Professional Documents
Culture Documents
Reactor Calculations
Content
! The continuous-flow, stirred tank reactor, CSTR ! ! ! ! Properties Mass balance equation The residence time Reactor calculations ! Methodology ! Example: 1st order irreversible reaction ! Sequential solution ! Simultanuous solution ! Conversion ! Remarks
Lund University / Faculty of Engineering LTH / Department of Chemical Engineering / Per Warfvinge
Lund University / Faculty of Engineering LTH / Department of Chemical Engineering / Per Warfvinge
Qout c
! Steady-state
Qcin + rV = Qc
Q cin V r c
Q c
Lund University / Faculty of Engineering LTH / Department of Chemical Engineering / Per Warfvinge
r c
Lund University / Faculty of Engineering LTH / Department of Chemical Engineering / Per Warfvinge
Lund University / Faculty of Engineering LTH / Department of Chemical Engineering / Per Warfvinge
! System properties: ! Input flow concentration of A: 3 mole/m3 ! Input flow concentration of B: 0.2 mole/m3 ! Volumetric input flow rate: 1.25 m3/min ! Volumetric output flow rate: 1.25 m3/min ! Reactor volume: 5 m3 ! Kinetic rate coefficient: 0.5 1/min
Lund University / Faculty of Engineering LTH / Department of Chemical Engineering / Per Warfvinge
Example
1.! Flow and mixing conditions ! Reactor model: Steady-state CSTR
Q cin,A cin,B Q V cA r c B cA cB
! To mass balances needed are: ! To calculate cA : Mass balance equation for A ! To calculate cB : Mass balance equation for A and B ! Mass balance equations: Qcin,A + rA V = QcA
Lund University / Faculty of Engineering LTH / Department of Chemical Engineering / Per Warfvinge
Qcin,B + rB V = QcB
Example
2.! Kinetic equation ! 1st order with respect to cA :
Q cin,A cin,B r = kcA rA = kcA rB = kcA Q V cA r c B cA cB
3.! Combine mass balances with kinetic equations to the design equations: Qcin,A kcA V = QcA
Lund University / Faculty of Engineering LTH / Department of Chemical Engineering / Per Warfvinge
Example
4.! Calculations
Q cin,A cin,B Q V cA r c B cA cB
Two strategies ! Sequential calculation: Solve for cA , then for cB ! Simultanuous calculation for cA and cB The seqential strategy works for A since the kinetic expression for the formation of A only includes cA
Lund University / Faculty of Engineering LTH / Department of Chemical Engineering / Per Warfvinge
Example
! Sequential solution, start with cA :
Qcin,A kcA V Qcin,A cin,A cA = QcA = (Q + kV )cA 1 1 + k = (1 + k )cA = cin,A = 2
And, since cB
cB
Lund University / Faculty of Engineering LTH / Department of Chemical Engineering / Per Warfvinge
Example
! Simultaneous solution: Qcin,A kcA V = QcA
Qcin,B + kcA V (1 + k )cA k cA + cB
= QcB
cA 0.6667 = cB 1.5333
Lund University / Faculty of Engineering LTH / Department of Chemical Engineering / Per Warfvinge
Conversion
! The conversion, X with respect to a reactant component is:
X= Fin Fout Qin cin Qout cout = Fin Qin cin
! For a steady-state reactor where Qin = Qout : cin cout cout X= =1 cin cin
Lund University / Faculty of Engineering LTH / Department of Chemical Engineering / Per Warfvinge
Remarks
! The mass balance is defined for the whole reactor volume ! The concentration in the output stream is the same as the concentration in the reactor ! Since the fact that the reactor operates with the output concentration of reactans means the kinetic driving force is constant: rA = kcA ! Real life advantages: ! Long residence times in relation to reaction rate makes the reactor stable ! Heat may be added/removed through the reactor walls
Lund University / Faculty of Engineering LTH / Department of Chemical Engineering / Per Warfvinge
Content
! The continuous-flow, stirred tank reactor, CSTR ! ! ! ! Properties Mass balance equation The residence time Reactor calculations ! Methodology ! Example: 1st order irreversible reaction ! Sequential solution ! Simultanuous solution ! Conversion ! Remarks
Lund University / Faculty of Engineering LTH / Department of Chemical Engineering / Per Warfvinge