TamPur 130 1 lDENTlFlCATlON OF THE SUBSTANCE/PREPARATlON AND OF THE COMPANY/UNDERTAKlNG PRODUCT NAME TamPur 130 TAM lnternational Singapore Pte Ltd SUPPLlER 21 Moonstone Lane Poh Leng Building #07-03 Singapore 328462 +65 6296 0364 +65 6392 5895 sales@tam.com.sg 2 HAZARDS lDENTlFlCATlON Harmful by inhalation. lrritating to eyes, respiratory system and skin. May cause sensitisation by inhalation and skin contact. CLASSlFlCATlON Xn;R20. R42/43. Xi;R36/37/38. 3 COMPOSlTlON/lNFORMATlON ON lNGREDlENTS EC No. Name Classification CAS-No. Content 201-553-2 Dl-lSO-BUTYL PHTHALATE - Proprietary 30-60% DlPHENYLMETHANEDllSOCYANATE -lsomers & homologues Xn;R20. Xi;R36/37/38. R42. Proprietary 10-30% HOMOPOLYMER OF METHYLENEDlPHENYL DllSOCYANATE Xn;R20. Xi;R36/37/38. R42/43. Proprietary < 1% lSOCYANATES, REACTlON PRODUCT OF POLYOL WlTH METHYLENEDlPHENYL DllSOCYANATE Xn;R20. Xi;R36/37/38. R42/43. Proprietary 5-10% 247-714-0 METHYLENEDlPHENYL DllSOCYANATE Xn;R20 R42/43 Xi;R36/37/38 Proprietary 5-10% MODlFlED MDl Xn;R20. Xi;R36/37/38. R42. Proprietary 1-5% The Full Text for all R-Phrases are Displayed in Section 16 4 FlRST-AlD MEASURES lNHALATlON Move the exposed person to fresh air at once. Get medical attention if any discomfort continues. When breathing is difficult, properly trained personnel may assist affected person by administering oxygen. Get medical attention immediately! lNGESTlON DO NOT induce vomiting. Get medical attention immediately. SKlN CONTACT Remove affected person from source of contamination. Remove contaminated clothes and rinse skin thoroughly with water. Get medical attention if irritation persists after washing. Get medical attention promptly if symptoms occur after washing. EYE CONTACT Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes and get medical attention. 5 FlRE-FlGHTlNG MEASURES EXTlNGUlSHlNG MEDlA Extinguish with foam, carbon dioxide, dry powder or water fog. SPEClAL FlRE FlGHTlNG PROCEDURES Keep up-wind to avoid fumes. Containers close to fire should be removed or cooled with water. Avoid water in straight hose stream; will scatter and spread fire. Keep run-off water out of sewers and water sources. Dike for water control. SPEClFlC HAZARDS ln case of fire, toxic gases may be formed. 4 1 / REVlSlON DATE: 22/12/2008 TamPur 130 PROTECTlVE MEASURES lN FlRE Self contained breathing apparatus and full protective clothing must be worn in case of fire. 6 ACClDENTAL RELEASE MEASURES PERSONAL PRECAUTlONS Wear protective clothing as described in Section 8 of this safety data sheet. ENVlRONMENTAL PRECAUTlONS Do not discharge into drains, water courses or onto the ground. SPlLL CLEAN UP METHODS Stop leak if possible without risk. DO NOT touch spilled material! Absorb in vermiculite, dry sand or earth and place into containers. Flush with plenty of water to clean spillage area. Cordon off area. Avoid sparks and open flames. Absorb / contain spillage using inert absorbent granules, sand or earth. Transfer collected material to heavy-duty plastic / steel drums and keep in a well ventilated place for subsequent safe disposal. Containers with collected spillage must be properly labelled with correct contents and hazard symbol. 