Professional Documents
Culture Documents
UNITS/UNIT CONVERSIONS/DIMENSIONAL
ANALYSIS
31
.
B. 8.00 g/cm
C. 16.1 g/cm3
D. 45.2 g/cm3
E. 20.3 g/cm3
First convert numerator; then convert denominator; then divide num. by denom.
0.289 lb x 453.6 g/lb = 131.09 g
1 in3 x (2.54 cm/in)3 = 16.39 cm3
131.09 g/16.39 cm3 = 7.998 g/cm3
E.
atm
Atm is not an SI unit; the SI unit for pressure is newtons per meter squared (N/m2) and is called the Pascal
(Pa). One atmosphere is 101.325 Pa.
Chem 161-2007 Exam I
Hill, Petrucci et al., 4th edition
Chapter 1 Chemistry: Matter and Measurement
Units/unit conversions/dimensional analysis
15. In the SI metric system, which power of ten is associated with the prefix n?
A. 109
B. 10-6
C.
10-9
D. 106
E. 10-12
n means nano which means 10-9; e.g., a nanometer is 1 x 10-9 m.
C.
-40
D. 212
E. -80
o
C = 5/9(oF 32)
A. oC = 5/9(oF 32)
o
C = 5/9(o0 32) = -18oC
0o -18o
B. oC = 5/9(oF 32)
o
C = 5/9(273 32) = 134oC
273o 134o
C. oC = 5/9(oF 32)
o
C = 5/9(-40 32) = -40oC
-40o = -40o
D. oC = 5/9(oF 32)
o
C = 5/9(212 32) = 100oC
212o 100o
E. oC = 5/9(oF 32)
o
C = 5/9(-80 32) = -62oC
-80o -62o
A.
B.
C.
D.
E.
8.39
1.30
31.2
0.0312
3.90
(8 in)3 x (2.54 cm/in)3 x (1 mL/cm3) x (1 L/1000 mL) = 8.39 L
12
The density of gold is 19.3 g/cm3. What is the density of gold in lb/in3?
A.
B.
C.
D.
E.
0.697
19.3
100
1000
1.20 103
453.59 g = 1 lb
2.54 cm = 1 in
19.3g x (1 lb/453.6 g) = 0.0425 lb
1 cm3 x (1 in/2.54 cm)3 = 0.06102 in3
0.0425 lb/0.06102 in3 = 0.696 lb/in3
A.
B.
C.
D.
E.
g
cm3
$2340
$5460
$1520
$3410
$4250
m
m
into
.
min
s
A.
B.
C.
D.
4.18 x 10-6m/s
1.51 x 1010m/s
4.18 x 1012m/s
1.51 x 10-2m/s
E.
4.18 x 106m/s
E.
3.51 g/cm3
B.
L
C. mol
D. m
E. K
kg, mol, m and K are all SI units. A dm3 is called a liter, but neither dm nor L is an SI unit.
A.
B.
C.
D.
E.
kg m-1 s-2
kg m2 s-2
kg m s-2
kg m-2 s-2
kg m-3 s-2
D.
G 109
E. p 10-15
m = milli = 10-3
M = mega = 106
= micro = 10-6
G = giga = 109
p = pico = 10-12
B. 286.3 K
C. 315.7 K
D. 341.3 K
E. 68.1 K
Co = (5/9)(F-32) = (5/9)(55.6-32) = 13.11
K = 273 + Co = 273 + 13.11 = 286.11
11.
4.0 carats
2.0 carats
C.
49 carats
choose this choice if none of the others is correct
170 carats
D.
E.
1 cm3 = 1 mL
Begin with what you know, and end with what youre trying to find.
2.8 mL x (1 cm3/1 mL) x (3.51 g/cm3) x (1 carat/0.200 g) = 49.1 carats
25.
3.2 x 10-3 L
26 L
0.40 L
1.8 L
E.
2.6 L
B. 286.3 K
C. 315.7 K
D. 341.3 K
E. 68.1 K
Co = (5/9)(F-32) = (5/9)(55.6-32) = 13.11
K = 273 + Co = 273 + 13.11 = 286.11
D.
G 109
E. p 10-15
m = milli = 10-3
M = mega = 106
= micro = 10-6
G = giga = 109
p = pico = 10-12
10
A.
B.
C.
D.
