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(K.E )max
1 2 m (u cos ) 2
at the
higher point 1 = mu 2 x 2
kmax u2 x
Given
ux ux
Given
which should be perpendicular to the wind screen. As a result the velocity components of VR and Vc along the wind screen must cancel each other. That is,
VR cos = VC cos ( 90 )
6 cos = 2 sin tan = 3. and hence = tan
1
H1 4 = H2 1 2 1
uy uy
R=
(3)
IIT/BMAT5/PMC(MAIN)/Solns - 1
2 3. (1) Second overtone of the closed pipe is 3rd harmonic. It has a frequency of 5v / 4 .
First overtone of the open pipe is the second harmonic and it has a frequency = 2 ( v / 2 ) 5v 2v = 100 4 2 (i.e.) v = 100 or v = 400 4
6.
= mv cos 45 =
mv 2 v 2 sin2 45 2g
= L = momentum height = mv 2 v2 mv 3 = 4g 4 2g
4.
(1) Clearly ADBC is a rhombus. Let each side have a length a whose charge +Q is at A only, then
Q Q and E = along 40a 40a2 AD. When the charge 2Q and Q are placed at the corners of B and C the new value of the potential is VD = 1 Q 2Q Q = VD + =0 4 0 a a a The value of field will be
v2 = h or v = 4gh 4g
m 4 2
L=
( 4gh) 2
g
= m 2gh3
7.
=
5.
Q 40a2
= E
v=
2 r 22 8 106 = 2 T 7 2 60 60
= 7 103 ms1
(2) Let the particle leave the sphere at an angle with the vertical.
Energy conservation = 1 mv 2 = mgR (1 cos ) 2 (1) (2) 2 3
2 mvr h
IIT/BMAT5/PMC(MAIN)/Solns - 2
)(
)
3/2
J 3 3 = 2 2 2 4 3 = 2 2
If N is the number of photons emitted by the source per second , the power P transmitted in the beam equals to N times energy per photon E so that P = NE N= P 2 10 3 W = E 3.98 10 19 J = 5 1015 photons per second
B=
0 0 = 4 2 R 8R
V where Z
2
9.
2 V = VR + ( VL VC )
and
Z = R2 + ( XL XC )
At resonance XL = XC , Z = R and VL = VC , V = VR
Given = 2271A = 2271 10 10 m and V0 = 1.3V work function 0 = 6.63 10 34 3 108 2271 10
10 19
1.6 10
1.3
1 1 = s V 100
e =
= 0.5 Vm1
IIT/BMAT5/PMC(MAIN)/Solns - 3
2 (i.e.) 4 = a2 a2 / 2 16
Resolve E along CO and E along BO into two r components. In this problem the sine components will cancel each other. Only the cosine components add up along OA to give 2E cos 60. the resultant field along AO = 2E 2E cos 60 = 2E E = E The resultant field will be E along AO (i.e.) = a 32 2 or a = 8 2 T2 T1
Initially
50 273 + 17 = 1 100 T1
Finally
g = 5mA
nhc
s+G = g s 4 + 20 = 5 mA = 30 mA 4 15. (3) At time t = 2 sec the particle crosses the mean position. At time t = 4 sec
its velocity is 4 ms . For S.H.M y = a sin t
1
2 y = a sin t T
2 y1 = a sin 2 16
n=
1 64 = 400Hz 2 0.1 10 2
IIT/BMAT5/PMC(MAIN)/Solns - 4
5
The source is moving away from the observer. The apparent frequency
20.
