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DLP/BOE-II/ I/03012008
CHAPTER - 1
Fundamentals of Physics
1.1 Units for measurement
Physical measurement always requires specification of both a value (i.e., a
number representing how much) and a unit (i.e., of what). Systems of
measurement are formal strategies for indexing amounts of specified physical
quantities.
1.1.1 Unit:
To express the magnitude of a physical quantity a standard is chosen which is
of the same kind as physical quantity. This standard is taken as reference to
measure a physical quantity which is known as unit.
Therefore the process of measurement of a physical quantity involves.
i) The selection of the unit and
ii) Number of times the unit is contained in that physical quantity
In general,
measure of a physical quantity = numerical value of the quantity X size of its
unit
1.1.2 Fundamental and derived units:
Fundamental units are those units, which can neither be derived from one
another, nor can they be further resolved into any other units.
The three fundamental units are
(i) Mass (ii) Length and (iii) Time
Derived units are units of all such physical quantities which can be expressed
in terms of the fundamental units of mass, length and time.
Ex. unit of area = (metre)2
unit of volume = (metre)3
hence all derived units can be obtained by writing it in terms of fundamental
units.
1.1.3 System of Units:
The common system of units are:
(i) CGS system: It was set up in France and is based on centimetre, gram and
second as the fundamental units of length, mass and time respectively. It is a
metric system of unit
(ii) FPS system or British system of units: - It is based on foot, pound and
second as the fundamental units of length mass and time.
(iii) MKS system: It was also set up in France and is based on metre, kilogram
and second as the fundamental units of mass, length and time.
1.1.4
SI system of unit:
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Symbol
m
kg
s
A
K
mol
cd
Symbol
rad
sr
All properties of interest to a Boiler Engineer can be derived from the above
Base and Supplementary Units as can be seen from the following:
1.1.4.3 Derived Units:
Name
of
the Unit of Measurement
Property
Acceleration
metre per sec2
Area
square metre
Density
kilogram per cubic metre
Energy
Joules
Entropy
Joules per Kelvin
Specific entropy
Joule per gram Kelvin
Force
Newton
Power (Rate of Work)
Watt
Pressure
Pascal
Quantity of Heat
Joules
Stress
(Same
as
Pascal
Pressure)
Symbol
m/s2
m2
kg/m2
J = N.m
J/K
J/(gK)
N = kg.m/s2
W = J/s
Pa = N/m2
J = N.m
Pa = N/m2
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Velocity
Work
Moment of force
specific energy
m/s
J = N.m
Nm
J/kg
1.1.4.4 Advantage of SI
(i) It is a rational system of units - Its makes use of only one unit for one
physical quantity. Ex. all types of energies are expressed in Joules. Whereas in
MKS system different units are used for different types of energies. For ex.
mechanical energy is measured in Joule, heat energy in calorie and electrical
energy in watt hour.
(ii) SI is a coherent system of units i.e all derived units can be obtained by
dividing and multiplying the basic and supplementary units and no numerical
factors are introduced as used to be the case with certain units of the CGS and
MKS systems.
(iii) SI is a metric system. The multiples and sub-multiples can be expressed
as the powers of 10.
1.1.4.5 The Prefixes of the S I
The S I allows the sizes of units to be made bigger or smaller by the use of
appropriate prefixes. For example, the electrical unit of a watt is not a big unit
even in terms of ordinary household use, so it is generally used in terms of
1000 watts at a time. The prefix for 1000 is kilo so we use kilowatts[kW] as
our unit of measurement. For makers of electricity, or bigger users such as
industry, it is common to use megawatts [MW] or even gigawatts [GW]. The
full range of prefixes with their [symbols or abbreviations] and their
multiplying factors are given below.
yotta [Y] = 1024
zetta [Z] = 1021
exa [E] = 1018
peta [P] = 1015
tera [T] = 1012
giga [G] = 109
(a thousand millions = a billion)
mega [M] = 106
(a million)
kilo [k] = 1000
(a thousand)
hecto [h] = 100
deca [da] = 10
1 deci [d] = 0.1
1 centi [c] = 0.01
1 milli [m] = 0.001 (a thousandth)
1 micro [] = 10-6
(a millionth)
1 nano [n] = 10-9
(a thousand millionth)
1 pico [p] = 10-12
1 femto [f] = 10-15
1 atto [a] = 10-18
1 zepto [z] = 10-21
1 yocto [y] = 10-24
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Rules
a. Derived units, when written in words, are not written with a capital letter
unless they are at the beginning of a sentence. The exception is the Celsius
degree which is always written with a capital letter.
Symbols are written with the following:
no full stop except at the end of a sentence;
as singular even though the written term is plural;
a space between the numerical value and the symbol, e.g. 12 m; 1.2
kg/m 3 and 0.12 rad;
in lower case unless the symbol has been taken from a proper name, e.g.
ampere is written as "A"; kelvin as "K"; and volt as "V";
in lower case unless the prefix is mega, giga, tera, peta or exa, e.g.
megawatt is written as MW; gigamole as Gmol and petahertz as PHz;
the product in a compound unit should be indicated by "." eg "N.m"; and
"cd.sr";
"." and "/" are only used with symbols and not with unit names written
in full eg m/s and not "metre/second"; and kW.s and not
"kilowatt.second"; and
when a unit involves the division of one symbol by another it can be
written in one of three ways eg "m/s"; "m.s-1"; and " m "
b. The combination of a prefix and a unit is written as one word, eg,
millimetre, microgram or nanosecond.
c. Prefixes are generally used in combination with the units so that, for
convenience, the number portion of the measurement is greater than 0.1
and usually below 1,000. For example, 0.005 grams is written as 5
milligrams or 5 mg.
d. When writing a numerical measurement, the symbol for the prefix is placed
in front of the symbol for the unit eg, ninety nine millimetres = 99 mm,
nine point nine micrograms = 9.9 mg and nine nanoseconds = 9 ns.
e. Where a compound unit has both a numerator and a denominator, any
prefix is preferably attached to the symbol in the numerator eg kJ/mol and
not J/mmol; and mA/mol and not A/kmol.