E.
kg m-1 s-2
kg m2 s-2
kg m s-2
kg m-2 s-2
kg m-3 s-2
B.
L
C. mol
D. m
E. K
kg, mol, m and K are all SI units. A dm3 is called a liter, but neither dm nor L is an SI unit.
E.
3.51 g/cm3
14.
57.0 Z
98.6 Z
C.
69.6 Z
77.0 Z
44.4 Z
D.
E.
Boiling point
Body temperature
Freezing point
C
100
37
0
Z
120
X
40
7.
1.50 x 1014 nm
1.50 x 102 nm
1.50 x 1017 nm
1.50 x 1011 nm
E.
12
1-37
Perform the following unit conversion.
c. A rectangular solid measures 1.0 m by 5.6 cm by 2.1 dm. Express its
volume in cubic inches.
(c) 1 cm = 1 x 10-2 m
2.54 cm = 1 in
1 dm = 1 x 10-1 m
1.0 m x (1 cm/1 x 10-2 m) x (1 in/2.54 cm) x 5.6 cm x (1 in/2.54 cm) x 2.1 dm x
(10-1 m/dm) x (1 cm/1 x 10-2 m) x (1 in/2.54 cm) = 7.176 x 102 = 7.2 x 102 in3
13
TEMPERATURE
ZUMDAHL 5TH EDITION
CHEM 161-2002 RECITATION 2ND WEEK-2
CHAPTER 1 - CHEMICAL FOUNDATIONS
UNITS/UNIT CONVERSIONS/DIMENSIONAL ANALYSIS
1-49
Many chemical quantities are specified as being measured at 25oC. What is
this temperature on the Fahrenheit scale? on the Kelvin scale?
F = ((9/5) C) + 32 = ((9/5)x25) + 32 = 77oF
K = C + 273.15 = 25 + 273.15 = 298.15 K = 298 K
The three key formulas are:
C = 5/9 (F-32)
F = (9/5 C) + 32
K = C + 273.15
The C and F formulas are sometimes difficult to remember. For example, does
C = 5/9 (F-32) or 9/5 (F-32) or ((5/9)F) -32?
A way to sort this out is to make certain that the equation you choose provides
answers that you already know are correct. So set up this table each time (or
just set up the BP part).
BP
FP
C
100oC
0oC
F
212oF
32oF
K
373.15K
273.15K
Lets say that we want the equation for F to C. The only equation for F to C
that makes sense is C = 5/9 (F-32). 100 = 5/9 (212-32).
14
3.
C.
niobium
D. vanadium
E. zirconium
4.
B.
1.495 g/mL
C. 1.657 g/mL
15
D. 1.982 g/mL
E. 3.018 g/mL
5.
C.
2.0 x 10-4 m
D. 200 pm
E. 2.0 x 10-9 dm
Convert everything to the same unit. cm is a convenient unit.
A.
B.
C.
D.
E.
2.0 x 10-10 cm
2.0 nm x (10-9 m/nm) x (1 cm/0.01m) = 2 x 10-7 cm
2.0 x 10-4 m x (1 cm/0.01 m) = 2 x 10-2 cm
200 pm x (10-12 m/pm) x (1 cm/0.01m) = 2 x 10-8 cm
2.0 x 10-9 dm x (0.1 m/dm) x (1 cm/0.01m) = 2 x 10-8 cm
xxxx
CHEM 161-2001 EXAM I + ANSWERS
ZUMDAHL CHAPTER I - CHEMICAL FOUNDATIONS
UNITS/UNIT CONVERSIONS/DIMENSIONAL ANALYSIS
Chem 161-Su01-Unit Conversions
2. The density of mercury is 13.6 g/cm3. What is its density when expressed in lb/in3?
A. 0.0762
B. 0.491
C. 2.04
D. 0.193
E. 376
453.59 g = 1 lb
2.54 cm = 1 in
(13.6 g/cm3) x (1 lb/453.59 g) x ([2.54 cm]3/[1 in]3) = 0.491 lb/in3
16
125 m/s
B.
2200 m/min
C.
D.
671 m/s
201 km/hr
E.
55.9 m/s
17
E.
1.
-40
1012
B.
1036
1027
10-24
10-27
C.
D.
E.