(1)
v n = n v + v
n = 400 v = 300 m / s a = ? n n = 1 n = n 1 = 400 1 = 399
Let be the temperature after next 7 minutes 40 40 + =k 10 7 2 Dividing (1) by (2) = ...(2)
19. (1) h1 0 = E1 h2 h1 = E2 E1
h2 0 = E2 hc hc = E2 E1 2 1
20 40 2 = 40 20 +
1 1 hc = E2 E1 1 2 2 hc 1 = E2 E1 1 2
h=
(E2 E1) 12 c ( 1 2 )
1 = 800 A
R m2 = R2 3
= 8R2 9
= 8 10 8 m
Let the position of the centre of mass of the remaining portion be . From the centre of the disc,
2R m2 ( ) + m 3 0= m1 + m2 m 2R 2R m2 = m1 i.e. = 1 m2 3 3
(4 1.6 10
h=
19
1.8 1.6 10 19 8 10
8
)
8
7 10
3 108 8 10 8 7 108
)
IIT/BMAT5/PMC(MAIN)/Solns - 5
= 6.57 10 34 J.s
6
R 3 2R = R = 8 R2 3 12 9 Moment of inertia of the system about O2 is given by
2
1/4mg 3/4mg
R2 2 R R2 + R2 o = 2 2 12
2 2 (R / 3 )2 R 2 R 3R + 2 3 3 4
mg
O x
3 1 mgx + mg = mg 4 4 2 3 mg mg mg x = 4 2 4 3 mg mg x = 4 4 3 x= 4 4 or x = 3
22. (3) Let be the length of the block immersed in liquid when the block is floating.
mg = A g If the block is given a vertical displacement M then the effective restoring force
( 5 0.5) V = 4.5V
i= i= V R 4.5 A = 30 mA 150
F = ( A ( + y ) g mg))
= A ( + y ) g A g = Ag y F y . As this F is directed towards its equilibrium position of block, if the block is left free it will execute simple harmonic motion. Hence inertia factor = mass of block = m Spring factor = Ag i.e. Time period
60
= T = 2
m 1 i.e., T Ag A
IIT/BMAT5/PMC(MAIN)/Solns - 6
7
sin60 = sin r = 3 4 4 sinr 3
3 3 3 = 2 8
28. (3) In circuit A diodes are forward biased, current flowing in the circuit is
= 8V 8V = = 4A 4 4 2 4 + 4
3 3 r = sin1 8
From the figure it is clear that the angle of incidence on the glass slab 3 3 is i = r = sin1 8
In the circuit upper diode is forward biased and lower diode is reverse biased. Current flowing into circuit 8v B=I= = 2A 4
27. (2)
y1 = 0.5 sin ( 3t 2x ) y2 = 0.5 sin ( 3 t 2x ) According to the principle of super position, the resultant displacement is y = y1 + y 2 = 0.05 sin ( 3t 2x ) + sin ( 3t + 2x ) y = 0.05 2 sin 3 t cos 2x y = ( 0.1cos 2x ) sin 3t = A sin 3t where A = 0.1 cos 2x = amplitude of the resultant standing wave At x = 0.5 m A = 0.1 cos 2x = 0.1 cos 2 0.5 A = 0.1cos1 radian = 0.1cos = 0.1cos 57.3 A = 0.1 0.54 m = 0.054 m = 5.4 cm 180
29. (1) The magnitude of electric field at a distance r from a thin infinitely long straight wire of uniform linear charge density is
E= 1 2.1 . where r is the 4 0 r 1 cm1 3
1 10 11 NC1 3
= 0.33 1011NC1
IIT/BMAT5/PMC(MAIN)/Solns - 7
8 30. (3) As T = 2
L g 4 2L g
or g =
T=
42L T2
n
and T =
The percentage of error in g is g L 2 T 100 = + 100 g T L The errors in both L and T are least count.