1.1.6
105
Pa (N/m2)
1.02
kgf/cm2
750
mmHg
1.02 x 104
mmwc
0.987
atm
14.504
psi
737.6 x 103
0.278
106
238.85
948.0
101.97 x 103
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Nm
k cal
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Btu
kg m
ft lb
kW h
Power:
1 MW = 106 Watt 1 MJ/ s
238.85 k cal/s
101.97 x 103
kg m/s
1360
metric hp
56880
Btu/min
238.85
k cal/kg
101.97 x 103
kg m/kg
334.55 x 103
ft lb/lb
429.92 x 103
Btu/lb
0.2388 Kcal/kgoC
0.2388 Btu/lboF
HP:
1 metric HP = 735.75 watt*
1 British HP = 746
Matter:
The Matter exists in three states:
Solid, Liquid and Vapour.
All matter comprises of atoms and molecules. The extent to which these
atoms are bonded to each other decides the state of the matter. As long as the
bonding force between the atoms is large, the matter remains Solid and retains
its shape and tends to oppose any cause, which tends to change its shape. This
is the reason that solids have the property of elasticity and are stressed if
strained. The Bonding Forces are of several types such as gravitational pull
between atoms and Covalent Bonds.
The atoms and molecules of any matter is in a constant state of random
vibrations and the vibrations amplitude increases with temperature of the
matter. Depending on temperature the Inter-atomic Distance varies and when
the Inter-atomic Distance is such that force of attraction between tow atoms
equals force of repulsion, a threshold state is reached when state of matter
changes from Solid to Liquid and the matter no longer exhibits the property
of elasticity and does not resist a change in its shape.
At a further higher temperature the atoms and molecules reach a state of
vibration when there exist no cohesive force between its atoms or molecules.
At such a temperature the matter changes its state from Liquid to Vapour.
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The temperature at which a solid matter changes its state to liquid is called its
Melting Point and the temperature at which the matter in Liquid state changes
to Vapour is called Boiling Point. These temperatures depend upon pressure.
To the extent that the three phases of matter relate to the subject of Boiler
Technology and Engineering, the reader is advised to recall that Water is
Solid when it is Ice. When heated, Ice (which is water in solid state) changes
its state to Liquid (Water) and when further heated, water changes to the third
state, which is vapour and called Steam.
Under atmospheric pressure Melting Point of Ice is 00C or 320F and Boiling
Point of Water is 1000C or 2120F. However, these points of temperature
depend on pressure. The change in melting point of ice is not relevant to
boilers and steam engines and turbines hence we will not deal with it further.
However, the boiling point of water varies greatly with its pressure.
This matter is covered in greater details under Properties of Steam in this
tutorial. The characteristics of change of state or phase of water to steam are
derived experimentally and are published by various renowned international
bodies (such as ASME) as Steam Tables.
It is considered relevant here to mention that in a boiler just above the surface
of water in the boiler drum, contains tiny particles of water which though
suspended above the surface of water in the drum, is not actually in vapour
state and needs to absorb heat in order to get converted into vapour or steam.
That is why the steam just above the water surface in boiler drums is called
wet steam. When each and every tiny water particle has got fully converted
into vapour or steam it is called dry saturated steam.
1.2.1
Mass:
Mass is a property of physical objects that, roughly speaking, measures the
amount of matter they contain.
Strictly speaking, there are three different quantities called mass:
Inertial mass is a measure of an object's inertia: its resistance to changing
its state of motion when a force is applied. An object with small inertial
mass changes its motion more readily, and an object with large inertial
mass does so less readily.
Passive gravitational mass is a measure of the strength of an object's
interaction with the gravitational field. Within the same gravitational field,
an object with a smaller passive gravitational mass experiences a smaller
force than an object with a larger passive gravitational mass. (This force is
called the weight of the object. In informal usage, the word "weight" is
often used synonymously with "mass", because the strength of the
gravitational field is roughly constant everywhere on the surface of the
Earth. In physics, the two terms are distinct: an object will have a larger
weight if it is placed in a stronger gravitational field, but its passive
gravitational mass remains unchanged.)
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1.2.2
Mole:
The mole is the amount of substance. The unit is call the mole (mol), and its
defined as the number of molecules present in 0.012 kilograms of carbon-12.
In other words, 1 mole of carbon-12 has a mass of 12 grams. 1 kmol = 103 mol
1.2.3
Volume:
Volume of gas or any substance is defined as the space, which it occupies.
Unit of volume of any substance is cubic centimeter or cubic meter.
The volume is also expressed in litre.
1 liter = 1000 cm3 =106 mm3 = 10-3 m3
1.2.4
Specific volume:
The specific volume of a substance is its volume per unit mass i.e m3/kg.
The unit of specific volume is m3/kg.
One kilogram of air at 00 C and under an absolute pressure of 1.0332 kg/cm2
(760 mm of Hg) has volume of 0.7734 m3.
Therefore the specific volume of air under these conditions is 0.7734 m3/kg. It
is denoted by v
1.2.5
1.2.6
Concentration:
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1.2.6.6 Percent
Percent (%) is also used to express concentration much the same as parts per
million (ppm). The difference is that percent relates to one in a hundred
compared to ppm, which relates to one in a million.
1.2.7
Pressure:
Pressure is defined as Force per Unit Area. Take a jar of glass with a flat
bottom, filled with water and keep it over a table. The weight of water in the
jar exerts a force on the surface of the table. If this force is measured over a
unit area of the surface, then it is called the pressure. Therefore pressure can
be defined as the force exerted by an object over the surface of unit Area.
i.e. pressure = force / area
In practice it is expressed or measured in following units:
N/m2
Kg/cm2
Lb/in2
bar (1 bar=105N/m2)
pascal (1Pascal= 1 N/m2)
height of liquid column (Normally water & Mercury)
1.2.8
Atmospheric Pressure:
The atmosphere, surrounding the earth, exerts a pressure on its surface
equivalent to the weight of air acting over unit area of the earth's surface and it
is known as atmospheric pressure. At sea level, the weight of air over a weight
of unit area of earths surface is equivalent to weight of a column of 76 cm
(760 mm) of mercury column (Hg) at 0 0C. It is taken as the standard
barometric pressure. This is also known as a physical atmosphere or
barometric atmosphere.
The density of mercury is 13. 595 grams per cubic centimeter
Therefore standard barometric pressure = 76 x 13. 595 = 1033. 32 grams / sq.
cm. i.e. 1.03322 kg/sq.cm
1 ata = 1 metric or technical atmosphere (1 kg/cm2 ab.) = 760 /1.0332 =735.6
mm of Hg
Pressure is also measured in the unit of mm of water column. One
Atmospheric pressure is equivalent to 760x13.595mm of water column. That
is 10332.2mm of water. This is 10.332 meter of water.
