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454t/3
3. Write your answers fot Question 3 on the "helaian tambahan". You may use
equation, diagralns, tables, gfaphs and other suitable methods to explain your answer.
4. Show your working" it may help you to gt marks5. lf you wjsh to change your answef, neatly
Therr write down the new answer. cross out &e answer that you have done.
6. The diagrams in the q*estions are not drawn to scale 'tnless stated.
7. Mark allocated for each question orpart question are shown in brackets.
B. The time suggested to srxwers Que$tion
Marks awarded:
Mark
3
Descrintion
t
0
4541/3
pihat
sebelah
SULIT
SULIT
1 Diagram
fujah
4s4113
l.l
Experimerit
I
of
Reaction between 25 cm3 of sodium hydroxide solution , NaOH 1.0 mol dm-3 and 25 cm3 hydrochloric acid, HCI 1.0 mol dm-' Tinrlak bulus anturuZ5om3 letrutan fiatrium hi<Irol*idu, NaOH l-0 mol dm'3 elengtn 25cmi ucid hklxtWorik HCt 1.0 mol dm'3
OC
OC
tertingf cdrnpaftrn
OC
Change in temperanrre
Perubo.hnt suhu
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sul,rT
Experiment
4
II
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Reaction between 25 cm3 of sod.ium hydroxide solution , NaOH 2.0 mol dm-3 and 25 cm3 of ethanoic acid, CH3 COOH 2.0 mol dm-i l Tirutak balas antara 25 cml larutan natrium hidroksida, NaOH 2.0 mol dm'3 deng*t 25 cm asid et6noik2.0 mol dm-3
W#f, W
\
Polystyrene cups Cawan polistirena
il|fl
f}Il ilil
: Tr oC
Tz
uC
mixture:
temperature
T3 "C
(a)
Wdte the initial and the highest temperature of the mixhne and change in tem.perafure for Experimeni I in Diagram 1.1 Tulis suhu crwal dan suhu tertinggi campuran serta perubahan suhu untuk Elxperitnenldalam Rajah l.l
13 marks)
(b)
Construct a table that can be used to record the data from both experiments. Bina satuja&nl ymg boleh dignakn wrtuk merekod data bagi kedua-daa eksperimen
13 marrs'l
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sultT
(c)
4541t3
State one hypothesis for both experiments. Nyalakm satu hipotesis bagi kedaa-dua eh,sperimen
13
marbl
(d) .
Il
[3
marks]
these
{e}
Why must the initial temperature and the higlrest temperature be rscorded in
experiments?
Mengapakah suhu swal dwr suha tertinggi perlu direkodkan dalam ekrperimen ini?
[3
narfu]
(0
How can the value of the change of lenrperature be obtained? Bagaimwtakah nilai perubahan suhu diperoleh?
[3 wr.lesl
(g)
ti)
Manipulated Variable
P embol e hubah dimantpulas
(it
(iii)
RcspondingVariable
P em b a I e lubuh
beryerakbalus
[ 3 marks]
454v3
SULIT fri)
45411-\
for the Diagram 1.2 shows the calculation to determinc tlre heat of neutralisation reactions in Experiments I and II n";"n 1.2 menmju*kan perhitungan untah menentukm haba peneatralan bogi tiwlak balos daiam Ekperimenl dan Eksperimenll
Experiment
Experiment
II
Heat released
Haba yang dibebaskan
: mcO
*xJ
=50Bx4.2Jgr x
Heat $f neutralisation
oc
: mc0
=yJ
= 50 8 x4.21
XT3oC
Heat of neutralisation
tr{aba peneutra}rm
Haba penedralan
xkJ
y-ki
It *'as found that the value of x is greater than value of y' Explain why. Didapa{i nilai x lebih hesat dtnipada nilai y'
Teranglam mengsps.
t3
morksJ
454t13
flLihat sebelah
SULIT
sulrT
2 Table
1 shows
'7
454113
Experiment I, Experiment II and Experiment III which arc conducted to study the solubility of salts in water. Jadaal 1 menunjukkon Ekperimen [" Eksperimen {( don Eksperimen lll vang diljalankm untak
nengkqji keterlarulan gararn dalam air.
