PART A PHYSICS

1.

From the following combinations of 1.

physical constants (expressed through
their usual symbols) the only combination,
that would have the same value in different

A
SU (
U mU ),
,
U ,

systems of units, is :
(1)

(2)

2.

ch
e2
2peo Gm e 2

ch

(1)

2 peo2

(me5 mass of electron)

2 peo2
e2

(2)

2peo Gm e 2

(me5U

(3)

mo e o G
c2
h e2

(3)

mo eo G
c2
h e2

(4)

2 p mo eo h
G
ce 2

(4)

2 p mo eo h
G
ce 2

A person climbs up a stalled escalator 2.

in 60 s . If standing on the same but
escalator running with constant velocity
he takes 40 s. How much time is taken by
the person to walk up the moving

S SUU U 60 s
U U U SU
SUU U 40 s
SUU U U U
U ?

escalator ?
(1)

37 s

(1)

37 s

(2)

27 s

(2)

27 s

(3)

24 s

(3)

24 s

(4)

45 s

(4)

45 s

English : 1

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Hindi : 1

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3.

Three masses m, 2m and 3m are moving 3.

in x-y plane with speed 3u, 2u, and u
respectively as shown in figure. The three
masses collide at the same point at P and
stick together. The velocity of resulting

x-y
3u, 2u, u ,
U
^ U U U

m, 2m

3m

mass will be :

(1)
(2)
(3)
(4)

u
i1
12

u
i2
12

3j

3j

u
2i 1
12

u
2i 2
12

u
i 1 3j
12

(2)

u
i 2
12

(3)

u
2i 1
12

(4)

u
2i 2
12

3j

3j

4.
4.

(1)

A 4 g bullet is fired horizontally with a

speed of 300 m/s into 0.8 kg block of wood
at rest on a table. If the coefficient of
friction between the block and the table is

3j

)
)

3j

3j

$ U S S 0.8 kg
300 m/s 4 g
$
0.3 , U
?

0.3, how far will the block slide

approximately ?

(1)

0.19 m

(1)

0.19 m

(2)

0.379 m

(2)

0.379 m

(3)

0.569 m

(3)

0.569 m

(4)

0.758 m

(4)

0.758 m

English : 2

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Hindi : 2

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5.

A spring of unstretched length l has a 5.

mass m with one end fixed to a rigid
support. Assuming spring to be made of a
uniform wire, the kinetic energy possessed
by it if its free end is pulled with uniform

l
m U U
U U
U ,
S U v

velocity v is :
(1)
(2)

6.

1
m v2
2
mv 2

(1)
(2)

1
m v2
2
mv 2

(3)

1
m v2
3

(3)

1
m v2
3

(4)

1
m v2
6

(4)

1
m v2
6

A particle is moving in a circular path of 6.

radius a, with a constant velocity v as
shown in the figure. The center of circle is
marked by C. The angular momentum

a U SU
v
C
O U

from the origin O can be written as :

(1)
(1)
(2)
(3)
(4)

va(11cos 2u)
va(11cos u)
va cos 2u
va

English : 3

(2)
(3)
(4)

Set : 06

va(11cos 2u)
va(11cos u)
va cos 2u
va

Hindi : 3

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7.

7.
Two hypothetical planets of masses m1 and

m 2 are at rest when they are infinite

distance apart. Because of the gravitational

force they move towards each other along
the line joining their centres. What is their
speed when their separation is d ?

(Speed of m1 is v1 and that of m2 is v2)

(1) v 15v 2
(2)

(3)

(4)

v1 5 m 2

2G
d(m 11m 2 )

v2 5 m 1

2G
d(m 11m 2 )

v1 5 m 1

2G
d(m 11m 2 )

v2 5 m 2

2G
d(m 11m 2 )

v1 5 m 2

2G
m1

v2 5 m 1

2G
m2

English : 4

m1 m2 U
S U U U
L U
U U U U U U
U U d ,
?
( m1 v1 m2 v2 )
(1)

v 15v 2

(2)

v1 5 m 2

2G
d(m 11m 2 )

v2 5 m 1

2G
d(m 11m 2 )

v1 5 m 1

2G
d(m 11m 2 )

v2 5 m 2

2G
d(m 11m 2 )

v1 5 m 2

2G
m1

v2 5 m 1

2G
m2

(3)

(4)

Set : 06

Hindi : 4

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8.

Steel

ruptures

when

shear

of 8.

3.5310 8 N m 22 is applied. The force

needed to punch a 1 cm diameter hole in
a steel sheet 0.3 cm thick is nearly :

9.

(1)

1.43104 N

(2)

SU U U 3.53108 Nm22
M 0.3 cm U SU
U 1 cm U U

(1)

1.43104 N

2.73104 N

(2)

2.73104 N

(3)

3.33104 N

(3)

3.33104 N

(4)

1.13104 N

(4)

1.13104 N

A cylindrical vessel of cross-section A 9.

contains water to a height h. There is a
hole in the bottom of radius a. The time
in which it will be emptied is :
(1)

(2)

(3)

(4)

2A
pa

h
g

(1)

h
g

(2)

2A
pa 2
2 2A
pa

h
g

A
2 pa

English : 5

S U A U
h U a
U , U
,

(3)

h
g

(4)

Set : 06

Hindi : 5

2A
pa

h
g

2A

h
g

pa 2
2 2A
pa

h
g

A
2 pa

h
g

Set : 06

10.

Two soap bubbles coalesce to form a single 10.

bubble. If V is the subsequent change in
volume of contained air and S the change
in total surface area, T is the surface
tension and P atmospheric pressure, which

U
S U U
V U c U S ,
T cU U P U ,
- ?

of the following relation is correct ?