1 nm = 1 x 10-9 m
1 nm3 = (1 x 10-9 m)3
1 km = 1000 m = 1 x 103 m
(1 km)3 = (1 x 103 m)3
1 km3 x (1 x 103 m)3/1 km3 x (1 nm)3/(1 x 10-9 m)3 = 109 nm/10-27
= 1036 nm
18
E.
CHEM 161-1999 FINAL EXAM + ANSWERS
ZUMDAHL CHAPTER I - CHEMICAL FOUNDATIONS
UNITS/UNIT CONVERSIONS/DIMENSIONAL ANALYSIS
18. What is the area covered by 1.00 liter of paint when it is brushed on a wall
with a uniform thickness of 100 micrometer?
A. 0.100m2
B.
10.0 m2
C. 20.0 m2
D. 1.00m2
E. 2.00m2
Plan: Convert liters, which is volume, into m3, which is also volume. Convert micrometers into meters
(m), which is thickness. m3/m = m2, which is area. That is, area x thickness = volume. Therefore,
volume/thickness = area.
1 liter x (1000 mL/L) x (1 cm3/1 mL) x (0.01m/cm)3 = 1 x 10-3 m3
100 m x (10-6m/m) = 1 x 10-4 m
1 x 10-3 m3/(1 x 10-4 m) = 10 m2
19
A. 1.707 x 10
-3
B. 351.2
C. 6.720 x 10-2
D. 585.9
E. 4.101 x 103
6.
CHEM 161-2002 FINAL EXAM + ANSWERS
ZUMDAHL CHAPTER I - CHEMICAL FOUNDATIONS
UNITS/UNIT CONVERSIONS/DIMENSIONAL ANALYSIS
According to the SI which one of the following is a correct definition
A. 1 mol is 6.022 x 1023 entities
A is close to the correct answer, but not correct. The SI definition of the mole is
the amount of a substance that contains as many entities as there are in exactly 12 g
of carbon-12. It has been determined, through experimentation, that this number is
6.022 x 1023. Therefore, one mole is 6.022 x 1023 entities, but the latter isnt the SI
definition of a mol.
B. 1 L is 1.000 US quart
A L is not an SI unit. The SI unit of volume is m3. Furthermore, 1 L = 1.057 quart.
C. 1 kg is the length of a platinum iridium bar stored in France.
1 kg is the mass of a platinum iridium bar stored in France.
D.
E.
108
20
B.
C.
D.
E.
10-27
1036
1027
1021
Strategy: Convert cm to nm; then cube both sides to change cm3 to nm3.
1 cm x (1 x 10-2 m/1 cm) x (1 nm/1 x 10-9 m) = 1 x 107 nm
1 cm = 1 x 107 nm
(1 cm)3 = (1 x 107 nm)3
1 cm3 = 1 x 1021 nm3
1.
Chem 161-2003 Exam I
Chapter 1 - Chemical Foundations
Unit conversions/dimensional analysis
The number of cubic nanometers in 1 cm3 is
A.
B.
C.
D.
E.
1027
1036
1021
108
10-27
21
625 mi/hr x 5289 ft/mi x 12 in/ft x 1m/39.4 in x 1hr/60 min x 1min/60 sec = 280 m/s
6.
C.
D.
E.
CLASSIFICATION OF MATTER
Chem 161-2007 Exam I
Hill, Petrucci et al., 4th edition
Chapter 1 Chemistry: Matter and Measurement
Classification of matter
16. A substance
A. is always a compound.
B.
22
D.
A fruit smoothie
E. A glass f Kool AidTM
(A) Distilled water is a single phase under a conventional laboratory microscope, and is therefore
homogeneous.
(B) Filtered air is a single phase under a conventional laboratory microscope, and is therefore
homogeneous.
(C) Vinegar is a single phase under a conventional laboratory microscope, and is therefore homogeneous.
(D) A fruit smoothie is a beverage made by blending fruit with yogurt, milk or ice cream until it's thick
and smooth. Under a microscope, or with the naked eye, particles of fruit in this concoction may be seen
among the ice and milk and ice cream. Therefore, this is heterogeneous.
(E) Kool Aid is a homogeneous sugar-enriched drink in fruity flavors.
Chem 161-2007 Exam I
Hill, Petrucci et al., 4th edition
Chapter 1: Chemistry: Matter and Measurement
Classification of matter
3. Which of the following is an example of a chemical change?
A. melting ice
B. adding carbon to iron to make steel
C. Carbon dioxide escaping from soda
23
D.