g 100 = g
IIT/BMAT5/PMC(MAIN)/Solns - 8
Lt
f (x)
( x 2 )2
=3
perpendicular bisector of the line joining A ( 2, 0 ) and A ( 2, 0 ) i.e., B lies on y axis. (Above x axis). The le is equilateral. BO From ABO, tan60 = 2
BO = 2 3 . B is 0, 2 3 Since the le is equilateral. orthocenter is the 2 3 centroid which is 0, which 3
0 f ( 2 ) = 0 form 0
Also
x2
Lt
f ( x ) 2 ( x 2)
is
0 0
form
f ( 2 ) = 0
Now Lt f ( x ) 2
x2
= 3 f ( 2 ) = 6
2
32. (2)
f (x ) = 1
lies on 3 ( x + y ) = 2 3
x 4 x 2 2x + 4
35. (1)
which is
y F 3 B
A y
= 1
( x 1)
2
+ ( x 1) + 2
E
6
3 D
x x b a 2 2
( 6 + 3 )2 + ( y + 3 ) 2 = ( y + 6 )2 y = 9
1 9 12 2 = 54 36. (2) Let E1, E2 , E3 denote the events that the bag contains 2 white, 3 white and 4 white balls respectively. All the three are equally likely. Hence 1 P (E1) = P (E2 ) = P (E3 ) = . Let A denote 3 the event that the 2 balls drawn are Area of the triangle =
2 C2 1 P = AE = 4 1 C2 6 3 4 A = C2 = 1 ; P A = C2 = 1 P 4 E 4 E 2 3 C2 2 C2
B C, 2B, B A are in HP
2B =
B2 = AC
a x x x ,b and c are in G.P 2 2 2
y B
34. (3)
By Bayes theorem
A ( 2, 0 )
A ( 2, 0 )
1 1 3 E3 3 P = = A 1 1 + 1 1 + 1 1 5 3 6 3 2 3
IIT/BMAT5/PMC(MAIN)/Solns - 9
39. (3)
3y 2 = ( x + 2 )
Differentiating w. r. to x 6y dy 2 = 3 ( x + 2) dx dy ( x + 2 ) = dx 2
2
1 1 1 1 = a2 a3 d a2 a3 1 1 1 1 = a100 a101 d a100 a101 1 1 1 Adding + + ... a1 a2 a2 a3 a100 a101 = 1 100d 1 = = d a1 a101 14 1 1 1 d a1 a101
Sub normal = y
Sub tangent =
y 2y 2 = dy ( x + 2 )2 dx = 2 ( x + 2) 3
( Sub t angent )2
Sub normal
8 9
equation
2
x y + =1 12 4
P is 2 3 cos , 2 sin
3 3 M is 2 2
Let ( , ) be the mid point of PM. Then 2 2 3 = 2 3 cos , 2
Lt
2x 2x f x
1 1 1 1 24 + 40 5 5 5 1 1 = 3 1 15 5
3 = 2 sin 2
Eliminating
41. (2)
2
3 3 4 4 + =1 3 1
Locus of ( , ) is
3 x 4 + 3
3 y 4 =1 1
px 2 + qx + r = 0
roots say and . suppose p > 0, then the graph is as above. Then the curve y = px 2 + qx + r has a minimum below and . Now,
IIT/BMAT5/PMC(MAIN)/Solns - 10
11
px 2 + (10p + q) x + ( 5q + r ) = f ( x ) + 5 f ( x ) Let g ( x ) = f ( x ) + 5 f ( x ) g ( ) = 0 + 5 f ( ) = 5 f ( ) g ( ) = 5 f ( ) Now g ( ) and g ( ) are of
44. (4)
I=
(1 + x
2
x2 + x2
2
(1 + x )(1 x
1
+ x4
dx
0
dx 2 1+ x
1 3
3x 2 2 1 + x3
( )
dx
opposite signs. The same result holds good if p < 0 g ( x ) = 0 has atleast one positive root.
