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Phng php 8000, COD dng cho my DR890, dch bi Hach Vit Nam

Nhu cu oxy ha hc, COD


Phng php 80001 Phm vi ng dng: nc, nc thi v nc bin Phng php ph mu c USEPA chp nhn trong phn tch nc thi2
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1 Jirka, A.M.; Carter, M.J., Analytical Chemistry, 1975, 47(8), 1397 2 Federal Register, April 21, 1980, 45(78), 26811-26812. Thang o 0-15000mg/L

khng c chng nhn bi USEPA.

Tin trnh ph mu

1. ng nht 500mL 2. Bt thit b nung mu trong 2 pht DRB200. Cho gia trong my xay. nhit n 1500C.
Ch : i vi thang o 0-15000 mg/L, ng nht 100mL. mu xay ra cc 250mL. mu khuy t trong khi ht mu. iu ny gip tng chun xc v lp li. Ch : Xem hng dn s dng DRB200 chn chng trnh ci t sn theo nhit ph hp.

3. M np y ng thuc th COD theo thang o thch hp. Nng mu (mg/L) 0 n 150 0 n 1500 0 n 15000 Loi ng thuc th COD Thang thp Thang cao Thang cc cao

4. Gi ng nghing 45 . Dng pipet nh mc cho vo 2mL mu (hoc 0.2 mL i vi thang o 0 n 15000 mg/L)
Ch : i vi thang o t 0 n 15000 mg/L, s dng TenSette pipet ly 0.2 mL thay v 2 mL. c kt qu phn tch chun xc hn th phn tch ba mu c gi tr trung bnh. Ch : Thuc th b trn s nh hng n chun xc v gy hi n da hoc ph hy vt liu nu tip xc. Khng tip tc thc hin test vi ng b thuc th. Nu b trn, lp tc ra sch vi nc.

Ch : Thuc th nhy vi nh sng. Gi cc ng COD cha s dng trong hp cha hoc trong t lnh nu c. nh sng chiu ti ng trong qu trnh phn tch th s khng nh hng n kt qu.

Phng php 8000, COD dng cho my DR890, dch bi Hach Vit Nam

Ch : Mt s ha cht v dng c s dng trong quy trnh ny c th c hi cho sc khe v s an ton ca ngi s dng nu khng c s dng ng cch v c tai nn khng mong mun xy ra. Hy c ton b cc phn v bo m an ton v cnh bo ca ti liu ny. eo knh bo v v bo h. Nu c tip xc ha cht, ra sch khu vc b nh hng. Tun th theo cc hng dn mt cch cn thn.

5. Vn cht li np. Ra nc kh ion qua bn ngoi ng v lau kh bng giy sch.

6. Gi ng pha trn np v o ng ngc ln xung nhiu ln xo trn. t ng vo bp DRB200 nng. y np bo v li.


Ch : Mu bn trong s rt nng trong khi lc.

7. Chun b mu trng bng cch lp li cc bc 3 n 6 thay mu bng pipet 2mL nc kh ion (0.2 mL i vi thang o 0-15000 mg/L)
Ch : m bo pipet sch Ch : Mt mu trng cn cho mt lt test cc mu. Thc hin mu v mu trng cho cng mt l thuc th ging nhau (Lot# c ghi trn nhn hp cha)

8. Nung cc trong 2 gi.

ng

Ch : Nhiu mu c th phn hy nhanh hn. Nu cn nh gi, c th ly mu c (trong khi ng cn nng) sau mi 15 pht cho n khi thy gi tr c khng i. Lm ngui mu n nhit phng c kt qu cui cng.

Phng php 8000, COD dng cho my DR890, dch bi Hach Vit Nam

9. Tt bp nung. Ch 20 pht ngui bt xung 120oC hoc thp hn.

10. Lc ngc ng vi ln trong khi ch ngui. Cho ng vo gi lm mt n nhit phng.


Ch : Nu mu xanh trong xut hin trong mu phn ng, th o COD v nu cn thit th thc hin li vi mu pha long.

11. S dng mt trong cc phng php phn tch sau xc nh COD: Phng php so mu 0-150 mg/L Phng php so mu 0-1500 mg/L Phng php so mu 0-15000 mg/L

Phng php so mu 0-150mg/L

1. Chn chng trnh phn tch COD ci t sn trong my, thang o thp. Nhn phm: PRGM Mn hnh s hin: PRGM ?

2. Nhn: 16 ENTER. Mn hnh s hin th mg/L COD v biu tng ZERO


Ch : thay i cng thc ha hc (O2), nhn chn phm CONC.

3. t adapter COD/TNT vo trong bung cha cell bng cch xoay adapter n khi khp v tr. Sau y n xung.
Ch : tng hiu qu phn tch, mt di bng khuch tn bao quanh ly cc l truyn nh sng trn adapter. Khng tho di bang ny ra.