24
C.
Concrete
D. Vinegar
E. Table salt
A mixture contains two or more substances. Heterogeneous means that under a simple
laboratory microscope it exhibits at least two phases.
A. False. This is a mixture in that it contains at least flavorants, sweetener and water. It
is homogeneous under a laboratory microscope.
B. False. This is a mixture in that it contains at least sodium chloride and water. It is
homogeneous under a laboratory microscope.
C. True. This is a mixture in that it contains a mixture of at least various types of
silicates and water. It is heterogeneous to the naked eye and therefore under a simple
laboratory microscope.
D. False. This is a mixture in that it contains acetic acid and water. It is homogeneous
under a laboratory microscope.
E. False. This is a mixture in that it contains sodium chloride and sodium iodide. It is
homogeneous under a laboratory microscope.
20
Which of the following physical quantities is not a base unit of the SI?
A. length
B.
volume
C. mass
D. temperature
E. time
Volume is not an SI base unit. Volume is a derived unit, in which length is cubed.
25
19
A.
Only experimental results that are consistent with your hypothesis are
considered valid.
B. A hypothesis should be as simple as possible to account for the observations.
C. Scientific laws are brief statements summarizing large amounts of scientific
data.
D. A hypothesis is a tentative explanation or prediction which can be tested by
experiment.
E. A hypothesis must be consistent with all known information.
A. False. This means that if the experimental results are inconsistent with your
hypothesis then the experimental results are not valid. This is not true. If the
experimental results are inconsistent with your hypothesis then the hypothesis is
invalid, not the experimental results. Experimental results (assuming they are
reproducible) are always valid, regardless of the hypothesis. The hypothesis has to
change, not the experimental results.
B. True.
C. True.
D. True.
E. True.
26
17
D.
flammability
E. color
A. A change in clarity can come about by heating a substance. This does not require
a change in the chemical structure of a molecule. Hence, clarity is a physical change.
B. A change in hardness can come about by heating a substance. This does not
require a change in the chemical structure of a molecule. Hence, hardness is a
physical change.
C. When a substance melts, there is no accompanying change in the chemical
structure of a molecule. Hence, melting point is a physical change.
D. Flammability is related to burning (combusting; reacting with oxygen) a molecule.
This results in a change in the chemical structure of a molecule. Hence, flammability
is chemical property, not a physical property.
E. A change in color can result from the type of incident light. This does not require
a change in the chemical structure of a molecule. Hence, color is a physical change.
E.
27
D.
28
Granite
Iron
sand
Tomato juice
Heterogeneous
mixture
Clean air
steel
marble
Milk
Table salt
Compound: A substance that can be broken down into elements by chemical processes.
Argon is not a compound. It is an element. Marble is not a pure compound. It is CaCO3 (a
compound mixed with colored impurities. Water is a compound. Granite is a mixture of
several compounds (SiO2 and various silicates). Iron is an element. Hence, the only choice
that is a compound is C, water.
Homogeneous mixture: A mixture consists of two or more substances. Homogeneous means
having visibly indistinguishable parts. Milk is a mixture of several substances, including
water and carbohydrates, and may be homogeneous (if it is homogenized milk). Jello is made
from gelatin (a mixture of proteins), fruit flavoring and dyes, so it is a mixture and is
homogeneous. Filtered sea water contains water, salt, and other microscopic material. It is a
mixture and is homogeneous. Sand is made from several compounds, the major one being
silica (SiO2), so it is a mixture. I think that if we looked at sand under a microscope it would
not be homogeneous. Tomato juice contains water, carbohydrates, proteins and other
substances, so it is a mixture, but I think if we looked at it under a microscope it would not
appear to be homogeneous. So only A, B and C are homogeneous mixtures.
Heterogeneous mixture: A mixture consists of two or more substances. Heterogeneous means
having visibly distinguishable parts. Clean air consists of many compounds, including N2,
O2 and CO2, so it is a mixture. However, under a microscope clean air is homogeneous.
Steel is a mixture, containing mainly iron and carbon. It is homogeneous under a microscope.
Marble is a mixture of CaCO3 and dyes. Due to the colored bands, it is heterogeneous. Milk
is a mixture of several substances, including water and carbohydrates, and may be
homogeneous (if it is homogenized milk) or heterogeneous (if it is not homogenized milk).