1kg/cm2 = 735.6mm of Hg = 735.6x13.595 = 10meter of water
We know that the atmosphere exerts pressure as mentioned. However, if we
take a pressure gauge in our hand, it reads Zero, even though the atmospheric
pressure is present. Thus pressure Gauge measures the pressure with reference
to Atmospheric pressure (Ref. Fig.-1). The pressure indicated by the gauge
above atmosphere is known as gauge
pressure. The pressure indicated by the
Pressure Gauge Reading
gauge Pressure
when the system pressure
is less than atmospheric is termed as
Absolute
Vacuum,
which
is generally
measured
inPressure
mm of water or mercury column
Gauge
= Atm. Pressure
+ Gauge
Pressure
and the gauges are known as vacuum gauges.
Atmospheric Pressure
1.0332 kg/cm2
Vacuum =
Atm. Pressure - Absolute Pressure
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Fig. 1
Thus the Absolute pressure = Atmospheric pressure + Gauge pressure
Pab
=
Pat
+ Pg
or
Absolute pressure = Atmospheric pressure Vacuum
Pab
=
Pat
- Vacuum
1.2.9
Barometer:
The barometer is the simplest instrument for measuring atmospheric pressure.
The earth's atmosphere at sea level has a weight of 14.7 pounds over a square
inch of surface. This is the weight of a column of air that extends from sea
level at the earth's surface to the edge of the atmosphere. This weight changes
as the temperature and composition of the air mass changes. A barometer uses
a substitute column of mercury fluid in place of the air. One atmosphere in a
mercury barometer is equaled by a column of only 760 mm Hg.
h = 760 mm of
Hg
A simple Mercury
Barometer
Fig.2
1.2.10 Manometer:
The manometer is one of the simplest tools for measuring gas pressure
differences. A manometer is a u-tube. One side of the "U" is open to
atmosphere and the other side is connected to a closed container. The "U" is
filled with a fluid. If both sides of the "U" have the same liquid levels then the
pressure inside and the pressure outside are the same. The difference between
the liquid levels equals the pressure difference between inside and outside.
The mercury level will be lower on the side with greater pressure. The higher
pressure "pushes" the mercury down. The Manometer measures the Gauge
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G
AS
GAS
Fig-3
h
GAS
G
AS
Manometer
1.2.11.2
Boyle's Law
Boyle's Law states the volume of a definite quantity of dry gas is inversely
proportional to the pressure, provided the temperature remains constant.
Mathematically Boyle's law can be expressed as P1V1 = P2V2
V1 is the original volume
V2 is the new volume
P1 is original pressure
P2 is the new pressure
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1.2.11.3
Charles's Law
Charles's Law can be stated as the volume occupied by any sample of gas at a
constant pressure is directly proportional to the absolute temperature.
V / T =constant
V is the volume
T is the absolute temperature (measured in Kelvin)
Charles's Law can be rearranged into two other useful equations.
V1 / T1 = V2 / T2 & V2 = V1 (T2 / T1)
V1 is the initial volume
T1 is the initial temperature
V2 is the final volume
T2 is the final temperature
Charles's Law only works when the pressure is constant.
Note: Charles's Law is fairly accurate but gases tend to deviate from it at very
high and low pressures.
1.2.11.4
NTP
NTP stands for Normal Temperature and Pressure. NTP is 0o Celcius and 1
atmospheric pressure. Gases properties can be compared using NTP as a
reference.
1.2.11.5
Combined Law
The combined gas law is a combination of Boyle's Law and Charles's Law;
hence its name the combined gas law. In the combined gas law, the volume of
gas is directly proportional to the absolute temperature and inversely
proportional to the pressure.
This can be written as PV / T = constant.
Therefore we can write P1V1 / T1 = P2V2 / T2.
P1 is the initial pressure
V1 is the initial volume
T1 is the initial temperature (in Kelvin)
P2 is the final pressure
V2 is the final volume
T2 is the final temperature (in Kelvin)
Also Vt = V0 { 1 + t / 273 }.
Where V0 is the volume at 00C andt is the temperature in 0C
1.2.11.6
Ideal Gas Law
The ideal gas law is a combination of all the gas laws. The ideal gas law can
be expressed as PV = mRsT.
P is the pressure in atm
V is the volume in liters
m is the mass of the gas considered
Rs is a constant
T is the temperature in Kelvin
This equation is known as Characteristic equation of a gas.
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Temperature:
Temperature is the measure of the relative warmth or coolness of an object.
The temperature of a substance does not measure its heat content but rather
the average kinetic energy of its molecules resulting from their motions. A
one-pound block of iron and a two-pound block of iron at the same
temperature do not have the same heat content. Because they are at the same
temperature the average kinetic energy of the molecules is the same; however,
the two-pound block has more molecules than the one-pound block and thus
has greater heat energy.
For measurement of Temperature there are two scales of measurements, one is
Fahrenheit and the other is Centigrade or Celsius. The arbitrary
reference taken is the freezing point of water under atmospheric conditions.
This point at which water freezes to a solid state is considered as ZERO in
Celsius or Centigrade Scale. Again the point of reference of water boiling at
atmospheric condition and transforming to vapor stage is taken as 100 in
Celsius or Centigrade Scale. In the Fahrenheit Scale the point corresponding
to temperature at freezing of water is taken as 32, for water boiling point as
212
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1.3.2 Thermometer:
An instrument used for measuring temperature is called a thermometer and is
constructed by using one of the following principles:
the change of length, such as length of a mercury column,
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1.3.2.1 Glass Bulb (Mercury thermometer): Most common for measuring air
temperature is the liquid-in-glass thermometer, which consists of a glass tube
enlarged at the bottom into a bulb that is partially filled with mercury(or
organic liquid). The tube's bore is extremely smallless than 0.02 inch (0.5
millimeter) in diameter. Thus a small amount of expansion or contraction of
the mercury in the bulb, caused by heating or cooling, produces a noticeable
rise or fall in its level in the tube.
1.3.2.2 Bimetal thermometer: Two different metals are bonded together with one
end attached to an indicating needle which aligns with a circular scale on the
face of the instrument. Since the metals expand at different rates, movement
occurs depending on the temperature fluctuation and the needle moves.