11.

(1)

4PV13ST50

(1)

4PV13ST50

(2)

3PV14ST50

(2)

3PV14ST50

(3)

2PV13ST50

(3)

2PV13ST50

(4)

3PV12ST50

(4)

3PV12ST50

Hot water cools from 608C to 508C in the 11.

first 10 minutes and to 428C in the next
10 minutes. The temperature of the

608C 508C 10 U UU
U 428C U 10 U UU
U

surroundings is :

12.

(1)

258C

(1)

258C

(2)

108C

(2)

108C

(3)

158C

(3)

158C

(4)

208C

(4)

208C

40%
50%
70%

A Carnot engine absorbs 1000 J of heat 12.

energy from a reservoir at 1278C and rejects
600 J of heat energy during each cycle. The
efficiency of engine and temperature of

U 1278C U 1000 J
c U U
600 J c SU U
U

sink will be :
(1)

20% and 2438C

(1)

(2)

40% and 2338C

(2)

(3)

50% and 2208C

(3)

(4)

70% and 2108C

(4)

English : 6

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20%

Hindi : 6

2438C
2338C
2208C
2108C

Set : 06

13.

1930 ms21. The gas is :

U U mU
-- 1930 ms21

(1)

H2

(1)

O2

(3)

At room temperature a diatomic gas is 13.

found to have an r.m.s. speed of

(2)
(3)
(4)
14.

Cl2

(2)

F2

(4)

Which of the following expressions 14.

corresponds to simple harmonic motion
along a straight line, where x is the

H2

Cl2
O2

F2

U U
U U , x S
U a, b, c SU ?

displacement and a, b, c are positive

constants ?

15.

(1)

a1bx2cx 2

(1)

a1bx2cx 2

(2)

bx2

(2)

bx2

(3)

a2bx1cx 2

(3)

a2bx1cx 2

(4)

2bx

(4)

2bx

A source of sound A emitting waves of 15.

frequency 1800 Hz is falling towards
ground with a terminal speed v. The
observer B on the ground directly beneath
the source receives waves of frequency
2150 Hz. The source A receives waves,

1800 Hz U U U
d A v U U U U
d U U U B
2150 Hz U U d A,
U U U
U ( 5343 m/s)

reflected from ground, of frequency

nearly : (Speed of sound 5343 m/s)
(1)

2150 Hz

(1)

2150 Hz

(2)

2500 Hz

(2)

2500 Hz

(3)

1800 Hz

(3)

1800 Hz

(4)

2400 Hz

(4)

2400 Hz

English : 7

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Hindi : 7

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16.

spherically

symmetric

charge 16.

distribution is characterised by a charge

density having the following variation :
r

r(r)5ro 1 2 for r < R

U
U U
r

r(r)5ro 1 2 r < R

r U U U ro
SU (r < R) U l

r(r)50

r(r)50
for r / R
Where r is the distance from the centre of
the charge distribution and ro is a constant.
The electric field at an internal point
(r < R) is :

r / R

(1)

ro r
r2
2

4eo 3
4R

(1)

ro r
r2
2

4e o 3
4R

(2)

ro r
r2
2

4R
eo 3

(2)

ro r
r2
2

4R
eo 3

(3)

ro r
r2
2

3e o 3
4R

(3)

ro r
r2
2

3eo 3
4R

(4)

ro r
r2
2

12 eo 3
4R

(4)

ro r
r2
2

12 eo 3
4R

English : 8

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Hindi : 8

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17.

The space between the plates of a parallel 17.

plate capacitor is filled with a dielectric
whose dielectric constant varies with
distance as per the relation :
K(x)5Ko1lx (l5 a constant)

The capacitance C, of this capacitor, would

be related to its vacuum capacitance Co

as per the relation :

U ^ U ^
S l U Ul
SU U U U

K(x)5Ko1lx (l5 SU)
U U C, U, Co
U

(1)

C5

ld
Co
l n (1 1 K o ld)

(1)

C5

ld
Co
l n (1 1 K o ld)

(2)

C5

l
Co
d. l n (1 1 K o ld)

(2)

C5

l
Co
d. l n (1 1 K o ld)

(3)

C5

ld
Co
l n (1 1 ld/K o )

(3)

C5

ld
Co
l n (1 1 ld/K o )

(4)

C5

l
Co
d. l n (1 1 K o /ld)

(4)

C5

l
Co
d. l n (1 1 K o /ld)

English : 9

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Hindi : 9

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18.

3 V, 9 V and 9 V and a capacitor 5.0 mF.

U 8.0 V 16.0 V
UU U 3 V, 9 V 9 V U
5.0 mF U

How much is the current I in the circuit in

S S U U I ?

The circuit shown here has two batteries 18.

of 8.0 V and 16.0 V and three resistors

steady state ?

19.

(1)

1.6 A

(1)

1.6 A

(2)

0.67 A

(2)

0.67 A

(3)

2.5 A

(3)

2.5 A

(4)

0.25 A

(4)

0.25 A

A positive charge q of mass m is moving 19.

along the 1x axis. We wish to apply a
uniform magnetic field B for time Dt so that
the charge reverses its direction crossing
the y axis at a distance d. Then :

m q, 1x
U B
Dt
d U U y - U
,

(1)

5

pd
mv
DQGDW5
qd
v

(1)

5

pd
mv
  D W5
qd
v

(2)

5

mv
pd
DQG D W5
2 qd
2v

(2)

5

mv
pd
  D W5
2 qd
2v

(3)

5

pd
2 mv
DQG D W5
qd
2v

(3)

5

pd
2 mv
  D W5
qd
2v

(4)

5

pd
2 mv
DQG D W5
qd
v

(4)

5

pd
2 mv
  D W5
qd
v

English : 10

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Hindi : 10

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20.

