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BRILLIANTS FULL SYLLABUS TEST 5


FOR OUR STUDENTS TOWARDS

JEE 2013 B.MAT 5 (MAIN) SOLNS

JOINT ENTRANCE EXAMINATION, 2013

PHYSICS MATHEMATICS CHEMISTRY SOLUTIONS


PART A : PHYSICS 1. (2) Velocity of rain drop with respect to car is VRC = VR VC 2. (2)

(K.E )max

1 2 m (u cos ) 2

at the

higher point 1 = mu 2 x 2

kmax u2 x
Given

(K.E )max1 4 = (K.E)max 2 1


2 1

ux ux

Similarly maximum height H u2 y H=


2 u2 sin2 uy = 2g 2g

Given

which should be perpendicular to the wind screen. As a result the velocity components of VR and Vc along the wind screen must cancel each other. That is,
VR cos = VC cos ( 90 )
6 cos = 2 sin tan = 3. and hence = tan
1

H1 4 = H2 1 2 1

uy uy

R=

2u2 sin cos 2ux uy = g g

(3)

R1 ux1 uy1 2 2 4 = . = = R2 ux2 uy 1 1 1 2

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IIT/BMAT5/PMC(MAIN)/Solns - 1

2 3. (1) Second overtone of the closed pipe is 3rd harmonic. It has a frequency of 5v / 4 .
First overtone of the open pipe is the second harmonic and it has a frequency = 2 ( v / 2 ) 5v 2v = 100 4 2 (i.e.) v = 100 or v = 400 4

6.

(4) Momentum at the highest point

= mv cos 45 =

mv 2 v 2 sin2 45 2g

Maximum height h = = v 2 / 4g Angular momentum

Fundamental frequency of open v pipe is = 200 s1 . 2

= L = momentum height = mv 2 v2 mv 3 = 4g 4 2g

4.

(1) Clearly ADBC is a rhombus. Let each side have a length a whose charge +Q is at A only, then
Q Q and E = along 40a 40a2 AD. When the charge 2Q and Q are placed at the corners of B and C the new value of the potential is VD = 1 Q 2Q Q = VD + =0 4 0 a a a The value of field will be

v2 = h or v = 4gh 4g
m 4 2

L=

( 4gh) 2
g

= m 2gh3

7.

(1) Time period T = 2h


i.e., T = 2 60 60 s radius 8000 km. = 8 106 m

Q 2Q 120 = 2 ED Cos 4 a2 2 40a2 0

=
5.

Q 40a2

= E

v=

2 r 22 8 106 = 2 T 7 2 60 60
= 7 103 ms1

(2) Let the particle leave the sphere at an angle with the vertical.
Energy conservation = 1 mv 2 = mgR (1 cos ) 2 (1) (2) 2 3

According to Bohrs postulate mvr = n= nh 2

mv 2 = mgcos R solving (1) and (2), cos =

2 mvr h

2 3.14 10 7 103 8 106 6.6 10 34

At this point the tangential acceleration is aT = g sin = g 5 3

= 5.3 1045 This is the quantum number of orbit of the satellite.

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IIT/BMAT5/PMC(MAIN)/Solns - 2

3 8. (2) Each photon has an energy


E = h = 6.63 10 34 Js 6.0 1014 Hz = 3.98 10
19

)(

)
3/2

J 3 3 = 2 2 2 4 3 = 2 2

If N is the number of photons emitted by the source per second , the power P transmitted in the beam equals to N times energy per photon E so that P = NE N= P 2 10 3 W = E 3.98 10 19 J = 5 1015 photons per second

B=

0 0 = 4 2 R 8R
V where Z
2

9.

(3) Einsteins photo electron ic equation is


Kmax = h 0 = hc 0

11. (4) Current =

2 V = VR + ( VL VC )

and

Maximum kinetic energy k = eV0 Work function 0 = hc eV0

Z = R2 + ( XL XC )

At resonance XL = XC , Z = R and VL = VC , V = VR

Given = 2271A = 2271 10 10 m and V0 = 1.3V work function 0 = 6.63 10 34 3 108 2271 10
10 19