1.3.2.3 Indicating Material: A variety of crayons and pellets are available that
melt at specific temperatures. These do not really measure temperature
directly, but do indicate the maximum temperature that a material was
exposed to.
1.3.2.4 Vapor/Gas Filled: Such thermometer operates on a similar principle to the
glass bulb type thermometer.
1.3.2.5 Galileo thermometer: These tend to be used in decorative settings around
the home or office. These interesting models operate based on principles of
specific gravity.
1.3.2.6 RTD and Thermistor: These are based on the change in resistance of a
conductor when the temperature of the wire changes. In both the instruments
temperatures are digitally displayed and have better accuracies.
1.3.2.7 Thermocouple: These operate based on the temperature change that occurs
at the junction of two dissimilar wires. When the temperature changes a small
current is generated by the junction. This current is then compared to a
reference junction (calibrated standard or ice water bath) and converted to a
temperature by electric or electronic means. So the system includes the
thermocouple itself, connecting wiring and some method (Generally a digital
meter) to display the temperature reading.
Another significant advantage of the thermocouple is that the indicating
instrument can be a very long distance from the thermocouple environment.
Once the system is calibrated and the current from the thermocouple is
captured, a variety of electrical options are available for getting the
information to a display unit.
1.3.3 Pyrometer: It is a non-contacting device intercepting and measuring thermal
radiation emitted from an object to determine surface temperature. Pyrometer
is derived from the Greek word pyro, meaning fire.
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The temperature of a material, affects the color. The infrared light spectrum
works very well for this and is the basis for the infrared thermometer or
pyrometer. These units do not require a contact with the material and are
available as hand held units. They can sense a very high range of
temperatures.
Some applications of pyrometers
Item
Instrument used to measure temperature
Boiler combustion space
Optical pyrometer
Economiser, feed water heaters and Base metal thermo-couple
chimney gases
Incandescent filaments
Optical pyrometer
Incandescent gas mantels
Radiation pyrometer
1.4
Work:
If a heavy mass is to be moved from one place to other, one has to apply force
or spend energy. The Force applied to a body multiplied by the distance
moved is the amount of work done or amount of energy spent.
Work = Force x distance (traveled in the direction of force)
Work only involves the useful part of a force, namely the part that is effective
in causing the motion.
[Suppose a pail of water weighing 7 N is carried over a distance of 10 m. In
order to hold the pail up against gravity a vertical force of 7 N is exerted on
the pail. The motion, however, is horizontal, and the force exerted does no
work, even though one might get tired of holding the pail after a while.]
In SI system, the unit for work done is Newton-metre (Nm), which is the
product of a unit force (one Newton) acting through a 1-metre distance. This
unit of work done is also called joules (J).
1 J = 1 Nm
1 kg.m = 9.81 Nm = 9.81 Joules (J)
Work can also be measured in foot pounds or Kg metres
1.5 Power:
Suppose a weight is lifted off the floor at a fixed a distance. The work done in
this case would be the product of the force exerted times the distance covered,
independent of how fast the weight was lifted. Now if the same weight is
lifted faster that is in lesser period, then one might be tempted to say that more
``work'' is done. Actually the work done in both the cases is same and it is the
Power that is different.
The power exerted by a force is defined as change in work done over a period.
Power exerted = work / time = force x distance / time = force x velocity.
The SI Unit for Power is Watt. In other words Jules/sec = Watt.
In British Units the Unit of Power is Horse Power or HP, which
corresponds to a rate of work of 550 ft-lb/sec or 1 British HP = 746 Watts.
But unless and other wise mentioned, HP should be considered as Metric HP
1 Metric HP = 75 kg m/ s = 735.75 Watts.
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1.6
Energy:
In mechanics is defined as capacity of doing work. Units of Energy and
Work are same. Energy exists in two forms, namely, Potential Energy and
Kinetic Energy.
1.6.1 Potential Energy is possessed by a body due to its position relative to
other body or of parts of the same body under the action of a force or forces
tending to alter their relative position. For example, a body which is allowed
to fall towards earth may be made to do work; hence before it begins to fall it
possesses potential energy, or energy due to its position relative to earth.
PE=mg
h
h Gravitational
Potential
Energy
PE=0
Fig 4
Kinetic Energy of a body is due to its being in motion with respect to another
body. A kilogram of water at rest at a height of 100 metres above level of the
sea possesses 100 kg.m of potential energy and if this water is allowed to fall
freely to the level of the sea, without doing work on the way it will in every
position of its fall possess 100 kg.m of energy, but as it descends its potential
energy will diminish, and the remainder of 100 kg.m will be stored in water as
kinetic energy. When the 1kg of water would have fallen 25 metres its
potential energy would be reduced by 25 kg.m to be only 75 kg.m and its
kinetic energy would then be 25 kg.m so that total is 75 kg.m (Potential
Energy) + 25 kg.m (Kinetic Energy) = 100 kg.m.
A body of weight w kg, moving with a velocity v possesses a certain
amount of kinetic energy (KE) with reference to earth gravitational force,
K.E = w. v2/2g.
The unit of K.E. is also kg.m in MKS and Newton metre in SIS.
Other forms of energy are also different manifestations of these two forms.
For example Electricity stored in a Capacitor having a Capacitance of C
Farads and charged to a Voltage of V Volts is a Potential Energy and its value
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1.8
Torque:
Torque is a measure of the 'strength' being used in turning (or attempting to
turn) something.
A common example is that of a spanner being used to move a nut. A force is
being applied at one end of the spanner. That force is multiplied by the
distance between it and the turning-point (which, in this case, is the centre of
the nut) to give a measure of the torque which is being applied. This seems to
be the same as for work which is also a force being multiplied by a distance
but look closely, in the definition for torque there is no mention of the force
moving as there is in the full definition for work.
So, they are different things even though the units are the same, and no work
is done until, in this case, the spanner moves - and even then it is a matter of
how far the force moves, and not its distance from the centre.
The SI preferred unit for torque is newton metres [Nm] and for work is
joules [J].
1.9
Specific Energy :
This is a measure of the amount of energy contained in a unit quantity of some
substance. The unit quantity may be either of mass or of volume. For unit
mass, usually referred to as Specific Energy, Its units are [J/kg] or [kJ/kg]
For unit volume, usually referred to as Calorific Value, units such as [kJ/m]
or [MJ/m]. should be used .