4. Lau sch bn ngoi ng.


Ch : Lau bng ming vi m sau lau li bng ming vi kh loi b cc du tay hay cc du khc.

Phng php 8000, COD dng cho my DR890, dch bi Hach Vit Nam

5. t ng cha mu trng vo adapter. n u ng thng xung n khi nm khp bn trong adapter.


Ch : Khng di chuyn ng bng cch tip xc hai bn thnh ng v c th gy sai s.

6. y cht np my che ng.


Ch : Mu trng n nh nu bo qun trong ti. Xem quy trnh thc hin i vi mu trng trong phng php so mu.

7. Nhn: ZERO Con tr s di chuyn bn tri sau mn hnh hin th: 0 mg/L COD

8. Lau sch bn ngoi ng mu bng khn mm.

9. t ng cha mu trng vo adapter. n u ng thng xung n khi nm khp bn trong adapter.


Ch : Khng di chuyn ng bng cch tip xc hai bn thnh ng v c th gy sai s.

10. y cht np my che ng.

11. Nhn: READ Con tr s di chuyn bn tri sau mn hnh hin th kt qu: mg/L COD

Phng php so mu 0-1500mg/L v 0-15000 mg/L COD


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Phng php 8000, COD dng cho my DR890, dch bi Hach Vit Nam

1. Chn chng trnh phn tch COD ci t sn trong my, thang o cao. Nhn phm: PRGM Mn hnh s hin: PRGM ?

2. Nhn: 17 ENTER. Mn hnh s hin th mg/L COD v biu tng ZERO


Ch : thay i cng thc ha hc (O2), nhn chn phm CONC.

3. t adapter COD/TNT vo trong bung cha cell bng cch xoay adapter n khi khp v tr. Sau y n xung.

4. Lau sch bn ngoi ng.


Ch : Lau bng ming vi m sau lau li bng ming vi kh loi b cc du tay hay cc du khc.

5. t ng cha mu trng vo adapter. n u ng thng xung n khi nm khp bn trong adapter.


Ch : Khng di chuyn ng bng cch tip xc hai bn thnh ng v c th gy sai s.

6. y cht np my che ng.


Ch : Mu trng n nh nu bo qun trong ti. Xem quy trnh thc hin i vi mu trng trong phng php so mu.

7. Nhn: ZERO Con tr s di chuyn bn tri sau mn hnh hin th: 0 mg/L COD

8. Lau sch bn ngoi ng mu bng khn mm.

Phng php 8000, COD dng cho my DR890, dch bi Hach Vit Nam

9. t ng cha mu trng vo adapter. n u ng thng xung n khi nm khp bn trong adapter.


Ch : Khng di chuyn ng bng cch tip xc hai bn thnh ng v c th gy sai s.

10. y cht np my che ng.

11. Nhn: READ Con tr s di chuyn bn tri sau mn hnh hin th kt qu: mg/L COD
Ch : Khi dng ng thuc th TNT thang o cc cao th nhn kt qu vi 10 Ch : c kt qu chun xc vi mu gn 1500 hay 15000 mg/L, lp li phn tch vi mu pha long.

Thu thp mu v bo qun


Thu mu bng chai thy tinh. Ch dng chai nha khi bit chng hon ton khng c cht nhim hu c. Thc hin th nghim i vi mu c hot ng sinh hc cng sm cng tt. Thc hin ng nht mu c cha cht rn m bo ly c mu i din. Mu c x l vi axit sulfuric pH thp hn 2 (t l 2mL cho 1 lt) v c th trong t ng 4oC trong vng 28 ngy. iu chnh kt qu vi lng th tch thm vo.

Kim tra chun xc


Phng php s dng dung dch chun Kim tra s chnh xc trong dy o 0 n 150 mg/L vi dung dch chun 100 mg/L. Dng dng c loi A, chun b bng cch cho 85 mg (120 C, kh qua m) potassium acid phthalate (KHP) vo 1 lt nc kh ion. Ly 2.0mL lm mu. Kt qu d kin thu c l 100-mg/L COD. Hoc c th pha long bng cch ly 10mL dung dch chun COD c nng 1000mg/L vo bnh nh mc 100.0 mL c dung dch chun 100-mg/L. Kim tra s chnh xc trong dy o 0 n 1500 mg/L vi dung dch chun 300mg/L hoc 1000 mg/L COD. Hoc chun b dung dch chun 500mg/L bng cch ha tan 425 mg (120 C, kh qua m) potassium acid phthalate (KHP) vo 1 lt nc kh ion. Ly 2.0mL ca mt trong cc dung dch ny lm mu. 6

Phng php 8000, COD dng cho my DR890, dch bi Hach Vit Nam Kim tra s chnh xc trong dy o 0 n 15000 mg/L vi dung dch chun 10000 mg/L COD. Chun b dung dch chun 10000mg/L bng cch ha tan 8500 mg (120 C, kh qua m) potassium acid phthalate (KHP) vo 1 lt nc kh ion. Ly 2.0mL ca dung dch ny lm mu, kt qu d kin thu c phi l 10000 mg/L COD.