Consider two thin identical conducting 20.

wires covered with very thin insulating
material. One of the wires is bent into a
loop and produces magnetic field B1, at its
centre when a current I passes through it.

The second wire is bent into a coil with

three identical loops adjacent to each other
and produces magnetic field B 2 at the
centre of the loops when current I/3 passes

21.

M U U
U U
U
B1 U U I
U U M U U
UU U
U B2 U
U I/3 B1 : B2
(1)

1:1

through it. The ratio B1 : B2 is :

(1) 1 : 1

(2)

1:3

(3)

1:9

(2)

1:3

(4)

9:1

(3)

1:9

(4)

9:1

21.

A sinusoidal voltage V(t)5100 sin (500t)

U V(t)5100 sin (500t)

h U L50.02 H U
U U

is applied across a pure inductance of

L50.02 H. The current through the coil

(1)

10 cos (500t)

is :

(2)

210 cos (500t)

(1)

10 cos (500t)

(3)

10 sin (500t)

(2)

210 cos (500t)

(4)

210 sin (500t)

(3)

10 sin (500t)

(4)

210 sin (500t)

English : 11

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Hindi : 11

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22.

A lamp emits monochromatic green light 22.

uniformly in all directions. The lamp is 3%
efficient in converting electrical power to
electromagnetic waves and consumes
100 W of power. The amplitude of the
electric

field

associated

with

the

M
U U U l
l U U U
3% U 100 W U
5 m U U l U
h l

electromagnetic radiation at a distance of

(1)

1.34 V/m

5 m from the lamp will be nearly :

(2)

2.68 V/m

(1)

1.34 V/m

(3)

4.02 V/m

(2)

2.68 V/m

(4)

5.36 V/m

(3)

4.02 V/m

(4)

5.36 V/m

English : 12

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Hindi : 12

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23.

The refractive index of the material of a 23.

concave lens is m. It is immersed in a
medium of refractive index m1. A parallel
beam of light is incident on the lens. The
path of the emergent rays when m1 > m is :

m
m1 U
U U
m1 > m , U

(1)

(1)

(2)

(2)

(3)

(3)

(4)

(4)

English : 13

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Hindi : 13

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24.

Interference pattern is observed at P due 24.

to superimposition of two rays coming out
from a source S as shown in the figure.
The value of l for which maxima is
obtained at P is :

d S U U U
P U U ,
l ,
P U ,
(R U cU )

(R is perfect reflecting surface) :

(1)
(2)
(3)
(4)

l5

l5
l5
l5

2 nl
321

(2n21)l
2 ( 3 2 1)
(2n21)l 3
4 ( 22 3 )
(2n21)l
3 21

25.
25.

In an experiment of single slit diffraction

pattern, first minimum for red light
coincides with first maximum of some

2 nl
321

(1)

l5

(2)

l5

(2n21)l
2 ( 3 2 1)

(3)

l5

(2n21)l 3
4 ( 22 3 )

(4)

l5

(2n21)l
3 21

SU ,
U U
U 6600
, U

other wavelength. If wavelength of red

light is 6600 , then wavelength of first
maximum will be :

(1)

3300

(1)

3300

(2)

4400

(2)

4400

(3)

5500

(3)

5500

(4)

6600

(4)

6600

English : 14

Set : 06

Hindi : 14

Set : 06

26.

A beam of light has two wavelengths 26.

4972 and 6216 with a total intensity
of 3.631023 Wm22 equally distributed
among the two wavelengths. The beam
falls normally on an area of 1 cm2 of a clean
metallic surface of work function 2.3 eV.
Assume that there is no loss of light by
reflection and that each capable photon
ejects one electron. The number of photo
electrons

liberated

in

2s

UZ 4972 6216
3.631023 Wm22
UZ U 2.3 eV
c U
1 cm2 U
U mU
O U U U
U 2s U U

is

approximately :

27.

(1)

6310 11

(1)

6310 11

(2)

9310 11

(2)

9310 11

(3)

11310 11

(3)

11310 11

(4)

15310 11

(4)

15310 11

A piece of bone of an animal from a ruin 27.

is found to have

14 C

activity of

12 disintegrations per minute per gm of

its carbon content. The 14C activity of a
living animal is 16 disintegrations per
minute per gm. How long ago nearly did
the animal die ? (Given half life of

UU a U
14C
U 12 U 14C
16 U U
? ( 14C h
t1/255760 )

14C

is t1/255760 years)
(1) 1672 years

(1)

1672

(2)

2391 years

(2)

2391

(3)

3291 years

(3)

3291

(4)

4453 years

(4)

4453

English : 15

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Hindi : 15

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28.

For LEDs to emit light in visible region of 28.

electromagnetic light, it should have
energy band gap in the range of :

29.

(1)

0.1 eV to 0.4 eV

(2)

0.5 eV to 0.8 eV

(3)

0.9 eV to 1.6 eV

(4)

1.7 eV to 3.0 eV

For sky wave propagation, the radio 29.

waves must have a frequency range in

l
U, U
U
(1) 0.1 eV 0.4 eV
(2) 0.5 eV 0.8 eV
(3) 0.9 eV 1.6 eV
(4) 1.7 eV 3.0 eV
U U , UU U
U

LEDs

between :

30.