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of the fuel used is converted into the work done by the engine. When the
brakes are applied to the wheels of a moving train, in order to bring it to rest,
the kinetic energy of the train is converted into heat at the rubbing surfaces of
the brake blocks and wheels, or if the wheels skid the heat is produced at the
rubbing surfaces of wheels and rails. Careful experiments have shown that a
certain definite number J or foot pound of work is equivalent to one unit of
heat.
In British Units J is 778 ft.lb. for 1 Btu.
and in metric units, 4.187 Kilojoules = 1 Kilocalories &
1 Kilocalories = 427 kg-m
1.11
1.11.1 Heat
Heat is believed to be a mode of motion. It is supposed that a body
possessing heat has its particles or molecules in a state of motion, the rate of
motion increasing as the body gets warmer and diminishing as the body cools.
As to the character of motion of the molecules it may be imagined to be an
oscillatory motion in the case of solids and liquids, but in the case of gases it
is supposed to be a motion of translation.
It is found that all the phenomenon of Heat may be explained by this theory.
For example, it is well known that in general the effect of heat on matter is to
enlarge it. A piece of iron when heated gets longer, wider and thicker (due to
thermal expansion). Now it is natural to expect that if the molecule of iron
have more motion as the iron gets hotter they will require more room and will
therefore push one another further apart and consequently cause the whole
body to get larger, just as a crowd of people take up more space when they
jostle one another than they do when standing still or when jostling to a less
extent.
For the purpose of explaining how heat is transmitted through space the latter
is supposed to be filled or permeated with an invisible imponderable (and
imaginary) fluid called the ether which takes up the motion of the molecules
of a body and transmits them to the molecules of other bodies in space, just as
when a body is made to move up and down in a trough of water a similar
motion is given to a cork floating in the water at the same distance.
Different units of measurement of heat are as given bellow.
In British System:
British Thermal Unit (BTU):
The quantity of heat required to raise the temperature of one pound of water
through 1F is defined as a BTU.
In MKS Units:
Centigrade Heat Unit (CHU):
The quantity of heat required to raise the temperature of one pound of water
through 1C is defined as a CHU.
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The unit of specific heat in MKS System of units is kcal/kg 0C and in the SI
system of units it is kJ/ kg K.
1.11.2.3 Ratio of specific heats: The ratio of two specific heats, C p and Cv of any
given gas is assumed to be constant. It is expressed by the symbol
(gamma). It is called Gas Constant and is an universal constant for ideal
gases. It has no units for measurement.
= Cp/Cv
For air, Cp = 0.24 kcal/kg 0C or 1.0035 kJ/ kg 0K
and
Cv = 0.172 kcal/kg 0C or 0.7165 kJ/kg 0K
hence, = 0.24/0.172 = 1.4
1.11.3 Enthalpy (H) or Total Heat or Heat Content: Enthalpy is nothing but total
heat energy content in a substance. It is denoted by H and is defined as
follows:
H = E + (PV/J) kcal
Where, E is the Internal Energy, P is the Absolute Pressure, V is the Volume
in m3 and J = 427 kg-m.
1.11.4 HEAT TRANSFER:
In Boiler heat energy is released from the combustion of fossil fuels and the
heat is transferred to different fluids in the system and a part of it is lost or left
out as unutilized. It is therefore essential to study the general principle of heat
transfer for understanding the behaviour of boiler in relation to heat transfer
during different conditions of operation.
Let us take an example of a kettle of water being heated under fire. When fire
is applied the water in the kettle gets heated. Heat to water is passed through
the metal wall of the kettle. Now remove fire. The water in the kettle cools
down. The heat is now given to the air which surrounds the kettle.
In this process the heat is transferred from fire to kettle then to the water. On
cooling the transfer has taken place from water to kettle and from kettle to
surrounding air. The transfer of heat first has taken by way of Conduction
within the Kettle walls and then heat by the process of Convection transferred
to water in centre of the Kettle from the water immediately in contact with
walls of the kettle. When the fire is put out, the water started cooling down as
transfer of heat in water occurs by Convection from centre of the Kettle to the
water layer immediately in contact with Kettle walls and by Conduction
within walls of the Kettle. Outer surface of the Kettle transfers heat to the
surroundings by way of Convection & Radiation.
.
In Boiler generally the heat transfer takes place in all the three modes of heat
transfer process namely Conduction, Convection and the Radiation.
1.11.4.1 Conduction:
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Conduction is the process of transfer of heat through solids from one part of
the body to the other, by physical contact, without the molecules moving, but
imparting vibration from one molecule to the neighbouring one.
In a Boiler the water tubes are exposed to fire. The heat travels by Conduction
from outer surface to inner surface of water tubes and then transfers to water
at centre of the tubes and in the drum from the water immediately in contact
with inner surface of the tubes by convection. In a metal the heat transfer
takes place by passing on heat from particle to particle by contact without any
physical movement of the particles themselves.
The quantity of heat conducted depends on:
a. the differential temperature between combustion chamber and the water
inside the tube,
b. the thickness of the tube,
c. surface area of the tube,
d. the characteristics of the metal and
e. the cleanliness of the surface.
1.11.4.2 Convection:
This process can occur only in fluids or gases. This process of heat transfer
takes place when the molecules are displaced physically. The fluid or gas
when heated expands, becomes less dense and raises up causing movement
and allowing the colder and more dense gas or liquid to replace it. In the
Boiler the heat from tube metal goes to water flowing inside. Similarly when
gas or liquid is heated, it expands, becomes less dense and rises up causing
movement and allowing the colder and denser gas or liquid to replace it.
Mainly in Superheater, Reheater and Economizer the heat from hot gas is
getting transferred to metal outer surface by way of convection process.
Heat transfer by convection depends on the specific characteristics of the
medium i.e. gas or liquid.
1.11.4.3 Radiation:
Heat when it travels from source to another substance through an empty space
(often imagined as ether) or through vacuum or gas or air in straight lines, the
process of heat transfer is called radiation. The tube metal surface at the top of
the furnace of a Boiler gets heat by way of radiation. We get heat from Sun by
radiation.
All substances emit heat energy by radiation depending on their temperature.
