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MONOPROPYLENE GLYCOL - Industrial

CAS No.: 57 - 55 - 6 UN No.: Not applicable EC No.: 200 - 38 - 0 SECTION I. PRODUCT AND COMPANY IDENTIFICATION Product Name Commercial Name Non-scientific Name Suppliers Name and Address AN VNH PHT Ltd Co. No 1, 31E Street, Quarter 5, An Ph Ward, District 2, H Ch Minh City Tel: (08) 6281 3425 - Fax: (08) 6281 3422 - Mobile: 0903 711 265 Manufacturers Name and Address Product Use : : Information not available : : : : Monopropylene Glycol Monopropylene Glycol - Industrial Information not available

Material Safety Data Sheet

Used in unsaturated polyester and benzoate processing.

Emergency Contact: AN VNH PHT Ltd Co. No 1, 31E Street, Quarter 5, An Ph Ward, District 2, H Ch Minh City Tel: (08) 6281 3425 - Fax: (08) 6281 3422 - Mobile: 0903 711 265

SECTION II. INFORMATION ON INGREDIENTS

Chemical Identity Propane-1,2-diol

CAS No. 57 - 55 - 6

Chemical formula HO-CH2-CHOH-CH3

Concentration 100.00 %

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SECTION III. HAZARDS IDENTIFICATION 1. Hazards Classification: - Not harmful 2. Hazard Statements Physical Hazards Health Hazards Environmental Hazards - No physical hazard under GHS criteria. - No health hazard under GHS criteria. - Not classified as an environmental hazard under GHS criteria. Prevention

- Keep away from heat/sparks/open flames/hot surfaces. - No smoking. - Keep container tightly closed. - Ground/bond container and receiving equipment. - Use explosion-proof electrical/ventilating/lighting equipment. - Use only non-sparking tools. - Take precautionary measures against static discharge. - Avoid breathing dust/fume/gas/mist/vapours/spray. - Wash hands thoroughly after handling. - Use only outdoors or in a well-ventilated area. - Wear protective gloves/protective clothing/eye protection/face protection. Storage

- Store in a well-ventilated place. Keep container tightly closed. - Keep cool. - Store locked up. Disposal

- Dispose of contents and container to appropriate waste site or reclaimed in accordance with local and national regulations. Aggravated medical condition

- No specific hazards under normal use conditions.

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3. Routes of Entry and Symptoms Eye: No specific symptoms and effects. Inhalation: No specific symptoms and effects. Skin: No specific symptoms and effects. Ingestion: No specific symptoms and effects.

SECTION IV. FIRST AID MEASURES 1. Eye contact: Remove to fresh air. If rapid recovery does not occur, transport to nearest medical facility for additional treatment. 2. Skin contact: Remove contaminated clothing. Flush exposed area with water and follow by washing with soap if available. 3. Inhalation: Remove to fresh air. If rapid recovery does not occur, transport to nearest medical facility for additional treatment while keeping the body at rest in a position comfortable for breathing. 4. Ingestion: Does not required medical care unless a large amount of MDG is swallowed. However medical guidance is still recommended.

SECTION V. FIRE FIGHTING MEASURES 1. Flammability classification: Not applicable 2. Specific hazards arising from Chemicals: The vapour is heavier than air, spreads along the ground and distant ignition is possible. Will only burn if enveloped in a preexisting fire. 3. Emission: CO 4. Flames Causes: Sparks; open flames; static discharge 5. Suitable Extinguishing Media: Alcohol-resistant foam, water spray or fog. Dry chemical powder, carbon dioxide, sand or earth may be used for small fires only. Do not use water in a jet. Clear fire area of all non-emergency personnel.

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6. Protective Equipment and Precautions for Fire Fighters: Wear full protective clothing and self contained breathing apparatus. Proper protective equipment including breathing apparatus must be worn when approaching a fire in a confined space. 7. Additional Advice: All storage areas should be provided with adequate fire fighting facilities. Keep adjacent containers cool by spraying with water.

SECTION VI. ACCIDENTAL RELEASE MEASURES Observe all relevant local and international regulations. Avoid contact with spilled or released material. Immediately put away contaminated equipment. Isolate hazard area and deny entry to unnecessary or unprotected personnel. Stay upwind and keep out of low areas. Shut off leaks, if possible without personal risks. Remove all possible sources of ignition in the surrounding area. Use appropriate containment (of product and fire fighting water) to avoid environmental contamination. Prevent from spreading or entering drains, ditches or rivers by using sand, earth, or other appropriate barriers. Attempt to disperse the vapour or to direct its flow to a safe location for example by using fog sprays. Take precautionary measures against static discharge. Ensure electrical continuity by bonding and grounding (earthing) all equipment. Ventilate contaminated area thoroughly. Local authorities should be advised if significant spillages cannot be contained. Vapour may form an explosive mixture with air. 1. For small liquid spills (1 drum): Transfer by mechanical means to a labelled, sealable container for product recovery or safe disposal. Allow residues to evapourate or soak up with an appropriate absorbent material and dispose of safely. Remove contaminated soil and dispose of safely. 2. For large liquid spills (> 1 drum): Transfer by mechanical means such as vacuum truck to a salvage tank for recovery or safe disposal. Do not flush away residues with water. Retain as contaminated waste. Allow residues to evapourate or soak up with an appropriate absorbent material and dispose of safely. Remove contaminated soil and dispose of safely.