Experiment
Reaction
TindaL balas
Observations Penerhstian
Add water
Tambah
sir
Calcium
Kqlsium
nitrate nitrat
II
Add water Tsmbahair
sulfat
NI
SULIT I (a) V/rite the observation for Experiment I. II and III in Table L
Tul is pemerlnt ian bagi Eksperimen
454t/3
I. 13
marksl
(b)
Based on Experiment I and II, state the operational definition of soluble salt. Berdasskan Eksperimen I dmt fI" nyatakm definisi secaro operasi bagi garam terlarut.
f3 marks]
(c)
salts into solubl salts and insoluble salts. ke@a garom terlarw de, garam tak terlsrut.
l3 marksl
454t/3
pihat
sebelsh
SULIT
SULIT
3
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The distance between pnirs of different metals in the electrochemical serisr aflect the.voltnge produced. Jarak di antara pasangan logamyntg berlainon di dolam shi elehtto*imia mcnpengarahi voltan yrng lerhssil
Diagram 3 shows a voltaic cell which consist of two different metals dipped in an electrolyte. Rajah 3 newnjul*an salu sel voltan yang terdiri daripada dua logam yang berlainan di celup dalan satu elektolit.
Diagranr 3
Based on Diagram 3, plan one laboratory experiment to investigate the efTect of the distance betwon two metals in the electrochemical series on the voltage produced. Berdacwksn Rcjah3, rancang sata ekryrimen mobtwl wtak mengkaji kescn jwuk di sntara dua logam dalam siri elektrokimis kE atas voltan yang terhasil.
Problem statement
Pernyataan masalah
Hypothesis
Hipotesis
[17 marks]
pihat
sebsldh
SULIT
PAPER 3: CHEMISTRY
Question 1(a)
Mark Scheme Able to record all the temperature accurately Answer Initial temperature Highest temperature = 29.0 = 41.0
Marks 3
Change of temperature = 12.0 2 Able to record all the temperature correctly Sample answers Initial temperature Highest temperature = 29 = 41
Change of temperature = 12 Able to record one temperature correctly No response or wrong response 1(b) Able to construct table accurately with correct title and unit Sample answer TemperatureC I Initial temperature of mixture Highest temperature of mixture 29.0 41.0 T1 T2 Experiment II 1 0 3
Able to construct table less accurate with at least one experiment No response or wrong response 1(c ) Able to state the hypothesis accurately Sample answer The heat of neutralization of a weak acid and strong alkali is smaller than the heat of neutralization of strong acid by a strong alkali Able to state the hypothesis correctly Sample answer The heat of neutralization changes when different acids react with strong alkali Able to state the idea of hypothesis Sample answer The heat of neutralization changes No response or wrong response 1(d) Able to predict the change of temperature accurately 11C Able to predict the change of temperature correctly 9-10C Able to predict less correctly 7-8C No response or wrong answer 1(e) Able to explain with two correct reasons Sample answer *This is to enable the change in temperature to be measured. *The change of temperature is needed to calculate the heat of neutralization
1 0 3
0 3
0 3
Able to explain at least one reason from the above Able to give an idea of explaining No response or wrong response 1(f) Able to state the formula accurately Sample answer Change in temperature= Highest temperature of mixture- initial temperature of mixture Able to state the formula correctly Sample answer Difference of temperature between highest and lowest Able to give an idea of calculating No response or wrong response 1(g) Able to state all the variables correctly Answer Manipulated Variable: The type of acid used // ethanoic acid, hydrochloric acid Responding Variable : The heat of neutralisation
2 1 0 3
1 0 3
Constant Variable : The concentration and the volume of acid and alkali // the type of container that is used to hold the mixture Able to state two variables correctly Able to state one variable correctly No response or wrong response 2 1 0
1(h)
Able to explain with two reasons correctly Sample answer 1.Experiment I uses a strong acid whereas Experiment II uses a weak acid. The heat of neutralization of a weak acid by a strong alkali is less than the heat of neutralization of a strong acid by a strong alkali . 2 This is because during neutralization of a weak acid such as ethanoic acid , part of the heat is used to dissociate the acid molecules Able to explain with one of the reasons Able to give an idea Sample answer Ethanoic acid is a weak acid No response or wrong response
2 1
Question
2 (a)
Mark Scheme Able to state all observation correctly Sample answer EXPERIMENT EXPT I Calcium nitrate dissolves // Colourless solution is formed. EXPT II Copper(II) sulphate dissolves// Blue solution is formed EXPT III . Calcium carbonate does not dissolve/remains unchanged // No change. Observation
Marks
Able to state any 2 observations correctly. Able to state any 1 observation correctly. No response or wrong response (b)
2 1 0 3
Able to state the operational definition of soluble salt correctly Sample answer: When a salt is added into water and dissolves to form a solution, it is a soluble sal t.// When a salt dissolves in water to form a solution, it is a soluble salt. Able to state the operational definition of soluble salt less correctly Sample answer When a salt is added into water and forms a solution, it is a soluble salt. When a salt dissolves to form a solution, it is a soluble salt. Salt dissolves in water to form a solution.