Table salt is a mixture of NaCl and additives to make it free flowing. Under a microscope it is
homogeneous. The only heterogeneous mixtures are C (marble) and D, if the milk is nonhomogenized.
Only C (water, filtered sea water, marble) fit all three criteria.
20.
three of them
B.
one of them
two of them
none of them
all of them
C.
D.
E.
30
Granite
Iron
sand
Tomato juice
Heterogeneous
mixture
Clean air
steel
marble
Milk
Table salt
Compound: A substance that can be broken down into elements by chemical processes.
Argon is not a compound. It is an element. Marble is not a pure compound. It is CaCO3 (a
compound mixed with colored impurities. Water is a compound. Granite is a mixture of
several compounds (SiO2 and various silicates). Iron is an element. Hence, the only choice
that is a compound is C, water.
Homogeneous mixture: A mixture consists of two or more substances. Homogeneous means
having visibly indistinguishable parts. Milk is a mixture of several substances, including
water and carbohydrates, and may be homogeneous (if it is homogenized milk). Jello is made
from gelatin (a mixture of proteins), fruit flavoring and dyes, so it is a mixture and is
homogeneous. Filtered sea water contains water, salt, and other microscopic material. It is a
mixture and is homogeneous. Sand is made from several compounds, the major one being
silica (SiO2), so it is a mixture. I think that if we looked at sand under a microscope it would
not be homogeneous. Tomato juice contains water, carbohydrates, proteins and other
substances, so it is a mixture, but I think if we looked at it under a microscope it would not
appear to be homogeneous. So only A, B and C are homogeneous mixtures.
Heterogeneous mixture: A mixture consists of two or more substances. Heterogeneous means
having visibly distinguishable parts. Clean air consists of many compounds, including N2,
O2 and CO2, so it is a mixture. However, under a microscope clean air is homogeneous.
Steel is a mixture, containing mainly iron and carbon. It is homogeneous under a microscope.
Marble is a mixture of CaCO3 and dyes. Due to the colored bands, it is heterogeneous. Milk
is a mixture of several substances, including water and carbohydrates, and may be
homogeneous (if it is homogenized milk) or heterogeneous (if it is not homogenized milk).
Table salt is a mixture of NaCl and additives to make it free flowing. Under a microscope it is
homogeneous. The only heterogeneous mixtures are C (marble) and D, if the milk is nonhomogenized.
Only C (water, filtered sea water, marble) fit all three criteria.
31
D.
1-65
Classify each of the following as a mixture or a pure substance.
A pure substance is a pure element or chemical compound. A mixture is two or
more substances.
a. water is a pure chemical compound; hence it is a pure substance.
32
B.
rusting of a nail
freezing of water
decomposition of water into hydrogen and oxygen gases
compression of oxygen gas
A. 2, 3, & 4
B. 1, 3, & 4
C.
1&3
D. 1 & 2
E. 1 & 4
33
xxxx
CHEM 161-2001 EXAM I + ANSWERS
ZUMDAHL CHAPTER I - CHEMICAL FOUNDATIONS
CLASSIFICATION OF MATTER
1. For which of the following can the composition vary?
1. pure substance
2. element
3. homogeneous mixture
4. heterogeneous mixture
A. 1 only
B. 2 only
C. 3 only
D. 4 only
E. Both 3 and 4
CHEM 161-2001-HOURLY EXAM I + ANSWERS
ZUMDAHL CHAPTER I - CHEMICAL FOUNDATIONS
CLASSIFICATION OF MATTER
1.Consider the following:
W.an 8 oz glass of orange juice.
X.an 8 oz glass of Coca-Cola.
Y.1 L of clean air.
Z.8 oz of steel.
Which are homogeneous?
A.none of them
B.all of them
C.W and X
D.W, X, and Y
E.Y and Z
2.
Choose this choice if all the other choices are pure substances
dinitrogen pentoxide
C.
D.
34
E.
All substances are either elements or compounds. A pure substance is one consisting
only of an element or a compound. H2O is a substance, but sea water, which also
contains other substances (e.g., NaCl) is not a pure substance. Air (pure or impure)
consists of a mixture of nitrogen, oxygen, carbon dioxide, argon and other substances.
35
SIGNIFICANT FIGURES/PRECISION/ACCURACY
10.
C.
C.
A.
B.
C.
D.
E.