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SECTION VII. USAGE AND STORAGE Avoid breathing vapours or contact with material. Only use in well ventilated areas. Wash thoroughly after handling. Forguidance on selection of personal protective equipment see Section VIII of this Material Safety Data Sheet. Use the information in this data sheet as input to a risk assessment of local circumstances to help determine appropriate controls for safe handling, storage and disposal of this material. 1. Precautions for Safe Handling: In accordance with good industrial hygiene practices, precautions should be taken to avoid breathing of material. Use local exhaust extraction over processing area. For lines and fittings, avoid copper, copper alloys, zinc. Avoid contact with skin, eyes, and clothing. Air-dry contaminated clothing in well-ventilated area before laundering. Extinguish any naked flames. Do not smoke. Remove ignition sources. Avoid spark. Do not empty into drains. Handling Temperature: Ambient. When handling product in drums, safety footwear should be worn and proper handling equipment should be used. 2. Conditions for Safe Storage: Prevent all contact with water and with moist atmosphere. Tanks must be clean, dry and rust-free. Must be stored in a diked (bunded) well- ventilated area, away from sunlight, ignition sources and other sources of heat. Nitrogen blanket is recommended for large tanks (capacity 100 m3 or higher). Drums should be stacked to a maximum of 3 high. Keep container tightly closed. Keep dry. Prevent ingress of water. Storage temperature: 40C maximum. Lines should be purged with nitrogen before and after product transfer. Electrostatic charges may be generated during pumping. Electrostatic discharge may cause fire. Keep containers closed when not in use. 3. Container Advice: For containers, or container linings use mild steel, stainless steel. For container paints, use epoxy paint, zinc silicate paint. Containers, even those that have been emptied, can contain explosive vapours. Do not cut, drill, grind, weld or perform similar operations on or near containers.

SECTION VIII. EXPOSURE CONTROLS/PERSONAL PROTECTION 1. Occupational Exposure Limits: Information not available Additional information - Wash hands before eating, drinking, smoking and using the toilet.

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Biological exposure index (BEI) - See reference for full details: No biological limit allocated.

2. Appropriate Engineering Controls: The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Select controls based on a risk assessment of local circumstances. Appropriate measures include: Provide adequate ventilation in storage areas. Use sealed systems as far as possible. Adequate explosion - proof ventilation to control airborne concentrations below the exposure guidelines/limits. Local exhaust ventilation is recommended. Firewater monitors and deluge systems are recommended. 3. Individual Protection Measures: Personal protective equipment (PPE) should meet recommended national standards. Check with PPE suppliers. Eye Protection: Chemical splash goggles (chemical monogoggles). Protective Clothing: Use protective clothing which is chemical resistant to this material. Hand Protection: Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, chemical resistance of glove material, glove thickness, dexterity. Always seek advice from glove suppliers. Contaminated gloves should be replaced.Where hand contact with the product may occur the use of gloves approved to relevant standards (e.g. Europe: EN374, US: F739) made from the following materials may provide suitable chemical protection: Nitrile rubber, PVC, Viton. Personal hygiene is a key element of effective hand care. Gloves must only be worn on clean hands. Feet Protection: Safety shoes and boots should also be chemical resistant. Respiratory Protection: If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker health, select respiratory protection equipment suitable for the specific conditions of use and meeting relevant legislation. Where airfiltering respirators are suitable, select an appropriate combination of mask and filter. Select a filter suitable for organic gases and vapours [boiling point > 65C (149F)] meeting EN141. Where respiratory protective equipment is required, use a full-face mask. Where air filtering respirators are unsuitable (e.g. airborne concentrations are high, risk of oxygen deficiency, confined space) use appropriate positive pressure breathing apparatus.

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4. Thermal Hazards: Information not available. 5. Hygiene Advices: After using gloves, hands should be washed and dried thoroughly. Application of a non-perfumed moisturizer is recommended. 6. Monitoring Methods: Monitoring of the concentration of substances in the breathing zone of workers or in the general workplace may be required to confirm compliance with an OEL and adequacy of exposure controls. For some substances biological monitoring may also be appropriate. Examples of sources of recommended air monitoring methods are given below or contact supplier. Further national methods may be available. National Institute of Occupational Safety and Health (NIOSH), USA: Manual of analytical Methods http://www.cdc.gov/niosh/nmam/nmammenu.html Occupational Safety and Health Administration (OSHA), USA: Sampling and Analytical Methods http://www.oshaslc. gov/dts/sltc/methods/toc.html Health and Safety Executive (HSE), UK: Methods for the Determination of Hazardous Substances http://www.hsl.gov.uk/search.html