VR 100 = = 0.1A R 1 103

Voltage across the inductance VL is VL = VC = I C = = 250 V I 0.1 = C 200 2 10 6

1.6 10

1.3

= 8.76 10 19 2.08 1019 = 6.68 1019 1.6 1019 = 4.2 eV

12. (2) r = 1m, B = 0.01T, and t =


Induced e.m.f = e = d dt

1 1 = s V 100

10. (4) For a loop magnetic induction at 2 the center will be B = 0 4 R


When the loop subtends an angle at the centre then B = 0 4 R In the problem = 3 , given 2

e =

BA Br 2 0.01 1 (1) = = = V t t 1/100

Induced electric field =E = e = = 2 r 2 1

= 0.5 Vm1

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IIT/BMAT5/PMC(MAIN)/Solns - 3

4 13. (1) a y1 = a sin = 2 4


After 4 sec or after 2 sec from mean position velocity = 4ms1 Velocity = a2 y12

2 (i.e.) 4 = a2 a2 / 2 16
Resolve E along CO and E along BO into two r components. In this problem the sine components will cancel each other. Only the cosine components add up along OA to give 2E cos 60. the resultant field along AO = 2E 2E cos 60 = 2E E = E The resultant field will be E along AO (i.e.) = a 32 2 or a = 8 2 T2 T1

16. (1) Efficiency = 1

Initially

50 273 + 17 = 1 100 T1

290 1 = or T1 = 580K T1 2 60 273 + 17 290 2 = 1 or = 100 T1 T1 5

Finally

14. (3) There are 50 divisions on the scale.


Full scale current for 50 divisions = 1 50 = 5 mA 10 g I = 50 s+G

= 725 K T1 Change in source temperature = ( 725 580 ) K = 145 K

g = 5mA

17. (4) Energy of n photon E =

nhc

s+G = g s 4 + 20 = 5 mA = 30 mA 4 15. (3) At time t = 2 sec the particle crosses the mean position. At time t = 4 sec
its velocity is 4 ms . For S.H.M y = a sin t
1

Momentum gained by the body E nhc nh P= = = c c

18. (2) Tension = 64N


length = 10 cm = 0.1m

mass per unit length m= 10 3 = 10 2 kg/ m 0.1

2 y = a sin t T

2 y1 = a sin 2 16

Frequency of fundamental mode 1 T =n= 2 m

n=

1 64 = 400Hz 2 0.1 10 2
IIT/BMAT5/PMC(MAIN)/Solns - 4

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5
The source is moving away from the observer. The apparent frequency

20.

(1)

According to Newtons law 1 2 + 2 =k 1 0 where 0 t 2 is the surrounding temperature. 60 40 60 + 40 =k 10 7 2 20 = k 40 7 (1)

v n = n v + v
n = 400 v = 300 m / s a = ? n n = 1 n = n 1 = 400 1 = 399

300 399 = 400 300 + v


v = 300 = 0.7518 m/ sec 399 = 0.75 m/sec

Let be the temperature after next 7 minutes 40 40 + =k 10 7 2 Dividing (1) by (2) = ...(2)

19. (1) h1 0 = E1 h2 h1 = E2 E1
h2 0 = E2 hc hc = E2 E1 2 1

20 40 2 = 40 20 +

i.e. 20 + = 160 4 5 = 160 20 = 140 or = 140 = 28 C 5


2

1 1 hc = E2 E1 1 2 2 hc 1 = E2 E1 1 2
h=

R 21. (2) Mass of the cavity m1 = 3


Mass of the remaining portion

(E2 E1) 12 c ( 1 2 )

1 = 800 A

R m2 = R2 3
= 8R2 9

= 8 10 8 m

2 = 700A = 7 108 m E1 = 1.8eV = 1.8 1.6 10 19 J E2 = 4.eV = 4 1.6 10 19 J


c = 3 108 m / sec

Let the position of the centre of mass of the remaining portion be . From the centre of the disc,

2R m2 ( ) + m 3 0= m1 + m2 m 2R 2R m2 = m1 i.e. = 1 m2 3 3

(4 1.6 10
h=

19

1.8 1.6 10 19 8 10
8

)
8

7 10

3 108 8 10 8 7 108

)
IIT/BMAT5/PMC(MAIN)/Solns - 5

= 6.57 10 34 J.s

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6
R 3 2R = R = 8 R2 3 12 9 Moment of inertia of the system about O2 is given by
2

23. (1) Applying conditions of rotational equilibrium

1/4mg 3/4mg

R2 2 R R2 + R2 o = 2 2 12
2 2 (R / 3 )2 R 2 R 3R + 2 3 3 4

mg

O x

3 1 mgx + mg = mg 4 4 2 3 mg mg mg x = 4 2 4 3 mg mg x = 4 4 3 x= 4 4 or x = 3

1 1 1 1 = R4 + 2 144 162 16 = 0.44 R4

22. (3) Let be the length of the block immersed in liquid when the block is floating.
mg = A g If the block is given a vertical displacement M then the effective restoring force