1
2
3
4
5
27.053
- 26.557
0.496 This has three significant figures.
15.90
- 15.887
0.013 Since 15.90 has only two digits to the right of the decimal point, the significant figures of
this answer must have only two digits to the right of the decimal point. Hence, we would round off 0.013
to be 0.01, which has only one significant figure.
0.496/0.013 = 38.15. Since 0.013 really only has one significant figure, then 38.15 must have only one
significant figure. Hence, the answer is 4 x 101, which is one significant figure. (Answer A).
Mass (g)
4.95, 5.05, 4.00, 6.26, 4.75
4.25, 4.27, 4.22, 4.23, 4.29
5.00, 4.00, 3.00, 3.50, 2.00
A. Student A is most precise. Student B is most accurate. Student C was neither precise nor accurate.
B.
Student A is most accurate. Student B is most precise. Student C was neither precise nor accurate.
C. Student A is both accurate and precise. Student B is least precise. Student C is accurate.
D. Student A was least sensitive. Student B was more precise. Student C was most accurate.
E. One of Student As nickel was dirty. Student B was most accurate. Student C was most precise.
37
Average
Mean difference from the average
Student A
5.00
0.52
Student B
4.25
0.02
Student C
3.50
0.80
Accuracy means the closeness of the average to the correct answer. Student As average is very accurate,
in that the average is the correct answer. The accuracies of Student B and Student C are poor.
Precision means reproducibility, or closeness to its own average. Student Bs reproducibility is excellent,
while the reproducibilities of Student A and Student C are quite poor.
B. Student A is the most accurate. Student B is the most precise. Student C is neither precise nor
accurate.
A.
A.
38
Perform the following calculation and express the answer to the correct number of
significant figures.
0.05
8.9782
3
5.98 10
A. 0.6
B. 0.62
C. 0.617
D. 0.6170
E.
39
What are the results of the following two calculations, expressed respectively, to the
correct number of significant figures?
Calculation A: 8103.5/23.0
Calculation B: 2.63 + 0.0006 + 1.4
A. 352.3, 4.04
B.
352, 4.0
C. 352.33, 4.03
D. 3.5x103, 4.04
E. 352.3, 4.036
Calculation A: 5 significant figures divided by 3 significant figures 3 sig. figures
8103.5/23.0 = 3.52326 x 102 = 3.52 x 102 = 352
Calculation B: 1.4 has only one figure to the right of the decimal point. 2.63 + 0.0006
+ 1.4 = 4.0306 = 4.0
C.
40
A. 1
B.
2
C. 3
D. 4
E. 5
0.108 x 0.05431 = 0.00586548 (three significant figures, based on mult/div rule)
4.31 1.2 = 3.11 (two significant figures, based on addition/subtraction rule)
0.00586548/3.11 = 1.88601 x 10-3 = 1.9 x 10-3 (two sign. figures, based on mult/div rule)
C.
8.87 104 Pa
D. 8.64 10-6 Pa
E. 8.75 10-1 Pa
0.875 atm x (101,325 Pa/atm) = 8.87 x 104 Pa
Although 88.7 x 103 Pa is exactly the same as 8.87 x 104 Pa, scientific notation requires only one
digit to the left of the decimal point.
41
E.
42
A. 1
B. 2
C. 3
D. 4
E. 5
2.7612 - 2.7609 = 0.0003 (1 significant figure)
0.0003/2.2046 = 1.3608x10-4 = 1 (i.e., one significant figure since the division involved a number
containing only one significant figure).
1.
0.4567
B.
0.04501
0.045
0.4501
0.04500
C.
D.
E.
The leading zeros are not significant figures. Four significant figures means: 0.04500.
The last number should be rounded. Hence, 0.04501.
43
A. 1
B. 2
C. 3
D. 4
E. 5
2.7612 - 2.7609 = 0.0003 (1 significant figure)
0.0003/2.2046 = 1.3608x10-4 = 1 (i.e., one significant figure since the division involved a number
containing only one significant figure).
44
E.
45
C.
8.87 104 Pa
D. 8.64 10-6 Pa
E. 8.75 10-1 Pa
0.875 atm x (101,325 Pa/atm) = 8.87 x 104 Pa
Although 88.7 x 103 Pa is exactly the same as 8.87 x 104 Pa, scientific notation requires only one
digit to the left of the decimal point.
