl2, Mg(OH)2, (NH4)2CO3, NH4NO3, Ba(NO3)2.
CAU 20: Cac chat va ion sau la axit, baz hay trung tnh : Na +, Zn(OH)2 ,
Cr(OH)3, Fe3+, CH3COO -, HS- , NH4+ , CO32, HPO42 .
CAU 21: Tnh [H+] cua dd H2SO4 80% (D = 1,4 g/ml). Tnh the tch dd KOH
co pH = 10 can dung e trung hoa 100 ml dd tren.
CAU 22: Dung dch A cha AlCl3. Tnh nong o mol/l cua muoi va ion
co trong dd A trong cac trng hp sau :
a) Cho sud vao 100ml dd A, lng ket tua cc ai thu c la 7,8g.
b) Cho dd KOH 2M vao 200 ml ddA en khi ket tua vua tan het th ton
400ml.
CAU 23: Hoa tan kem trong 240ml dd axit nitric va u thu c 2,24
lit kh hi nhe hn khong kh ktc.
a) Tnh khoi lng kem b hoa tan.
b) Them 500ml dd KOH a M vao dd thu c thay xuat hien 39,6g ket
tua. Tnh a.
CAU 24: Mot ddX cha : Ba2+ , Cl- , NH4+ , NO3 . Lay 100ml dd X tac
dung vi NaOH nong, d thu c 5600 cm 3 kh 00C, 760 mmHg. Neu
cho axit sunfuric d vao 400 ml ddX th thu c 93,2 g ket tua. Tnh nong
o mol/l cua cac ion trong dd biet t le mol gia Cl- va NO3
la 1:2.
CAU 25: Tron 2,24 lit nit va 78,4 lit hidro (ktc). un nong, phan ng
xay ra vi hieu suat la 25%. Dan hh san pham qua 5 lit nc. Tnh
the tch kh khong b hap thu. Tnh pH dd thu c biet o ien li cua
NH4OH la 20% va ch co 10% amoniac tan trong nc tac dung vi
nc.
CAU 26: Cap chat nao sau ay khong ton tai trong cung mot dung
dch, viet phng trnh dang phan t va ion rut gon : KNO 3 va BaCl2 ;
Fe(NO3)3 va NaOH ; (NH4)3PO4 va Ba(OH)2 ; FeCl2 va Na2CO3; AlCl3 va
ddNH3 ; ZnCl2 va Ba(OH)2.
CAU 27: Hoa tan 6,4g S trong 147g dd HNO 3 60% ( ac), nong. Pha
loang dd thu c bang nc en 600ml. Tnh pH. Tnh C% cua cac
chat trong dd trc khi pha loang.
CAU 28 : Can bang cac phan ng sau bang phng phap electron.
Viet di dang phan t va ion rut gon :
a) FeSO4 + H2SO4 + KMnO4 K2SO4 + MnSO4 + Fe2(SO4)3 + H2O.
b) FexOy + HNO3 Fe(NO3)3 + NO2 + H2O .
c) Na + H+ + NO3 Na+ + NH4+ + H2O.
d) Cu + H+ + SO42 Cu2+ + SO2 + H2O.
CAU 29 : Nguyen t cua nguyen to A co phan lp ngoai cung la
2p. So electron tren phan lp nay bang 0,75 lan tong so electron
con lai. T n chat A hay ieu che axit trong o A co so oxi hoa
cao nhat.
VC-11.2.2008