(1)

1 MHz to 2 MHz

(1)

(2)

5 MHz to 25 MHz

(2)

(3)

35 MHz to 40 MHz

(3)

(4)

45 MHz to 50 MHz

(4)

In the experiment of calibration of 30.

voltmeter, a standard cell of e.m.f. 1.1 volt
is

balanced

against

440

cm

of

potentiometer wire. The potential

difference across the ends of resistance is
found to balance against 220 cm of the

2 MHz
5 MHz 25 MHz
35 MHz 40 MHz
45 MHz 50 MHz

1 MHz

U , 1.1 U
l
440 cm U
U U U U U 220 cm
U U
0.5 U U U U

wire. The corresponding reading of

voltmeter is 0.5 volt. The error in the
reading of voltmeter will be :
(1)

20.15 volt

(1)

(2)

0.15 volt

(2)

(3)

0.5 volt

(3)

(4)

20.05 volt

(4)

English : 16

Set : 06

U
0.15 U
0.5 U
20.05 U
20.15

Hindi : 16

Set : 06

PART B CHEMISTRY
31.

If m and e are the mass and charge of the 31.

revolving electron in the orbit of radius r
for hydrogen atom, the total energy of the

B U
U r UU
U m U e
, U

revolving electron will be :

32.

(1)

1 e2
2 r

(1)

1 e2
2 r

(2)

e2
r

(2)

(3)

me 2
r

(3)

me 2
r

(4)

(4)

1 e2
2 r

The de-Broglie wavelength of a particle of 32.

mass 6.63 g moving with a velocity of
100 ms21 is :

33.

e2
r

1 e2
2 r

6.63 g 100 ms21

U - U

(1)

10233 m

(1)

10233 m

(2)

10235 m

(2)

10235 m

(3)

10231 m

(3)

10231 m

(4)

10225 m

(4)

10225 m

What happens when an inert gas is added 33.

to an equilibrium keeping volume
unchanged ?
(1)

More product will form

(2)

Less product will form

(3)

More reactant will form

(4)

Equilibrium will remain unchanged

English : 17

Set : 06

U U U
S U ?
(1)
(2)
(3)
(4) U U

Hindi : 17

Set : 06

34.

The amount of BaSO4 formed upon mixing 34.

100 mL of 20.8% BaCl 2 solution with

50 mL of 9.8% H2SO4 solution will be :

(Ba5137, Cl535.5, S532, H51 and
O516)

35.

U
O516 20.8% BaCl2
100 mL 9.8%, H 2 SO 4
50 mL U BaSO4 ?
Ba5137, Cl535.5, S532, H51

(1)

23.3 g

(1)

23.3 g

(2)

11.65 g

(2)

11.65 g

(3)

30.6 g

(3)

30.6 g

(4)

33.2 g

(4)

33.2 g

The rate coefficient (k) for a particular 35.

reactions is
and

1.331024

1.331023

M21

M21 s21

s21

at 1008C,

at 1508C. What

is the energy of activation (EA) (in kJ) for

this reaction ? (R5molar gas
constant58.314 JK21 mol21)

U U (k)
1.331024 M21 s21 U 1508C U
1.331023 M21 s21
U (EA) kJ ?
(R5U 58.314 JK21 21)
1008C

(1)

16

(1)

16

(2)

60

(2)

60

(3)

99

(3)

99

(4)

132

(4)

132

English : 18

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Hindi : 18

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36.

How many electrons would be required to 36.

deposit 6.35 g of copper at the cathode
during the electrolysis of an aqueous
solution of copper sulphate ? (Atomic mass
of copper 5 63.5 u, N A 5Avogadros
constant) :

37.

U $UU U
U 6.35 U
U ? (U
U 5 63.5 , NA5
)

(1)

NA
20

(1)

NA
20

(2)

NA
10

(2)

NA
10

(3)

NA
5

(3)

NA
5

(4)

NA
2

(4)

NA
2

The entropy (S o ) of the following 37.

substances are :
CH4 (g) 186.2 J K21 mol21
O2

(g) 205.0 J K21 mol21

CO 2 (g) 213.6 J K21 mol21

H2O (l) 69.9

J K21 mol21

The entropy change (DSo) for the reaction

CH4(g)12O2(g) CO2(g)12H2O(l) is :
(1) 2312.5 J K21 mol21
(2)
(3)
(4)

2242.8 J K21 mol21

Z U (So)
CH4 (g) 186.2 J K21 21
O 2 (g) 205.0 J K21 21
CO 2 (g) 213.6 J K21 21
H2O (l) 69.9 J K21 21

CH 4 (g)12O 2 (g) CO 2 (g)12H 2 O(l)

U U (DSo)
(1)
(2)

2108.1 J

K21

mol21

(3)

237.6 J

K21

mol21

(4)

English : 19

Set : 06

21
2242.8 J K21 21
2108.1 J K21 21
237.6 J K21 21
2312.5 J K21

Hindi : 19

Set : 06

38.

39.

The conjugate base of hydrazoic acid is : 38.

(1)

N23

(2)

(1)

N23

N2
3

(2)

N2
3

(3)

N2
2

(3)

N2
2

(4)

HN2
3

(4)

HN2
3

In a monoclinic unit cell, the relation of 39.

sides and angles are respectively :

40.

U$ U U

(1)

a5b c and a5b5g5908

(2)

a b c and a5b5g5908

(3)

a b c and b5g5908 a

(4)

a b c and a b g 908

The standard enthalpy of formation 40.

(D f H o 298 )

for

methane,

CH 4

is

274.9 kJ mol21. In order to calculate the

average energy given out in the formation

U
(1) a5b c U a5b5g5908
(2) a b c U a5b5g5908
(3) a b c U b5g5908 a
(4) a b c U a b g 908
,

CH4,

(DfHo298)
274.9 kJ 21 C2H
U
?

of a C2H bond from this it is necessary to

know which one of the following ?
(1)

the dissociation energy of the

(1)

(2)

hydrogen molecule, H2.

the first four ionisation energies of

H2

(2)

(3)

H2

U ($)U

(4)

U
U U

carbon.
(3)

the dissociation energy of H2 and

enthalpy of sublimation of carbon
(graphite).

