MATERIALSAFETYDATASHEET Phthalicanhydride

Section1ChemicalProductandCompanyIdentification MSDSName: Catalog Numbers: Synonyms: Phthalicanhydride 154960000,154960010,154960025,154960050,154962500,220881000,42332 0000,423320020,423320250,423325000 1,3Isobenzofurandione AcrosOrganicsBVBA JanssenPharmaceuticalaan3a 2440Geel,Belgium AcrosOrganics OneReagentLane FairLawn,NJ07410 800ACROS01 +3214575211 +3214575299 2017967100 8004249300 7035273887

CompanyIdentification:

CompanyIdentification:(USA)

ForinformationintheUS,call: ForinformationinEurope,call: EmergencyNumber,Europe: EmergencyNumberUS: CHEMTRECPhoneNumber,US: CHEMTRECPhoneNumber,Europe:

Section2Composition,InformationonIngredients CAS# 85449 HazardSymbols: XN ChemicalName: Phthalicanhydride % 99% EINECS# 2016075

RiskPhrases:

2237/384142/43 Section3HazardsIdentification

EMERGENCYOVERVIEW Harmfulifswallowed.Irritatingtorespiratorysystemandskin.Riskofseriousdamagetoeyes.May causesensitizationbyinhalationandskincontact. PotentialHealthEffects Eye: Skin: Riskofseriousdamagetoeyes. Causesskinirritation.Maycausesensitizationbyskincontact.

Ingestion: Harmfulifswallowed.Maycauseirritationofthedigestivetract. Inhalation: Causesrespiratorytractirritation.Maycauserespiratorysensitization. Chronic: Maycauseliverandkidneydamage.Repeatedexposuremaycausesensitizationdermatitis. Repeatedexposuremaycauseallergicrespiratoryreaction(asthma).

Section4FirstAidMeasures Eyes: Skin: Ingestion: Inhalation: Flusheyeswithplentyofwaterforatleast15minutes,occasionallyliftingtheupper andlowereyelids.Getmedicalaid. Getmedicalaid.Flushskinwithplentyofwaterforatleast15minuteswhileremoving contaminatedclothingandshoes. Getmedicalaid.Washmouthoutwithwater. Getmedicalaidimmediately.Removefromexposureandmovetofreshairimmediately. Ifnotbreathing,giveartificialrespiration.Ifbreathingisdifficult,giveoxygen.Get medicalaid. Treatsymptomaticallyandsupportively. Section5FireFightingMeasures General Information: Extinguishing Media: Asinanyfire,wearaselfcontainedbreathingapparatusinpressuredemand, MSHA/NIOSH(approvedorequivalent),andfullprotectivegear.Thismaterialin sufficientquantityandreducedparticlesizeiscapableofcreatingadustexplosion. Usewaterspray,drychemical,carbondioxide,orchemicalfoam. Section6AccidentalReleaseMeasures General Information: Spills/Leaks: UseproperpersonalprotectiveequipmentasindicatedinSection8. Vacuumorsweepupmaterialandplaceintoasuitabledisposalcontainer.Donot letthischemicalentertheenvironment. Section7HandlingandStorage Handling: Avoidbreathingdust,vapor,mist,orgas.Avoidcontactwithskinandeyes.Avoidingestion andinhalation. Storage: Storeinacool,dryplace.Storeinatightlyclosedcontainer. Section8ExposureControls,PersonalProtection EngineeringControls: Facilitiesstoringorutilizingthismaterialshouldbeequippedwithaneyewashfacilityand asafetyshower.Useadequateventilationtokeepairborneconcentrationslow. Exposure Limits CAS#85449: UnitedKingdom,WELTWA:4mg/m3TWAUnitedKingdom,WELSTEL:12 mg/m3STEL UnitedStatesOSHA:2ppmTWA12mg/m3TWA BelgiumTWA:1ppmVLE6.2mg/m3VLE FranceVLE:6mg/m3VLE Germany:1mg/m3TWA(inhalablefraction) Japan:0.33ppmCeiling0.2mg/m3Ceiling Malaysia:1ppmTWA6.1mg/m3TWA Netherlands:2mg/m3STELNetherlands:1mg/m3MAC Spain:1ppmVLAED6mg/m3VLAED PersonalProtectiveEquipment Eyes: Skin: Clothing: Wearchemicalsplashgoggles. Wearappropriateprotectiveglovestopreventskinexposure. Wearappropriateprotectiveclothingtopreventskinexposure.