CAU 30 : Tnh nong o mol/l cua muoi va ion trong dd thu c khi :
a) Cho 3,36 lit NH3 (ktc) vao 100ml dd H2SO4 1M.
b) Cho 8,96 lit CO2 (ktc) vao 500ml dd NaOH 1M.
c) Cho 16,8 lit CO2 (ktc) vao 400ml dd Ba(OH)2 2M.
d) Tron 100ml dd NaOH 2M vi 400ml dd H3PO4 0,4M.
e) Cho V lit CO2 vao 200ml dd Ba(OH)2 a M thu c 29,55g ket tua, loc
bo ket tua, them 500ml KOH 3M vao phan nc loc lai thu c
9,85g ket tua na. Tnh V, a.
CAU 31: Dung dch A gom HCl 2M va H 2SO4 1M. Dung dch B gom NaOH
1M va Ba(OH)2 1,5M. tron A va B theo t le nao ve the tch e thu
c dung dch co pH la 0; 7; 14.
CAU 32: Cho 5g hon hp gom Zn va Al vao 220ml dung dch HNO 3.
Sau khi phan ng xong thay co 2,013g kim loai cha tan, thu c
0,896lit ( ktc ) hon hp NO va N 2O co t khoi so vi hidro la
16,75. Tnh khoi lng muoi va CM dung dch HNO3 ban au.
CAU 33: Tron NH3 vi Cl2, phan ng xay ra hoan toan, lam nguoi
hon hp san pham ch thu c 24,075g chat ran. Cung lay lng
NH3 nh tren ieu che HNO3 th thu c 65,625ml dung dch 40%
(D=1,2g/ml). Tnh hieu suat qua trnh ieu che axit nitric.
CAU 34:
a) Tnh lng quang pyrit 2% tap chat can dung e ieu che 800ml
dung dch H2SO4 co pH=2.
b) Tnh lng NH3 can thiet e ieu che 600ml dung dch HNO 3 co
pH=1.
c) Tron dung dch cau a vi dung dch cau b th thu c dung
dch co pH la bao nhieu?
CAU 35: Hoa tan 42,9g Na2CO3.10H2O vao nc thanh 700ml ddA .
a) Dung dch A co moi trng g? vit phng trnh phan ng xy ra khi
cho AlCl3 vao ddA.
b) Them 150ml dung dch MgCl2 1M vao ddA. Xac nh nong o ion
trong dung dch mi.
CAU 36:
a) Lay 400ml dung dch hon hp hai axit HCl va HBr hoa tan mot lng
quang dolomit thu c V lit kh ktc. Cho toan bo kh qua dung
dch Ca(OH)2 thu c 20g ket tua, loc bo ket tua, un soi dung
dch nc loc th thu c 10g ket tua na. Tnh pH dung dch axit
ban au va khoi lng dolomit 25% tap chat.
b) Cho V/2 lit kh tren vao 34,2g dung dch Ba(OH) 2 5%. Tnh C% dung
dch thu c.
CAU 37: Hoa tan Fe trong dung dch HNO 3 loang, lanh thu c dung
dch A va hon hp ang mol B gom hai kh, dB/hidro=11,5. Them NaOH
vao dung dch sau phan ng ch thu c mot ket tua trang anh
luc hoa nau o trong khong kh. Viet phng trnh phan ng di
dang phan t va ion rut gon.
CAU 38: T FeS2, Ca3(PO4)2, K2CO3, khong kh, than , xuc tac va ieu
kien co u, ieu che: supephotphat n, supephotphat kep, ure, kali
nitrat, amophot, sat.
CAU 39: Mo ta va giai thch hien tng xay ra khi:
a) Cho Fe d vao dung dch HNO3 ac.
b) Cho Cu vao dung dch HNO3 thu c dung dch B.
VC-11.3.2008

c) Cho Fe vao dung dch B ch thu c dung dch C. Cho ddKOH t t

vao dung dch C.
CAU 40: Hay chon bon dung dch moi dung dch cha hai ion trong
so cac ion sau (khong trung lap): SO 42 , NO3 , CO32 , Cl-, K+, Ba2+, Mg2+,
Pb2+.
CAU 41: Nhan biet cac lo mat nhan sau:
a) Ch dung mot thuoc th : (NH4)2SO4, K2SO4, NaCl, NH4Cl.
b) Ch dung qu tm : NaOH, H2SO4, Na2SO4, Ba(OH)2, NaCl.
c) CO2, SO2, SO3, N2, CO.
CAU 42: Tron dung dch co pH=5 vi dung dch co pH=8 theo t le
nao th thu c dung dch co pH=6.
CAU 43: Viet phng trnh phan ng nhiet phan: CaCO 3, NH4Cl,
Na2SO4, KCl, NaHCO3, Ca(NO3)2, Hg(NO3)2.
CAU 44: Hoan thanh s o phan ng sau :
t0