(4)

the first four ionisation energies of

carbon and electron affinity of

hydrogen.

English : 20

Set : 06

Hindi : 20

Set : 06

41.

hydrolysis of xenon fluorides ?

$ UU U $-
?

(1)

(1)

Which of the following xenon-OXO 41.

compounds may not be obtained by

(2)
(3)
(4)
42.

Xe O2F2
Xe O F4

(2)

Xe O3
Xe O4

(3)
(4)

Excited hydrogen atom emits light in the 42.

ultraviolet region at

2.4731015

Hz. With

this frequency, the energy of a single

Xe O2F2
Xe O F4
Xe O3
Xe O4

U U
U U U
U
2.47310 15 Hz

(h56.63310234 Js)

photon is :
(h56.63310234 Js)

43.

(1)

8.041310 240 J

(1)

8.041310240 J

(2)

2.680310 219 J

(2)

2.680310219 J

(3)

1.640310 218 J

(3)

1.640310218 J

(4)

6.111310 217 J

(4)

6.111310217 J

largest number of oxidation states ?

U
S ?

(1)

Ti (22)

(1)

Ti (22)

(2)

V(23)

(2)

V(23)

(3)

Cr (24)

(3)

Cr (24)

(4)

Mn (25)

(4)

Mn (25)

Which one of the following exhibits the 43.

English : 21

Set : 06

Hindi : 21

Set : 06

44.

Copper becomes green when exposed to 44.

moist air for a long period. This is due to :
(1)

the formation of a layer of cupric

oxide on the surface of copper.

(2)

the formation of a layer of basic

carbonate of copper on the surface

U U
U U U
(1) U U U U

(2) U U U U U
U

of copper.
(3)

the formation of a layer of cupric

(3)

hydroxide on the surface of copper.

(4)

the formation of basic copper

(4)

sulphate layer on the surface of the

U U UU U

U U U $U U

metal.
45.

Among the following species the one 45.

which causes the highest CFSE, Do as a

Z U M
CFSE, Do U ?

ligand is :
(1)

CN2

(1)

CN2

(2)

NH3

(2)

F2

(3)

NH3

CO

(4)

(3)
(4)
46.

Similarity in chemical properties of the 46.

atoms of elements in a group of the
Periodic table is most closely related to :
(1)

atomic numbers

(2)

atomic masses

(3)

number of principal energy levels

(4)

number of valence electrons

English : 22

Set : 06

F2

CO

U U
U U

(1) U U
(2) U
(3) (Principal) SU
(4) U

Hindi : 22

Set : 06

47.

Which of the following arrangements 47.

represents the increasing order (smallest
to largest) of ionic radii of the given species
O22, S22, N32, P32 ?

48.

S Z
O22, S22, N32, P32
( ) S U ?

(1)

O22< N32< S22 < P32

(1)

O22< N32< S22 < P32

(2)

O22< P32< N32 < S22

(2)

O22< P32< N32 < S22

(3)

N32 < O22< P32 < S22

(3)

N32 < O22< P32 < S22

(4)

N32< S22< O22 < P32

(4)

N32< S22< O22 < P32

Global warming is due to increase of :

(1)

48.

methane and nitrous oxide in

U U U

(1) U U U

atmosphere
(2)
(3)
(4)
49.

methane and CO2 in atmosphere

methane and O3 in atmosphere

(2)
(3)

methane and CO in atmosphere

(4)

Hydrogen peroxide acts both as an 49.

oxidising and as a reducing agent
depending upon the nature of the reacting
species. In which of the following cases
H 2 O 2 acts as a reducing agent in acid

U CO2
U O3
U CO

U UU
U U U U U U
U S$ S U
H2O2
M U ?

medium ?
(1)

MnO42

(1)

MnO42

(2)

Cr2 O 7

(2)

Cr2 O 7

(3)

SO 3

(3)

SO 3

(4)

KI

(4)

KI

22

22

English : 23

Set : 06

22

22

Hindi : 23

Set : 06

50.

Which one of the following complexes will 50.

most likely absorb visible light ?
(At nos. Sc521, Ti522, V523, Zn530)
(1)
(2)
(3)
(4)

[Sc(H2O)6]31

Zn530)

]41

[Ti (NH3)6
[V(NH3)6]31

(1)
(2)

[Zn(NH3)6]21

51.

(U)
U U ?
( U Sc521, Ti522, V523,

(3)
(4)
on mercuration-

51.

[Sc(H2O)6]31

[Ti (NH3)6]41
[V(NH3)6]31

[Zn(NH3)6]21

UU-UU

demercuration produces the major

product :

(1)

(1)
(2)
(2)
(3)
(3)
(4)
(4)
52.

In the Victor-Meyers test, the colour given

by 18, 28 and 38 alcohols are respectively : 52.
(1)

Red, colourless, blue

(2)

Red, blue, colourless

(3)

Colourless, red, blue

(4)

Red, blue, violet

English : 24

Set : 06

UU U U 18, 28 U
mU U U
(1) , U,
(2) , , U
(3) U, ,
(4) , ,

Hindi : 24

38

Set : 06

53.

Conversion of benzene diazonium chloride 53.

to chloro benzene is an example of which
of the following reactions ?

54.

