Bi tp phn: CC HIN TNG B MT V HP PH.

1.
o


o
) m / N ( 10 . 96 , 71
3
O H
2

= o ; ) ml / g ( 1 d
O H
2
= (/S: 44 )
2. T o x 9K o
q :
- K o q P
max
=11,82.10
2
(N/m
2
)
- Khi cho khn q P
max
=701,5 (N/m
2
)
o
o
=72,5.10
-3
(N/m).
/S: 4 d/
3. T o S
o
= 1000m
2
/ x
o

3

4 o
3
o
8
cm

3
x o o o q 4 /S: 4
4. T - 9K d d 48 /
o eo : o = 72,6.10
3
16,7.10
3
ln(1+21,5.C) N/m.
/S:
-6
mol/m
3

5. Tnh xe d 8 o o q 4
-2

xe /cm
3
. /S: d/
6. T o o q
-2

1,2cm. K 13,6 g/cm
3
/S: 489,6 dyn/cm
7. d d e =M o o o d d S
=M o o o d d
=4M eo L o
e d W=
2 o
) A ( . /S: S
r
=1170 cm
2
/g
8. T x 9 K, d d
C=0,1 mol/l , o eo o =75,5.10-3 -16,7.10-3 ln(1+21,5).
S:
-6
mol/g
9.
2
trn silicagel sau:
P/P
o
0,055 0,061 0,077 0,095
V(cm
3
.lg.10
-3
) 0,1313 0,1343 0,1399 0,1489
x ng S
BET
PT ET () S
BET
=4,38 V
m

S: 4
2
/g, C = 166
10. Se d d eo Fed =8; /= (
o/ d d o/) o e o d d M
d d o ?
S: 4M
11. T=278
0
K sc cng b mt ca nc o=75,41.10
-3
N.m
-1
, ca dung dch axt valerc o=53,1.10
-3
N.m
-1
.
Hy xc nh nng axt trong dung dch, bit rng cc hng s trong phng trnh Shi-cp-xky c gi tr
nh sau :
S A=14,72.10
-3
v B=10,4
12. Hi ru mtylic khi hp ph trn 1 loi than tun theo phng trnh BET. T thc nghim thu c
phng trnh hp ph c dng :
g mol
P
P
P
P
P
P
a
s s
/
004 , 0 1 1
10 . 4 , 2
5
|
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.
|

\
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+
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\
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=



g mol
P
P
P
P
P
P
a
s s
/
004 , 0 1 1
10 . 4 , 2
5
|
|
.
|

\
|
+
|
|
.
|

\
|

=


nhit hp ph, p sut hi bo ho ca ru l P
s
=12,8.10
3
Nm
-2
. Hy xc nh hp ph p sut
P=9.000 Nm
-2
v xc nh b mt ring ca than. Cho bit mi phn t ru khi hp ph chim din tch
20.10
-16
cm
2
.