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Definitions
1) Using the 2p and 2s atomic orbitals will lead to two different types of
C—H bonds: Those from the overlap of a 2p orbital of carbon and a 1s
orbital of hydrogen and those from the overlap of a 2s orbital of
carbon and a 1s orbital of hydrogen. This is a problem because
methane is known to have four identical C—H bonds.
2) Since the carbon 2p orbitals are mutually perpendicular, we might
expect the three C—H bonds formed with these orbitals to be oriented
at 90-degree angles. However, the methane molecule is known by
experiment to be tetrahedral with bond angles of 109.5 degrees.
Sp2 Hybridization
In ethylene, the sp3 orbitals we just considered will not work because
they are at angles of 109.5 degrees rather than the required 120 degrees.
These angles can be obtained by combining one s orbital and two p
orbitals, this is called sp2 hybridization.
The three sp2 orbitals on each carbon can be used to share electrons.
This type of bonding is called a sigma bond. But how can we explain the
double bond? The second bond is the result from sharing an electron
pair above and below the sigma bond, this type of bond is called a pi
bond.
Bond Order
To indicate bond strength, we use the concept of bond order. Bond order
is the difference between the number of bonding electrons and the
number of antibonding electrons divided by two. The higher the bond
order, the more stable the atom is.