(1)

Claisen

(2)

Friedel-craft

(3)

Sandmeyer

(4)

Wurtz

In the presence of peroxide, HCl and HI 54.

do not give anti-Markownikoffs addition

$ U$ UU U $
U
?
(1) $
(2) U-$$U
(3) UU
(4) U $
UU S HCl U
HI UU

to alkenes because :
(1)

One of the steps is endothermic in

(1)

HCl and HI
(2)

Both HCl and HI are strong acids

(2)

(3)

HCl is oxidizing and the HI is

(3)

reducing
(4)

All the steps are exothermic in HCl

(4)

and HI
55.

The major product obtained in the photo 55.

catalysed bromination of 2-methylbutane

mU U

(1)

1-bromo-2-methylbutane

(1)

(2)

1-bromo-3-methylbutane

(2)

(3)

2-bromo-3-methylbutane

(3)

(4)

2-bromo-2-methylbutane

(4)

Set : 06

U HI U
c
HCl

2- U

is :

English : 25

U HI U
c
HCl U HI ,
HCl U HI
HCl

1--2-U
1--3-U
2--3-U

2--2-U

Hindi : 25

Set : 06

56.

sigma(s) and two pi(p) bonds ?

(s) U
(p) ?

(1)

C 2H 4

(1)

C2H2Cl2

(3)

Which of the following molecules has two 56.

(2)
(3)
(4)
57.

N2F2

(2)

HCN

(4)

Which one of the following acids does not 57.

exhibit optical isomerism ?

58.

59.

(1)

Lactic acid

(2)

Tartaric acid

(3)

Maleic acid

(4)

a-amino acids

Aminoglycosides are usually used as :

(1)

antibiotic

(2)

analgesic

(3)

hypnotic

(4)

antifertility

58.

Which of the following will not show 59.

C2H2Cl2

HCN

UUU ?

(1)

Maltose

(1)

(2)

Lactose

(2)

(3)

Glucose

(3)

(4)

Sucrose

(4)

Set : 06

N2F2

?
(1) U U
(2) UUUU U
(3) U
(4) a- U
U U
?
(1) U U M ( )
(2) M ( )
(3) U M ( )
(4) U UUU M (U )

mutarotation ?

English : 26

C2H 4

U$
U$
$
$

Hindi : 26

Set : 06

60.

Phthalic acid reacts with resorcinol in the 60.

presence of concentrated H2SO4 to give :
(1)

Phenolphthalein

(2)

Alizarin

(3)

Coumarin

(4)

Fluorescein

English : 27

Set : 06

H 2SO4 S U
U$U U
(1)
(2) $U
(3)
(4) $U

Hindi : 27

Set : 06

PART C MATHEMATICS
61.

A relation on the set A5{x : ?x? < 3, xeZ}, 61.

where Z is the set of integers is defined by
R5{(x, y) : y 5? x ? , x 2 1 }. Then the
number of elements in the power set of R

A5{x : ?x? < 3, xeZ}, Z Z

, U R,
R5{(x, y) : y5?x?, x 2 1 } mU U
R

is :

62.

(1)

32

(1)

32

(2)

16

(2)

16

(3)

(3)

(4)

64

(4)

64

z 2i

Let z 2i be any complex number such 62.

that

z2 i
is a purely imaginary number.
z1 i

Then z1

z2 i
z1 i

1
is :
z

z1

h ,

1
z

(1)

(1)

(2)

any non-zero real number other

(2)

1 U U S

U S
h

than 1.

63.

(3)

any non-zero real number.

(3)

(4)

a purely imaginary number.

(4)

x21?2x23?2450, is :

U x21?2x23?2450,

(1)

(1)

(2)

22

(2)

22

(3)
(4)

(3)
(4)

The sum of the roots of the equation, 63.

2 2

English : 28

Set : 06

2 2

Hindi : 28

Set : 06

64.

64.

If
a2

65.

66.

b2

( a1l

)2

( a2l

)2

c2

( b1l

)2

( b2l

)2

a2

a2

b2

( c1l 5k l a

c , l 0,

)2

( c2l

)2

c2

b2

( a1l

)2

( a2l

)2

c2

( b1l

)2

( b2l

)2

, k UU

(1)

4labc

(1)

4labc

(2)

24labc

(2)

24labc

(3)

4l2

(3)

4l2

(4)

24l2

(4)

24l2

y
x
1 2
If A 5
and
B 5 x be such 65.

3 21 2
1

6
that AB 5 , then :
8

6
AB 5 , ,
8

(1)

y52x

(1)

y52x

(2)

y522x

(2)

y522x

(3)

y5x

(3)

y5x

(4)

y52x

(4)

y52x

digits 1, 1, 2, 2, 2, 3, 4, 4. The number of

such numbers in which the odd digits do

b2

( c1l 5k l a

c , l 0,

( c2l

then k is equal to :

8 - digit numbers are formed using the 66.

a2

)2
)2

x
1 2
A5

3 21 2

c2

y
B 5 x

1

1, 1, 2, 2, 2, 3, 4, 4 , U

S U ,

not occupy odd places, is :

(1)

160

(1)

160

(2)

120

(2)

120

(3)

60

(3)

60

(4)

48

(4)

48

English : 29

Set : 06

Hindi : 29

Set : 06

67.

x 55

If 2 1 is expanded in the ascending 67.

3

x 55

21
3

x U U

U U, U x
,

powers of x and the coefficients of powers

of x in two consecutive terms of the
expansion are equal, then these terms
are :

68.

(1)

7th and 8th

(1)

(2)

8th

(2)

and

9th

(3)

28th

29th

(3)

(4)

27th and 28th

(4)

and

8
8 9
28 29
27 28

Let G be the geometric mean of two 68.

a b U G

positive numbers a and b, and M be the

1
1
arithmetic mean of 1 and . If
: G is
b
M
a
4 : 5, then a : b can be :

69.

