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INTORMATION FOR CANDIDTTES

l. This question paper consists of three questions. Answer all questions.


2. Write your answers for Question I and Question
question paper.
2 in the spaces provided in the

3. Write your answers fot Question 3 on the "helaian tambahan". You may use

equation, diagralns, tables, gfaphs and other suitable methods to explain your answer.

4. Show your working" it may help you to gt marks5. lf you wjsh to change your answef, neatly
Therr write down the new answer. cross out &e answer that you have done.

6. The diagrams in the q*estions are not drawn to scale 'tnless stated.
7. Mark allocated for each question orpart question are shown in brackets.
B. The time suggested to srxwers Que$tion

nnd Qucstion 2 is 45 minutes and

Question3h45minutes. 9. You may


use enon-programrnable scientific calculator'

10. Hand your atlswer sheets at the end of the examination.

Marks awarded:

Mark
3

Descrintion

t
0

Excellent Satisfactory Weak

: The best resPonse : An average response : An inaccrnate response

No response or wrong rsponse

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1 Diagram
fujah

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l.l

1.1 shows two experiments to deterrnine the heat of nzutnalization.


menunjukkan dua eksperimen tmtuft menentukan haba peneunalan

Experimerit

I
of

Reaction between 25 cm3 of sodium hydroxide solution , NaOH 1.0 mol dm-3 and 25 cm3 hydrochloric acid, HCI 1.0 mol dm-' Tinrlak bulus anturuZ5om3 letrutan fiatrium hi<Irol*idu, NaOH l-0 mol dm'3 elengtn 25cmi ucid hklxtWorik HCt 1.0 mol dm'3

Stirred ___--____4 dikacau


Polystyrene cups Cw'ot polistirena

hitial temperature of the mixture


Suhu awal campuran

OC

Higbest temperature ofthe mixtue:


Sahu

OC

tertingf cdrnpaftrn
OC

Change in temperanrre
Perubo.hnt suhu

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sul,rT
Experiment

4
II

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Reaction between 25 cm3 of sod.ium hydroxide solution , NaOH 2.0 mol dm-3 and 25 cm3 of ethanoic acid, CH3 COOH 2.0 mol dm-i l Tirutak balas antara 25 cml larutan natrium hidroksida, NaOH 2.0 mol dm'3 deng*t 25 cm asid et6noik2.0 mol dm-3

W#f, W
\
Polystyrene cups Cawan polistirena

il|fl

f}Il ilil

Inifial temperature of the rnixture


Suhu cwal campuran

: Tr oC
Tz
uC

Highest temperature of the Subu te r t inggi c amFar sn


Change in Perubahsn sulnt

mixture:

temperature

T3 "C

(a)

Wdte the initial and the highest temperature of the mixhne and change in tem.perafure for Experimeni I in Diagram 1.1 Tulis suhu crwal dan suhu tertinggi campuran serta perubahan suhu untuk Elxperitnenldalam Rajah l.l
13 marks)

(b)

Construct a table that can be used to record the data from both experiments. Bina satuja&nl ymg boleh dignakn wrtuk merekod data bagi kedua-daa eksperimen

13 marrs'l

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sultT
(c)

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State one hypothesis for both experiments. Nyalakm satu hipotesis bagi kedaa-dua eh,sperimen

13

marbl

(d) .

Based on the temperatures in Experiment I, predict the change in temperature in

Experiment II Eerdasskot suhu dalsm Ehrperimenl, ramslkwt peruhahan

suhu bagi Eksperimen

Il

[3

marks]
these

{e}

Why must the initial temperature and the higlrest temperature be rscorded in
experiments?
Mengapakah suhu swal dwr suha tertinggi perlu direkodkan dalam ekrperimen ini?

[3

narfu]

(0

How can the value of the change of lenrperature be obtained? Bagaimwtakah nilai perubahan suhu diperoleh?

[3 wr.lesl

(g)

For this experimentstate


Bagi eksperimen ini , nyatakan

ti)

Manipulated Variable
P embol e hubah dimantpulas

(it
(iii)

RcspondingVariable
P em b a I e lubuh

beryerakbalus

ConstantVariable P e mbo I e la$ ah d i tzna,la r km

[ 3 marks]

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SULIT fri)

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for the Diagram 1.2 shows the calculation to determinc tlre heat of neutralisation reactions in Experiments I and II n";"n 1.2 menmju*kan perhitungan untah menentukm haba peneatralan bogi tiwlak balos daiam Ekperimenl dan Eksperimenll

Experiment

Experiment

II

Heat released I{aba yang dihebaskan

Heat released
Haba yang dibebaskan

: mcO
*xJ

=50Bx4.2Jgr x
Heat $f neutralisation

oc

: mc0
=yJ

= 50 8 x4.21

XT3oC

Heat of neutralisation
tr{aba peneutra}rm

Haba penedralan

xkJ

y-ki

number ol'mole of water Produced bilangan mol air.vang dihs$ilksn

numtrer of mole of water Produced bilangon mol air Yang dihusilkan

It *'as found that the value of x is greater than value of y' Explain why. Didapa{i nilai x lebih hesat dtnipada nilai y'
Teranglam mengsps.

t3

morksJ

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sulrT
2 Table
1 shows

'7

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Experiment I, Experiment II and Experiment III which arc conducted to study the solubility of salts in water. Jadaal 1 menunjukkon Ekperimen [" Eksperimen {( don Eksperimen lll vang diljalankm untak
nengkqji keterlarulan gararn dalam air.