24. (2) Voltage drop across. 150


resistor is given by

( 5 0.5) V = 4.5V
i= i= V R 4.5 A = 30 mA 150

F = ( A ( + y ) g mg))
= A ( + y ) g A g = Ag y F y . As this F is directed towards its equilibrium position of block, if the block is left free it will execute simple harmonic motion. Hence inertia factor = mass of block = m Spring factor = Ag i.e. Time period

25. (4) Applying snells law at air water interface.

Air Water flim 4 w = 3

60

Glass slab g = 1.5

= T = 2

m 1 i.e., T Ag A
IIT/BMAT5/PMC(MAIN)/Solns - 6

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7
sin60 = sin r = 3 4 4 sinr 3

3 3 3 = 2 8

28. (3) In circuit A diodes are forward biased, current flowing in the circuit is
= 8V 8V = = 4A 4 4 2 4 + 4

3 3 r = sin1 8
From the figure it is clear that the angle of incidence on the glass slab 3 3 is i = r = sin1 8

( 4 and 4 are parallel )


4 4 4 4

26. (1) If 0 is the intensity of unpolarised


light, then intensity of light transmitted through first polariser = 0 2 Intensity of light transmitted through the second polarizer is (by Malus, Law) = cos2 45 = I0 1 0 = 2 2 4
2

In the circuit upper diode is forward biased and lower diode is reverse biased. Current flowing into circuit 8v B=I= = 2A 4

27. (2)

y1 = 0.5 sin ( 3t 2x ) y2 = 0.5 sin ( 3 t 2x ) According to the principle of super position, the resultant displacement is y = y1 + y 2 = 0.05 sin ( 3t 2x ) + sin ( 3t + 2x ) y = 0.05 2 sin 3 t cos 2x y = ( 0.1cos 2x ) sin 3t = A sin 3t where A = 0.1 cos 2x = amplitude of the resultant standing wave At x = 0.5 m A = 0.1 cos 2x = 0.1 cos 2 0.5 A = 0.1cos1 radian = 0.1cos = 0.1cos 57.3 A = 0.1 0.54 m = 0.054 m = 5.4 cm 180

29. (1) The magnitude of electric field at a distance r from a thin infinitely long straight wire of uniform linear charge density is
E= 1 2.1 . where r is the 4 0 r 1 cm1 3

distance of the point from the wire. =

r = 18 cm = 18 10 2 m 9 109 2 E= 18 10 2 9 109 2 3 18 102 NC1 1 3

1 10 11 NC1 3

= 0.33 1011NC1

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IIT/BMAT5/PMC(MAIN)/Solns - 7

8 30. (3) As T = 2

L g 4 2L g

squaring on both sides T2 =

or g =
T=

42L T2
n

and T =

The percentage of error in g is g L 2 T 100 = + 100 g T L The errors in both L and T are least count.

g 100 = g

0.1 1 + 2 100 20.0 90

= ( 0.05 + 0.2 ) 100 = 0.205 100 = 20.5 = 21%

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IIT/BMAT5/PMC(MAIN)/Solns - 8

9 PART B: MATHEMATICS 31. (4)


x2

Lt

f (x)

( x 2 )2

=3

perpendicular bisector of the line joining A ( 2, 0 ) and A ( 2, 0 ) i.e., B lies on y axis. (Above x axis). The le is equilateral. BO From ABO, tan60 = 2
BO = 2 3 . B is 0, 2 3 Since the le is equilateral. orthocenter is the 2 3 centroid which is 0, which 3