SECTION IX. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Colour: Colourless Odour: None Vapour Pressure: ca. 10 Pa at 20oC / 68 oF Vapour Density (air=1): 2.5 at 20 oC / 68 oF Water Solubility: Completely miscible pH: 7 Density: 1.036 kg/m3 at 20 oC / 68 oF Initial Boiling Point: 186 - 189 oC / 367 - 372 oF Melting/Freezing Point: -59 oC / -74 oF Flash point: 99 oC / 210 oF Auto-ignition Temperature: 421 oC / 790 oF Explosion / Flammability limits in air: 2.6 - 12.6 % (V) Evapouration Rate: Not applicable Molecular Weight: 76.09 g/mol

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SECTION X. STABILITY AND REACTIVITY 1. Stability: Stable, hygroscopic. 2. Possibility of Hazardous Reactions: Reacts with strong oxidizing agents, strong acids. 3. Conditions to avoid: Avoid heat, sparks, open flames and other ignition sources 4. Incompatible Materials Hazardous: Strong oxidising agents, strong acids. 5. Decomposition Products: Carbonyl and dioxolane derivatives may be formed. SECTION XI. TOXICOLOGICAL INFORMATION

Chemical Identity Monopropylene Glycol

Dose LD50 > 5000 mg/kg LD50 > 5000 mg/kg

Routes of Entry Oral

Result Low acute toxicity Low acute toxicity

Tested on

Rat

Dermal

Rabbit

1. Permanent Effects on Human: Information not available 2. Other Effects on Human Skin corrosion/irritation: Not irritating to skin Eye irritation: Not irritating to eyes Respiratory irritation: Not expected to be a respiratory irritant. Skin sensisation: Not a skin sensitiser. Repeated dose toxicity: Low systemic toxicity on repeated exposure. The reduction of survival of erythrocyte exists in cats (for high dose).

SECTION XII. ECOLOGICAL INFORMATION 1. Acute Toxicity

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Chemical Identity

Ecological Type Fish, aquatic

Effected Cycle

Dose

Result

Monopropylene Glycol

invertebrates, algae, microorganisms

Information not available

LC/EC/IC50 > 100 mg/l

Low toxicity

2. Effects on Ecology

Persistence/degradability: Inherently biodegradable.


BOD and COD level: Information not available Emission of Degradation: Information not available Toxicity Level of Degradation: Information not available Mobility: If product enters soil, it will be highly mobile and may contaminate groundwater. Dissolves in water. Bioaccumulative Potential: Does not bioaccumulate significantly.

SECTION XIII. DISPOSAL LEGISLATION AND WASTE DISPOSAL METHOD 1. Information of Disposal Regulation: Information not available 2. Disposal Hazards Identification: Information not available 3. Disposal Measures: Information not available 4. Emission of Disposal, Waste Disposal Methods: Information not available 5. Disposal Considerations: Material Disposal: Recover or recycle if possible. It is the responsibility of the waste generator to determine the toxicity and physical properties of the material generated to determine the proper waste classification and disposal methods in compliance with applicable regulations. Do not dispose into the environment, in drains or in water courses. Waste product should not be allowed to contaminate soil or water. Container Disposal: Drain container thoroughly. After draining, vent in a safe place away from sparks and fire. Residues may cause an explosion hazard. Do not, puncture, cut, or weld uncleaned drums. Send to drum recoverer or metal reclaimer. Local Legislation: Local regulations may be more stringent than regional or national requirements and must be complied with.

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SECTION XIV. TRANSPORTATION LEGISLATION This material is not subject to US Department of Transportation Classification, DOT regulations under 49 CFR Parts 171-180. This material is not classified as dangerous under IMDG and IATA regulations. Packing: 215 kg/drum Additional Information: This product may be transported under nitrogen blanketing. Nitrogen is an odourless and invisible gas. Exposure to nitrogen may cause asphyxiation or death. Personnel must observe strict safety precautions when involved with a confined space entry.

SECTION XV. REGULATORY INFORMATION 1. Regulatory Information (under European Commision) AICS DSL INV (CN) ENCS (JP) ISHL (JP) ISHL (JP) ISHL (JP) NZ CLSC TSCA EINECS KECI (KR) PICCS (PH) NZIOC 2. Hazards Classification - Not harmful : : : : : : : : : : : : : Listed. Listed. Listed. Listed. (2)-234 Listed. 2-(8)-321 Listed. 2-(8)-323 Listed. (2)-234 Listed. Listed. Listed. 200-338-0 Listed. KE-29267 Listed. Listed.

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SECTION XVI. OTHER INFORMATION MSDS Preparation Date: 25/12/2004 MSDS Latest Revisions: 07/10/2011 Name of MSDS Preparing Individual and Organisation: AN VNH PHT Ltd Co. MSDS Distribution: The information in this document should be made available to all who may handle the product. Notes to Users:

Information provided in this MSDS is compiled based on latest knowledge of Chemicals and must be used to implement accidental prevention methods. This MSDS is composed based on Law on Chemicals and Decree 108/2008/ND - CP of Government. Chemicals in this MSDS may have other dangerous characteristics by usage and handling circumstances.

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