7 HANDLlNG AND STORAGE USAGE PRECAUTlONS Avoid inhalation of vapours/spray and contact with skin and eyes. Provide good ventilation. Persons susceptible for allergic reactions should not handle this product. STORAGE PRECAUTlONS Store in a dry place. Store in closed original container at temperatures between 15C and 35C. 8 EXPOSURE CONTROLS/PERSONAL PROTECTlON Std STEL - 15 min TWA - 8 hrs Name Notes 5 mg/m3 WEL Dl-lSO-BUTYL PHTHALATE 0.02 mg/m3(Sen) WEL 0.07 mg/m3(Sen) DlPHENYLMETHANEDllSOCYANATE -lsomers & homologues 0.02 mg/m3(Sen) WEL 0.07 mg/m3(Sen) METHYLENEDlPHENYL DllSOCYANATE WEL = Workplace Exposure Limit. PROTECTlVE EQUlPMENT ENGlNEERlNG MEASURES Provide adequate ventilation. RESPlRATORY EQUlPMENT ln case of inadequate ventilation use suitable respirator. HAND PROTECTlON Use protective gloves. The most suitable glove must be chosen in consultation with the gloves supplier, who can inform about the breakthrough time of the glove material. EYE PROTECTlON Use approved safety goggles or face shield. HYGlENE MEASURES Promptly remove any clothing that becomes contaminated. Wash contaminated clothing before reuse. Wash promptly with soap & water if skin becomes contaminated. Wash hands after handling. When using do not eat, drink or smoke. 9 PHYSlCAL AND CHEMlCAL PROPERTlES APPEARANCE Liquid SOLUBlLlTY lnsoluble in water 10 STABlLlTY AND REACTlVlTY STABlLlTY Stable under normal temperature conditions and recommended use. 4 2 / REVlSlON DATE: 22/12/2008 TamPur 130 CONDlTlONS TO AVOlD Water, moisture. The product will harden into a hard mass in contact with water and moisture. 11 TOXlCOLOGlCAL lNFORMATlON lNHALATlON lrritating to respiratory system. Harmful by inhalation. May cause sensitisation by inhalation. lNGESTlON May cause discomfort if swallowed. SKlN CONTACT May cause sensitisation by skin contact. EYE CONTACT lrritating to eyes. MEDlCAL CONSlDERATlONS Skin disorders and allergies. 12 ECOLOGlCAL lNFORMATlON ECOTOXlClTY The product components are not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. 13 DlSPOSAL CONSlDERATlONS GENERAL lNFORMATlON When handling waste, consideration should be made to the safety precautions applying to handling of the product. DlSPOSAL METHODS Dispose of waste and residues in accordance with local authority requirements. Recover and reclaim or recycle, if practical. 14 TRANSPORT lNFORMATlON GENERAL The product is not covered by international regulation on the transport of dangerous goods (lMDG, lATA, ADR/RlD). 15 REGULATORY lNFORMATlON LABELLlNG Harmful CONTAlNS DlPHENYLMETHANEDllSOCYANATE -lsomers & homologues lSOCYANATES, REACTlON PRODUCT OF POLYOL WlTH METHYLENEDlPHENYL DllSOCYANATE METHYLENEDlPHENYL DllSOCYANATE MODlFlED MDl RlSK PHRASES R20 Harmful by inhalation. R36/37/38 lrritating to eyes, respiratory system and skin. R42/43 May cause sensitisation by inhalation and skin contact. SAFETY PHRASES S23 Do not breathe vapour/spray. S24/25 Avoid contact with skin and eyes. S26 ln case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S37 Wear suitable gloves. S38 ln case of insufficient ventilation, wear suitable respiratory equipment. 4 3 / REVlSlON DATE: 22/12/2008 TamPur 130 S45 ln case of accident or if you feel unwell, seek medical advice immediately (show label where possible). S60 This material and its container must be disposed of as hazardous waste. P4 Contains isocyanates. See information supplied by the manufacturer. STATUTORY lNSTRUMENTS Control of Substances Hazardous to Health. Chemicals (Hazard lnformation and Packaging) Regulations. APPROVED CODE OF PRACTlCE Safety Data Sheets for Substances and Preparations. Classification and Labelling of Substances and Preparations Dangerous for Supply. GUlDANCE NOTES CHlP for everyone HSG(108). Workplace Exposure Limits EH40. 16 OTHER lNFORMATlON REVlSlON DATE 22/12/2008 REV. NO./REPL. SDS GENERATED 4 RlSK PHRASES lN FULL Not classified. NC Harmful by inhalation. R20 lrritating to eyes, respiratory system and skin. R36/37/38 May cause sensitisation by inhalation. R42 May cause sensitisation by inhalation and skin contact. R42/43 DlSCLAlMER The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. TAM lnternational shall not be held liable for any damage resulting from contact with or handling of the above product. 4 4 /