1-25
How many signficant figures are in each of the following?
a. 12
2
b. 1098
4
c. 2001
4
3
d. 2.001 x 10
4
0.000101
3 (The four zeros are just space holders.)
-5
f. 1.01 x 10
3
g. 1000.
4 (If there was no decimal point there could be
anything between 1and 4 significant figures.
h. 22.04030
7 (The two internal zeros are captive zeros and are
therefore significant. The final zero wouldnt be there unless it was
significant.)
6
46
B.
2
C. 3
D. 4
E. 5
A. 1.244 x 10
-7
B. 10.445
C. 0.133 x 103
D. 102.667 x 106
E. 12.556 x 10-2
CHEM 161-2001-HOURLY EXAM I + ANSWERS
ZUMDAHL CHAPTER I - CHEMICAL FOUNDATIONS
SIGNIFICANT FIGURES/PRECISION/ACCURACY
7.
Which has the most significant figures?
47
A.
B.
16.
B.
25.
E.
48
|
0
|
0.050
|
0.100
A. 1
B. 2
C. 3
D. 4
E. 5
B.
3
C. 4
D. 5
E. 1
49
1-27 mod.
Write the number below in standard exponential notation.
Standard exponential notation, also known as scientific notation, is a single
digit followed by a decimal point, followed by other digit(s) times ten to an
exponent. (Times ten to an exponent is frequently represented by Eexp.)
a. 312.54 = 3.1254 x 102 = 3.1254E2
b. 0.00031254 = 3.1254 x 10-4 = 3.1254E-4
50
1-31
Perform the following mathematical operations, and express each result to the
correct number of significant figures.
First do the addition and subtraction to determine the number of significant
figures in that answer; then do multiplication or division:
c. (9.04 - 8.23 + 21.954 + 81.0)/3.1416
9.04
-8.23
+21.954
+81.0
103.764 = 103.8 (four significant figures based on
addition/subtraction rule)
103.764/3.1416 = 33.029 = 33.03 (Based on multiplication-division significant
figure rules, four significant figures because the least number of significant
figures in this division is four.)
11.
Chem 161-2003 Exam I
Chapter 1 - Chemical Foundations
Significant figures
The result of the following calculation to the correct number of significant figures is
(4.6 x 10-2)(1.41 x 10-1) - 2.183 x 10-5
6.464 x 10-3
6.4642 x 10-3
C. 6.5 x 10-3
D. 6.46417 x 10-3
E. 6.46 x 10-3
A.
B.
(4.6 x 10-2)(1.41 x 10-1) = 6.486 x 10-3; two SFs because 4.6 has only 2 SFs.
0.00648600 This has 2 SFs, therefore 0.0065 = 4 places after the decimal point.
51
-0.00002183 This has 4 SFs, therefore 0.00002183 = 8 places after the dec point.
0.00646417 is limited by the four places after the decimal point in 0.0065, and therefore also has 4
places after the decimal point which results in 0.00646417 rounding off to 0.0065 = 6.5 x 10-3
11.
370.4
3.7 x 102
370.394
3.704 x 102
E.
3.70 x 102
22.41
+ 0.464
22.874 rounded to 22.87 (four significant figures based on addition/subtr SF rule).
22.874 x 299/18.465 = 370.39 rounded off to 370. (three significant figures based on
multiplication/division significant figures rule). 370. = 3.70 x 102
52
MISCELLANEOUS
A.
B.
C.
D.
E.
Testing a soil sample with a pesticide added before attempting to measure pesticide levels
in samples from farms.
Reviewing results from other experimenters before planning an experiment.
Testing many samples for different locations to make sure the results are reproducible.
Measuring pesticide levels at different times of day, to determine if rain or dew changes
the concentration.
Comparing urban and rural samples to measure the effect of wind on pollutants..
A positive control is a cell in an experimental study which is set up to provide a reference point
for the desired results. A negative control is a cell in an experimental study which is set up to
provide a reference point for the absence of the desired effect.
A. This is a positive control. If a specified of pesticide is put into the soil sample, and then
analyzed acceptably, it will serve as a reference point.
B. A review is not an experimental cell. A control must be an experimental cell.
C. Reproducibility is important, but it doesnt serve as a positive or negative reference point.
D. This is an experimental cell, not a positive or negative control cell.
E. This also is an experimental cell, not a positive or negative control cell.
53