Notesto Physician:

Respirators: FollowtheOSHArespiratorregulationsfoundin29CFR1910.134orEuropeanStandardEN 149.UseaNIOSH/MSHAorEuropeanStandardEN149approvedrespiratorifexposure limitsareexceededorifirritationorothersymptomsareexperienced. Section9PhysicalandChemicalProperties PhysicalState: Flakes Color: white Odor: Notavailable pH: 2(6g/laq.sol.) VaporPressure: 0.01mbar@20degC Viscosity: 6.4mP@197degC BoilingPoint: 284degC@760mmHg(543.20F) Freezing/MeltingPoint: 129132degC AutoignitionTemperature: 580degC(1,076.00degF) FlashPoint: 152degC(305.60degF) ExplosionLimits:Lower: 1.7Vol% ExplosionLimits:Upper: 10.5Vol% DecompositionTemperature: Notavailable Solubilityinwater: 6g/l(20C) SpecificGravity/Density: MolecularFormula: C8H4O3 MolecularWeight: 148.12 Section10StabilityandReactivity ChemicalStability: ConditionstoAvoid: IncompatibilitieswithOther Materials HazardousDecomposition Products HazardousPolymerization Stableundernormaltemperaturesandpressures. Incompatiblematerials,exposuretomoistairorwater. Strongoxidizingagents,strongreducingagents,strongacids,strong bases,nitricacid,sodiumnitrate. Carbonmonoxide,carbondioxide. Willnotoccur. Section11ToxicologicalInformation RTECS#: LD50/LC50: CAS#85449:TI3150000 RTECS: CAS#85449:Draizetest,rabbit,eye:50mg/24HModerate Draizetest,rabbit,skin:500mg/24HMild Inhalation,rat:LC50=>210mg/m3/1H Oral,mouse:LD50=1500mg/kg Oral,rat:LD50=1530mg/kg Skin,rabbit:LD50=>10gm/kg . Other: SeeactualentryinRTECSforcompleteinformation.Thetoxicologicalpropertieshave notbeenfullyinvestigated. Section12EcologicalInformation Ecotoxicity: Other: Fish:Leuciscusidus:LC50313mg/l48h. Donotemptyintodrains.

Carcinogenicity: PhthalicanhydrideNotlistedasacarcinogenbyACGIH,IARC,NTP,orCAProp65. Other:

biodegradability:99%/14d Section13DisposalConsiderations Disposeofinamannerconsistentwithfederal,state,andlocalregulations. Section14TransportInformation IATA Notregulatedasa hazardousmaterial IMO Notregulatedasa hazardousmaterial RID/ADR Notregulatedasa hazardousmaterial

Shipping Name: Hazard Class: UNNumber: Packing Group:

USARQ:CAS#85449:5000lbfinalRQ2270kgfinalRQ Section15RegulatoryInformation European/InternationalRegulations EuropeanLabelinginAccordancewithECDirectives HazardSymbols:XN RiskPhrases: R22Harmfulifswallowed. R37/38Irritatingtorespiratorysystemandskin. R41Riskofseriousdamagetoeyes. R42/43Maycausesensitizationbyinhalationandskincontact. SafetyPhrases: S22Donotbreathedust. S24/25Avoidcontactwithskinandeyes. S26Incaseofcontactwitheyes,rinseimmediatelywithplentyofwaterandseekmedical advice. S37/39Wearsuitableglovesandeye/faceprotection. S46Ifswallowed,seekmedicaladviceimmediatelyandshowthiscontainerorlabel. WGK(WaterDanger/Protection) CAS#85449:0 Canada CAS#85449islistedonCanada'sDSLList USFederal TSCA CAS#85449islistedontheTSCAInventory. Section16OtherInformation MSDSCreationDate: 7/16/1996 Revision#2Date 6/17/2008 RevisionsweremadeinSections: 1,2,3,4,6,8,9,12,14
Theinformationaboveisbelievedtobeaccurateandrepresentsthebestinformationcurrentlyavailableto us.However,wemakenowarrantyofmerchantibilityoranyotherwarranty,expressorimplied,with respecttosuchinformation,andweassumenoliabilityresultingfromitsuse.Usersshouldmaketheirown investigationstodeterminethesuitabilityoftheinformationfortheirparticularpurposes.Innoeventshall thecompanybeliableforanyclaims,losses,ordamagesofanythirdpartyorforlostprofitsorany special,indirect,incidental,consequential,orexemplarydamageshowsoeverarising,evenifthecompany hasbeenadvisedofthepossibilityofsuchdamages.