+HCl

Na2CO3 CO2 CO Fe Fe(NO3)3 A B PbCl2

+HCl
? Fe3O4 Fe2O3 D Fe(OH)2 Fe(NO3)2 HNO3 N2 NO NO2
N2O4.
CAU 45: e trung hoa 100ml dung dch (HNO 3 + H2SO4) can 40ml dung
dch KOH 0,5M. Neu lay mot lit dung dch axit tren em trung hoa
bang NaOH roi co can dung dch sau phan ng th thu c 15,32g
muoi khan.
a) Tnh pH dung dch axit va nong o moi axit trong dung dch.
b) e trung hoa 50ml dung dch axit can bao nhieu ml dung dch gom
NaOH 1M va Ba(OH)2 2M ?
CAU 46: Dan 600g hon hp N2 va H2 co t le 1:1 ve the tch qua
bot Pt nung nong, co 30% hidro b phan ng.
a) Xac nh phan tram hon hp kh sau phan ng.
b) Lay toan bo lng NH3 thu c i ieu che HNO 3, tnh the tch
dung dch HNO3 50% (D=1,42g/ml) thu c. Biet hieu suat qua trnh
la 80%.
CAU 47: Hoa tan het muoi sunfit cua kim loai hoa tr II bang dung
dch HCl va u thu c dung dch A. Them Na 2CO3.10H2O cho en
khi thu c ket tua cc ai, nung ket tua en khoi lng khong
oi thu c 30,6g chat ran va 4,48 lit CO2 ktc.
a) Xac nh kim loai.
b) Tnh the tch dung dch HCl 20% (D=1,2g/ml) va lng Na 2CO3.10H2O
a dung.
CAU 48: Them dung dch HCl 0,5M vao 100ml dung dch hai muoi
Na2CO3 , NaHCO3 en khi het sui bot kh thu c 3,36 lit kh ktc. Co
can 50ml dung dch hai muoi tren thu c 14,4g Na 2CO3.10H2O.
a) Tnh nong o mol moi muoi trong dung dch.
b) Tnh the tch dung dch HCl biet a dung d 10%.
c) Them phenolphtalein vao dung dch muoi th co hien tng g?
CAU 49: Hoa tan 40,25g ZnSO4 vao nc thu c 400ml dung dch A.
Tnh the tch dung dch NaOH 5M toi thieu can cho vao 200ml dung
dch A e thu c ket tua ln nhat, nho nhat.

VC-11.4.2008

CAU 50: Cho 2,24 lit NH3 ktc qua 16g CuO un nong thu c chat
ran X. Hoa tan het X trong dung dch HNO 3 ac. Cac phan ng xay
ra hoan toan. Tnh so mol san pham thu c?
CAU 51: Nung 24,2g muoi nitrat en khoi lng khong oi thu c
8g oxit kim loai. Xac nh cong thc muoi.
CAU 52: Ch dung them mot hoa chat nhan biet cac chat mat
nhan sau:
Na2SO4, CaCO3, FeS, BaSO4, ZnS, HgI2, PbI2, CuSO4,Fe(OH)3.
CAU 53:
a) Ch dung mot hoa chat hay phan biet Fe2O3, Fe3O4.
b) So sanh pH cua cac dung dch co cung nong o : NH 3, NaOH,
Ba(OH)2. Giai thch.
c) Cho hai dung dch H2SO4 co pH=2 va pH=1. Them 100ml dung dch
KOH 0,1M vao 100ml moi dung dch tren. Tnh nong o mol/lit moi
dung dch thu c.
CAU 54: Cho 18,5g hon hp Z gom Fe, Fe3O4 tac dung vi 200ml dung
dch HNO3 loang nong. Sau khi phan ng xay ra hoan toan thu c
2,24 lit NO duy nhat ktc, dung dch Z1 va con lai 1,46g kim loai.
a) Tnh nong o mol/lit cua dung dch HNO3.
b) Tnh khoi lng muoi trong dung dch Z1.
CAU 55: Cho phng trnh:
M2Ox + HNO3 M(NO3)3 + NO + H2O
a) Hay can bang phng trnh theo phng phap thang bang e.
b) Vi gia tr nao cua x phan ng tren la phan ng oxi hoa kh.
CAU 56: Tnh pH cua dung dch axit yeu HX 0,01M co pKa = 6.
CAU 57: Cho 13,5 g bot nhom phan ng het vi 300 ml dung dch
HNO3 8M thu c dung dch X va kh NO. Them 200ml dung dch KOH
22,4% (D = 1.2 g/ml) vao dung dch X th thu c bao nhieu gam ket
tua.
CAU 58:a) Viet cong thc cau tao cua H 3PO4 va H3PO3va phng
trnh ien li cua hai axit nay.
b) Tron hai axit tren theo t le 1:1 ve khoi lng thu c 18 g hon
hp. Tnh khoi lng dung dch NaOH 20% can trung hoa hon hp
tren.
CAU 59:Kh m g quang photphorit 96% tinh chat bang C nhiet o
cao vi hieu suat 80%. Lng photpho thu c ieu che c 1kg
dung dch H3PO4 19,6%. Tnh m.
CAU 60: T quang apatit hay viet cac phng trnh ieu che P; PH 3;
Zn3P2; P2O5.
CAU 61: Neu cac qui luat bien thien tnh chat cua cac n chat
cung nh hp chat trong phan nhom chnh. Minh hoa bang cac
nhom IVA; VA.
CAU 62: So sanh kim cng va than ch.
CAU 63: Neu thanh phan va phan ng cua thuoc no en, thuoc
au que diem.
CAU 64:Them t t dung dch HCl 1M vao 500 ml dung dch cha
ong thi Na2CO3 va KHCO3 khi co kh bat au thoat ra th dung het
0,5 lit; khi va het bot kh th dung het 1,2 lit. Tnh C M cua moi muoi
trong dung dch ban au.