Experiment

Reaction
TindaL balas

Observations Penerhstian

Add water
Tambah

sir

Calcium
Kqlsium

nitrate nitrat

Colourless solution Larwan tak berwama

II
Add water Tsmbahair

-|} Copper(Il) sulphate


Kr,prrndll)

sulfat

Blue solufion Larutat biru

NI

Calcium carbonate Kalsium ka*anat Table I 454U3

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SULIT I (a) V/rite the observation for Experiment I. II and III in Table L
Tul is pemerlnt ian bagi Eksperimen

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l, ll don lll dalaw Jadaal

I. 13

marksl

(b)

Based on Experiment I and II, state the operational definition of soluble salt. Berdasskan Eksperimen I dmt fI" nyatakm definisi secaro operasi bagi garam terlarut.

f3 marks]

(c)

Classif the following

Kelaskon gsram-gmrofi, di bowuh

salts into solubl salts and insoluble salts. ke@a garom terlarw de, garam tak terlsrut.

$odium sulphate, Lead(II) sulphate, Barium sulphate, Magnesium sulphate


Natriam sulfat, Plumbum$l) sulfat, Borium sulfal, Magtesium sulfut

l3 marksl

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3

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The distance between pnirs of different metals in the electrochemical serisr aflect the.voltnge produced. Jarak di antara pasangan logamyntg berlainon di dolam shi elehtto*imia mcnpengarahi voltan yrng lerhssil

Diagram 3 shows a voltaic cell which consist of two different metals dipped in an electrolyte. Rajah 3 newnjul*an salu sel voltan yang terdiri daripada dua logam yang berlainan di celup dalan satu elektolit.

Copper{Il) sulphate solution


Lar u t an kup r wn(ll)s u Ifu t

Diagranr 3
Based on Diagram 3, plan one laboratory experiment to investigate the efTect of the distance betwon two metals in the electrochemical series on the voltage produced. Berdacwksn Rcjah3, rancang sata ekryrimen mobtwl wtak mengkaji kescn jwuk di sntara dua logam dalam siri elektrokimis kE atas voltan yang terhasil.

Your planning should include the follorrying aspects:


Perancangan anda lendailah tnengqftdungi aspek-aspe k ber ikut:

Problem statement
Pernyataan masalah

AII the variables


Semua pemboleh ubah

Hypothesis
Hipotesis

List of materials and apparatus Senaai balmn danradas


Procedtrre
Prosedur

Tabulation of data Peqiadualan data


END OF QUESTION PAPER 4541/3

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PAPER 3: CHEMISTRY

Question 1(a)

Mark Scheme Able to record all the temperature accurately Answer Initial temperature Highest temperature = 29.0 = 41.0

Marks 3

Change of temperature = 12.0 2 Able to record all the temperature correctly Sample answers Initial temperature Highest temperature = 29 = 41

Change of temperature = 12 Able to record one temperature correctly No response or wrong response 1(b) Able to construct table accurately with correct title and unit Sample answer TemperatureC I Initial temperature of mixture Highest temperature of mixture 29.0 41.0 T1 T2 Experiment II 1 0 3

Able to construct table correctly without unit

Able to construct table less accurate with at least one experiment No response or wrong response 1(c ) Able to state the hypothesis accurately Sample answer The heat of neutralization of a weak acid and strong alkali is smaller than the heat of neutralization of strong acid by a strong alkali Able to state the hypothesis correctly Sample answer The heat of neutralization changes when different acids react with strong alkali Able to state the idea of hypothesis Sample answer The heat of neutralization changes No response or wrong response 1(d) Able to predict the change of temperature accurately 11C Able to predict the change of temperature correctly 9-10C Able to predict less correctly 7-8C No response or wrong answer 1(e) Able to explain with two correct reasons Sample answer *This is to enable the change in temperature to be measured. *The change of temperature is needed to calculate the heat of neutralization

1 0 3

0 3

0 3

Able to explain at least one reason from the above Able to give an idea of explaining No response or wrong response 1(f) Able to state the formula accurately Sample answer Change in temperature= Highest temperature of mixture- initial temperature of mixture Able to state the formula correctly Sample answer Difference of temperature between highest and lowest Able to give an idea of calculating No response or wrong response 1(g) Able to state all the variables correctly Answer Manipulated Variable: The type of acid used // ethanoic acid, hydrochloric acid Responding Variable : The heat of neutralisation