0 f ( 2 ) = 0 form 0

Also

x2

Lt

f ( x ) 2 ( x 2)

is

0 0

form

f ( 2 ) = 0
Now Lt f ( x ) 2

x2

= 3 f ( 2 ) = 6
2

32. (2)

f (x ) = 1

lies on 3 ( x + y ) = 2 3

x 4 x 2 2x + 4

35. (1)
which is
y F 3 B

A y

= 1

( x 1)
2

+ ( x 1) + 2

E
6

< 1but 0 The range is [0, 1) x x x x c , b +b 2 2 2 2 are in HP

3 D

33. (2) Now


and

Let AE = y then AF = y Evidently BF = BD = 3 = inradius B = 90

x x b a 2 2

( 6 + 3 )2 + ( y + 3 ) 2 = ( y + 6 )2 y = 9
1 9 12 2 = 54 36. (2) Let E1, E2 , E3 denote the events that the bag contains 2 white, 3 white and 4 white balls respectively. All the three are equally likely. Hence 1 P (E1) = P (E2 ) = P (E3 ) = . Let A denote 3 the event that the 2 balls drawn are Area of the triangle =
2 C2 1 P = AE = 4 1 C2 6 3 4 A = C2 = 1 ; P A = C2 = 1 P 4 E 4 E 2 3 C2 2 C2

(given) Let a x x x = A , b = B and c = C 2 2 2 2 (B C )(B A) BC+BA

B C, 2B, B A are in HP

2B =

B2 = AC
a x x x ,b and c are in G.P 2 2 2
y B

34. (3)

By Bayes theorem
A ( 2, 0 )
A ( 2, 0 )

The third vertex lies on the

1 1 3 E3 3 P = = A 1 1 + 1 1 + 1 1 5 3 6 3 2 3

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IIT/BMAT5/PMC(MAIN)/Solns - 9

10 37. (4) Now


1 1 1 1 = a1 a2 d a1 a2

39. (3)

3y 2 = ( x + 2 )

Differentiating w. r. to x 6y dy 2 = 3 ( x + 2) dx dy ( x + 2 ) = dx 2
2

1 1 1 1 = a2 a3 d a2 a3 1 1 1 1 = a100 a101 d a100 a101 1 1 1 Adding + + ... a1 a2 a2 a3 a100 a101 = 1 100d 1 = = d a1 a101 14 1 1 1 d a1 a101

Sub normal = y
Sub tangent =

y 2y 2 = dy ( x + 2 )2 dx = 2 ( x + 2) 3

( Sub t angent )2
Sub normal

8 9

a1 a101 = 1400 38. (1) The


2

40. (4) The slope of the normal to y = f(x) at x = 0 is 5


of the ellipse is

equation
2

x y + =1 12 4

P is 2 3 cos , 2 sin

1 slope of the tangent = = f ( 0 ) 5 Now the limit is


x0

3 3 M is 2 2
Let ( , ) be the mid point of PM. Then 2 2 3 = 2 3 cos , 2

Lt

2x 2x f x

( ) 48x f (4x ) + 80x f ( 8x )


2 2 2

1 1 1 1 24 + 40 5 5 5 1 1 = 3 1 15 5

3 = 2 sin 2

Eliminating

41. (2)
2

3 3 4 4 + =1 3 1
Locus of ( , ) is

3 x 4 + 3

3 y 4 =1 1

px 2 + qx + r = 0

has exactly two

roots say and . suppose p > 0, then the graph is as above. Then the curve y = px 2 + qx + r has a minimum below and . Now,

3 3 which is an ellipse with centre , 4 4

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IIT/BMAT5/PMC(MAIN)/Solns - 10

11
px 2 + (10p + q) x + ( 5q + r ) = f ( x ) + 5 f ( x ) Let g ( x ) = f ( x ) + 5 f ( x ) g ( ) = 0 + 5 f ( ) = 5 f ( ) g ( ) = 5 f ( ) Now g ( ) and g ( ) are of

44. (4)

I=

(1 + x
2

x2 + x2
2

(1 + x )(1 x
1

+ x4

dx

0
dx 2 1+ x

1 3

3x 2 2 1 + x3

( )

dx

opposite signs. The same result holds good if p < 0 g ( x ) = 0 has atleast one positive root.

1 = tan1 x + tan 1 x 3 3 0

( )

+ = 4 12 3
P

42. (1) Equation to the perpendicular bisector of the chord joining (2, 4) and (6, 4) is x = 4. Solving with y = x + 6 , we get centre of the
circle is (4, 10). Slope of one diagonal = Slope of 6 = =3 2 Angle another 6 =3 2 diagonal

45. (2)

P/ 2 P/ 2
Q
Q/2

P 1

Join QP 1 PQP 1= Q+ P 2

between

the

diagonals

= tan

6 1 9

In PQP 1 P PP 1 = 2 4 sin Q + 2 Q R = 8 sin Q + 2 2 2

3 = tan1 4 43. (2) The equation is

( 4x 1)109 = 4109 x109


109C1 ( 4x )
108

Q R = 8 cos 2 2
107

+ 109C2 ( 4x )