VC-11.5.2008

CAU 65: Tai sao SiH4 kem ben hn CH4? Neu ng dung cua cac
muoi silicat.
CAU 66: Cho 100ml dung dch A cha Na 2CO3 1M va K2CO3 1,5M phan
ng va u vi 200 ml dung dch B cha MCl 2 va NCl2 thu c 23,4 g
ket tua. Xac nh M, N biet chung la kim loai IIA thuoc 2 chu k ke
tiep.
CAU 67: e 10,08 g Fe ngoai khong kh sau mot thi gian thu c m
gam 4 chat ran, hoa tan het lng chat ran nay trong dung dch
HNO3 thu c 2,24 lit NO ktc. Tnh m.
CAU 68: Cho 5,5 g hon hp MgO va Al 2O3 tac dung vi dung dch
NaOH d thu c chat ran B, hoa tan B trong HCl d thu c dung dch
C, them KOH d vao dung dch C thu c ket tua D, nung D en khoi
lng khong oi th thay khoi lng chat nay giam 0,18 g. Tnh %
khoi lng moi chat trong hon hp ban au.
CAU 69: Viet phng trnh oxi hoa FeSO4 bang KMnO4; K2Cr2O7 trong
moi trng H2SO4. (Di dang phan t va ion rut gon.)
CAU 70: Lap cong thc tnh o ien li, nong o H +, pH cua dung
dch axit yeu HA co nong o C mol/lit va hang so can bang phan li
la Ka.
CAU 71: Hoa tan hon hp 3 kim loai kiem trong nc thu c 500 ml
dung dch A va 17,92 lit kh 273oC; 2at. Tnh pH dung dch thu c.
CAU 72: Cho m g Na vao 200 ml dung dch HCl 1M thu c dung dch A.
Cho t t Fe2(SO4)3 vao dung dch A thu c ket tua B, nung B trong
khong kh en khoi lng khong oi thu c 3,2 g chat ran. Tnh m.
CAU 73: Lay 10 ml dung dch NH 4Cl 0,1M roi them vai giot
phenolphtalein, them tiep 10ml dung dch NaOH 0,1M vao, khuay eu,
un soi. Mo ta va giai thch hien tng.
CAU 74: Viet cac phng trnh phan ng xay ra khi:
a) Them t t ddCa(OH)2 vao ddH3PO4 sau o lai them t t dung
dch HCl vao.
b) Cho HCl vao ddNa2SiO3, loc ket tua va nung, ngam chat ran thu
c trong ddHF.
CAU 75:
a) Tron 10 lit NO vi 50 lit khong kh (20% O 2). Tnh the tch kh thu c
sau khi phan ng xay ra hoan toan.
b) un 150 lit hon hp H2 va N2 (t le 3:1 ve the tch) thu c 140 lit
hon hp. Tnh hieu suat.

VC-11.6.2008