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Examples
1. Question: Defined absolute temperature scale
(Feb-88, Aug-89)
Answer:
Absolute temperature is expressed by the capital latter K and at this scale the
freezing point of water (0C) is 273 K, and the boiling point of water (100C), is
373K, respectively.
2. Question: The temperature of water while entering an economiser is 20C, while
leaving the economiser is 80C. If the rate of flow of water is 500 kg per minute,
how much quantity of heat is supplied in the economiser? Specific heat of water
may be taken as 4.182 kJ/ kg.
Answer:
Quantity of water flowing m = 500 kg/minute
Rise in temperature of circulating water t = 80 20 = 60C.
Specific heat of water CP = 4.182 kJ/kg
Therefore, quantity of heat supplied to water in the economiser per minute
mCP t = 500 x 4.182 x 60 = 125460 kJ/minute i.e. 125.46 MJ/minute.
3.
Question: A certain gas occupies 3 cubic metres at a temperature of 150C.
The pressure of the gas is 7 bar. The gas expands in such a manner that the volume
becomes 9 cu metre and the temperature is 10C. What is the pressure of the gas?
Answer:
Considering the pressure given in absolute,
P1 = 7 bar Ab.; V1 = 3 cu meter; V2 = 9 cu meter
T1 = 150 + 273 = 423 K and
T2 = 273 + 10 = 283 K
Using the relation P1V1/ T1 = P2V2/ T2
or, (7 x 3) / 423 = P2 x 9 / 283
Or
P2 = 1.561 bar Ab.
4. Question: The compression ratio of an engine is 12 to 1, the pressure at the
commencement of the compression stroke is 100 kN/m 2 and the temperature 115C.
Calculate the absolute pressure at the end of compression stroke if the temperature
has then risen to 180C.
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Answer:
From the relation
P1V1/ T1 = P2V2/ T2
We have,
P1 = 100 kN/m2 (considering pressure given in Absolute);
T1 = 115 + 273 = 388 K; T2 = 180 + 273 = 453 K
V2 = V1/12
On substitution of values, we get
100 x V1/ 388 = P2 x V1/ (12 x 453)
or P2 = 1401 kN/m2 (14.01 bar) absolute
5. Question: Calculate the molecular volume of all gases at 200 kN/ m2 and 30C.
According to the characteristic equation of a gas we have pV = mRT where p is the
pressure of the gas in N/m2, V is the volume of mass m kg of gas in cu metre, R is
the characteristic gas constant and T is the absolute temperature of the gas in
Kelvin.
Answer:
If m is the molecular mass, then V will be molecular volume of the gas and
mR = 8.3143 kJ/ kg mole K
We have, P = 200 kN/ m2; T = 273 + 30 = 303 K
Therefore, 200 x V = 8.3143 x 303
V = (8.3143 x 303) / 200 =12.596 m3
6. Question: A steel cylinder of 77 litres of capacity contains CO 2 at 27 Deg. C and
pressure of 110 ata. Calculate the weight of gas contained in the steel cylinder.
Solution: Here,
Volume = 77 liters = 77 x 10-3 m3
Pressure = 110 ata = 110 kg/cm2 ab = 110 x 0.981 = 107.91 bar ab.
= 107.91 x 102 kN/ m2
Temperature = 27o C = 27 + 273 = 300 K
We know MR = 8.3143 kJ/kg mol K and M of CO2 = 44 kg
Sp. Gas constant R of CO2 = 8.3143/44 = 0.189 kJ/ kg K
From the relation PV = mRT,
107.91 x 102 x 77 x 10-3 = m x 0.189 x 300
or, m = (107.91 x 102 x 77 x 10-3)/ (0.189 x 300) = 14.65 kg
7. Question: Define a new temperature scale, say oD in which the boiling and
freezing points of water are 300oD and 100oD respectively. Correlate this scale with
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the Centigrade scale. The oD reading on this scale is a certain number of degrees on
a corresponding absolute temperature scale. What is this absolute temperature at
o
D?
Solution: Here, the freezing point and the boiling point are 100 oD and 300oD
respectively.
Comparing it with centigrade scale, we see a rise of 100 oC (100oC 0oC) will be
equal to a rise of 200oD (300oD 100oD) in the new scale.
So for every 1o rise in the centigrade scale, there will be 2o rise in the new scale.
Again 0oC = 100oD
Therefore the relation between these two scales will be
D = 100 + 2C
For example 25oC will read in the new scale as 100 + 2 25 = 150oD
We can write the above relation as C = (D-100)/ 2
In absolute scale, any reading in the new scale will read as (D-100)/ 2 + 273
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7. Question: A body weights 50kg on earth. Find its weight on the (a) Moon where
gravitational acceleration is 1.7M/sec2 (b) Sun where gravitational acceleration is
270 M/sec2
8. Question: A thermometer immersed in fluid the value of temperature in F and C
shows same what will be value of temp.? Express this value of temp. in deg.R &
deg.K.
9. Question: A vacuum gauges reads the vacuum in a chamber as 300 MM of Hg,
what is the absolute pressure in the chamber if the atmospheric pressure is 760 mm
of Hg. The specific weight of mercury at this temp. is 13550 kg/M3
(Feb.91).
10. Question: A manometer joined to a gas cylinder indicates 20 kPa, while the
barometer reads 760 mm of mercury. What will be the reading of the manometer if
the barometric pressure drops to 730 mm mercury?
11. Question: A steam power plant develops 4460 kW. What is the equivalent of
this power in thermal unit?
12. Question: The gas used in gas engine trial was tested in a Boys calorimeter.
The pressure of gas supply was 70 mm of water column. What is the absolute
pressure of the gas if the barometric pressure is 760 mm of mercury?
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APPENDIX
HEAT TRANSFER CALCULATIONS
The general equation for heat flow rate by any of the above three modes of
heat transfer from one media to other may be written as
q = US t
Where q = heat flow rate in K.Cal/hr
S = Surface area involved in the heat transfer in m2
t = Temperature difference causing heat flow in C
U = Overall heat transfer coefficient in K.cal/m2/hr/C
= 1/R where R is overall resistance
Conduction:
If a flat plate is heated on one side and cooled on other side, heat will flow
from hot side to the cold. The heat flow rate q can be expressed as below:
q = KS (t1 t2) / l
Where q = rate of heat flow K.Cal/hr
K = Thermal conductivity for 1 cm thickness K.cal/m2/hr/C
S = Heating surface in m2
t = temperature difference causing heat flow (t1 t2) in C
l = length or thickness of the plate in cm.