1 1
b
a

(1)

1:4

1
: G 5 4 : 5 ,
M
(1) 1 : 4

(2)

1:2

(2)

1:2

(3)

2:3

(3)

2:3

(4)

3:4

(4)

3:4

The least positive integer n such that 69.

12

2
2
2
1
2 2 2........ 2 n21 <
, is :
3
100
3
3

Z
12

(1)

(2)

(2)

(3)

(3)

(4)

(4)

Set : 06

Hindi : 30

a : b

2
2
2
1
2 2 2........ 2 n21 <
,
3
100
3
3

(1)

English : 30

Set : 06

70.

Let f, g : RR be two functions defined by 70.

(2)

Both statements I and II are true.

(3)

Statement I is true, statement II is

1
x sin , x 0
x
, g ( x ) 5 x f ( x )
0
, x50

mU U
I : x50 U f
II : x50 U g

71.

1
, and g(x) is its
2
inverse function, then g9(7) equals :

If f(x)5x22x15, x >

(1)

1
2
3

(2)

1
13

(3)

1
3

(4)

1
2
13

English : 31

Set : 06

(4)

I ,

(2)

Statement I is false, statement II is

true.

(3)

I II
I II
I , II

(1)

false.
(4)

f (x)5

Statement I : f is a continuous function at

x50.
Statement II : g is a differentiable function
at x50.
Both statements I and II are false.

f, g : RR

1
x sin , x 0
x
, and g ( x ) 5 x f ( x )
0
, x50

f (x)5

(1)

71.

f(x)5x22x15, x >

II

1
, g(x)
2

, g9(7) UU
1
3

(1)

(2)

1
13

(3)

1
3

(4)

Hindi : 31

1
13

Set : 06

72.

all x e R. Then for all x :

R U f g
x e R f 9(x) > 0 g9(x) < 0 ,
x

(1)

f(g(x)) > f (g(x21))

(1)

f(g(x)) > f(g(x21))

(2)

f(g(x)) > f (g(x11))

(2)

f(g(x)) > f(g(x11))

(3)

g(f(x)) > g (f(x21))

(3)

g(f(x)) > g(f(x21))

(4)

g(f(x)) < g (f(x11))

(4)

g(f(x)) < g(f(x11))

Let f and g be two differentiable functions 72.

on R such that f 9(x) > 0 and g9(x) < 0, for

73.

i
If 11x41x55 ai ( 1 1 x ) , for all x in R,

73.

i50

x e R

ai ( 1 1 x )i , a2

11x41x55

then a2 is :

74.

i50

(1)

24

(1)

24

(2)

(2)

(3)

28

(3)

28

(4)

10

(4)

10

The integral

sin 2 x cos2 x
3

sin x 1 cos

x)

d x is 74.
2

sin 2 x cos 2 x

( sin 3 x 1 cos3 x )2

dx

UU

equal to :
1

(1)

( 1 1 cot x )

(2)

3 ( 1 1 tan 3 x )

sin 3 x

(3)

( 1 1 cos3 x )

(4)

English : 32

1c

cos 3 x

1c

1c

3 ( 1 1 sin 3 x )

1c

Set : 06

(1)

( 1 1 cot 3 x )

(2)

3 ( 1 1 tan 3 x )

sin 3 x

(3)

( 1 1 cos3 x )

(4)

Hindi : 32

1c

cos 3 x

1c

1c

3 ( 1 1 sin 3 x )

1c

Set : 06

75.

If [ ] denotes the greatest integer function, 75.

then the integral

(2)

p
2
0

(3)

21

(4)

(1)

76.

p
2

2
2
( f ( x ) 1 x)d x 5 p 2 t ,

for

all

p
t/2p, then f 2 is equal to :
3

(1)

(2)

p
2

(3)
(4)

p
3
p
6

English : 33

Set : 06

Z ,

(2)

p
2
0

(3)

21

(4)

(1)

[ ]

p
0 [ cos x ] d x UU

0 [ cos x ] d x is equal to :

If for a continuous function f(x), 76.

2p

p
2

t /2p

f(x)

2
2
( f ( x ) 1 x)d x 5 p 2 t

2p

p
f 2
3

(1)

(2)

p
2

(3)

p
3

(4)

p
6

Hindi : 33

UU

Set : 06

77.

The general solution of the differential 77.

dy
equation, sin 2x
2
dx

dy
sin 2x
2
dx

tan x 2 y 5 0 ,

(1)

y tan x 5x1c

(1)

y tan x 5x1c

(2)

y cot x 5tan x1c

(2)

y cot x 5tan x1c

(3)

y tan x 5cot x1c

(3)

y tan x 5cot x1c

(4)

y cot x 5x1c

(4)

y cot x 5x1c

(1)

4x23y57

If a line intercepted between the coordinate 78.

axes is trisected at a point A(4, 3), which
is nearer to x-axis, then its equation is :

79.

is :

78.

tan x 2 y 5 0

U U,
A(4, 3) x- , U S
, U

(1)

4x23y57

(2)

3x12y518

(2)

3x12y518

(3)

3x18y536

(3)

3x18y536

(4)

x13y513

(4)

x13y513

If the three distinct lines x12ay1a50, 79.

x13by1b50 and x14ay1a50 are
concurrent, then the point (a, b) lies on a :
(1)

circle

(2)

hyperbola

(3)

straight line

(4)

parabola

English : 34

Set : 06

U x12ay1a50,
x13by1b50 x14ay1a50 ,
(a, b)
(1) U S
(2) U U S
(3) U U U S
(4) U U S

Hindi : 34

Set : 06

80.

For the two circles x 2 1y 2 516 and 80.

x21y222y50, there is/are :

81.