... 1 = 0

sum of the roots =


27 2

109C 1 2 109C 4
1

PP 1 cos

P P Q R = 8 cos cos 2 2 2

Q R Q + R = 8 cos sin 2 2
PP 1 cos P = 4 sinQ + sinR 2 Q = 4 sinR + sinP 2

similarly QQ1 cos

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IIT/BMAT5/PMC(MAIN)/Solns - 11

12
and RR1 cos R = 4 sinP + sinQ 2

= 4C3 + 4C2 + 5C2 + 6C2

P PP sinP + sinQ + sinR 1 cos = 8 2


P PP 1 cos 2 =8 sinP

(n+1)C Formula nC + nC r r 1 = r
= 5C3 + 5C2 + 6C2 = 6C3 + 6C2 = 7C3 = 35

46. (4)

a b a b = a b a b
= a b b a ba b

49. (2) Even power of a function is always


positive. Hence we can ignore even powers Inequality is

{(

)}

= aa bb ab a b a b + a b

)(

) ( (

( 3x 7 )3 ( x 7 )5

= a

47. (1) Total number of functions from A to


B = 35 . Let us find the number of nononto functions from A to B. (1) 3 functions f1, f2 , f3 in which all the elements go to 1, 2, 3 (2) Select any two elements of B in
3

7 3

By wavy curve method


7 x , 7 3

Integral values are 3, 4, 5, 6 Their sum = 18

C2 i.e., 3 ways. Then number of

nononto function = 3C2 25 2

50. (3) Since is a 6th root of unity


1 + + 2 + 3 + 4 + 5 = 0
1 + + 2 + 3 = 4 (1 + )

Required number of onto functions

= 35 3 + 3C2 25 2

)} = 150

48. (2) Minimum values of a, b, c are


respectively equal to 1 we get 3 a + b + c 7 This a + b + c = 3, a + b + c = 2, ... a+b+c=7 Total number of positive integral solutions

1 + + 2 + 3 = 4 1 +
= 1 1+

Now = cos 1 + = 2 cos2


= 2 cos

+ i sin 3 3 + i2 sin cos 6 6 6

= C2 + C2 + C2 + C2 + C2 = 3C3 + 3C2 + 4C2 + 5C2 + 6C2

cos + i sin 6 6 6 3 =2 = 3 6 2

1 + = 2 cos

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IIT/BMAT5/PMC(MAIN)/Solns - 12

13 51. (3)
tan x tan2 x = 1
tan x = sec2 x

54. (2)

The
4

given
2 5

expression

is

( sec x sec x ) + 32 = ( tan x sec x ) + 32


2 2 5

= 1 + 32 = 31

Let OA = a OB = b
OC = a + b = c

52. (4)

x y =a

dy dy x 2x 2y =0 = dx dx y
The point P is nearer to the line y = 3x + 5 means, the tangent at P is parallel to the above line.

Let AD = a
OE = OD + BD = 2a + b = d

Since a = c quadrilateral OAEC is a rhombus Diagonals AC and OE are perpendicular b d = 0

x = 3 x 3y = 0 y
locus required.

which is the

53. (1) When 1 < x < e,0 < nx < 1


Hence

nx )( nx )( nx ) ... 0

55. (3)

f (x) =

1 x

( 3t

2f ( t ) dt

f (x) =

x2 = x2 1+ 0

Differentiating w.r. to x

x2 when x = e f ( x ) = 2 when x>e

f ( x ) =

1 x3

{3x
+

2f ( x ) . 1 0

nx )( nx )( nx )( nx ) ...

( 3t

3 2f ( t ) dt 4 x

f (x) = 0

[I differentiation is by Lebnitz Rule and II is ordinary differentiation] f ( 2 ) =


Hence
2e

e 2e

1 12 2f ( 2 ) +0 8

f ( x ) dx = f ( x ) dx +
1 e

f ( x ) dx

3 1 f ( 2 ) 2 4

5 3 f ( 2 ) = 4 2
e

x3 e3 1 = x 2dx + 0 = = 3 3 1
1

6 slope of the normal to 5 5 y = f ( x ) at x = 2 is 6 f ( 2 ) =

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IIT/BMAT5/PMC(MAIN)/Solns - 13