1 = tan1 x + tan 1 x 3 3 0
( )
+ = 4 12 3
P
42. (1) Equation to the perpendicular bisector of the chord joining (2, 4) and (6, 4) is x = 4. Solving with y = x + 6 , we get centre of the
circle is (4, 10). Slope of one diagonal = Slope of 6 = =3 2 Angle another 6 =3 2 diagonal
45. (2)
P/ 2 P/ 2
Q
Q/2
P 1
Join QP 1 PQP 1= Q+ P 2
between
the
diagonals
= tan
6 1 9
Q R = 8 cos 2 2
107
+ 109C2 ( 4x )
... 1 = 0
109C 1 2 109C 4
1
PP 1 cos
P P Q R = 8 cos cos 2 2 2
Q R Q + R = 8 cos sin 2 2
PP 1 cos P = 4 sinQ + sinR 2 Q = 4 sinR + sinP 2
IIT/BMAT5/PMC(MAIN)/Solns - 11
12
and RR1 cos R = 4 sinP + sinQ 2
(n+1)C Formula nC + nC r r 1 = r
= 5C3 + 5C2 + 6C2 = 6C3 + 6C2 = 7C3 = 35
46. (4)
a b a b = a b a b
= a b b a ba b
{(
)}
= aa bb ab a b a b + a b
)(
) ( (
( 3x 7 )3 ( x 7 )5
= a
7 3
= 35 3 + 3C2 25 2
)} = 150
1 + + 2 + 3 = 4 1 +
= 1 1+
cos + i sin 6 6 6 3 =2 = 3 6 2
1 + = 2 cos
IIT/BMAT5/PMC(MAIN)/Solns - 12
13 51. (3)
tan x tan2 x = 1
tan x = sec2 x
54. (2)
The
4
given
2 5
expression
is
= 1 + 32 = 31
Let OA = a OB = b
OC = a + b = c
52. (4)
x y =a
dy dy x 2x 2y =0 = dx dx y
The point P is nearer to the line y = 3x + 5 means, the tangent at P is parallel to the above line.
Let AD = a
OE = OD + BD = 2a + b = d
x = 3 x 3y = 0 y
locus required.
which is the
nx )( nx )( nx ) ... 0
55. (3)
f (x) =
1 x
( 3t
2f ( t ) dt
f (x) =
x2 = x2 1+ 0
Differentiating w.r. to x
f ( x ) =
1 x3
{3x
+
2f ( x ) . 1 0
nx )( nx )( nx )( nx ) ...
( 3t
3 2f ( t ) dt 4 x
f (x) = 0
Hence
2e
e 2e
1 12 2f ( 2 ) +0 8
f ( x ) dx = f ( x ) dx +
1 e
f ( x ) dx
3 1 f ( 2 ) 2 4
5 3 f ( 2 ) = 4 2
e
x3 e3 1 = x 2dx + 0 = = 3 3 1
1
IIT/BMAT5/PMC(MAIN)/Solns - 13
= Coeff of t
40
1 1 = + ( q 1) d b f 1 1 = + ( r 1) d c f where f is the I term of the HP and d, C-D of the corresponding AP 1 a Det = abc p 1 1 b q 1 1 c r 1
1 t16 in 1 t
1 t21 1 t
= Coeff of t40 in
(1 3t
16
)(
= Coeff of t40 in (1 t )
4 + 40 1) =( C40 = 43
C40 =
43
C3
59. (4) The condition for the existence of non trivial solution is
a sin cos 1 cos sin = 0 1 sin cos
a = sin2 + cos 2
1 1 1 + (p 1) d + ( q 1) d + ( r 1) d f f f = abc p q r 1 1 1
Now C2 C1, C3 C1 gives
= 2 sin 2 + 4 Maximum of a is 2
Minimum of a is 2
1 + (p 1) d f = abc p 1
= abc. 0 = 0
(q p) d (r p) d
qp 0
(r p )
0
60. (4) The equation can be written as xdx + ydy xdy ydx = 2 2 x 2 + y2 1 x + y
xdx + ydy x + y2
2
1 x 2 + y2
)
= xdy ydx
57. (3)
5x x 2 3 0 x 2 5x + 2 0
Range of I term is 0, (closed 2
(x
+ y2
In LHS put u = x 2 + y 2 du = 1 2 x + y2 du 1 u2
2
interval)
Range of II term is 0, (open 2
( 2xdx + 2ydy )
interval)
Sum of the two terms of LHS can never be equal to Number of solutions is zero
LHS
= sin 1 u = sin1 x 2 + y2
required
3
number
1
of
ways
= Coeff of t40 in
(t
+ .. t15
) (t
+ ... t20
In multiplicanumber of
64. (3)
significant digits as that of the operand having the least significant digits. Since 4 9 is the number with least significant digit (two) the final result is limited to two significant digits. Thus the result is 1 3 102