Able to state any idea of operational definition of soluble salt Salt dissolves//Salt dissolves in water. Solution forms. No response or wrong response
(d)
0 3
Able to classify all the solutions correctly Sample answer Soluble salt Potassium sulphate Zinc sulphate
# Score 1 if state in the reverse
Able to classify at least 3 salts correctly Able to classify any 2 salts correctly No response or wrong response
2 1 0
Question
Mark Able to state the problem statement correctly Sample answer: How does the distance between two metals in the electrochemical series affect the voltage produced? Able to state the problem statement less correctly No response or wrong response
Score
3(a)
1 0
Question
Rubric Able to state the three variables correctly Sample answer: Manipulated: Pairs of metals Responding: Voltage // Voltmeter reading
Score
3(b)
Constant: Electrolyte // Copper(II) sulphate solution // Copper electrode//Concentration of electrolyte Able to state any two variables correctly Able to state any one variable correctly No response or wrong response 2 1 0
Question
Rubric Able to state the hypothesis correctly and with direction Sample answer: Hypothesis: The further the distance of the pairs of metals in the electrochemical series, the greater the voltage produced Able to state the relationship between manipulated variable and responding variable but in the opposite direction // no direction Able to state an idea of the hypothesis
Score
3(c)
1 No response or wrong response Question Rubric Able to give complete list of substances and apparatus Sample answer: Substances Copper (II) sulphate solution, magnesium metal, zinc metal, iron metal, copper metal, sandpaper. 3(d) Apparatus Beaker, connecting wire, voltmeter Able to give at least two substances and at least two apparatus Able to give at least one substance and at least one apparatus No response or wrong response 2 1 0 3 0 Score
Question
Rubric Able to list all the steps correctly Sample answer: 1. Clean the strips of magnesium and copper with sandpaper. 2. Measure 50 100 cm3 of copper(II)sulphate solution and pour into a beaker. 3. Dip the magnesium and copper strips into the copper(II) sulphate solution. 4. Complete the circuit // Connect the strips to the voltmeter. 5. Record the voltmeter reading. 6. Repeat steps 1 to 5 by replacing pairs of Mg/Cu with Zn/Cu, Al/Cu and Fe/Cu . Able to list down steps 2, 3, 4 and 5
Score
3(e)
Question 2(f)
Marks Scheme Able to exhibit the tabulation of data that includes the following four information. 1. Heading for the manipulated variables 2.. Heading for responding variable 3. All Manipulated variables Sample answer: Pairs of metals Voltmeter reading // Voltage (V) Mg / Cu Al / Cu Fe / Cu Zn / Cu
Marks
Able to exhibit the tabulation of data that includes the following three information. 1. Heading for the manipulated variables 2.. Heading for responding variable 3. One Manipulated variable Sample answer: Pairs of metals Voltmeter reading // Voltage (V) Mg / Cu 2
Able to exhibit the tabulation of data that includes the following two information. 1. Heading for the manipulated variables 2.. Heading for responding variable Sample answer: Pairs of metals Voltmeter reading // Voltage (V)