K/l is expressed as conductance and hence l/K is the resistivity.
Convection:
Heat transfer by convection between a fluid and a solid such as in a boiler
tube is expressed as below:
qc = Uc S t
.. (3)
Where qc = rate of heat flow by convection in K.Cal/hr
U = Convection film conductance in K.cal/m2/hr/C
S = heat transfer surface in m2
t = temperature difference between fluid bulk temperature
and solid surface temperature in C.
Radiation:
Radiation emitted by a body depends upon its surface area and temperature.
The relationship between them is given by Stefan-Boltzman law
q = S T4
q rate of heat flow
Stefan-Boltzman constant
S surface area of body
T absolute temperature of the emitter
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For bodies other than black bodies whose emissivity will be less than 1, the
formula will be changed as
q = ES T4
where E is emissivity of the body
If we consider two parallel planes of infinite size and they are black bodies,
then heat transfer from the hot plane (at T 1 K) to the other plane (at T 2 K) is
given by the formula
q = S (T14 T24)
If all the radiation emitted by one does not fall on the other it is essential to
introduce an angle factor in the formula
In boiler the radiation becomes luminous by entrained particles such as
pulverised coal, soot etc. and calculation of luminous radiation is complex.
The gases such as oxygen and nitrogen absorbs or emit only slight amount of
radiation. But water vapours, carbon dioxide, sulphur dioxide and carbon
monoxide which are part of flue gases in the boiler also absorb and emit. They
emit and radiate only in certain wave length bands that lie outside of the
visible range and are called as non-luminous gas radiation.
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Example:6 A steel pipe 3.4 meters long with an outside diameter of 31.75 mm and
thickness of 5.25 mm. If density of materials is 7.6 gm/ cc. Find out the mass of
pipe.
Solution: Here
Length of pipe = 3.4 m = 340 cm
Outside diameter of pipe = D = 31.75 mm = 3.175 cm
Thickness of pipe = 5.25 mm
Inside diameter of pipe d = 31.75 2 5.25 = 21.25 mm = 2.125 cm.
Volume of pipe material = (/4) L (D2 - d2) = (/4) 340 (3.1752 2.1252)
= 1486.05 cm3
Density of the material = 7.60 g/ cc
Mass of the pipe = 1486.05 7.60 = 11293.98 g = 11.294 kg
Example:7 A horizontal return tabular boiler is 180 cm in diameter and 600 cm
long contains 75 tubes of 75 mm OD 70 mm ID. Find the boiler heating surface
area, where heat transfer may be taken as inner surface area of all tubes, half the
area of boiler shell and 2/3rd of the tube plates less the area of the tube holes.
(Aug 1999)
Solution:
Given,
Length of the shell ( L )= 600cms = 6.0 m
Dia of shell (D) = 180cms = 1.8 m
I D of tube (DI) = 70 mm = 0.07 m
O D of tubes = 75 mm = 0.075 m
No.of tubes = 75
Now Inner heating surface area of 75 no. of tubes S1 = 75 0.07 6
= 98.96 m2
Half surface area of shell ( heating surface area of shell cylindrical portion) S2
= 1.8 6 = 16.96 m 2
Area of tube plate S3 (2 nos in case of horizontal return tubular boiler)
= 2 2/3 [( /4) 1.802 75 ( /4)(0.075)2]
=2.951 m2
Total heating surface area = S1 + S2 + S3 = 98.96 + 16.96 + 2.951 = 118.871 m2
Example:8 An immersion heater of 1500 watt is immersed in 200 kg of water. If no
heat loss is assumed, find the time taken to heat the water from 30 deg. C to 80 deg.
C. Find also the units of electricity consumed.
Solution: Given, Heater capacity = 1500 Watt = 1.5 kW = 1.5 kJ/ sec
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Power of a pump:
The power of a pump driven by steam, water or air is to be found out as under.
We know that Power = rate of work done, where work = force distance, where
force = Pressure area
In a pump, the piston is driven by the working substance (i.e. steam or water or
air) under a pressure through the length of the cylinder.
Therefore the force acting on the piston with an area A, driven by the working
substance under a pressure P = P A.
Now the work done by the piston while it moves through the length of the cylinder L
in a single stroke = force distance = P A L
If the pump makes N working strokes per minute, then the power of the pump = the
rate of work done per minute = P A L N
In SI units, if P is in N/ m2, L is in m, A is in m2 and N is in number of the strokes per
minute, then rate of work done P A L N will be in N m2 m = N-m/ min
m2 min
= J/ min = J/ 60 sec = W/60 (J/ sec = Watt)
So we can see that the above relation when expressed as P A L N/ 60 will give
us the power of the pump in Watt. If P is taken in kN/ m2, then the result will be in
kW.
To find out the horse power of a pump, we can find out the power in Watt and then
find out the HP from the relation 1 HP = 735.75 Watt.
Alternatively we know that 1 HP = 75 kg-m/ sec.
Now if the pressure P is taken in kg/ cm2, Length L in m, area A in cm2 and N is in
number of strokes per minute, then rate of work done P A L N/ 60 will be in
kg cm2 m = kg-m/ sec
cm2 sec
So we can see that the above relation when expressed as P A L N/ (60 75) or
P A L N/ 4500 will give us the power of the pump in HP. (as 1 HP = 75 kg-m/
sec)
[Unless HP is asked, while finding out the power of a pump or an engine, always
work out in SI unit and find out the power in Watt or kilo Watt]
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Example:9 What is the horse power developed in a simple steam pump cylinder
200 mm diameter 300 mm stroke, with pump making 50 working strokes per
minute, with steam pressure 7 kg/cm2 g.
( Feb.1988)
Solution: Given,
Dia. of piston = 200 mm = 20 cm.
Length of stroke =300 mm = 0.30 m
N =50 strokes /min.
Pressure P = 7 kg/ cm2
We know HP = P A L N / 4500
Here area A = d2/ 4 = 202/ 4 = 314.16 cm2
HP = 7 314.16 0.30 50/ 4500 = 7.33 HP
Example:10 Find the HP at the shaft of the pump required to lift 50000 lit. of water
per hour through a total head of 100 meter. The efficiency of the pump is 60%.Find
the HP of the motor which driven a pump, if the efficiency of the motor is 80%.