14 56. (4) Now


1 1 = + (p 1) d a f

= Coeff of t

40

1 1 = + ( q 1) d b f 1 1 = + ( r 1) d c f where f is the I term of the HP and d, C-D of the corresponding AP 1 a Det = abc p 1 1 b q 1 1 c r 1

1 t16 in 1 t

1 t21 1 t

= Coeff of t40 in

(1 3t

16

+ 3t32 t48 1 t21 (1 t )


4

)(

= Coeff of t40 in (1 t )
4 + 40 1) =( C40 = 43

C40 =

43

C3

59. (4) The condition for the existence of non trivial solution is
a sin cos 1 cos sin = 0 1 sin cos
a = sin2 + cos 2

1 1 1 + (p 1) d + ( q 1) d + ( r 1) d f f f = abc p q r 1 1 1
Now C2 C1, C3 C1 gives

= 2 sin 2 + 4 Maximum of a is 2

Minimum of a is 2

1 + (p 1) d f = abc p 1
= abc. 0 = 0

(q p) d (r p) d
qp 0

(r p )
0

60. (4) The equation can be written as xdx + ydy xdy ydx = 2 2 x 2 + y2 1 x + y

xdx + ydy x + y2
2

1 x 2 + y2

)
= xdy ydx

57. (3)

5x x 2 3 0 x 2 5x + 2 0
Range of I term is 0, (closed 2

(x

+ y2

In LHS put u = x 2 + y 2 du = 1 2 x + y2 du 1 u2
2

interval)
Range of II term is 0, (open 2

( 2xdx + 2ydy )

interval)
Sum of the two terms of LHS can never be equal to Number of solutions is zero

LHS

= sin 1 u = sin1 x 2 + y2

58. (2) The

required
3

number
1

of

ways

= Coeff of t40 in

(t

+ .. t15

) (t

+ ... t20

y d y x RHS 2 = tan1 Solution is x y 1+ 2 x y 1 2 sin x + y2 = tan1 + k x


IIT/BMAT5/PMC(MAIN)/Solns - 14

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15 PART C : CHEMISTRY s 61. (4)


25.55 4.9 = 125.195

In multiplicanumber of

64. (3)

tion the result will be expressed correct to same


(in SO )
2 3

significant digits as that of the operand having the least significant digits. Since 4 9 is the number with least significant digit (two) the final result is limited to two significant digits. Thus the result is 1 3 102

(125.195 is rounded to 1 3 10 )
2

62. (3)

SO2C
1mo

+ 2H2O H2 SO4 + 2HC


1mo 2 mo

Therefore, 2 mol SO2C

2 on

hydro-

As C, N and B have no d orbitals, they do not form p d bonds.

lysis will give 2 mol H2 SO4 and 4 mol HC


2H2 SO 4 + 2Mg ( OH )2 2MgSO4

65. (3)

+ 4H2O

4HC + 2Mg ( OH)2 2MgC

NH3 and NF3 : Due to greater electronegativity of F, the N F bond electrons are more towards fluorine in N F bonds. Hence there is less bond pair- bond pair repulsion in NF3 than in NH3 . Hence NF3 has lower bond angle than NH3 PF3 and PH3 : Partial double bond between P and F due to d p back bonding in PF3 , so bond

+ 4H2O Thus for complete neutralization we need 2 + 2 = 4 mols Mg(OH)2

63. (4) orbital angular momentum is given


by

+ ( + 1)

h for a 3d orbital 2

=2 orbital angular momentum = 2 ( 2 + 1) h h = 6 2 2

angle is greater in PF3 than in PH3 .

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IIT/BMAT5/PMC(MAIN)/Solns - 15

16 66. (3) For a molecule with 3 bond pairs and T shape, there should be 2 lone pairs. (like C F3 )
Molar concentration

1.2 1000 = C2 100 60

Osmotic pressure = CRT


X A X

C1 RT = C2 RT
X

PM 67. (2) Density is given by d = RT Thus it is maximum at highest pressure (2 atm) and lowest temperature (200 K)

3 1000 1.2 1000 R T = R T 100 M 100 60


M = 150

70. (2)

k = A.e Ea /RT n k = n A Ea /RT, Intercept is n A

68. (2) In Na C we have type A particles


at 8 corners and 6 face centers. Type B particles are at 12 edges and 1 at the centre of the body. Removal of half of the atoms from face centers means removal of 3 A atoms. Then, number of A atoms = 1 1 1 8+ 3=2 8 2 2

nA

nk

71. (3)

24 24 11 Na 12

Mg + ( electron)

Number of B atoms 1 = 12 + 1 = 4 4 Formula = A2.5B4 or A5B8

When the n/p ratio is > 1 , emission occurs.