2 1 0 3

1 0 3

Constant Variable : The concentration and the volume of acid and alkali // the type of container that is used to hold the mixture Able to state two variables correctly Able to state one variable correctly No response or wrong response 2 1 0

1(h)

Able to explain with two reasons correctly Sample answer 1.Experiment I uses a strong acid whereas Experiment II uses a weak acid. The heat of neutralization of a weak acid by a strong alkali is less than the heat of neutralization of a strong acid by a strong alkali . 2 This is because during neutralization of a weak acid such as ethanoic acid , part of the heat is used to dissociate the acid molecules Able to explain with one of the reasons Able to give an idea Sample answer Ethanoic acid is a weak acid No response or wrong response

2 1

Question
2 (a)

Mark Scheme Able to state all observation correctly Sample answer EXPERIMENT EXPT I Calcium nitrate dissolves // Colourless solution is formed. EXPT II Copper(II) sulphate dissolves// Blue solution is formed EXPT III . Calcium carbonate does not dissolve/remains unchanged // No change. Observation

Marks

Able to state any 2 observations correctly. Able to state any 1 observation correctly. No response or wrong response (b)

2 1 0 3

Able to state the operational definition of soluble salt correctly Sample answer: When a salt is added into water and dissolves to form a solution, it is a soluble sal t.// When a salt dissolves in water to form a solution, it is a soluble salt. Able to state the operational definition of soluble salt less correctly Sample answer When a salt is added into water and forms a solution, it is a soluble salt. When a salt dissolves to form a solution, it is a soluble salt. Salt dissolves in water to form a solution.

Able to state any idea of operational definition of soluble salt Salt dissolves//Salt dissolves in water. Solution forms. No response or wrong response
(d)

0 3

Able to classify all the solutions correctly Sample answer Soluble salt Potassium sulphate Zinc sulphate
# Score 1 if state in the reverse

Insoluble salt Lead(II) sulphate Barium sulphate

Able to classify at least 3 salts correctly Able to classify any 2 salts correctly No response or wrong response

2 1 0

Question

Mark Able to state the problem statement correctly Sample answer: How does the distance between two metals in the electrochemical series affect the voltage produced? Able to state the problem statement less correctly No response or wrong response

Score

3(a)

1 0

Question

Rubric Able to state the three variables correctly Sample answer: Manipulated: Pairs of metals Responding: Voltage // Voltmeter reading

Score

3(b)

Constant: Electrolyte // Copper(II) sulphate solution // Copper electrode//Concentration of electrolyte Able to state any two variables correctly Able to state any one variable correctly No response or wrong response 2 1 0

Question

Rubric Able to state the hypothesis correctly and with direction Sample answer: Hypothesis: The further the distance of the pairs of metals in the electrochemical series, the greater the voltage produced Able to state the relationship between manipulated variable and responding variable but in the opposite direction // no direction Able to state an idea of the hypothesis

Score

3(c)

1 No response or wrong response Question Rubric Able to give complete list of substances and apparatus Sample answer: Substances Copper (II) sulphate solution, magnesium metal, zinc metal, iron metal, copper metal, sandpaper. 3(d) Apparatus Beaker, connecting wire, voltmeter Able to give at least two substances and at least two apparatus Able to give at least one substance and at least one apparatus No response or wrong response 2 1 0 3 0 Score

Question

Rubric Able to list all the steps correctly Sample answer: 1. Clean the strips of magnesium and copper with sandpaper. 2. Measure 50 100 cm3 of copper(II)sulphate solution and pour into a beaker. 3. Dip the magnesium and copper strips into the copper(II) sulphate solution. 4. Complete the circuit // Connect the strips to the voltmeter. 5. Record the voltmeter reading. 6. Repeat steps 1 to 5 by replacing pairs of Mg/Cu with Zn/Cu, Al/Cu and Fe/Cu . Able to list down steps 2, 3, 4 and 5

Score

3(e)

2 1 Able to list down steps 3 and 4 No response or wrong response 0

Question 2(f)

Marks Scheme Able to exhibit the tabulation of data that includes the following four information. 1. Heading for the manipulated variables 2.. Heading for responding variable 3. All Manipulated variables Sample answer: Pairs of metals Voltmeter reading // Voltage (V) Mg / Cu Al / Cu Fe / Cu Zn / Cu

Marks

Able to exhibit the tabulation of data that includes the following three information. 1. Heading for the manipulated variables 2.. Heading for responding variable 3. One Manipulated variable Sample answer: Pairs of metals Voltmeter reading // Voltage (V) Mg / Cu 2

Able to exhibit the tabulation of data that includes the following two information. 1. Heading for the manipulated variables 2.. Heading for responding variable Sample answer: Pairs of metals Voltmeter reading // Voltage (V)

END OF MARKING SCHEME

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