(Feb 1988)
Solution:
Here pump discharge Q = 50000 l/ hr = 50 m3/ hr
= 50/ 3600 = 0.0139 m3/ s,
H = h = 100 1000 = 105kg/ m2
Pump eff. Pump = 60%
HP at the shaft of the pump = HQ/ 75 Pump
= (0.0139 105)/(75 0.60) = 30.89 HP
since motor eff. motor = 80%
HP of motor = 30.89/ 0.80 = 38.61 HP
Example:11 1360 Litres of water is pumped into tank per minute under pressure of
1.41 kg/cm2 by pump. Find the H.P. required for pumping the water. Assume no
loss and pump efficiency is 85%.
Solution: Here,
Q = 1360 litres/minute = 1.36 m3/ min = 1.36/ 60 = 0.023 m3/sec.
H = 1.41 kg/cm2 = 1.41 104 kg/ m2
= 85 %
H.P. = (Q H) / 75 = (0.023 1.41 104) / 75 0.85 = 5.09
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Example:12 Determine the work in forcing 5 litres of water into a vessel against a
pressure of 1.2 MN / m2.
Solution: As we know,
Work = Quantity of water in m3 pressure in N/ m2
Given, 5 litres of water = 0.005 m3 & Pressure = 1.2 MN/m2 = 1.2 106 N / m2
Work = 0.005 1.2 106 = 6000 N-m
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deg.C. The temp. of the surrounding is 25 deg. C and the loss from the lagging
surface is 12 Kcal / m2 .hr deg.C. Calculate the loss in Kcal per meter length of the
pipe. The heat loss through an insulated pipe per meter length is given by
(T1-T2)
Q =2K
Log e (r2/r1)
Case I
When trains moving in the opposite direction
V= relative velocity = 80 + 45 = 125 km/hr. = 34.722 m/sec.
S = Distance to be traveled = 125 + 80 = 205 m.
Using the relation, S = Vt
34.722 t = 205,
t = 205 /34.722 = 5.90 sec.
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Case II
When trains moving in the same direction.
V= relative velocity = 80 - 45 = 35 km/hr. = 9.722 mt/sec.
S = Distance to be traveled = 125 + 80 = 205 mt.
Using the relation, S = Vt
9.722 t = 205
t = 205 /9.722 = 21.09 sec.
Case - III
When train Y standing on station.
V = relative velocity = 80 + 0 = 80 km/hr. = 22.22 m/sec.
S = Distance to be traveled = 125 + 80 = 205 mt.
Using the relation, S = Vt , 22.22 t = 205
t = 205 / 22.22 = 9.23 seconds
Example:16 Two trains whose lengths are 100 m and 50 m respectively are
moving on parallel tracks and take 5 seconds to cross each other completely. If the
shorter train is moving with double the speed of the longer one find the speed of the
train.
(i)
When bath the trains are moving in the same direction.
(ii)
When the trains are moving in opposite direction.
Solution: Here,
Length of Train A = 100 m.
Length of Train B = 50 m
Let speed of train `A is x m/sec
Speed of train `B = 2 x m/sec
Case I
When both Trains are moving in same direction, then relative velocity of train `B
= 2x x = x m/sec
To cross the train `A, distance is required to be traveled by train B = 100 + 50 =
150 m
From the relation S = Vt
150 = x 5, or x = 150/ 5 = 30 m/ sec.
Speed of train A = 30 m/ sec.
And speed of train B = 60 m/ sec
Case II
When both Trains are moving in the opoosite direction, then relative velocity of
train `B = 2x + x = 3x m/sec
To cross the train `A, distance is required to be traveled by train B = 100 + 50 =
150 m
From the relation S = Vt
150 = 3x 5, or x = 150/ 15 = 10 m/ sec.
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We know that, v = u + ft
Therefore the time taken by train A to attain its final speed is
tA = vA/ fA = 6.9446 = 41.66 sec and
at a distance SA = 6.94441.66/2 = 144.64 m
Similarly, the time taken by train B to attain its final speed
tB = 13.8883 = 41.66 sec and SB = 13.88841.66/2 = 289.28 m
Let us consider the time T = 0, when train A starts from the station. It reaches its
final speed when T = 41.66 s and at time T=81.66 sec the train B reaches its final
speed.
By the time train B reaches its final speed, the train A moves [144.64(during 41.66
sec) + 6.94440 (during 40 sec at cont. speed)] = 422.40 m away from the station.
Position of both the train at T= 81.66 sec is
422.4 m
A
B
289.28 m
133.12 m
Train B is 133.12 m behind the train A and both the trains are traveling at their
corresponding uniform speed.
Let us assume they meet at a distance after time t,
The relative speed of train B with respect to train A will be 13.888 6.944
= 6.944 m/ s.
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Example: 7
A feed pump supplies 135 m/hr feed water to a boiler at a pressure of 135 bar. The
pump is operated by an electrical motor of 90% & pump is operated at 83%
efficiency. Determine the power required to drive the pump. If the cost of electricity
is 4.5 Rs./ kWH. Calculate the total cost of power for running feed pump for 24 hrs.
(2004)
Example: 8
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A feed water tank is 10 meter in dia. and 15 meter in height is supplying water to
boiler through a deaerator 5 meter dia. & 5 long, both ends hemispherical. If the
water level in feed tank remains full & in deaerator at half level, what is the
quantity of feed water in storage of both? If a boiler of 15 MT/ hr is running on this
system with 10 MT/ hr extraction condensing plant & if condenser extraction pump
is supplying water directly to deaerator, how much time plant can be operated
safely if DM supply is totally stopped.
(2005)
Example: 9
(a) A force fan supplies air to the furnace of the boiler at the head of 40mm water
column. Determine the absolute pressure of the air supply if the barometric reading
is 760 mmHg.
(b) A pump delivers 1200 liters of water per hour against constant head of 328 ft.
Calculate the work done per hour in heat unit.
(2006)
Example: 10
A 10cm lever loaded safety valve is fitted on super heater steam outlet pipeline. If
boiler drum pressure is 10.15 bar & pressure drop from drum to superheater is 2
bar. The center line of dead weight is 60 cm. center line of valve is 10 cm & center
line of lever is 20 cm from fulcrum respectively if the weight of lever is 2 kg &
combined weight of spindle & valve is 1 kg. To find the dead weight required to
control the pressure.
(2007)
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