Hiu qu phng php


chnh xc Chng trnh # 16: trong mt phng th nghim c lp, s dng dung dch chun 100 mg/L COD v ly i din t hai l thuc th phn tch, ngi thc hin c lp thu c lch chun l 2 mg/L COD. Chng trnh # 17: trong mt phng th nghim c lp, s dng dung dch chun 1000 mg/L COD v ly i din t hai l thuc th phn tch, ngi thc hin c lp thu c lch chun l 16 mg/L COD.

Gii hn pht hin (EDL)


EDL i vi chng trnh 16 l 4mg/L COD. EDL cho chng trnh 17 l 30 mg/L COD.

Thuc th thay th
Mercury-free COD2 Reagents khng c cha thnh phn c hi c th s dng trong th nghim khng cn bo co. i vi ng dng trong kim sot quy trnh, thuc th COD2 s loi tr vic thi b thy ngn v tit kim chi ph x l cht thi nguy hi. Nhng thuc th ny hon ton thch ng vi cc quy trnh th nghim v cc ng cong chun c ci t sn trong my quang ph. Cn xc nh thnh phn chloride v ammonia cho kt qu chnh xc cao. Ghi ch: Nhng thuc th ny khng c USEPA chng nhn dng cho mc ch bo co. bit thm thng tin chi tit, xem COD Reagent Vial Information Brochure, Lit. No. 1356.

Cc cht cn tr
Chloride l cht cn tr u tin khi xc nh nng COD. Mi ng COD cha mercuric sulfate loi b cn tr do chloride theo mc trong bng 1 bn di. Mu c chloride cao phi c pha long gim nng chloride theo nh ct 2 trong bng. Nu pha long mu lm nng COD thp qu, kh o chnh xc th cho 0.5g mercuric sulfate (HgSO4) (Cat. No. 1915-20) vo mi ng COD trc khi cho mu vo. Phn b sung ny s lm tng nng chloride ti a cho php c nu trong ct 3.

Phng php 8000, COD dng cho my DR890, dch bi Hach Vit Nam Bng 1

Ct 1 Nng Cl ti a trong mu (mg/L) 2000 2000 20,000

Ct 2 Nng Cl ngh pha long (mg/L) 1000 1000 10,000

Ct 3 Nng Cl ti a trong mu khi cho thm 0.50 HgSO4 (mg/L) 8000 4000 40,000

ng nghim s dng Thang thp Thang cao Thang cc cao

Xc nh mu trng theo phng php so mu


Mu trng thuc th c o v tr vo kt qu ca mu mi khi s dng lot thuc th mi. Mu trng c th c s dng lp li i vi cc ng o c cng l hng. Bo qun trong bng ti v theo di phn phn hy bng cch o kim tra hp th ti cc bc sng tng ng (420 hay 620nm). Zero my ch o hp th sng, dng ng cha 5mL nc kh ion v o hp th ca mu trng. Ghi li gi tr. Chun b mu trng mi khi hp th thay i 0.01 n v.

Tm tt phng php
Kt qu o mg/L COD c nh ngha l mg oxy c tiu th trn 1 lt mu di iu kin th nghim. Trong th nghim ny, mu c un trong 2 gi vi tc nhn oxy ha mnh l K 2 Cr2O7 . Cc cht hu c c th oxy ha c phn ng, kh ion dichromate ( Cr2O72) thnh ion chromic xanh (Cr3+). Khi s dng phng php so mu trong dy 0 n 150mg/L, tng lng Cr6+ cn li c xc nh. Khi s dng phng php so mu 0-1500 hay 0 n 15000 mg/L, tng lng Cr3+ sinh ra c xc nh. Thuc th COD c cha bc v ion thy ngn. Bc l cht xc tc v thy ngn c dng hn ch cht cn tr clorua.

Ngn nga nhim v qun l cht thi


Mu sau cng c cha thy ngn (D009), bc (D011) v Crom (D007) mc nng b kim sot bi Federal RCRA. Vui lng xem hng dn vic thi b ng cch Phn 3 ca ti liu Cc quy trnh phn tch ca my DR890.

Danh mc thay th v tiu th


Thuc th cn thit

Phng php 8000, COD dng cho my DR890, dch bi Hach Vit Nam

Dng c cn thit

Cc thuc th thay th

Cc thuc th ty chn

Phng php 8000, COD dng cho my DR890, dch bi Hach Vit Nam

Dng c ty chn

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