(1)

one pair of common tangents

(2)

two pairs of common tangents

(3)

three common tangents

(4)

no common tangent

Two tangents are drawn from a point 81.

(22, 21) to the curve, y254x. If a is the
angle between them, then ?tan a? is equal

x21y2516 x21y222y50,
/
(1) cU S U
(2) cU S U
(3) cU S U
(4) cU S U
(22, 21) y254x U
S U , a
, ?tan a? UU

to :
(1)

1
3

(1)

(2)

1
3

(2)

1
3

(3)

(3)

(4)
82.

1
3

(4)

The minimum area of a triangle formed

by

any

tangent

to

the

ellipse 82.

y2
x2
1
5 1 and the co-ordinate axes
16
81

y2
x2
1
51
16
81

U S

U mU

is :
(1)

12

(1)

12

(2)

18

(2)

18

(3)

26

(3)

26

(4)

36

(4)

36

English : 35

Set : 06

Hindi : 35

Set : 06

83.

A symmetrical form of the line of 83.

intersection of the planes x5ay1b and

x5ay1b
U M

z5cy1d

z5cy1d is :

84.

(1)

y 21
x2b
z2d
5
5
a
1
c

(1)

y 21
x2b
z2d
5
5
a
1
c

(2)

y 21
x 2 b2 a
z 2 d2 c
5
5
a
1
c

(2)

y 21
x 2 b2 a
z 2 d2 c
5
5
a
1
c

(3)

y 20
x2a
z2c
5
5
b
1
d

(3)

y 20
x2a
z2c
5
5
b
1
d

(4)

y 21
x 2 b2 a
z 2 d2 c
5
5
b
0
d

(4)

y 21
x 2 b2 a
z 2 d2 c
5
5
b
0
d

If

the

distance

between

planes, 84.

4x22y24z1150

and

4x22y24z1d50 U 7, d

4x22y24z1d50 is 7, then d is :

85.

(1)

41 or 242

(1)

(2)

42 or 243

(2)

(3)

241 or 43

(3)

(4)

242 or 44

(4)

4x22y24z1150

242
42 243
241 43
242 44
41

If x , y and z are three unit vectors in 85.

three-dimensional space, then the

minimum value of

?x 1 y?2 1 ?y 1 z?2 1 ?z 1 x?2 is :

(1)
(2)
(3)
(4)

3
2
3

(2)
(3)
(4)

English : 36

Set : 06

?x 1 y?2 1 ?y 1 z?2 1 ?z 1 x?2

(1)

3 3

x, y

3
2
3

3 3
6

Hindi : 36

Set : 06

86.

Let X and M.D. be the mean and the mean 86.

n xi, i51, 2, ....., n

deviation about X of n observations

M.D.
5

xi, i51, 2, ....., n. If each of the observations

is increased by 5, then the new mean and

the mean deviation about the new mean,
respectively, are :

87.

(1)

X , M.D.

(1)

X , M.D.

(2)

X 15, M.D.

(2)

X 15, M.D.

(3)

X , M.D.15

(3)

X , M.D.15

(4)

X 15, M.D.15

(4)

X 15, M.D.15

event : A5 the chosen number x satisfies

{1, 2, 3, 4, ....., 100} x

U U A U
A5 x

( x 2 10) ( x 2 50)
/0
( x 2 30)

( x 2 10) ( x 2 50)
/0
( x 2 30)

A number x is chosen at random from the 87.

set {1, 2, 3, 4, ....., 100}. Define the

P(A)

Then P(A) is :
(1)

0.71

(2)

0.70

(3)

0.51

(4)

0.20

English : 37

c U

Set : 06

(1)

0.71

(2)

0.70

(3)

0.51

(4)

0.20

Hindi : 37

Set : 06

88.

Statement

The

equation 88.

(sin 21 x) 3 1(cos 21 x) 3 2ap 3 50 has a

I:

(sin21x)31(cos21x)32ap350

solution for all a/ 1 .

32
Statement II : For any x e R,
sin21x1cos21x5

32
II :

a/

p
and
2

xeR

sin21x1cos21x5

p
2

p 2 9p2
21
0 [ sin x2 [
.

4
16

p 2 9p2
21
0 [ sin x2 [
.

4
16

(1)

Both statements I and II are true.

(1)

(2)

Both statements I and II are false.

(2)

(3)

Statement

is

true

and

(3)

I II
I II
I II

false

and

(4)

I S , II

statement II is false.
(4)

Statement

is

statement II is true.

1
89.

cos u

2cos u and
If f (u) 5 2sin u 1
21
sin u
1
A and B are respectively the maximum and
the minimum values of f (u), then

89.

cos u

2cos u
f (u) 5 2sin u 1
21
sin u
1

A B f (u)
, (A, B) UU

(A, B) is equal to :
(1)

(3, 21)

(2)

(4, 22 2 )

(1)

(3, 21)

(3)

( 21

2, 22 2)

(2)

(4, 22 2 )

(4)

( 21

2 , 21 )

(3)

( 21

2, 22 2)

(4)

( 21

2 , 21 )

English : 38

Set : 06

Hindi : 38

Set : 06

90.

Let p, q, r denote arbitrary statements. Then 90.

the

logically

equivalent

of

the

p, q, r

S U
p (q r)

statement p (q r) is :
(1)

(p q) r

(1)

(p q) r

(2)

(p q) (p r)

(2)

(p q) (p r)

(3)

(p ~q) (p r)

(3)

(p ~q) (p r)

(4)

(p q) (p ~r)

(4)

(p q) (p ~r)

-o0o-

English : 39

-o0o-

Set : 06

Hindi : 39

Set : 06