72. (3)

MA4 = m4 + + 4A
s
4

4s

69. (1) For solution of A of molecular weight M,


Molar concentration

Ksp = s ( 4s ) = 256 s5

3 1000 = C1 100 M

K sp s= 256

1/ 5

For solution of urea

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IIT/BMAT5/PMC(MAIN)/Solns - 16

17
Fe3 + + 3e Fe; E0 = 0.036 V; G = nFE nFE0 = 3F 3Fx 0.036V = + 0.108 FV Fe
3+

73. (2)

Fe2 + + 2e ; E0 = + 0.439V; G0 = 2Fx 2F + 0.439 = 0.878 FV Adding (1 ) and (2), we get + e Fe2 + ; G0 = nFE0 = 0.770 FV

Fe

In the above reaction n = 1 Then E0 = + 0.77 V

74. (3) For l mole,


H = U + PV = CV ( T2 T1) R ( T2 T1) = ( CV + R ) ( T2 T1) Since T = T2 T1 = 0 , H = 0 for the process. O 75. (4) In CH2 CH = CH CHO, the hydrogen is lost as H+ because the resulting anion is stabilised by resonance and is most likely to be formed. The reaction is crossed aldol reaction as follows: OH O CH3 CH = CH CHO

77. (3)

78. (4) Neutral dichlorocarbene (: CC


the elctrophile reaction. formed in

is

O CH2 CH = CH CHO
CH3 CHO
[

the

HCC : CC

O + OHO H2O + CC : CC
2 +C Dichlorocarbene

O
3

= CH CHO + OH Product
ii

76. (2)

CC


Ca2 +
heat

CC 2 OH ; H2O

CHC

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IIT/BMAT5/PMC(MAIN)/Solns - 17

18

81. (4)

OH H2O

H2O

HO

OH

Br2 / CC

79. (2)
CH3C > CHC
C

( ) 2, 3
3

dibromobutane

C C

82. (1) (1) is most stable. The two C are farthest from each other in (1). In (2) and (3) the two C are close to each other causing electronic repulsion. In (4) there is instability due to both electronic as well as steric repulsion.

(4) CH3C > CH3F

83. (4)
CH3C has greater dipole moment due to larger C C

is a stronger base than

than CH3F

distance than C F distance though F is more electronegative than C because of the + and hyper conjugation of CH3 group

80. (1)

The chain with greater number of side chains is selected as principal chain. Hence the name is 2, 3, 5trimethyl-4-propyl heptane

is more strongly

deactivated by NO2 group compared to CN. Hence the order is:

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IIT/BMAT5/PMC(MAIN)/Solns - 18

19 87. (1) Due to gradual increase in size of


the M2 + cation both lattice energy and hydration energy decrease down the group. Decrease in lattice energy causes increase in solubility but decrease in hydration energy tends to decrease it .But since lattice energy has a dominating role the overall effect is an increase in solubility down the group.

88. (1) Oxidizing power in the decreasing order is: 84. (2) 85. (1) Molarity is the number of moles per litre of solution.
1mL of '10 - volume' H2O2 HC O > HC O2 > HC O3 > HC O4 . As the oxidation number of C increases the C O bond becomes stronger and the thermal stabilities of oxychlorides increase. Hence HC O is the strongest oxidizer and HC O4 is the weakest.
Mn C
4 2

gives 10ml O2 at STP 1L (1000 mL) of 10 volume. H2O2 gives 10000 mL O2 at STP

89. (3)
2 34 = 68 g H2O2

22400 mL O2 at STP is given by 2240 mL or 2.24 L of 10 vol H2O2 solution. 2240 mL or 2.24 L of H2O2 (10 volume) solution contains 2 mol H2O2

Mn2 + :

Magnetic moment Molatity of 10 volume = n (n + 2 ) = 5 ( 5 + 2 ) BM = 5.9 BM en-

H2O2 =

2 moL = 0.892 M 2.24 litre

86. (3) The smallest ion F will have the highest value for hydration ergy.(most negative). Brilliant Tutorials Pvt. Ltd.

()

90. (4)

Mg2 + is not precipitated by H2 S in ammoniaccal medium.

IIT/BMAT5/PMC(MAIN)/Solns - 19

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