(125.195 is rounded to 1 3 10 )
2
62. (3)
SO2C
1mo
2 on
hydro-
65. (3)
+ 4H2O
NH3 and NF3 : Due to greater electronegativity of F, the N F bond electrons are more towards fluorine in N F bonds. Hence there is less bond pair- bond pair repulsion in NF3 than in NH3 . Hence NF3 has lower bond angle than NH3 PF3 and PH3 : Partial double bond between P and F due to d p back bonding in PF3 , so bond
+ ( + 1)
h for a 3d orbital 2
IIT/BMAT5/PMC(MAIN)/Solns - 15
16 66. (3) For a molecule with 3 bond pairs and T shape, there should be 2 lone pairs. (like C F3 )
Molar concentration
C1 RT = C2 RT
X
PM 67. (2) Density is given by d = RT Thus it is maximum at highest pressure (2 atm) and lowest temperature (200 K)
70. (2)
nA
nk
71. (3)
24 24 11 Na 12
Mg + ( electron)
72. (3)
MA4 = m4 + + 4A
s
4
4s
Ksp = s ( 4s ) = 256 s5
3 1000 = C1 100 M
K sp s= 256
1/ 5
IIT/BMAT5/PMC(MAIN)/Solns - 16
17
Fe3 + + 3e Fe; E0 = 0.036 V; G = nFE nFE0 = 3F 3Fx 0.036V = + 0.108 FV Fe
3+
73. (2)
Fe2 + + 2e ; E0 = + 0.439V; G0 = 2Fx 2F + 0.439 = 0.878 FV Adding (1 ) and (2), we get + e Fe2 + ; G0 = nFE0 = 0.770 FV
Fe
77. (3)
is
O CH2 CH = CH CHO
CH3 CHO
[
the
HCC : CC
O + OHO H2O + CC : CC
2 +C Dichlorocarbene
O
3
= CH CHO + OH Product
ii
76. (2)
CC
Ca2 +
heat
CC 2 OH ; H2O
CHC
IIT/BMAT5/PMC(MAIN)/Solns - 17
18
81. (4)
OH H2O
H2O
HO
OH
Br2 / CC
79. (2)
CH3C > CHC
C
( ) 2, 3
3
dibromobutane
C C
82. (1) (1) is most stable. The two C are farthest from each other in (1). In (2) and (3) the two C are close to each other causing electronic repulsion. In (4) there is instability due to both electronic as well as steric repulsion.
83. (4)
CH3C has greater dipole moment due to larger C C
than CH3F
distance than C F distance though F is more electronegative than C because of the + and hyper conjugation of CH3 group
80. (1)
The chain with greater number of side chains is selected as principal chain. Hence the name is 2, 3, 5trimethyl-4-propyl heptane
is more strongly
IIT/BMAT5/PMC(MAIN)/Solns - 18
88. (1) Oxidizing power in the decreasing order is: 84. (2) 85. (1) Molarity is the number of moles per litre of solution.
1mL of '10 - volume' H2O2 HC O > HC O2 > HC O3 > HC O4 . As the oxidation number of C increases the C O bond becomes stronger and the thermal stabilities of oxychlorides increase. Hence HC O is the strongest oxidizer and HC O4 is the weakest.
Mn C
4 2
gives 10ml O2 at STP 1L (1000 mL) of 10 volume. H2O2 gives 10000 mL O2 at STP
89. (3)
2 34 = 68 g H2O2
22400 mL O2 at STP is given by 2240 mL or 2.24 L of 10 vol H2O2 solution. 2240 mL or 2.24 L of H2O2 (10 volume) solution contains 2 mol H2O2
Mn2 + :
H2O2 =
86. (3) The smallest ion F will have the highest value for hydration ergy.(most negative). Brilliant Tutorials Pvt. Ltd.
()
90. (4)
IIT/BMAT5/PMC(MAIN)/Solns - 19